1st INTERMEDIATE QUESTION BANK

JUNIOR CHEMISTRY QUESTION BANK INTERMEDIATE
1.Atomic Structure
1. What are the Postulates of Bohr’s Model of Hydrogen atom? Give its limitations and Explain different Series in Hydrogen
Spectrum? (Mar-11,13,16,19)( May-14)
2. What are Quantum Numbers? Give its Significances? (May 10, 13,15,16, Mar-10,14,15,)
3. Derive de-broglie’s equation?(Mar-12) 4. Explain about plank’s Quantum theory?
5. Explain about Heisenberg Uncertainty Principal?
6. Define atomic orbital? Explain the Shapes of s ,p and d-orbital with the help of diagram?
7. Explain about Aufbou, Pauli’s, Hund’s Principle?(Mar-19) And Compare the difference between emission spectrum and
adsorption spectrum.
8. Explain the Photo electric effect.
2 Marks Questions
9. What is Zeeman and Stark effect ? 10. What is the significance of  and 2 ?
11. What is Black body? 12.Calculate the frequency of light radiation whose wavelength is 2000 0Ao?
13. Calculate the wave number of sodium vapour lamp whose case wavelength is 5000A o?
14. What is the frequency of radiation of wave-length 600nm.(May-6,8)
2. Classification of Elements and Periodicits and Periodic Properties

15. Describe the classification of Elements into s ,p ,d ,f- blocks?(Mar-11,13,19)(May-13,15) 16.
Describe the of classification of Elements based on Chemical Properties?
17. Define IE1 and IE2 why IE2 > IE1 ? Discus the factors that effect I.E of an element (Mar-10,12,13, 16)( May-13)
18. What is Periodicity or Periodic Properties? How they varies in groups and periods.
(1) Atomic Radius (2) I.E (3) E.N (4) Electron gain enthalpy (Mar-14,15)(May-10,12,14,15) 19.
What is Lanthanide Contraction? Give its Consequenses.(May-4,6,7)
20. Give the characterstic properties of transition elements. Very short answer type questions
21. What is screening effect? 22.What is diagonal relationship? Give example? 23. Why
I.P of ‘N’ has more than ‘’O’’ 24 .What is inert pair effect? 25.An element ‘X’ has
atomic number 34 Give its position in the periodic table.
26. Among N 3−,O2−,F−,Na+,Mg and Al+2 +3 (Mar-7)(May-5)
(a)What is common in them (b)Arrange them in increasing ionic radii 27.
Give outer electronic configuration of s, p, d and f-block elements.
28. How does the nature of oxides vary in the 3rd period.
3. Chemical Bonding and Molecular Structures

