journal of environmental sciences 135 (2024) 656–668

Available online at www.sciencedirect.com

www.elsevier.com/locate/jes

MAX-DOAS and in-situ measurements of aerosols

and trace gases over Dongying, China: Insight into
ozone formation sensitivity based on secondary
HCHO

Xiaojun Zheng 1,∗∗, Zeeshan Javed 1,∗∗, Cheng Liu 2,3,4,5,∗, Aimon Tanvir 6,
Osama Sandhu 7, Haoran Liu 8, Xiangguang Ji 8,9, Chengzhi Xing 3,
Hua Lin 10, Daolin Du 1,∗
1 Institute of Environment and Ecology, School of the Environment and Safety Engineering, Jiangsu University,
Zhenjiang 212013, China
2 Department of Precision Machinery and Precision Instrumentation, University of Science and Technology of China,

Hefei 230026, China

3 Key Laboratory of Environmental Optics & Technology, Anhui Institute of Optics and Fine Mechanics, Hefei

Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

4 Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of

Sciences, Xiamen 361021, China

5 Key Laboratory of Precision Scientific Instrumentation of Anhui Higher Education Institutes, University of Science

and Technology of China, Hefei 230026, China

6 Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental

Science and Engineering, Fudan University, Shanghai 200433, China

7 National Agromet Center, Pakistan Meteorological Department, Islamabad 44000, Pakistan
8 Institute of Physical Science and Information Technology, Anhui University, Hefei, 230601, China
9 Information Materials and Intelligent Sensing Laboratory of Anhui Province, Anhui University, Hefei, Anhui

230601, China
10 School of Environmental Science and Optoelectronic Technology, University of Science and Technology of China,

Hefei, 230026, China

a r t i c l e i n f o a b s t r a c t

Article history: This study presents a comprehensive overview of the atmospheric pollutants including Sul-
Received 12 April 2022 fur dioxide (SO2 ), Nitrogen dioxide (NO2 ), Formaldehyde (HCHO), Particulate Matter PM; PM10 :
Revised 31 August 2022 diameter ≤ 10 μm, and PM2.5 : diameter ≤ 2.5 μm), and Ozone (O3 ), over Dongying (Shandong
Accepted 12 September 2022 Province) from March-April 2018 and September-October 2019 by employing ground-based
Available online 24 September 2022 Multiple Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations along
with the in-situ measurements attained by the national air quality monitoring platform. The
concentrations of SO2 and NO2 were under the acceptable level, while both PM2.5 , and PM10

∗
Corresponding authors.
E-mails: [email protected] (C. Liu), [email protected] (D. Du).
∗∗
These authors contributed equally to this work.

https://doi.org/10.1016/j.jes.2022.09.014
1001-0742/© 2023 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
 journal of environmental sciences 135 (2024) 656–668 657

Keywords: were higher than the safe levels as prescribed by national and international air quality stan-
MAX-DOAS dards. The results depict that 21% of the total observation days were found to be complex
Trace gases polluted days (PM2.5 > 35 μg/m3 and O3 > 160 μg/m3 ). The secondary HCHO was used for ac-
Ozone sensitivity curate analysis of O3 sensitivity. A difference of 11.40% and 10% during March-April 2018 and
Secondary HCHO September-October 2019 respectively in O3 sensitivity was found between HCHOtotal /NO2
Complex Pollution and HCHOsec /NO2 . The results indicate that primary HCHO have significant contribution in
HCHO. O3 formation predominantly remained to be in VOC-limited and transitional regime
during March-April 2018 and September-October 2019 in Dongying. These results imply that
concurrent control of both NOx and VOCs would benefit in ozone reductions. Additionally,
the criteria pollutants (PM, SO2 , and NO2 ) depicted strong correlations with each other ex-
cept for O3 for which weak correlation coefficient was obtained with all the species. This
study will prove to be baseline for designing of air pollution control strategies.
© 2023 The Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences. Published by Elsevier B.V.

PM2.5 , diameter ≤ 2.5 μm) and carbon monoxide (CO). These

Introduction six pollutants are considered as key while developing policies
and designing pollution control strategies. Several control reg-
Atmospheric pollution has gained much attention during the
ulations were adopted at national, provincial and metropoli-
past decade owing to acute impacts on ecosystem and human
tan levels to combat these pollutants. These measures which
health. Rapid urbanization, industrialization and increasing
include optimization of industrial structure, reduction of coal
use of fossil fuels to meet the demands of booming population
usage, increase in share of clean energy sources and instal-
are deemed as the important aspects that lead to deterioration
lation of installation of fuel gas desulfurization (FGD) devices
in air quality, consequently posing serious threat to human
have been significantly effective in controlling the criteria pol-
health (Tian et al., 2018; Cheng et al., 2019a; Li et al., 2020a;
lutants including NO2 , SO2 , and PM10 (Wang et al., 2021). How-
Yin et al., 2021; Zhou et al., 2021). Air pollution in China during
ever, it is worth to mention that these strategies are not effec-
the 21st century accords with the fast-paced urban develop-
tive enough to control near-ground PM2.5 and the secondary
ment and rapid economic growth (Zhou et al., 2021). Owing to
pollution problem marked by excessive O3 due to their com-
significant population and clustered industrial sectors, which
plex pollution sources (Dai et al., 2021; Li et al., 2019a; Qin et al.,
enhance fossil fuel combustion by vehicular transport and in-
2021). Therefore, this needs to be studied further by analysing
dustrial activities, urban areas are more prone to experience
O3 sensitivity to its precursors, to come up with efficient policy
high pollution levels and deteriorated air quality (Tian et al.,
towards controlling O3 pollution in China. The other main pol-
2018).
lution issue currently in China is a phenomenon in which high
In wake of the severity of the atmospheric pollution prob-
O3 and high PM2.5 coincided beyond the National Ambient Air
lem, China had started air quality monitoring network in 2013
Quality Standards (NAAQS) (Dai et al., 2021; Qin et al., 2021).
with monitoring stations all across the country. The measure-
This condition is termed as a complex pollution in this study
ments taken at these monitoring stations have been used to
here-after, where the daily mean PM2.5 concentration exceeds
analyze the characteristics of different air pollution episodes
35 μg/m3 , and the daily mean O3 concentration exceeds 160
in various regions of China (Qin et al., 2021; Sulaymon et al.,
μg/m3 on the same day.
2021; Rupakheti et al., 2021; Li et al., 2020a). For the past
The oxides of nitrogen (NOx) and volatile organic com-
few decades, the use of remote sensing techniques to mon-
pounds (VOCs) are the major precursors for O3 formation. NO2
itor air quality has also got huge attention. Remote sensing
constitutes a major portion of NOx and is, therefore, used for
techniques include both ground and satellite-based instru-
O3 sensitivity studies. It is a crucial atmospheric pollutant
ments to carry out three dimensional (3-D) observations of
coming from anthropogenic sources mainly fossil fuel com-
the atmosphere. The Multi Axis Differential Optical Absorp-
bustion (Vinken et al., 2014) and plays a key role in tropo-
tion Spectroscopy (MAX-DOAS) is one of the remote sensing
spheric O3 formation as well as the generation of hydroxyl
techniques that is used to monitor trace gases and aerosol
(OH) radicals (Cheng et al., 2019b). The OH radicals play an
pollutants in the atmosphere by employing Beer-Lambert law
important role in the atmospheric chemical processes espe-
(Wagner et al., 2011; Platt and Stutz, 2008; Hönninger et al.,
cially contributing the formation of secondary aerosols and
2004; Bobrowski et al., 2003). Owing to relatively low opera-
nitric acid (Huang et al., 2014; Zhao et al., 2018), making it a
tional cost and easy installation, the MAX-DOAS instrument is
critical reduction target for the policymakers. Formaldehyde
widely being used to monitor atmospheric species for ground-
(HCHO) is the most abundant aldehyde in the atmosphere
based, satellite based, ship-based, vehicle-mounted and air-
which comes as an oxidation product of VOCs in the atmo-
borne observation platforms (Zhou et al., 2021).
sphere, thereby serving as an ideal proxy for VOCs (Javed et al.,
The Ministry of the Environmental Protection of the Peo-
2019a; Tanvir et al., 2021). Upon photolysis, this gas gener-
ple’s Republic of China classified nitrogen dioxide (NO2 ) and
ates HO2 free radicals which then react with NO to generate
sulfur dioxide (SO2 ) as criteria pollutants along with ozone
OH radicals, thereby playing an important role in defining at-
(O3 ), particulate matter (PM: PM10 , diameter ≤ 10 μm; and
mospheric chemistry (Tian et al., 2018). The ratio of HCHO to
658 journal of environmental sciences 135 (2024) 656–668

