Scribd
Upload
70 views57 pages

Statistical Thermo and Assignment

Uploaded by

shakeeliiim
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
70 views57 pages

Statistical Thermo and Assignment

Uploaded by

shakeeliiim
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
You are on page 1/ 57
® Classical << stoliscal > quam macroxopic. wmicOscopic. enetay iS Grtinuoug ning 38 warded (Contam) anid ous of themcynommies :- ew ns ae 3. the entropy of “pure aed pe fly ° Coystaline Cotid at alosoluute! 2ex0( 12 at OK) | is 2er0s Composition < Oriwhonon . Resins entropy , 8 = KginwW W= 70 of now or, Mo. of wi a et lydot of for co rmoleaug ., WW = 2, eS jar Kelnw Caleitalees for A mal geunoity A mleale 2 eet as kets 3 NA 3 - 2 4 22-234 Na ~ a2 2" Ss kgnw - --~ -----. fon mle. kg fad kp oo 2A _ formate & S = ken, lod A Fe molar yecuduunt . entropy i £ x Q Jer AL: We3 S= Kem3 ‘oO aod © Digwibution of moleats :-/pavticales ' Oistinguishable ; indistuteguichalole, oo OO Q Q2e@ © Mlomecrestriehion: 60 + 90 = 190 ay Re | { wn €iae we need 4o tind oud tne eccupubion “) MF hwo: Tord wo com we arrange, 4 a Parheales jy dmee. ut Aovelg of enevny gC ond 2E | Sut, duuk tiie toted ener 38 Ae, j | > N=4 wml) fe S4Eo) See | ken a Oe ta ae Hoss fp anah fs 4) re 4! | = Gag Ton t+ OK (2m ) i | : Type "3": Ms 2) Ne o> na colt s Gs | i se £2 & “4, Ni se | = n= pa, dayne of ith state, i| Larges no. so rite in th state. of parti e we S! ae - yt Fnaishin quishalsle, particles * - Gi). NO. sestiction:- M @) Restriction *- ® one state Gnlaing only one, portile . » 2) M23) Neg fe! ve ® Oceeepation um. bea: © A system. Gasisting of 4 idenkeal and dis tinguiduate ponticle each possessing tree availuole states of-1,2 ard. ZBanits ras (0 units of exergy. The, energy of uy, wy in whidw thas. Grdibow, are: vatished: Inet» 2otp dee! > ideal A Idichnuyl shade. M3, Ned % ° Yin : 000 ee Rady | ws oo oa. 20 f F ae x Me Gortect entropy for 6. identicle particles. With tHuin — occupal ; ruil i four states ig s an L010, 35 in. 7 Na Neg Ba we fh _ 6 Fini Oo: 23! We 60. S§= Kamw S = kg méo. © Catutule te doled ewmber of microclates for 6 ‘\dentical . porticles. with thet. occupation number , C4243) in three. stele ig: Net. Dune 2013 >. N=6, M23. Ni ni, 2 al éi EX CXAKZALA | SS oulakeae oy. PO ZEZ | = 60 W= © the mweber of is in ‘which four reolecules car be distributed in 40 ditlerenf- energy Let! Net dec: 2013 > Ns 4 Me 2Q i we He . VHha = ah ee © the term Bymbo| tor tne groand stofe of a rmefak ton, ig 2p. the. vesidust entsupy. ota eryted of a. cng Ei atuig metol- ion od OK Is, G= Kp w | => Binjoomn 8 f 2Ut ” type. | wt = “ASy BR a : 26rd Dea Asal Ls 3p. Je2 a deguwoy = (a0n) = Qx2t! =; = leinw = kgln wd ® Cuv dubia rmoleng ore distributed ty | energy ‘lwrels and By with degowraay of 2 ond. 8 ‘eapertiony ww. of miaostales , with, 3 muleuas - energy forel VB) and ome ip. enery torel § Gr iS, —F 4:3 =—f Ae 2 Neq, MD ni we wt X(%) Be eri? boda @ YQ 4 (Gx@) = %6 © Qrnsider a System of Arve, iden and distinguishuble non interacting parties ond tree avallone, non oto. i Luelg heviny energy O,£, 28. the Sywem is in forty wor of fewpT. * tofol. enemy of 2€ is shared ny, Aierese Hee. particles THe numer of Woy, the, “pores - Com be- distvivuled ig... e