Ppr.1 Circ.6 Gesamp Ehs List

Download as pdf or txt
Download as pdf or txt
You are on page 1of 95

E

4 ALBERT EMBANKMENT
LONDON SE1 7SR
Telephone: +44 (0)20 7735 7611 Fax: +44 (0)20 7587 3210

PPR.1/Circ.6
2 May 2019

HAZARD EVALUATION OF SUBSTANCES TRANSPORTED BY SHIPS

Report of the fifty-sixth session of the GESAMP Working Group on the


Evaluation of the Hazards of Harmful Substances Carried by Ships

The report of the fifty-sixth session of the GESAMP Working Group on the Evaluation of
the Hazards of Harmful Substances Carried by Ships (GESAMP/EHS Working Group), held
from 8 to 12 April 2019, is attached.

Any comments or questions should be addressed to:

Technical Secretary of the GESAMP/EHS Working Group


Marine Environment Division
International Maritime Organization
4 Albert Embankment
London SE1 7SR
United Kingdom

Email: [email protected]

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


E

WORKING GROUP ON THE EVALUATION EHS 56/9


OF THE HAZARDS OF HARMFUL 12 April 2019
SUBSTANCES CARRIED BY SHIP Original: ENGLISH
56th session
Agenda item 9

REPORT OF THE FIFTY-SIXTH SESSION

1 INTRODUCTION ....................................................................................................... 2
2 OUTCOME OF OTHER BODIES .............................................................................. 2
3 EVALUATION OF NEW SUBSTANCES ................................................................... 4
4 RE-EVALUATION OF SUBSTANCES AND CONSIDERATION OF ISSUES
RELATED TO EVALUATIONS .................................................................................. 5
5 CLASSIFICATION ISSUES ....................................................................................... 7
6 CONSOLIDATION OF EXISTING DATA FILES ....................................................... 8
7 COMMUNICATION AND PUBLICATION .................................................................. 8
8 ANY OTHER BUSINESS .......................................................................................... 8
9 CONSIDERATION AND ADOPTION OF THE REPORT .......................................... 8

LIST OF ANNEXES

ANNEX 1 LIST OF MEMBERS ATTENDING THE FIFTY-SIXTH SESSION OF THE


GESAMP/EHS WORKING GROUP
ANNEX 2 REPORT ON GESAMP ACTIVITIES
ANNEX 3 OUTCOME OF ESPH 24 AND THE ESPH WORKING GROUP AT PPR 6
ANNEX 4 CONCENTRATION OF INGREDIENTS OF A MIXTURE THAT WOULD
TRIGGER LONG-TERM HEALTH EFFECT RATINGS OF A MIXTURE
ANNEX 5 GESAMP HAZARD PROFILES FOR NEW SUBSTANCES SUBMITTED FOR
EVALUATION TO GESAMP/EHS 56
ANNEX 6 UPDATED GESAMP COMPOSITE LIST
ANNEX 7 PROVISIONAL AGENDA FOR THE FIFTY-SEVENTH SESSION OF THE
GESAMP/EHS WORKING GROUP

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 2

1 INTRODUCTION

1.1 The fifty-sixth session of the GESAMP Working Group on the Evaluation of
the Hazards of Harmful Substances Carried by Ships (GESAMP/EHS Working Group) was
held at IMO in London, United Kingdom, from 8 to 12 April 2019, chaired by Dr. Thomas Höfer.
The list of experts attending the meeting is set out in annex 1.

1.2 The Group reviewed the agenda and the provisional timetable, and agreed to some
modifications to the timetable. Subsequently, the Group adopted both.

2 OUTCOME OF OTHER BODIES

Outcome of GESAMP 45

2.1 The Group noted the report by the Chair on the outcome of the forty-fifth session of
GESAMP, which took place from 17 to 20 September 2018 in Rome, Italy, hosted by the Food
and Agriculture Organization (FAO). A summary of the outcome of the meeting is set out in
annex 2.

Outcome of IMO bodies

2.2 The Group noted that the following meetings of relevance had taken place since the
fifty-fifth session of the GESAMP/EHS Working Group:

.1 the twenty-fourth intersessional meeting of the Working Group on the


Evaluation of Safety and Pollution Hazards of Chemicals (ESPH 24), which
took place from 1 to 5 October 2018 (PPR 6/3); and

.2 the Working Group on the Evaluation of Safety and Pollution


Hazards (ESPH), which met during the sixth session of the
PPR Sub-Committee from 18 to 20 February 2019 (PPR 6/WP.3).

2.3 The Group noted the information presented by the Secretariat on the outcome of the
above-mentioned meetings on matters of relevance to the work of the GESAMP/EHS Working
Group, as summarized in annex 3.

2.4 The Group noted that PPR 6 had invited GESAMP/EHS to review the guidance
contained in the draft PPR.1 circular on decisions with regard to the categorization and
classification of products (PPR 6/20, annex 5), and to consider the possibility of a review and
update of GHP ratings for products in the GESAMP Composite List, in line with this guidance,
for purposes of consistency and harmonization (PPR 6/20, paragraph 3.38).

2.5 The Group reviewed the above-mentioned draft PPR.1 circular and also reviewed the
draft revised MEPC.1/Circ.512 on guidelines for the provisional assessment of liquid
substances transported in bulk (PPR 6/20, annex 4). Subsequently, the Group agreed to
suggest the following editorial modifications:

.1 the addition under paragraph 1.12 of the draft revised MEPC.1/Circ.512 of a


reference to the revised GESAMP Hazard Evaluation Procedure for
Chemicals Carried by Ships, specifically under "GESAMP Hazard Profile",
and the inclusion in appendix 2 of the up-to-date reference to the revised
GESAMP Hazard Evaluation Procedure for Chemicals Carried by Ships; and

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 3

.2 in paragraph .9 of the draft PPR.1 circular on decisions with regard to the


categorization and classification of products (PPR 6/20, annex 5), the
reference to BLG/Circ.15 should be replaced with the up-to-date reference
to the revised GESAMP Hazard Evaluation Procedure for Chemicals Carried
by Ships.

2.6 In the context of the draft PPR.1 circular on decisions with regard to the categorization
and classification of products (PPR 6/20, annex 5), the Group requested the Secretariat to
bring the following points to the attention of ESPH 26:

.1 The last sentence of paragraph .6 could be reworded, with a view to avoiding


any misunderstanding that minerals are readily biodegradable. As a
suggestion the sentence should indicate that the rating of Inorg is treated as
being equivalent to an R rating for the purpose of following the guidance rules
for pollution category and ship type.

.2 The last sentence of paragraph .11 may be misinterpreted as an obligation


for the submitters to inform GESAMP/EHS that a submission relates to a
reduced hazard profile. As a suggestion the word "should" could be replaced
by "may".

.3 In the context of paragraph .12, it should be noted that the GESAMP/EHS


Working Group includes in the EHS name of mixtures an indication of
components that have an impact on the environmental or health hazards of
the mixture, as appropriate. This could result in mineral oil being reflected in
the EHS name.

2.7 In relation to the possibility of a review and update of GHP ratings for products in the
GESAMP Composite List, in line with the guidance contained in the draft PPR.1 circular on
decisions with regard to the categorization and classification of products, the Group advised
that the GHP ratings reflect scientific data. The Group agreed that it is not appropriate to show
amended GHP ratings in the Composite List based on the guidance in the draft revised PPR.1
circular.

Cut-off values to be used when assessing mixtures containing components with a long-
term health effect

2.8 The Group recalled that PPR 5 had requested it to consider the proposal in
document PPR 5/3/3 (Norway) and to advise the ESPH Working Group with regard to
recommended cut-off values to be used when assessing mixtures containing components with
a long-term health effect.

2.9 The Group also recalled that due to time constraints at its fifty-fifth session, it had
been unable to finalize the requested advice but had agreed that the relevant text from the
revised GESAMP Hazard Evaluation Procedure for Chemicals Carried by Ships would form
the basis for developing a recommendation, at EHS 56, for consideration by the ESPH Working
Group.

2.10 The Group agreed that the table of concentrations of ingredients of a mixture that
would trigger long-term health effect ratings for that mixture, which had been developed by the
Group and included in the draft revised GESAMP Hazard Evaluation Procedure for Chemicals
Carried by Ships, could be used by the ESPH Working Group. The rules are set out in annex 4.
With regard to the two thresholds for mutagenicity, sensitization (skin and respiratory) and
target organ toxicity, the Group was of the view that the ESPH Working Group could go for the

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 4

worst-case option and use the lower percentage limits when utilizing the mixture calculation
rules for assigning carriage requirements. In this context, the Group noted the perspective that
manufacturers could request GESAMP/EHS for a full profile of a mixture, which would then be
rated based on the appropriate percentage limits for the subcategories of the above-mentioned
health effects, subject to appropriate data being submitted.

3 EVALUATION OF NEW SUBSTANCES

3.1 The Group recalled that when submitting new substances for evaluation by the
GESAMP/EHS Working Group, a full set of data, addressing all the relevant information
requirements set out in the GESAMP/EHS Product Data Reporting Form, was required. The
Group further noted that insufficient data, or a lack of adequate supporting arguments, where
estimates had been used, would result in no rating being assigned for the end-point concerned
or, as a worst case, no full hazard profile being issued for the chemical under review. In
addition, the Group emphasized that requests for evaluations of mixtures, for which the
assessment would be based on data for individual components of the mixture, should be
accompanied by detailed and realistic compositional information (i.e. percentages, ratios or
concentrations of the components).

3.2 The Group considered the following new substances, which had been submitted
for evaluation to this session:

.1 alpha-Olefins (C12+), mixture EHS 2516


.2 Alkyl (C3-C11) benzenes with EHS 2517
phenol-formaldehyde/acrylate polymers (33% or less)
.3 Sodium oxalate solution EHS 2518

3.3 The Group, in assessing the submitted products, made observations and reached
conclusions, as set out in the ensuing paragraphs. The resultant hazard profiles assigned by
the Working Group for inclusion in the GESAMP Composite List are set out in annex 5.

EHS 2516 alpha-Olefins (C12+), mixture

3.4 In considering the submission, the Group noted that according to the information
provided, the product was a mixture of variable composition of different organic aliphatic
substances. The information on composition according to the submitter indicated that each of
the ingredients may be present in a range from 0 to 100%. The Group also noted that no
impurities (e.g. alpha-olefins of a chain length lower than 12) were reported. In this regard, the
Group reiterated that submitters should provide detailed and realistic compositional information
(i.e. percentages, ratios or concentrations of the components) in order for the Group to be able
to produce an accurate GESAMP Hazard Profile.

3.5 Notwithstanding the above, the Group considered the data provided for the product
and assigned a GESAMP Hazard Profile accordingly. In reviewing the data available, the
Group noted that the acute inhalation toxicity of the vapour of the mixture was lower than the
toxicity based on exposure to mist. Therefore, the Group agreed to append a hash mark (#) to
the entry, denoting that a lower acute inhalation risk may be considered for the purposes of
risk management of exposure to the vapour.

Rating A1a=(5) A1b=(5) A1=(5) A2= (R) B1= (0) B2= NI


C1= (0) C2= (0) C3= (1) D1= (1) D2= (0) D3= A
E2= Fp E3= 3 (#) to the entry

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 5

EHS 2517 Alkyl (C3-C11) benzenes with phenol-formaldehyde/acrylate polymers


(33% or less)

3.6 In considering the submission, the Group noted that a full set of data had been
provided for the mixture and all components. Consequently, the Group assigned a GESAMP
Hazard Profile accordingly. In reviewing the data available, the Group noted that the acute
inhalation toxicity of the vapour of the mixture was lower than the toxicity based on exposure
to mist. Therefore, the Group agreed to append a hash mark (#) to the entry, denoting that a
lower acute inhalation risk may be considered for the purposes of risk management of
exposure to the vapour.

Rating A1a= 4 A1b= NI A1= 4 A2=NR B1=2 B2=0


C1=0 C2=0 C3=(2) D1=(2) D2=(2) D3=MASs
E2 = F E3 =3 (#) to the entry

EHS 2518 Sodium oxalate solution

3.7 In considering the submission, the Group noted that a full set of data had been
provided for the product and assigned a GESAMP Hazard Profile accordingly. The assessment
was based on the most concentrated aqueous solution. Having also noted the low vapour
pressure, the Group agreed to append a hash mark (#) to the entry, denoting that a lower acute
inhalation risk may be considered for the purposes of risk management of exposure to the
vapour.

Rating A1a= 0 A1b= (1) A1= (1) A2=R B1=2 B2=1


C1=1 C2=0 C3=(2) D1=(2) D2=2 D3=blank
E2 = D E3 =2 (#) to the entry

4 RE-EVALUATION OF SUBSTANCES AND CONSIDERATION OF ISSUES


RELATED TO EVALUATIONS

4.1 The Group recalled that, as part of its work, it routinely considered requests for the
re-assessment of products, based on the submission of new data or new scientific insights into
the hazards of substances that may result in a change to a hazard profile.

4.2 The Group also recalled its ongoing review and update of the existing GESAMP/EHS
files for completeness and consistency and the need for communication of any amendments
relating to such matters, bringing these to the attention of IMO (i.e. the ESPH Working Group
of the PPR Sub-Committee).

4.3 The Group considered a request to undertake a review of the hazard profiles for Ethyl
tert-butyl ether (EHS 2085), Fish by-products (fresh) (EHS 2499), Fish silage (containing 3%
or less formic acid with antioxidant) (EHS 2500) and Sodium aluminate (solution) (EHS 1234).
In the context of the latter substance, the Group also agreed to re-evaluate Sodium hydroxide
(30% or less)/Sodium aluminate (25% or less) solution (EHS 2486). Any agreed modifications
to the respective hazard profiles for these substances are highlighted in the revised GESAMP
Composite List, set out in annex 6.

EHS 2085 Ethyl tert-butyl ether

4.4 The Group considered a request for a re-evaluation of the B2 rating for this material.
In reviewing the data available, the Group agreed to amend column B2 from NI to 0. The Group
noted that the acute inhalation toxicity of the vapour of the mixture was lower than the toxicity
based on exposure to mist. Therefore, the Group agreed to append a hash mark (#) to the
entry, denoting that a lower acute inhalation risk may be considered for the purposes of risk

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 6

management of exposure to the vapour. The Group also amended a number of other ratings,
as set out below.

Amended rating A2=NR B2=0 C3=(1) D1=1 D2=0 E3=1


(#) to the entry

EHS 2499 Fish by-products (fresh)

4.5 The Group considered a request for a re-evaluation of the E2 rating for this material.
Having reviewed the information provided, the Group amended the E2 rating as set out below.

Amended rating E2=FD

EHS 2500 Fish silage (containing 3% or less formic acid with antioxidant)

4.6 The Group considered a request for a re-evaluation of the E2 rating for this material.
Having reviewed the new information provided by the submitters, which included information
on composition and solubility, the Group amended the E2 rating as set out below.

Amended rating E2=FD

EHS 1234 Sodium aluminate (solution)

4.7 The Group considered a request for a re-evaluation of this material. In reviewing the
data available, the Group amended the B1 and B2 ratings, as set out below.

Amended rating B1=3 B2=1

EHS 2486 Sodium hydroxide (30% or less)/Sodium aluminate (25% or less)


solution

4.8 Having reviewed Sodium aluminate (solution) (EHS 1234), the Group also
re-evaluated Sodium hydroxide (30% or less)/Sodium aluminate (25% or less) solution
(EHS 1253), taking into account that similar data considerations to the former substance would
apply. Subsequently, the Group amended the B1 and B2 ratings, as set out below.

Amended rating B1=3 B2=1

4.9 The Group further agreed to revise ratings for seven substances that were already
listed in the Composite List (see paragraphs 4.10 to 4.16 below), based on discussions
emanating from the review of the new substances that had been submitted at this session. Any
agreed modifications to the respective hazard profiles for these substances are highlighted in
the revised GESAMP Composite List, set out in annex 6.

EHS 720 Dodecene (all isomers)

4.10 The Group reviewed the ratings for Dodecene (all isomers) (EHS 720) and modified
the ratings as set out below. In reviewing the data available, the Group noted that the acute
inhalation toxicity of the vapour of the mixture was lower than the toxicity based on exposure
to mist. Therefore, the Group agreed to append a hash mark (#) to the entry, denoting that a
lower acute inhalation risk may be considered for the purposes of risk management of
exposure to the vapour.

Amended rating C3=1 D1=1 D2=0 (#) to the entry

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 7

EHS 2473 1-Dodecene

4.11 The Group reviewed the ratings for 1-Dodecene (EHS 2473) and modified the ratings
as set out below. In reviewing the data available, the Group noted that the acute inhalation
toxicity of the vapour of the mixture was lower than the toxicity based on exposure to mist.
Therefore, the Group agreed to append a hash mark (#) to the entry, denoting that a lower
acute inhalation risk may be considered for the purposes of risk management of exposure to
the vapour.

Amended rating D1=1 D2=(0) (#) to the entry

EHS 2028 Olefins C13 and above, all isomers

4.12 The Group reviewed the ratings for Olefins C13 and above, all isomers (EHS 2028)
and modified the ratings as set out below. In reviewing the data available, the Group noted
that the acute inhalation toxicity of the vapour of the mixture was lower than the toxicity based
on exposure to mist. Therefore, the Group agreed to append a hash mark (#) to the entry,
denoting that a lower acute inhalation risk may be considered for the purposes of risk
management of exposure to the vapour.

Amended rating C3=(1) D1=(1) D3=A E3=3 (#) to the entry

EHS 2423 Alkylbenzenes mixture (containing less than 1% naphthalene)

4.13 The Group reviewed the ratings for Alkylbenzenes mixture (containing less than 1%
naphthalene) (EHS 2423) and modified the rating for D3 by deleted the existing C.

Amended rating D3=A

EHS 2424 Alkylbenzenes mixtures (containing naphthalene)

4.14 The Group reviewed the ratings for Alkylbenzenes mixtures (containing naphthalene)
(EHS 2424) and modified the rating for D3 by deleting the existing C.

Amended rating D3=A

EHS 740 Ethylbenzene

4.15 The Group reviewed the ratings for Ethylbenzene (EHS 740) and modified the rating
for D3 by deleting the existing C and adding a T.

Amended rating D3=T

EHS 547 Cyclopentene

4.16 The Group reviewed the ratings for Cyclopentene (EHS 547) and added brackets to
the existing rating for D1, since it was based on read-across information.

Amended rating D1=(2)

5 CLASSIFICATION ISSUES

Introduction of new column E1 on flammability

5.1 The Group continued its review of flashpoint information for products, as extracted from
the GISIS database, and agreed to continue the review intersessionally, with a view to

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Page 8

completing the work at EHS 57 for incorporation in the Composite List once the revised
GESAMP Hazard Evaluation Procedure for Chemicals Carried by Ships had been published.
This will amend the E1 column in the GESAMP Hazard Profile from indicating tainting to rating
flammability.

6 CONSOLIDATION OF EXISTING DATA FILES

6.1 The Group recalled the ongoing review of the GESAMP/EHS files was a regular
agenda item.

6.2 Not having had sufficient time to review these files during the session, in light of other
higher priority work on its agenda, the Group agreed to defer consideration of this item to its
next session.

7 COMMUNICATION AND PUBLICATION

7.1 The Chair informed the Group of the review of the draft revised GESAMP Hazard
Evaluation Procedure for Chemicals Carried by Ships being conducted by GESAMP. In this
regard, the Group considered feedback from the GESAMP reviewers and agreed on
amendments to the draft. As the review process was ongoing, the Group noted that the Chair
would contact the members of GESAMP/EHS should there be any further comments by the
reviewers that would require significant amendments to the draft.

7.2 Subsequently, the Group invited the Secretariat to take the appropriate action for
finalizing the publication of the revised GESAMP Hazard Evaluation Procedure for Chemicals
Carried by Ships, once the review had been finalized.

8 ANY OTHER BUSINESS

8.1 Based on the volume of information contained in submissions in recent sessions, the
Group suggested that the deadline for submissions to future GESAMP/EHS meetings should
be set sufficiently in advance of the meeting so as to allow the members of the Group to
commence preparatory work at least three weeks prior to the session.

Draft provisional agenda and date of the next session

8.2 The Group agreed to the draft provisional agenda for its next session, set out in
annex 7, and that its next meeting had been tentatively scheduled to take place from
4 to 8 May 2020, at IMO headquarters in London. Subject to the aforementioned dates being
confirmed, the deadline for manufacturers to submit information to GESAMP/EHS 57 would
be 6 March 2020.

9 CONSIDERATION AND ADOPTION OF THE REPORT

9.1 The Group adopted its report, noting that it would be circulated as PPR.1/Circ.6.

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 1, page 1

ANNEX 1

LIST OF MEMBERS ATTENDING THE FIFTY-SIXTH SESSION


OF THE GESAMP/EHS WORKING GROUP

Dr. Thomas Höfer (Chair) Email: [email protected]


Schwendenerstrasse 21 Tel: +49 30 811 8141
D-14195 Berlin Mob.: +49 152 539 005 34
Germany

Mr. Michael Morrissette Email: [email protected]


Dangerous Goods Advisory Council Tel: +1 202 289 4550
Suite 760 Fax: +1 202 289 4074
7501 Greenway Center Drive
Greenbelt, MD 20770
United States

Dr. Stéphane Le Floch Email: [email protected]


Cedre Tel: +33 2 98 33 67 02
715 rue Alain Colas Fax: +33 2 98 44 91 38
CS 41836 Mob.: +33 627 46 11 53
29218 Brest Cedex 2
France

Dr. Wenxin Jiang Email: [email protected]


Tianjin Research Institute of Tel: +86 22 59812 345 ext 8411
Water Transport Engineering (TRIWTE) Fax: +86 22 59812 118
2618#, Xingang Road No.2 Mob.: +86 186 2259 9805
Tanggu, Tianjin
China

Mr. Richard Luit Email: [email protected]


RIVM, Centre for Safety of Substances and Tel: +31 302 743 073
Products Mob: +31 646 860 770
PO Box 1, 3720 BA Bilthoven
Netherlands

Dr. Patricio H. Rodríguez Email: [email protected]


Clemente Fabres 1025, D63 Tel: +56 2 2204 5726
Providencia Mob: +56 9 9889 6027
Santiago 750 1192
Chile

Dr. Bette Meek Email: [email protected]


McLaughlin Centre for Risk Science Tel: +613 276 4134
University of Ottawa Fax: +613 562 5944
600 Peter-Morand Crescent, Room 216
Ottawa, ON K1G 5Z3
Canada

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 1, page 2

IMO SECRETARIAT

Mr. Loukas Kontogiannis Email: [email protected]


Head, Carriage of Chemicals in Bulk & Tel: +44 20 7587 4151
Technical Secretary of the GESAMP/EHS Fax: +44 20 7587 3210
Working Group
International Maritime Organization
Marine Environment Division
4 Albert Embankment
London SE1 7SR
United Kingdom

Dr. Ken McDonald Email: [email protected]


GESAMP Technical Advisor Tel: +44 20 7587 3249
International Maritime Organization Fax: +44 20 7587 3210
Marine Environment Division
4 Albert Embankment
London SE1 7SR
United Kingdom

Ms. Jurga Kononovaite Email: [email protected]


Administrative Assistant Tel: +44 20 7463 4202
International Maritime Organization Fax: +44 20 7587 3210
Marine Environment Division
4 Albert Embankment
London SE1 7SR
United Kingdom

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 2, page 1

ANNEX 2

REPORT ON GESAMP ACTIVITIES

1 The Joint Group of Experts on the Scientific Aspects of Marine Environmental


Protection (GESAMP) held its forty-fifth session, from 17 to 20 September 2017, in Rome,
Italy, hosted by the Food and Agriculture Organization (FAO). The session was held under the
Chairmanship of Dr. Peter Kershaw.

GENERAL ACTIVITIES

2 The Group recognized the services of Dr. Stefan Micallef, Administrative Secretary
for GESAMP, who could not attend the session due to his retirement from United Nations
service. It was noted that Dr. Micallef had more than 20 years of experience in GESAMP,
initially as a member of Working Group 1 (1995-2001), then a Technical Secretary for Working
Group 1 (2005-2007), and finally as Administrative Secretary for GESAMP in his position as
the Director of the Marine Environment Division of IMO (2007-2018).

3 GESAMP noted that the independence, credibility and cost-effectiveness of GESAMP


was well recognized, and the continuing delivery of high-quality outputs were appreciated. This
could only be maintained with continuing support of the UN Sponsoring Organizations. The
addition of the International Seabed Authority (ISA) as one of GESAMP's sponsoring
organizations was noted with great appreciation and showed the growing interest for
GESAMP's work within the UN system.

4 The 10 Sponsoring Organizations committed to support the activities of GESAMP


in 2018/2019 at least to the level of the previous years. In 2019, GESAMP will be
celebrating 50 years since its establishment in 1969. In this context, the GESAMP Office will
organize an anniversary task team to prepare for GESAMP's 50th anniversary in New York.

WORKING GROUP 1

5 The Chair of Working Group 1 reported on progress made during EHS 55 and the
months after. GESAMP noted:

.1 that 11 new substances had been evaluated and full GESAMP Hazard
Profiles (GHPs) assigned, and that the GHPs for four substances had either
been modified or reconfirmed, based on consideration of new data;

.2 the WG's finalization of the revision of the existing hazard evaluation


procedure;

.3 the WG's progress in drafting a new GESAMP Reports and Studies report
with its publication planned to be in time for GESAMP's 50th anniversary in
2019; and

.4 that the IMO ESPH Working Group and the PPR Sub-Committee had
requested Working Group 1 (WG 1) to give more guidance for the hazard
evaluation of mixtures.

6 GESAMP noted that WG 1 had informally discussed the procedures and the workload
when evaluating new substances. The total volume of data sets, the number of publications
linked to the submitted data and the risk assessment reports on the chemical substances
involved have all increased significantly during the last decade. The main reason for such an

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 2, page 2

increase in the volume of data sets is the European chemicals policy with the requirements set
under the so-called REACH regulation. Under this European legislation, the chemical industry
has not only to establish a full set of safety information including competent summaries of
scientific studies, but also to compile specific Chemical Safety Reports (CSR). Such reports
usually exceed 100 pages (often running into several hundred pages as in the cases of the
substances evaluated during EHS 55) and are of a confidential nature. With the number of
submissions to be evaluated during a five-day session, a full study of such documents by all
members of the Working Group is not possible. New ways of making such confidential
information available for the Working Group's experts in preparation of the meeting should be
discussed. It was noted that there were legal restrictions for circulation of confidential data and
practical challenges concerning the overall workload of the members of the Working Group
when such homework would be introduced. The situation will be further discussed within WG 1.