NO2 (RFN) is a common method employed to study the sen- northeast. The climate is characterized by hot and rainy sum-
sitivity of O3 to its precursor species. Nonetheless, in case of mer, shorter and humid spring, and a dry and cold winter.
higher primary emissions of HCHO (>50%), the corresponding The MAX-DOAS instrument was mounted at (36°55 –38°10 N,
ratio of HCHO/NO2 is likely to be overestimated, thereby mis- 118°07 –119°10 E) in Dongying. The site selected for the exper-
diagnosing numerous VOC-limited scenarios as NOx-limited iment was located near the Yellow River estuary at the Yel-
(Xue et al., 2022). Hence, the accurate analysis of O3 -NOx- low River Delta Coastal Wetland Ecological experiment sta-
VOC sensitivity can more arguably be possible with secondary tion. This site is around 50 km away from urban Dongying near
HCHO. Considering the aforementioned scenario of O3 pollu- S228 provincial highway with reed as the dominant vegeta-
tion in China, the study of O3 sensitivity based on secondary tion.
HCHO is crucial, in different regions of China with discrete cli-
matic characteristics.
The atmospheric quality in China has been extensively
1.2. MAX-DOAS instrument
studied using the MAX-DOAS instrument over various cities
of China located in different regions including Beijing-Tianjin-
The observations of several trace gases are carried out us-
Hebei region (Jing–Jin–Ji (JJJ) in Chinese) (Zhang et al., 2016),
ing the MAX-DOAS (Multi-AXis DOAS) instrument which is
Pearl River Delta (PRD) region (Ding et al., 2017), and Yangtze
based on Differential Optical Absorption Spectroscopy (DOAS)
Rivere Delta (YRD) region (Javed et al., 2021). Despite being
technique which mainly consists of a spectrometer (Avaspec-
economically crucial, there exist sparse studies on air pollu-
UL2048L-USB2) with spectral range between 300–460 nm and
tion in Shandong Province. Using the data from the Depart-
resolution of 0.6 nm. Scattered sunlight is used as principal
ment of Ecological Environment of Shandong Province from
source of light by the instrument while the spectral observa-
2013 to 2019, Zhao et al. (2021) reported trends in the con-
tions to retrieve information about the species of concern are
centrations of air pollutants along with the impact of meteo-
made at various viewing angles (Plane and Saiz-Lopez, 2007).
rology. Zhong et al. (2022) studied the inter-annual variations
A built-in processor mechanically controls the everyday mea-
of six criteria pollutants over Shandong province by employ-
surements made by the MAX-DOAS.
ing data from the National Air Quality Monitoring Network
(NAQMN) from 2014 to 2018. Xing et al. (2022) reported the air
quality over Shandong province before and after the COVID-
19 using satellite observations. Some studies have been re- 1.3. DOAS analysis
ported over different cities of Shandong Province including
Jinan (Cui et al., 2020; Zhang et al., 2017a), Weifang (Li et al., Accurate tropospheric columns of trace gas species are re-
2019b), and Qingdao (Li et al., 2017). However, there is no re- trieved using the MAX-DOAS instruments which are capable
ported study on O3 sensitivity to its precursors and status of of performing measurements at various elevation viewing an-
complex air pollution episodes in Shandong. gles called as EVAs (1°, 2°, 3°, 4°, 5°, 6°, 8°, 10°, 15°, 30°, and
The current study uses MAX-DOAS observations and in- 90°). The technique reduces the contributions of the strato-
situ measurements of trace gases and particulate matter dur- sphere to the tropospheric measurements by employing the
ing March-April 2018 and September-October 2019 in Dongy- zenith angle as reference. The obtained spectra were analysed
ing, Shandong. The two different time periods i.e. March- via QDOAS software (version 2.109.4) established by BIRA-IASB
April 2018 and September-October 2019 were used to examine (Danckaert et al., 2013; Javed et al., 2019b). In order to come up
the variation in trace gases, particulate matter and pollution with the finest possible retrieval settings for the concerned
episodes during different seasons. The economy of the city species, several sensitivity tests were performed. Table 1 de-
thrives on crucial oil exploration activities which is why air scribes the retrieval settings used for the current analysis
quality monitoring of the city is highly important. The main incorporating the best suited wavelength window and the
objective of this study is to report current status of air pollu- absorption cross-sections for fitting algorithm. Furthermore,
tion and occurrence of complex pollution episodes and iden- high-resolution solar spectrum was utilized to calibrate wave-
tification of ozone sensitivity based on secondary HCHO. This length (Chance and Kurucz, 2010). The spectra were adjusted
study is unique and vital due to different prospects to the best for offset and dark current before performing the spectral
of author’s knowledge 1) it is first study to report O3 sensitivity analysis.
to its precursors in Shandong province 2) secondary HCHO is For each scanning series, the spectral fitting at various
utilized to identify ozone sensitivity instead of primary HCHO viewing angles was ensured by selecting Fraunhofer reference
3) it is first study to report complex air pollution episodes in at 90°. Thus, differential slant column densities (dSCDs) are
Dongying city. obtained as an outcome. Owing to the scattering processes in
the atmosphere, the quality of data is likely to be impacted. In
order to minimize the contribution of atmospheric scattering
1. Methodology processes and improve the data quality, the measurements at
solar zenith angle (SZA) higher than 75° and root mean square
1.1. Description of the study area (RMS) more than 0.004 were filtered out. The spectral DOAS fit
for HCHO, SO2 and NO2 at elevation angle 2° is shown in Fig.
Dongying city lies on the northern side of Shandong province S2. Differential air mass factors (DAMFs) were utilized for the
in China (Fig. S1). The area has a terrain which inclines in calculation of tropospheric vertical column density (VCDtrop )
the direction of the Yellow River from the southwest to the (Wagner et al., 2010; Solomon et al., 1987).
 journal of environmental sciences 135 (2024) 656–668 659

Table 1 – Retrieval settings for the analysis of SO2 , NO2 , and HCHO.