GATB 2019 gil => N=3 Morwell Bote mun =] ql MA (Gent! Mee . f B inched yeraed! | Er-2¢ se. Pres wei ae 0 1 2g, am Ae j devant Dr we nino a — & n;\ ee: 00 4, ie : Eq = 2¢ 1 Voy wlocl 3! _ 3226 Toast Toll! Clas =3 >. Prtori/ Equal probability : Qe om ee System, the members | ot engemble ae equa tH stil over the possible, vv Stotes te, at wicsostates aye probable. Engerable :- fooye Collection. of irdividuat mils of 0 Sythe Clossibicatorn ot expen SS” ~~~ C om tne boris of-inlerattion of members of engemnle with tw Surteurdi ee i Ps ee 2 Mon - Cormnicle ensemble. Sere ee ¢ Isoloded Sys), (os 4s). ( oa syle) re, aay axe Hed ot Ove. od. t ore, fixed Gub. fixed. 5 au ave - (erbersiven property - T 77 intone, © isoboric.- isotheemal Bremble:. ( N, p, +) ave fred partition function (¢) ib. indices 660 tre partic are. distvitubed b/w yorloug enero Gols / stake. Bot - Disipabion_:. Roeenoon DReibstion;- energy of tth Level . Mh = aie ‘Teer, eccry particles im. th level. Me 13ex 78 OKA Qi ge ob - bf a Me We ay + By 5 ee eT f : ~ bs, ag shige gett toial. wo. of particle t= Pot Man, \) pation function (9) ; q Properties, ot povtition junction. *# poxtifion durction 1g anit us amd. dimunkonless . ee Fraction of Parties in ith. levels = | : et Bey * si 6 Flkst ge Eat for. Ground state ; to =I =o (energy of ground stale), Porhtion function ig defied an fraction ot partides in ground 3 as rea procod of @ (3). Bptition furclton at low temp: fir Co Ua rst 4 = x te fet J -& | 4, 6 tet 4 ae fur vg [er for . ground: alate. & +0. , 4. wy He ye = a ae ah. lod tow. Aira Ct —e).. yh Eg "At fous temp orly grund state accessible . (4) Paxfition Junction ot be ‘aah Be m ey ot bees g 6 ge We Ye +0. ez] | — J 1 At Wtgly temp. aut tne. stakes ave acescible, ®) Powtition. function. is rulhpticadive in nal. (6) Canonicle partition funchoy,s . (i) Re distinguishable particles ». for ore land of disribwrsow, of N porticles . ‘ for 3-Uind of dictributton oF NM = 4x99 Roe NeKind ge of - distribubion of N peat! ( oT rolecanlin. partition ult, Conia positon. P © Ge indistinguishewre posticles ». r se SP % le. * Bons tadboncs partition fa Drapagpile chon: . = ~ Bi, + Salt, eae Vegr j Ta9 “therm dy names grunt Stote energy =0 ie 2g Varnns = Fae Stat 9 guantam Mechanics ,tiarsfohonot amotion i$ represen bed by Portion iygepan model, foe AD bow) qi = Os are ad fs ah 7 Bm aye Tins = s oom AT 2] 6 ath? ¥ 4rang = hs 7 OME RT emi = A 2 | Jor 4D box fon BD. wox. 4 exang 5 4,0). 4,0 ) (1), ANrareT yp (QTmKeT = / 1 4 [SF 7A i 4%, 4 = (Boney) Me dy. n3 Cea Nouns , gs ee sy ton = 3 a Ae S © [> ve i AMIKGT Ch h h = thermak waved {RRART h Ree] —o fon BD lox. is 2M Nh, Ning. = SOT, n3 ‘ Vv SY (anomie V2 v — wih fl A) \3 | (aime A) { “SS thermal Wave Luft, itis extensive, (depend Upor) Voluwwe \ a © Relational pthtion fanchon ». ae q EE bo wigid tolow » eet as an) (ae0.,2 ~ 63+) bets = (aan) @ KT gsound stote | energy (a0) f= abt) en Sk ” -& Vaot' = (20m) € *fat m (one) € : Lp 4 Gane 2/kt es # == - Of 2a - 68 G robbs C es + 6e@ Wet 3.e XT DPB - £6 Vat = It Be KT 4 oe RT use if 1< Op (2-2) ear T>. Or Cp Ms Ore a 62 Oyernalt 2 BTL aogeurkenist Tb Vy f = bar ane Characteristic sotational temp (6) ) One He % Ta a £ por Or fe Gorrechon m atotahonat portition function’. 