Chemistry Syllabus 2019-22

Bhavan’s Vivekananda College
Of Science, Humanities and Commerce

Autonomous College – Affiliated to Osmania University
Accredited with ‘A’ Grade by NAAC
Sainikpuri, Secunderabad – 500094
Ph : +91-04-27111611, 27115878
Visit us at: www.bhavansvc.ac.in
CHEMISTRY
SYLLABUS
(2019-22)
CBCS SYSTEM
Page 1 of 3
CREDITS IN CHEMISTRY
CHEMISTRY -MbGC,MbBcC,BTGC (2019-22)
I YEAR SEMESTER-I
CODE COURSE TITLE COURSE HPW CREDITS
TYPE
CT135 CHEMISTRY-I DSC-3A 4T+2P=6 4+1=5
6 5
I YEAR SEMESTER-II
TYPE
CT235 CHEMISTRY-II DSC-3B 4T+2P=6 4+1=5
6 5
II YEAR SEMESTER-III
TYPE
CT335 ORGANIC CHEMISTRY-II AND DSC-3C 4T+2P=6 4+1=5
GENERAL CHEMISTRY -II
SE 335 CHEMISTRY SEC-1 2 2
8 7
TYPE
CT435 PHYSICAL CHEMISTRY-II AND DSC-3D 4T+2P=6 4+1=5
INORGANIC CHEMISTRY-II
8 7
III YEAR SEMESTER-V

TYPE
GE535 CHEMISTRY GE-1 2 2
CT535 ORGANIC CHEMISTRY- DSC-3E 3T+2P=5 3+1=4
III,INORGANIC CHEMISTRY-
III&PHYSICAL CHEMISTRY-III
CT535A PHYSICO-CHEMICAL METHODS OF DSE-3E 3T+2P=5 3+1=4
ANALYSIS, SPECTROSCOPY AND
CATALYSIS/ SPECTROSCOPY
,ELECTRO ANALYTICAL
TECHNIQUES, ANALYSIS OF
WATER.
14 12
Page 2 of 3
III YEAR SEMESTER-VI
TYPE
GE 635 CHEMISTRY GE-2 2 2
CT635 ORGANIC CHEMISTRY- DSC-3F 3T+2P=5 3+1=4
IV,INORGANIC CHEMISTRY-
IV&PHYSICAL CHEMISTRY-IV
CT635A DRUGS AND FORMULATIONS, DSE-3F 3T+2P=5 3+1=4
PESTICIDES, MACROMOLECULES/
BIOMOLECULES.
14 12
TOTAL CREDITS 56 48
Page 3 of 3
BHAVAN’S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND COMMERCE,
SAINIKPURI, SECUNDERABAD. Autonomous College
Affiliated to OSMANIA UNIVERSITY, Hyderabad.
(Accredited with ‘A’ grade by NAAC)
Department Of Chemistry
PRGORAM NAME: MbGC, MbBcC, BtGC
Course Name: Inorganic/Organic/Physical and General Chemistry-I
PAPER CODE: CT135 & CT135P HPW:4
YEAR/SEMESTER: I/I No. Of Credits:4 Theory+1 Practical
COURSE OBJECTIVE: To familiarize the students with the basic concepts of physical,
organic, inorganic & general chemistry
UNIT WISE COURSE OBJECTIVES:

COb1. To explain the basic concepts of structural inorganic chemistry, s- & p- block elements &
organometallic chemistry.
COb2.To explain basics in stereochemistry of organic compounds & various reactions of acyclic
hydrocarbons.
COb3.To explain the concepts involved in gaseous state, liquid state and solutions.
COb4. To discuss concepts of principles involved in qualitative analysis of ions & electronic effects,
types of organic reactions.
UNIT I-Inorganic Chemistry-I 15 hrs (1 h / w)
1. Structural inorganic chemistry 4h
2. s-Block elements 2h
3. Organometallic Chemistry 4h
4. p-Block elements - I 5h
UNIT II-Organic Chemistry-I 15 hrs (1 h / w)
1. Stereo chemistry of carbon compounds 8h
2. Acyclic hydrocarbons 7h
UNIT III-Physical Chemistry-I 15 hrs (1 h / w)

1. Gaseous State 5h
2. Liquid State 4h
3. Solutions 6h
Page 1 of 12
UNIT IV - General Chemistry-I 15 hrs (1 h / w)
1. General principles of Inorganic qualitative analysis 6h
2. Structural theory in Organic Chemistry 9h
I - SEMESTER (Theory)
I SEMESTER / PAPER - I (60 hrs / 15 weeks)
(Inorganic/Organic/Physical and General Chemistry-I)
-------------------------------------------------------------------------------------------------------------------------------
UNIT I-Inorganic Chemistry-I 15 hrs (1 h / w)
S1-I-1. Structural Inorganic Chemistry: (4h)
Ionization energy, electro positivity, basic nature, reducing behavior, electron affinity, concept of
electronegativity- methods of determination and evaluation-Paulings approach. Mullikens approach,
applications in predicting and explaining chemical nature of bond, bond length and bond angles, diagonal
relationship.
S1-I-2. s-block elements: (2 h)
General characteristics of groups I & II elements, diagonal relationship between Li & Mg, Be & Al.
S1-I-3. Organometallic Chemistry (4 h)
Definition and classification of organometallic compounds, nomenclature, preparation, properties and
applications of alkyls of 1, 2 and 13 group elements.
S1-I-4. p-block elements: (5 h)
Group – 13: Synthesis and structure of diborane and higher boranes (B4H10 and B5H9), Boron-nitrogen
compounds (B3N3H6 and BN), Lewis acid nature of BX 3.
Group – 14: Preparation and applications of silanes and silicones.
UNIT II-Organic Chemistry-I 15 hrs (1 h / w)
S1-O-1. Stereochemistry of carbon compounds: (10h)
Three dimensional structures of organic molecules and Molecular representations- Wedge, Fischer,
Newman and Saw-horse formulae. Homomers, Isomers, Constitutional isomers (chain, positional,
functional), Stereoisomers, Enantiomers and Diastereomers, Configurational and Conformational
stereoisomers – definitions and examples.
Enantiomers: Optical activity- wave nature of light, plane polarised light, interaction with molecules,
optical rotation and specific rotation. Racemic mixture- racemisation and resolution techniques. Chiral
molecules- definition and symmetry criteria- classification to asymmetric and dissymmetric molecules –.
Examples - Glyceraldehyde, Lactic acid, Alanine and trans -1,2-dichloro cyclopropane. Chiral centers:
definition- molecules with similar and dissimilar chiral carbons – examples - tartaric acid and 2,3-
dibromopentane - definition of mesomers - formulae for calculating the number of stereoisomers. D, L
Page 2 of 12
and R, S configuration in molecules with chiral centers - Cahn-Ingold-Prelog rules. Geometrical isomerism
in alkenes- Cis, trans nomenclature and E, Z- configuration.
S1-O-2. Acyclic Hydrocarbons: (8h)
Alkanes– IUPAC Nomenclature of Hydrocarbons. Methods of preparation: Hydrogenation of alkynes and
alkenes, Wurtz reaction, Kolbe’s electrolysis, Corey- House reaction. Chemical reactivity – inert nature,
free radical substitution mechanism. Halogenation example- reactivity, selectivity and orientation;
Alkenes – Preparation of alkenes by (a) dehydration of alcohols (b) dehydrohalogenation of alkyl halides
(c) dehalogenation of 1,2 dihalides - mechanisms - Saytzev’s rule. Properties: Addition of hydrogen –
heat of hydrogenation and stability of alkenes. Addition of halogen and its mechanism. Addition of HX,
Markonikov’s rule, addition of H2O, HOX, H2SO4 with mechanism and addition of HBr in the presence of
peroxide (anti – Markonikov’s addition). Oxidation – hydroxylation by KMnO4, OsO4, peracids (via
epoxidation) hydroboration,
Dienes – Types of dienes, reactions of conjugated dines – 1,2 and 1,4 additions of HBr to 1,3 – butadiene
and Diel’s – Alder reaction.
Alkynes – Preparation by dehydrohalogenation of dihalides, dehalogenation of tetrahalides, Properties;
Acidity of acetylenic hydrogen (formation of Metal acedtylides). Preperation of higher acetylenes, Metal
ammonia reductions - Physical properties. Chemical reactivity – electrophilic addition of X2, HX, H2O
(Tautomerism), Oxidation with KMnO 4, OsO4, reduction and Polymerisation reaction of acetylene.
UNIT III-Physical Chemistry-I 15 hrs (1 h / w)
S1-P-1. Gaseous state: (5h)
Ideal gas equation, compression factors, deviation of real gases from ideal behavior. Van der Waal’s
equation of state.
P-V Isotherms of real gases, Andrew’s isotherms of carbon dioxide, continuity of state. Critical phenomena.
The van der Waal’s equation and the critical state. Relationship between critical constants and van der
Waal’s constants. The law of corresponding states and reduced equation of states.
Joule Thomson effect. Liquefaction of gases: i) Linde’s method and ii) Claude’s method
S1-P-2. Liquid State: (4h)
Intermolecular forces, structure of liquids (qualitative description). Structural differences between solids,
liquids and gases.
Surface tension and its determination using stalagmometer. Viscosity of a liquid and determination of
coefficient of viscosity using Ostwald viscometer. Effect of temperature on surface tension and coefficient
of viscosity of a liquid (qualitative treatment only).
Liquid crystals, the mesomorphic state: Classification of liquid crystals in to Smectic and Nematic,
differences between liquid crystal and solid / liquid. Application of liquid crystals as LCD devices.
S1-P-3. Solutions: (6h)

Liquid-liquid - ideal solutions, Raoult’s law. Ideally dilute solutions, Henry’s law. Non-ideal solutions.
Vapour pressure – composition and vapour pressure-temperature curves. Azeotropes-HCl-H2O, ethanol-
water systems and fractional distillation. Partially miscible liquids-phenol-water, trimethylamine-water,
nicotine-water systems. Effect of impurity on consulate temperature. Immiscible liquids and steam
Page 3 of 12
distillation. Nernst distribution law. Calculation of the partition coefficient. Applications of distribution
law.
UNIT IV-General Chemistry-I 15 hrs (1 h / w)
S1-G-1. General Principles of Inorganic qualitative analysis : (6h)
Anion analysis: Theory of sodium carbonate extract, classification and reactions of anions-CO3 , Cl , Br-
2- -
SO42-, PO43-, BO33- ,CH3COO-, NO3-
Cation Analysis: Principles involved - Solubility product, common ion effect, general discussion for the
separation and identification of group I individual cations (Hg+ Ag+, Pb+) with flow chart and chemical
equations.
Principle involved in separation of group II & IV cations. General discussion for the separation and
identification of group II (Hg2+, Pb2+, Bi3+, Cd2+, Sb3+, III (Al3+, Fe3+), IV ((Mn2+, Zn2+) individual cations
with flow chart and chemical equations.
Application of concept of hydrolysis in group V cation analysis. General discussion for the separation and
identification of group V individual cations (Ba 2+, Sr2+, Ca2+) with flow chart and chemical equations.
Theory of flame test.
Identification of Group VI cations (Mg2+, NH4+)
S1-G-2.Structural theory in Organic Chemistry: (9h)