Cross-sections Data source Trace gases

SO2 NO2 HCHO

√ √
HCHO 297 K, (Meller and Moortgat, 2000) X
√ √ √
NO2 220 K, (Vandaele et al., 1998)
√ √
SO2 298 K, (Vandaele et al., 1998) X
√ √ √
O3 243 K, (Fleischmann et al., 2004)
√ √ √
O3 223 K, (Serdyuchenko et al., 2014)
√ √
O4 293 K, (Thalman and Volkamer, 2013) X
√ √ √
BrO 223 K, (Fleischmann et al., 2004)
√ √ √
Ring Calculated with QDOAS
Polynomial degree 5 5 5

The vertical column densities (VCDs) are calculated from regression model, given by Eq. (8).
the dSCDs of trace gases using dAMFs (Liu et al., 2016).
[HCHO] = α0 + α1 [CO] + α2 [Ox ] (8)
dSCDα
VCDtrop = (1)
dAMFα where, α 0 , α 1 , and α 2 denote fitting coefficients of the model, α 0
represents the background HCHO. The background levels can-
where, α denotes the elevation angle used for making the cor-
not be enumerated into either primary or secondary sources
responding observation, dAMF is calculated as:
of emission. The [HCHO] shows level of HCHO, [CO] represents
concentration of CO, and [Ox ] depicts Ox concentration. The
dAMF = AMFα − AMF90◦ (2)
relative contribution of primary, secondary, and background
HCHO to the ambient HCHO can be computed by employing
dSCDα the following equations.
VCDtrop = (3)
AMFα − AMF90◦
Geometric approximation is used to calculate AMF HCHO primary = α1 (CO )/HCHO × 100% (9)
(Tan et al., 2018):

1 HCHOSecondary = α2 (Ox )/HCHO × 100% (10)

AMF = (4)
Sin (α)

Eq. (3) now implies: HCHObackground = α0 /HCHO × 100% (11)

where, HCHOprimary , HCHOSecondary and HCHObackground signify

dSCDα
VCDtrop = (5) the contributions of primary, secondary, and background
1
Sin(α)
−1 HCHO, respectively.
A simplified equation was employed to convert HCHO
1.4. Error estimation DSCDs to ground surface mixing ratios of HCHO (ppbv). Ma-
jority of the previously published literature over China reports
For the MAX-DOAS observations, the error is estimated by con- that HCHO in the atmosphere is mostly concentrated in the
sidering DOAS fitting error. lower atmosphere (i.e., below 1km) (Chan et al., 2019). Hence,
Eq. (6) represents the fitting error of the DOAS to the ob- the mixing ratios are calculated here by using the following
served VCDs: Eq. (12).

VCDerror 1.25 × DSCD mol/cm2 )
VCD f itt ing error = (6) Rppbv = (12)
VCD a × P
here, R denotes mixing ratio for HCHO, a is termed as the
√    
2 dSDs2α=90◦ + dSDs2α=90◦ unit conversion factor of DU to mol /cm2 and is equal to
=   (7)
2.688 × 1016 , DSCD represents HCHO VCDs, while p denotes
2 Sin1(α) − 1 × VCD
the difference in pressure between the surface and at 1 km
For our study, the hourly error means around 15% for (Ziemke et al., 2001).
HCHO, 12% for NO2 and 17% for SO2 .
1.6. Ancillary data
1.5. Linear regression model
In situ measurements for the criteria pollutants including
By employing CO and Ox (NO2 + O3 ) as tracers, primary NO2 , SO2 , CO, O3 , PM10 and PM2.5 were attained from national
and secondary ground-surface sources HCHO can be distin- online database for air quality analysis and monitoring plat-
guished. The sources of HCHO can be enumerated by linear form (http://www.cnemc.cn/). The data is available online and
660 journal of environmental sciences 135 (2024) 656–668

Fig. 1 – Time series of MAX-DOAS observed VCDs for (a) SO2 , (b) HCHO, and (c) NO2 at elevation angle 2° at Dongying during
March-April 2018 and September- October 2019.

the monitoring stations are managed by China National En- evident from the figure, the study period has been split to
vironmental Monitoring Center. The daily mean concentra- two distinct time periods for March-April 2018 and October-
tion of these measurements spanning from 01st March- 30th November 2019. During 2018, the observation period lays in
April 2018 and 1st September 2019-30th October 2019 was used the spring while for 2019, the observations were made during
in this study. ERA5 reanalysis data for meteorological param- autumn. The minimum, maximum and mean SO2 VCDs re-
eters (relative humidity, temperature, wind speed and wind mained to be 1.28×1016 mols/cm2 , 5.54 ×1016 mol/cm2 , and
direction) over Dongying were obtained from the Copernicus 2.89 ×1016 mol/cm2 respectively during March-April 2018,
Data Hub (available online: https://cds.climate.copernicus.eu, while 1.67×1015 mol/cm2 , 4.32×1016 mol/cm2 , and 1.68×1016
last accessed on 14 October 2021). The time series of temper- mol/cm2 respectively for September-October 2019. For HCHO,
ature, relative humidity, wind speed and wind direction over the minimum, maximum and mean VCDs was found to
Dongying for observation period are shown in Fig. S3. The tem- be 2.28×1016 mol/cm2 , 4.61×1016 mol/cm2 , and 3.57×1016
perature, relative humidity and wind speed ranges from 1°C mol/cm2 respectively during 2018, while 1.78×1016 mol/cm2 ,
- 24°C, 24%-90%, 1–7 m/sec respectively during March-April 7.85×1016 mols/cm2 , and 2.99×1016 mol/cm2 respectively dur-
2018. Whereas during September – October 2019 temperature, ing 2019. The NO2 vertical columns over the observation site
relative humidity and wind speed ranges from 7°C-27°C, 37%- depicted minimum, maximum and mean values of 2.42×1016
97%, 2–17 m/sec. mol/cm2 , 6.95×1016 mols/cm2 , and 3.38×1016 mol/cm2 respec-
tively for 2018, and 1.75×1015 mol/cm2 , 8.48×1016 mol/cm2 ,
and 3.65×1016 mol/cm2 respectively for 2019. It is notewor-
thy that the mean concentrations of all the observed species
2. Results and discussions
during 2018 and 2019 remained to be almost identical de-
spite the fact the observations were made in different sea-
2.1. Timeseries for MAX-DOAS and In-situ observations
sons. It has already been established in literature that the con-
centrations of these trace gas species remain almost iden-
The time series of (a) SO2 , (b) HCHO, and (c) NO2 for the
tical during spring and autumn which can be attributed to
study period over the studied site are shown in Fig. 1. As
 journal of environmental sciences 135 (2024) 656–668 661

Fig. 2 – Time-series of In-situ Measurements in Dongying where dashed lines indicate NAAQS Grade 1 standard and dotted
lines indicate Grade 2 standard.