7 GESAMP further noted that WG 1 initiated discussions on possible future


amendments to the existing guidance during its fifty-third session in 2016, developed first drafts
intersessionally and finalized draft texts and rationales during the fifty-forth session in 2017. In
2018, at the fifty-fifth session, the Group considered the draft revision of this Hazard Evaluation
Procedure that had been prepared intersessionally by EHS expert subgroups under the
coordination of the Chair. As requested by IMO bodies, WG 1 developed guidance for
assessing mixtures during its fifty-fifth session and finalized it by correspondence during the
weeks after to be integrated into the new Hazard Evaluation Procedure.

8 Having recalled the agreed timeline for completion of the revision of the Hazard
Evaluation Procedure for finalization and publication in time for the 50th anniversary of
GESAMP in 2019, the Group comprehensively reviewed the draft that had been prepared
intersessionally and concluded that all technical and scientific matters had been considered
sufficiently and to the satisfaction of the Group. GESAMP noted the progress and agreed that,
as the draft revision was a result of a comprehensive review by WG 1, it should be subject to
a formal review by GESAMP and it should be assigned a new Report and Studies number.
Subsequently, GESAMP invited the Secretariat to take appropriate action for the revised
"GESAMP Hazard Evaluation Procedure for Chemicals Carried by Ships, 2019" to be
published before EHS 56.

8 The terms of reference of the GESAMP EHS Working Group, as given by GESAMP
at its sixth session in 1974 and amended at its eighth session in Rome (1976) are: "To examine
and evaluate data and to provide such other advice as may be requested, particularly by IMO,
for evaluating the environmental hazards of harmful substances carried by ships, in
accordance with the rationale approved by GESAMP for this purpose".

9 GESAMP noted that the above terms restricted the scientific evaluation and advice to
environmental hazards. However, during the last years, Working Group 1 had been requested
to evaluate occupational hazards for ships crews and those handling the cargo, as well as to
offer advice on maritime emergency response. The GESAMP Hazard Profile is used by IMO
and maritime administrations for assigning minimum carriage requirements for the transport of
liquid bulk cargoes in general. Most of these technical requirements target ship safety, many
relate to environmental protection and others relate to occupational protection. Upcoming IMO
regulations will specify the involvement of the GESAMP EHS Working Group and the use of
the GESAMP Hazard Profile in all of these three areas.

10 Accordingly, GESAMP approved the revised Terms of Reference for Working Group 1
to read as follows: "The GESAMP Working Group on the Evaluation of the Hazards of Harmful
Substances Carried by Ships is an expert group to provide best available scientific assessment
of the environmental, occupational and safety hazards of chemicals, in particular to:

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 2, page 3

.1 provide scientific advice on the hazards of chemicals transported by ships as


may be requested, particularly by IMO;

.2 evaluate safety data and test reports on specific chemicals submitted by


industry in accordance with the rationale approved by GESAMP for this
purpose and create a GESAMP Hazard Profile for such chemicals
accordingly;

.3 maintain a list of hazard evaluations ("Composite List" of GESAMP Hazard


Profiles) for the use by IMO and keep it up to date based on available
scientific data; and

.4 observe the developments concerning the international harmonization of


hazard classification by the United Nations and scientific guidance on hazard
assessment published by international organizations to improve the
GESAMP hazard evaluation procedure and GESAMP hazard ratings."

OTHER WORK

11 The task of Working Group 34 (WG 34), the "GESAMP Ballast Water Working
Group", is to evaluate the risks for the crew and the ships safety, the risk for the public at large,
and the environmental safety of the Ballast Water Management Systems. During two sessions
in November 2017 and June 2018, the Group evaluated three systems. WG 34 had initiated
the drafting of a Reports & Studies report on the whole subject including the Methodology for
working procedures. GESAMP decided that the current draft should be distributed among
GESAMP members for peer review, for the final publication to be available before the 50th
anniversary of GESAMP in 2019. (Review has taken place.)

12 Working Group 38 on "Atmospheric input of chemicals to the ocean" had prepared


a synthesis of the results from seven scientific papers in a report which had been reviewed by
GESAMP and published in early 2018 as Reports & Studies No.97. The work led to the new
scientific activities on the changing atmospheric acidity and the impact of ocean acidification
on fluxes of non-CO2 climate-active species in two workshops in February and March 2018
with 34 scientists from 15 countries.

13 Working Group 39, the "Establishment of trends in global pollution in coastal


environments" is to provide a retrospective analysis using dated environmental archives and
time-series data from peer-reviewed published research. The Working Group had completed
a draft report by August 2018, first reviewed by GESAMP members, followed by external
reviewers in the latter half of 2018. Some principal issues resulting from the review were
discussed, which resulted in amendments of the graphical presentation. GESAMP agreed that
after completion, the report should be published. GESAMP noted that, overall, the results
presented in the report showed that for most contaminants that have been regulated the
concentration had gone down, which should be highlighted better, since this would be
particularly important, when interpreted in a policy context.

14 "Sources, fate and effects of plastics and micro-plastics and in the environment" are
dealt with in Working Group 40 (WG40). WG 40 held three workshops in September 2017 in
Paris, in March 2018 in San Diego, and in June 2018 in Bangkok. A report on guidelines covering
terminology and methodologies for the monitoring and assessment of marine macro-plastics and
microplastics was finalized in late 2018 and published as Reports and Studies No.99.

15 Working Group 41, the "Working Group on marine geoengineering" had finalized a
draft report, which underwent internal and external review. GESAMP noted that the report

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 2, page 4

would be published in early 2019. The Working Group had no scheduled meetings and
depending on the discussion of the report, the lead agencies would consider their interest in
further funding. Key points from the report were: .1 some 25 approaches had been assessed
in 8 categories; .2 the information available varied widely from just concepts to many scientific
papers; .3 there was generally insufficient information to assess to permit robust scientific
assessment; and .4 consequently, the WG focused on evaluating illustrative examples from
each of the eight categories. The report has since been published as Reports and Studies
No.98.

16 In 2016, GESAMP established Working Group 42 on the "Impacts of wastes and


other matter in the marine environment from mining operations, including deep-sea mining",
which had its first meeting in September 2017. A draft report was expected to be finalized in
late 2018 to be reviewed in early 2019.

17 As always, the Sponsoring Organizations and the Secretariat reported their work
related to the marine environment, e.g. the UN Regular Process and the 2030 Agenda for
Sustainable Development, the Sustainable Development Goals (SDGs) and the United
Nations Decade of Ocean Science for Sustainable Development. GESAMP experts are
involved in some of these activities.

18 FAO, supported by IMO, proposed the establishment of a new working group on


Sea-based sources of marine litter, including fishing gear and other shipping-related matter.
GESAMP agreed in principle to the establishment, pending the development of a full working
group proposal, including terms of reference. (This was approved in early 2019.)

19 GESAMP agreed to further scope out the issue of the impact of "armed conflict on the
marine environment" in the intersessional period. GESAMP noted the progress of some
scoping activities including the "Relevance of inputs of disinfection byproducts (DBPs) into the
marine environment", the "Update the Information on Sources of the Main Pollutants Impacting
the Global Marine Environment (The 80:20 Conundrum)" and "Sand and Gravel Mining".

20 Several institutions and NGOs presented their work on marine environment


protection, including the World Maritime University, Greenpeace, Oceana, NAFO and ACOPS.
On one afternoon GESAMP held a special side event titled "Harmful algal blooms and food
security and safety in the context of climate change".

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 3, page 1

ANNEX 3

OUTCOME OF ESPH 24 AND THE ESPH WORKING GROUP AT PPR 6

1 OUTCOME OF ESPH 24

Evaluation of chemicals

1.1 ESPH 24 considered a number of products as part of its routine assessment and
assignment of carriage requirements, in accordance with the IBC Code. Decisions that were
based on the outcome of GESAMP/EHS 55 or that are relevant to GESAMP/EHS 56 are
summarized below.

VAPOUR-RELATED CARRIAGE REQUIREMENTS FOR NON-VOLATILE CORROSIVE PRODUCTS

1.2 The Group considered document ESPH 24/3/26 (Norway), which proposed that the
Group reconsider the requirements for controlled venting and increased ventilation rates for
non-volatile corrosive products in a similar manner as had been done at PPR 5 for non-volatile
toxic products.

1.3 In this context, the Group recalled that the ESPH Working Group at PPR 5 had agreed
to follow, on a case-by-case basis, a similar approach for non-volatile solid substances
transported in aqueous solutions as had been used in the case of inorganic brines
(see BLG.1/Circ.33, annex, paragraph 10) in relation to inhalation toxicity when the SVC/LC 50
ratio could not be calculated due to the exact vapour pressure of the solid not being available.

1.4 The Group further recalled that the rationale behind the above-mentioned decision
was that, in general, the vapour pressure of solid substances was very low and only water
vapour (i.e. non-toxic vapours) would be emitted when transporting such non-volatile solid
substances in aqueous solution.

1.5 Subsequently, the Group agreed that the same rationale could be extended, on a
case-by-case basis, to non-volatile corrosive solid substances transported in aqueous
solutions. Specifically, it would be applicable when considering vapour-related requirements
such as whether controlled or open venting arrangements should be assigned (column g of
chapter 17 of the IBC Code) or whether or not increased ventilation would be required
(paragraph 15.17 of the IBC Code). The Group also agreed to amend paragraph 10 of the
annex to BLG.1/Circ.33 accordingly.

1.6 The Group noted that, had the above decision regarding non-volatile corrosive solid
substances been reached before or during PPR 5, less stringent requirements could have
been assigned in columns g and o (i.e. "Open" in column g, "No" in column n and no "15.17"
in column o) for "Potassium hydroxide solution", "Sodium borohydride (15% or less)/sodium
hydroxide", "Sodium chlorate solution (50% or less)", "Potassium formate solutions" and
"Sodium hydroxide solution" in the draft revised chapter 17 of the IBC Code (PPR 5/24/Add.1).

1.7 In this regard, the Group suggested that the delegation of Norway could submit a
document to MEPC 74 and MSC 101 proposing that the carriage requirements in columns g,
n and o for "Potassium hydroxide solution", "Sodium borohydride (15% or less)/sodium
hydroxide", "Sodium chlorate solution (50% or less)", "Potassium formate solutions" and
"Sodium hydroxide solution" be modified prior to the adoption of the draft revised chapter 17
of the IBC Code.

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 3, page 2

Guidance for assessing and classifying products under Annexes I and II of MARPOL

Energy-rich fuels

1.8 The Group agreed that the following products, that were listed in annex 11 (Biofuels
recognized under the 2011 Guidelines for the carriage of blends of petroleum oil and biofuels)
of MEPC.2/Circ.23, fulfilled the characteristics described in section 4 of the draft guidelines for
the carriage of energy-rich fuels and their blends:

.1 Alkanes (C4-C12) linear, branched and cyclic (containing benzene up to 1%);

.2 Alkanes (C5-C7), linear and branched;

.3 Alkanes (C9-C24) linear, branched and cyclic with a flashpoint ≤60°C;

.4 Alkanes (C9-C24) linear, branched and cyclic with a flashpoint >60°C;

.5 Alkanes (C10-C17), linear and branched;

.6 Alkanes (C10-C26), linear and branched with a flashpoint ≤60°C; and

.7 Alkanes (C10-C26), linear and branched with a flashpoint >60°C.

1.9 Consequently, the Group agreed that, subject to the draft guidelines for the carriage
of energy-rich fuels and their blends being approved at MEPC 73, the products listed in
paragraph 1.8 above should be listed in a new annex 12 (Energy-rich fuels subject to Annex I
of MARPOL) to MEPC.2/Circ.24 (issued on 1 December 2018). Accordingly, the
above-mentioned products and their corresponding biofuel entries would be deleted from list 1
and annex 11 of the MEPC.2/Circular, as appropriate.

1.10 With regard to consequential amendments emanating from the inclusion of the
annex 12 to MEPC.2/Circ.24, the Group noted that consequential modifications would have to
be made to the draft revised chapter 17 of the IBC Code prior to its adoption (i.e. deletion of
the entries that had been included in annex 12 to MEPC.2/Circ.24, as well as deletion of their
corresponding biofuel blend entries).

1.11 Similarly, consequential amendments to the 2011 Guidelines for the carriage of
blends of petroleum oil and biofuels, as amended (MEPC.1/Circ.761/Rev.1) would have to be
made (i.e. deletion of references to alkanes (C10-C26), linear and branched with a flashpoint
of either 60°C or less or more than 60°C).

2 OUTCOME OF THE ESPH WORKING GROUP AT PPR 6

Evaluation of chemicals

2.1 The Group evaluated and assigned minimum carriage requirements for one list 1
products and three list 3 products (PPR 6/WP.3, section 3 and annexes 1 and 2).

Draft modifications to the draft amendments of the IBC Code

2.2 The Group recalled that ESPH 24 had noted that, as a result of the addition of
annex 12 to MEPC.2/Circ.24, consequential modifications to the draft revised chapters 17
and 19 of the IBC Code would need to be introduced prior to their adoption (i.e. deletion of the

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 3, page 3

entries that had been included in annex 12 to MEPC.2/Circ.24, as well as deletion of their
corresponding biofuel blend entries).

2.3 Consequently, the Group prepared draft modifications to the draft revised chapters 17
and 19 of the IBC Code. The full set of modifications to the amendments are set out in annex 5
to document PPR 6/WP.3, to be considered and adopted together with the amendments to the
IBC Code by MEPC 74 and MSC 101.

Revision of MEPC.2/Circ.512

2.4 The Group, having recalled that PPR 5 had requested GESAMP/EHS 55 to advise
the ESPH Working Group with regard to recommended cut-off values to be used when
assessing mixtures containing components with long-term health effects, considered whether
to await the outcome of this work by the GESAMP/EHS Working Group for the current revision
of the MEPC.1/Circ.512. However, having noted that the revision of the circular was almost
finished and the timeline for the completion of the work by GESAMP/EHS was unclear, the
Group agreed that there was no need to include this in the current revision of the circular and
instead to revisit this at a future session once GESAMP/EHS had completed its work.

2.5 Having agreed on a number of final modifications and having resolved the outstanding
issues, including the development of recommendations for the assessment of complex
petrochemical mixtures, the Group finalized the draft revision to MEPC.1/Circ.512 on Revised
guidelines for the provisional assessment of liquid substances transported in bulk, as set out
in annex 7 to document PPR 6/WP.3.

Revision of BLG.1/Circ.33

2.6 The Group recalled that ESPH 24 had prepared an updated draft list of decisions with
regard to the classification of products, as set out in annex 5 to document PPR 6/3. The Group
further recalled that ESPH 24 had agreed that the ESPH Working Group at PPR 6 would
prepare a final revised circular for consideration by the Sub-Committee.

2.7 The Group reviewed the draft in detail and, having agreed on a number of final
modifications, finalized the draft revised PPR circular on decisions with regard to the
categorization and classification of products, as set out in annex 8 to document PPR 6/WP.3.

2.8 The Group further agreed to invite GESAMP/EHS to review the guidance contained
in the circular and to consider the possibility of a review and update of GHP ratings for products
in the GESAMP Composite List, in line with this guidance, for purposes of consistency and
harmonization.

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 4, page 1

ANNEX 4

CONCENTRATION OF INGREDIENTS OF A MIXTURE THAT WOULD TRIGGER


LONG-TERM HEALTH EFFECT RATINGS OF A MIXTURE

Column D3 Hazard evaluation Concentration


limit
C Carcinogenicity  0.1%
M Mutagenicity  0.1%
Mutagenicity equivalent to GHS cat. 2  1%
R Reproductive toxicity  0.3% *
Ss Skin sensitization equivalent to GHS sub-cat. 1A  0.1%
Skin sens. equivalent to GHS sub-cat. 1B  1%
Sr Respiratory sensitization equivalent to GHS sub-cat. 1A  0.1%
Resp. sens. equivalent to GHS sub-cat. 1B  1%
A Aspiration hazard  10% **
T (N, I) Specific target organ toxicity (STOT)  1%
STOT equivalent to GHS cat. 2  10%
* GESAMP/EHS normally adopts a 0.3% limit value, which is accepted by most
authorities; GHS specifies values of both 0.1% and 0.3%.
** The mixture must have a kinematic viscosity  20.5 mm2/s, measured at 40oC.

***

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


EHS 56/9
Annex 5, page 1

ANNEX 5

GESAMP HAZARD PROFILES FOR NEW SUBSTANCES SUBMITTED FOR


EVALUATION TO GESAMP/EHS 56

1 This annex sets out the GESAMP Hazard Profiles (GHP) assigned for the
products submitted to the current session. The respective substances and their GHPs are
summarized in the subsequent table.

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


ANNEX 5 - GESAMP HAZARD PROFILES FOR NEW SUBSTANCES SUBMITTED FOR EVALUATION TO GESAMP/EHS 56 12 April 2019
Page 1 of 1
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Alkyl (C3-C11) benzenes with phenol-formaldehyde/acrylate polymers (33% or less) (#) 2517 4 NI 4 NR 2 0 0 0 (2) (2) (2) MASs F 3
Alkyl (C3-C11) benzenes with phenol-formaldehyde/acrylate polymers (33% or less) 4198 CAS No
alpha-Olefins (C12+), mixture (#) 2516 (5) (5) (5) (R) (0) NI (0) (0) (1) (1) (0) A Fp 3
alpha-Olefins (C12+), mixture 4197 CAS No
Sodium oxalate solution (#) 2518 0 (1) (1) R 2 1 1 0 (2) (2) 2 D 2
Sodium oxalate solution 4199 CAS No

***
EHS 56/9
Annex 6, page 1

ANNEX 6

UPDATED GESAMP COMPOSITE LIST

Notes:

1 In the Composite List, both EHS and TRN (shipping) names are shown for each
product. The alphabetical listing of the products is based on the EHS names.

2 Any changes introduced in the table since the last issue of the Composite List are
highlighted.

3 Entries with an EHS name marked with a single asterisk (*) represent cleaning
additive components that have only a partial hazard profile assigned. These profiles cannot
be used for mixture calculations in relation to bulk shipments.

4 Entries with an EHS name marked with a double asterisk (**) represent mixture
components for which only a partial hazard profile has been assigned. These profiles
may be used for mixture calculations in relation to bulk shipments.

5 Entries with an EHS name marked with a hash mark (#) reflect that for the C3 rating,
the product, as a vapour rather than an aerosol or mist, could be considered to have a lower
inhalation hazard for the purposes of risk management.

6 Entries with an EHS name marked with an exclamation mark (!) refer to a mixture that
contains components with substantially different physical properties and therefore different
physical behaviours when released in the marine environment. The E2 rating assigned reflects
the most severe impact from an environmental standpoint. For example, a mixture assigned a
rating of Fp may also have a major component(s) with sinker characteristics (S) or dissolver
characteristics (D).