Types of bond fission and organic reagents (Electrophilic, Nucleophilic, and free radical reagents including
neutral molecules like H2O, NH3 & AlCl3).
Bond polarization: Factors influencing the polarization of covalent bonds, electro negativity – inductive
effect. Application of inductive effect (a) Basicity of amines (b) Acidity of carboxylic acids (c) Stability
of carbonium ions. Resonance or Mesomeric effect, application to (a) acidity of phenol and (b) acidity of
carboxylic acids. Hyper conjugation and its application to stability of carbonium ions, Free radicals and
alkenes, carbanions, carbenes and nitrenes.
Types of Organic reactions : Addition – electrophilic, nucleophilic and free radical. Substitution –
electrophilic, nucleophilic and free radical, Elimination- Examples (mechanism not required).
Outcomes:
By the end of this course, students will be able to
CT135.CO1. Use the knowledge of Ionization energy and Electronegativity to predict types of compounds
(Ionic /Covalent) & their reactivity, compare the properties of s-& p-block elements & organometallic
compounds.
CT135.CO2. To implement the knowledge of stereochemistry to identify the stereoisomers and interpret
the reactions of alkanes, alkene and alkynes.
CT135.CO3. Implement Nernst Distribution law to relate the solubility of solute in immiscible solvents,
to interpret the change in physical parameters to liquefy gases & use of Liquid crystals in LCDs
CT135.CO4. To examine the ions in soil, water by the semi micro analysis method & Interpret organic
reaction mechanisms, reactivity of a few organic compounds.
Page 4 of 12
Laboratory Course: Paper code: CT135P
30h (2h / week)
Paper I
Qualitative Analysis - I
Objective:
1.To prepare inorganic complexes & test the anions & cations in different salt mixtures.
Prepare
I. Preparations:
1.Tetrammine copper (II) sulphate,
2.Potash alum KAl(SO4)2. 12H2O,
3. Bis (dimethylglyoximato) nickel(II)
II. Analysis of two anions and two cations in a mixture
Outcome:
Prepare inorganic complexes, recognize the role of reagents used & types of reaction & test the presence
of ions in the salt mixtures.
Text books:
Unit - I: Inorganic chemistry by P.L.Soni & others.
Unit- II: Text book of organic chemistry by R.L.Madan
Unit- III: Text Book of Physical Chemistry by Puri and Sharma and Pathania.
Unit- IV: Vogel’s Text Book of Qualitative Analysis by G.H.Jeffery, J.Bassett,J.Mendham and R.C.
Denney 5th edn Addison Wesley Longman Inc. 1999
Text book of organic chemistry by R.L.Madan
References:
Unit- I
1. Principles of Inorganic Chemistry by Puri, Sharma and Kalia, Vishal Publications1996.
2. Concise Inorganic Chemistry by J.D. Lee 3rd edn.
3. Basic Inorganic Chemistry by F.A.Cotton, G.Wilkinson and Paul.L. Gaus ,3rd edn ,Wiley Publishers
2001. Chem.
4. Inorganic Chemistry Principles of structure and reactivity by James E.Huhey,E.A. Keiter and R.L.
Keiter 4th edn.
Page 5 of 12
5. Chemistry of the elements by N.N.Greenwood and A. Earnshaw Pergamon Press1989.
6. Inorganic Chemistry by Shriver and Atkins 3rd edn Oxford Press 1999.
Unit- II
1. Text book of organic chemistry by Morrison and Boyd.
2. Text book of organic chemistry by Graham Solomons.
3. Text book of organic chemistry by Bruice Yuranis Powla.
4. Text book of organic chemistry by Soni.
5. General Organic chemistry by Sachin Kumar Ghosh.
Unit- III
1. Principles of physical chemistry by Prutton and Marron.
2. Text Book of Physical Chemistry by Soni and Dharmahara.
3. Text Book of Physical Chemistry by K. L. Kapoor
4. Physical Chemistry through problems by S.K. Dogra.
5. Elements of Physical Chemistry by Lewis and Glasstone.
Unit- IV
1. Analytical chemistry by G. L. David Krupadanam, D. Vijaya Prasad, K.Varaprasada Rao, K.L.N.
Reddy and C. Sudhakar
Page 6 of 12
BHAVAN’S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND COMMERCE,
SAINIKPURI, SECUNDERABAD. Autonomous College
Affiliated to OSMANIA UNIVERSITY, Hyderabad.
(Accredited with ‘A’ grade by NAAC)
Department Of Chemistry
PRGORAM NAME: MbGC, MbBcC, BtGC
Course Name: Inorganic/Organic/Physical and General Chemistry-II
PAPER CODE: CT235 & CT235P HPW:4
YEAR/SEMESTER: I/II No of Credits:4 Theory+1 Practical
II SEMESTER / PAPER – II (60 hrs / 15 weeks)
COURSE OBJECTIVE: To familiarize the students with the basic concepts and applications in
physical, organic, inorganic & general chemistry
UNIT WISE COURSE OBJECTIVES:

COb1.To use the knowledge of p-block elements to interpret structure and reactivity of compounds.
COb2.To explain stability of cycloalkanes and reactivity of Benzene and polynuclear hydrocarbons.
COb3.To relate laws of crystallography, discuss crystal defects & explain properties of colloids.
COb4.To explain quantum chemistry and chemical bonding of diatomic molecules and discuss the
properties & uses of nanomaterials, composites & superconductors.
UNIT I-Inorganic Chemistry-II 15 hrs (1 h / w)
1. p-Block elements - II 15 h
UNIT II-Organic Chemistry-II 15 hrs (1 h / w)
1. Alicyclic hydrocarbons 6h
2. Benzene and its reactivity 7h
3. Poly nuclear hydrocarbons 2h
UNIT III-Physical Chemistry-II 15 hrs (1 h / w)

1. Solid State 9h
2. Colloids and Surface Chemistry 6h
UNIT IV- General Chemistry-II 15 hrs (1 h / w)
1. Atomic structure and Elementary quantum mechanics 5h
2. Chemical Bonding 6h
3. Material Science 4h
Page 7 of 12
II - SEMESTER (Theory)
II SEMESTER / PAPER - II (60 hrs / 15 weeks)

(Inorganic/Organic/Physical and General Chemistry-II)
-------------------------------------------------------------------------------------------------------------------------------
UNIT I-Inorganic Chemistry-II 15 hrs (1 h / w)
S2-I-1. p-block elements: (15h)
Group – 15: Preparation and reactions of hydrazine, hydroxylamine, phosphazenes.
Group – 16: Classifications of oxides based on (i) Chemical behaviour and (ii) Oxygen content. Oxy acids:
Structure and acidic nature of oxyacids of B, C, N, P, S and Cl.
Group – 17: Inter halogen compounds and pseudo halogens
Chemistry of Zero group elements General preparation, structure, bonding and reactivity of Xenon
compounds – Oxides, Halides and Oxy-halides.
UNIT II-Organic Chemistry-II 15 hrs (1 h / w)
S2-O-1. Alicyclic hydrocarbons (Cycloalkanes): (4h)
Nomenclature, Preparation by Freunds methods, heating dicarboxylic metal salts. Properties – reactivity
of cyclopropane and cyclobutane by comparing with alkanes, Stability of cycloalkanes – Baeyer’s strain
theory, Sachse and Mohr predictions and Pitzer’s strain theory. Conformational structures of cyclobutane,
cyclopentane, cyclohexane.
S2-O-2. Benzene and its reactivity: (5h)
Concept of aromaticity – aromaticity (definition), Huckel’s rule – application to Benzenoid (Benzene,
Napthalene) and Non – Benzenoid compounds (cyclopropenyl cation, cyclopentadienyl anion and
tropylium cation).
Reactions – General mechanism of electrophilic substitution, mechanism of nitration, sulphonation,
halogenation. Friedel Craft’s alkylation and acylation. Orientation of aromatic substitution – Definition of
ortho, para and meta directing groups. Ring activating and deactivating groups with examples (Electronic
interpretation of various groups like NO2 and Phenolic). Orientation of (i). Amino, methoxy and methyl
groups (ii). Carboxy, nitro, nitrile, carbonyl and Sulfonic acid groups. (iii). Halogens (Explanation by
taking minimum of one example from each type).
S2-O-3. Polynuclear Hydrocarbons: (2h)
Structure of naphthalene and anthracene (Molecular Orbital diagram and resonance energy) Any two
methods of preparation of naphthalene and reactivity. Reactivity towards electrophilic substitution:
Nitration and sulfonation as examples.
Page 8 of 12
UNIT III-Physical Chemistry-II 15 hrs (1 h / w)
S2-P-1. Solid state Chemistry: (9h)
Laws of Crystallography – (i) Law of Constancy of interfacial angles (ii) Law of
Symmetry, Symmetry elements in crystals (iii) Law of rationality of indices.
Definition of space lattice, unit cell. Bravais Lattices and Seven Crystal systems (a brief review).
Xray diffraction by crystals; Derivation of Bragg’s equation,
Determination of structure of NaCl, KCl & CsCl (Bragg’s method and Powder method).
Defects in crystals. Stoichiometric and non-stoichiometric defects.

Band theory of semiconductors. Extrinsic and intrinsic semiconductors, n- and p-type semiconductors and
their applications in photo electrochemical cells.
S2-P-2. Colloids and surface chemistry: (6h)

Definition of colloids. Solids in liquids(sols), preparation, purification, properties- kinetic, optical,
electrical. Stability of colloids, Hardy-Schulze law, protective colloid.
Liquids in liquids (emulsions) preparation, properties, uses. Liquids in solids (gels) preparation, uses.
Adsorption: Physical adsoption, chemisorption. Freundlich, Langmuir adsorption isotherms. Applications
of adsorption
UNIT IV-General Chemistry-II 15 hrs (1 h / w)
S2-G-1. Atomic Structure and elementary quantum mechanics: (5h)
Blackbody radiation, Planck’s radiation law, photoelectric effect, Compton effect, de Broglie’s hypothesis,
Heisenberg’s uncertainty principle.
Limitations of Classical Mechanics. Postulates of quantum mechanics. Schrodinger wave equation and a
particle in a box, energy levels, wave functions and probability densities, Schrodinger wave equation for
H-atom, quantum numbers and their importance.
S2-G-2. Chemical Bonding: (6h)
Valence bond theory, hybridization, VB theory as applied to ClF 3, BrF5, Ni (CO) 4 and XeF2
Dipole moment – orientation of dipoles in an electric field, dipole moment, induced dipole moment, dipole
moment and structure of molecules.
Molecular orbital theory – LCAO method, construction of M.O. diagrams for homo-nuclear and hetero-
nuclear diatomic molecules (N2, O2, O2+, O2--, CO and NO). Comparison of VB and MO theories.
S2-G-3. Material Science (4h)
Superconductivity, characteristics of superconductors, Meissner effect, types of superconductors and
applications.
Nanomaterials- synthetic techniques, bottom-up-sol-gel method, top-down- electro deposition method.
Properties and applications of nano-materials in electronics, medicine, industry (textile, cosmetics) and
agriculture.
Page 9 of 12
Composites-definition, general characteristics, particle reinforce and fiber reinforce composites and their
applications.
Outcome:
CT235.CO1. Implement the basics of p-block elements to interpret acidity of oxyacids and compare
halogens with pseudohalogens.
CT235.CO2. Interpret the stability of cycloalkanes, predict aromaticity of Benzenoid and non-Benzenoid
compounds & sketch the mechanism of electrophilic substitution of Benzene & polynuclear hrdocarbons.
CT235.CO3. Appraise the crystal lattice of simple salts, interpret crystal defects, applications of
semiconductors & demonstrate the various properties of colloids.
CT235.CO4. Interpret properties & applications of composites, superconductors, nanoparticles, implement
the concept of VBT & MOT to differentiate physical parameters of various diatomic moleculecules,use the
knowledge of quantum mechanics to explain atomic structure.
Laboratory Course Paper code: CT235P
30hrs (2 h / week)
Paper II - Qualitative Analysis - II
Objective:
1.To test the ions present in the salt mixtures using semi micro qualitative technique.
I Semi micro analysis of mixtures
Analysis of two anions and two cations in the given mixture. (group separation for cations)
Anions: CO32- Cl-, Br-, I-, CH3COO-, NO3-, PO43-, SO42-
Cations: Pb2+, Hg2+
Pb2+, Bi3+, Cd2+, Cu2+, Sb3+/5+, Sn2+/4+
Al3+, Fe3+,
Zn2+, Mn2+
Ca2+, Sr2+, Ba2+
Mg2+, NH4+, K+
Outcome:
1.Test the presence of anions & cations in the salt mixtures.
Page 10 of 12
Text books:
Unit - I: Inorganic chemistry by P.L.Soni & others.
Unit- II: Text book of organic chemistry by R.L.Madan
Unit- III: Text Book of Physical Chemistry by Puri and Sharma and Pathania.
Unit- IV: Vogel’s Text Book of Qualitative Analysis by G.H.Jeffery, J.Bassett,J.Mendham and R.C.
Denney 5th edn Addison Wesley Longman Inc. 1999
Text book of organic chemistry by R.L.Madan
References:
Unit- I
1. Principles of Inorganic Chemistry by Puri, Sharma and Kalia, Vishal Publications1996.
2. Concise Inorganic Chemistry by J.D. Lee 3rd edn.
3. Basic Inorganic Chemistry by F.A.Cotton, G.Wilkinson and Paul.L. Gaus ,3rd edn ,Wiley Publishers
2001. Chem.
4. Vogel’s Qualitative Inorganic Analysis by Svehla
5. Inorganic Chemistry Principles of structure and reactivity by James E.Huhey,E.A. Keiter and R.L.
Keiter 4th edn.
6. Chemistry of the elements by N.N.Greenwood and A. Earnshaw Pergamon Press1989.
7. Inorganic Chemistry by Shriver and Atkins 3rd edn Oxford Press 1999.
Unit- II
1. Text book of organic chemistry by Morrison and Boyd.
2. Text book of organic chemistry by Graham Solomons.
3. Text book of organic chemistry by Bruice Yuranis Powla.
4. Text book of organic chemistry by Soni.
5. General Organic chemistry by Sachin Kumar Ghosh.
Unit- III
3. Text Book of Physical Chemistry by K. L. Kapoor
4. Physical Chemistry through problems by S.K. Dogra.
5. Elements of Physical Chemistry by Lewis and Glasstone.
Page 11 of 12
Unit- IV
1. Nano: The Essentials by T. Pradeep, McGraw-Hill Education.
2. Chemistry of nanomaterials: Synthesis, Properties and applications by CNR Rao et.al.
3. Nanostructured Materials and Nanotechnology, edited by Hari Singh Nalwa, Academic Press
6. Text Book of Physical Chemistry by Puri and Sharma
Page 12 of 12
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r BHAVAN'S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND
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(Accredited with 'A' grade by NAAC)
DEPARTMENT OF CHEMISTRY
B .Sc CHEMISTRY COURSE SYLLABUS-CBCS
UI SEMESTER / PAPER - IU (6O hrs/15 weeksl

lOrganlc Chemlstry -II and General Chemistry -IIl
Utf IT I-Orgaaic chemlstry-Il 3() hrs {2hlwl
1. Halogen compounds 411
o 2. Hydroxy compounds
3. Ethers and Epoxides
6h
2h
IINIT ll-Organic chemistry-Il
1. Carbonyl compounds 10h
2. Carborylic acids and derivatives 5h
3. Active methylene compounds and their reactivity 3h
III{IT III-General chemistry-Il 3O hrs (2hlwl