the identical sources of emissions during these two sea- overall reduction in SO2 levels can be linked to the strong and
sons (Xue et al., 2022; Hong et al., 2022; Rupakheti et al., effective measures taken to reduce the SO2 level. The previous
2021), for instance, biogenic emissions in case of HCHO studies reported a decrease in industrial SO2 emissions fol-
(Chan et al., 2019). lowing the widespread installation of fuel gas desulfurization
The in-situ measurements of particulate matter and trace (FGD) devices in China (Li et al., 2020a; Rupakheti et al., 2021;
gases from the national environment monitoring station Zhang et al., 2017b). The daily mean NO2 concentrations did
taken at observation site are depicted by the time series in not exceed from the prescribed standards. The daily mean O3
Fig. 2. The mean concentrations of SO2 , NO2 , O3 , PM2.5 , PM10 , concentrations exceeded the China National Air Quality Stan-
and CO in Dongying as a whole ranged from 6 to 39 μg/m3 , 8 dard Grade 1 on about 63% and 67% of the observation days
to 73 μg/m3 , 61-232 μg/m3 , 12-149 μg/m3 , 36-223 μg/m3 , and during 2018 and 2019. The previous studies also reported that
0.3-1.4 mg/m3 respectively during March-April 2018, and 3 to concentration of particulate matter and trace gases in differ-
34 μg/m3 , 8 to 88 μg/m3 , 53-256 μg/m3 , 2-121 μg/m3 and 34- ent pars of China exceeded the WHO guidelines and China Na-
191 μg/m3 0.2-1.3 mg/m3 during October-November 2019. The tional Air Quality Standards (Li et al., 2020a; Rupakheti et al.,
overall range of trace gases and particulate matter is consis- 2021).
tent with the mean values of these trace gases and partic- The relationship between in-situ measurements and MAX-
ulate matter in 2018 and 2019 reported in Harbin, Xinjiang, DOAS observations for NO2 and SO2 is shown in Fig. 3. It is evi-
Yangtze River Delta region (Li et al., 2020a; Qin et al., 2021; dent that both the observations are in good agreement depict-
Sulaymon et al., 2021; Rupakheti et al., 2021). ing a correlation coefficient (R2 ) of 0.60 and 0.61 for NO2 and
Table 2 represents China National Air Quality Standards for SO2 respectively at 0.05 significant level (2-tailed), thereby af-
various criteria pollutants. The daily mean PM2.5 concentra- firming the validity of the observations made by MAX-DOAS
tions exceeded the China National Air Quality Standard Grade instrument. It is worth to mention that as MAX-DOAS obser-
1 on about 68% and 48% of the observation days during 2018 vations are made during sunlight. Therefore, the data of same
and 2019. For PM10 , the concentration exceeded about on 92% time period was used to investigate the relationship between
and 62% days for 2018 and 2019 respectively for Grade 1 China the in-situ measurements and MAX-DOAS observations
National Air Quality standards. The daily mean SO2 concen- Despite the inability of MAX-DOAS instrument to detect
trations did not exceed from the prescribed standards. The atmospheric species near the ground, the retrieval of trace
662 journal of environmental sciences 135 (2024) 656–668

Table 2 – Comparison of the mean concentration of different pollutants with the available guidelines/standards.

Parameters China This study (mean)

Grade 1 Grade 2 (March-April 2018) (Sept.-Oct. 2019)

PM10 50 150 118 83

PM2.5 35 75 54 40
SO2 50 150 22 12
NO2 80 80 32 37
O3 100 160 124 133

Fig. 3 – Correlation between MAX-DOAS observed VCDs of a) NO2 and b) SO2 with the in-situ measurements.

gas species at lower level provides with a reliable and robust 2021; Yue et al., 2017). It is evident from literature that com-
measurements of surface concentrations and trends of atmo- plex pollution episodes mostly occur during spring and au-
spheric species. The concentrations of trace gas species in- tumn seasons (Qin et al., 2021). Table 3 shows the mean values
cluding NO2 and SO2 are normally concentrated in the lower of trace gases, particulate matter and meteorological parame-
atmosphere, usually below 300 m, the concentrations can be ters during two different complex pollution episodes. The typ-
found consistent with the VCDs. Therefore, the influence of ical values of temperature, relative humidity and wind speed
near surface emissions on air pollution can be discussed us- ranges from 14-28◦ C, 53%-79% and 1.5-5.3 m/s respectively.
ing VCDs (Hong et al., 2019). The study conducted in southern China reported that dur-
ing summer days when air temperature is high, the corre-
2.2. Complex pollution episodes lation between PM2.5 and O3 was found strongly positive.
The other studies also reported that complex pollution of
The higher concentrations of O3 and PM2.5 have adversative PM2.5 and O3 was observed during days with relatively higher
effects on community health and the environment (Yue et al., temperature, relatively high RH, and lower wind speed. Ele-
2017). The complex pollution episode is basically the co- vated temperature promotes O3 as well as sulfate formation
occurrence of both PM2.5 and MDA8 O3 at higher levels. The (Liao et al., 2009), higher RH favor the hygroscopic develop-
complex pollution days in this study refer to the pollution ment of PM2.5 and its corresponding constituents (Tie et al.,
conditions where the daily mean PM2.5 concentration exceeds 2017), and dilution of pollutants in the atmosphere is dis-
35 μg/m3 , and the daily mean O3 concentration exceeds 160 couraged by lower wind speed. Lv et al. 2021 reported that
μg/m3 on the same day. The results depict that 20% of the higher complex pollution hours (co-occurrence of both PM2.5
observation days in 2018 are identified as complex pollution and MDA8 O3 at higher levels) were observed in Shanghai a
days, while during 2019, 21% of the observation days are found coastal city as compared to other in land cities e.g., Hefei,
to be complex polluted days. The previous studies also re- which is likely because the sea-land breeze convergences
ported the occurrence of the complex pollution episodes in cause accretion of hourly O3 and PM2.5 in coastal areas. The
different regions of China recently (Lv et al., 2021; Qin et al., current study also reported frequent occurrence of complex
 journal of environmental sciences 135 (2024) 656–668 663

Table 3 – Comparison of the mean (standard deviation) concentration of different pollutants and meteorological parameters
during two complex pollution episodes.

Parameter (mean) Case 1 (23-28 March 2018) Case 2 (6-9 September 2019)
3
PM2.5 (μg/m ) 93(24) 53(9)
NO2 (μg/m3 ) 54(17) 25(8)
O3 (μg/m3 ) 159(24) 224(26)
SO2 (μg/m3 ) 30(5) 11(0.8)
PM10 (μg/m3 ) 173(18) 100(14)
CO (mg/m3 ) 1(0.1) 1(0.1)
Temp (◦ C) 18(3) 26(1)
RH (%) 58(8) 66(2)
Wind speed (m/s) 3(1) 5(2)

pollution episodes during March-April 2018 and September- ever, Tan et al. (2018) found O3 concentrations in ECS and YRE
October 2019 in Dongying, a coastal city of Shandong province. to be NOx limited attributed to ship emissions. A difference
The atmospheric oxidation capacity Ox (O3 + NO2 ) for com- of 11.40% and 10% during March-April 2018 and September-
plex pollution days is compared with other days of the ob- October 2019 respectively in O3 sensitivity was found between
servation. The results are indicative that higher oxidation ca- HCHOtotal /NO2 and HCHOsec / NO2 . The results are indication
pacity is observed during complex pollution days. The higher that primary HCHO have significant contribution in HCHO.
oxidation capacity can increase the rate of formation of sec- Therefore, the study of O3 sensitivity based on secondary
ondary pollutants. The similar results were reported in previ- HCHO is crucial. A diurnal shift in O3 sensitivity was observed
ous studies (Lv et al., 2021). from VOC-limited during the morning hours to VOC-NOx lim-
ited in the afternoon. The previous studies also reported in-
crease in O3 concentration during noon time while the O3 sen-
2.3. Ozone formation sensitivity
sitivity correspondingly shifted from VOC-limited to VOC-NOx
limited.
O3 formation in the atmosphere can be broadly categorized
into three distinct regimes: a) VOC-limited where VOC con-
centration determines O3 concentration, b) NOx limited where 2.4. Diurnal variations
the concentrations of NOx limit O3 formation, and c) transi-
tion regime where both VOCs and NOx play a role towards O3 The variation in pollutant concentrations through the day
formation (Hong et al., 2022). HCHO is the most abundant VOC varies significantly depicting a peculiar diurnal trend specific
and NO2 constitutes major portion of NOx. Therefore, the ra- to each pollutant. This is because of the variability in emission
tio of HCHO/NO2 (RFN) has been employed by various stud- sources at different parts of the day as well as meteorological
ies to assess the O3 -NOx-VOC sensitivity (Hong et al., 2022; parameters including solar radiation and other meteorologi-
Xue et al., 2022; Zhang et al., 2021) where RFN less than 1 cal parameters (Wang et al., 2013). The mean diurnal varia-
corresponds to VOC–limited regime, RFN more than 2 char- tions in the concentrations of species as observed by MAX-
acterizes NOx–limited regime, while an RFN value between DOAS instrument during March-April 2018 and September-
1 and 2 corresponds to transition regimes (Duncan et al., October 2019 are shown in the Fig. 5. The trend depicts that
2010). Fig. 4 shows the daily mean RFN based on secondary NO2 concentration was higher during the morning hours at-
HCHO for Dongying. During March-April 2018, O3 formation tributed to low solar intensity and more anthropogenic activ-
predominantly remained to be VOC-limited (52%) followed ity especially vehicle influx during the morning (Wang et al.,
by transitional (33%) and NOx-limited (15%) regimes. Dur- 2014; Kumar et al., 2015) and began to decline during the
ing September-October 2019, no contribution of NOx was ob- day. This drop is linked to the increase in solar intensity
served towards O3 formation in Dongying while both VOC- during the day which enhances photolytic reactions that act
limited and transitional regime had significant contribution of as major sinks (Kumar et al., 2015). The concentration be-
55% and 45% respectively. These results imply that concurrent gins to rise in the afternoon owing to the influx of traffic
control of both NOx and VOCs would benefit in ozone reduc- during evening rush hours. Similar diurnal trend has been
tions. observed for SO2 which has sources and sinks similar to
Various studies conducted using MAX-DOAS observations that of NO2 . Additionally, higher concentrations of pollutants
for O3 -NOx-VOCs sensitivity have been reported over differ- during the morning and evening hours might be related to
ent parts of China in different seasons and are summarized lower PBL during these hours, whereas, the PBL is raised
in Table 4. Our results are consistent with the studies con- during the day time which allows for more diffusion and
ducted over these regions. Near surface O3 sensitivity pre- thereby reduced concentrations in lower level (Pancholi et al.,
dominantly remained to be in VOC-limited regime for all the 2018). HCHO depicts opposite diurnal trend implying the sec-
seasons. Luo et al. (2020) classified the observation period ondary sources of formation especially by the oxidation of
into clear and polluted days, reporting mixed sensitivity sce- VOCs during the daytime (Gratsea et al., 2016; Chan et al.,
nario on clear days and VOC-limited in polluted days. How- 2019), thereby depicting a higher concentration during the
664 journal of environmental sciences 135 (2024) 656–668