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx


ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 1 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Acetic acid 13 0 0 0 R 1 NI 1 1 1 3C 3 D 3
Acetic acid 64 CAS No 64-19-7
Acetic anhydride 12 0 0 0 R 1 NI 1 0 2 3 3 A D 3
Acetic anhydride 65 CAS No 108-24-7
Acetochlor (ISO) 2047 3 2 2 NR 4 NI 1 0 (1) 0 0 S 2
Acetochlor 66 CAS No 34256-82-1
Acetone 15 0 0 0 R 0 0 0 0 0 1 2 NT DE 2
Acetone 67 CAS No 67-64-1
Acetone cyanohydrin 14 0 0 0 R 4 NI 3 4 3 (3) (3) D 3
Acetone cyanohydrin 68 CAS No 75-86-5
Acetonitrile 16 0 0 0 R 1 NI 1 1 2 1 2 D 2
Acetonitrile 69 CAS No 75-05-8
Acetonitrile (Low purity grade) 2333 0 NI 0 R 3 NI 1 1 2 1 2 D 2
Acetonitrile (Low purity grade) 2876 CAS No
Acid mixtures (nitrating acid) 289 Inorg NI 0 Inorg (2) NI 3 3 4 3C 3 D 3
Nitrating acid (mixture of sulphuric and nitric acids) 497 CAS No
Acrylamide 23 0 0 0 R 2 0 2 2 (2) 1 2 CMNSs D 3
Acrylamide solution (50% or less) 70 CAS No 79-06-1
Acrylic acid 24 0 0 0 R 4 NI 2 2 2 3C 3 D 3
Acrylic acid 71 CAS No 79-10-7
Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, 2406 0 NI 0 R 0 0 0 0 (0) 0 0 D 0
aqueous solution)
Acrylic acid / dimethyldiallylammonium chloride copolymer, partial sodium salt (MWt 1500-4000, 3682 CAS No
aqueous solution)
Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt (aqueous solution) 2417 0 NI 0 NR 0 NI 0 (0) (0) 0 0 D 0
Acrylic acid/ethenesulphonic acid copolymer with phosphonate groups, sodium salt solution 3693 CAS No
Acrylonitrile 25 0 2 2 NR 3 0 2 3 3 2 2 CMSs NT DE 3
Acrylonitrile 72 CAS No 107-13-1
Acrylonitrile-styrene copolymer dispersion in polyether polyol (LOA) 1432 NI 0 0 NI 1 NI 0 (0) (0) 0 (0) S 0
Acrylonitrile-Styrene copolymer dispersion in polyether polyol 73 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 2 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Adiponitrile 26 0 0 0 R 1 NI 3 (3) 3 3 (3) FD 3
Adiponitrile 74 CAS No 111-69-3
Alachlor (ISO) 1488 3 3 3 NI 4 1 1 0 (2) 1 0 CSs S 3
Alachlor technical (90% or more) 75 CAS No 15972-60-8
Alcoholic beverages 293 0 0 0 R 0 0 0 0 0 0 1 D 1
Alcoholic beverages, n.o.s. 85 CAS No
Alcoholic silicasol 2198 0 0 0 R 0 0 0 0 0 1 2 DE 2
Tetraethyl silicate monomer/oligomer (20% in ethanol) 2475 CAS No
Alcohol(C12-C16) poly(20 and above)ethoxylates 1482 4 (3) (3) R 2 0 (0) (0) (2) 2 1 D 2
Alcohol (C12-C16) poly(20+)ethoxylates 78 CAS No
Alcohol(C6-C17)(secondary) poly(3-6)ethoxylate 722 4 3 3 R 4 2 0 (0) (3) 3 2 D 3
Alcohol (C6-C17) (secondary) poly(3-6)ethoxylates 81 CAS No
Alcohol(C6-C17)(secondary) poly(7-12)ethoxylate 295 3 3 3 R 4 1 1 0 (3) 3 3 D 3
Alcohol (C6-C17) (secondary) poly(7-12)ethoxylates 80 CAS No
Alcohol (C10-C18) poly (7) ethoxylate (#) 2488 NI (3) (3) R 3 1 (1) (0) (2) (2) (2) D 2
Alcohol (C10-C18) poly (7) ethoxylate 3979 CAS No 85422-93-1
Alcohol (C8-C11) poly(2.5-9)ethoxylates 2094 3 3 3 R 3 NI 1 0 (2) (2) (2) D 2
Alcohol (C9-C11) poly(2.5-9)ethoxylate 2209 CAS No
Alcohol(C12-C16) poly(1-6) ethoxylates 294 5 3 3 R 4 1 0 0 (2) 2 2 FD 2
Alcohol (C12-C16) poly(1-6) ethoxylates 77 CAS No
Alcohol(C12-C16) poly(7-19)ethoxylates 1481 4 3 3 R 4 1 1 0 (3) 3 3 D 3
Alcohol (C12-C16) poly(7-19)ethoxylates 79 CAS No
Alcohol(C12-C14)poly(2)ethoxylate sulphate, sodium salt (*) 2419 2 NI 2 R 3 NI NI NI NI NI NI NI NI
3695 CAS No
Alcohols (C8-C11) 2279 5 2 2 (R) (3) (1) (0) (0) (2) (2) (2) Fp 2
Alcohols (C8-C11), primary, linear and essentially linear 2887 CAS No
Alcohols, C13 and above as individuals and mixtures 2039 5 2 2 R 4 1 0 0 0 (1) (1) Fp 2
Alcohols (C13+) 86 CAS No
Alcohols, C10-C16 ethoxylated propoxylated (*) 2450 0 NI 0 R 3 NI NI NI NI NI NI NI NI
3868 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 3 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Alcohols (C12-C13), linear 2294 5 2 2 R 4 (1) 0 0 (1) 1 1 Fp 2
Alcohols (C12-C13), primary, linear and essentially linear 2950 CAS No
Alcohols (C14-C18), linear 2293 5 2 2 R 0 1 0 0 (1) 1 1 Fp 2
Alcohols (C14-C18), primary, linear and essentially linear 2951 CAS No
Alcohols, linear (C10-C14) 2365 (5) (2) (2) (R) (4) (1) 0 0 (2) (2) (2) Fp 2
Decyl/Dodecyl/Tetradecyl alcohol mixture 3128 CAS No
Alkanes (C6-C9) 2202 (5) NI (5) (R) (4) NI (0) (0) (1) (2) (2) N FE 2
Alkanes (C6-C9) 88 CAS No
Iso- and cyclo-alkanes (C10-C11) 2203 (5) NI (5) NI (0) (0) (0) (0) (1) (1) (0) F 1
Iso- and cyclo-alkanes (C10-C11) 393 CAS No
Iso-and cyclo-alkanes (C12+) 2204 (5) NI (5) NI (0) NI 0 0 (1) (0) (0) A NI 2
Iso- and cyclo-alkanes (C12+) 394 CAS No
n-Alkanes (C9-C11) 2449 (5) NI (5) R 0 (0) 0 0 (0) 1 0 A F 3
n-Alkanes (C9-C11) 3884 CAS No
n-Alkanes (C10-C20) 296 (5) (5) (5) (R) (0) NI (0) (0) (0) (1) (1) A Fp 3
n-Alkanes (C10-C20) 471 CAS No
Alkane (C14-C17) sulphonic acid, sodium salt (60-65% solution) 334 2 2 2 R 3 1 0 0 (2) 2 2 D 2
Sodium alkyl (C14-C17) sulphonates (60-65% solution) 1153 CAS No
Alkaryl polyether (C9-C20) (LOA) 1974 4 NI 4 NR 3 NI 0 0 (3) 2 3 S 2
Alkaryl polyethers (C9-C20) 90 CAS No
Alkenoic acid ester, borated 2376 5 (3) (3) R 2 NI 0 0 (2) 2 0 Fp 2
3153 CAS No
Alkenylamide, long chain, more than C10 1858 3 NI 3 (NR) 4 NI 0 (0) (1) 0 1 Fp 2
Alkenyl (C11+) amide 838 CAS No
Alkenyl succinic anhydride 298 0 0 0 NR 1 NI 0 0 (2) 2 (2) SsSr FD 2
Alkenyl (C16-C20) succinic anhydride 2336 CAS No
Alkyl acrylate/Vinyl pyridine copolymer in toluene 299 2 2 2 R 2 0 0 0 (2) 2 2 RNA F/Fp 3
Alkyl acrylate/vinylpyridine copolymer in toluene 94 CAS No
Alkyl/cyclo(C4-C5)alcohols 2447 (1) (1) (1) (R) (2) (0) (1) (1) (2) (2) (3) FED 3
Alkyl/cyclo (C4-C5) alcohols 3962 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 4 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Alkyl/cyclo(C4-C5)alcohols 2447 (1) (1) (1) (R) (2) (0) (1) (1) (2) (2) (3) FED 3
3825 CAS No
Alkyl amine, alkenyl acid ester, mixture 1433 NI NI NI NI 1 NI (0) (0) NI NI NI Fp 2
Alkyl(C8+)amine, Alkenyl (C12+) acid ester mixture 98 CAS No
Alkylaryl phosphate mixtures (more than 40% Diphenyl tolyl phosphate, less than 0.02% ortho-isomers) 2267 4 4 4 R 4 4 0 0 (1) 1 0 S 1
Alkylaryl phosphate mixtures (more than 40% Diphenyl tolyl phosphate, less than 0.02% ortho-isomers) 280 CAS No
Alkylated phenols (C4-C9) 2273 0 2 0 NR 1 0 1 0 (2) 1 1 Fp 2
Alkylated (C4-C9) hindered phenols 2575 CAS No
Alkylbenzene distillation bottoms 300 0 2 2 NR 0 (3) 0 0 1 1 1 Fp 2
Alkylbenzene distillation bottoms 3106 CAS No
Alkyl (C12-C15) benzene/indane/indene mixture 1872 0 4 4 NR 0 NI 0 0 0 0 2 FE 2
Alkylbenzene, alkylindane, alkylindene mixture (each C12-C17) 103 CAS No
Alkylbenzene mixtures (containing at least 50% of toluene) 2303 (2) (2) (2) (R) (3) (0) 0 0 (2) 2 2 ACMNR FE 3
Alkylbenzene mixtures (containing at least 50% of toluene) 2909 CAS No
Alkyl (C3-C4) benzenes 2206 (3) NI (3) R 4 NI 0 0 (2) (2) (1) FE 2
Alkyl (C3-C4) benzenes 91 CAS No
Alkyl (C5-C8) benzenes 2207 5 4 4 (NR) 4 NI 0 0 (2) (2) (1) F 2
Alkyl (C5-C8) benzenes 92 CAS No
Alkyl benzenes, C9-C17 (straight or branched) 1783 0 4 4 NR 1 NI 0 (0) (1) (1) (1) F 1
Alkyl(C9+)benzenes 100 CAS No
Alkylbenzenes mixture (containing less than 1% naphthalene) 2423 3 3 3 NR 4 NI 0 0 (2) 2 1 A F 3
Alkylbenzenes mixture (containing less than 1% naphthalene) 3600 CAS No
Alkylbenzenes mixtures (containing naphthalene) 2424 (3) (3) (3) (NR) (4) NI 0 0 (1) 1 1 A F 3
Alkylbenzenes mixture (containing naphthalene) 3698 CAS No
Alkylbenzenes mixtures (containing naphthalene) 2424 (3) (3) (3) (NR) (4) NI 0 0 (1) 1 1 A F 3
Alkylbenzenes mixtures (containing naphthalene) 3966 CAS No
Alkyl(C11-C13)benzenesulphonates, straight chain 301 3 3 3 R 3 1 1 (1) (3) 2 3 FD 3
Alkylbenzene sulphonic acid, sodium salt solution 102 CAS No 42615-29-2
Alkyl (C3-C11) benzenes with phenol-formaldehyde/acrylate polymers (33% or less) (#) 2517 4 NI 4 NR 2 0 0 0 (2) (2) (2) MASs F 3
Alkyl (C3-C11) benzenes with phenol-formaldehyde/acrylate polymers (33% or less) 4198 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 5 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Alkyl(branched C10-C18, C12 rich)phenols 2504 0 4 4 NR 5 3 0 0 (3) 3 3 R Fp 3
Alkylphenols (C10-C18, C12 rich) 4070 CAS No
Alkyl dithiocarbamate (C19-C35) 2236 0 NI 0 NI 1 NI 0 0 (0) 0 0 S 0
Alkyl dithiocarbamate (C19-C35) 2538 CAS No
Alkyl dithio thiadiazole (C6-C24) (LOA) 1981 5 NI 5 NR 1 NI 0 0 (0) 0 0 S 2
Alkyl dithiothiadiazole (C6-C24) 104 CAS No
Alkyl(C4-C20) ester copolymer (LOA) 1986 NI 0 0 NR 0 NI 0 0 (0) 0 0 Fp 2
Alkyl ester copolymer (C4-C20) 2202 CAS No
Alkylnaphthalenes, crude (containing less than 1% naphthalene) 2425 4 4 4 R 4 NI 0 0 (1) 1 1 AC F 3
Alkylnaphthalenes (containing less than 1% naphthalene), crude 3601 CAS No
Alkylnaphthalenes, crude (containing naphthalene) 2426 (4) (4) (4) (R) (4) NI 0 0 (1) 1 1 AC F 3
Alkylnaphthalenes (containing naphthalenes), crude 3699 CAS No
Alkyl (C7-C9) nitrates 8 4 NI 4 NR 3 NI 0 0 (3) 2 (3) F 3
Alkyl (C7-C9) nitrates 93 CAS No
Alkyl(C8-C40)phenol sulphide (LOA) 1985 0 NI 0 NR 0 NI 0 0 (1) 1 1 FD 1
Alkyl (C8-C40) phenol sulphide 2253 CAS No
Alkyl(C8-C9)phenylamine, in aromatic solvent (LOA) 2096 2 NI 2 NR 3 NI (0) (0) (2) 2 2 S 2
Alkyl (C8-C9) phenylamine in aromatic solvents 2200 CAS No
Alkyl (C9-C15) phenyl propoxylate 2188 0 NI 0 NR 0 NI 0 0 (2) 2 2 FD 2
Alkyl (C9-C15) phenyl propoxylate 2430 CAS No
Alkyl[(C8-C10)/(C12-C14)]:(<40%/>60%)polyglucoside mixture solution (max 55% active material) 2134 3 NI 3 R 3 0 0 0 (3) 2 3 D 3
Alkyl (C8-C10)/(C12-C14):(40% or less/60% or more) polyglucoside solution (55% or less) 2248 CAS No 141464-42-8
Alkyl[(C8-C10)/(C12-C14)]:(>60%/<40%)polyglucoside mixture solution (max 55% active material) 2135 3 NI 3 R 2 0 0 0 (2) 2 2 D 2
Alkyl (C8-C10)/(C12-C14):(60% or more/40% or less) polyglucoside solution(55% or less) 2246 CAS No 141464-42-8
Alkyl(C8-C10)polyglucoside solution (max 65% active material) 2136 1 NI 1 R 2 0 0 0 (2) 2 2 D 2
Alkyl (C8-C10) polyglucoside solution (65% or less) 2245 CAS No 68515-73-1
Alkyl (C8-C10)/(C12-C14):(50%/50%) polyglucoside solution (55% or less) 2133 3 NI 3 R 2 0 0 0 (3) 2 (3) D 3
Alkyl (C8-C10)/(C12-C14):(50%/50%) polyglucoside solution (55% or less) 2247 CAS No
Alkyl(C12-C14)polyglucoside solution (max 55% active material) 2137 3 NI 3 R 3 0 0 0 (3) 2 3 D 3
Alkyl (C12-C14) polyglucoside solution (55% or less) 2249 CAS No 110615-47-9
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 6 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate (#) 2480 (5) (4) (4) (NR) (2) NI (0) (0) (2) (2) (1) SD 2
Alkyl (C10-C15, C12 rich) phenol poly(4-12)ethoxylate 3953 CAS No
Alkylsulphonic acid ester of phenol (MESAMOLL) 1878 5 NI 5 NR 0 NI 0 (0) (0) 0 0 S 0
Alkyl sulphonic acid ester of phenol 1701 CAS No 91082-17-6
Alkyltoluenes 2374 0 2 2 NR 0 NI 0 (0) (1) 0 1 Fp 2
Alkyl (C18+) toluenes 3148 CAS No
Alkyl(C18-C28)toluenesulphonic acid (>90% in mineral oil) 2429 0 4 4 NR 3 NI 0 0 (3) 2 3 Ss Fp 3
Alkyl(C18-C28)toluenesulphonic acid 3658 CAS No
Alkyl(C18-C28)toluenesulphonic acid, calcium salts, borated (up to 70% in mineral oil) 2404 0 4 4 NR 0 NI (0) (0) (1) (1) (1) Ss S 2
Alkyl(C18-C28)toluenesulphonic acid, calcium salts, borated 3661 CAS No
Alkyl(C18-C28)toluenesulphonic acid, calcium salts, high overbase (up to 70% in mineral oil) 2373 (0) (4) (4) (NR) (0) NI 0 0 (0) 0 0 Ss S 2
Alkyl (C18-C28) toluenesulphonic acid, calcium salts, high overbase 3149 CAS No
Alkyl(C18-C28)toluenesulphonic acid, calcium salts, low overbase (up to 60% in mineral oil) 2409 0 4 4 NR 0 NI 0 0 (2) 2 0 Ss Fp 3
Alkyl (C18-C28) toluenesulphonic acid, calcium salts, low overbase 3685 CAS No
Allyl alcohol 28 0 0 0 R 4 NI 2 3 3 2 3 A D 3
Allyl alcohol 105 CAS No 107-18-6
Aluminium chloride/hydrogen chloride solution 336 Inorg NI 2 Inorg 3 1 1 (0) 3 (3C) 3 D 3
Aluminium chloride (30% or less)/Hydrochloric acid (20% or less) solution 110 CAS No
Aluminium hydroxide, sodium hydroxide, sodium carbonate solution (40% or less) 2438 Inorg 0 0 Inorg 3 NI 0 0 (3) 3B (3) D 3
Aluminium hydroxide, sodium hydroxide, sodium carbonate solution (40% or less) 3807 CAS No
Aluminium sulphate solution 2205 Inorg Inorg 2 Inorg 3 1 1 (0) (3) (2) (3) D 3
Aluminium sulphate solution 111 CAS No
Amides, coco, N-[3-(dibutylamino) propyl], acrylates 2513 (4) NI (4) NR 4 NI 0 0 (2) 2 2 Fp 2
4162 CAS No 851545-09-0
2-(2-Aminoethoxy) ethanol 75 0 0 0 NR 1 0 0 1 (3) 3 3 D 3
2-(2-Aminoethoxy) ethanol 37 CAS No 929-06-6
Aminoethylethanolamine 68 0 0 0 NR 1 0 0 0 (3) 3B 2 SsSr D 3
Aminoethyl ethanolamine 112 CAS No 111-41-1
Aminoethylethanolamine/Aminoethyldiethanolamine solution 74 Inorg 0 0 NR 1 0 (0) (0) (3) (3B) (2) SsSr D 3
Aminoethyldiethanolamine/Aminoethylethanolamine solution 113 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 7 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
N-Aminoethylpiperazine 88 0 0 0 NR 1 NI 0 2 (3) 3 3 Ss D 3
N-Aminoethylpiperazine 472 CAS No 140-31-8
2-Amino-2-(hydroxymethyl)-1,3-propanediol solution(40% or less) 89 0 NI 0 NI 1 NI 0 0 NI NI NI D NI
2-Amino-2-hydroxymethyl-1,3-propanediol solution (40% or less) 38 CAS No 77-86-1
2-Amino-2-methyl-1-propanol 90 0 0 0 NR 1 NI 0 0 (3) 3 3 DE 3
2-Amino-2-methyl-1-propanol 39 CAS No 124-68-5
Ammonia (anhydrous and aqueous, 28% or less) 91 0 0 0 R 3 2 1 (2) 3 3 3 DE 3
Ammonia aqueous (28% or less) 114 CAS No 7664-41-7
Ammonium bisulphite solution, greater than 15% 1730 NI NI NI NI 1 NI NI NI NI 2 2 D 2
Ammonium bisulphite solution (70% or less) 115 CAS No 10192-30-0
Ammonium chloride solution (less than 25%) 2388 0 NI 0 Inorg 1 0 0 (0) (2) 2 2 D 2
Ammonium chloride solution (less than 25%) (*) 3411 CAS No 12125-02-9
Ammonium lignosulphonate (46% solution in water) 2086 0 NI 0 NR 0 NI 0 (0) (0) 0 0 D 0
Ammonium lignosulphonate solutions 118 CAS No 8061-53-0
Ammonium nitrate solutions 1912 Inorg 0 0 Inorg 1 NI 0 0 (2) 1 2 D 2
Ammonium nitrate solution (93% or less) 119 CAS No
Ammonium polyphosphate solution 1764 Inorg 0 0 Inorg 1 NI 0 0 0 1 0 D 1
Ammonium polyphosphate solution 120 CAS No 10-34-0
Ammonium sulphate 99 0 0 0 Inorg 1 (0) 0 (0) (0) 0 0 D 0
Ammonium sulphate solution 121 CAS No 7783-20-2
Ammonium sulphide soln.(45% or less) 310 Inorg 0 0 Inorg 3 NI 1 0 (2) 2 2 N D 2
Ammonium sulphide solution (45% or less) 122 CAS No 12124-99-1
Ammonium thiocyanate/ Ammonium thiosulphate solution 1732 Inorg 0 0 Inorg 1 NI 1 NI NI NI NI D NI
Ammonium thiocyanate (25% or less)/Ammonium thiosulphate (20% or less) solution 123 CAS No
Ammonium thiosulphate solution (60% or less) 312 Inorg 0 0 Inorg 1 NI 0 (0) (1) (1) (1) D 1
Ammonium thiosulphate solution (60% or less) 124 CAS No 7783-18-8
Amyl acetate 255 2 2 2 NR 2 NI 0 (0) 0 1 1 NT FED 2
Amyl acetate (all isomers) 125 CAS No 628-63-7
tert-Amyl ethyl ether 2428 3 NI 3 NR 1 NI 0 (0) 0 2 2 E 2
tert-Amyl ethyl ether 3623 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 8 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
tert-Amyl methyl ether 2141 1 NI 1 NI 4 NI 1 0 2 0 1 ED 2
tert-Amyl methyl ether 2210 CAS No
Amyl propionate 1484 2 NI 2 R 2 NI 0 0 (2) 2 1 F 2
n-Pentyl propionate 484 CAS No 624-54-4
Aniline 261 0 0 0 R 3 2 2 2 3 1 3 CTSs NT FD 3
Aniline 127 CAS No 62-53-3
Apple juice 275 0 NI 0 R 0 0 0 0 0 0 0 D 0
Apple juice 130 CAS No
Aryl polyolefin (C11-C50) (LOA) 1979 NI NI 0 NR 0 NI 0 0 0 0 0 Fp 2
Aryl polyolefins (C11-C50) 131 CAS No
L-Aspartic acid, homopolymer, sodium salt (aqueous solution) 2421 0 0 0 NR 0 NI 0 (0) 0 0 0 D 0
L-Aspartic acid, homopolymer, sodium salt (aqueous solution) 3697 CAS No
Aviation alkylates (C8 paraffins and iso-paraffins BPt 95-120 Celcius) 286 (5) NI (5) (R) (4) NI 0 0 (0) (0) (0) FE 2
Aviation alkylates (C8 paraffins and iso-paraffins BPT 95 - 120°C) 132 CAS No
Aziridine polymer with methyloxirane (78% in diethylene glycol monoethyl ether) 2436 0 NI 0 NR 2 0 0 0 0 1 0 Fp 2
Aziridine polymer with methyloxirane (78% in diethylene glycol monoethyl ether) 3751 CAS No
Barium long chain alkaryl sulphonate (C11-C50) (LOA) 1978 4 NI 4 NR 3 NI 2 0 (2) 0 0 S 2
Barium long chain (C11-C50) alkaryl sulphonate 2370 CAS No
Benzaldehyde 2498 1 NI 1 R 3 NI 1 (1) 2 2 2 FD 2
Benzaldehyde 4132 CAS No 100-52-7
Benzene 324 2 1 1 R 2 NI 1 0 0 2 2 CTM NT E 3
Benzene and mixtures having 10% benzene or more (i) 133 CAS No 71-43-2
Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl), 4-hydroxy-C7-C9 alcohols branched and linear 2378 0 3 3 NR 3 0 0 0 (0) 0 0 Fp 2
Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl), 4-hydroxy-C7-C9 alcohols branched and linear 3405 CAS No
Benzene sulphonyl chloride 320 1 1 1 R 3 NI 1 (2) (3) 3 3 Ss SD 3
Benzene sulphonyl chloride 134 CAS No 98-09-9
1,2,4-Benzene tricarboxylic acid, trioctyl ester 1733 0 0 0 NR 0 NI 0 (0) 2 1 1 Fp 2
Benzenetricarboxylic acid, trioctyl ester 136 CAS No
Benzyl acetate 348 1 NI 1 R 3 1 1 0 2 1 1 SD 2
Benzyl acetate 138 CAS No 140-11-4
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 9 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Benzyl alcohol 349 1 NI 1 R 2 NI 1 1 2 2 2 SD 2
Benzyl alcohol 139 CAS No 100-51-6
Benzyl chloride 352 NI 1 1 R 3 1 1 (2) 3 3 3 CSsA S 3
Benzyl chloride 140 CAS No 100-44-7
Bis(2-ethylhexyl) terephthalate 2437 0 3 3 R 0 0 0 0 (1) 1 1 Fp 2
Bis(2-ethylhexyl) terephthalate 3752 CAS No
N,N-Bis(2-hydroxyethyl)oleamide (LOA) 2110 5 NI 5 NR NI NI 0 0 (2) 2 2 Fp 2
N,N-bis(2-hydroxyethyl) oleamide 2201 CAS No
Bismuth oxide 2483 Inorg (0) (0) Inorg (0) (0) 0 (0) 0 0 0 S 0
Bismuth oxide 4059 CAS No 1304-76-3
Bis[3-(triethoxysilyl)propyl]amine 2444 1 NI 1 R 1 NI 0 0 (2) 2 2 D 2
3823 CAS No 13497-18-2
Borax, anhydrous or hydrated, crude or refined 359 Inorg 0 0 Inorg 1 0 0 0 (1) 1 1 R S 3
Borax 143 CAS No 1303-96-4
Boric acid 360 Inorg 0 0 Inorg 1 0 0 (0) (1) 1 1 R S 3
Boric acid 2254 CAS No 10043-35-3
Bromochloromethane 2084 1 1 1 NR 1 NI 0 0 0 1 0 SD 1
Bromochloromethane 145 CAS No 74-97-5
1-Bromopropane 2229 2 NI 2 NI NI NI 0 (0) 0 (2) (2) SD 2
1-Bromopropane 2696 CAS No
Butanol 381 0 (0) 0 R 0 NI 0 0 0 2 3 NT D 3
n-Butyl alcohol 474 CAS No 71-36-3
Butanol 381 0 (0) 0 R 0 NI 0 0 0 2 3 NT D 3
Butyl alcohol (all isomers) 2216 CAS No 71-36-3
sec-Butanol 383 0 (0) 0 R 0 NI 0 0 0 0 2 NT D 2