4 KE) 4 Mr-ard Ge Be ae Ry & it gives aceurvote rresuihe imty fon, hetero dickomic moleats. fromo- dobre Be 0° Sat) ie Qt 36a ORG n ‘ a =H | H-H 10 WW ! Hin eee hoy Ass equivewd,, Gnformukon (2) Ss Sdistinguishose « 4 el fol \ word I ech (oa Glormation)) \ asagaie. +k ne / indigtin guishable factor: ; («) a ther Corretion Homodictome muleate..(eq- Wa,%,&) => 622 ' Reter o diatomic molecule Cutt ,co,o) ®> 6=\ # oO WO Nu OF ots of rotation Ca-ans , +e C3 @23 i * +e | He re We CSemh i! plnty (_ Simian fo #2) | G>2 ee CHZ — CR cw u | w Similan to Atty Hl c 623, wry Na ' t Vilrodional partition. unelion: fata Ya yhett Foo 4. D 80, = Bethe gs =. = ! are, a = +1) ws 39 fas. fy) aot RQ z sD mw sy & 20a as & (4) Ww . o ie $09 409 be és (3m) gy 30 te i? iy wv ”, Cm) D9 = es Co), FN ® Vieratonal ousttion unelton, titty out 2°81 mt, E20 i ~8i/, Vin 2 5 e a ap Seley -Efer — Bfet- Sir Date: +e +e +8 -9 se tet + eer = mY 31g ‘4 +e act 5 oe fe | = ox =a 6 \+ okt as Vey Petia | Ra ow) we Vaid 2 Veer sential’ o Sikpelsady > “G | (t-e)" aie ee OO Ped eT a Vi 7 ive * et | equicpace4 me 1 wee ses ere T © Winwtienat partition funekon with Beopeint ener Cy 4ni, ey 309, & {Ww fin eo Van eo Ee [est Ld Elke = S/he ~ EJ | Arse a ee ea ne aa: with —2PR © — Ghavacteristic. vibvetional tomb". (6v) Portion function is dimutfionless , & “FET ip) = pallets Gay F g rem Tae wd Shoud the. dimudion of ten. g ae Py Re = Ov 8y% Ve yo Ov Kk te fi & long > eg i mb) Ov | ale Tt= gba Ores dant Se heres Gown tN 1-Cen) a owe Wetec it KH O/T = ey Ye in ee aes vi = = - OF s we 6 , v7 A Sep * A Yostional partition fanckion at lox) temp: unit: Og. | ’ eP/ athe \ eg Sir { uw wi 7 j ep tae Te wr can be vruplaedt 214i = —W@ ae 9 wie Fila io =e at ‘fa Lledwonie parton function: => eletlonic motion iS napresented by H-atom madel , for tH ab, 186 2> Jey En = oye for Habe, 2!) 13-6 cee —. e« (0) : ai ; mae een ee ES ay : “on? ee array on Case iB (-12108) 5 f 3 oe, ae . ef en (+ -2us4) (7 “hd r y phatase 6 y (10983) -” at ; i = Bien Yo zt eet 20 en Sep foe Ess we: ue +he 4 4;¢ > -£ Ve = 20) € omer a ata) - e sosne G tmor tog , 4 Ve = At Smut term, Yur C eukronic anion rare TS approvimndty = Claws», | Cle: A 1 to Kat Ke Teen. Yor ae = OR ones i ‘ . See SE = ach 8 | Ve = G groond state = 2 F cmsin Sf hemodyranies — propabiess - U,8,4,A,% Cv, Pov. 8. O ment enerys:. (v) Us Fries ---- O . = Drie qctlet 4: ether ANE ta PP ol See caet - y 8 m Bie ie wy -& ne = Yue ian ping ts valu in ee eFlkt U= oe a _ ir é che & —®@ ye rae tet DY" wat T ot mene 2 iu Sey > [ar (He N, oe aoa e@ a | sl J} v Bee - Sifer [ | Bay ze Le —"@ 7 Kr v #95 U= er (SH), ; =( bn > parkhon 4a, fee Us EE ath Cress) oho nw.of porkele Na 2 N=1Naq Ke ae © Heuk Copauity ». (©) Ok Genk volume Cev) P ‘ 2nd 8), 2 aCe (8D,)] | ) ot Gant pressure (ep), Op -Cy =n Cp = Cyte. ve AbnG Ces Rt [3 (nwt? Ga) © Entropy :. Gakinw ight : dita : indist eo n eee, 7 we Jt we we NI la RD fom B= Ning + S y He vtPVv Helrn| Acu-1$ . mmass of Ay is Intqlan Ahn. Ve, tous wy Sq Ar > $, We, a8, So Py w~ (2H) € det j GS denotes —Papulsstion_. Be ® = ge KOT wees 5 x) -_ ox , ay a ee ee. eT a a Statistical Thermodynamics Assignment 1 Q.1 A certain system of noninteracting particles has the single-particle m partition