Fig. 4 – Daily averaged RFN based on secondary HCHO showing O3 sensitivity to its precursors during March-April 2018 and
September- October 2019.

Table 4 – Overview of O3 -NOX -VOCs sensitivity over different regions of China.

Reference Study Location Study Period Study Season Study Findings

Chi et al., 2018 University of Chinese October 26 - November Autumn VOC-limited up to 700m,
Academy of Sciences, 6, 2014 Transitional from 700m to
Beijing 1km
Tan et al. (2018) East China Sea (ECS) and June 2 - 29, 2017 Summer NOx-limited
Yangtze River Estuary (YRE),
Shanghai
Zeng et al. (2018) Wuhan August 1 - 31, 2016 Summer VOC-limited
He et al. (2019) Heshan, Guangzhou October 22 - November Autumn VOC-limited
20, 2014
Luo et al. (2020) Jinan University Site, September 20 - Autumn Transitional under clear
Guangzhou November 20, 2018 conditions, VOC-limited on
polluted days
Zhang et al. (2021) Dianshan Lake, Qingpu October 17 - November Autumn VOC-limited within the
District, Shanghai 20, 2019 boundary layer
Hong et al. (2022) Guangzhou institute of July- September, 2019 Summer/Wet Season VOC-limited near surface,
Geochemistry, Chinese transitional between 0.4 -
Academy of Sciences 1.6km, VOC-limited above
1.6km
Xue et al. (2022) Liaoning University, January - November, Almost Year round VOC-limited
Shenyang 2019

day while lower concentrations during morning and evening PM2.5 , PM10 , NO2 , SO2 , O3 , and CO the daily mean concen-
hours. trations of these atmospheric species from the in-situ mea-
surements were utilized. The analysis was performed using
2.5. Correlation among criteria pollutants and pairwise pearson’s correlation coefficient over the study area
meteorological parameters and has been given in Fig. 6. During both the studied peri-
ods (March-April, 2018 and September-October 2019) PM2.5 de-
In order to study the correlation among the daily mean picted strongly positive correlation with PM10 , NO2 , and CO,
meteorological parameters and criteria pollutants including whereas for SO2 the correlation is strong for 2018 and mod-
 journal of environmental sciences 135 (2024) 656–668 665

Fig. 5 – Diurnal cycle of a) HCHO, b) NO2 and c) SO2 at elevation angle 2°.

Fig. 6 – Pearson Correlation between daily mean concentration of trace gases, particulate matter and meteorological
parameters (temperature and relative Humidity).

erate during 2019. With O3 , PM2.5 depicted weak correlation served during 2019 especially with NO2 . Strong correlations
for both the periods. The correlation between other species among the pollutants indicate similar sources of emission for
were also found to be strong for both the studied periods ex- the pollutant species which may include the emissions from
cept for O3 which depicted moderate correlation with PM10 , automobiles and burning of fossil fuel. Our results are con-
SO2 , and NO2 during 2018 while weak correlation was ob- sistent with the studies reported earlier (e.g., Sulaymon et al.,
666 journal of environmental sciences 135 (2024) 656–668

2021). It is worth mentioning here that the positive correla- all species had weak correlation with O3 confirming that the
tion of PM2.5 observed with NO2 and SO2 is majorly accred- formation of O3 is linked to VOCs.
ited to huge traffic emissions and power plants that utilize
coal as a major source of fuel (Zhang et al., 2020). Further, the
positive correlation of PM with major primary gaseous pollu- Declaration of competing interest
tants (SO2 and NO2 ) might arguably be because these species
act as precursor for PM formation, especially sulfate and ni- The authors declare that they have no known competing fi-
trate components (Li et al., 2021). The relatively weaker cor- nancial interests or personal relationships that could have ap-
relation of O3 with other species reinforce that O3 formation peared to influence the work reported in this paper.
over the studied area is mostly VOC-limited. These results
reaffirm the previously reported conclusions (Sulaymon et al.,
2021). The results shown moderate positive correlation of tem- Acknowledgments
perature with particulate matter in spring 2018 while dur-
ing autumn 2019 temperature shows weak positive correla- This study was supported by the Jiangsu Funding Program
tion with particulate matter. The temperature shows moder- for Excellent Postdoctoral Talent (Grant No. 2022ZB651), the
ate positive correlation with NO2 , SO2 and CO during spring National Natural Science Foundation of China (Grant No.
2018, while in autumn 2019 temperature shows weak cor- 32071521), the Scientific Research Foundation for Senior Tal-
relation with NO2 and SO2 . However, O3 shows strong posi- ent of Jiangsu University, China (Grant No. 20JDG067), the
tive correlation with temperature during spring 2018 and au- Jiangsu Province “Double Innovation PhD” Grant.
tumn 2019. The rate of formation of O3 is higher when tem-
perature increases, as photolytic activity is increased which
helps in the formation of secondary pollutant O3 (Chen et al., Supplementary materials
2019; Li et al., 2020b). The relative humidity shows weak
to moderate negative correlation with particulate matter Supplementary material associated with this article can be
and different trace gases during spring 2018 and autumn found, in the online version, at doi:10.1016/j.jes.2022.09.014.
2019.
references