sec-Butyl alcohol 638 CAS No 78-92-2
tert-Butanol 384 0 0 0 NR 1 NI 0 0 0 1 3 NT D 3
tert-Butyl alcohol 686 CAS No 75-65-0
2-Butanone 385 0 NI 0 R 1 0 0 0 1 2 2 DE 2
Methyl ethyl ketone 446 CAS No 78-93-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 10 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Butene oligomer 386 0 NI 0 NR (4) 0 0 0 0 0 1 FE 2
Butene oligomer 146 CAS No
2-Butoxyethanol/hyperbranched polyesteramide mixture 2446 NI NI (0) NR (2) NI 1 2 2 1 2 D 2
2-Butoxyethanol (58%)/Hyperbranched polyesteramide (42%) (mixture) 3901 CAS No
Butyl acetate 387 1 NI 1 R 2 NI 0 0 0 0 1 FED 2
Butyl acetate (all isomers) 147 CAS No 123-86-4
Butyl acrylate 390 2 NI 2 R 3 NI 1 1 1 2 2 SsA FED 2
Butyl acrylate (all isomers) 148 CAS No 141-32-2
Butylamine 392 0 NI 0 R 2 NI 2 2 3 3C 3 DE 3
Butylamine (all isomers) 154 CAS No 109-73-9
Butyl benzene 1774 4 NI 4 NI 4 1 0 0 (2) 2 1 Fp 2
Butylbenzene (all isomers) 155 CAS No 104-51-8
Butyl benzyl phthalate 398 4 4 4 R 4 2 0 0 (0) (0) (0) R S 3
Butyl benzyl phthalate 149 CAS No 85-68-7
Butyl butyrate 399 2 NI 2 (R) 2 NI 0 0 (1) 1 NI FE 2
Butyl butyrate (all isomers) 150 CAS No 109-21-7
Butyl/Decyl/Cetyl/Eicosyl methacrylate mixture 2295 (5) NI (5) (R) (3) NI 0 0 0 2 2 Ss FE 2
Butyl/Decyl/Cetyl/Eicosyl methacrylate mixture 153 CAS No
Butylene glycol(s) 402 0 NI 0 R 1 NI 1 0 0 0 0 D 1
Butylene glycol 156 CAS No 110-63-4
Butylene glycol methyl ether acetate 953 1 1 1 R 3 NI 0 (0) (1) 1 1 FED 1
3-Methoxybutyl acetate 58 CAS No 4435-53-4
Butylene glycol monomethyl ether 952 0 NI 0 R 1 NI 0 0 (1) 0 1 D 1
3-Methoxy-1-butanol 57 CAS No 2517-43-3
1,2-Butylene oxide 403 0 NI 0 NR 2 NI 1 1 2 2 2 C DE 3
1,2-Butylene oxide 8 CAS No 106-88-7
Butyl methacrylate 409 2 NI 2 NR 1 NI 0 0 0 2 2 Ss FE 2
Butyl methacrylate 151 CAS No 97-88-1
Butyl octyl phthalate 410 5 NI 5 (R) 0 2 0 (0) (1) (1) (1) Fp 2
Butyl octyl phthalate 2749 CAS No 84-78-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 11 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Butyl phosphate/dibutyl phosphate mixture 2434 2 NI 2 R 1 0 0 (0) (3) 2 3 D 3
Butyl phosphate/dibutyl phosphate mixture 3749 CAS No
Butyl propionate 1483 2 NI 2 R 2 NI 0 0 0 1 1 FED 2
n-Butyl propionate 476 CAS No 590-01-2
1-Butylpyrrolidin-2-one 2490 1 (1) 1 R 1 0 1 0 0 1 2 D 2
4124 CAS No 3470-98-2
Butyl stearate 413 0 NI 0 (R) 0 NI 0 NI NI 2 NI Fp 2
Butyl stearate 152 CAS No 123-95-5
Butyraldehyde 416 1 NI 1 R 2 0 0 1 0 3 3 DE 3
Butyraldehyde (all isomers) 157 CAS No 123-72-8
Butyric acid 418 0 NI 0 R 2 0 0 0 0 3A 3 D 3
Butyric acid 158 CAS No 107-92-6
Butyrolactone 420 0 NI 0 R (3) NI 1 (0) 0 0 1 C D 3
gamma-Butyrolactone 360 CAS No 96-48-0
Calcium alkyl (long chain) salicylate (overbased) in mineral oil (LOA) 70 0 NI 0 NR 2 NI 0 0 (1) (1) (1) Ss Fp 3
Calcium long-chain alkyl salicylate (C13+) 166 CAS No
Calcium alkyl phenol sulphide,polyolefin phosphorosulphide mixture (LOA) 1435 NI NI NI NR 4 NI 0 0 (0) NI NI NI NI
Calcium alkyl (C9) phenol sulphide/Polyolefin phosphorosulphide mixture 160 CAS No
Calcium alkyl salicylate 2015 3 NI 3 NR 2 NI 0 0 (2) 2 2 Fp 2
Calcium alkyl (C10-C28) salicylate 3152 CAS No
Calcium bromide (solutions) 427 Inorg NI 0 Inorg 0 0 (0) (0) (2) (1) (2) D 2
Drilling brines (containing calcium bromide) 308 CAS No 7789-41-5
Calcium carbonate slurry 2016 Inorg 0 0 Inorg 0 NI 0 (0) (0) 0 0 S 0
Calcium carbonate slurry 161 CAS No 471-34-1
Calcium hydroxide 431 Inorg 0 0 Inorg 2 NI 0 (0) (2) 1 2 S 2
Calcium hydroxide slurry 162 CAS No 1305-62-0
Calcium hypochlorite solutions containing 15% Ca(OCl)2 or more 432 Inorg 0 0 Inorg 5 NI 1 0 2 3A 3 D 3
Calcium hypochlorite solution (more than 15%) 164 CAS No 7778-54-3
Calcium hypochlorite solutions containing less than 15% but more than 1.5% Ca(OCl)2 2073 Inorg 0 0 Inorg (4) NI 1 0 2 3A 3 D 3
Calcium hypochlorite solution (15% or less) 163 CAS No 7778-54-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 12 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Calcium lignosulphonate (52% solution in water) 2087 0 NI 0 NR 0 NI 0 (0) (0) 0 0 D 0
Calcium lignosulphonate solutions 165 CAS No 8061-52-7
Calcium long chain alkaryl sulphonate (C11-C50) (LOA) 1973 NI 0 0 NR 0 NI 0 0 (1) 1 1 FD 1
Calcium alkaryl sulphonate (C11-C50) 169 CAS No
Calcium long chain alkyl (C5-C10) phenate (LOA) 2106 0 NI 0 NR 2 NI 0 0 (0) 0 0 FD 1
Calcium long-chain alkyl (C5-C10) phenate 168 CAS No
Calcium long chain alkyl (C11-C40) phenate (LOA) 2097 0 NI 0 NR 0 NI 0 0 (1) 1 1 Fp 2
Calcium long-chain alkyl (C11-C40) phenate 167 CAS No
Calcium long chain alkyl phenate sulphide (C8-C40) (LOA) 1756 0 NI 0 NR 1 NI 0 0 (1) 1 1 Fp 2
Calcium long-chain alkyl phenate sulphide (C8-C40) 170 CAS No
Calcium long-chain alkyl phenolic amine (C8-C40) 1728 NI NI NI NR 0 NI 0 0 (1) 1 (1) Fp 2
171 CAS No
Calcium long-chain alkyl (C18-C28) salicylate 2383 0 NI 0 NR 0 NI 0 0 (1) 1 0 Ss Fp 3
Calcium long-chain alkyl (C18-C28) salicylate 3426 CAS No
Calcium nitrate 1803 Inorg 0 0 Inorg 0 NI 0 (0) (1) 1 1 D 1
Calcium nitrate solutions (50% or less) 172 CAS No 10124-37-5
Calcium nitrate/ Magnesium nitrate/Potassium chloride solution 1734 Inorg 0 0 Inorg 1 0 0 (0) (1) (1) 1 D 1
Calcium nitrate/Magnesium nitrate/Potassium chloride solution 173 CAS No
Camelina oil 2440 (0) NI (0) (R) (0) (0) (0) (0) (1) (0) (1) Fp 2
Camelina oil 3767 CAS No 68956-68-3
Camphor oil, white 1897 NI NI NI NI NI NI 2 NI (2) 1 NI (T) FE 2
Camphor oil 174 CAS No 8008-51-3
Caprolactam 436 0 NI 0 R 1 0 1 1 2 1 2 D 3
epsilon-Caprolactam (molten or aqueous solutions) 310 CAS No 105-60-2
Carbolic oil 437 (3) 3 (3) (NR) (3) (1) 2 2 3 3 3 ATNCM FED 3
Carbolic oil 176 CAS No
Carbon disulphide 439 2 1 1 NR 3 NI 2 (3) 4 3A 3 RN SD 3
Carbon disulphide 177 CAS No 75-15-0
Cashew nut shell oil (untreated) 443 0 NI 0 R 0 NI (0) (0) (2) 2 (2) Ss Fp 3
Cashew nut shell oil (untreated) 179 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 13 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Castor oil (containing less than 10% free fatty acids) 2314 0 NI 0 R (2) NI 0 0 (1) 1 1 Fp 2
Castor oil 3044 CAS No
Cesium Formate, drilling brines 2384 0 3 3 Inorg 2 NI 1 0 (2) 2 2 D 2
Cesium formate solution (*) 3421 CAS No 3495-36-1
Cetyl/Eicosyl methacrylate (mixture) 445 0 NI 0 (NR) (0) NI 0 (0) (1) (1) (1) Fp 2
Cetyl/Eicosyl methacrylate mixture 180 CAS No
Chlorinated paraffins (C18 and above) with any level of chlorine 2024 0 4 4 NR 0 2 0 0 (1) (1) (1) C S 3
Chlorinated paraffins (C18+) with any level of chlorine 183 CAS No
Chlorinated paraffins (C10-C13) with 60% chlorine or more 2021 5 5 5 NR 5 2 0 0 (1) 1 1 C S 3
Chlorinated paraffins (C10-C13) 181 CAS No
Chlorinated paraffins (C10- C13) with less than 60% chlorine 2020 5 5 5 NR 5 3 (0) (0) (1) (1) (1) C S 3
Chlorinated paraffins (C10-C13) (60% chlorine or less) 2832 CAS No
Chlorinated paraffins (C14-C17) with less than 1% shorter chain length 2112 5 4 4 NR 6 3 0 0 (2) 2 2 C S 3
Chlorinated paraffins (C14-C17) (with 50% chlorine or more, and less than 1% C13 or shorter chains) 182 CAS No
Chloroacetic acid 450 0 NI 0 R 2 0 2 3 (4) 3C 3 A D 3
Chloroacetic acid (80% or less) 184 CAS No 79-11-8
Chlorobenzene 456 2 2 2 NR 3 0 1 0 2 2 0 S 2
Chlorobenzene 185 CAS No 108-90-7
Chlorohydrins 463 0 NI 0 R 0 NI (2) (2) (3) (3A) 3 C D 3
Chlorohydrins (crude) 187 CAS No 96-24-2
N-(3-Chloro-2-hydroxypropyl) trimethylammonium chloride solution (75% or less) 2286 0 0 0 NR 1 NI 0 0 (2) 0 (2) C D 3
N-(3-Chloro-2-hydroxypropyl)trimethyl ammonium chloride solution (75% or less) 2579 CAS No
4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt solution 1536 2 NI 2 NI 2 NI 1 0 2 1 1 S 2
4-Chloro-2-methylphenoxyacetic acid, dimethylamine salt solution 62 CAS No
Chloronitrobenzenes 467 2 2 2 NR 3 NI 2 2 2 1 1 S 2
o-Chloronitrobenzene 533 CAS No 25167-93-5
1-(4-Chlorophenyl)-4,4-dimethyl-3-pentanone 1772 3 3 3 NR 3 NI 0 0 (1) 1 0 S 1
1-(4-Chlorophenyl)-4,4- dimethyl-pentan-3-one 21 CAS No
2-Chloropropionic acid 474 0 NI 0 R 1 NI 1 (3) 2 3A 3 D 3
2- or 3-Chloropropionic acid 36 CAS No 598-78-7
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 14 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
3-Chloropropylene 478 1 1 1 R 3 NI 1 0 2 1 3 T E 3
Allyl chloride 106 CAS No 107-05-1
Chlorosulphonic acid 479 Inorg 0 0 Inorg 2 NI (2) (3) 4 3C 3 D 3
Chlorosulphonic acid 188 CAS No 7790-94-5
m-Chlorotoluene 481 3 NI 3 NR 2 NI 2 0 (2) 1 1 S 2
m-Chlorotoluene 426 CAS No 108-41-8
o-Chlorotoluene 480 3 3 3 NR 3 1 0 0 0 1 1 S 1
Chlorotoluenes (mixed isomers) 189 CAS No 95-49-8
o-Chlorotoluene 480 3 3 3 NR 3 1 0 0 0 1 1 S 1
o-Chlorotoluene 534 CAS No 95-49-8
p-Chlorotoluene 482 3 3 3 NR 3 0 0 0 0 1 1 S 2
p-Chlorotoluene 551 CAS No 106-43-4
Choline chloride, solutions 485 0 NI 0 R 1 NI 0 (0) (0) 0 0 D 0
Choline chloride solutions 190 CAS No 67-48-1
Cinnamaldehyde 2485 1 (2) (2) R 2 0 1 1 (2) 2 1 Ss SD 2
Cinnamaldehyde 4061 CAS No 104-55-2
Citric acid 493 0 NI 0 R 1 0 0 (0) (3) 1 3 D 3
Citric acid (70% or less) 748 CAS No 77-92-9
Citric juices 494 0 0 0 Inorg 0 0 0 0 0 0 0 D 0
Water 740 CAS No
Clay 495 Inorg 0 0 Inorg 0 0 0 0 0 0 0 S 0
Clay slurry 191 CAS No
Coal slurry 498 Inorg 0 0 Inorg 0 0 0 0 0 0 0 S 0
Coal slurry 192 CAS No
Coal tar 499 (4) 4 4 NR 3 1 0 0 0 2 2 CMR (T) S 3
Coal tar 193 CAS No 8007-45-2
Coal tar naphtha 500 3 NI 3 NR 3 NI 0 0 (1) 1 1 C (T) FE 3
Coal tar naphtha solvent 194 CAS No 8030-30-6
Coal tar pitch (molten) 491 3 (3) (3) NR (4) (2) 0 0 (1) 1 0 CM S 3
Coal tar pitch (molten) 195 CAS No 65996-93-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 15 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Cobalt naphthenate in solvent naphtha 501 NI NI NI NR 3 NI 0 (0) (1) NI 1 C FE 3
Cobalt naphthenate in solvent naphtha 196 CAS No
Cocoa butter 2342 0 NI 0 R 0 NI (0) (0) (1) (0) (1) Fp 2
Cocoa butter 3096 CAS No
Coconut acid oil 2370 0 0 0 R 3 NI (0) (0) (1) (1) (1) Fp 2
Coconut acid oil 3139 CAS No
Coconut fatty acid distillate 2366 0 NI 0 R (3) NI 0 (0) (1) (1) (1) Fp 2
Coconut fatty acid distillate 3130 CAS No
Coconut oil 503 0 NI 0 R 1 NI 0 (0) (1) 0 (1) Fp 2
Coconut oil 2772 CAS No 8001-31-8
Coconut oil fatty acid 505 0 0 0 (R) (3) NI 0 (0) (1) (1) (1) Fp 2
Coconut oil fatty acid 197 CAS No 61788-47-4
Coconut oil fatty acid methyl ester 506 5 0 0 R 0 NI (0) (0) (0) (0) (1) Fp 2
Coconut oil fatty acid methyl ester 198 CAS No 61788-59-8
Copper salt of long chain(>C17) alkanoic acid (LOA) 2111 0 NI 0 (R) 2 NI 0 0 (0) 0 0 Fp 2
Copper salt of long chain (C17+) alkanoic acid 2214 CAS No
Corn oil 521 0 NI 0 R (2) NI 0 (0) (1) 1 1 Fp 2
Corn Oil 2781 CAS No 8001-30-7
Cotton seed oil 523 0 NI 0 R (2) NI (0) (0) (1) 0 1 Fp 2
Cotton seed oil 2783 CAS No 8001-29-4
Creosote (coal tar) 524 (4) (4) (4) NR 4 (2) 1 0 2 2 1 CMRSs (T) S 3
Creosote (coal tar) 199 CAS No 8001-58-9
Creosote (wood tar) 525 NI NI NI NR 5 NI 1 0 2 2 1 CM (T) SD 3
Creosote (wood) 200 CAS No 8021-39-4
Creosote (coal tar) C8-C22, MW 116-278 2514 NI (3) (3) (NR) 4 1 1 0 (2) 2 1 CMRSs S 3
Creosote (coal tar) (C8-C22, MW 116-278) 4163 CAS No
Cresol/Phenol/Xylenol mixture 2471 (2) (2) (2) R (3) (1) 1 2 3 3B 3 SD 3
Cresol/Phenol/Xylenol mixture 4021 CAS No
Cresols (mixed isomers) 527 2 2 2 R 3 (1) 2 2 4 3A 3 T SD 3
Cresols (all isomers) 201 CAS No 1319-77-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 16 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Cresylic acids, dephenolized 1875 2 2 2 R 3 0 (2) (2) (3) (3A) (3) (T) S 3
Cresylic acid, dephenolized 202 CAS No
Cresylic acid, sodium salt solution 1914 (2) (2) (2) (R) (3) (0) 1 (1) (3) 3 3 TCM (T) D 3
Cresylic acid, sodium salt solution 203 CAS No
Crotonaldehyde 528 0 NI 0 NR 4 1 2 4 4 2 3 D 3
Crotonaldehyde 204 CAS No 4170-30-3
Crude Piperazine 2331 0 NI 0 R 2 NI (1) (2) (3) 3 3 SsSr D 3
Crude Piperazine 2810 CAS No
Crude Tall Oil 2357 4 NI 4 R 2 0 0 0 (0) 0 0 Ss Fp 3
Tall oil, crude 3118 CAS No
1,5,9-Cyclododecatriene 534 5 5 5 NR 4 NI 0 0 1 2 1 A F 3
1,5,9-Cyclododecatriene 17 CAS No 4904-61-4
Cycloheptane 535 4 NI 4 (NR) 4 NI (0) 0 (1) (0) (1) FE 2
Cycloheptane 205 CAS No 291-64-5
Cyclohexane 536 3 3 3 NR 3 NI 0 0 1 0 1 E 2
Cyclohexane 206 CAS No 110-82-7
Cyclohexane-1,2-dicarboxylic acid, diisononyl ester 2472 0 3 3 R 0 0 0 0 (1) 1 0 Fp 2
Cyclohexane-1,2-dicarboxylic acid, diisononyl ester 3915 CAS No 166412-78-8
Cyclohexane oxidation products, sodium salts solution 2458 0 NI 0 Inorg 1 0 0 (0) (0) 0 0 D 0
Cyclohexane oxidation products, sodium salts solution 3739 CAS No
Cyclohexanol 537 1 NI 1 R 2 NI 0 0 0 2 2 Fp 2
Cyclohexanol 207 CAS No 108-93-0
Cyclohexanone 539 0 1 1 R 1 0 1 1 1 2 2 FED 2
Cyclohexanone 208 CAS No 108-94-1
Cyclohexanone/Cyclohexanol mixture 1436 1 1 1 R 2 NI 1 1 1 2 2 FED 2
Cyclohexanone, Cyclohexanol mixture 209 CAS No
Cyclohexyl acetate 541 2 NI 2 (R) (2) NI 0 0 (2) 2 1 FED 2
Cyclohexyl acetate 210 CAS No 622-45-7
Cyclohexylamine 542 1 NI 1 R 2 NI 2 2 3 3 3 D 3
Cyclohexylamine 211 CAS No 108-91-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 17 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
1,3-Cyclopentadiene dimer (molten) 545 3 3 3 NR 3 NI 2 0 2 2 2 Fp 2
1,3-Cyclopentadiene dimer (molten) 11 CAS No 77-73-6
Cyclopentane 546 3 NI 3 NR 3 NI (0) (0) 0 1 (1) E 2
Cyclopentane 212 CAS No 287-92-3
Cyclopentene 547 2 NI 2 (R) 3 NI 1 1 0 (2) (0) A E 2
Cyclopentene 213 CAS No 142-29-0
Decahydronaphthalene 551 4 4 4 NR 3 NI 0 0 2 2 1 F 1
Decahydronaphthalene 214 CAS No 91-17-8
Decane 554 5 NI 5 R 0 0 0 0 0 1 0 F 1
Decane 2620 CAS No 124-18-5
Decanoic acid 555 4 NI 4 R 4 1 0 0 (2) 2 2 Fp 2
Decanoic acid 215 CAS No 334-48-5
1-Decene 558 5 NI 5 R 4 2 0 0 0 2 0 A F 3
Decene 216 CAS No 872-05-9
Decyl acetate 1767 4 NI 4 NI NI NI 0 0 (1) (1) (1) F 1
Decyl acetate 217 CAS No 112-17-4
Decyl acrylate 559 5 NI 5 (R) 5 NI 0 0 (2) 2 1 Fp 2
Decyl acrylate 218 CAS No 2156-96-9
Decyloxytetrahydrothiophene dioxide 1859 3 NI 3 NR 4 NI 0 0 (1) 1 0 Fp 2
Decyloxytetrahydrothiophene dioxide 220 CAS No
Dextrose solution 562 0 0 0 R 0 NI 0 0 0 0 (0) D 0
Glucose solution 361 CAS No 50-99-7
Dextrose solution 562 0 0 0 R 0 NI 0 0 0 0 (0) D 0
Dextrose solution 221 CAS No 50-99-7
Diacetone alcohol 563 0 NI 0 R 1 0 0 0 (2) 2 2 D 2
Diacetone alcohol 226 CAS No 123-42-2
Dialkyldiphenylamines (LOA) 1852 5 NI 5 NR 1 0 0 0 (0) 0 0 FD 0
Dialkyl (C8-C9) diphenylamines 2255 CAS No
Dialkyl (C9 - C10) phthalates 2359 (0) (0) (0) (R) (0) (0) (0) (0) (1) (1) (1) Fp 2
Dialkyl (C9 - C10) phthalates 3121 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 18 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Dialkyl phthalates C9-C13 566 (0) (4) (4) (NR) (0) (2) (0) (0) (1) (1) (1) R Fp 3
Dialkyl (C7-C13) phthalates 227 CAS No
2,6-Diaminohexanoic acid phosphonate mixed salts solution (#) 2469 1 NI 1 NR 1 (0) (1) (1) (3) (3) (3) D 3
2,6-Diaminohexanoic acid phosphonate mixed salts solution 3989 CAS No
Diammonium hydrogen phosphate 98 0 0 0 Inorg 1 NI 0 0 (0) (1) (1) D 1
Ammonium hydrogen phosphate solution 117 CAS No 7783-28-0
Dibromomethane 574 1 NI 1 NR (2) NI 1 0 0 (2) (2) SD 2
Dibromomethane 228 CAS No 74-95-3
Di-n-butylamine 577 2 NI 2 R 3 NI 2 2 3 3 3 FD 3
Dibutylamine 231 CAS No 111-92-2
Di-butyl ether 578 3 3 3 NR 2 NI 0 0 0 1 1 FE 2
n-Butyl ether 475 CAS No 142-96-1
Dibutyl hydrogen phosphonate 1857 1 NI 1 NI 2 NI 0 0 (3) 3 3 F 3
Dibutyl hydrogen phosphonate 229 CAS No 1809-19-4
2,4-Di-tert-butyl phenol 2083 5 4 4 NR 4 NI NI NI NI NI NI NI NI
2,4-Di-tert-butylphenol 2339 CAS No 96-76-4
2,6-Di-tert-butyl phenol 2082 4 NI 4 NR 4 NI 0 0 (1) 1 1 Fp 2
2,6-Di-tert-butylphenol 2250 CAS No 128-39-2
Di-n-butyl phthalate 582 4 4 4 R 4 1 0 0 1 0 1 R S 3
Dibutyl phthalate 230 CAS No 84-74-2
Dibutyl terephthalate 2430 5 (3) (3) R 4 2 0 0 (0) 0 0 S 0
Dibutyl terephthalate 3596 CAS No
Dichlorobenzene (all isomers) 333 3 4 4 NR 3 1 1 0 1 (2) 2 CMR T S 3
Dichlorobenzene (all isomers) 232 CAS No
3,4-Dichlorobut-1-ene 2079 2 2 2 NR 3 NI 1 0 2 2 3 S 3
3,4-Dichloro-1-butene 56 CAS No 760-23-6
1,1-Dichloroethane 590 1 NI 1 NR 1 NI 1 (1) 0 2 2 SD 2
1,1-Dichloroethane 4 CAS No 75-34-3
1,2-Dichloroethane 591 1 1 1 NR 2 0 1 0 2 1 2 C SD 3
Ethylene dichloride 330 CAS No 107-06-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 19 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
1,6-Dichlorohexane 593 3 NI 3 NR 3 NI 0 (0) (0) 0 0 S 0
1,6-Dichlorohexane 19 CAS No 2163-00-0
Dichloromethane 594 1 2 2 NR 1 0 1 0 0 2 2 C SD 3
Dichloromethane 234 CAS No 75-09-2
2,4-Dichlorophenol 596 3 2 2 NR 3 2 3 2 3 3 3 T S 3
2,4-Dichlorophenol 30 CAS No 120-83-2
2,4-Dichlorophenoxyacetic acid, diethanolamine salt, solution 599 0 1 1 R 2 NI 1 0 (3) 1 3 (T) D 3
2,4-Dichlorophenoxyacetic acid, diethanolamine salt solution 32 CAS No
2,4-Dichlorophenoxyacetic acid, dimethylamine salt, 70 % or less solution 600 0 1 1 R 3 NI 1 0 (3) 1 3 (T) D 3
2,4-Dichlorophenoxyacetic acid, dimethylamine salt solution (70% or less) 33 CAS No
2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt soln. 602 0 NI 0 R 2 NI 1 0 (3) (1) 3 (T) D 3
2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt solution 34 CAS No
1,1-Dichloropropane 605 2 1 1 NR 2 1 0 0 1 1 1 SD 1
1,1-Dichloropropane 5 CAS No 78-99-9
1,2-Dichloropropane 606 2 1 1 NR 2 0 1 0 2 2 2 SD 2
1,2-Dichloropropane 9 CAS No 78-87-5
1,3-Dichloropropane 607 2 1 1 NR 2 1 0 NI NI NI NI SD NI
1,3-Dichloropropane 12 CAS No 142-28-9
Dichloropropane and dichloropropene, mixture 608 (2) (1) (1) (NR) (4) (1) 2 1 2 3 3 CSs SD 3
Dichloropropene/Dichloropropane mixtures 235 CAS No 8003-19-8
1,3-Dichloropropene 612 1 NI 1 NR 4 1 2 1 2 3 3 CSs SD 3
1,3-Dichloropropene 13 CAS No 542-75-6
2,2-Dichloropropionic acid 609 2 2 2 NR 2 NI 1 0 (3) 3 3 D 3
2,2-Dichloropropionic acid 28 CAS No 75-99-0
Di-(2-chloro-iso-propyl) ether 615 2 2 2 NR 2 NI 2 0 2 0 2 SD 2
2,2'-Dichloroisopropyl ether 25 CAS No 108-60-1
Dicyclopentadiene(80-90%)/Co-dimers(10-20%), mixtures 2389 2 3 3 NR 3 0 2 0 3 2 2 AR FED 3
Dicyclopentadiene, Resin Grade, 81-89% 3559 CAS No
Diethanolamine 620 0 NI 0 R 1 0 1 0 0 2 3 T D 3
Diethanolamine 236 CAS No 111-42-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 20 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Diethylamine 621 0 NI 0 R 2 NI 1 2 3 3C 3 DE 3