function f = A> where A is some constant. The average energy per particle will be [NET Ju (a) mkT (b) AKT (c) kT/m Q.2 If 6; denotes the characteristic temperatiite fhe magnitude of [9y (H2) ®r (D2)\/[ 8y (HD) 2,(a8su ond lengths (a) 23 (d) 9/8 and distinguishable particle, tates of 1,2 and 3 units, has 10 units ys, W, in which these conditions are [NET Dec. 2011] 4 (6 (d) 10 of energy. The satisfiedsi Q.4 The energy levels of the harmonic oscillator (neglecting zero point energy) are €y = nhv forn=0, 1, 2, ....00. Assuming hv = KT, the partition function is: [NET June 2012] @e (b+ @ 1-5 Oa GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom paeeeaiars Q.5 The correct entropy for 6 identical particles with their occupation number {0, 1, 2, 3} in four states is [NET June 2012] (a) keln6 (b) keln12 (c) keIn60 (d) keln720 Q.6 A system has 100 degenerate energy levels and 100 bosons are kept in it. Find the entropy of the system at equilibrium. (a) 10? kp (b) 10° kp (c) 460.6ke Q.7 Calculate the total number of microstates with their occupation numbers {1, 2, 3}.i [NET June 2013] (a) (d) 720 Q.8 The nu: Si ich four molecules can be distributed in two different e1 [NET Dec. 2013] (a) 6 (c) 16 (d)8 Q.9 The ith the smallest rotation partition function at any temperature among the following is [NET Dec. 2013] (a) CH3-C=C-H (b) H-C=C-H (c) H-C=C-D (d) D-C=C-D GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom paeeeaiars Q.10 The number of configurations in the most probable state, according to Boltzmann formula, is [NET June 2014] (a) ek (b) eske (c) eP&aT (d) e746 /ket Q.11 Using Boltzmann distribution, the probability of an oscillator occupying the first three levels (n=0, 1 and 2) is for 0.633, pi = 0.233 and p2 = 0.086. The probability oscillator in energy levels in n > 3 is 4] (a) 0.032 (b) 0.048 () (d) 1.000 Q.12 Th i ibrational partition functii [NET Dec. 2014] (a) e®/T and ) 0/27 and 5 eer (c) e6/2 (d) @ 9/27 and 2 e0/2T f microstates that are possible, when two particles are distributed in four states such that the resulting wave functions are antisymmetric with respect to exchange of the particles, is [NET Dec. 2014] (a) 16 (b) 12 (8 (d) 6 GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom paeeeaiars Q.14 When T - co, value of the single-particle partition function will be (given: degeneracy of level j=gj) [NET Dec. 2014] 1 @1 (b) go ©) Dj9j Ore Q.15 The probability of finding the harmonic oscillator in the energy level n = | is (neglect zero point energy and assume hy,= kT. (aye (b) e? (c) 1-e?7 @ Q.16 The single-particle partition function a in system has ergy le will then be (k is [NET June 2015] (d) kT/B? ition function) [NET June 2015] (b) replace f% by FY/N! (c) replace f by f/ln (N!) (d) replace f% by fX/In (N!) Q.18 The vibrational frequency of a homo-nuclear diatomic molecule is v. The temperature at which the population of the first excited state will be half that of the ground state is given by [NET Dec. 2015] (a) hv-In 2/kp = (b) hv/ (In 2-kp) — (c) In 2/ (hv-kp) (d) hv-log 2/ kp GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.19 The single-particle translational partition function (f) for an ideal gas in a fixed volume V depends on the thermal de-Broglie wavelength