3. Conclusion
Bobrowski, N., Hönninger, G., Galle, B., Platt, U., 2003. Detection of
bromine monoxide in a volcanic plume. Nature 423 (6937),
This study was conducted over the city of Dongying in Shan- 273–276. https://www.nature.com/articles/nature01625.
dong Province of China. MAX-DOAS and in-situ observations Chan, K.L., Wang, Z., Ding, A., Heue, K.P., Shen, Y., Wang, J., et al.,
were used to monitor air quality of the city for two distinct 2019. MAX-DOAS measurements of tropospheric NO2 and
time periods, i.e., 9th March 2018 to 25th April 2018 and 1st HCHO in Nanjing and a comparison to ozone monitoring
instrument observations. Atmos. Chem. Phys. 19 (15),
September to 30th October 2019. It is worth mentioning here
10051–10071. doi:10.5194/acp- 19- 10051- 2019.
that mean concentrations for NO2 and SO2 remained signifi-
Chance, K., Kurucz, R.L., 2010. An improved high-resolution solar
cantly below the acceptable national and international stan- reference spectrum for earth’s atmosphere measurements in
dards. However, both PM2.5 , and PM10 were observed to be the ultraviolet, visible, and near infrared. J. Quant. Spectrosc.
higher than the prescribed safe levels. The correlation coef- Radiat. Transfer 111 (9), 1289–1295.
ficient (R2 ) between the MAX-DOAS observations and in-situ doi:10.1016/j.jqsrt.2010.01.036.
measurements for SO2 and NO2 was found to be 0.60 and 0.61 Chen, Z., Zhuang, Y., Xie, X., Chen, D., Cheng, N., Yang, L., et al.,
2019. Understanding long-term variations of meteorological
respectively, indicating that both the observations are in good
influences on ground ozone concentrations in Beijing During
agreement and affirming the validity of MAX-DOAS instru-
2006–2016. Environ. Pollut. 245, 29–37.
ment. RFN indicates that the O3 production over Dongying lies doi:10.1016/j.envpol.2018.10.117.
mostly in the VOC-limited region. The primary HCHO have Cheng, S., Ma, J., Cheng, W., Yan, P., Zhou, H., Zhou, L., Yang, P.,
significant contribution in total HCHO. Therefore, the study 2019a. Tropospheric NO2 vertical column densities retrieved
of O3 sensitivity based on secondary HCHO is crucial. A diur- from ground-based MAX-DOAS measurements at
nal shift in O3 sensitivity was observed from VOC-limited dur- Shangdianzi regional atmospheric background station in
China. J. Environ. Sci. 80, 186–196. doi:10.1016/j.jes.2018.12.012.
ing the morning hours to VOC-NOx limited in the afternoon.
Cheng, Y., Wang, S., Zhu, J., Guo, Y., Zhang, R., Liu, Y., Zhang, Y.,
These results imply that concurrent control of both NOx and Yu, Q., Ma, W., Zhou, B., 2019b. Surveillance of SO2 and NO2
VOCs would benefit in ozone reductions. The diurnal pattern from ship emissions by MAX-DOAS measurements and the
of HCHO showed an increase in concentration from morning implications regarding fuel sulfur content compliance. Atmos.
to noon and a reduction occurred afterward in the evening. Chem. Phys. 19 (21), 13611–13626.
NO2 showed a prominent diurnal cycle peak in morning rush doi:10.5194/acp- 19- 13611- 2019.
Chi, X., Liu, C., Xie, Z., Fan, G., Wang, Y., He, P., et al., 2018.
hour followed by a decline towards noon and then a gradual
Observations of ozone vertical profiles and corresponding
increase during evening. Similar to NO2 , SO2 concentrations
precursors in the low troposphere in Beijing, China. Atmosph.
are higher during morning and evening hours, suggesting sim- Res. 213, 224–235. doi:10.1016/j.atmosres.2018.06.012.
ilar sources of emission. Strong positive correlation was ob- Cui, L., Zhou, J., Peng, X., Ruan, S., Zhang, Y., 2020. Analyses of air
served between PM (PM10 and PM2.5 ), SO2 and NO2 while these pollution control measures and co-benefits in the heavily
 journal of environmental sciences 135 (2024) 656–668 667