29. Define Ionic bond? Explain the factors favorable for the formation of Ionic Compounds?(May-15)
30. What is Hybridization? Explain sp,sp2,sp3 hybridization with one example each? (Mar-13,14)(May-15,16TS)
31. Explain VSEPR theory.
32. Write the difference between Ionic and Covalent Compounds
33. Write the salient features of Molecular orbital theory? Draw M.O.E.D of N 2,O2? (Mar-14, May-14)
34. Explain Fajans rules?(Mar-7,19)(May-15,16)
35. What are the Postulates of Valency bond theory?
36. Explain about H-bonding (Mar-16)(May-15)
37. Write notes on (a) Bond angle (b) bond enthalpy (c) Bond length (d) Bond order with one example?
38. Explain the formation of Co-ordinate Covalent bond with one example?(Mar-7)(May-13)
39. Explain the hybridization involved in PCl5 molecule.(Mar-12)(May-13,16)
40. Explain the hybridization involved in SF6 molecule.(Mar-10,14,19) Very short answer type questions
41. What is octet rule? Briefly explain its significance and limitations.
42. Which of the two ions Ca+2 or Zn+2 is more stable and why.
43. Even though both NH3 and NF3 are pyramidal , NH3 has higher dipole moment compared to NF3 .Why?(May-16)
44. What is co-ordination number of ‘Na’ in NaCl and ‘Cs’ in CsCl
45. What type of bonds are present in NH4Cl ? Write its structure.
4. States of matter Gases and liquids
46. State (a) Boyl’s law (b) Charl’s law (c) Avagadro’s law
47. Derive Ideal gas equations?(Mar-14,16)
48. State and explain grahams law of Diffusion? (Mar-14)
49. State and explain Daltons law of Partial Pressures? (Mar-14)(May-11,14)
50. Explain kinetic molecular theory of gases? (Mar-13) 51. Derive expression for kinetic Energy of gas molecule?
52. Deduce gas laws form kinetic gas equation? (May-10,11,13)(Mar-16,19)
53. Derive Grahams law of diffusion and Dalton’s law of partial pressure from kinetic gas equation. (Mar-15) 54. Find
the pressure of 8gm of oxygen when heated to 2000C in a lit vessel?
55. Calculate the volume occupied by 25gm of C02 at 303k and 0.974 atm pressure?
56. 360cm3 of CH4 gas diffused through a porous membrane in 15 minutes. Under similar conditions 120cm 3 of another gas
diffused in 10 minutes. Find the molar mass of the gas.
57. If 500cm3 of hydrogen diffused in 16 minutes through a fine hole, how much time does the same volume of ozone(O 3) take
for diffusion.
2 Marks Questions
58. What are (a) Iso-therms (b) Iso-bars (c) Iso-chores
59. Which of the gases diffuses faster among N 2,O2 and CH4? Why?
60. what is compressability factor. 62.what is Joul-Thomson effect.
75. Why is the Velocity is used in Kinetic gas equation?
5. Stoichiometry
78. Chemical analysis of a carbon compound gave the following percentage composition by weight of the element carbon
10.06%, Hydrogen 0.84% and Chlorine 89.10% . Calculate the Empirical formula of the compound.
14.50%, Hydrogen 1.8%, Chlorine 64.46% , and Oxygen 19.24%. Calculate the Empirical formula of the compound.
80. Chemical analysis of a carbon compound gave the following percentage composition by weight of the element potassium
26.57%, Chromium 35.36% and Oxygen 38.07%. Calculate the Empirical formula of the compound.
12.80%, Hydrogen 2.10%, bromine 85.10%. .Molecular mass of the compound is 187.9 grams. Calculate the molecular
formula of the compound.
82. Balance the following redox reaction in acid medium. a) MnO4- +SO32- →Mn2+ + SO2 b) MnO4- +C2O42- →Mn2+ +CO2.
c) Fe+2 +Cr2 O7-2 → Fe+3 +Cr+3 (Mar-15,16)
83. Balance the following redox reaction in basic medicine. a) MnO 4- +I- →MnO2+ I2. b) Cr(OH)3 +IO3-→I-+ CrO42- c) P4
→PH3+H2PO 2 -
2 Mark Questions
84. What are comproportionation reactions? Give example.
85. What are disproportionation reactions? Give example.
86. Balance the following reaction by using oxidation number method. Cr + Pb(NO3)2→Cr(NO3)+Pb.
87. Calculate the oxidation numbers of some important compounds and ions (Mar-15)
88. How many number of moles of glucose are present in 540 grams of glucose. (Mar-14)
89. How many number of moles of glucose are present in 5.23 grams of glucose.
90. calculate the weight of 0.1 moles of sodium carbonate.
91. Calculate the volume of O2 at STP requires to completely burn 100 ml of acetylene.
92. The EF of the compound is CH2O and molecular weight is 90.Then calculate molecular formula.
6. Thermo Dynamics
93. What are open, Closed and Isolated Systems? Give example?
94. Explain Ist, IInd, IIIrd law of Thermodynamics?(Mar-19)(May-16)
95. Explain about Hess law of Constant Heat Summation. (Mar-13,15)
96. Write notes on (a) Internal energy (b) Enthalpy (c) Entropy (Mar-14)
97. Define the following (a) Enthalpy of Combustion (b) Enthalpy of Sublimation (c) Enthalpy of formation (d)Enthalpy of
atomization (Mar-11,13,14,15)(May-13,15,16)
98. What are intensive and extensive properties
7. Chemical Equilibrium & Acids –Bases

101. What is Homogeneous and Heterogeneous equilibrium reactions. Give examples.
102. What is Le-chateliers Principle? Discus Briefly the factors Which can Influence the Equilibrium?
103. Discus the application of Le-chatelier Principle for the Industrial Synthesis of Ammonia and Sulphur trioxide.
(May-10,11,15,16)
104. Explain Bronsted –Lowry Acid-base theory? (Mar-14,16)
105. What is conjugate Acid-Base pair? Give the conjugate acid and base of the following compounds or ions.
(a) OH- (b) H2O (c) HCO-3 (d)H2O2
106. Explain Lewis Acid-base theory?(Mar-15)(May-16)
107. Derive the relation between Kp and Kc? Give the relation for (i) H2 + I2 2HI (ii) 2NH3 N2 +3H2
(iii) 2SO2 +O2 2SO3 (Mar-13,15) ff
109. What is Solubility Product? Explain the Common ion effect on Solubility of Ionic Salt 111. What is P H?
(i) Calculate the PH of (a)10-3M HCl (b) 10-3M H2SO4 (c) 10-6M HNO3 (d) 0.02M H2SO4 (e) 10-8M HCl
(ii)Calculate the PH of (a)0.001M NaOH (b)0.01M Ca(OH)2 (c)0.0008M Ba(OH)2 (d)0.004M NaOH (e) 10-8M NaOH
112. What is ionic product of water? Give it’s value.
8. Hydrogen and its Compounds
113. Define Hard water and Soft water.
(a) Explain about methods to removal of Permanent Hardness of Water. (Mar-14,15)
(b) Explain the methods to remove temporary hardness of water.
114. Describe the preparation of Heavy Water? Give its uses
115. Write Short notes on Hydride? (Mar-14)
116. Explain the following hydrides with suitable examples.
(i) Electron-deficient(Mar-19) (ii)Electron-precise (iii) Electron-rich (iv)Ionic Hydrides. (Mar-19)
117. Discus the Position of Hydrogen in the Periodic Table 120. Explain any four Chemical Properties of water.
121. Hydrogen is a fuel? Explain? (May-13,14)
2 Marks Questions
122. What is deuterolysis? Give example? 123.Write any two use of Heavy water?
124. Which dissolved salts produce temporary hardness to the water?
1 26. Which dissolved salts produce permanent hardness to the water?
9. Alkali and Alkaline earth metals