1. Evaluation of analytical data 5h
2. Theory of quantitative analysis 5h
3. Molecular symmetry 5h
IJNIT W-Ge neral ehemlstry-U
l. Nuclear chemistry 5h
2. Stereo selectivity in Chemistry 5h
3. Introduction to Pericyclic Reactions 5h
MEMESTER / PAPER - IV (6O hrs/ 15 weeks)
(Inorganle Chemlstry -II aud Physlcal Chemistry -IIl
o IINIT l-Inorgaaic chenistry-Il 3O hrs (2hlwl

l. Chemistry of d-block elements th
2. Chemistry of f-block elements 8h
UNIT ll-Inorganlc chemlstry-Il
1. Theories of bonding in metals 6h
2. Metal carbonyls and related compounds 7h
UNIT IU .Physlcal cheelstry-U 30 hrs (2hlwl
I. Phase Rule 5h
2. Dilute solutions 8h
IJ}{IT IV Phystcal chemistry-Il
1. Electro chemistry 17 h
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PAPER -III (6Oh/ 15 weeks|
(Organic Chemistry - II & General Chemistry-Ill
UNIT I:
l.Ha,iogen compounds:
Nomenclature and classification of alkyl (into primary, secondarSr, tertiary), aryl,
arallryl, allyl, vinyl, benzyl halides.
Chemical Reactivity, formation of RMgX
Nucleophilic aliphatic substitution reaction- classification into Snl and Sr2.
Energz profile diagram of Sr,r 1 and Sn2 reactions. Stereochemistr5r of Sr2 (Walden
Inversion) SNI (Racemisation). Explanation of both by taking the example of optically
active allryl halide - 2bromobutane. Ease of hydrolysis - comparision of alkyl, benzyl,
alkyl, vinyl and aryl halides (4h)
2.Hydroxv compounds:
Nomenclature and classification of hydrory compounds.
a Alcohols: Preparation with hydroboration reaction, Grignard sJmthesis of alcohols.
Phenols: Preparation i) from diazonium salt, ii) from aryl sulphonates, iii) from
cumene.
Physical properties- Hydrogen bonding (intermolecular and intramolecular). Effect of
hydrogen bonding on boiling point ald solubilitiy in water.
Chemical properties:
acidic nature of phenols.
fornration of alkoxides/phenoxides and their reaction with RX.
replacement of OH by X using PC15, PCL, PBrs, SOCIz and with l7X/ZnCll
esterifcation by acids ( mechanism).
dehydration of alcohols.
oxidation of alcohols by CrO:, KMnO+.
special reaction of phenols: Bromination, Kolb-Schmidt reaction, Riemer-Tiemann
reacdon, Fries rearrangement, azocoupling.
Identifrcation of alcohols by oxidation with KMnO+, ceric ammonium nitrate, lucas
reagent and phenols by reaction with FeClg.
Polyhydrory compounds: Pinacol-Pinacolone rearrangement. (6 h)
-o 3.Ethers and Epoxides:
Nomenclature,preparation by:
a)Williamsons synthesis b)from alkenes by the action of HzSO+
Physical properties -Absence of hydrogen bonding,Insoluble in water,low boiling point
Chemical properties-Inert nature, action of conc. HzSOq and HI.Acid and base
catalysed ring opening of epoxides-stereoselective and regioselective vrith examples.
(2h)
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UNIT II:
[i l.CarbonvI compounds:
Nomenclature of aliphatic and aromatic carbonyi compounds, structure of the
H- carbonyl group.
r Synthesis of aldehydes from acid chlorides, synthesis of aldehydes and ketones using
1,3-dithianes, synthesis of ketones from nitriles and from carboxylic acids.
r Physical properties: absence of hydrogen bonding, keto-enol tautomerism, reactivity of

carbonyl group in aldehydes and ketones.
Nucleophilic addition reaction with a) NaHSOo b) HCN c) RMCX d) NHzOH
e)PhNHNHz 0 2,4 DNP g) Alcohols-formation of hemiaceta-l and acetal.
Halogenation using PCls with mechanism.
Base cata.lysed reactions: a) Aldol bl Cannizzaro reaction c) Perkin reaction d) Benzoin
condensation e) Haloform reaction Oxidation of aldehydes-Baeyer-Villiger oxidation of
ketones.
I Reduction: Clemmensen reduction, Wolf-Kishner reduction, MPV reduction, reduction

with LiAIH+ and Na-EtH+.
Analysis of aldehydes and ketones with a) 2,4-DNl, test b) Tollen's test c) Fehling text
l.- o d) Schiff test e) Haloform test (with equation). (1O h)
2. Carboxylic acids and derivatives:

Nomenclature, classifrcation and structure of carborylic acids.
Methods of preparation by a) hydrolysis of nitriles, amides and esters.
b) carbonation of Grignard reagents.
Special methods of preparation of aromatic acids by
a) oxidation of side chain.
b) hydrolysis by benzotrichlorides.
c) Kolbe reaction.
Physical properties: Hydrogen bonding, dimeric association, acidity- strength of acids
with examples of trimethyl acetic acid and trichloroacetic acid. Relative differences in
the acidities of aromatic and aliphatic acids.
Chemical properties: Reactions involving H, OH and COOH groups- salt formation,
anhydride formation, acid chloride formation, amide formation and esterification
(mechanism). Degradation of carboxylic acids by Huns-Diecker reaction,
decarboxylation by Schimdt reaction, Arndt-Eistert synthesis, halogenation by Hell-
a Volhard- Zelinsky reaclion.
Derivatives of carbo>rylic acids: Reaction of acid chlorides, acid anhydrides, acid
amides, esters (mechanism of the hydrolysis of esters by acids and bases). (5 h)
3. Active methvlene comp ounds and their reactivitv:

Acetoacetic esters: preparation by Claisen condensation, keto-enol tautomerism. Acid
hydrolysis and ketonic hydrolysis.
Preparation of a) monocarboxylic acids. and b) dicarboxylic acids.
Reaction with urea
Malonic ester: preparation from acetic acid.
Synthetic applications: Preparation of
a) monocarboxylic acids (propionic acid and n-butyric acid).
b) dicarboxylic acids (succinic acid and adipic acid).
c) o,B-unsaturated carboxylic acids (crotonic acid).
Reaction with urea. ,(3h)
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UNIT III:
1. Evaluation of ata:
Theory of errors, idea of significant frgures and its importance, accuracy - methods of
expressing accuracy, error analysis and minimization of errors, precision - methods of
expressing precision, standard deviation and confidence limit (5 h)
2. Thoery ofquantitative analysrs

Principles olvolumetric analysis, Theories ofacid-base, redox, complexometric, iodometric and
precipitation titrations, choice ofindicators for these titrations. Principles of gravimetric analysis:
precipitation, coagulation, peptization, coprecipitation, post precipitation, digestion, filtration and
washing ofprecipitate, drying and ignition, precipitation from homogenous solutions,
requirements of gravimetric analysis. (5 h)
3. Molecular symmetry
C Concept of symmetry in chemistry-symmetry operations, symmetry elements.
Rotational axis of symmetry and types of rotational axes. Planes of symmetry and
types of planes. Improper rotational axis of symmetry. Inversion centre. Identity
element. The symmetry operations of a molecule form a group. Flow chart for the
identifrcation of molecular point group. (5 h)
UNIT TV:
1. Nuclear Chemistry
The atom, nucleus and outer sphere, classification ofnuclides, nuclear stability and binding
energy.Discovery of radioactivity, types of radioactivity, general characteristics of radioactive
decay and decay kinetics,Measurements radioactivity, gaseous ion collection method,
proportional and G.M. counter.
Applications of radioactivity-
Radiochemical principles in the use oftracers, Typical applications ofradioisotopes as a tracer-
i) Chemical investigations- reaction mechanism,
o ii)Structure determination- phosphorus pentachloride and thiosulphate ion
iii)Age determination- by Carbon-14 dating and Uranium-Lead/ Thorium-Lead Ratio
iv) Medical applications-Assess the volume of blood in patients body, Goiter
2.Stereoselectivity in Chemistry:
Selectivity in chemistry - Defrnition and examples of Chemoselectivity, Regioselectivity
and Stereoselectivity - Stereospecific reactions - Defrnition of enantiomeric and
diastereomeric excess (e e and d e) -. Mechanism of Iodide catalysed dehalogenation
of meso and active 2,3-dibromobutane
Brief introduction to As)rmmetricsynthesis (5h)
M
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r 3. Introduction to Pericvclic Reactions:
il" Definition and 'Ilpes of Pericyclic reactions - Electrocyclisation, Cycloaddition and
r Sigmatropic reactions - examples - Stereo specifrcity under thermal and
photochemical conditions - selection rules of pericyclic reactions - Molecular orbital
diagrams for ethylene, l,3-butadiene and 1,3,5-hexatriene and their symmetry
properties - definition of HOMO and LUMO - Mechanism of electrocyclisation and
cycloaddition reactions by Frontier Molecular Orbital (FMO) theory. (5h)
E
L
Laboratory Course 3Oh l2hlweekl
Paper III
L Quantltative Aaalysis-Ill
Tltrlmetrlc Analysts-
l.Estimation of Carbonate in Sodium Carbonate-(Acid-Base Titration)
l" 2.Estimation of Bicarbonate in Sodium Bicarbonate-(Acid-Base Titration)
l.- a
3.Estimation of Magnesium using EDTA(Complexometric Titration)
4.Determination of Fe(lI) using Potassium dichromate(Red-Ox Titration)
S.Estimation of Cu(Ii) using Sodium thiosulphate with Potassium dichromate as
primary standard(Iodometry Titration)
Gravlmetric Analysis I
l.Determination of Barium as Barium sulphate
2.Determination of Lead as Lead chromate.
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Inorganic Chemistry-Il & Physical Chernistry-Il
(6Oh/ 15 weeksf
r UNIT I:
l.Chemistry of d-block elements:

Characteristics of d-block elements with special reference to electronic configuration,
variable valence, magnetic properties, catalydc properLies and ability to form
complexes. Stability of various oxidation states and e.m.f. Comparative treatment of
second and third transition series u/itl their 3d analogues. Study of Ti, Cr and Cu
triads in respect of electronic configuration and change of reactivity with different
oxidation states, applications.
(eh)
2.Chemistry of f-block elements:

Chemistry of lanthanides - electronic structure, oxidation states, lanthanide
contraction, Separation of lanthanides by ion exchange and solvent extraction
methods. Chemistry of actinides - electronic configuration, oxidation states, actinide
O contraction, position of actinides in the periodic table, comparison with lanthanides in
terms of magnetic properties. (8h)
UNIT II:
LTheories of bonding in meta-ls:

Valence bond theory, Explanation of metallic properties and its limitations, Free
electron theory, thermal and electrical conductivity of metals, limitations, Band
theory, formation of bands, explanation of conductors, semiconductors and
insulators. (6h)
2.Meta-l carbonyls and related compounds:

