Version: 5.

0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Trade name or designation of KLEEN MCT103
the mixture
Version number 5.0
Revision date 24/12/2013
Supersedes date 29/11/2012
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Membrane cleaner
Uses advised against None known.
1.3. Details of the supplier of the safety data sheet
GE Water & Process Technologies Middle East FZE
P.O. Box 261939
Plot S20143
Jebel Ali Free Zone South
Dubai , UAE
Tel : +971 4 8101777
Fax : +971 4 224 7922
e-mail : [email protected]

1.4. Emergency telephone number

Multilingual emergency number (24/7)

Europe, Middle East, Africa, Israel (Europe and English

language speaking countries):
+44(0)1235 239670
Middle East & Africa (speaking Arabic):
+44(0)1235 239671

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Directive 67/548/EEC or 1999/45/EC as amended
Classification C;R34
Hazard summary
Physical hazards Not classified for physical hazards.
Health hazards Causes burns.
Environmental hazards Not classified for hazards to the environment.
Main symptoms Inhalation may cause irritation of mucous membranes and respiratory tract.
Skin contact causes severe irritation or burns.
Classification according to Regulation (EC) No 1272/2008 as amended
Health hazards
Skin corrosion/irritation Category 1B H314 - Causes severe skin burns and
eye damage.

2.2. Label elements

Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Hydroxyacetic acid

Page: 1 / 10
 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Hazard pictograms

Signal word Danger

Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P310 Immediately call a POISON CENTRE or doctor/physician.
Supplemental label information Not applicable.
2.3. Other hazards Not assigned.

SECTION 3: Composition/information on ingredients

Mixtures
Chemical description Aqueous solution of an organic acid, inorganic acid and chelant
Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes

N-hydroxyethylenediamine triacetic >= 20 139-89-9 - -

acid trisodium salt 205-381-9
Classification: DSD: Xi;R36
CLP: Eye Irrit. 2;H319

Hydroxyacetic acid 10 - < 25 79-14-1 01-2119485579-17 -

201-180-5
Classification: DSD: C;R34, Xn;R20
CLP: Skin Corr. 1B;H314, Acute Tox. 4;H332

methoxyacetic acid < 0,3 625-45-6 - 607-312-00-1

210-894-6
Classification: DSD: Repr. Cat. 2;R60-61, C;R34, Xn;R22
CLP: Acute Tox. 4;H302, Skin Corr. 1B;H314, Repr. 1B;H360FD

The classification of the above substance(s) is given, including the symbol letters, R-phrases, hazard class, category code and hazard
statements which are assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16
where the full text of each relevant R-phrase and H-statement is listed.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Remove victim from contaminated area to fresh air and allow to rest.
Skin contact Immediately remove all contaminated clothing.
Wash immediately with plenty of water.
Seek medical attention.

Material name: KLEEN MCT103 Page: 2 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Eye contact Flush immediately with plenty of running water.
Continue rinsing for at least 10 minutes.
Keep eyelids apart.
Seek medical attention.
Ingestion First rinse mouth with water.
Immediately give 1-2 glasses of water, if victim is fully conscious.
Do NOT induce vomiting!
Seek medical attention.
4.2. Most important symptoms Corrosive effects.
and effects, both acute and
delayed
4.3. Indication of any immediate Not available.
medical attention and special
treatment needed

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media Carbon dioxide, dry chemicals, foam, water spray (fog).
Unsuitable extinguishing Not available.
media
5.2. Special hazards arising from Oxides of carbon, nitrogen and phosphorus evolved in fire.
the substance or mixture
5.3. Advice for firefighters
Special protective equipment Self contained breathing apparatus. (CEN : EN 137)
for firefighters Protective clothing (CEN : EN 469)
Protective gloves (CEN : EN 659)
Helmet (CEN : EN 443)
Special fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
procedures Prevent spillage and fire-fighting water from entering in public sewers or the immediate environment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Wear protective clothing, gloves and safety goggles.
personnel
For emergency responders Use personal protection recommended in Section 8 of the MSDS.
6.2. Environmental precautions Prevent from entering sewers or the immediate environment.
Accidental release of large quantities into the aquatic environment may harm aquatic organisms.
6.3. Methods and material for Absorb onto inert material and dispose of according to Hazardous Waste Regulations.
containment and cleaning up Remove small spills with plenty of water.
Spread sand/grit.
6.4. Reference to other sections Please refer also to section no. 8 'Exposure controls' for further information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling Avoid contact with skin and eyes.
7.2. Conditions for safe storage, Store containers closed when not in use.
including any incompatibilities Do not freeze.
If frozen, thaw completely and mix thoroughly prior to use.
7.3. Specific end use(s) Only for professional and industrial users
Shelf life 720 days

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).

Material name: KLEEN MCT103 Page: 3 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Recommended monitoring Not available.
procedures
Derived no-effect level (DNEL) Not available.