At as f ~ (Am)" where [NET June 2016] (a) n =3 (byn=1 (c)n=-1 (d)n=-3 Q.20 The weight of the configuration with two up and three down spins in a system with five spin ; particles is [NET D ] (a) 120 (b) 60 (20 ( GBs chemistry @ichomistrycontine [~ jemistryoossgnaitcom W Sae0Esz875 Aaspooent- A ue Single porticle ins ‘) Us ner>( Set) U> wr? ( = nef a fuse =r = Int? wy) : Vv ne (3 s At mint - a) D(1nA) B, az (™mnv as Vv ker ie Or(%). Ox(,) a i [Ox (mp) > = ay Bo, Fe x (2 cat = 442 op.) iy oe 8. N=4 Sunt 22 oo Drown toga Ot hs Aunt — freg 44 \ \ a + mh AREY. 4 he aie * ERR E 6484 = 10 ee: pe 2 (meqledting 28) Aan = = leer Assam? WD = kay = / ge} Bo oe SH = GWE = ———— l-e a a I ~ aay e 2. B= kginw 6! Ne ee 12131 exe pinahy KZBBLE = 60 Q- Kg inéo 6. ; Cosong % Rasen: anh Sym sree fo Synd indistiquighuicle, cuove-funiior ; we My a v0 100 too | 00 Ss ep oT ? i Me i = Mg ( 19 m100 —n 10) ON! = nin gy LAY 2 kp }t00Inwo - (Votntea 29} aes rajfieo - Lee feo t sh 2 106 Ky OP») = 10" ky Ww ( mievo stale) —___ 112131 ERS HERERY SZ > 60! ob ko) : Me Mn ‘no restriction, = 24 _ 2° 26 o-@) Fotation portion, si wane Veot = “eB ? ‘= Date: Db der 2s ya fe a-&) lo. S= kin w ee iG w e A). ete ad M- tod popes? ae a Pre Batebe Pathe ---- l= 0643 + 0:233+0-086 + Bp ae \- (0-633+6-233 10-086) = te = 6-048 Yibrotionnd pothbon Lorecki on, _ nd j,28 SE cr le Se ee : wae = . = withow 2PR re 7 Ob low top. pans q-4 at \o) teh 5 (itis ath ged oe ab Wigh tener Q FeS” | Mpg £4 Sta te ere iB) 3S eS ae sg & 13. N=2 Me 4 ‘ati gm edyi¢ indistingudshudsle, : 16 Bue Linen Stohshad . c We Crm)! Ler. ne(mry | Suchen Dirve: Stokistig, Ss we _M! Chat Tie (oy! QE we top Pesmivwy : ‘ill " j rey ns ANA ox ay it. ARH ! 26 op. d) ° el MWe fe Cttyh temp) ose oy ree 2 phe eee zeta wd a este a e . a Le G-€) el ie =; Q-+ -! =, oe os leer «oa *@ ie). and ee aes) 9 att mm (Ave y » (rar mya meet), l br wert Bare emery a a - anny ra er { = Kez KB ; Hlre)-] oP) 2, : Ne © a no. Yedrichen , Biv ‘el CoRR op. (d’) cee Bs 2131 = Jangxes- = 40 Statistical Thermodynamics Assignment 2 Q.1 If the energies of a bare proton aligned along and against an a = AyB. AyB. 7" external static magnetic field (B,) are - and + a, respectively, then the ratio of probabilities of finding the proton along an inst the magnetic field is U | (a) e7PYBz/4keT (b) e~*YBz/2ksT (c) efVBz/2ket (d) e?YBz/keT ator having ing equal to kpT and zero [NET Dec. 2016] e 1 @ (e+1) uted among 4 levels as shown in state I. system and no work is done. The final state could [NET June 2016] (a) I (b) II (c) IV dv GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.4 The translational partition function of a hydrogen molecule confined in a 100 mL flask at 298K (Mol. Wt. of hydrogen = 2.016) is: [GATE 2003] (a) 2.810% (b) 2.8 10% (ce) 2.8x 10% — (d) 2.8 x 10?” Q.5 The vibrational partition function for a molecule with fun mental frequency v is given by 5] (a) exp( mn ©) |a-e edistributed among three non- £0=0, €1= 1.3! id €2 = 2.76 x 10°'J, at LOOK. If the average total en stem at this temperature is 1.38 x 10°'8J, the s in the system is: [GATE 2007] (a) 1000 (b) 1503 (c) 2354 (d) 2987 Q.7 Assuming H2 and HD molecules having equal lengths, the ratio of the rotational partition functions of these