127. Explain anomalous Behavior of Lithium?
130. Anomalous Behavior or Berylium?
2 Mark Questions
133. Lithium salts are mostly hydrated.Why? 135.What happens when magnesium metal is burnt in air?(Mar-
15)AP,138. Why are alkali metals not found in the free state in nature?
141. Elements of IA group are called alkali metals.Why?
10. Group-13 Elements
150. What is Milk of Magnesia? Give it uses (Mar-13,15) 151. Define inert pair effect.(Mar-19)
152. What are electron deficient compounds? Is BCl 3 is an electron deficient specie .Explain.
11. Group-14 Elements

153. Explain the Structures of Diamond and Graphite
154. Write notes on Fullerence
155. Explain the Structure of Silica? How does it react with (a) NaOH (b) HF 2 Marks Questions
156. Why diamond is bad conductor of Electricity?
157. Why graphite is a good conductor of electricity? (May-15)
158. Why graphite is used as Lubricant?(May-15)
159. What is the hybridization of carbon in diamond ,graphite ,Fullerene and CO 3-2? (Mar-13,16)
160. What is syn gas? 162. Give any two uses of Quartz glass?
163. What is dry ice (Mar-15) 164. Why is CO poisonous?
165. What is allotropy? Give the crystalline allotropes of carbon.(Mar-13,19)(May-13)
167. Diamond has high melting point. Explain?(Mar-13). 170. SiF6-2 is known, while SiCl6-2 is not.
Explain?
13.Organic chemistry
186. Explain Inductive effect with suitable examples.
187. Explain Mesomeric effect with suitable examples.
188. Explain Resonance effect with suitable examples.
189. Explain about types of Organic reactions.
190. Explain about Structural Isomerism with examples? (Mar-13)
191. Explain the mechanism of free radical Halogenation of alkanes?
192. Write the preparation and properties of Ethane.(Mar-19)
193. Write the preparation and Properties of Ethene molecule? (Mar-13, Mar-14) 194. Write the preparation and Properties
of Acetylene?
195. What are the Preparation methods of Benzene? Give electrophilic Substitution reaction of Benzene? (Mar-13,16,15May-14)
196. Discus Markovnikov’s rule and Kharasch effect?
197. Write short notes on geometrical Isomerism
198. Explain the mechanism involved in aromatic electrophilic Substitution reaction of Benzene? (Mar-13, Mar-14) 199.
Write Short note on Confirmation Isomerism of Ethane
2 Marks Questions
200. What is metamerism? Give example? 201. What is wurtz reaction?
202. What is friedel craft alkylation? 203. How to prepare nitro benzene from Benzene?
204. How to prepare ethyl chloride from ethylene
205. Give I.U.P.A.C Name of the follow? (a) Tetra 30-Butyl Methane (b) Neopentane
(c) (CH3)3CCH C CH2 ( 3)3 (d) (CH3)2C C H( 2 5 )2
206. Write the structural formula of the following compounds.
(a) 3,4,4,5-Tetra methyl Heptane. (b) 2,5-di Methyl Hexane (c) 2-Methyl Propanoic acid.
(d) 2,3- di Chloro butane. (e) Tri-chloro ethanoic acid (f) Neo pentane.
207. What is decarboxylation? 208. What is Soda lime mixture ?
209. What is dehydration? 210. What is ozonolysis? Give example?
211. What is dehydrohalogenation.
212. Name the products A,B,C are formed in the following reactions.
(i) Ethylene⎯⎯⎯⎯→ ⎯⎯⎯⎯→ ⎯⎯→Br CCl2 / 4 A Alc KOH. B Br2 C
(ii)CaC2 ⎯⎯⎯→ ⎯⎯⎯⎯→ ⎯⎯⎯⎯⎯→H O2A HotCutube B AlCl3+CH Cl3 C
(iii) CH  CH + H O2 ⎯⎯⎯⎯→ ⎯⎯⎯⎯⎯→301%%HgSOH SO2 44 A Re−arrangement B
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JUNIOR CHEMISTRY QUESTION BANK INTERMEDIATE

2. Classification of Elements and Periodicits and Periodic Properties

3. Chemical Bonding and Molecular Structures

7. Chemical Equilibrium & Acids –Bases

9. Alkali and Alkaline earth metals

11. Group-14 Elements

(iii) CH  CH + H O2 ⎯⎯⎯⎯→ ⎯⎯⎯⎯⎯→301%%HgSOH SO2 44 A Re−arrangement B

All The Best

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