Diethylamine 240 CAS No 109-89-7
2,6-Diethylaniline 1437 3 3 3 NR 2 NI 1 1 (2) 1 2 FD 2
2,6-Diethylaniline 35 CAS No 579-66-8
Diethyl benzene (mixed isomers) 624 4 4 4 NR 3 NI 0 (0) (2) 2 1 F 2
Diethylbenzene 242 CAS No 25340-17-4
Di-(2-ethylbutyl) phthalate 625 5 NI 5 R 0 2 0 0 (1) 1 (1) R Fp 3
Di-(2-ethylbutyl) phthalate 2750 CAS No 84-75-3
Diethylene glycol 628 0 NI 0 R 0 0 1 0 2 1 1 D 2
Diethylene glycol 243 CAS No 111-46-6
Diethylene glycol di-n-butyl ether 629 2 NI 2 NI 1 NI 0 0 (1) 1 1 FD 1
Diethylene glycol dibutyl ether 244 CAS No 112-73-2
Diethylene glycol diethyl ether 630 0 NI 0 NR 0 NI 1 0 (2) (2) 2 D 2
Diethylene glycol diethyl ether 245 CAS No 112-36-7
Diethylene glycol initiated polyoxypropylene diamine 2353 0 NI 0 NR 2 NI 0 0 (3) 3B (3) D 3
Polyetheramine 2946 CAS No
Diethylene glycol initiated polyoxypropylene diamine 2353 0 NI 0 NR 2 NI 0 0 (3) 3B (3) D 3
Diethylene glycol initiated polyoxypropylene diamine 3113 CAS No
Diethylene glycol phthalate 1438 2 NI 2 NR 1 NI 0 0 (2) (1) 2 S 2
Diethylene glycol phthalate 247 CAS No
Diethylene triamine 638 0 1 1 (R) 2 NI 1 3 3 3A 3 Ss FD 3
Diethylenetriamine 248 CAS No 111-40-0
Diethylenetriamine pentaacetic acid, pentapotassium salt solution (40%) (**) 2466 1 NI 1 NR 2 NI NI NI NI NI NI D NI
Diethylenetriamine pentaacetic acid, pentapotassium salt (40% solution) 3929 CAS No
Diethylenetriamine pentaacetic acid, pentasodium salt (40% solution in water) 2076 0 NI 0 NR 0 NI 0 (0) (0) 0 0 D 0
Diethylenetriaminepentaacetic acid, pentasodium salt solution 249 CAS No
Diethylenetriamine pentamethylene phosphonic acid, pentasodium salt solution (47 %) (**) 2467 0 NI 0 R 2 NI NI NI NI NI NI D NI
Diethylenetriamine pentamethylene phosphonic acid, pentasodium salt solution 3930 CAS No
Diethyl ethanolamine 622 0 NI 0 NR 3 NI 1 1 2 3 3 D 3
Diethylaminoethanol 241 CAS No 100-37-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 21 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Diethyl ether 640 0 1 1 NR 0 NI 1 0 0 1 1 DE 2
Diethyl ether 237 CAS No 60-29-7
Di-(2-ethylhexyl) adipate 641 0 2 2 R 4 2 0 0 0 1 1 R Fp 3
Di-(2-ethylhexyl) adipate 222 CAS No 103-23-1
Di-(2-ethylhexyl) phosphoric acid 643 (2) 1 1 NR 2 NI 0 1 (2) 2 2 Fp 2
Di-(2-ethylhexyl) phosphoric acid 223 CAS No 298-07-7
Di-(2-ethylhexyl) phthalate 642 0 4 4 R 0 0 0 0 1 1 1 R Fp 3
Di-(2-ethylhexyl) phthalate 2751 CAS No 117-81-7
Diethyl phthalate 648 3 3 3 R 2 0 0 0 (1) 1 1 S 1
Diethyl phthalate 238 CAS No 84-66-2
Diethyl sulphate 649 1 NI 1 R (2) NI 1 2 3 2 3 CM SD 3
Diethyl sulphate 239 CAS No 64-67-5
Diglycidyl ether of Bisphenol A 653 3 NI 3 NR 4 NI 0 0 (2) 1 2 Ss S 2
Diglycidyl ether of bisphenol A 250 CAS No 1675-54-3
Diglycidyl ether of Bisphenol F 728 0 NI 0 NR 3 NI 0 (0) (2) 1 (2) SsR S 3
Diglycidyl ether of bisphenol F 251 CAS No 55492-52-9
Diheptyl phthalate 655 0 (4) (4) R 0 NI 0 0 (1) 1 1 Fp 3
Diheptyl phthalate 252 CAS No 3648-21-3
Di-n-hexyl adipate 656 5 NI 5 (NR) 5 0 0 0 (1) 0 1 FE 1
Di-n-hexyl adipate 224 CAS No 110-33-8
Di-hexyl phthalate 2125 5 NI 5 R 0 2 0 0 (1) 1 1 R Fp 3
Dihexyl phthalate 253 CAS No 84-75-3
1,4-Dihydro-9,10-dihydroxy anthracene disodium salt (soln.) 657 1 NI 1 NI 1 NI 0 NI NI NI NI D NI
1,4-Dihydro-9,10-dihydroxyanthracene, disodium salt solution 15 CAS No
Diisobutene 575 4 4 4 NR 3 NI 0 0 0 1 0 FE 2
Diisobutylene 257 CAS No 11071-47-9
Diisobutylamine 576 (2) NI (2) (R) (3) NI 2 (2) 2 (3) (3) FED 3
Diisobutylamine 256 CAS No 110-96-3
Diisobutyl ketone 579 3 NI 3 R 2 NI 0 0 2 2 2 F 2
Diisobutyl ketone 254 CAS No 108-83-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 22 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Diisobutyl phthalate 581 4 (4) 4 R (4) 1 0 0 1 0 0 R S 3
Diisobutyl phthalate 255 CAS No 84-69-5
Diisodecyl phthalate 619 0 0 0 (R) 0 (0) 0 0 (1) 0 1 Fp 2
Diisodecyl phthalate 3119 CAS No 26761-40-0
Diisoheptyl phthalate 2391 0 (4) (4) R 0 0 0 0 (1) 1 1 R Fp 3
Diisoheptyl phthalate 3561 CAS No
Diisononyl adipate 690 0 NI 0 R 0 0 0 0 (1) 1 1 Fp 2
Diisononyl adipate 258 CAS No 33703-08-1
Diisononyl phthalate 691 0 0 0 R 0 0 0 0 (0) 0 0 Fp 2
Diisononyl phthalate 3120 CAS No
Diisooctyl phthalate 693 0 4 4 (R) 0 0 0 0 (1) 1 0 Fp 2
Diisooctyl phthalate 259 CAS No 27554-26-3
Diisopropanolamine 703 0 NI 0 NR 1 NI 0 0 0 2 3 FD 3
Diisopropanolamine 260 CAS No 110-97-4
Diisopropylamine 705 1 NI 1 NR 2 0 1 1 2 3 3 ED 3
Diisopropylamine 261 CAS No 108-18-9
Diisopropyl benzene (mixed isomers) 2220 5 4 4 NR 4 NI 0 0 2 2 1 (T) F 2
Diisopropylbenzene (all isomers) 262 CAS No
1,3-Diisopropylbenzene 706 5 4 4 NR 4 NI 0 0 2 2 1 F 2
1,3-Diisopropyl benzene 2626 CAS No 25321-09-9
Diisopropyl ether 711 1 NI 1 NR 2 NI 0 0 0 1 2 E 2
Isopropyl ether 406 CAS No 108-20-3
Diisopropylnaphthalene, mixed isomers 712 5 4 4 NR 3 NI 0 0 (1) 1 1 Fp 2
Diisopropylnaphthalene 263 CAS No 38640-62-9
Dimethyl acetamide 658 0 NI 0 R 1 NI 0 0 2 1 2 D 2
N,N-Dimethylacetamide 2730 CAS No 127-19-5
Dimethyl acetamide 658 0 NI 0 R 1 NI 0 0 2 1 2 D 2
N,N-Dimethylacetamide solution (40% or less) 466 CAS No 127-19-5
Dimethyl adipate 659 1 NI 1 (R) 4 NI 0 0 (0) 1 1 SD 2
Dimethyl adipate 264 CAS No 627-93-0
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 23 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Dimethylamine (40-50% aq.sol.) 661 0 NI 0 R 3 0 2 0 2 3B 3 Ss NT DE 3
Dimethylamine solution (greater than 55% but not greater than 65%) 272 CAS No 124-40-3
Dimethylamine (40-50% aq.sol.) 661 0 NI 0 R 3 0 2 0 2 3B 3 Ss NT DE 3
Dimethylamine solution (greater than 45% but not greater than 55%) 271 CAS No 124-40-3
Dimethylamine (40-50% aq.sol.) 661 0 NI 0 R 3 0 2 0 2 3B 3 Ss NT DE 3
Dimethylamine solution (45% or less) 270 CAS No 124-40-3
N,N-Dimethyl cyclohexylamine 665 2 NI 2 NR 2 NI 1 2 3 3C 3 FD 3
N,N-Dimethylcyclohexylamine 467 CAS No 98-94-2
Dimethyl disulphide 1616 1 NI 1 NR 3 2 2 0 2 1 1 SD 2
Dimethyl disulphide 2504 CAS No 624-92-0
N,N-Dimethyldodecylamine 2126 3 NI 3 R 4 NI 1 (1) (3) 3 3 F 3
N,N-Dimethyldodecylamine 468 CAS No 112-18-5
Dimethylethanolamine 667 0 NI 0 R 2 NI 1 1 2 3 3 D 3
Dimethylethanolamine 273 CAS No 108-01-0
Dimethyl formamide 676 0 0 0 R 1 0 0 1 2 1 2 R D 3
Dimethylformamide 274 CAS No 68-12-2
Dimethyl glutarate 670 0 NI 0 R 3 NI 0 0 2 3 2 A SD 3
Dimethyl glutarate 265 CAS No 26717-67-9
Dimethyl hydrogen phosphite 673 0 NI 0 NR 2 NI 1 0 0 1 1 D 1
Dimethyl hydrogen phosphite 266 CAS No 868-89-9
2,2-Dimethyloctanoic acid 675 3 NI 3 R 4 1 0 0 (2) 2 2 Fp 2
Dimethyl octanoic acid 267 CAS No 29662-90-6
Dimethyl phthalate 678 2 2 2 R 2 0 0 0 (1) 0 1 SD 1
Dimethyl phthalate 268 CAS No 131-11-3
2,2-Dimethylpropane-1,3-diol 679 0 0 0 NR 0 0 0 0 0 2 2 FD 2
2,2-Dimethylpropane-1,3-diol (molten or solution) 29 CAS No 126-30-7
Dimethyl succinate 681 0 NI 0 NI 2 NI 0 0 0 0 2 SD 2
Dimethyl succinate 269 CAS No 106-65-0
Dinitrotoluene 688 2 2 2 NR 4 2 2 (2) (2) 1 0 CMR S 3
Dinitrotoluene (molten) 276 CAS No 25321-14-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 24 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Dinonyl phthalate 689 0 NI 0 R 0 0 0 0 (1) 1 1 Fp 2
Dinonyl phthalate 2993 CAS No 84-76-4
Di-n-octyl phthalate 692 0 (4) (4) (R) 0 0 0 0 (1) 1 (1) Fp 2
Dioctyl phthalate 277 CAS No 117-84-0
1,4-Dioxane 682 0 0 0 NR 0 0 0 0 0 0 2 C D 3
1,4-Dioxane 16 CAS No 123-91-1
Dipentene 686 4 NI 4 NR 2 NI 0 0 (2) 2 2 Ss F 3
Dipentene 278 CAS No 138-86-3
Diphenyl 694 3 4 4 R 4 1 0 0 (1) 0 1 S 1
Diphenyl 279 CAS No 92-52-4
Diphenylamine (molten) 2186 3 3 3 NR 3 1 0 0 (1) 1 1 S 1
Diphenylamine (molten) 285 CAS No
Diphenylamine, reaction product with 2,4,4-trimethylpentene 1500 NI 1 1 NR 3 NI 0 0 (1) 1 1 Fp 2
Diphenylamine, reaction product with 2,2,4-Trimethylpentene 286 CAS No
Diphenylamines, alkylated 1770 5 NI 5 NR (3) NI 0 0 (1) (1) (1) F 2
Diphenylamines, alkylated 287 CAS No
Diphenyl/Diphenyl ether (mixtures) 698 NI NI 4 NR 4 1 0 0 (1) 1 1 (T) S 1
Diphenyl/Diphenyl ether mixtures 283 CAS No 8004-13-5
Diphenyl ether 699 4 4 4 NR 4 NI 0 0 0 1 1 T S 1
Diphenyl ether 281 CAS No 101-84-8
Diphenyl ether/ Biphenyl phenyl ether mixtures 702 5 NI 5 NR 4 NI 0 0 0 1 1 (T) S 1
Diphenyl ether/Diphenyl phenyl ether mixture 282 CAS No
Diphenylmethane-4,4'-diisocyanate (#) 700 5 2 2 NR 0 0 0 0 3 2 2 SsSr S 3
Diphenylmethane diisocyanate 288 CAS No 101-68-8
Diphenylol propane-epichlorohydrin resins 2237 3 NI 3 NR 4 NI 0 0 (2) 1 2 S 2
Diphenylol propane-epichlorohydrin resins 290 CAS No
Di-n-propylamine 704 1 NI 1 NR 3 NI 2 2 2 3C 3 FED 3
Di-n-propylamine 225 CAS No 142-84-7
Dipropylene glycol 707 0 1 1 R 0 NI 0 0 0 0 1 D 1
Dipropylene glycol 291 CAS No 25265-71-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 25 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Dipropylene glycol dibenzoate 708 3 NI 3 R 3 NI 0 0 0 0 0 S 0
Dipropylene glycol dibenzoate 2431 CAS No 94-51-9
Di-n-propyl phthalate 713 3 NI 3 (R) 3 NI (0) (0) (1) (1) (1) R S 3
Di-n-propyl phthalate 2752 CAS No 131-16-8
Distilled Resin Oil, DRO 2299 (3) NI (3) (NR) (3) NI 0 0 (2) 2 1 MN FE 3
Resin oil, distilled 2958 CAS No
Dithocarbamate ester (C7-C35) 2185 NI 2 2 NR 4 NI 0 0 (1) 1 1 S 1
Dithiocarbamate ester (C7-C35) 2371 CAS No
Ditridecyl adipate 2351 0 NI 0 NR 0 NI 0 0 (2) 2 1 Fp 2
Ditridecyl adipate 293 CAS No
Ditridecyl phthalate 714 0 (0) 0 NR 0 (0) 0 0 (1) 1 (1) Fp 2
Ditridecyl phthalate 2994 CAS No 119-06-2
Diundecyl phthalate 715 0 (0) 0 NR 0 0 0 0 (1) 1 1 Fp 2
Diundecyl phthalate 294 CAS No 3648-20-2
Dodecane 718 5 NI 5 (R) 0 NI 0 0 (1) (1) (0) Fp 2
Dodecane (all isomers) 295 CAS No 112-40-3
tert-Dodecanethiol 2233 5 4 4 NR 0 0 0 0 (2) 2 1 Ss F 3
tert-Dodecanethiol 2418 CAS No
1-Dodecanol 719 5 2 2 R 4 1 0 0 (1) 1 (1) Fp 2
Dodecyl alcohol 298 CAS No 112-53-8
1-Dodecene (#) 2473 5 NI 5 R 0 NI 0 0 1 1 (0) A F 3
1-Dodecene 3990 CAS No 112-41-4
Dodecene (all isomers) (#) 720 5 NI 5 NR 4 NI 0 0 1 1 0 A F 3
Dodecene (all isomers) 296 CAS No
2-Dodecenyl succinic acid, dipotassium salt, solution 727 4 NI 4 NR 1 NI (0) (0) NI NI NI D NI
Dodecenylsuccinic acid, dipotassium salt solution 297 CAS No 57195-28-5
Dodecylamine/Tetradecylamine mixture 721 3 NI 3 R 4 NI 1 0 (3) 3 3 F 3
Dodecylamine/Tetradecylamine mixture 303 CAS No
Dodecyl benzene 126 0 NI 0 NR 0 3 0 0 (2) (2) (1) F 2
Dodecylbenzene 304 CAS No 123-01-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 26 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Dodecyl benzene sulphonic acid (contains 1.5% Sulphuric acid) 1739 NI NI 3 R 3 1 1 (1) (2) (1) (1) D 2
Alkyl (C11-C17) benzene sulphonic acid 101 CAS No
Dodecyl diphenyl oxide disulphonate (solns.) 723 (5) NI 5 NR 4 1 1 0 (3) 1 3 D 3
Dodecyl diphenyl ether disulphonate solution 299 CAS No
Dodecyl hydroxypropyl sulphide (LOA) 1861 5 NI 5 NI 4 NI 0 0 (0) 0 0 FD 0
Dodecyl hydroxypropyl sulphide 2252 CAS No
n-Dodecyl mercaptan 2462 5 3 3 NR 5 NI 0 0 (3) 3 (3) Ss F 3
n-Dodecyl mercaptan 3743 CAS No
Dodecyl/octadecyl methacrylate (mixtures) 2116 (5) NI (5) (NR) (0) NI 0 0 (1) 1 (1) Fp 2
Dodecyl/Octadecyl methacrylate mixture 1717 CAS No
Dodecyl/pentadecyl methacrylate (mixture) 724 (5) NI (5) (NR) (0) NI 0 (0) (1) (1) (1) Fp 2
Dodecyl/Pentadecyl methacrylate mixture 302 CAS No
Dodecyl phenol 725 0 4 4 NI 4 (3) 0 0 (3) 3 2 R Fp 3
Dodecyl phenol 301 CAS No 27193-86-8
Dodecyl-, Tetradecyl-, Hexadecyl-dimethylamine mixture 2248 3 NI 3 R 5 2 1 (1) (3) 3C 3 F 3
Alkyl (C12+) dimethylamine 2485 CAS No
Dodecylxylene 1763 0 NI 0 NI 0 NI 0 0 (1) 1 1 Fp 2
Dodecyl Xylene 306 CAS No
Epichlorohydrin 731 0 0 0 R 2 NI 2 2 3 3A 3 CSs D 3
Epichlorohydrin 309 CAS No 106-89-8
Ethanol 732 0 NI 0 R 0 NI 0 0 0 1 2 D 2
Ethyl alcohol 315 CAS No 64-17-5
Ethanolamine 733 0 NI 0 R 2 0 1 1 3 3A 3 D 3
Ethanolamine 311 CAS No 141-43-5
Ethanoltriazine (aqueous solution) 2411 (0) NI (0) R 3 NI 1 0 4 0 2 Ss D 3
1,3,5-Hexahydrotriethanol-1,3,5-triazine solution 3687 CAS No 4719-04-4
Ethoxylated long chain (>C16)alkyloxyalkanamine (LOA) 2103 5 NI 5 NR 1 NI 0 0 (3) 3 (3) Fp 3
Ethoxylated long chain (C16+) alkyloxyalkylamine 2203 CAS No
Ethoxylated tallow amine (>95%) 2313 0 NI 0 NR 4 NI 1 (1) 3 2 3 Ss Fp 3
Ethoxylated tallow amine (> 95%) 2959 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 27 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Ethoxylated tallow amine, glycol mixture 2252 2 NI 2 NR 6 NI 1 0 3 2 3 D 3
Ethoxylated tallow amine, glycol mixture 2476 CAS No
Ethyl acetate 735 0 2 2 R 1 0 0 0 1 0 1 DE 2
Ethyl acetate 312 CAS No 141-78-6
Ethyl acetoacetate 736 0 0 0 R 1 NI 0 0 (1) 1 1 D 1
Ethyl acetoacetate 313 CAS No 141-97-9
Ethyl acrylate 734 1 NI 1 R 3 1 1 2 2 2 2 CSs T ED 3
Ethyl acrylate 314 CAS No 140-88-5
Ethylamine 1016 0 NI 0 R 2 NI 2 2 1 3 3 GD 3
Ethylamine 322 CAS No 75-04-7
Ethylamine solutions (72% or less) 2219 NI NI 0 R 2 NI 2 2 1 3 3 DE 3
Ethylamine solutions (72% or less) 323 CAS No
Ethyl amyl ketone 1784 2 NI 2 NI 2 NI 0 0 (2) 2 NI FD 2
Ethyl amyl ketone 316 CAS No 106-68-3
Ethylbenzene 740 3 2 2 R 3 (1) 0 0 0 2 2 T FE 3
Ethylbenzene 324 CAS No 100-41-4
N-Ethyl butylamine 745 1 NI 1 NI NI NI 1 1 2 3 3 FED 3
N-Ethylbutylamine 477 CAS No 13360-63-9
Ethyl tert-butyl ether (#) 2085 1 NI 1 NR 2 0 0 0 (1) 1 0 E 1
Ethyl tert-butyl ether 320 CAS No 637-92-3
Ethyl butyrate 748 1 NI 1 NI 2 NI 0 0 (2) 2 NI FED 2
Ethyl butyrate 317 CAS No 105-54-4
Ethyl cyclohexane 751 4 4 4 NR 3 NI (0) (0) (1) (1) (1) FE 2
Ethylcyclohexane 325 CAS No 1678-91-7
N-Ethyl cyclohexylamine 752 2 NI 2 NI (3) NI 1 2 2 3 3 FED 3
N-Ethylcyclohexylamine 478 CAS No 5459-93-8
S-Ethyl dipropylthiocarbamate 2081 3 2 2 NI 3 NI 1 1 2 2 (2) N F 3
S-Ethyl dipropylthiocarbamate 2302 CAS No 759-94-4
Ethylene carbonate 755 0 NI 0 R 0 NI 0 0 (2) 1 2 SD 2
Ethylene carbonate 326 CAS No 96-49-1
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 28 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Ethylene chlorohydrin 756 0 0 0 R 3 NI 2 3 4 2 3 D 3
Ethylene chlorohydrin 327 CAS No 107-07-3
Ethylene cyanohydrin 757 0 0 0 NI 2 NI 1 0 (2) 1 2 D 2
Ethylene cyanohydrin 328 CAS No 109-78-4
Ethylene diamine 758 0 1 1 R 3 1 1 2 1 3 3 SsSr D 3
Ethylenediamine 343 CAS No 107-15-3
Ethylene diamine, tetra acetic acid, di- and tetra-sodium salt 759 0 NI 0 NR 2 0 1 (1) (2) 1 2 D 2
Ethylenediaminetetraacetic acid, tetrasodium salt solution 344 CAS No 64-02-8
Ethylene dibromide 760 1 2 2 NR 3 NI 2 2 2 3 3 CRT SD 3
Ethylene dibromide 329 CAS No 106-93-4
Ethylene glycol 761 0 NI 0 R 0 NI 1 (1) (1) 0 0 D 1
Ethylene glycol 331 CAS No 107-21-1
Ethylene glycol acrylate 869 0 NI 0 R 4 NI 1 3 3 3 3 MSs D 3
2-Hydroxyethyl acrylate 51 CAS No 818-61-1
Ethylene glycol butyl ether acetate (#) 764 1 NI 1 R 2 NI 1 1 (1) 1 1 FD 1
Ethylene glycol butyl ether acetate 334 CAS No 112-07-2
Ethylene glycol diacetate 765 0 NI 0 NI 2 NI 0 0 (1) 1 NI D 1
Ethylene glycol diacetate 335 CAS No 111-55-7
Ethylene glycol ethyl ether acetate 767 0 NI 0 R 2 0 1 0 1 1 1 R D 3
2-Ethoxyethyl acetate 41 CAS No 111-15-9
Ethylene glycol methyl butyl ether 772 1 NI 1 NI 1 NI NI NI NI NI NI D NI
Ethylene glycol methyl butyl ether 336 CAS No 13343-98-1
Ethylene glycol methyl ether acetate 773 0 NI 0 R 2 NI 0 0 (0) (1) 1 R D 3
Ethylene glycol methyl ether acetate 337 CAS No 110-49-6
Ethylene glycol monoacetate 762 0 NI 0 R 2 NI 0 0 (3) NI (3) D 3
Ethylene glycol acetate 333 CAS No 542-59-6
Ethylene glycol monoalkyl ethers 2268 0 NI 0 R 2 NI 1 2 2 1 2 D 2
Ethylene glycol monoalkyl ethers 338 CAS No
Ethylene glycol monoethyl ether 766 0 NI 0 R 0 0 0 0 1 2 2 D 3
2-Ethoxyethanol 40 CAS No 110-80-5
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 29 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Ethylene glycol phenyl ether 775 1 NI 1 R 1 0 1 0 0 1 2 SD 2
Ethylene glycol phenyl ether 339 CAS No 122-99-6
Ethylene glycol phenyl ether/Diethylene glycol phenyl ether, mixture 1740 NI NI 1 R 1 NI 1 0 (2) (2) (2) SD 2
Ethylene glycol phenyl ether/Diethylene glycol phenyl ether mixture 340 CAS No
Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture (#) 2477 NI (1) (1) R 1 NI 1 (1) (2) (1) (1) R D 3
Ethylene glycol (>75%)/Sodium alkyl carboxylates/borax mixture 4006 CAS No
Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture (#) 2475 NI (1) (1) R 1 NI 1 (1) (1) 0 0 D 1
Ethylene glycol (>85%)/Sodium alkyl carboxylates mixture 4005 CAS No
Ethylene oxide 77 NI NI NI NI NI NI 1 (1) 3 3 3 CMR GD 3
Ethylene oxide 2744 CAS No 75-21-8
Ethylene-propylene copolymer 1508 NI NI NI NI NI NI (0) (0) (0) (0) (0) NI 0
Propylene-Butylene copolymer 633 CAS No
Ethylene vinyl acetate copolymer (emulsion) 779 0 1 1 NR 0 0 0 (0) (2) 2 0 S 2
Ethylene-vinyl acetate copolymer (emulsion) 342 CAS No
Ethyl 3-ethoxypropionate 1439 1 NI 1 NR 2 NI 0 0 0 1 1 FD 1
Ethyl-3-ethoxypropionate 321 CAS No 763-69-9
2-Ethylhexanoic acid 776 2 NI 2 R 2 NI 0 0 (2) 2 2 FD 3
2-Ethylhexanoic acid 45 CAS No 149-57-5
2-Ethylhexyl acrylate 782 3 NI 3 R 2 NI 0 0 (2) 2 2 Ss F 3
2-Ethylhexyl acrylate 46 CAS No 103-11-7
2-Ethylhexyl esters of fatty acids 2221 0 NI 0 R 1 NI 0 (0) (0) 1 0 F 1
2578 CAS No
2-Ethyl-2-(hydroxymethyl)propane-1,3-diol C8-C10 ester (LOA) 2054 0 NI 0 R 0 NI 0 (0) (0) 0 (0) Fp 2
2-Ethyl-2-(hydroxymethyl) propane-1,3-diol (C8-C10) ester 42 CAS No
5-Ethylidene-2-norbornene 783 3 3 3 NR 3 0 0 0 2 1 2 FE 2
Ethylidene norbornene 345 CAS No 16219-75-3
Ethyl isoamyl ketone 737 NI NI NI NI NI NI 0 0 (1) 1 (2) FD 2
Ethyl isoamyl ketone 2618 CAS No 541-85-5
Ethyl methacrylate 785 1 NI 1 R 2 0 0 0 0 (2) (2) Ss FE 2
Ethyl methacrylate 318 CAS No 97-63-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 30 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
N-Ethyl-2-methallylamine 2228 0 NI 0 NR 2 NI 3 2 2 3A 3 D 3
N-Ethylmethylallylamine 2417 CAS No
o-Ethyl phenol 788 2 NI 2 NI (2) NI 1 NI NI NI NI S NI
o-Ethylphenol 535 CAS No 90-00-6
Ethyl propionate 790 1 NI 1 NI 2 0 0 (1) (2) 2 2 ED 2
Ethyl propionate 319 CAS No 105-37-3
2-Ethyl-3-propylacrolein 791 2 NI 2 R 3 NI 0 0 1 3 3 F 3
2-Ethyl-3-propylacrolein 43 CAS No 645-62-5
Ethyl toluene (all isomers) 2297 3 NI 3 NI (3) NI 0 0 0 2 2 F 2
Ethyl toluene 346 CAS No