EAN rule, classification of metal carbonyls, structures and shapes of metal carbonyls
of V, Cr Mn, Fe, Co and Ni. Metal nitrosyls and metallocenes (only ferrocene). (7h)
UNIT III:
a l.Phase rule:
Concept of phase, components, degree of freedom. Derivation of Gibbs phase rule.
Phase equilibrium of one component - water system. Phase equilibrium of two-
component system, solid-liquid equilibrium. Simple eutectic diagram of Pb-Ag system,
desilverisation of lead. Solid solutions- compound witJr congruent melting point- (Mg-
Zn) system, compound with incongruent melting point - NaCl- water system. Freezing
mixtures. (5h)
2.Dilute solu S:
Colligative properties. Raoult's law, relative lowering of vapour pressure, its relation to
molelular weight of non-volatile solute. Elevation of boiling point and depression of
freezing point. Derivation of relation between molecular weight and elevation in boiling
point and depression in freezing point. Experimental methods of determination.
bsmosis, os-otic pressure, experimental determination. Theory of dilute solutions.
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Abnorma] Colligative properties. Vant Hoff factor, degree of dissociation and
association. (8h)
UNIT IV:
l Electrochemistry:
Specifrc conductance, equivalent conductance, measurement of equivalent
conductance. Variation of equivalent conductalce with dilution. Migration of ions,
Kohlrausch's law. Arrhenius theory of electrolyte dissociation and its fimitations.
Ostwald's dilution law. Debye-Huckel-Onsagar's equation for strong electrol)rtes
(elementary treatment only). Delinition of transport number, determination by Hittorfs
method. Application of conductivity measurements-determination of dissociation
constant (IG) of an acid, determination of solubility product of sparingly soluble salt,
conductometric titrations.
I}pes of reversible electrodes- the gas electrode, metal-metal ion, metal-insoluble salt
and redox electrodes. Electrode reactions, Nernst equation, single electrode potential,
3 stardard Hydrogen electrode, reference electrodes, standard electrode potential, sign
convention, electrochemica-l series and its signifrcance. Reversible and irreversible
cells, conventional representation of electrochemical cells. EMF of a cell and its
measurements. Computation of cell EMF. Applications of EMF measurements,
Calculation of thermodynamic quantities of cell reactions (AG, AH and K).
Determination of pH using quinhydrone electrode, Solubility product of AgCl.
Potentiometric titrations. (17h)
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r Laboratory Course
Paper IV
Quaatitative Analysls-IV
Titrimetric Aaalysis-
l.Estimation of Carbonate and Bicarbonate in a mixture - (Acid-Base Titration)
2.Estimation of Bicarbonate in Baking soda- (Acid-Base Titration)
3.Estimation of total hardness of water using EDTA (Complexometric Titration)
4.Determination of Fe(II) usiog Potassium permanganate with oxalic acid as primary
standard (Redox Titration)
S,Estimation of Potassium dichromate using dichromate as primar5z standard
(Iodometry Titration).
6. Estimation of Zitc by ferrocyanide (precipitation titration)
Gravimetric Analysis
l.Determination of nickel as Ni-DMG complex
2.Determination of magnesium as magnesium pyrophosphate.
J
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R.EFERENCES SEM III
UNIT I AND UNIT II
1. Organic Chemistry by R.T.Morrison and R.N .Boyd

2. Organic chemistry by John Mc Murrys.
3. Problems and their solutions in organic chemistry by I.L Finar
4. Reaction mechanisms in organic chemistry by S.M.Mukherji and S.Singh
v UNIT III AND UNIT TV
l. A text book of Quantitative analysis by A.I Vogel.

2. Symmetry by Veera Reddy
3. Stereochemistry by P.S Kalsi
4. Principles of nuclear chemistry by H.J.Arnikar
a
REFERENCES SEM Iv
UNIT I AND UNIT II
1 Concise Inorganic Chemistry by J.D.Lee
2 Basic Inorganic Chemistry by Cotton and Wilkinson
J Advanced Inorganic Chemistry Vol-I by Satyaprakash,T\rli,Basu and Madan
4 Inorganic Chemistry by J.D.Huheey.
5 Inorganic Chemistry by Chopra and Kapoor.
6 Inorganic chemist4r by R. R Heslop and P. L Rohinson.
7 Inorganic chemistry by D.F Shriver, P.W Atkins and C.H Langford.
T'NIT III AND UNIT tV
I Principles of Physical chemistry by Puri, Sharma and Pathania

,.-o 2 Physical Chemistry by D.F Shriver, P.W.Atkinson and C.H. Langford
3 An Introduction to Electrochemistry by S Glasstone.
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SEMESTER lll and lV SYLLABUS
OBJECTIVES:
Organic chemistry:
L. Students will gain an understanding of

i) Fundamental electronic structure and bonding in organic molecules.
ii) Correlate the physical properties of organic compounds with the structure of the
molecules.
iii) The reactivity of different compounds.
2. Students will be able to discuss the reactions involved in the preparation of Hydroxyl, halogen,
carbonyl compounds, etc.
3. To predict the outcome and mechanism of some simple organic reactions, using a basic
understanding of the relative reactivity of functional groups.
Phvsical chemistrv:
t. Students will gain an understanding of: States of matter and how they depend on temperature
and pressure as well as how they co-exist in phase equilibria.
.2. Calculate standard cell potentials for any redox reaction and combine this information with
concentration data to determine the effect concentration will have on the cell potential.
3. Draw a redox cell diagram given cell notation.
4. The aim of this module will be to provide a general introduction to the enormous positive
impact chemistry has on our lives. ln addition to lectures, students will work in groups to
prepare and deliver an oral presentation on an assigned topic in an area covered by the course.
Genera! Chemistry:
1. To become familiar with the scope, methodology, and application of modern chemistry.
2. to learn problem solving and learning to interpret the data, to employ valid and efficient
methods of analysis, and to assess whether or not the results of calculations are
reasonable.
3. Determine the symmetry operations that can be applied to several molecules, and
hence the molecular point group.
'4. Promote logical, independent and criticalthinking
5. Motivate students to take responsibility for their own learning process.
ln-organic chemistry:
L. To understand the trends in properties and reactivity of the periodic elements.

2. Provide students with the opportunity to apply and integrate concepts and principles to
ascertain molecu lar properties
Laboratorv Course:
1. Titrimetric analysis- is a method of quantitative analysis used to determine unknown

concentration of known substance.
2. A review of classic methods of analysis, which includes stoichiometry, solution,
equilibrium and acid/bases; classical analytical method of gravimetric and volumetric
analyses.
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BHAVAN'S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND COMMERCE,

SAINIKPURI, SECUNDERABAD.
Autonomous College
Affiliated to OSMANIA UNMRSITY, flyderabad.
(Accredited with 'A' grade by NAAC)
DEPARTMENT OF CHEMISTRY
B. Sc CHEMISTRY COURSE SYLLABUS-CBCS
v SEMESTER / PAPER - V (a5 hrs / 15 weeks)
ORGAN!C, PHYSICAL AND GENERAL CHEMISTRY III
ORGANIC CHEMISTRY III
UNIT I
l.Nitrogen compounds 11h
INORGAN!C CHEMISTRY. I II
UNIT II
1.Co-ordination chemistry 11h
ORGANIC CMISTRY & INORGANIC CHEMISTRY-III
UNIT III
l.Hetero cyclic compounds 6h

2.Spectral and magnetic properties of metal complexes sh
PHYSICAL CHEMISTRY I!I
UNIT IV
l.Thermodynamics 72h
\ Page 19 of48
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V SEMESTER / PAPER - Vl Elective{ (45 hrs / 15 week)
PHYSICO-CHEMICAL METHODS OF ANALYSIS, MOTECU tAR SPECTROSCOPY AND CATALYSIS
UNIT I
l.Separation techniques 1lh
UNIT II
l.Spectrophotometry 5h
2. Mass Spectrometry 5h
UNIT III
l.Molecular spectroscopy 12h
UNIT IV
l.Catalysis 11 h
V SEMESTER / PAPER - Vl Elective- ll I (45 hrs / 15 weeks)
ELECTROANALYTICA t TECHNIOU ES & MOTECULAR SPECTROSCOPY
UNIT I
l.Conductometric methods-1 11 h
UNIT II
l.Conductometric methods-2 5h
2.Potentiometric titrations 6h
UNIT III
1.pH measurements & applications 5h

2.Mass Spectrometry 6h
UNIT IV
l.Molecular spectroscopy 12h

Page 20 of 48
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vt SEMESTER / PAPER - V[ (45 hrs / 15 weeks)
ORGANIC, PHYSICAL AND GENERAL CHEMISTRY IV
ORGANIC CHEMISTRY IV
UNIT I
l.Carbohydrates 6h
2.Amino acids and proteins 5h
UNIT II
INORGANIC CHEMISTRY IV
1. Reactivity of metal complexes 4h
2.Stability of complexes 4h
3. Hard and soft bases 4h
UNIT III
ORGANIC CHEMISTRY & INORGANIC CHEMISTRY IV
1. Synthetic strategies 6h
2 .Bioinorganic chemistry sh
UNIT IV
PHYSICAL CHEMISTRY{V
l.Chemical kinetics th
2.Photochemistry 2h
Page 21 of 48
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Vl SEMESTER 1 PAPER - Vlll Elective-l (45 hrs / 15 weeks)
DRUGS, PESTICIDES, MACROMOLECULES
UNIT I
l.Pharmaceutical drugs 12h
UNIT II
1.HlV and AIDS 5h

2.Formulations 3h
3.Pestiscides - | 3h
UNIT III
l.Pesticides - ll 3h
2.Material Science 8h
UNIT IV
1. M acromo lecu les 11 h
Vl SEMESTER / PAPER - Vlll Elective-ll (45 hrs / 15 weeks)
BIOMOTECULES
UNIT I
l.Alkaloids 11 h
UNIT II
l.Terpenoids 11 h
UNIT III
l.Steroids 6h
2.Vitamins 5h
Page 22 of 48
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UNIT IV
l.Carbohydrates 4h
2.Proteins and Nucleic acids 8h
TABORATORY COURSE (3oh/15weeks)2hlw
SEM.V
Practical Paper - V (Organic Chemistry)
1, Synthesis of Organic Compounds
a) Aromatic electrophilic substitution Nitration: Preparation of nitro salicylic acid and p-nitro acetanilide,
b) Halogenation: Preparation of p-bromo acetanilide
c) Diazotization and coupling: Preparation of phenyl azo p-napthol
d)Oxidation: Preparation of benzoic acid from toluene
e) Reduction: Preparation of m-nitro aniline from m-dinitro benzene
f) Esterfication: Preparation of methyl p-nitro benzoate from p-nitro benzoic acid.
g) Methylation: Preparation of p-napthyl methyl ether
h) Condensation: Preparation of benzylidine aniline
2. Thin layer Chromatography & Column Chromatography
a) Preparation of the TLC plates. Checking the purity of the compounds by TLC:
Determination of Rr values and identification of organic compounds by TLC: preparation and separation
of 2,4-dinitrophenyl hydrazones of acetone and 2-butanone using toluene and light petroleum (40:60)
b) Microwave assisted Green synthesis, one example: 1. Hydrolysis of Benzamide
TAEORATORY COURSE (30h/lsweeks)2hlw
sEM-VI
Practical Paper - Vll (Organic Chemistry)
1, Organic Qualitative Analysis:
a) ldentification of an organic compound through the functional group analysis, determination
Page 23 of 48
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of melting point and preparation of suitable derivatives.
b) Separation of two component mixtures
c) Aniline + Naphthalene 2) Benzoic acid + Benzophenone 3) p-Cresol + Chlorobenzene.
TABORATORY COURSE (30h/15weeks)2hlw
SEM.V
Practical Paper - Vl (Physical Chemistry)
1. Electrochemistry
a) Determination of concentration of HCI conductometrically using standard NaOH solution.
b) Determination of concentration of acetic acid conductometrically using standard NaOH solution.
c) Determination of dissociation constant (Ka) of acetic acid by conductivity measurements.
d)Determination of solubility and solubility product of Ba5O4.
2. pH metry
a) pH metric titration of weak acid, acetic acid with strong base NaOH and calculation of dissociation
constant.
3. Colorimetry
a) Verification of Beer-Lambert law for KMnOr, K2Cr2O7 and determination of concentration of the given
solution.
4. Properties of liquids
a) Surface tension of liquids b) Viscosity of liquids.
LABORATORY COURSE - Vl (30h/15weeks)Zhlw
sEM-Vt
Practical Paper - Vlll (Physical Chemistry)
1. Chemical kinetics
a) Determ inatio n of specific reactio n rate of the hydrolysis of methyl acetate
catalyzed by hydrogen ion at room temperature.
b) Determination of rate of decomposition of hydrogen peroxide.

c) Determination of overall order of sa ponification of ethyl acetate
2. Distribution law
a) Determination of distribution coefficient of acetic acid between water and butanol.
Page 24 of48
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b) Determination of molecular status and partition coefficient of benzoic acid in Toluene and water.
3.Colorometry
a) Composition of complex of Cu2* - EDTA disodium salt
4, Project Work
Collection of spectral data of a minimum of four compounds belonging to different functional groups
(other than those included in the syllabus) and submission of the report.
,*r
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v SEMESTER PAPER-V
/ (45 hrs/ 15 weeks)
organic chemistry - lll (3 h / w)
UNIT.I
l.Nitrogen compounds 11 h
Nitro hydrocarbons: Nomenclature and classification - nitro hydrocarbons - structure. Tautomerism of

nitroalkanes leading to aci a nd keto form. Preparation of Nitroalkanes. Reactivlty - halogenation, reaction
with HONO (Nitrous acid), Nef reaction, Mannich reaction leading to Michael addition and reduction.
Amines (Aliphatic and Aromatic)
Nomenclature, Classification into quarternary ammonium compounds. Preparative