air-polluted Jinan city of China, 2013–2017. Sci. Rep. 10 (1), Kumar, K., et al., 2015. Spatial and temporal variability of
1–10. doi:10.1038/s41598- 020- 62475- 0. surface ozone and nitrogen oxides in urban and rural ambient
Dai, H., Zhu, J., Liao, H., Li, J., Liang, M., Yang, Y., et al., 2021. air of Delhi-NCR, India. Air Qual. Atmos. Health 8 (4), 391–399.
Co-occurrence of ozone and PM2.5 pollution in the Yangtze doi:10.1007/s11869- 014- 0309- 0.
River Delta over 2013–2019: spatiotemporal distribution and Li, C., Dai, Z., Yang, L., Ma, Z., 2019b. Spatiotemporal
meteorological conditions. Atmos. Res. 249, 105363. characteristics of air quality across weifang from 2014–2018.
doi:10.1016/j.atmosres.2020.105363. Int. J. Environ. Res. Public Health 16 (17), 3122.
Danckaert, T., Fayt, C., Van Roozendael, M., De Smedt, I., doi:10.3390/ijerph16173122.
Letocart, V., Merlaud, A., et al., 2013. QDOAS Software User Li, L., Yan, D., Xu, S., Huang, M., Wang, X., Xie, S., 2017.
Manual; Belgian Institute for Space Aeronomy: Brussels. Characteristics and source distribution of air pollution in
Belgium. winter in Qingdao, eastern China. Environ. Pollut. 224, 44–53.
Ding, H., Liu, Y., Yu, Z., Cheung, C., Zhan, J., 2017. Spatial and doi:10.1016/j.envpol.2016.12.037.
temporal characteristics and main contributing regions of Li, K., Jacob, D.J., Liao, H., Shen, L., Zhang, Q., Bates, K.H., 2019a.
high PM2. 5 pollution in Hong Kong. Aerosol Air Quality Res. Anthropogenic drivers of 2013–2017 trends in summer surface
17 (12), 2955–2965. doi:10.4209/aaqr.2016.09.0412. ozone in China. Proc. Natl. Acad. Sci. 116 (2), 422–427.
Duncan, B.N., Yoshida, Y., Olson, J.R., Sillman, S., Martin, R.V., doi:10.1073/pnas.1812168116.
Lamsal, L., et al., 2010. Application of OMI observations to a Li, L., Li, Q., Huang, L., Wang, Q., Zhu, A., Xu, J., Liu, Z., Li, H., Shi, L.,
space-based indicator of NOx and VOC controls on surface Li, R., Azari, M., 2020b. Air quality changes during the
ozone formation. Atmos. Environ. 44 (18), 2213–2223. COVID-19 lockdown over the Yangtze River Delta Region: an
doi:10.1016/j.atmosenv.2010.03.010. insight into the impact of human activity pattern changes on
Fleischmann, O.C., Hartmann, M., Burrows, J.P., Orphal, J., 2004. air pollution variation. Sci. Total Environ. 732, 139282.
New ultraviolet absorption cross-sections of BrO at doi:10.1016/j.scitotenv.2020.139282.
atmospheric temperatures measured by time-windowing Li, B., Shi, X.F., Liu, Y.P., Lu, L., Wang, G.L., Thapa, S., Sun, X.Z.,
Fourier transform spectroscopy. J. Photochem. Photobiol. A 168 Fu, D.L., Wang, K., Qi, H., 2020a. Long-term characteristics of
(1-2), 117–132. doi:10.1016/j.jphotochem.2004.03.026. criteria air pollutants in megacities of Harbin-Changchun
Gratsea, M., Vrekoussis, M., Richter, A., Wittrock, F., megalopolis, Northeast China: Spatiotemporal variations,
Schönhardt, A., Burrows, J., et al., 2016. Slant column source analysis, and meteorological effects. Environ. Pollut.
MAX-DOAS measurements of nitrogen dioxide, formaldehyde, 267, 115441. doi:10.1016/j.envpol.2020.115441.
glyoxal and oxygen dimer in the urban environment of Li, X., Xie, P., Li, A., Xu, J., Hu, Z., Ren, H., et al., 2021. Variation
Athens. Atmos. Environ. 135, 118–131. characteristics and transportation of aerosol, NO2, SO2, and
doi:10.1016/j.atmosenv.2016.03.048. HCHO in coastal cities of eastern china: dalian, qingdao, and
He, Z., Wang, X., Ling, Z., Zhao, J., Guo, H., Shao, M., et al., 2019. shanghai. Remote Sens. 13 (5), 892. doi:10.3390/rs13050892.
Contributions of different anthropogenic volatile organic Liao, H., Zhang, Y., Chen, W.T., Raes, F., Seinfeld, J.H., 2009. Effect of
compound sources to ozone formation at a receptor site in the chemistry-aerosol-climate coupling on predictions of future
Pearl River Delta region and its policy implications. Atmos. climate and future levels of tropospheric ozone and aerosols.
Chem. Phys. 19 (13), 8801–8816. doi:10.5194/acp- 19- 8801- 2019. J.Geophys. Res. 114 (D10).
Hong, Q., Liu, C., Hu, Q., Xing, C., Tan, W., Liu, H., et al., 2019. Liu, H., Liu, C., Xie, Z., Li, Y., Huang, X., Wang, S., et al., 2016. A
Evolution of the vertical structure of air pollutants during paradox for air pollution controlling in China revealed by
winter heavy pollution episodes: the role of regional transport “APEC Blue” and “Parade Blue. Sci. Rep. 6 (1), 1–13.
and potential sources. Atmos. Res. 228, 206–222. doi:10.1038/srep34408.
doi:10.1016/j.atmosres.2019.05.016. Luo, Y., Dou, K., Fan, G., Huang, S., Si, F., Zhou, H., et al., 2020.
Hong, Q., Zhu, L., Xing, C., Hu, Q., Lin, H., Zhang, C., et al., 2022. Vertical distributions of tropospheric formaldehyde, nitrogen
Inferring vertical variability and diurnal evolution of O3 dioxide, ozone and aerosol in southern China by
formation sensitivity based on the vertical distribution of ground-based MAX-DOAS and LIDAR measurements during
summertime HCHO and NO2 in Guangzhou. China. Sci. Total PRIDE-GBA 2018 campaign. Atmos. Environ. 226, 117384.
Environ. 827, 154045. doi:10.1016/j.scitotenv.2022.154045. doi:10.1016/j.atmosenv.2020.117384.
Hönninger, G., Von Friedeburg, C., Platt, U., 2004. Multi axis Lv, M., Li, Z., Jiang, Q., Chen, T., Wang, Y., Hu, A., et al., 2021.
differential optical absorption spectroscopy (MAX-DOAS). Contrasting trends of surface PM2.5 , O3 , and NO2 and their
Atmos. Chem. Phys. 4 (1), 231–254. doi:10.5194/acp- 4- 231- 2004. relationships with meteorological parameters in typical
Huang, R., Zhang, Y., Bozzetti, C., Ho, K., Cao, J., Han, Y., et al., 2014. coastal and inland cities in the Yangtze river delta. Int. J.
High secondary aerosol contribution to particulate pollution Environ. Res. Public Health 18 (23), 12471.
during haze events in China. Nature 514 (7521), 218–222. doi:10.3390/ijerph182312471.
doi:10.1038/nature13774. Meller, R., Moortgat, G.K., 2000. Temperature dependence of the
Javed, Z., Liu, C., Khokhar, M., Tan, W., Liu, H., Xing, C., Ji, X., absorption cross sections of formaldehyde between 223 and
Tanvir, A., Hong, Q., Sandhu, O., Rehman, A., 2019a. 323 K in the wavelength range 225–375 nm. J. Geophys. Res.
Ground-Based MAX-DOAS Observations of CHOCHO and 105 (D6), 7089–7101. doi:10.1029/1999JD901074.
HCHO in Beijing and baoding. China. Remote Sens. 11 (13), Pancholi, P., Kumar, A., Bikundia, D.S., Chourasiya, S., 2018. An
1524. doi:10.3390/rs11131524. observation of seasonal and diurnal behavior of O3–NOx
Javed, Z., Liu, C., Khokhar, M.F., Xing, C., Tan, W., Subhani, M.A., relationships and local/regional oxidant (OX= O3+ NO2) levels
Rehman, A., Tanvir, A., 2019b. Investigating the impact of at a semi-arid urban site of western India. Sustain. Environ.
Glyoxal retrieval from MAX-DOAS observations during haze Res. 28 (2), 79–89. doi:10.1016/j.serj.2017.11.001.
and non-haze conditions in Beijing. J. Environ. Sci. 80, 296–305. Plane, J.M., Saiz-Lopez, A., 2007. UV-visible differential optical
doi:10.1016/j.jes.2019.01.008. absorption spectroscopy (DOAS). Anal. Tech. Atmos. Measur.
Javed, Z., Tanvir, A., Wang, Y., Waqas, A., Xie, M., Abbas, A., et al., 147–188. doi:10.1002/9780470988510.ch3.
2021. Quantifying the impacts of COVID-19 lockdown and Platt, U., Stutz, J., 2008. Differential Absorption Spectroscopy:
spring festival on air quality over Yangtze river delta region. Principles and Applications. Springer, Berlin.
Atmosphere 12 (6), 735. doi:10.3390/atmos12060735. Qin, Y., Li, J., Gong, K., Wu, Z., Chen, M., Qin, M., et al., 2021. Double
Kumar, A., Singh, D., Singh, B.P., Singh, M., Anandam, K., high pollution events in the Yangtze River Delta from 2015 to
668 journal of environmental sciences 135 (2024) 656–668