Fatty acid methyl esters 2362 0 NI 0 R 2 NI 0 (0) (2) 2 2 Fp 2
Fatty acid methyl esters (m) 3125 CAS No
Fatty acids, essentially linear, C6-C18, 2-ethylhexyl ester 2253 0 NI 0 R 1 NI 0 0 (1) 1 0 Fp 2
Fatty acids, essentially linear (C6-C18) 2-ethylhexyl ester 1914 CAS No
Fatty acids, essentially linear, C6-C18, 2-ethylhexyl ester 2253 0 NI 0 R 1 NI 0 0 (1) 1 0 Fp 2
Fatty acid (C8-C16) ethyl hexyl esters 2759 CAS No
Fatty acids, linear, C8-C18 saturated with C18 unsaturated 2260 (4) NI (4) R (4) (1) (0) (0) (1) (1) (1) Fp 2
Fatty acids, (C8-C18) 2779 CAS No
Fatty acids, linear C12+ saturated with C12+ unsaturated 2261 5 0 0 (R) 0 NI (0) (0) (1) (1) (1) Fp 2
Fatty acids, (C12+) 2780 CAS No
Fatty acids saturated, C8-C10 2324 0 NI 0 R 4 NI 0 0 (3) 3C 3 Fp 3
Fatty acids, (C8-C10) 3079 CAS No
Fatty acids, unsaturated, linear, C16+ 2259 0 0 0 R (0) NI 0 0 (0) 0 0 Fp 2
Fatty acids, (C16+) 2778 CAS No
Fatty alcohols, linear, (C12+) 2326 (5) (2) (2) (R) (4) (1) 0 0 (1) 1 1 Fp 2
Alcohols (C12+), primary, linear 3081 CAS No
Fatty alcohols, linear, (C16+) 2327 (5) (2) (2) (R) (0) (1) 0 0 (1) 1 1 Fp 2
Alcohols, linear (C16+) 3082 CAS No
Ferric chloride 339 Inorg 5 5 Inorg 2 0 1 (0) (3) 2 3 D 3
Ferric chloride solutions 348 CAS No 7705-08-0
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 31 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Ferric hydroxyethyl ethylene diamine triacetic acid, tri- sodium salt, solution 796 NI NI NI NI NI NI 0 0 (1) (0) 1 D 1
Ferric hydroxyethylethylenediaminetriacetic acid, trisodium salt solution 349 CAS No
Ferric nitrate/nitric acid solution 337 Inorg (5) (5) Inorg (2) (0) 0 (0) (3) 3 3 D 3
Ferric nitrate/Nitric acid solution 350 CAS No
Fish by-products (fresh) 2499 NI NI (0) NR 1 (0) (0) (0) (0) (0) (0) FD 1
3893 CAS No
Fish oil (containing less than 10% free fatty acids) 2316 0 NI 0 R 2 NI (0) (0) (1) (0) (1) Fp 2
Fish oil 3046 CAS No
Fish protein concentrate (containing 4% or less formic acid) 2502 NI NI (0) R 1 (0) (0) (0) (0) (1) (1) D 1
Fish protein concentrate (containing 4% or less formic acid) 4090 CAS No
Fish silage (containing 3% or less formic acid with antioxidant) 2500 NI NI (0) R 0 (0) (0) (0) (0) (1) (1) FD 1
3892 CAS No
Fish silage protein concentrate (containing 4% or less formic acid) 2487 NI 0 0 R 2 NI (0) (0) (0) (1) (1) D 2
Fish silage protein concentrate (containing 4% or less formic acid) 4062 CAS No
Fish solubles 1509 NI NI NI NI NI NI (0) (0) (0) (0) (0) NI NI
Fish solubles (water-based fish meal extract) 351 CAS No
Fluorosilicic acid 806 Inorg 0 0 Inorg 2 NI 2 (2) 4 3 3 D 3
Fluorosilicic acid 2716 CAS No 16961-83-4
Fluorosilicic acid solution (20-30%) 2240 Inorg 2 2 Inorg 2 0 (1) (1) (3) 3B 3 T D 3
Fluorosilicic acid solution (20-30%) 353 CAS No
Formaldehyde (37%-50% solution) 807 0 NI 0 R 2 NI 2 2 3 3 3 CMSs NT D 3
Formaldehyde solutions (45% or less) 354 CAS No 50-00-0
Formaldehyde, polymer with isobutylenated phenol 2377 NI NI NI NR NI NI NI NI NI NI NI Fp NI
Formaldehyde, polymer with isobutylenated phenol 1203 CAS No
Formamide 808 0 NI 0 NR 1 NI 0 0 1 1 2 R D 3
Formamide 355 CAS No 75-12-7
Formic acid 809 0 NI 0 R 2 NI 1 (1) 2 3C 3 D 3
Formic acid (over 85%) 3830 CAS No 64-18-6
Formic acid 809 0 NI 0 R 2 NI 1 (1) 2 3C 3 D 3
Formic acid (85% or less acid) 356 CAS No 64-18-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 32 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Formic acid mixture (containing up to 18% propionic acid and up to 25% sodium formate) 2408 0 NI 0 R 1 NI (0) (0) (2) (2) (3) D 3
Formic acid mixture (containing up to 18% propionic acid and up to 25% sodium formate) 3684 CAS No
Fumaric adduct of rosin (water dispersion) 810 3 NI 3 NR 3 NI 0 (0) (3) 0 3 Ss D 3
Fumaric adduct of rosin, water dispersion 357 CAS No 65997-04-8
Furfural 812 0 NI 0 R 2 1 2 (2) 3 2 2 C D 3
Furfural 358 CAS No 98-01-1
Furfuryl alcohol 813 0 NI 0 R 1 NI 2 2 3 2 2 D 2
Furfuryl alcohol 359 CAS No 98-00-0
Glucitol/glycerol blend propoxylated (containing 10% or more amines) 2441 2 NI 2 NR 1 1 1 0 (2) (1) (1) D 2
Glucitol/glycerol blend propoxylated (containing 10% or more amines) 3919 CAS No
Glucitol/glycerol blend, propoxylated (containing less than 10% amines) 2368 0 NI 0 NR 1 NI 1 0 (2) (1) (1) SD 2
Glucitol/glycerol blend propoxylated (containing less than 10% amines) 3074 CAS No
Glycerine 814 0 NI 0 R 0 0 0 0 (1) 0 1 D 1
Glycerine 363 CAS No 56-81-5
Glycerine (83%)/ Dioxane-dimethanol (17%) mixture 1743 NI NI NI R 1 NI 0 (0) (1) (0) 1 D 1
Glycerine (83%), Dioxanedimethanol (17%) mixture 364 CAS No
Glycerol ethoxylated 2360 0 NI 0 R 0 NI 0 0 (0) 0 0 D 0
Glycerol ethoxylated 3123 CAS No
Glycerol monooleate 1898 0 0 0 R 0 NI 0 (0) (1) 1 1 Fp 2
Glycerol monooleate 365 CAS No 25496-72-4
Glycerol propoxylated 2346 0 NI 0 NR 1 NI 1 0 (2) 1 0 D 2
Glycerol propoxylated 3110 CAS No
Glycerol, propoxylated and ethoxylated 2276 0 NI 0 NR 1 0 0 0 0 0 0 SD 2
Glycerol, propoxylated and ethoxylated 2872 CAS No
Glycerol/sorbitol blend, propoxylated and ethoxylated 2372 0 NI 0 NR 2 NI NI NI NI NI NI NI NI
Glycerol/sorbitol blend, propoxylated and ethoxylated 3136 CAS No
Glycerol/sucrose blend, propoxylated and ethoxylated 2361 0 NI 0 NR 1 NI 0 0 0 0 0 SD 0
Glycerol/sucrose blend propoxylated and ethoxylated 3124 CAS No
Glyceryl triacetate 816 0 NI 0 R 1 0 1 0 0 0 1 D 1
Glyceryl triacetate 367 CAS No 102-76-1
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 33 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Glycidyl ester of C10 trialkyl acetic acid 441 3 NI 3 NR 3 NI 0 0 (2) 2 1 F 2
Glycidyl ester of C10 trialkylacetic acid 368 CAS No
Glycine, Sodium salt, solution 817 0 NI 0 NI 0 NI 0 (0) (1) (0) (1) D 1
Glycine, sodium salt solution 369 CAS No 56-40-6
Glycolic acid 2218 0 0 0 R 1 NI 1 (1) 2 3C 3 D 3
Glycolic acid solution (70% or less) 2539 CAS No
Glyoxal solutions (40% or less) 84 0 NI 0 R 1 NI 0 0 2 2 3 MSsSr D 3
Glyoxal solution (40% or less) 370 CAS No 107-22-2
Glyoxylic acid 1535 0 NI 0 R 2 0 0 0 (3) 0 3 Ss D 3
Glyoxylic acid solution (50 % or less) 371 CAS No 298-12-4
Glyphosate solution, without surfactant 1765 0 0 0 NR 3 0 0 0 (3) 0 3 D 3
Glyphosate solution (not containing surfactant) 2204 CAS No 1071-83-6
Grape Seed Oil 2442 (0) NI (0) (R) (0) (0) (0) (0) (1) (0) (1) Fp 2
Grape Seed Oil 3643 CAS No 8024-22-4
Groundnut oil 820 0 NI 0 R (2) NI (0) (0) (0) (0) 0 Fp 2
Groundnut oil 2769 CAS No 8002-03-7
Heptane 827 4 NI 4 R 4 NI 0 0 0 (1) 1 A E 2
Heptane (all isomers) 372 CAS No 142-82-5
Heptanoic acid 831 2 NI 2 R 1 NI 0 0 1 3B (3) FD 3
n-Heptanoic acid 479 CAS No 111-14-8
Heptanol (all isomers) 2223 2 NI 2 R (2) NI 0 0 (2) (1) (2) FD 2
Heptanol (all isomers) (d) 373 CAS No
1-Heptanol 828 2 NI 2 R 2 0 1 0 2 (2) (2) FD 2
1-Heptanol 2688 CAS No 111-70-6
Heptene (all isomers) 2225 3 NI 3 NI 2 NI (0) (0) (0) (2) (1) E 2
Heptene (all isomers) 374 CAS No
1-Heptene 832 3 NI 3 NI 2 NI (0) (0) (0) (2) (1) E 2
1-Heptene 2685 CAS No
Heptyl acetate 833 3 NI 3 (R) (3) NI 0 0 (2) 1 2 F 2
Heptyl acetate 375 CAS No 112-06-1
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 34 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Hexadecyl naphthalene/dihexadecyl naphthalene mixture 2159 0 NI 0 NR 0 NI 0 0 (1) 1 1 Fp 2
1-Hexadecylnaphthalene / 1,4-bis(hexadecyl)naphthalene mixture 2373 CAS No
Hexahydro-1,3,5-trimethyl-1,3,5-triazine solution (45% or less) 2489 (2) NI (2) R 3 NI 1 (1) (3) 3A 3 Ss D 3
Hexahydro-1,3,5-trimethyl-1,3,5-triazine solution (45% or less) 4123 CAS No 108-74-7
Hexamethylene diamine 845 0 NI 0 R 2 NI 1 1 (3) 3A 3 R D 3
Hexamethylenediamine solution 380 CAS No 124-09-4
Hexamethylene diamine 845 0 NI 0 R 2 NI 1 1 (3) 3A 3 R D 3
Hexamethylenediamine (molten) 378 CAS No 124-09-4
Hexamethylene diamine 845 0 NI 0 R 2 NI 1 1 (3) 3A 3 R D 3
Hexamethylenediamine 377 CAS No 124-09-4
Hexamethylene diamine adipate, 50% in water 846 0 NI 0 R 1 NI 0 (0) (0) 0 0 D 0
Hexamethylenediamine adipate (50% in water) 379 CAS No 3323-53-3
Hexamethylene diisocyanate 2142 3 0 0 NR 2 NI 1 2 4 3 3 SsSr S 3
Hexamethylene diisocyanate 18 CAS No 822-06-0
Hexamethylene glycol 847 0 NI 0 R 1 NI 0 0 (1) 0 1 D 1
Hexamethylene glycol 376 CAS No 629-11-8
Hexamethyleneimine 848 1 NI 1 NI 2 NI 3 1 2 2 2 FED 2
Hexamethyleneimine 381 CAS No 111-49-9
Hexamethylene tetramine (40% solution) 849 0 NI 0 R 0 NI 0 0 (1) 0 1 Ss D 2
Hexamethylenetetramine solutions 382 CAS No 100-97-0
Hexane 850 3 NI 3 R 4 NI 0 0 0 2 2 NA E 2
Hexane 2683 CAS No 100-54-3
Hexane 850 3 NI 3 R 4 NI 0 0 0 2 2 NA E 2
Hexane (all isomers) 383 CAS No 100-54-3
1,6-Hexanediol, distillation overheads 2143 4 NI 4 NR 2 NI 0 0 2 1 2 FED 2
1,6-Hexanediol, distillation overheads 2641 CAS No
Hexanoic acid 853 2 NI 2 R 2 NI 0 0 (3) (3) 3 FD 3
Hexanoic acid 384 CAS No 142-62-1
1-Hexanol 854 1 0 0 (R) 2 NI 1 0 (3) 1 3 FD 3
Hexanol 385 CAS No 111-27-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 35 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Hexene (all isomers) 2224 3 NI 3 R 3 NI (0) (0) (1) (1) (1) E 2
Hexene (all isomers) 386 CAS No
1-Hexene 855 3 NI 3 R 3 NI 0 0 0 1 1 E 2
1-Hexene 2681 CAS No 592-41-6
2-Hexene (mixed isomers) 856 3 NI 3 R 3 NI (0) (0) 0 (1) (1) E 2
2-Hexene (mixed isomers) 2682 CAS No
Hexyl acetate 857 2 NI 2 NI 3 NI 0 0 (1) 1 1 FE 2
Hexyl acetate 387 CAS No 142-92-7
sec-Hexyl acetate 858 2 NI 2 NI 3 NI 0 0 0 1 (2) FED 2
Methylamyl acetate 456 CAS No 108-84-9
Hexylene glycol 859 0 NI 0 R 0 0 0 0 (3) 2 3 D 2
Hexylene glycol 388 CAS No 107-41-5
Hydrocarbon wax 2278 (5) NI (5) NR 0 0 (0) (0) (0) (0) (0) CT Fp 3
Hydrocarbon wax 741 CAS No
Hydrochloric acid 864 Inorg 0 0 Inorg 1 NI 1 1 3 3C 3 DE 3
Hydrochloric acid 389 CAS No 7647-01-0
Hydrogenated Starch Hydrolysate 2347 0 NI 0 R 0 NI 0 0 (0) 0 0 D 0
Hydrogenated starch hydrolysate 3077 CAS No
Hydrogen peroxide, more than 60% 867 Inorg 0 0 Inorg 3 NI 1 0 2 3 3 D 3
Hydrogen peroxide solutions (over 60% but not over 70% by mass) 390 CAS No 7722-84-1
Hydrogen peroxide, more than 60% 867 Inorg 0 0 Inorg 3 NI 1 0 2 3 3 D 3
Hydrogen peroxide, more than 60% 2689 CAS No 7722-84-1
Hydrogen peroxide, more than 8% but not more than 60% 2231 Inorg 0 0 Inorg 3 NI 1 0 (2) 3 3 D 3
Hydrogen peroxide solutions (over 8% but not over 60% by mass) 391 CAS No
Hydrogen peroxide, more than 8% but not more than 60% 2231 Inorg 0 0 Inorg 3 NI 1 0 (2) 3 3 D 3
Hydrogen peroxide, more than 8% but not more than 60% 2690 CAS No
N-(2-Hydroxyethyl) ethylene diamine triacetic acid, trisodium salt (solution) 870 0 NI 0 NI 1 NI 0 0 (1) 1 1 R D 3
N-(Hydroxyethyl)ethylenediaminetriacetic acid, trisodium salt solution 470 CAS No 150-30-0
[[(2-hydroxyethyl)imino]dimethylene]bisphosphonic acid, sodium salt 2493 0 NI 0 NR 1 NI 0 0 (0) 0 1 D 1
4127 CAS No 22036-78-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 36 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
2-Hydroxy-4-(methylthio) butanoic acid 871 1 NI 1 R 1 NI 0 0 (3) 1 3 D 3
2-Hydroxy-4-(methylthio)butanoic acid 49 CAS No 583-91-5
Icosa(oxypropane-2,3-diyl)s 2092 NI NI NI NI NI NI 0 (0) (2) 2 (2) Fp 2
Icosa(oxypropane-2,3-diyl)s 392 CAS No
Icosa(oxypropane-2,3-diyl)s 2092 NI NI NI NI NI NI 0 (0) (2) 2 (2) Fp 2
Icosa(oxypropane-2,3-diyl)s 2691 CAS No
Illipe oil (containing less than 10% free fatty acids) 2304 (0) NI (0) (R) (0) NI (0) (0) (0) (0) (0) Fp 2
Illipe oil 3034 CAS No
Imidazolium compounds, 1-benzyl-4,5-dihydro-1-(hydroxyethyl)-2-norcoco alkyl, chlorides 2505 (0) NI (0) NR 4 NI NI NI NI (2) (3) Fp 3
Imidazolium compounds, 1-benzyl-4,5-dihydro-1-(hydroxyethyl)-2-norcoco alkyl, chlorides 4157 CAS No 61791-52-4
Interesterified Mixed Vegetable Oils 2355 0 NI 0 R (0) NI (0) (0) (1) (1) (1) Fp 2
Interesterified vegetable oils 3115 CAS No
Isobutanol 382 0 NI 0 R 1 0 0 0 1 2 3 D 3
Isobutyl alcohol 397 CAS No 78-83-1
Isobutyl formate 405 1 NI 1 NI 1 NI 0 (0) 0 (1) (2) E 2
Isobutyl formate 398 CAS No 542-55-2
Isobutyl methacrylate 408 2 NI 2 NR 1 NI 0 0 0 2 2 Ss FED 2
Isobutyl methacrylate 2673 CAS No 97-86-9
Isobutyric acid 419 0 NI 0 R 2 NI 2 2 (3) 3 3 E NI
Isobutyric acid 2459 CAS No 79-31-2
Isodecanol 557 3 2 2 R 3 NI 0 0 0 2 1 Fp 2
Decyl alcohol (all isomers) 219 CAS No 25339-17-7
Isononanol 1059 3 NI 3 NR 3 1 0 0 (2) 2 2 Fp 2
Nonyl alcohol (all isomers) 510 CAS No 2430-22-0
Isononylaldehyde 2300 3 NI 3 NR (3) NI 0 0 (2) 2 1 F 2
Isononylaldehyde 2754 CAS No
Isooctaldehyde 1071 2 NI 2 NI 3 NI 0 0 (1) 1 1 F 1
Octyl aldehydes 542 CAS No 63885-09-6
Isooctanol 1076 3 NI 3 R 2 0 1 0 (2) 2 (2) F 2
iso-Octanol 2675 CAS No 26952-21-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 37 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Isooctylamine 1081 2 NI 2 NI 3 NI 1 1 3 3 3 FD 3
2-Ethylhexylamine 48 CAS No 104-75-6
Isopentene 1113 2 NI 2 NI 2 NI (0) (0) (0) (0) (1) E 2
iso-Pentene 2677 CAS No 563-45-1
Isophorone 879 1 1 1 R 2 0 1 1 (2) 1 2 FD 2
Isophorone 399 CAS No 78-59-1
Isophorone diamine 880 0 0 0 NR 2 0 1 (1) (3) 3 3 Ss D 3
Isophoronediamine 401 CAS No 2855-13-2
Isophorone diisocyanate 881 1 NI 1 NR 3 NI 0 0 3 3 3 SsSr S 3
Isophorone diisocyanate 400 CAS No 4098-71-9
Isoprene 882 2 2 2 NR 3 1 0 0 0 1 2 CM E 3
Isoprene 402 CAS No 78-79-5
Isopropanol 1181 0 NI 0 R 0 0 0 0 0 1 2 D 2
Isopropyl alcohol 405 CAS No 67-63-0
Isopropanolamine 1182 0 NI 0 R 2 NI 0 1 0 3 3 D 3
Isopropanolamine 403 CAS No 78-96-6
Isopropyl acetate 1192 1 NI 1 R 1 NI 0 0 0 1 2 ED 2
Isopropyl acetate 404 CAS No 108-21-4
Isopropylamine 1195 0 NI 0 R 2 NI 2 2 1 3 3 DE 3
Isopropylamine 407 CAS No 75-31-0
Isopropylamine (70%) 2350 0 NI 0 R 2 NI 2 2 1 3 3 DE 3
Isopropylamine (70% or less) solution 395 CAS No
Isopropyl benzene 1197 3 2 2 R 3 NI 0 0 0 2 1 FE 2
Isopropylbenzene 2687 CAS No 98-82-8
Isopropyl benzene 1197 3 2 2 R 3 NI 0 0 0 2 1 FE 2
Propylbenzene (all isomers) 623 CAS No 98-82-8
Isopropyl cyclohexane 1199 4 NI 4 (NR) (3) NI (0) (0) (1) (0) (1) FE 2
Isopropylcyclohexane 408 CAS No 696-29-7
Isopropyltoluenes 549 4 4 4 (NR) 3 NI 0 (0) 1 2 (1) FE 2
p-Cymene 552 CAS No 99-87-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 38 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Isovaleraldehyde 1390 1 NI 1 R 3 NI 0 0 0 2 2 D 2
Valeraldehyde (all isomers) 731 CAS No 590-86-3
Jatropha oil 2402 0 NI (0) (R) (2) NI (0) (0) (0) (0) (0) Fp 2
Jatropha oil 3637 CAS No
Kaolin slurry 883 Inorg NI 0 Inorg 0 NI 0 0 0 0 0 S 0
Kaolin slurry 409 CAS No 1332-58-7
Lactic acid 886 0 NI 0 R 1 NI 0 0 (3) 2 3 D 3
Lactic acid 410 CAS No 50-21-5
Lactonitrile solution (80% or less) 887 0 NI 0 R 4 NI 3 4 (4) NI NI D 3
Lactonitrile solution (80% or less) 411 CAS No 78-97-7
Lard (containing less than 10% free fatty acids) 2317 0 NI 0 R 0 NI 0 (0) (1) 0 1 Fp 2
Lard 3047 CAS No
Latex, ammonia inhibited 889 0 NI 0 NI (2) NI 0 0 (1) 0 1 D 1
Latex, ammonia (1% or less)- inhibited 413 CAS No
Lauric acid 891 4 NI 4 R 4 1 0 (0) (2) 1 2 Fp 2
Lauric acid 415 CAS No 143-07-7
Lauroamidopropyl betaine solution (#) 2479 (4) (2) (2) R (4) (1) (0) (0) (3) (1) (3) D 3
4055 CAS No 4292-10-8
Lauryl methacrylate 893 0 2 2 R 0 0 0 (0) (1) 1 1 F 1
Dodecyl methacrylate 300 CAS No 142-90-5
Lecithin (soybeans) 2146 0 NI 0 R 0 NI 0 0 (0) 0 (0) SD 0
Lecithin 417 CAS No
Lignin sulphonic acid, salt solution 34 0 NI 0 (NR) (0) NI 0 (0) (0) (0) (0) D 0
Ligninsulphonic acid, sodium salt solution 419 CAS No
Linear alkyl (C12-16) propoxyamine ethoxylate 2380 3 0 3 NR 4 NI 1 (1) (3) 3 (3) D 3
Alkyl(C12-C16) propoxyamine ethoxylate 3423 CAS No
Linseed oil (containing less than 4% free fatty acids) 2318 0 NI 0 R (2) NI 0 (0) (1) 0 (1) Fp 2
Linseed oil 3048 CAS No
Long chain alkaryl polyether (C11-C20) (LOA) 1982 (4) NI (4) NR 3 (1) 0 0 (2) 0 2 Fp 2
Long-chain alkaryl polyether (C11-C20) 421 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 39 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Long chain alkaryl sulphonic acid (C16-C60) (LOA) 1966 0 NI 0 (NR) 0 NI 0 0 (2) (1) 2 Fp 2
Long-chain alkaryl sulphonic acid (C16-C60) 424 CAS No
Long-chain alkylphenate/Phenol sulphide mixture 1754 (0) NI (0) (NR) 0 NI 0 0 (2) 2 2 Fp 2
Long-chain alkylphenate/Phenol sulphide mixture 425 CAS No
Long chain alkylphenol (C14-C18) (#) 2478 (0) NI (0) NR (0) (0) (0) (0) (2) (2) (0) Fp 2
Long-chain alkylphenol (C14-C18) 4029 CAS No
Long chain alkylphenol (C18-C30) (#) 2476 (0) NI (0) (NR) (1) (0) (0) (0) (2) (2) (0) Fp 2
Long-chain alkylphenol (C18-C30) 4040 CAS No
Long-chain polyetheramine in alkyl(C2-C4)benzenes 1457 NI NI NI NR 2 NI 0 0 (2) 2 2 Fp 2
422 CAS No
Lubrizol polyolefin anhydride 1865 0 NI 0 NR 1 NI 0 0 (2) 1 (2) Fp 2
Polyolefin anhydride 605 CAS No
L-Lysine solution (50% or less) 2199 0 0 0 R 1 0 0 0 0 1 NI D 1
L-Lysine solution (60% or less) 2306 CAS No
Magnesium alkyl (long chain) salicylate (overbased) in mineral oil (LOA) 71 (0) NI (0) NR (2) NI 0 0 (1) (1) (1) Ss S 2
Magnesium long-chain alkyl salicylate (C11+) 429 CAS No
Magnesium chloride 915 Inorg 0 0 Inorg 1 0 0 0 (0) 0 0 D 0
Magnesium chloride solution 427 CAS No 7786-30-3
Magnesium hydroxide slurry 916 Inorg 0 0 Inorg 0 NI 0 0 (1) (0) 1 S 1
Magnesium hydroxide slurry 428 CAS No 1309-42-8
Magnesium lignosulphonate solutions 2356 (0) NI (0) (NR) (0) NI 0 0 (0) (0) (0) D 0
Ligninsulphonic acid, magnesium salt solution 3116 CAS No
Magnesium long chain alkaryl sulphonate (C11-C50) (LOA) 1967 0 NI 0 NR 0 NI 0 0 (2) 1 2 Fp 2
Magnesium long-chain alkaryl sulphonate (C11-C50) 430 CAS No
Maleic acid/allyl sulphonic acid copolymer with phosphonate groups, partial sodium salt (aqueous 2412 0 NI 0 NR 0 NI (0) (0) (0) (0) (0) D 0
solution)
Maleic acid/allyl sulphonic acid copolymer with phosphonate groups, partial sodium salt (aqueous 3688 CAS No
solution)
Maleic anhydride 921 1 NI 1 R 2 0 1 2 (3) 3 3 SsSr D 3
Maleic anhydride 431 CAS No 108-31-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 40 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Maleic anhydride - sodium allylsulphonate copolymer (aqueous solution) 2410 0 NI 0 NR 1 NI 0 0 (0) (0) 0 D 0
Maleic anhydride-sodium allylsulphonate copolymer solution 3686 CAS No
Maltitol Syrup 2348 0 NI 0 R 0 NI 0 0 (0) 0 0 D 0
Maltitol solution 3078 CAS No