10, 20, 30 amines and
methods -1. Ammonolysis of alkyl halides 2. Gabriel synthesis 3. Hoffman's bromamide reaction
(mechanism). 4. Reduction of Amides and Schmidt reaction. Physical properties and basic character -
Comparative basic strength of Ammonla, methyl amine, dimethyl amine, trimethyl amine and aniline -
comparative basic strength of aniline, N-methylaniline and N, N-dimethyl aniline (in aqueous and non-
aqueous medium), steric effects and substituent effects. Use of amine salts as phase transfer catalysts.
Chemical properties: a)Alkylation b)Acylation c) Carbylamine reaction d) Hinsberg separation e) Reaction
with Nitrous acid of 10, 20, 30 (Aliphatic and aromatic amines). Electrophilic substitutions of Aromatic
amines - Bromination and Nitration. oxidation of aryl and 30 Amines. Diazotization
Cyanides and isocyanides: Nomenclature (aliphatic and aromatic) structure. Preparation of cyanides from
a) Alkyl halides b) amides c) aldoximes. Preparation of isocyanides from Alkyl halides and Amines.
Properties of cyanides and isocyanides - a) hydrolysis b) addition of Grignard reagent iii) reduction iv)
oxidation.
lnorganic Chemistry-lll
UNIT-II
1. Coordination Chemistry 11h
IUPAC nomenclature, bonding theories - review of Werne/s theory and Sidgwick's concept of
coordination, Valence bond theory, Beometries of coordination numbers 4-tetrahedral and square planar
and 5-octahedral and its limitations, crystal filed theory, splitting of d-orbitals in octahedral, tetrahedral
and square-planar complexes - low spin and high spin complexes - factors affecting crystal-field splitting
energy, merits and demerits of crystal-field theory. lsomerism in coordination compounds - structural
isomerism and stereo isomerism, stereochemistry of complexes with 4 and 6 coordination numbers.
Organic Chemistry & Inorganic Chemistry-lll
UNITIII
l.Heterocyclic Compounds 6h
Page 26 of48
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lntroduction and definition: Simple 5 membered ring compounds with one hetero atom Ex. Furan.
Thiophene and pyrrole. lmportance of ring system - presence in important natural products like
hemoglobin and chlorophyll. Numbering the ring systems as per Greek letter and Numbers. Aromatlc
character - 6- electron system (four-electrons from two double bonds and a pair of non-bonded electrons
from the hetero atom). Tendency to undergo substitution reactions.
Resonance structures: lndicating electron surplus carbons and electron deficient hetero atom.
Explanation of feebly acidic character of pyrrole, electrophillic substitution at 2 or 5 position,
Halogenation, Nitration and Sulphonation under mild conditions. Reactivity of furan as l,3-diene, Diels
Alder reactions (one example). Sulphonation of thiophene purificatlon of Benzene obtained from coal tar).
Preparation of furan, Pyrrole and thiophene from 1,4,- dicarbonyl compounds only, Paul-Knorr synthesis,
structure of pyridine, Basicity - Aromaticity - Comparison with pyrrole - one method of preparation and
properties - Reactivity towards Nucleophilic substitution reaction - chichibabin reaction.
2, Spectral and magnetic properties of metal complexes 5h
Electronic absorption spectrum of [Ti(HrO)6]3- ion.(Jahn-Teller effect). Types of magnetic behavior, spin-
only formula, calculation of magnetic moments, experimental determination of magnetic susceptibility -
Gouy method.
Physical Chemistry - lll

uNrTlv
l,Thermodynamics 12 h
The first law of thermodynamics-statement, definition of internal energy and enthalpy. Heat capacities
and their relationship. Joule's Law-Joule-Thomson coefficient. Calculation of w, q, dU and dH for the
expansion of perfect gas under isothermal and adiabatic conditions for reversible processes. State
fu nctio n.
Temperature dependence of enthalpy of formation-KirchofFs equation.
Second law of thermodynamics. Different Statements of the law. Carnot cycle and its efficiency. Carnot
theorem. Thermodynamic scale oftemperature. Concept of e ntro py, e ntropy as a state fu nction, entropy
changes in clclic, reversible, and irreversible processes and reversible phase change. Calculation of
entropy changes with changes in V & T and P&T. Entropy of mixing inert perfect gases. Entropy changes
in spontaneous and equilibrium processes.
The Gibbs (G) and Helmholtz (A) energies. A & Gas criteria for thermodynamic equilibrium and
spontaneity-advantage over entropy change. Gibbs equations and the Maxwell relations. Variation of G
with P, V and T.
Page27 of 48
:x;u TO U"'9J br/

V SEMESTER / PAPER-VI (Elective-l) (45 hrs / 15 weeks)
Physico-chemical Methods ofAnalysis, Spectroscopy and catalysis (3h/w)
uNtT-l
1, Separation techniques 4 h
Solvent extraction: Principle and process, Batch extraction, continuous extraction and counter current
extraction. Application - Determination of lron (lll)
Chromatography: Classification of chromatoBraphy methods, principles of differential migration

adsorption phenomenon, Nature of adsorbents, solvent systems, Rr values, factors effecting Rrvalues.
Paper Chromatography: Principles, Rf values, experimental procedures, choice of paper and solvent
systems, developments of chromatogram -
ascending, descending and radial. Two dimensional
chromatography, applications in analysis of free amino acids in rats,analysis of alkalolds.
Thin layer Chromatography (TLC): Advantages. Principles, factors effecting Rr values. Experimental
procedures. Adsorbents and solvents. Preparation of plates. Development of the chromatogram.
Detection of the spots. Applications in the drug industry.
Column Chromatography: Principles, experimental procedures, Stationary and mobile Phases, Separation
technique.
High Performance Liquid Chromatography (HPLC): Principles and Applications in pharmaceutical and food
industry.
Gas Liquid Chromatography (GLC): Principles and Applications in qualitative analysis.
UNIT-II
1, Spectrophotometry 5h
General features of absorption -

spectroscopy, Beer-Lambert's law and its limitations, transmittance,
Absorbance, and molar absorptivity. Single and double beam spectrophotometers. Application of Beer-
Lambert law for quantitative analysis of
1. Chromium in KzCrzOz
2. Manganese in Manganous sulphate
3. lron (lll) with thiocyanate.
2.Mass spectrometry 6h
Basic principles of - -
Mass spectrometry lnstrumentation lonization techniques - Molecular ion and
fragment ions ions. lsotopic peaks and their importance in the determination of Molecular peaks and
Page 28 of 48
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number and nature of hetero atoms in the molecule -
General fragmentation patterns - Mass spectra of
ethylbenzene, acetophenone, n-butyl amine and 1- proponal.
uNtT-
l,Molecular spectroscopy Lrh

(i) Electronic spectroscopy:
lnteraction of electromagnetic radiation with molecules and types of molecular spectra. Potential energy
curves for bonding and antibonding molecular orbitals. Energy levels of molecules (o, n, n). Selection rules
for electronic spectra. Types of electronic transitions in molecules effect of conjugation. Concept of
chromophore.
(ii) lnfra-Red spectroscopy
Energy levels of simple harmonic oscillator, molecular vibration spectrum, selection rules. Determination
of force constant (qualitative treatment only). Qualitative relation of force constant to bond enerBies.
Anharmonic motion of real molecules and energy levels. Modes of vibrations in polyatomic molecules.
Characteristic absorption bands of various functional groups. Finger print nature of infrared spectrum.
(iii) Raman spectroscopy,Concept of polarizability, selection rules and principles of Raman spectroscopy
(iv) Proton magnetic resonance spectroscopy (1H-NMR)
-
Principles of nuclear magnetic resonance - shielding and de-shielding equivalent and non-equivalent
protons, position ofsignals. Chemical shift and splitting of signals-spin-spin coupling, coupling constants.
-
Applications of NMR with suitable examples ethyl bromide, ethanol, acetaldehyde, 1,1,2-tribromo
ethane, ethyl acetate, toluene and acetophenone.
spectral interpretation
lnterpretation of lR, UV-Visible, 1H-NMR and mass spectral data of the foltowing compounds
1. Phenyl acetylene 2. Acetophenone 3. Cinnamic Acid 4. para-nitro aniline.
uNtT-tv
l.Catalysis 11 h
Homogeneous and heterogeneous catalysis, comparision with examples. Kinetics of specific acid catalyzed
reactions, inversion of cane sugar. Kinetics of specific base catalyzed reactions, base catalyzed conversion
of acetone to diacetone alcohol. Acid and base catalyzed reactions- hydrolysis of esters, mutarotation of
glucose. Catalytic activity at surfaces. Mechanisms of heterogeneous catalysis. Langmuir-Hinshelwood
mechanism.
Enzyme catalysis: Classification, characteristics of enzyme catalysis. Kinetics of enzyme catalyzed

reactions-M ichaelis Menton law, significance ofMichaelis constant (K.) and maximum velocity
Page 29 of48
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(V.*).Significance of different plots. Factors affecting enzyme catalysis- effect of temperature, pH,
concentration and inhibitor.
Catalytic efficiency. Mechanism of oxidation of ethanol by alcohol dehydrogenase.
V SEMESTER / PAPER-VI (Elective-2) (45hrs/l5weeks)

(3h/w)
l.Electro-Analytical Techniques:
UNIT.I
Conductometric methods-1: 11 h
lntroduction, conductance, applications of conductivity
1. Purity of Water 2. Measurement of salinity of sea water. 3. Analysis of fuming H NO3
4. Determination of specific ion in presence of others, 5. Determination of small amounts of ammonia in

biological materials.
Conductometric Titrations:
(1). Strong acid with a strong base. (2) Weak acid with a strong base.
(3) Moderately strong acid with strong base (4) Strong acid with weak base
(5) Weak acid with Weak base (5) Mixture of acids with a base.
UNIT-II
l.Conductometric methods-2: 5h
(1) Redox titrations (2) Precipitation titrations
(3) Complexometric titrations.
Applications-Determination of atmospheric sulphur dioxide. Advantages and disadvantages of

conductometric titrations
z.Potentiometric titrations: 5h
lntroduction, lnstrumentation-Types of potentiometric titrations.
(U Acid -base titrations. (2) Complexometric titrations (3) Redox titrations (4) Precipitation titrations (5)
Non-aqueous solvents. Advantages of potentiometric titrations.
uNtT-
1.pH measurements: 5h
Page 30 of 48
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Determination of pH (U Potentiometric method using Quinhydrone electrode and Glass electrode
lnstrumentation:(i) Potentiometric type (li) Direct Reading type, Applications of pH measurements
2. Mass spectrometry 6h
Basic principles of Mass spectrometry lnstrumentation - lonization techniques - Molecular ion and
-
fragment ions. lsotopic peaks and their importance in the determination of Molecular peaks and number
and nature of hetero atoms in the molecule - General fragmentation patterns - Mass spectra of
ethylbenzene, acetophenone. n-butyl amine and 1- proponal.
Spectral interpretation
lnterpretation of lR, UV-Visible, 1H-NMR and mass spectral data of the following compounds
1. Phenyl acetylene 2. Acetophenone 3. Cinnamic Acid 4. para-nitro aniline
uNtT-tv
l.Molecular spectroscopy 12 h
(i) Electronic spectroscopy:
lnteraction of electromagnetic radiation with molecules and types of molecular spectra. Potential energy
curves for bonding and antibonding molecular orbitals. Energy levels of molecules (o,n, n) . Selection rules
for electronic spectra. Types of electronic transitions in molecules effect of conjugation. Concept of
chromophore.
(ii) lnfra-Red spectroscopy
Energy levels of simple harmonic oscillator, molecular vibratlon spectrum, selection rules. Determination
of force constant (qualitative treatment only). Qualitative relation of force constant to bond enerBies.
Anharmonic motion of real molecules and energy levels. Modes of vibrations in polyatomic molecules.
Characteristic absorption bands of various functional groups. Finger print nature of infrared spectrum.
(iii) Raman spectroscopy
Concept of polarizability, selection rules and principles of Raman spectroscopy
(iv) Proton magnetic resonance spectroscopy (1H-NMR)
Principles of nuclear magnetic resonance - shielding and de-shielding - equivalent and non-equivalent
protons, position of signals. Chemical shift and splitting of signals - spin-spin coupling, coupling constants.
-
Applications of NMR with suitable examples ethyl bromide, ethanol, acetaldehyde, 1,1,2-tribromo
ethane, ethyl acetate, toluene and acetophenone.
of48
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VI SEMESTER / PAPER-VII (45 hrs / 15 weeks)
Organic Chemistry - lV
(3h/w)
UNIT-I
l,Carbohydrates 6h
Monosaccharides: All discussion to be confined to (+) glucose as an example of aldo hexoses and
(-) fructose as example of ketohexoses. Chemical properties and structureal elucidation: Evidences for
straight chain pentahydroxy aldehyde structure (Acetylation, reduction to n-hexane, cyanohydrin
formation, reduction of Tollen's and Fehling's reagents and oxidatlon to gluconic and saccharic acid).
Number of optically active isomers possible for the structure, configuration of glucose based on D-
glyceraldehyde as primary standard (no proof for configuration is required). Evidence for cyclic structure
of glucose (some negative aldehydes tests and mutarotation). Cyclic structure of glucose. Decomposition
of cyclic structure (Pyranose structure, anomeric Carbon and anomers). Proof for the rinB size
(methylation, hydrolysis and oxidation reactions). Different ways of writing pyranose structure (Haworth
formula and chair conformationa formula). Structure of fructose: Evidence of 2 - ketohexose structure
(formation of penta acetate, formation of cyanohydrin its hydrolysis and reduction by Hl to give 2-
Carboxy-n-hexane). Same osazone formation from glucose and fructose, Hydrogen bonding in osazones,
cyclic structure for fructose (Furanose structure and Haworth formula).
lnterconversion of Monosaccharides: Aldopentose to aldo hexose - eg: Arabinose to D-Glucose, O-