Predicted no effect Not available.

concentrations (PNECs)

8.2. Exposure controls

Appropriate engineering controls Adequate ventilation to maintain air contaminants below exposure limits.
Individual protection measures, such as personal protective equipment
Eye/face protection Splash proof chemical goggles.
Face shield.
CEN : EN 166
Skin protection
- Hand protection Gauntlet type neoprene gloves (Protection against unintentional short-term contact)
Gauntlet type nitrile gloves (Protection against unintentional short-term contact)
Gauntlet type butyl gloves (Protection against unintentional short-term contact)
CEN : EN 374-1/2/3; EN 420
- Other Chemical resistant apron.
CEN : EN 340; EN 368; EN 369; EN 467
Respiratory protection In case of insufficient ventilation, use a breathing mask with filter type: P2
CEN : EN 140; EN 143; EN 149
Thermal hazards Not available.
Environmental exposure controls Prevent from entering in public sewers or the immediate environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Colour Colourless to amber
Physical state Liquid
Odour Slight acetic
Odour threshold Not available.
pH (concentrated product) 3,4
pH in aqueous solution 3,3 (5% SOL.)
Melting point/freezing point -21 °C
Initial boiling point and boiling 99 °C
range
Flash point > 100 °C P-M(CC)
Evaporation rate < 1 (Ether = 1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower (%) Not available.
Flammability limit - upper Not available.
(%)
Vapour pressure 18 mm Hg
Vapor pressure temp. 21 °C
Vapour density > 1 (Air = 1)
Relative density 1,35
Relative density temperature 21 °C
Solubilities
Solubility (water) 100 %

Material name: KLEEN MCT103 Page: 4 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not available.
Viscosity 28 cps
Viscosity temperature 21 °C
Explosive properties Not available.
Oxidizing properties Not available.
9.2. Other information
Percent volatile 10 (Estimated)
Pour point -18 °C
Shelf life 720 days

SECTION 10: Stability and reactivity

10.1. Reactivity Not available.
10.2. Chemical stability Material is stable under normal conditions.
10.3. Possibility of hazardous Not applicable.
reactions
10.4. Conditions to avoid Protect from freezing.
10.5. Incompatible materials Avoid contact with strong oxidisers.
10.6. Hazardous decomposition Oxides of carbon, nitrogen and phosphorus evolved in fire.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Product Test results
KLEEN MCT103 (Mixture) Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated according
to GHS additivity formula)
Acute Inhalation LC50 Rat: 12,4 mg/l 4 hour (Calculated
according to GHS additivity formula)
Acute Oral LD50 Rat: 4630 mg/kg (Calculated according to GHS
additivity formula (Category 5))
Components Test results
methoxyacetic acid (625-45-6) Acute Inhalation LC50 Rat: > 3200 ppm 7 hour
Acute Oral LD50 Rat: 1000 mg/kg
Hydroxyacetic acid (79-14-1) Acute Inhalation LC50 Rat: 3,6 mg/l 4 hour
Acute Oral LD50 Rat: 1938 mg/kg
Acute toxicity Not classified.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Respiratory sensitisation Not classified.
Specific target organ toxicity Not classified.
- repeated exposure
Specific target organ toxicity Not classified.
- single exposure
Carcinogenicity Not classified.
Germ cell mutagenicity Not classified.
Reproductive toxicity Not classified.

Material name: KLEEN MCT103 Page: 5 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Information on likely routes of exposure
Ingestion Causes burns in mouth, throat and/or stomach.
May cause slight gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and
diarrhea.
Inhalation Irritating to respiratory system.
Prolonged exposure may cause dizziness and headache.
Skin contact Causes burns.
Eye contact Causes burns.
Symptoms Not available.
Mixture versus substance None known.
information
Other information Not available.

SECTION 12: Ecological information

12.1. Toxicity
Product Species Test results
KLEEN MCT103 (CAS Mixture)
0% Mortality Fathead minnow 2000 mg/l, Static Bioassay with 48-Hour
Renewal, 96 hour, (pH adjusted)
Crustacea LC50 Daphnia magna 1890 mg/l, Static Renewal Bioassay, 48
hour, (pH adjusted)
NOEL Daphnia magna 1060 mg/l, Static Renewal Bioassay, 48
hour, (pH adjusted)

12.2. Persistence and degradability

- COD (mgO2/g) 335 (calculated data)
- BOD 5 (mgO2/g) 70 (calculated data)
- BOD 28 (mgO2/g) 105 (calculated data)
- Closed Bottle Test (% 23 (calculated data)
Degradation in 28 days)
- Zahn-Wellens Test (% 27 (calculated data)
Degradation in 28 days)
- TOC (mg C/g) 150 (calculated data)
12.3. Bioaccumulative potential Not available.
Partition coefficient
n-octanol/water (log Kow)
Hydroxyacetic acid -1,1
Bioconcentration factor (BCF) Not available.
12.4. Mobility in soil Not available.
12.5. Results of PBT and Not a PBT or vPvB substance or mixture.
vPvB assessment
12.6. Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contaminated packaging According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 10

15 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not otherwise
specified.
15 01 Packaging (including separately collected municipal packaging waste).
15 01 10 Packaging containing residues of or contaminated by dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

Material name: KLEEN MCT103 Page: 6 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Disposal methods/information According to Hazardous Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 05

16 Wastes not otherwise specified in the list.
16 03 Off-specification batches and unused products.
16 03 05 Organic wastes containing dangerous substances.
Depending on the origin and state of the waste, other EWC numbers may be applicable too.