2019: characteristics, trends, and meteorological situations. Wang, Y., Ali, M., Bilal, M., Qiu, Z., Mhawish, A., Almazroui, M.,
Sci. Total Environ., 148349 doi:10.1016/j.scitotenv.2021.148349. et al., 2021. Identification of NO2 and SO2 pollution hotspots
Rupakheti, D., Yin, X., Rupakheti, M., Zhang, Q., Li, P., Rai, M., et al., and sources in Jiangsu Province of China. Remote Sens. 13
2021. Spatiotemporal characteristics of air pollutants over (18), 3742. doi:10.3390/rs13183742.
Xinjiang, northwestern China. Environ. Pollut. 268, 115907. Xing, H., Zhu, L., Chen, B., Niu, J., Li, X., Feng, Y., et al., 2022. Spatial
doi:10.1016/j.envpol.2020.115907. and temporal changes analysis of air quality before and after
Solomon, S., Schmeltekopf, A.L., Sanders, R.W., 1987. On the the COVID-19 in Shandong province, China. Earth Sci. Inf.
interpretation of zenith sky absorption measurements. J. doi:10.1007/s12145- 021- 00739- 7.
Geophys. Res. 92 (D7), 8311–8319. Xue, J., Zhao, T., Luo, Y., Miao, C., Su, P., Liu, F., et al., 2022.
doi:10.1029/JD092iD07p08311. Identification of ozone sensitivity for NO2 and secondary
Sulaymon, I.D., Zhang, Y., Hopke, P.K., Hu, J., Rupakheti, D., Xie, X., HCHO based on MAX-DOAS measurements in northeast
et al., 2021. Influence of transboundary air pollution and China. Environ. Int. 160, 107048.
meteorology on air quality in three major cities of Anhui doi:10.1016/j.envint.2021.107048.
Province, China. J. Cleaner Prod. 329, 129641. Yin, H., Liu, C., Hu, Q., Liu, T., Wang, S., Gao, M., et al., 2021.
doi:10.1016/j.jclepro.2021.129641. Opposite impact of emission reduction during the COVID-19
Serdyuchenko, A., Gorshelev, V., Weber, M., Chehade, W., lockdown period on the surface concentrations of PM2.5 and
Burrows, J.P., 2014. High spectral resolution ozone absorption O3 in Wuhan, China. Environ. Poll. 289, 117899.
cross-sections–Part 2: temperature dependence. Atmos. Meas. doi:10.1016/j.envpol.2021.117899.
Tech. 7 (2), 625–636. Yue, X., Unger, N., Harper, K., Xia, X., Liao, H., Zhu, T., et al., 2017.
Tan, W., Liu, C., Wang, S., Xing, C., Su, W., Zhang, C., et al., 2018. Ozone and haze pollution weakens net primary productivity
Tropospheric NO 2, SO 2, and HCHO over the East China Sea, in China. Atmos. Chem. Phys. 17 (9), 6073–6089.
using ship-based MAX-DOAS observations and comparison doi:10.5194/acp- 17- 6073- 2017.
with OMI and OMPS satellite data. Atmos. Chem. Phys. 18 (20), Zeng, P., Lyu, X.P., Guo, H., Cheng, H.R., Jiang, F., Pan, 2018. Causes
15387–15402. doi:10.5194/acp- 18- 15387- 2018. of ozone pollution in summer in Wuhan, Central China.
Tanvir, A., Javed, Z., Jian, Z., Zhang, S., Bilal, M., Xue, R., et al., 2021. Environ. Poll. 241, 852–861. doi:10.1016/j.envpol.2018.05.042.
Ground-Based MAX-DOAS observations of tropospheric NO2 Zhang, L., Lee, C.S., Zhang, R., Chen, L., 2017b. Spatial and
and HCHO during COVID-19 lockdown and spring festival over temporal evaluation of long-term trend (2005–2014) of OMI
shanghai, China. Remote Sens. 13 (3), 488. retrieved NO2 and SO2 concentrations in Henan Province,
doi:10.3390/rs13030488. China. Atmos. Environ. 154, 151–166.
Thalman, R., Volkamer, R., 2013. Temperature dependent doi:10.1016/j.atmosenv.2016.11.067.
absorption cross-sections of O 2–O 2 collision pairs between Zhang, K., Li, L., Huang, L., Wang, Y., Huo, J., Duan, Y., 2020. The
340 and 630 nm and at atmospherically relevant pressure. impact of volatile organic compounds on ozone formation in
Phys. Chem. Chem. Phys. 15 (37), 15371–15381. the suburban area of Shanghai. Atmos. Environ. 232.
doi:10.1039/C3CP50968K. doi:10.1016/j.atmosenv.2020.117511, Article 117511.
Tian, X., Xie, P., Xu, J., Li, A., Wang, Y., Qin, M., Hu, Z., 2018. Zhang, J., Liu, Y., Cui, L., Liu, S., Yin, X., Li, H., 2017a. Ambient air
Long-term observations of tropospheric NO2, SO2 and HCHO pollution, smog episodes and mortality in Jinan, China. Sci.
by MAX-DOAS in Yangtze River Delta area, China. J. Environ. Rep. 7 (1), 11209. doi:10.1038/s41598- 017- 11338- 2.
Sci. 71, 207–221. doi:10.1016/j.jes.2018.03.006. Zhang, S., Wang, S., Zhang, R., Guo, Y., Yan, Y., Ding, Z., et al., 2021.
Tie, X., Huang, R.J., Cao, J., Zhang, Q., Cheng, Y., Su, H., Chang, D., Investigating the sources of formaldehyde and corresponding
Pöschl, U., Hoffmann, T., Dusek, U., Li, G., 2017. Severe photochemical indications at a suburb site in shanghai from
pollution in China amplified by atmospheric moisture. Sci. MAX-DOAS measurements. J. Geophys. Res. 126 (6).
Rep. 7 (1), 1–8. doi:10.1029/2020JD033351.
Vandaele, A.C., Hermans, C., Simon, P.C., Carleer, M., Colin, R., Zhang, Y., Ding, A., Mao, H., Nie, W., Zhou, D., Liu, L., et al., 2016.
Fally, S., et al., 1998. Measurements of the NO2 absorption Impact of synoptic weather patterns and inter-decadal
cross-section from 42 000 cm−1 to 10 000 cm−1 (238–1000 nm) climate variability on air quality in the North China Plain
at 220 K and 294 K. J. Quant. Spectrosc. Radiat. Transfer 59 during 1980e2013. Atmos. Environ. 124, 119e128.
(3–5), 171–184. doi:10.1016/S0022- 4073(97)00168- 4. doi:10.1016/j.atmosenv.2015.05.063.
Vinken, G., Boersma, K., Maasakkers, J., Adon, M., Martin, R., 2014. Zhao, N., Wang, G., Li, G., Lang, J., 2021. Trends in air pollutant
Worldwide biogenic soil NOx emissions inferred from OMI concentrations and the impact of meteorology in shandong
NO2 observations. Atmos. Chem. Phys. 14 (18), 10363–10381. province, Coastal China, during 2013-2019. Aerosol Air Qual.
doi:10.5194/acp- 14- 10363- 2014. Res. 21 (6), 200545. doi:10.4209/aaqr.200545.
Wagner, T., Beirle, S., Brauers, T., Deutschmann, T., Frieß, U., Zhao, S., Liu, S., Hou, X., Cheng, F., Wu, X., Dong, S., et al., 2018.
Hak, C., et al., 2011. Inversion of tropospheric profiles of Temporal dynamics of SO2 and NOX pollution and
aerosol extinction and HCHO and NO2 mixing ratios from contributions of driving forces in urban areas in China.
MAX-DOAS observations in Milano during the summer of Environ. Pollut. 242, 239–248. doi:10.1016/j.envpol.2018.06.085.
2003 and comparison with independent data sets. Atmos. Zhong, X., Zhao, Y., Sha, J., Liang, H., Wu, P., 2022. Spatiotemporal
Meas. Tech. 4 (12), 2685–2715. doi:10.5194/amt- 4- 2685- 2011. variations of air pollution and population exposure in
Wagner, T., Ibrahim, O., Shaiganfar, R., Platt, U., 2010. Mobile Shandong Province, eastern China, 2014–2018. Environ. Monit.
MAX-DOAS observations of tropospheric trace gases. Atmos. Assess. 194 (2). doi:10.1007/s10661- 022- 09769- 0.
Meas. Tech. 3 (1), 129–140. doi:10.5194/amt- 3- 129- 2010. Zhou, B., Zhang, S., Xue, R., Li, J., Wang, S., 2021. A review of
Wang, Y., Hu, B., Tang, G., Ji, D., Zhang, H., Bai, J., et al., 2013. Space-Air-Ground integrated remote sensing techniques for
Characteristics of ozone and its precursors in Northern China: atmospheric monitoring. J. Environ. Sci.
a comparative study of three sites. Atmos. Res. 132, 450–459. doi:10.1016/j.jes.2021.12.008.
doi:10.1016/j.atmosres.2013.04.005. Ziemke, J.R., Chandra, S., Bhartia, P.K., 2001. Cloud slicing: a new
Wang, T., Hendrick, F., Wang, P., Tang, G., Clémer, K., Yu, H., et al., technique to derive upper tropospheric ozone from satellite
2014. Evaluation of tropospheric SO2 retrieved from measurements. J. Geophys. Res. 106 (D9), 9853–9867.
MAX-DOAS measurements in Xianghe, China. Atmos. Chem.
Phys. 14 (20), 11149–11164. doi:10.5194/acp- 14- 11149- 2014.