Mannose (Kiliani - Fischer method). Epimers, Epimerisation - Lobry de bruyn van Ekenstein
rearrangement. Aldohexose to Aldopentose eg: D-glucose to D-arabinose by Rufff degradation.
Aldohexose (+) (glucose) to ketohexose (-) (Fructoseland Ketohexose (fructose) to aldohexose (Glucose)
2.Amino acids and proteins 5h

lntroduction: Definition of Amino acids, classification of Amino acids into alpha, beta, and gamma amino
acids. Natural and essential amino acids - definition and exa mples, classification of a lpha amino acids into
acidic, basic and neutral amino acids with examples. Methods of synthesis: Genera I methods of synthesis
of alpha amino acids (specific examples - Glycine, Alanine, valine and leucene) by following methods: a)
from halogenated carboxylic acid b) Malonic ester synthesis c) strecker's synthesis.
Page 32 of 48
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Physical properties: Optical activity of naturally occurring amino acids: L-configuration, irrespective of sign
rotation, Zwitter ion structure - salt like character - solubility, melting points, amphoteric character,
definition of isoelectric point.
Chemical properties: General reactions due to amino and carboxyl groups - lactams from gamma and
delta amino acids by heating peptide bond (amide linkage). Structure and nomenclature of peptides and
proteins - introductory treatment.
lnorganic chemistry-lv
UNIT{I
l.Reactivity of metal complexes 4h
Labile and inert complexes, ligand substitution reactions - Sn1 and Sn2, substitution reactions of square
planar complexes - Trans effect and applications of trans effect.
z,Stability of metal complexes 4h
Thermodynamic stability and kinetic stability, factors affecting the stability of metal complexes, chelate
effect, determination of composition of complex by Job's method.
3.Hard and soft acids bases (HSAB) 4h
Classification, Pearson's concept of hardness and softness, application of HSAB principles - Stability of
compounds / complexes, predicting the feasibility of a reaction.
organic chemistry & lnorganic Chemistry-lv
UNIT III
l.Synthetic strategies 6h
Terminology-Disconnection(dix), Symbol 0,
Synthon, Synthetic equivalent(SE), Functional group
interconversion (FGl). Linear, Convergent and Combinatorial syntheses, Target molecule (TM).
Retrosynthesis of the following molecules-Acetophenone, Cyclohexene, Phenyl ethyl bromide
2,Bioinorganic chemistry 5h
Essential elements, biological significance of Na, K, Mg, Ca, Fe, Co, Ni, Cu, Zn and chloride (Cl-).
Metalloporphyrins - hemoglobin, structure and function, Chlorophyll, structure and role in
photosynthesis.
Page 33 of48
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Physical Chemistry - lV
UNIT-IV
l.Chemical kinetics th
Rate of reaction, factors influencing the rate of a reaction-concentration, temperature, pressure, solvent,
light, catalyst. Experimental methods to determine the rate of reaction. Definition of order and
molecularity. Derivation of rate constants for first, second, third and zero order reactions and examples.
Derivation for time half change. Methods to determine the order of reactions. Kinetics of complex
reactions (first order only): opposing reactions, parallel reactions, consecutive reactions and chain
reactions. Effect of temperature on rate of reaction, Arrhenius equation, concept of activation energy.
Theories of reaction rates- collision theory-derivation of rate constant for bimolecular reaction. The
transition state theory (elementary treatment).
z.Photochemistry 2h
Difference between thermal and photochemical processes. Laws of photochemistry-Grothus-Drape/s law

and Stark-Einstein's law of photochemical equivalence. quantum yield. Ferrioxalate actinometry.
Photochemical hydrogen- chlorine, hydrogen-bromine reaction. Jablonski diagram depicting various
processes occurring in the excited state, qualitative description of fluorescence, phosphorescence, non-
radiative processes (internal conversion, intersystem crossing). Photosensitized reactions- energy transfer
processes (simple example)
vl SEMESTER / PAPER-vlll ( Elective -1) (45 hrs l5weeks)
( 3h/w)
Drugs, Pesticides, Macromolecules
UNIT-I
1, Pharmaceutical Drugs 12 h
-
lntroduction to Medicinal Chemistry Historical evolution: Definition of a Drug and a Medicines -
therapeutic index - good drugs and bad drugs.
Sources of drugs - folklore medicines, natural sources, synthetic origin - one example each.
Nomenclature: Chemical name, Generic name and Trade names of drugs with examples.
Classification: Classification of drugs based on therapeutic activity with one example each.
Pencillin : lsolation, structural features and activity - semi-synthetic pencillins
Synthesis: Synthesis and therapeutic activity of the following drugs: L-Dopa, Chloroquin, Omeprazole,
Albuterol and ciprof loxacin.
Page 34 of48
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UNIT.II
1. HIV and AIDS: 5h
lmmunity - CD-4 cells, CD-8 cells Retrovirus, replication in human body - detection of AIDS. Drugs
available for curing AIDS - Names and structure only: lndinavir (Crixivan), Nelfinavir (Viracept), Abacavir
(ziagen), Lamivudlne (Epivir, 3TC), Zidovudine (Retravir, AzT, zDV)
2, Formulations 3h
lntroduction to formulations - basis, classifications and types of formulations - Additives in formulations

and their role (brief account only)
3, Pestiscides - | 3h
lntroduction to lnsecticides, Fungicides, Herbicides, Weedicides, Rodenticides, Plant Growth Regulators,

Pheromones and Hormones. Brief discussion with examples and structure.
uNtT-
1. Pesticides - ll 3h
Synthesis of the following pesticides:
DDI BHC, Malathion, Parathion, Endrin, Baygon, 2,4-D and Endo-sulphan
Natural products like Tobacco, Neem and Garlic.
Environmental problems in pesticide industry.
2. Materialscience 8h
Superconductivity, characteristics of superconductors, Meissner effect, types of superconductors and

applications.
Nanomaterials- synthetic techniques, bottom-up-sol-gel method, top-down- electro deposition method.
Properties and applications of nano-materials in electronics, medicine, industry (textile, cosmetics) and
agriculture.
Composites-definition, general characteristics, particle reinforce and fiber reinforce composites and
their applications.
UNIT III
1. Macromolecules 11 h
Polymers - Classification and Chemistry of polymerization, chain polymerization, step polymerization,

coordination polymerization - tacticity. Molecular weight of polymers-number average and weight
average molecular weight, degree of polymerization, determination of molecular weight of polymers by
viscometry, Osmometry and light scattering methods. Kinetics of free radical polymerization, derivation
of rate law. Preparation and industrial application of polyethylene, PVC, Teflon, polyacrylonitrile, terelene
and Nylon5,5. lntroduction to biodegradability.
Page 35 of48
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Vl SEMESTER / PAPER-Vlll ( Elective -2) (45 hrs 15 weeks)
(3h/w)
UNIT-I
BIOMOLECUTES
1. Alkaloids: 11 h
Definition of an alkaloid - Extraction of alkaloids - General properties and methods of determining

structure -functional nature of Orygen (if present) and Nitrogen - Hofmann's exhaustive methylation
method - Emde degradation and Von Braun,s method for opening nitrogen heterocyclic rings. Structures
of Ephedrine, Nicotine, Quinine. Structure and synthesis of Papaverine.
UNIT-II
l.Terpenoids: 11 h
lntroduction to terpenes - lsoprene and special lsoprene rules - lsolation of mono and sequi terpenoids
- Colour tests - General methods of determining the structure. Structures of Citral ( monoterpenoid), o-
Terpineol, Menthol and Camphor (monocyclic monoterpenoid), p-Bisabolene (monocyclic
sesquiterpenoid). Synthesis of Geraniol.
uNtT-
1. Steroids: 6h
lntroduction,cholesterol and ergosterol, sex hormones, adrenal steroids, anabolic steroids and
Oestrone.
2, Vitamins: 5h
lntroduction to vitamins, Structure and source of vitamins A, 81 82, pantothenic acid, vitamin86. vitamin
Dz,a-Tocopherol,0-Biotin, vitamin K1.
UNIT.IV
1. Carbohydrates: 5h
Definitions of Disccharides -
Conformational structures of (+)-Maltose, (+)-Cellobiose, (+)-Lactose and
(+)- Sucrose. Hydrolysis - Polysaccharides - Structure of Starch, Amylose, Cyclodextrins and Cellulose.
2. Proteins and Nucleic Acids: 7h
Peptides: Geometry of the peptide linkage. Determination of structure of peptides- Terminal residue
analysis - Partial hydrolysis. Synthesis of peptides. Proteins: Classification and Function. - Structure of
Proteins - Secondary structure of Proteins.
Nucleic acids: Structure of Nucleic acids- Pyrimidine and Purine bases - Suga rs - Structu re ofnucleosides
and nucleotides - RNA and DNA. Biosynthesis of proteins (introductory treatment only)
Page 36 of 48
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PAPER V and YII OBJECTIVES:
PHYSICAL CHEMISTRY:
Students will gain an understanding of:
I . Concepts in themrodynamics, different themrodynamic quantities such as heat and work and how
they are measured related or transformed from one to the other.
2. Chemical equilibrium and its relationship rvith thermodynarnic quantities.
3. The transport ofions and thermodynamic functions with applications to electron transfer in
biological systems.
4. Chemical kinetics; how reaction rates are measured and represented in rate laws, and applications
of chemical kinetics in studying enzyme mechanisms.
ORGANIC CHEMISTRY:
Students will gain an understanding of
l. Fundamental electronic structure and bonding in organic molecules.
2. Correlate the physical properties oforganic compounds with the structure ofthe molecules.
3. The reactivity of different compounds.
4. Students will be able to discuss the reactions involved in the preparation of nitrogen compounds,
heterocyc lic and biochemistry.
understanding of the relative reactivitv of functional groups.
IN.ORGANIC CHEMISTRY:
l. Student gain in depth knowledge oforbital picture and their enerry levels
2. They predict reaction mechanism and the connection between isomerism and reaction mechanism
of complex compounds.
3. They understand spectra ofcomplexes and various properties like color, magnetic properties of
complex compounds.
4. Students learn biological importance of hansition metals and their applications in the form of a
complex compound.
5. They get knowledge 0f complex compounds in the nature like chlorophyll and predict mechanism
0fphotosynthesis etc.., role of hemoglobin in oxygen transportation
LABORATORY COURSE:
1. The planning and implementation of advanced organic reactions.

2. Detailed organic structure analysis how to calculate a limiting reagent. yield, and percent yield.
3. How to critically evaluate data collected to determine the identity. purity, and yield ofproducts.
4. How to summarize findings in writing in a clear and concise manner.
5. Hou'to use the scientific method to create, test, and evaluate a hypothesis?
6. How to engage in safe laboratory practices handling laboratory glassware, equipment. and
chemical reagents.
7. How to perfonn common labolatory tecluriques, including rellux. distillation, steam distillation,
recrystallization, vacuurn filtration, aqueous extraction, thin layer chronatopgaphy, column
chromatography.
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Page 16 of25
PAPER VI OBJECTIVES:
Unit I - separation techniques are the basic tool to separate impurities in organic as well as
inorganic compounds. Chromatography is introduced in detail
Unit II - the basics ofspectroscopy and its applications are required to be understood by all
biologists and chemists
Unit III Catalysis are totally theoretical studies but are essential for students, as it is an
-
important topic for all post graduate entrance exams
Laboratorv Course:
1. Instrumentation-use of colorimeter, conductometer and ph-meter will help the students in the
industries
PAPER \TIII OBJECTIVES:
]@i!! - Basics of drugs & formulation chemistry is important for the pharmaceutical industries.
Unit II - Use ofgreen pesticides and harmful effect ofother pesticides are important area of
study.
Unit III - Material science, polymers and nanotechnology are the allied subjects in chemistry,
which find a great place in modem research.
Laboratory Course:
l. Kinetic studies and determining the order ofa reaction are the main experiments in this paper.
2. Distribution co-efficient for associated and non-associated compounds are also studied.
3. A project on analyses of spectra is allotted to the students
RTFERENCE BOOKS SEM V & VI
PAPERV&VII
ORGAI{IC CHEMISTRY
1. Organic Chemistry by R.T.Morrison and R.N .Boyd
2. Organic chemistry by John Mc Murrys.
3. Problems and their solutions in organic chemistry by I.L Finar
4. Reaction mechanisms in organic chemistry by S.M.Mukherji and S.Singh
INORGANIC CHEMISTRY
1. Concise Inorganic Chemistry by J.D.Lee
2. Basic Inorganic Chemistry by Cotton and Wilkinson
3. Advanced Inorganic Chemistry Vol-I by Satyaprakash,Tuli,Basu and Madan
4. Inorganic Chemistry by J.E.Huheey.
5. Inorganic Chemistry by Chopra and Kapoor.
6. Inorganic chemistry by R. R Heslop and P. L Rohinson.
7. Inorganic chemistry by D.F Shriver, P.W Atkins and C.H Langford.
bn/" PagelT of25

9
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PHYSICAL CHEMISTRY
l. Principles ofPhysical chemistry by Puri, Sharma and Pathania
2. Physical Chemistry by D. F Shriver, P.W.Atkinson and C.H. Langford
3. An Introduction to Electrochemistry by S Glasstone.
PAPERVI
l. Industrial chemistry by B.K.Sharma
2. Molecular spectroscopy by J R Dyer
3. Molecular spectroscopy by Silver Stein
4. Spectroscopy by Banwell
5. General chemistry by Scoog & West.
PAPER VIII
l. Synthetic drugs by David Krupa Dalam
2. Biomolecules by Satyanarana
3. Biomolecules A K Dey
4. material
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Page 18 of25
9
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SEMESTER V and Vll SYLLABUS
OBJECTIVES:
Phvsical chemistrv:
1. Concepts in thermodynamics, different thermodynamic quantities such as heat and work and how
they are measured related or transformed from one to the other.
2^ Chemical equilibrium and its relationship with thermodynamic quantities.
3. The transport of ions and thermodynamic functions with applications to electron transfer in
biological systems.
4. Chemical kinetics; how reaction rates are measured and represented in rate laws, and applications
of chemical kinetics in studying enzyme mechanisms.
Orpanic chemistry:
v Y Students willgain an understanding of
1. Fundamental electronic structure and bonding in organic molecules.