Mango kernel oil (containing less than 10% free fatty acids) 2305 (0) NI (0) (R) (0) NI (0) (0) (0) (0) (0) Fp 2
Mango kernel oil 3035 CAS No
2-Mercaptobenzothiazol 925 2 1 1 NR 4 2 0 0 (0) 0 0 Ss S 2
Mercaptobenzothiazol, sodium salt solution 432 CAS No 149-30-4
2-Mercaptoethanol 2495 0 NI 0 NR 1 NI 2 2 2 2 3 SsT D 3
4129 CAS No 60-24-2
Mesityl oxide 946 1 NI 1 R (1) NI 1 0 2 2 2 D 2
Mesityl oxide 433 CAS No 141-79-7
Metam-sodium (ISO) 202 0 NI 0 NR 4 NI 1 2 (2) 2 1 Ss D 2
Metam sodium solution 434 CAS No 137-42-8
Methacrylic acid-alkoxypoly (alkylene oxide) methacrylate co-polymer sodium salt (45% or less solution) 2288 NI 0 0 NR 1 NI 0 (0) (1) 1 0 D 1
Methacrylic acid - alkoxypoly (alkylene oxide) methacrylate copolymer, sodium salt aqueous solution 2819 CAS No
(45% or less)
Methacrylic acid, inhibited 948 0 NI 0 R 2 0 1 2 2 3 3 D 3
Methacrylic acid 435 CAS No 79-41-4
Methacrylic resin in 1,2 Dichloroethane soln. 2046 1 1 1 NR 2 0 (1) (0) (2) (1) (2) C SD 3
Methacrylic resin in ethylene dichloride 436 CAS No
Methacrylonitrile 949 0 NI 0 R 2 0 2 2 3 1 1 Ss NT ED 3
Methacrylonitrile 437 CAS No 126-98-7
Methanol 951 0 NI 0 R 0 0 (2) (2) (2) 2 2 T DE 3
Methyl alcohol 441 CAS No 67-56-1
(2-Methoxymethylethoxy)propanols 2452 0 NI 0 R 0 (0) 0 0 (0) 0 0 D 0
3870 CAS No
Methyl acetate 954 0 NI 0 R 1 NI 0 0 0 1 2 DE 2
Methyl acetate 438 CAS No 79-20-9
Methyl acetoacetate 335 0 NI 0 R 1 NI 0 0 (2) 1 2 D 2
Methyl acetoacetate 439 CAS No 105-45-3
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 41 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Methyl acrylate 955 0 NI 0 R 3 NI 1 1 2 2 3 MSs D 3
Methyl acrylate 440 CAS No 96-33-3
Methylamine solution 42% or less 957 0 NI 0 R 2 NI 2 (2) 3 3 3 M NT DE 3
Methylamine solutions (42% or less) 455 CAS No 74-89-5
Methyl amyl alcohol 958 1 NI 1 R 1 NI 1 0 2 1 3 FED 3
Methylamyl alcohol 457 CAS No 108-11-2
Methyl amyl ketone 959 1 NI 1 NI 1 NI 1 0 0 1 1 FED 2
Methyl amyl ketone 442 CAS No 110-43-0
N-Methyl aniline 961 1 NI 1 (NR) 3 1 1 1 (2) (1) 1 FD 2
N-Methylaniline 3107 CAS No 100-61-8
alpha-Methylbenzyl alcohol with acetophenone (15% or less) 2399 1 NI 1 (R) (1) NI (1) (0) (3) (2) (3) R Fp 3
alpha-Methylbenzyl alcohol with acetophenone (15% or less) 3634 CAS No 98-85-1
2-Methyl-2-butanol 964 1 1 1 (R) (1) 0 1 1 1 3 2 D 3
tert-Amyl alcohol 685 CAS No 75-85-4
3-Methyl-1-butanol 965 1 1 1 (R) 1 0 1 0 (2) 2 2 FED 2
Amyl alcohol, primary 126 CAS No 123-51-3
3-Methyl-1-butanol 965 1 1 1 (R) 1 0 1 0 (2) 2 2 FED 2
Isoamyl alcohol 396 CAS No 123-51-3
Methyl butenol 967 0 NI 0 R 2 NI 1 0 (2) 2 2 D 2
Methylbutenol 458 CAS No 556-82-1
Methyl tert-butyl ether 969 1 NI 1 NR 1 0 0 0 0 2 1 T ED 2
Methyl tert-butyl ether 454 CAS No 1634-04-4
Methyl butyl ketone 970 1 NI 1 (R) 1 (0) 0 0 0 1 1 RN FED 3
Methyl butyl ketone 443 CAS No 591-78-6
Methylbutynol 968 0 NI 0 NR 1 NI 1 1 0 0 2 D 2
2-Methyl-2-hydroxy-3-butyne 52 CAS No 115-19-5
Methylbutynol 968 0 NI 0 NR 1 NI 1 1 0 0 2 D 2
Methylbutynol 459 CAS No 115-19-5
Methyl butyrate 973 1 NI 1 NI (2) NI 0 0 2 2 (2) ED 2
Methyl butyrate 444 CAS No 623-42-7
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 42 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Methyl cyclohexane 976 3 3 3 NR 3 1 0 0 1 1 1 A E 2
Methylcyclohexane 460 CAS No 108-87-2
Methyl cyclopentadiene, dimer 977 4 NI 4 (NR) (3) NI 0 (0) (2) (2) (2) F 2
Methylcyclopentadiene dimer 461 CAS No 26472-00-4
Methyl cyclopentadienyl manganese tricarbonyl (60-70%) in mineral oil 2213 3 NI 3 NR 4 NI 2 3 4 1 1 S 3
Methylcyclopentadienyl manganese tricarbonyl 2692 CAS No
N-Methyldiethanolamine 1491 0 NI 0 R 2 NI 1 0 (2) 1 2 D 2
Methyl diethanolamine 445 CAS No 105-59-9
Methylene dithiocyanate 2235 2 NI 2 NR 5 NI 2 0 4 3 3 Ss NI 3
Methylene bisthiocyanate 2693 CAS No 6317-18-6
2-Methyl-6-ethylaniline 984 2 NI 2 NR 2 NI 1 1 (2) 0 2 FD 2
2-Methyl-6-ethyl aniline 54 CAS No 24549-06-2
2-Methyl-5-ethylpyridine 986 2 NI 2 R 2 0 1 2 (3) 3 3 FD 3
2-Methyl-5-ethyl pyridine 53 CAS No 104-90-5
Methyl formate 987 0 NI 0 R 1 NI 1 0 2 0 2 DE 2
Methyl formate 447 CAS No 107-31-3
N-Methylglucamine, 60% aqueous solution 2048 0 NI 0 R 0 NI 1 0 (3) 0 3 D 3
N-Methylglucamine solution (70% or less) 482 CAS No 6284-40-8
2-Methylglutaronitrile with 2-Ethylsuccinonitrile (12% or less) 2397 0 NI 0 R 0 NI 2 2 3 0 1 FD 2
2-Methylglutaronitrile with 2-Ethylsuccinonitrile (12% or less) 3632 CAS No 4553-62-2
Methyl heptyl ketone 988 3 NI 3 R 3 NI 0 0 NI NI NI FED NI
Methyl heptyl ketone 448 CAS No 821-55-6
Methyl isobutyl ketone 971 1 NI 1 R 1 0 1 0 2 2 3 FED 3
Methyl isobutyl ketone 449 CAS No 108-10-1
Methyl methacrylate 995 1 NI 1 R 2 NI 0 0 0 2 2 Ss ED 2
Methyl methacrylate 450 CAS No 80-62-6
3-Methyl-3-methoxy butanol 996 1 NI 1 NR 0 NI 0 (0) (2) 1 (2) FD 2
3-Methyl-3-methoxybutanol 59 CAS No
3-Methyl-3-methoxybutyl acetate 997 1 NI 1 NR 0 NI 0 (0) NI NI NI F NI
3-Methyl-3-methoxybutyl acetate 60 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 43 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Methyl naphthalenes 1999 4 NI 4 (NR) (4) NI 1 0 (2) 1 1 T F 2
Methyl naphthalene (molten) 451 CAS No
2-Methyl pentane 1000 3 NI 3 NI 4 NI (0) (0) (2) (2) (2) E 2
2-Methylpentane 2684 CAS No 107-83-5
2-Methyl-1,3-propanediol 2200 0 0 0 NR 0 0 0 0 (0) 0 0 D 0
2-Methyl-1,3-propanediol 2213 CAS No
Methyl propyl ketone 1003 0 NI 0 (R) 0 NI 1 0 (2) 1 2 FED 2
Methyl propyl ketone 452 CAS No 107-87-9
2-Methyl pyridine 1005 1 NI 1 R 1 NI 1 2 1 3A 3 D 3
2-Methylpyridine 55 CAS No 109-06-8
3-Methylpyridine 1006 1 NI 1 R 1 NI 1 2 2 3 3 D 3
3-Methylpyridine 61 CAS No 108-99-6
4-Methylpyridine 1007 1 NI 1 (R) 1 NI 1 2 2 3 3 D 3
4-Methylpyridine 63 CAS No 108-89-4
N-Methylpyrrolidone 1008 0 NI 0 R 1 NI 0 0 2 1 2 R D 3
N-Methyl-2-pyrrolidone 481 CAS No 872-50-4
Methyl salicylate 86 2 NI 2 R 2 NI 1 1 (2) 2 1 R SD 3
Methyl salicylate 453 CAS No 119-36-8
alpha-Methylstyrene 1010 3 3 3 NR 3 NI 0 0 1 2 1 M (T) FE 3
alpha-Methylstyrene 107 CAS No 98-83-9
3-(Methylthio) propionaldehyde 993 0 NI 0 R 3 1 1 1 2 2 3 NSs T D 3
3-(methylthio)propionaldehyde 2368 CAS No 3268-49-3
Metolachlor (ISO) 113 2 2 2 NR 5 1 1 0 (2) 1 0 Ss S 2
N-(2-Methoxy-1-methyl ethyl)-2-ethyl-6-methyl chloroacetanilide 469 CAS No 51218-45-2
Mixed acid oil 2306 (0) NI (0) (R) (0) NI 0 (0) (1) (1) 1 Fp 2
Acid oil mixture from soyabean, corn (maize) and sunflower oil refining 3036 CAS No
Mixture of dithiophosphate salts in water 2381 1 0 1 NR 2 NI 0 0 (2) 2 2 D 2
Dialkyl thiophosphates sodium salts solution 3424 CAS No
Molasses 1013 0 NI 0 R 0 NI 0 0 0 0 0 D 0
Molasses 462 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 44 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Molybdenum polysulphide long chain alkyl dithiocarbamide complex 2344 4 2 2 NR 2 0 0 0 (2) 2 2 Fp 2
Molybdenum polysulphide long chain alkyl dithiocarbamide complex 3108 CAS No
Mononitrobenzene 1017 1 1 1 R 3 (4) (2) 2 2 1 1 CRT SD 3
Nitrobenzene 501 CAS No 98-95-3
Morpholine 1018 0 0 0 R 2 NI 1 2 2 3 3 D 3
Morpholine 463 CAS No 110-91-8
Myrcene 1019 4 NI 4 R 4 1 0 0 (2) 2 NI F 2
Myrcene 465 CAS No 123-35-3
Naphthalene (molten) 1 3 3 3 NR 4 1 1 (0) (1) 0 0 T T S 2
Naphthalene (molten) 493 CAS No 91-20-3
Naphthalene, crude (molten) (#)(!) 2459 NI (3) (3) NR 3 0 0 (0) (2) 2 2 CMT Fp 3
Naphthalene crude (molten) 3858 CAS No 85117-10-8
Naphthalene sulphonic acid condensed with formaldehyde, sodium salt, solution 1020 0 1 1 (NR) 1 NI 0 (0) (1) 0 1 D 1
Naphthalenesulphonic acid-Formaldehyde copolymer, sodium salt solution 494 CAS No 9084-06-4
Neodecanoic acid 1025 4 NI 4 NR 2 NI 0 0 (2) 0 2 Fp 2
Neodecanoic acid 496 CAS No 26896-20-8
Nitric acid (90% or less) 1029 Inorg NI 0 Inorg 2 NI (3) (1) 3 3C 3 D 3
Nitric acid (less than 70%) 499 CAS No 7697-37-2
Nitric acid (90% or less) 1029 Inorg NI 0 Inorg 2 NI (3) (1) 3 3C 3 D 3
Nitric acid (70% and over) 498 CAS No 7697-37-2
Nitrilotriacetic acid,trisodium salt 1030 0 NI 0 R 1 0 1 (0) 0 1 1 CMR D 3
Nitrilotriacetic acid, trisodium salt solution 500 CAS No 5094-31-3
Nitroethane 1037 0 NI 0 NR 2 NI 1 0 (2) (0) (1) SD 2
Nitroethane 502 CAS No 79-24-3
Nitroethane (80%)/Nitropropane (20%) 2245 0 1 1 NR 2 NI 1 1 2 0 1 E 2
Nitroethane(80%)/ Nitropropane(20%) 503 CAS No
Nitroethane, 1-Nitropropane (each 15% or more) mixture 2270 (0) (1) (1) (NR) (2) NI 1 1 2 0 1 FED 2
Nitroethane, 1-Nitropropane (each 15% or more) mixture 2212 CAS No
2-Nitrophenol 1041 1 2 2 R 3 (2) 0 0 (1) 1 1 S 1
o-Nitrophenol (molten) 536 CAS No 88-75-5
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 45 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
1-Nitropropane 1044 0 1 1 NR 1 NI 1 0 2 0 1 FED 2
1-Nitropropane 2747 CAS No 108-03-2
1- or 2- Nitropropane 2242 0 1 1 NR 1 NI 2 0 2 0 1 C FED 3
1- or 2-Nitropropane 20 CAS No
2-Nitropropane 1045 0 1 1 NR 2 NI 2 0 2 0 0 C FED 3
2-Nitropropane 2748 CAS No 79-46-9
Nitropropane (60%) Nitroethane (40%) (mixture) 1046 0 1 1 NR 2 NI 1 0 2 0 1 C FED 3
Nitropropane (60%)/Nitroethane (40%) mixture 504 CAS No
o-Nitrotoluene 1049 2 2 2 NR 2 (1) 1 0 (2) 0 1 CMR S 3
o-Nitrotoluene 2745 CAS No 88-72-2
p-Nitrotoluene 1051 2 1 1 NR 3 0 1 0 (2) 0 1 R S 3
p-Nitrotoluene 2746 CAS No 99-99-0
o- or p-Nitrotoluenes 2241 2 2 2 NR 3 (1) 1 0 (2) 0 1 CMR S 3
o- or p-Nitrotoluenes 532 CAS No
Nonane 1054 4 NI 4 R 4 NI 0 0 1 1 1 A FE 2
Nonane (all isomers) 506 CAS No 111-84-2
Nonanoic acid 1055 3 NI 3 R 2 NI 0 0 (3) 2 3 F 3
Nonanoic acid (all isomers) 507 CAS No 112-05-0
Nonene (all isomers) 2222 4 NI 4 NI 3 NI 0 0 0 1 1 A FE 2
Nonene (all isomers) 508 CAS No
1-Nonene 1060 4 NI 4 NI 3 NI 0 0 0 1 1 A FE 2
1-Nonene 2680 CAS No 27215-95-8
Nonyl acetate 1766 4 NI 4 NI NI NI 0 0 NI NI NI F NI
Nonyl acetate 509 CAS No 143-13-5
Nonyl methacrylate monomer 1061 5 NI 5 R 3 NI (0) (0) (1) (1) (1) F 1
Nonyl methacrylate monomer 511 CAS No 2696-43-7
Nonyl phenol 1062 5 4 4 NR 5 3 1 0 (3) 3 3 Fp 3
Nonylphenol 512 CAS No 25154-52-3
Nonyl(C6-C12)phenol poly(4-12)ethoxylate 1063 4 NI 4 NR 3 1 0 0 (2) 2 1 D 2
Nonylphenol poly(4+)ethoxylate 513 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 46 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Nonyl(C6-C12)phenol poly(4-12)ethoxylate 1063 4 NI 4 NR 3 1 0 0 (2) 2 1 D 2
Alkyl(C7-C11)phenol poly(4-12) ethoxylate 97 CAS No
Octamethylcyclotetrasiloxane 2398 5 5 5 NR 0 3 0 0 0 0 0 F 1
Octamethylcyclotetrasiloxane 3633 CAS No
Octane 1072 5 NI 5 (R) 4 NI (0) (0) 0 0 0 A FE 2
Octane (all isomers) 538 CAS No 111-65-9
Octanoic acid (Caprylic acid) 1074 3 NI 3 R 1 NI 0 0 (3) 3 3 F 3
Octanoic acid (all isomers) 539 CAS No 124-07-2
1-Octanol 1075 3 NI 3 R 2 0 1 0 (2) 2 2 Fp 2
Octanol (all isomers) 540 CAS No 111-87-5
1-Octanol 1075 3 NI 3 R 2 0 1 0 (2) 2 2 Fp 2
1-Octanol 2676 CAS No 111-87-5
Octene (all isomers) 1079 4 NI 4 NR 3 NI 0 0 0 2 1 A FE 2
Octene (all isomers) 541 CAS No
Octyl acetate 1080 3 NI 3 R 2 NI 0 0 (1) 1 NI FD 1
n-Octyl acetate 483 CAS No 112-14-1
Octyl decyl adipate 1082 0 NI 0 (R) (0) (0) (0) (0) (1) (1) (1) Fp 2
Octyl decyl adipate 543 CAS No 110-29-2
n-Octyl mercaptan 2461 4 3 3 NR 5 NI 1 0 (1) 1 0 Ss F 3
n-Octyl mercaptan 3742 CAS No
Olefin/Alkyl ester copolymer (molecular weight 2000+) (LOA) 1965 NI NI 0 NR 0 NI 0 0 (0) 0 0 Fp 2
Olefin-Alkyl ester copolymer (molecular weight 2000+) 546 CAS No
Olefin mixture (C7-C9) 2385 5 4 4 NR 4 NI (0) 0 0 2 1 A E 2
Olefin mixture (C7-C9) C8 rich, stabilized 3548 CAS No 97593-00-5
Olefin mixtures (C5-C7) 2243 3 NI 3 R 3 NI (0) (0) (1) (2) (1) E 2
Olefin mixtures (C5-C7) 545 CAS No
Olefin mixtures (C5-C15) 2321 (5) NI (5) NR (4) NI (0) (0) (2) (2) (1) A FE 2
Olefin mixtures (C5-C15) 544 CAS No
Olefins C13 and above, all isomers (#) 2028 5 NI 5 NR 0 NI 0 0 (1) (1) 0 A Fp 3
Olefins (C13+, all isomers) 547 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 47 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
alpha-Olefins (C6-C18),mixture 2030 (5) NI (5) NR (4) NI (0) (0) (2) (2) (1) A FE 2
alpha-Olefins (C6-C18) mixtures 108 CAS No
alpha-Olefins (C12+), mixture (#) 2516 (5) (5) (5) (R) (0) NI (0) (0) (1) (1) (0) A Fp 3
alpha-Olefins (C12+), mixture 4197 CAS No
Oleic acid 1089 0 NI 0 R 0 NI 0 1 (2) 1 1 Fp 2
Oleic acid 548 CAS No 112-80-1
Oleylamine 1862 0 NI 0 NR 4 NI 1 (1) (3) 3B 3 Fp 3
Oleylamine 550 CAS No
Olive oil 1090 0 NI 0 R (2) NI (0) (0) (1) 1 1 Fp 2
Olive oil 2771 CAS No 8001-25-0
Orange juice 2375 0 0 0 R 0 0 0 0 (0) 0 0 D 0
Orange juice 3151 CAS No
Orange juice (not concentrated) 2382 0 0 0 R 0 0 0 0 (0) 0 0 D 0
Orange juice (not concentrated) 3425 CAS No
Oxatetra-azahydroxyalkanoic acid, substituted with acetic acid / acetoxyethanolamine 2413 1 NI 1 R 1 NI 0 0 0 0 0 D 0
Oxatetra-azahydroxyalkanoic acid, substituted with acetic acid / acetoxyethanolamine 3689 CAS No
Oxygenated aliphatic hydrocarbon mixture 2266 5 2 (2) NR 1 NI 0 0 (1) 1 1 FE 2
Oxygenated aliphatic hydrocarbon mixture 2825 CAS No
Palm acid oil 2307 (0) NI (0) (R) (0) NI 0 (0) (1) 0 1 Fp 2
Palm acid oil 3037 CAS No
Palm fatty acid distillate 2310 NI NI (0) (R) (0) NI 0 (0) (1) 0 1 Fp 2
Palm fatty acid distillate 3040 CAS No
Palm kernel fatty acid distillate 2335 (0) 0 0 R (3) NI 0 (0) (2) 1 2 Fp 2
Palm kernel fatty acid distillate 3111 CAS No
Palm kernel olein (containing less than 5 % free fatty acids) 2308 (0) NI (0) (R) 1 NI (0) (0) (0) (0) (0) Fp 2
Palm kernel olein 3038 CAS No
Palm kernel stearin (containing less than 5% free fatty acids) 2309 0 (0) (0) (R) 0 NI (0) (0) (0) (0) (0) Fp 2
Palm kernel stearin 3039 CAS No
Palm Mid Fraction 2363 (0) NI (0) (R) (0) NI 0 0 (0) (0) (0) Fp 2
Palm mid-fraction 3126 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 48 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Palm nut oil 1094 0 NI 0 R 1 NI (0) (0) (1) (0) (1) Fp 2
Palm kernel oil 2766 CAS No
Palm nut oil fatty acid 1095 0 NI 0 R (3) NI 0 0 (2) 1 2 Fp 2
Palm kernel acid oil 553 CAS No
Palm oil (containing less than 15% free fatty acids) 2249 0 NI 0 R 0 NI 0 (0) (0) 0 0 Fp 2
Palm oil 2764 CAS No
Palm oil (containing more than 15% and less than 30% free fatty acids) 2364 0 NI 0 R 0 NI 0 0 (2) (2) (2) Fp 2
Non-edible industrial grade palm oil 3127 CAS No
Palm oil fatty acid methyl ester 1097 0 NI 0 R 0 NI 0 0 0 0 1 Fp 2
Palm oil fatty acid methyl ester 554 CAS No
Palm olein 2250 0 NI 0 R 0 NI 0 (0) (0) 0 0 Fp 2
Palm olein 2765 CAS No
Palm stearin 2251 0 NI 0 R 0 NI 0 (0) (0) 0 0 Fp 2
Palm stearin 555 CAS No
Paraffin wax, highly-refined 1086 (5) NI (5) (NR) 0 (0) (0) (0) (0) (0) (0) Fp 2
Paraffin wax, highly-refined 556 CAS No 8002-74-2
Paraffin wax, semi-refined 2244 (5) NI (5) NR 0 (0) (0) (0) (0) (0) (0) T Fp 3
Paraffin wax, semi-refined 565 CAS No
Paraldehyde 1098 0 0 0 NR 0 NI 1 0 0 1 3 D 3
Paraldehyde 557 CAS No 123-63-7
Pentachloroethane 1099 3 2 2 NI 3 1 1 (1) 1 (1) (1) CT S 3
Pentachloroethane 558 CAS No 76-01-7
1,3-Pentadiene 1102 2 NI 2 NR 2 NI 0 0 0 1 (2) E 2
1,3-Pentadiene 14 CAS No 504-60-9
1,3-Pentadiene (greater than 50%), cyclopentene and isomers, mixtures. 2390 NI NI (3) (NR) (3) NI (2) (1) (3) (2) (2) CMR E 3
1,3-Pentadiene (greater than 50%), cyclopentene and isomers, mixtures 3560 CAS No
Pentaethylene hexamine 1103 0 NI 0 NI 4 NI 1 (2) (3) 3 (3) Ss D 3
Pentaethylenehexamine 560 CAS No 4067-16-7
Pentane 1105 3 NI 3 R 3 NI 0 0 0 1 1 E 2
Pentane (all isomers) 561 CAS No 109-66-0
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 49 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
1,5-Pentanedial solution, (5-50%) (#) 1107 0 NI 0 R 3 0 1 0 3 3 3 SsSr D 3
Glutaraldehyde solutions (50% or less) 362 CAS No 111-30-8
Pentanoic acid 1109 1 NI 1 NI 2 NI 1 2 (3) 3 3 FD 3
Pentanoic acid 562 CAS No 109-52-4
Pentanoic acid (64%)/2-methyl butyric acid (36%) mixture 2144 (1) NI (1) NI (2) NI (1) (2) (3) 3 (3) FD 3
n-Pentanoic acid (64%)/2-Methyl butyric acid (36%) mixture 2211 CAS No
1-Pentanol 1110 1 1 1 (R) 1 0 1 0 (3) 2 3 FED 3
n-Amyl alcohol 473 CAS No 71-41-0
2-Pentanol 1111 1 1 1 R 1 0 0 (0) (2) 2 2 D 2
sec-Amyl alcohol 637 CAS No 6032-29-7
Pentasodium triphosphate (*) 2418 Inorg 0 0 Inorg 1 NI NI NI NI NI NI NI NI
3694 CAS No
Pentene (all isomers) 1992 2 NI 2 NI (2) NI (0) (0) (0) (0) (1) E 2
Pentene (all isomers) 563 CAS No
1-Pentene 1114 2 NI 2 NI (2) NI (0) (0) 0 (0) (1) E 2
1-Pentene 2679 CAS No 109-67-1
2-Pentene 1115 2 NI 2 NI 2 NI (0) (0) (0) (0) (1) E 2
2-Pentene 2678 CAS No 109-68-2
Phenol 1124 1 2 2 R 3 0 2 2 (3) 3 3 NT S 3
Phenol 566 CAS No 108-95-2
Phenylxylylethane 1135 5 4 4 NR (2) NI 1 0 (1) (0) 0 F 1
1-Phenyl-1-xylyl ethane 23 CAS No 40766-31-2
Phosphate esters, alkyl(C12-C14)amine (LOA) 1854 2 NI 2 NR 3 NI 0 (0) (2) 1 2 FD 2
Phosphate esters, alkyl (C12-C14) amine 1345 CAS No
[[(phosphonomethyl)imino]bis[ethylenenitrilobis(methylene)]]tetrakisphosphonic acid, ammonium salt 2509 0 NI 0 NR 2 (0) (0) (0) (1) (1) (1) D 1
solution (60% or less)
[[(Phosphonomethyl)imino]bis[ethylenenitrilobis(methylene)]]tetrakisphosphonic acid, ammonium salt 4077 CAS No 70714-66-8
solution (60% or less)
Phosphoric acid 1138 0 NI 0 Inorg 1 NI 1 1 3 3 3 D 3
Phosphoric acid 567 CAS No 7664-38-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 50 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Phosphorus (elemental yellow) 1139 Inorg (3) (3) Inorg 6 4 0 0 0 2 1 S 2
Phosphorus, yellow or white 568 CAS No 7732-14-0
Phthalic anhydride (molten) 1146 1 NI 1 R 2 0 1 0 (3) 1 3 SsSr S 3
Phthalic anhydride (molten) 569 CAS No 85-44-9
alpha-Pinene 40 4 NI 4 R 4 NI 0 0 0 1 (1) Ss T F 3
alpha-Pinene 109 CAS No 80-56-8
beta-Pinene 41 4 NI 4 (R) 4 NI 0 0 0 1 (1) Ss NT F 3
beta-Pinene 141 CAS No 1330-16-1
Pine oil 1148 4 NI 4 NR 4 NI 0 0 (1) (1) (1) Ss (T) Fp 3
Pine oil 570 CAS No 8002-09-3
Piperazine, 68% Aqueous 2433 0 NI 0 NR 2 NI 0 0 2 3A 3 SsSrN SD 3
Piperazine, 68% solution 3748 CAS No 110-85-0
Pol (2-8) alkylene (C2-C3) glycols/ Polyalkylene (C2-C10) glycols monoalkyl ethers and their borate 2358 (1) NI (1) (R) (1) (0) 0 0 0 2 2 D 2
esters
Brake fluid base mix: Poly(2-8)alkylene (C2-C3) glycols/Polyalkylene (C2-C10) glycols monoalkyl (C1- 144 CAS No
C4) ethers and their borate esters
Polyacrylic acid (40% solution) 2302 (2) NI (2) NR 1 NI 0 0 (1) 1 1 D 1
Polyacrylic acid solution (40% or less) 2709 CAS No