molecules, at temperature above 100K is [GATE 2007] (a) 3/8 (b) 3/4 () 12 (d) 2/3 GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.8 A certain molecule can be treated as having only a doubly degenerate state lying at 360 cm’! above the non-degenerate ground state. The approximate temperature (K) at which 15% of the molecules will be in the upper state is [GATE 2008] (a) 500 (b) 150 (c) 200 (d) 300 Q.9 At T = 300K, the thermal energy (kpT) in cm" is approxi ly. 8] (a) 20000 (b) 8000 (c) 5000 Q.10 The molecular partition function q(T) (eect °° Is have their usual med e heat volume for this system is [GATE 2012] (a) 3R (©) 9R/2 (d) 3R/2 Q.11 T! partition function for a system in which the energy le uispaced by e, is [GATE 2014] 1 1 1 4. () Tete (b) oe (©) ee @) re Q.12 For an ideal gas with molar mass M, the molar translational entropy at a given temperature is proportional to [GATE 2015] (a) M32 (b) M'? (oe (d) In(M) GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.13 The rotational partition function of a diatomic molecule with energy levels corresponding to J = 0, 1, is (where, € is a constant) [GATE 2015] (a) 142272 (b) 143e77% (c) 1+e73£ (d) 143e73© Q.14 Consider N particles at temperature T, pressure P, volume V and chemical potential p having energy E. The paramet: t constant for a canonical ensemble are 7 (a) N,V, T (b) N, V,E ()N,P, Q.15 The first excited state ?P12) of fl [NET June 2017] 1 @ me ¢ te Q.16 The t bol for the ground state of a metal ion is *P2. The residual entropy of a crystal of a salt of this metal ion at 0 K is [NET Dec. 2017] (a) kg In 1 (b) kg In 3 (c) kp In S (d) kg In7 GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.17 Four distinguishable molecules are distributed in energy levels E; and E) with degeneracy of 2 and 3 respectively. Number of microstates, with 3 molecules in energy level E; and one in energy level Ea, is [NET Dec. 2017] (a4 (b) 12 (c) 96 (d) 192 Q.18 Translational partition function of D2 molecule cm? vessel at 25°C is 0 (a) 3.8 10% — (b) 5.8 x 10% — (c) 7.8 x 0% Q.19 The translational partition function to a volume x 107! m, is closest [NET Dec. 2018] (a) 24.4 x 10 (c) 0.244 x 10° (d) 244 x 10° Q.20 The differ en standard molar entropies of two mono- atomic (S°m,a- S°m,s) at a given temperature is (given that the m of A is twice the molar mass of B) [NET June 2019] (@)2Rin2 (b) Rin2 ()2RIn2 @ZRIn2 GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom paeeeaiars Q.21 For a linear molecule the mean energies for translation, rotation (T>>6g) and vibration (T>>®y) follow ratio: [NET June 2019] (a) l:=:1 niw (b) 3:1 (c) l:=:1 nie (5 e Q.22 The molar residual entropy (in JK"! closest to Q.23 Cons! ermal equilibrium having energies 0 an ie degeneracies are 1 and 2, respectively. The ye le partition function at the same absolute temperat is 1.4... (Round off to two decimal places) (kp is the constant) [GATE 2019] Q.24 Consider a system of three identical and distinguishable non- interacting particles and three available nondegenerate single particle energy levels having energies 0, € and 2¢. The system is in contact with a heat bath of temperature T K. A total energy of 2¢ is shared by these particles. The number of ways the particles can be distributed IS... [GATE 2019] GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom seseasars Q.25 At temperature T, the canonical partition function of a harmonic oscillator with fundamental frequency (v) is given by enhv/2kgT qvin(T) = —S=awyaret For = = 3, the probability of finding the harmonic oscillator in its ground vibrational state is........ (Up to two decimal places: 8] ® GB. chemistry @ichomistry.ontine [4] johemistryoo1egmailcom iene Assign: 2 A, Polow? _ ®. Fagpirst ty wo of proba. aloniptne shel z | ‘oto. mo. peer) B, ‘= q Ni ~ Gf KF Paw Na 5 <2 ne my MM BAe So &i = & Ere ey at E gee (ree) + AYR. _ es =e a 2nYBa » € 2p hy Ba = gn a Kets ny) cadspanrd . 1 | \ "ew = ren OE ithe 2e¢ we TI ER ny =x. enerey, level axe! changes, WS rah Coast ity meant ee pepastion of portide . © QS HW be adnays pe reitet. # OPQ) She ® [A aa et Awomed woeler Ass 6626x154 Is ing Zon = O°OFS £1g"B am ean l i 2% ADE Gwin"! AIO KY. “Eee ee xine d aoa QIK gs 60228102 Pra “ RO v Oey TED) Meat \q * \oo mL = eo mt ‘+ 6° OFIE Aigo) > 3 10 (we ») = £2! 26 = (TCNTAM ms = PEAI P-© ® wep | _ 0 -(6 \ eer re) Kr Goth) ay, kr x Bao Bue Yelp EE By ET Bay Bay n> aV he rs eel a eT Sx? 2yp = = Bg SE [os Bey, egg = = fe Jay x | 3, 3 = el ay toe IAL «i VD at Sa - &e/kr Ne & € a a5) Soa —— are Y & eae ie a ae = 349s oom! S gat Ve ver ISL of NYP ~ 360_ew! = =. gee Fr d 36 0, - we PL gg ic loo ~ Kaew! x Gases = 2-@ "RRBT RE : = yo geil B60 col x 6 626x10 Y as X43 XI0 cms V3 aK! AT o3 0 ih ey > =360 X 6626x105 2x10 [ec ee 38x AT 2s RNID are 200-2 kK -2 KBT = 38x Saye BeO1 = 36x10 5. 4300 a) és 36 Rip 4300 owl we re ne hag x16? x 300 aso 6626 wip a2 x IAC" Cms = 20%- 22 tw | 20, -[ Oe.) 2[o& ey (AS set] rere ne [ROC -([2e") ¢ NOs a 4 aler) | Cys 3NK ‘ts 3nk, = 3R MW. eqtspaced we % cere 9 (ged Re ed 85 ot tm, SL Sint oh.) 1s. 3 V %, a See YT on = fe = = 4 € ‘fake ¢ ae f “for at pation funihen - J Eepaooys (200) bases eek Sat He T =i : - Bon) = (2a) @ C eon) oe (238) € ee ee) aoe bee i vig oii i se ) G2. ca ruten PD ge C™n,) ; Sear ~ (2) E = ‘ze 4. eck = t. , Bite? Ite 6. Deyo: (221) ian “p-(¢) : S = lain ) ay” we pl y wt = ont] 3 - { BL = 96 / °C) ‘ 1g. Se ine € : rae nh CGE KIO tag A = = See REIN KARTCG MI TU | Senge? =) 010806 XID? mw Yay = too (ere)? » Cu eK Gy? = Tear? bp. (9) y. 4 = AK 109 m3 . Re frend) = O-aurxid 2 a KDB = 20x04 20. ™, = 26 S = TRING ae U{ and =MRIng + tio aa), = AeMG + NRT (oe 2 mol entopy () Z ip 3 meng y our a9 = R\nQ + RT eS = NE z= Canty Ma WG age 4 a m2 TS 4 nV’ a ra ; 2 = =] =m Bink : bd [2 — ‘nile : 3h 4 In 2mK = oe 2 "7 typ my oe ft Vv “+ iny = +(% (1m), ) s = 2 gees e(@ » arent tin) 4 anf T les 5 Sai =e 3 SAT oy v ree ee oh a Sime = e( =) a amv) +3 RL — (2) = ZS RMnaNmakT _ 3 pin BRMeKT ni 2 he ‘ = & Rhy BHT + 22mm \ ng 3 Rt aioe SS 2 in™, | ~ Bin™p | * Z2(Inmg—Inrng ) 3 A = Zk tm Se = 2 py amd = gem ing ob). 2 3 Shin. | a th, . y= ATK) vznurt (224) Se ; v iy oof WOKE y Shih. Bfaor) wi aT 2 34)3 ny Le a." vga NRT (Ss =$7 oY xT 4 Vea, EL Unot = enki? (ZY TPB heey ny = me 2, | = NAT F = bre) > 2 = NKT T nag | : . » Uae wet (4) A = MILT aa a Ua, Une 4 U ver NRT NRT Nut (3) : NK o% ad \ os a2, = Keln Ww SO. 22. 2 6T ra os 4-34e “Er — = ify, we Mt HE T ° 2k0t be + 2: eee = jane ) ' J 7 ay 4

You might also like