SECTION 14: Transport information

ADR
14.1. UN number UN3265
14.2. UN proper shipping name Corrosive liquid, acidic, organic, n.o.s. (Hydroxyacetic acid, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards No
Tunnel restriction code (E)
14.6. Special precautions for Not available.
user
RID
14.1. UN number UN3265
14.2. UN proper shipping name Corrosive liquid, acidic, organic, n.o.s. (Hydroxyacetic acid, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards No
14.6. Special precautions for Not available.
user
ADN
14.1. UN number UN3265
14.2. UN proper shipping name Corrosive liquid, acidic, organic, n.o.s. (Hydroxyacetic acid, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards No
14.6. Special precautions for Not available.
user
IATA
14.1. UN number UN3265
14.2. UN proper shipping name Corrosive liquid, acidic, organic, n.o.s. (Hydroxyacetic acid, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
14.5. Environmental hazards No
ERG Code Not available.
14.6. Special precautions for Not available.
user
IMDG
14.1. UN number UN3265
14.2. UN proper shipping name Corrosive liquid, acidic, organic, n.o.s. (Hydroxyacetic acid, Mixture)
14.3. Transport hazard 8
class(es)
Subsidiary class(es) -
14.4. Packing group II
Material name: KLEEN MCT103 Page: 7 / 10
 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103

14.5. Environmental hazards

Marine pollutant No
EmS No. F-A, S-B
14.6. Special precautions for Not available.
user
14.7. Transport in bulk This substance/mixture is not intended to be transported in bulk.
according to Annex II of
MARPOL 73/78 and the IBC
Code
ADN; ADR; IATA; IMDG; RID

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I
Not listed.
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended
Not listed.
Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry
Not listed.
Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA
methoxyacetic acid (CAS 625-45-6)
Authorisations
Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
methoxyacetic acid (CAS 625-45-6) 30
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work
Not regulated.
Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding
methoxyacetic acid (CAS 625-45-6)

Material name: KLEEN MCT103 Page: 8 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Other EU regulations
Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances
Not regulated.
Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work
methoxyacetic acid (CAS 625-45-6)
Directive 94/33/EC on the protection of young people at work
methoxyacetic acid (CAS 625-45-6)
National regulations Not available.
15.2. Chemical safety assessment Not available.
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical Substances Yes
(EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

SECTION 16: Other information

List of abbreviations CAS: Chemical Abstract Service Registration Number
TWA: Time Weighted Average
STEL: Short Term Exposure Limit
LD50: Lethal Dose, 50%
LC50: Lethal Concentration, 50%
EC50: Effect Concentration, 50%
NOEL: No Observed Effect Level
COD: Chemical Oxygen Demand
BOD: Biochemical Oxygen Demand
TOC: Total Organic Carbon
CEN: European Committee for Standardisation
EC-No: European Commission Number
CLP: Regulation on classification, labeling and packaging of substances and mixtures
DSD: Dangerous Substances Directive
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
RID: International Rule for Transport of Dangerous Substances by Railway
References Safety data sheets of raw materials.
Information on evaluation The physical, health and environmental hazards of this mixture are assessed by applying the
method leading to the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation (EC)
classification of mixture No 1272/2008 (CLP).
Full text of any statements or R20 Harmful by inhalation.
R-phrases and H-statements R22 Harmful if swallowed.
under Sections 2 to 15 R34 Causes burns.
R36 Irritating to eyes.
R60 May impair fertility.
R61 May cause harm to the unborn child.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H360D May damage the unborn child.
H360F May damage fertility.

Material name: KLEEN MCT103 Page: 9 / 10

 Version: 5.0
Effective date: 24/12/2013
Previous Date: 29/11/2012

SAFETY DATA SHEET

KLEEN MCT103
Revision information SECTION 2: Hazards identification: Response
Composition / Information on Ingredients: Disclosure Overrides
SECTION 3: Composition/information on ingredients: Composition comments
SECTION 8: Exposure controls/personal protection: - Hand protection
Physical & Chemical Properties: Multiple Properties
SECTION 10: Stability and reactivity: 10,5. Incompatible materials
Toxicological Information: Toxicological Data
SECTION 11: Toxicological information: Skin corrosion/irritation
SECTION 12: Ecological information: Summary
Transport Information: Material Transportation Information
SECTION 16: Other information: Based on EC Directive / Regulations
SECTION 16: Other information: Further information
SECTION 16: Other information: Information on evaluation method leading to the classification of
mixture
Training information Provide training on safe handling while considering the type of application and exposure scenarios.
Based on EC Directive / 1999/45/EC
Regulations 2001/118/EC
(EC) No 1907/2006 (REACH)
(EC) No 1272/2008
(EC) No 453/2010
Further information Correction in Section: 2,3,8,14,15,16

Material name: KLEEN MCT103 Page: 10 / 10