2. Correlate the physical properties of organic compounds with the structure of the molecules.
3. The reactivity of different compounds.
4. Students will be able to discuss the reactions involved in the preparation of nitrogen
compounds, heterocyclic and biochemistry.
ln-organic chemistrv:
1. Student gain in depth knowledge of orbital picture and their energy levels
2. They predict reaction mechanism and the connection between isomerism and reaction
mechanism of complex compounds.
.3. They understand spectra of complexes and various properties like color, magnetic properties of
complex compounds.
4. Students learn biological importance of transition metals and their applications in the form of a
complex compound.
5. They get knowledge 0f complex compounds in the nature like chlorophyll and predict
mechanism 0f photosynthesis etc.., role of hemoglobin in oxygen transportation
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Laboratorv Course:
1. The planning and implementation of advanced organic reactions.

2. Detailed organic structure analysis how to calculate a limiting reagent, yield, and percent yield.
3. How to critically evaluate data collected to determine the identity, purity, and yield of products.
'4. How to summarize findings in writing in a clear and concise manner.
5. How to use the scientific method to create, test, and evaluate a hypothesis.
6. How to engage in safe laboratory practices handling laboratory glassware, equipment, and
chemical reagents.
7. How to perform common laboratory techniques, including reflux, distillation, steam distillation,
recrystallization, vacuum filtration, aqueous extraction, thin layer chromatography, column
chromatography.
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SEMESTER V! SYLLABUS
OBJECTIVES:
Unit I - separation techniques are the basic tool to separate impurities in organic as well as inorganic
compounds. Chromatography is introduced in detail
Unit ll - the basics of spectroscopy and its applications are required to be understood by all
biologists and chemists
Unit lll - material science, polymers and nanotechnology are the allied subjects in chemistry, which
find a great place in modern research.
Lalpfalory Cqurse:
1. lnstrumentation-use of colorimeter, conductometer and ph-meter will help the students in the
ind u stries
SEMESTER VIII SYLLABUS
OBJECTIVES:
Unit I - Basics of drugs & formulation chemistry is important for the pharmaceutical industries.
Unit ll - Use of green pesticides and harmful effect of other pesticides are important area of study.
Unit !tt - Catalysis and nuclear chemistry are totally theoretical studies but are essential for students, as
they are important topics of all post graduate entrance exams.
Laboratorv Course:
1. Kinetic studies and determining the order of a reaction are the main experiments in this paper.
2. Distribution co-efficient for associated and non-associated compounds are also studied.
3. A project on analyses of spectra is allotted to the students
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OUTCOMES
CHEMISTRY:
OUTCOMES OF TEARNING ORGANIC CHEMISTRY
1. The reactivity and stability of an organic molecule based on structure, including conformation
and stereochemistry.
2. The prediction of mechanisms for organic reactlons.
3. How to predict the outcome and mechanism of some simple organic reactlons, using a basic
4. How to design syntheses of organic molecules?
5. How to determine the structure of organic molecules using lR and NMR spectroscopic
techniques?
5. How to perform common laboratory techniques, including reflux, distillation, steam distillation,
recrysta llizatlo n, vacuum filtration, aqueous extraction, thin layer chromatography, column
chromatography.
OUTCOMES OF LEARNING INORGANIC CHEMISTRY
Students will:
1. Understand the basic principles and concepts of inorganic chemistry and appreciate their
relevance to selected examples of biological processes and materials science
2. Demonstrate knowledge and understanding ofthe acid-base concept and definition.
3. Demonstrate knowledge and understanding of the structure and bonding of main group
compounds and transition metal complexes and their relevance to the electronic absorption and
maBnetic properties of transition metal complexes
4. Gain knowledge and understanding of the thermodynamic stability of metal complex formation.
5. Demonstrate knowledge and understanding of the role of main group elements and transition
metl complexes in bioinorganic chemistry.
5. Be abie apply the knowledge of quantitative and qualitative analysis in day to day life and
{ analyze and interpret the results.
OUTCOMES OF TEARNING PHYSICAL CHEMISTRY
Students will:
1. State a nd a pply the law of thermodynamics and predict chemical equilibriumand

sponta neity of chemical reactions.
2. Describe reaction rates and perform calculations to determine them.
3. ldentify an oxidation - reduction (redox) reaction based on changes in oxidation numbers
across the chemical change and describe the basic principles of battery design.
4. 4. Students will be able to design and carry out scientific experiments is well as accurately
record and analyze the results of such experiments.
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5. 5. Students will be skilled in problem solving, critical thlnking and analytical reasoning as
a pplied to scientific problems.
OUTCOMES OF LEARNING SPECTROSCOPY
1. After the end of the course the student:

1. Will gain the understanding of the use of nuclear magnetic resonance spectroscopy, mass
spectrometry and infrared spectroscopy for organic structure elucidation.
2. Will be able to interpret elemental analysis technique.
3. Explain working basic and using of elemental analysis device.
4. Student will be able to select molecular spectroscopy methods suitable for solving given
scientific problem.
5. Student will know the basic physical chemistry law that governs molecular spectroscopy.
OUTCOMES OF LEARNING NUCTEAR CHEMISTRY
Students will be able to:
1. Explain the macroscopic observables associated with nuclear change and the microscopic or
chemists view of nuclear change.
2. ldentify and define various types of nuclear transmutation including fission, fusion and decay
reactions.
3. Use proper isotopic notation to write down and balance a nuclear reaction.
4. State and compare the differences and similarities between a nuclear change and a chemical
cha nge.
5. Understand the basics of nuclear chemistry applications: nuclear power, medical treatment,
isotopic labeling, and carbon dating.
OUTCOMES OF LEARNING DRUGS
Students will be able to:
1. Explain the physic-chemical properties of drug molecules, its absorption, distribution,

metabolism and excretion (ADME).
2. Understand the chemical basis of pharmacoloBy and therapeutics.
3. Explain the mechanisms of drug pathways.
4. Explain the role of pharmacology in drug choice and the treatment of disease.
5. Analyze the adverse effects and side effects of drugs.
ba^
SKILL ENHANCEMENT COTJRSE (SEC)
SEMESTER III
SAFETY RULES IN CHEMISTRY LABORATORY AND PREPARING LAB
REAGENTS(credits:02) (30 hrs 15 weeks)
(2hlw)
IJNIT I:
Laboratory Safety Rules and Regulations

General rules and regulations for lab safety: Minimizing Risks of Hazards, Personal Protective Equipment
(PPE) - Hair, Dressing for the Laboratory, Eye Protection, Eye-wash fountain, Gloves.
Laboratory Protocols- Labeling Chemicals, Careful reading of labels Prevention of Inhaling
Harmful Chemicals- Guide to Chemical Hazards, Chemical Spills.
Accidents- use of fire extinguisher and first aid kit in the laboratory, safety symbols
Normality/Nfolarity and specific gravity ofconcentrated acids - Preparation of dilute solutions
(Numerical problems). Precautions to be taken
in the preparation ofdilute acids and bases and bases.
Preparation ofstock solutions ofsalts with specific examples. Properties of primary standard salt and
preparation of standard solution. Good
laboratory practices-maintenance of observation book record.
UNIT II:
Preparation of Lab Reagents:

Preparation of indicators and use of indicators in volumetric analysis- acid base titrations, redox titrations,
precipitation titrations and
complexometric titrations. Role ofan indicator in detecting end point (Phenolphthalein, Methyl orange,
Methyl-red, Potassium Chromate, Diphenylamine, EBT, Murexide, etc). Preparation of
buffers - pH l0 ammonical buffer and acetate buffer solutions.
Preparation of commonly used reagents : Ammonium hydroxide solution, Ammonium molybdate
reagent, Ammonium hydrogen phosphate solution, Bromine water, Dimethyl glyoxime reagent, 2,4-
Dinitrophenyl hydrazine reagent, Eriochrome black-T reagent Fehling solution, Ferric chloride solution,
Ferrous sulphate solution, Iodine solution, Molisch's reagent,
Neutral FeCl3, Schi{Ps reagent, Silver nitrate solution, Sodium carbonate solution, Sodium hydroxide
(Caustic soda) solution, Starch solution, Tollen's reagent.
(reference work and submission of assignments).
RECOMMENDED BOOKS
l. Vogel's Text Book of Quantitative Chemical Analysis, sthedition.
2. Vogel's Text Book of macro and semimicro qualitative inorganic analysis. G. Svehla, 5th edition.
3. American Chemical Society Safety in Academic Chemistry Laboratories 8thedition.
OUTCOMES FOR SAFETY RULES IN CHEMISTRY LABORATORY ANI)

PREPARINC LAB REAGENTS:
. To improve the skills of students in the application of theory and practical knowledge.
. To fill the gap between theory and practicals.
. To hain the students in understanding laboratory safety rules and to improve the skills in
preparation of laboratory regents.
. To make students aware about best lab practices.
Page2l of25
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SKILL ENIIANCf,MENT COI]RSE (SEC)
SEMESTf,R IV
GR-Ef,N METHODS IN CHf,MISTRY(credits:02) (30 hrs 15 weeks)
(2htw)
THEORY AND HANDS-ON EXPERIMENTS
INTRODUCTION: 8h
Definitions of Green Chemistry. Brief introduction of twelve principles of Green Chemistry,
with examples, special emphasis on atom economy, reducing toxicity,green solvents, green
reactants, green reagents,one pot syntheses. Green Chemistry and catalysis and altemative
sources of energy.
GREEN ENERGY AND SUSTAINABILITY. BETTER LIVING THR OUGH GREEN

CHEMISTRY: 10h
l.Surfactants for Carbon Dioxide -replacing smog producing and ozone depleting solvents with
CO2 for precision cleaning and dry cleaning of garments.
2 Designing of Environmentally safe marine antifoulant,green computing.
3.Rightfit pigment: synthetic azopigments to replace toxic organic and inorganic pigments, green
pigments.
4 An efficient, green synthesis of a compostable and widely applicable plastic (poly lactic acid)
made from corn, green plastics.
5.Improvement of lab atmosphere-green guidelines.
LAB COURSE: t2h

l.Altemate procedure for Lassaignes test
2.Acetylation of primary amine
3. Bromination of acetanilide
4.Transesterifi cation reaction -synthesis of biodiesel.
5.Green photochemical reaction-photoreduction of benzophenone to benzopinacol
REF'ERENCE BOOKS:
l.Anastas,P.T. andWamer,J.K. Oxford -Green Chemistry-Theory and Practical, University
Press,l998
2.Matlack,A.S., Marcel Dekker,200l - Introduction to Green Chemistry,
3. Sharma, R.K.,Sidhwani, I.T. andChaudhari, M.K.- Green Chemistry
4. Ahluwalia Vk Kidwai - New Trends In Green Chemistry
OTITCOMES T'OR GREEN METHODS IN CHEMISTRY:
o Know about green lab practices.

. Improving reaction efliciency by changing certain parameters and making it more environment
friendly.
o Leaming about green reagents and their mode ofaction in making chemistry less hazardous'
o Atom economy and its usefulness i.e. utilizing 10002 ofthe reactants.
o Different green reactions.
PageZ2 of25
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SKILL ENHANCEMENT COURSE (SEC)
SEMESTER V
BASI C ANALYTICAL CHEMISTRY: (CREDITS:02) (30 hrs 15 weeks)
(2hlw')
INTRODUCTION: 5h
Introduction to Analyical Chemistry and its interdisciplinary nature. Concept of sampling. Importance of
accuracy, precision and sources of error in analyical measurements. Presentation ofexperimental data
and r€sults, from the statistical point of view, using a few examples.
ANALYSIS OF SOIL: 5h
Composition of soil, Concept ofpH and pH measurement.
a. Determination of pH of soil samples.
b. Estimation ofCalcium and Magnesium ions as carbonates by complexmetric titration.
ANALYSISOFWATER: 5h
Definition of pure water, sources responsible for contaminating water, water sampling methods, water
purification methods.
a. Determination of pH, acidity and alkalinity of a water sample.
b. Determination ofdissolved oxygen (DO) ofa water sample.
ANALYSISOFCOSMETICS: 5h
Major and minor constituents and their functions
a. Analysis ofdeodorants and antiperspirants, Al, Zn, boric acid, chloride, sulphate.
b. Determination ofconstituents oftalcum powder: Magnesium oxide, Calcium oxide, Zinc oxide and
Calcium carbonate by complexometric titration.
LAB COIIRSE: lOh

a. Determination of of macro nutrients in soil samples.
b. Spectrophotometric determination of Iron in Vitamin / Dietary Tablets.
c. Spectrophotometric Identification and Determination ofCaffeine and Benzoic Acid in aerated drinks.
REFER-ENCE BOOKS:
l.Willard, H.H., Merritt, L.L., Dean, J. & Settoe, F.A. Instrumental Methods of Analysis. 7th Ed.
Wadsworth Publishing Co. Ltd., Belmont, California, USA, 1988.
2.Skoog, D.A. Holler F.J. & Nieman, T.A. Principles of Instrumental Analysis, Cengage Leaming India
Ed.
3.Skoog, D.A.; Wes! D.M. & Holler, F.J. Fundamentals of Analyical Chemistry 6th Ed., Saunders
College Publishing, Fort Worth (1992).
OUTCOMES OF ANALYTICAL CHEMISTRY:
l. It enhances the knowledge and skills required for attaining analltical and critical abilities,
logical thinking, and ability to apply knowledge leamt to solve issues and problems related
to chemical analysis.
2. Improve the use of statistical tools.
3.Used in determining the water quality refers to the chemical, physical, biological, and
radiological characteristics of water. It is a measure of the condition of water relative to the
requirements ofone or more biotic species and or to any human need or purpose.
Page 23 of25
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4. pH, hardness, presence ofa selected group of chemical parameters, biocides, highly toxic
chemicals, and B.O.D are estimated. pH is a measure of hydrogen ion concentration. It is an
indicator ofrelative acidity or alkalinity of water. ... Drinking water should have a pH between
6.5 and 8.5.
5. ph. Soil pH is one ofthe most important parameter son your soil test report. The pH level of
the soil can tell you a lot about the potential availability ofplant nutrients and on possible
toxicities of other elements (such as aluminum). Soils with pH greater than 7.0 are considered to
be alkaline soils.
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Page 24 of 25
SKILL ENHANCEMENT COI,]RSE (SEC)
SEMf,STERVI
CHEMINT'ORMATICS(credits: 02) (30 hrs 15 weeks)

(2hlw)
INTRODUCTION TO CHEMINFORMATICS: 2h
History and evolution of cheminformatics, use of cheminformatics, prospects of
cheminformatics, molecular modelling, structure elucidation.
RERESENTATION OF MOLECULES AND CHEMICAL REACTIONS: 7h

Chemical Nomenclature - (development, representation of elements and, Molecular formulas),
types of notations, SMILES coding, matrix representation, structue of Molfiles and Sdfiles,
libraries and tool kits, reaction classification.
SEARCHINGCHEMICALSTRUCTURES: th
Full structure search, sub-structure search, basic ideas, similarity search, 3D search methods,
Basics of computation ofphysical and chemical data and structure descriptors.
APPLICATIONS: l2h
Prediction ofproperties ofcompounds: Linear free energy relations, Quantitative Structure -
Property Relations, Descriptor analysis, model building, modelling toxicity.
COMPUTER ASSISTED SYNTHESIS DESIGN.
DRUG DESIGN - introduction, Drug discovery process (Target identification and validation,
Lead finding and optimization), Application of cheminformatics in drug design (Analysis of
HTS data, virtual screening, design of combinatorial libraries, ligand based and structure based
dnrg design).
REFERENCE BOOKS:
I . Andrew R. Leach & Valerie , J . Gillet (2207) An introduction to Cheminformatics.
2. Gasteiger, J. & Engel, T. (2003) Cheminformatics: A text book. Wliey-VCH
OUTCOMES FOR CHEMINFORMATICS:
o Leam about drawing chemical structures on pc

. Using the tools to search the chemicals in the database to help in research.
. Identificationofproteintargets.
. Spectral predictions ofvarious drugs.
o Molecular modeling
e Hands on experiment on drug development using cehminformatics.
o Hands on molisnpiration.
\u^
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GENERIC ELECTIYE - I
SEMESTERV
ORGANIC FARMING (CREDITS :02 )

(30 hrs 15 weeks)
(2hlw)
(Course include.s theory and practicals)
UNIT.I:
CONCEPT OF ORGAMC FAR}TING 5h
l. Introduction: Farming, organic farming, concept and development oforganic farming.
2. Principles of organic farming, Types of organic farming, Biodynamic farming
3. Benefits oforganic farming: Need for organic farming, Conventional farming v/s organic farming
4. Scope oforganic farming; national and intemational status
5. Agencies and institutions related to organic agriculture
6. Requirements for organic farming, Farm components for an organic farm
I]NIT - 2: ORGAIYIC PLANT NUTRIENT MANAGEMEI{T 5h

l. Organic farming systems: Soil tillage, Land preparation and mulching
2. Choice ofvarieties
3. Propagation-seed, planting materials and seed treatments, Water management
4. Green manuring, Composting- principles, stages, types and factors, Composting methods,
Vermicomposting
5. Bio.fertilizers- types, methods ofapplication, advantages and disadvantages, Standards for organic
inputs- fertilizers
UNIT.III: ORGANIC PLANT PROTECTION 5h

l. Plant protection- cultural, mechanical, botanical pesticides, control agents
2. Weed management
3. Standards for organic inputs- plant protection
UNIT- IV: ORGAIIIC CROP PRODUCTION PRACTICES 5h

l. Organic crop production methods
2. Livestock component in organic farming
IJNTT- V: ORGANIC CERTIFICATION 5h

l. Farm economy: Basic concept ofeconomics- Demand, supply, Economic Viability ofa farm.
2. Basic production principles, Reducing expenses, ways to increase retums, Cost of
production system.
Benefit/ cost ratio, Marketing Imports and exports
3. Policies and incentives of organic production.
4. Conversion to organic farming, Process
5. Income generation activities: Apiculture, Mushroom production, Terrace farming
PRACTICALS 5h
l. Preparation of vermi- compost
2. Preparation of green manure
3. Visit to an organic farm
Page 19 of25
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REFERENCE BOOKS:
L Farming system: Theory and Practice - S.A.Solaimalai
2. Organic Farming: Theory and Practice- S.P.Palaniappan and K.A. Annadurai
3. A hand book of Organic Farming by A.K.Sharma
S FOR ORGANIC FARMIN

Upon successful completion of this course, students will:
l) Have a better understanding of the basic principles of organic farming;
2) Recognize that organic farming systems, ifpracticed in a an environmentally
sound manner, can constitute a larger philosophy of sustainable agriculture;
3) Be able to devise an organic farm management plan.
4) Have improved their ability to think critically about the opportunities and
challenges faced by organic growers.
5) Leam the basic principles of managing biodiversity, crop rotations, non-crop
competitors (weeds) and plant health for productive cropping systems with
minimal off-farm resources.
GEI\ERIC ELECTIVf, - 2
SEMESTERVI
CHEMISTRY OF COSMETICS & PERFUMES: (CREDITS:02)

(30 hrc 15 weeks)
(2hlw)
(Course includes theory and practicals)
L A general study including preparation and uses ofthe following: Hair dye, hair spray, 10h
shampoo, suntan lotions, face powder, lipsticks, talcum powder, nail enamel, creams (cold cream,
vanishing and shaving creams), antiperspirants and artificial flavors.
2. Essential oils and their impo(ance in cosmetic industries with reference to Eugenol, Geraniol,
sandalwood oil, eucalyptus, rose oil,2-phenylethyl alcohol, Jasmine. 10h
Practicals: 10h
I Preparation
. oftalcum powder.
2.Preparation of shampoo.
3.Preparation of enamels.
4.Preparation of hair remover.
5.Preparation of face cream.
6.Preparation ofnail polish and nail polish remover.
Reference Books:
.E. Stocchi:Industrial Chemistry, Vol-l,Ellis Horwood Ltd. UK.
.P.C. Jain, M. Jain:Engineering Chemistry, Dhanpat Rai & Sons, Delhi
.B.K. Sharma:Industrial Chemistry,Goel Publishing House, Meerut.
OUTCOMf,S FOR CHEMIS TRY Of,' COSMETICS & PERFUMES:

l. Describe fundamentals of chemistry and the scientific basis for cosmetic formulation and the function
of the active ingredients.
2. Comprehend the efforts of scientists in cosmetic product design and developments.
3. Explair/interpret how cosmetics suit for a specific intended function, e.g. how sunscreen works for its
intended function.
W I Page 20 of25
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Bhavan’s Vivekananda College

Of Science, Humanities and Commerce

III YEAR SEMESTER-V

UNIT WISE COURSE OBJECTIVES:

UNIT III-Physical Chemistry-I 15 hrs (1 h / w)

S1-P-3. Solutions: (6h)

SO42-, PO43-, BO33- ,CH3COO-, NO3-

S1-G-2.Structural theory in Organic Chemistry: (9h)

UNIT WISE COURSE OBJECTIVES:

UNIT III-Physical Chemistry-II 15 hrs (1 h / w)

II SEMESTER / PAPER - II (60 hrs / 15 weeks)

Defects in crystals. Stoichiometric and non-stoichiometric defects.

S2-P-2. Colloids and surface chemistry: (6h)

r BHAVAN'S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND

r COMMERCE, SAINIKPURI, SECUNDERABAD.

r Affiliated to OSMANIA UNIVERSITY, Hyderabad.

B .Sc CHEMISTRY COURSE SYLLABUS-CBCS

UI SEMESTER / PAPER - IU (6O hrs/15 weeksl

III{IT III-General chemistry-Il 3O hrs (2hlwl

o IINIT l-Inorgaaic chenistry-Il 3O hrs (2hlwl

r Physical properties: absence of hydrogen bonding, keto-enol tautomerism, reactivity of

I Reduction: Clemmensen reduction, Wolf-Kishner reduction, MPV reduction, reduction

2. Carboxylic acids and derivatives:

3. Active methvlene comp ounds and their reactivitv:

2. Thoery ofquantitative analysrs

l.Chemistry of d-block elements:

2.Chemistry of f-block elements:

LTheories of bonding in meta-ls:

2.Meta-l carbonyls and related compounds:

1. Organic Chemistry by R.T.Morrison and R.N .Boyd

l. A text book of Quantitative analysis by A.I Vogel.

T'NIT III AND UNIT tV

I Principles of Physical chemistry by Puri, Sharma and Pathania

L. Students will gain an understanding of

L. To understand the trends in properties and reactivity of the periodic elements.

1. Titrimetric analysis- is a method of quantitative analysis used to determine unknown

BHAVAN'S VIVEKANANDA COLLEGE OF SCIENCE, HUMANITIES AND COMMERCE,

B. Sc CHEMISTRY COURSE SYLLABUS-CBCS

v SEMESTER / PAPER - V (a5 hrs / 15 weeks)

ORGAN!C, PHYSICAL AND GENERAL CHEMISTRY III

ORGANIC CHEMISTRY III

l.Nitrogen compounds 11h

1.Co-ordination chemistry 11h

ORGANIC CMISTRY & INORGANIC CHEMISTRY-III

l.Hetero cyclic compounds 6h

PHYSICO-CHEMICAL METHODS OF ANALYSIS, MOTECU tAR SPECTROSCOPY AND CATALYSIS

l.Separation techniques 1lh

l.Molecular spectroscopy 12h

V SEMESTER / PAPER - Vl Elective- ll I (45 hrs / 15 weeks)

ELECTROANALYTICA t TECHNIOU ES & MOTECULAR SPECTROSCOPY

1.pH measurements & applications 5h

l.Molecular spectroscopy 12h

ORGANIC, PHYSICAL AND GENERAL CHEMISTRY IV

2.Amino acids and proteins 5h

1. Reactivity of metal complexes 4h

3. Hard and soft bases 4h

ORGANIC CHEMISTRY & INORGANIC CHEMISTRY IV

DRUGS, PESTICIDES, MACROMOLECULES

l.Pharmaceutical drugs 12h

1.HlV and AIDS 5h