Polyalkene sulphonic acid (C20-C28), sodium salt (#) 2481 (5) (4) (4) (NR) 1 0 (1) (0) (2) (2) (2) Fp 2
Polyalkene sulphonic acid (C20-C28), sodium salt 4057 CAS No
Poly(C18-C22)alkyl acrylate in xylene 1151 (3) NI (3) NR 2 NI 0 0 (2) 2 1 Fp 2
Polyalkyl (C18-C22) acrylate in xylene 580 CAS No
Polyalkylalkenaminesuccinimide, molybdenum oxysulphide 2379 NI 0 0 NR 0 NI 0 0 (0) 0 0 Fp 2
Polyalkylalkenaminesuccinimide, molybdenum oxysulphide 3422 CAS No
Poly(2-8)alkylene glycol monoalkyl(C1-C6) ether 1152 1 NI 1 R 1 0 0 0 0 2 2 D 2
Poly(2-8)alkylene glycol monoalkyl(C1-C6) ether 576 CAS No
Poly(2-8)alkylene glycol monoalkyl (C1-C6) ether acetate 2254 1 NI 1 NR 2 1 0 0 0 2 2 D 2
Poly(2-8)alkylene glycol monoalkyl (C1-C6) ether acetate 575 CAS No
Poly N-alkylmethacrylamide ammonium acrylate copolymer (20 % in DEGME) (**) 2468 0 NI 0 NR 2 NI NI NI NI NI NI D NI
3931 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 51 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Poly alkyl methacrylate (C1-C20) (LOA) 1984 (5) NI (5) NR 0 NI 0 0 0 0 0 Fp 2
Polyalkyl (C10-C20) methacrylate 2189 CAS No
Poly alkyl(C10-C18) methacrylate/ethylene-propylene copolymeer mixture 2201 0 0 0 NR 0 0 0 0 (1) 1 1 A Fp 3
Polyalkyl (C10-C18) methacrylate/ethylene-propylene copolymer mixture 2188 CAS No
Poly alkyl(C18-C22)methacrylates/lauryl acrylate/vinyl acetate (40% in naphtha) 2512 (5) (5) (5) NR 0 NI 0 0 (1) 1 (1) Fp 2
4161 CAS No
Polyaluminium chloride (sol.) 1136 Inorg 0 0 Inorg 0 NI (0) (0) (1) (0) (1) D 1
Polyaluminium chloride solution 584 CAS No 1327-41-9
Polybutene 1154 0 NI 0 (NR) (0) (0) (0) (0) (0) (0) (0) Fp 2
Polybutene 585 CAS No 9003-29-6
Polybutenylsuccinimide in oil 2055 5 NI 5 NR 0 NI (0) (0) (0) 0 (0) Fp 2
Polybutenyl succinimide 586 CAS No
Poly(2+)cyclic aromatics 2246 4 4 4 NR (4) NI (1) (1) (2) (1) (1) CM S 3
Poly(2+)cyclic aromatics 574 CAS No
Polyether, borated 1863 0 NI 0 NR 3 1 0 (0) (1) 1 0 D 1
Polyether, borated 572 CAS No
Polyether (molecular weight 2000+) (LOA) 1975 0 NI 0 NR 1 NI 0 (0) (0) 0 0 Fp 2
Polyether (molecular weight 1350+) 587 CAS No
Polyethylene amines / paraffin mixtures 1991 (5) NI (5) NR 3 0 0 (1) (3) (2) (3) Ss Fp 3
Polyethylene polyamines (more than 50% C5 -C20 paraffin oil) 591 CAS No
Polyethylene glycol 1157 0 NI 0 NR 0 NI 0 0 0 1 1 D 1
Polyethylene glycol 589 CAS No 25322-68-3
Polyethylene glycol dimethyl ether 1158 0 NI 0 NR 0 NI 0 0 (1) 1 (1) D 1
Polyethylene glycol dimethyl ether 590 CAS No 24991-55-7
Poly(ethylene glycol) methylbutenyl ether (MW >1000) 2395 NI 0 0 R 1 NI 0 0 (0) 0 0 D 0
Poly(ethylene glycol) methylbutenyl ether (MW>1000) 3501 CAS No
Polyethylene polyamines 2367 0 NI 0 NR 3 0 1 0 (3) 2 (3) Ss D 3
Polyethylene polyamines 3131 CAS No
Polyferric sulphate solution 338 Inorg 0 0 Inorg (2) NI 1 (1) (3) 3 (3) D 3
Polyferric sulphate solution 592 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 52 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Polyglycerine, sodium salt, solution 1874 0 NI 0 R 0 NI 0 0 (3) (2) 3 D 3
Polyglycerin, sodium salt solution (containing less than 3% sodium hydroxide) 593 CAS No
Polyglycerol 1511 NI NI NI NI NI NI 0 (0) (0) (0) (0) D 0
Polyglycerol 594 CAS No
Poly (iminoethylene)-graft-N-poly (ethyleneoxy) solution (90% or less) 2287 0 0 0 NR 0 NI 0 0 (1) 0 1 D 1
Poly(iminoethylene)-graft-N-poly(ethyleneoxy) solution (90% or less) 2537 CAS No
Polyisobutenamine in aliphatic (C10-C14) solvent 2192 0 0 0 NR 2 NI 0 (0) (2) 2 1 FED 2
Polyisobutenamine in aliphatic (C10-C14) solvent 2374 CAS No
(Polyisobutene) amino products in aliphatic hydrocarbons 2455 0 NI (5) NR 2 NI 0 0 (1) 1 0 A Fp 3
(Polyisobutene) amino products in aliphatic hydrocarbons 3811 CAS No
Polyisobutenyl anhydride adduct 2127 0 NI 0 NR 0 NI 0 0 (1) 0 1 FD 1
Polyisobutenyl anhydride adduct 2256 CAS No
Poly(4+)isobutylene 2264 0 NI 0 NR 0 NI (0) (0) (0) (0) (0) Fp 2
Polyisobutylene (MW≤224) 578 CAS No
Polymethylene polyphenyl isocyanate 1153 NI (2) (2) NR 0 0 0 0 (2) 2 2 SsSr S 2
Polymethylene polyphenyl isocyanate 595 CAS No 9016-87-9
Polyolefin acid, potassium salt 1895 NI NI NI NR 0 NI 0 0 (0) 0 0 NI 0
Potassium salt of polyolefin acid 2199 CAS No
Polyolefinamide alkene(C16+)amine (LOA) 2104 5 NI 5 NR 0 NI 0 0 (1) 1 (1) Fp 2
Polyolefin amide alkeneamine (C17+) 597 CAS No
Polyolefin amide alkeneamine (C28+) (LOA) 1971 0 NI 0 NR 0 NI 0 0 (0) 1 (1) NI 1
Polyolefin amide alkeneamine (C28+) 598 CAS No
Polyolefin amide alkeneamine borate (C28-C250) (LOA) 1970 0 NI 0 NR 0 NI 0 0 (0) 0 (0) Fp 2
Polyolefin amide alkeneamine borate (C28-C250) 600 CAS No
Polyolefin amide alkeneamine/molybden oxysulphide mi 2256 NI NI NI NI NI NI NI NI NI NI NI NI NI
Polyolefin amide alkeneamine/molybdenum oxysulphide mixture 603 CAS No
Polyolefin amide alkylene amine polyol 1989 0 2 2 NR 0 NI 0 0 (0) 0 0 Fp 3
Polyolefin amide alkeneamine polyol 602 CAS No
Poly (17+) olefin amine 2049 0 NI 0 NR 2 NI 0 (0) (1) (1) (1) Fp 2
Poly (17+) olefin amine 571 CAS No 98761-78-5
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 53 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Polyolefinamine (C28-C250) (LOA) 2107 0 NI 0 NR 2 NI 0 (0) (2) 2 (1) Fp 2
Polyolefinamine in aromatic solvent 611 CAS No
Polyolefinamine (C28-C250) (LOA) 2107 0 NI 0 NR 2 NI 0 (0) (2) 2 (1) Fp 2
Polyolefinamine in alkyl (C2-C4) benzenes 610 CAS No
Polyolefinamine (C28-C250) (LOA) 2107 0 NI 0 NR 2 NI 0 (0) (2) 2 (1) Fp 2
Polyolefinamine (C28-C250) 609 CAS No
Polyolefin aminoester salt 2095 0 NI 0 NR 1 NI 0 0 (1) 1 (1) Fp 2
Polyolefin aminoester salts (molecular weight 2000+) 604 CAS No
Polyolefin ester (C28-C250) (LOA) 1969 0 NI 0 NR 0 NI 0 0 (0) 0 0 Fp 2
Polyolefin ester (C28-C250) 606 CAS No
Polyolefin (molecular weight 300+) (LOA) 1968 0 NI 0 NR 0 NI 0 0 0 0 0 Fp 2
Polyolefin (molecular weight 300+) 596 CAS No
Polyolefin phenolic amine (C28-C250) (LOA) 1980 0 NI 0 NI 0 NI 0 0 (1) (1) (1) Fp 2
Polyolefin phenolic amine (C28-C250) 607 CAS No
Polyolefin phosphoro sulphide - barium derivative (C28-C250) (LOA) 1976 0 NI 0 NI 2 NI 0 (0) (0) (0) (0) S 0
Polyolefin phosphorosulphide, barium derivative (C28-C250) 608 CAS No
Poly(oxy-1,2-ethanediyl), alpha-(nonylphenyl)-omega-hydroxy-, phosphate 2506 (4) (3) (3) NR 3 (1) (1) (1) (3) (2) (3) S 3
Poly(oxy-1,2-ethanediyl), alpha-(nonylphenyl)-omega-hydroxy-, phosphate 4158 CAS No 51811-79-1
Polyoxyethylene sorbitan monooleate 1442 3 (2) 3 R 2 0 0 (0) (0) 0 0 D 0
Poly(20)oxyethylene sorbitan monooleate 577 CAS No 9005-65-6
Polyoxypropylene diamine 2352 1 NI 1 NR 1 NI 0 0 (3) 3 3 D 3
3112 CAS No
Polypropylene 1512 0 NI 0 NR (0) NI (0) (0) (0) (0) (0) F 1
Poly(5+)propylene 579 CAS No 9003-07-0
Polypropylene glycol 1159 0 NI 0 (NR) 1 NI 1 0 (1) 1 1 D 1
Polypropylene glycol 612 CAS No 25322-69-4
Polysiloxane 1161 NI 4 4 NI 2 NI 0 (0) (0) 0 0 F 1
Polysiloxane 613 CAS No
Polysiloxane 1161 NI 4 4 NI 2 NI 0 (0) (0) 0 0 F 1
Dimethylpolysiloxane 275 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 54 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Poly (tetramethylene) ether glycol (mw 600-3000) 2147 2 NI 2 NR 3 NI 0 0 (0) 0 (0) FD 0
Poly(tetramethylene ether) glycol (mw 600-3000) 2540 CAS No
Potassium carbonate solution 2465 Inorg 0 0 Inorg 2 NI 0 0 (0) 2 2 D 2
Potassium carbonate solution 3928 CAS No
Potassium chloride brine (less than 26%) 2345 0 0 0 Inorg 0 0 0 (0) (0) 0 0 D 0
Potassium chloride solution (less than 26%) 3109 CAS No
Potassium chloride solution 1513 0 0 0 Inorg 1 0 0 (0) (0) 0 0 D 0
Potassium chloride solution 614 CAS No 7447-40-7
Potassium formate solution (75% or more) 2121 0 NI 0 R 0 NI (0) (0) (2) 2 2 D 2
Potassium formate solutions 615 CAS No 590-29-4
Potassium hydroxide (sol.) 1171 Inorg 0 0 Inorg 2 NI 2 (2) (3) 3C 3 D 3
Potassium hydroxide solution 616 CAS No 1310-58-3
Potassium iodide 2484 Inorg (0) (0) Inorg 1 0 0 0 (0) 0 0 T D 2
Potassium iodide 4060 CAS No 7681-11-0
Potassium oleate 1497 3 NI 3 R 4 NI (0) (0) (1) 1 1 FD 1
Potassium oleate 617 CAS No 143-18-0
Potassium thiosulphate solution (50% or less) 2152 Inorg 0 0 Inorg 2 NI 0 0 (2) 2 (2) D 2
Potassium thiosulphate (50% or less) 2335 CAS No
Propanol 1180 0 NI 0 R 0 NI 1 0 0 1 2 R D 3
n-Propyl alcohol 488 CAS No 71-23-8
Propanolamine 1183 0 NI 0 R 2 NI 0 1 (3) 3 3 D 3
n-Propanolamine 485 CAS No 156-87-6
2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer (aqueous solution) 2420 0 NI 0 R 2 0 0 (0) (0) 0 (0) D 0
2-Propene-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, homopolymer 3696 CAS No
2-Propenoic acid polymer with 4-(1,1-dimethylethyl)phenol, formaldehyde, 2,5-furandione, 2- 2491 (5) NI (5) NR 2 NI 0 0 (0) (0) 0 A Fp 3
methyloxirane and oxirane (65% in naphtha/xylene)
2-Propenoic acid polymer with 4-(1,1-dimethylethyl)phenol, formaldehyde, 2,5-furandione, 2- 4125 CAS No 178603-70-8
methyloxirane and oxirane (65% in naphtha/xylene)
2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol) 2435 0 NI 0 NR 2 0 1 0 0 2 2 Fp 2
2-Propenoic acid polymer with furandione (65% in 2-butoxyethanol) 3750 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 55 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
beta-Propiolactone 1184 0 NI 0 R (2) NI 2 (2) 4 3B 3 CM D 3
beta-Propiolactone 142 CAS No 57-57-8
Propionaldehyde 1185 0 NI 0 R 2 NI 1 0 1 2 2 DE 2
Propionaldehyde 619 CAS No 123-38-6
Propionic acid 1186 0 NI 0 R 2 NI 0 0 (3) 3B 3 D 3
Propionic acid 620 CAS No 79-09-4
Propionic anhydride 1187 0 NI 0 R 2 NI 0 0 (3) 2 3 FD 3
Propionic anhydride 621 CAS No 123-62-6
Propionitrile 1188 0 NI 0 NI 0 NI 3 3 4 1 2 R D 3
Propionitrile 622 CAS No 107-12-0
Propyl acetate 1191 1 NI 1 R 2 NI 0 0 0 1 1 ED 1
n-Propyl acetate 487 CAS No 109-60-4
Propylamine 1194 0 NI 0 NI 1 NI 2 2 3 3 3 DE 3
n-Propylamine 490 CAS No 107-10-8
Propyl benzene 1196 NI NI NI NI 3 NI NI NI NI NI NI (T) FE NI
Propylbenzene 2686 CAS No 103-65-1
Propyl chloride 1198 2 NI 2 NI 1 NI 0 NI NI NI NI FED 2
n-Propyl chloride 489 CAS No 540-54-5
Propylene carbonate 2056 0 NI 0 R 0 NI 0 0 (3) 2 3 D 3
Propylene carbonate 624 CAS No 108-32-7
Propylene dimer 1201 3 NI 3 R 3 NI NI NI NI NI NI E 2
Propylene dimer 625 CAS No
1,2-Propylene glycol 1202 0 NI 0 R 0 0 0 0 0 0 0 D 0
Propylene glycol 626 CAS No 57-55-6
Propylene glycol methyl ether acetate 1759 0 NI 0 NR 1 NI 0 0 0 0 1 D 1
Propylene glycol methyl ether acetate 627 CAS No 108-65-6
Propylene glycol monoalkyl ether 1958 0 NI 0 NR 0 NI 0 1 0 2 3 D 3
Propylene glycol monoalkyl ether 628 CAS No
Propylene glycol phenyl ether 2057 1 NI 1 NI 1 NI 0 0 (1) (1) (1) SD 1
Propylene glycol phenyl ether 629 CAS No 4169-04-4
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 56 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Propylene oxide 76 0 NI 0 R 2 NI 1 2 2 2 3 CM DE 3
Propylene oxide 630 CAS No 75-56-9
Propylene oxide/Ethylene oxide mixture 78 0 NI 0 R 1 NI 1 1 3 3 3 CMR DE 3
Ethylene oxide/Propylene oxide mixture with an ethylene oxide content of not more than 30% by mass 341 CAS No
Propylene tetramer 2255 NI 4 4 NR (4) NI (0) (0) (1) (1) (1) F 1
Propylene tetramer 631 CAS No 6842-15-5
Propylene trimer 1207 5 4 4 NR 3 2 (0) (0) (1) (1) (1) FE 2
Propylene trimer 632 CAS No 13987-01-4
Pyridine 1213 0 NI 0 R 3 0 1 1 2 1 3 NT D 3
Pyridine 634 CAS No 110-86-1
Pyridine bases 2131 1 NI 1 R 2 NI 2 1 (3) 3B 3 FED 3
Paraldehyde-ammonia reaction product 1989 CAS No
Pyridinium, 1-(phenylmethyl)-, ethyl methyl derivs., chlorides 2507 3 NI 3 NR 4 2 NI NI NI (3B) (3) D 3
Pyridinium, 1-(phenylmethyl)-, ethyl methyl derivs., chlorides 4159 CAS No 68909-18-2
Pyrolysis gasoline 2271 (4) (3) (3) (R) (3) (1) 1 0 (2) 2 2 TCM FE 3
Pyrolysis gasoline (containing benzene) 1990 CAS No
Quaternary ammonium compounds, benzyl-C12-14 (even-numbered)-alkyldimethyl, chlorides solution 2494 3 NI 3 NR 4 NI 1 0 (3) 3B 3 D 3
4128 CAS No 68424-85-1
Rapeseed oil (high erucic acid; containing less than 4% free fatty acids) 2315 0 NI 0 R (2) NI (0) (0) (0) (1) (1) Fp 2
Rapeseed oil 3045 CAS No
Rapeseed oil (Low erucic acid containing less than 4% free fatty acids) 2296 0 NI 0 R (2) NI 0 0 0 (1) (1) Fp 2
Rapeseed oil (low erucic acid containing less than 4% free fatty acids) 2956 CAS No
Rape seed oil fatty acid, methyl ester 2209 0 0 0 R 0 NI 0 (0) (1) 1 1 Fp 2
Rape seed oil fatty acid methyl esters 2576 CAS No
Rice bran oil (containing less than 15% of free fatty acids) 2312 (0) NI (0) (R) (0) NI 0 (0) (1) 0 1 Fp 2
Rice bran oil 3043 CAS No
Rosin 1219 3 NI 3 NR 3 NI 0 0 2 (1) 1 Ss S 2
Rosin 635 CAS No 8050-09-7
Rosin soap (disproportionated solution) 1220 3 NI 3 NR 3 NI 0 NI NI NI NI S NI
Rosin soap (disproportionated) solution 636 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 57 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Safflower oil (containing less than 5% free fatty acids) 1222 (0) NI (0) (R) (0) NI (0) (0) (1) 1 1 Fp 2
Safflower oil 3041 CAS No 8001-23-8
Saturated and unsaturated alkyl (C10-C20) phosphite (LOA) 2108 0 NI 0 R 1 NI 0 0 (0) 0 0 Fp 2
Alkyl (C10-C20, saturated and unsaturated) phosphite 96 CAS No
Shea butter (containing less than 15% free fatty acids) 2311 (0) NI (0) NR (0) NI (0) (0) (1) (0) (1) Fp 2
Shea butter 3042 CAS No
Silica slurry 1514 Inorg 0 0 Inorg 0 0 (0) (0) 0 (0) (0) S 0
Microsilica slurry 2507 CAS No 7631-86-9
Sodium acetate 1498 0 NI 0 R 0 NI 0 0 0 1 1 D 1
Sodium acetate solutions 639 CAS No 127-09-3
Sodium aluminate (solution) 1234 Inorg 0 0 Inorg 3 1 (0) (0) (3) (3) (3) D 3
Sodium aluminate solution 641 CAS No 11138-49-1
Sodium aluminosilicate slurry 1235 Inorg 0 0 Inorg 1 0 0 0 0 1 1 S 1
Sodium aluminosilicate slurry 643 CAS No 1344-00-9
Sodium benzoate 1475 0 NI 0 R 1 NI 0 (0) (1) 0 1 D 1
Sodium benzoate 644 CAS No 532-32-1
Sodium bicarbonate solution (less than 10%) 2386 0 NI 0 Inorg 0 0 0 0 (0) 0 0 D 0
Sodium bicarbonate solution (less than 10%) 3558 CAS No 144-55-8
Sodium borohydride/sodium hydroxide mixture (soln.) 1239 Inorg 0 0 Inorg 2 NI (2) (1) (3) (3) (3) D 3
Sodium borohydride (15% or less)/Sodium hydroxide solution 645 CAS No
Sodium bromide solution (less than 50%) 2387 0 NI 0 Inorg 0 0 0 0 (1) 0 1 R D 3
Sodium bromide solution (less than 50%) (*) 3410 CAS No 7647-15-6
Sodium carbonate 1243 Inorg 0 0 Inorg 1 NI 0 0 2 1 2 SD 2
Sodium carbonate solution 646 CAS No 497-19-8
Sodium chlorate solid and solutions (50% or less) 1244 Inorg 0 0 Inorg 1 NI 1 0 (2) 1 1 D 2
Sodium chlorate solution (50% or less) 647 CAS No 7775-09-9
Sodium dichromate solution 487 Inorg 0 0 Inorg 4 1 2 2 4 2 3 CMSsSr D 3
Sodium dichromate solution (70% or less) 649 CAS No 10588-01-9
Sodium dodecyl sulphate (*) 2451 0 NI 0 R 3 1 NI NI NI NI NI NI NI
3869 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 58 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Sodium hydrogen sulphide/Ammonium sulphide(mixture) 1253 Inorg 0 0 Inorg 3 NI (2) (2) (3) (3) (3) D 3
Sodium hydrosulphide/Ammonium sulphide solution 653 CAS No
Sodium hydrogen sulphide (6% or less)/sodium carbonate (3% or less) 2262 0 NI 0 Inorg 1 NI (0) (0) (1) (1) (1) D 1
Sodium hydrogen sulphide (6% or less)/Sodium carbonate (3% or less) solution 650 CAS No
Sodium hydrogen sulphide,solutions 1252 Inorg 0 0 Inorg 1 NI 2 2 (3) (3) 3 D 3
Sodium hydrosulphide solution (45% or less) 652 CAS No 16721-80-5
Sodium hydrogen sulphite,solutions 1251 Inorg 0 0 Inorg 1 NI 0 (0) (0) 0 0 D 0
Sodium hydrogen sulphite solution (45% or less) 651 CAS No 7631-90-5
Sodium hydroxide (30% or less)/Sodium aluminate (25% or less) solution (#) 2486 Inorg (0) (0) Inorg 3 1 0 (0) (3) 3 (3) D 3
3914 CAS No
Sodium hydroxide solution (#) 1254 Inorg 0 0 Inorg 2 NI 1 1 3 3C 3 D 3
Sodium hydroxide solution 654 CAS No 1310-73-2
Sodium hypochlorite solutions containing 20% and less but more than 2% NaOCl 1256 Inorg 0 0 Inorg (4) (1) 0 0 1 3 3 D 3
Sodium hypochlorite solution (15% or less) 2785 CAS No 7681-52-9
Sodium hypochlorite solutions containing more than 20% Na0Cl 1255 Inorg 0 0 Inorg 5 2 0 0 1 3 3 D 3
Sodium hypochlorite solution (Full strength solution) 655 CAS No 7681-52-9
Sodium methylate (**) 2443 NI NI (0) (R) (2) NI NI NI NI NI NI T DE NI
Sodium methylate 3822 CAS No
Sodium Methylate (21-30% in Methanol) 2427 0 NI 0 R 1 NI 2 (2) (3) 3 3 T D 3
Sodium methylate 21-30% in methanol 3608 CAS No
Sodium nitrate 1259 Inorg 0 0 Inorg 0 NI (0) (0) (0) (1) (1) SD 1
Sodium nitrate 656 CAS No 7631-99-4
Sodium nitrite 340 Inorg 0 0 Inorg 3 0 2 (2) 2 0 1 SD 2
Sodium nitrite solution 658 CAS No 7632-00-0
Sodium oxalate solution (#) 2518 0 (1) (1) R 2 1 1 0 (2) (2) 2 D 2
Sodium oxalate solution 4199 CAS No
Sodium perborate monohydrate 2284 Inorg NI NI Inorg 3 NI 1 0 (3) 2 3 NI 3
Sodium perborate monohydrate 2948 CAS No
Sodium petroleum sulphonate 1860 0 NI 0 (NR) 2 NI 0 (0) (2) 1 2 S 2
Sodium petroleum sulphonate 660 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 59 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Sodium polyacrylate solution 1487 0 NI 0 NR 1 0 0 (0) (1) 1 1 D 1
Sodium poly(4+)acrylate solutions 826 CAS No
Sodium silicate (solution) 1262 Inorg 0 0 Inorg 2 NI 1 0 (3) 3 3 D 3
Sodium silicate solution 661 CAS No 1344-09-8
Sodium sulphate (solution) 1499 Inorg 0 0 Inorg 0 0 0 (0) (1) 1 1 SD 1
Sodium sulphate solutions 662 CAS No 7757-82-6
Sodium sulphide (solution) 1263 Inorg 0 0 Inorg 3 NI 1 1 (3) 3A 3 D 3
Sodium sulphide solution (15% or less) 663 CAS No 1313-82-2
Sodium sulphite (solution) 9 Inorg 0 0 Inorg 2 NI 0 (0) (1) 0 1 D 1
Sodium sulphite solution (25% or less) 664 CAS No 7757-83-7
Sodium tartrate succinate/Sodium tartrate disuccinate mixtures 1771 NI 1 1 NI 1 NI 0 NI NI NI NI D NI
Sodium tartrates/Sodium succinates solution 665 CAS No
Sodium thiocyanate 1264 Inorg 0 0 Inorg 2 NI 1 (0) (1) 0 0 D 1
Sodium thiocyanate solution (56% or less) 667 CAS No 540-72-7
Sorbitan monooleate 2215 (5) NI (5) R 3 NI 0 NI NI 0 0 Fp 2
Sorbitan monooleate 2408 CAS No
Sorbitol 1265 0 NI 0 R 0 NI 0 (0) (0) (0) (0) D 0
Sorbitol solution 668 CAS No 50-70-4
Soyabean oil (containing less than 4% free fatty acids) 2320 0 NI 0 R 0 NI 0 (0) (1) (0) 1 Fp 2
Soyabean oil 3050 CAS No
Soybean oil fatty acids, methyl esters 2431 0 NI 0 R 2 NI 0 0 0 0 0 Fp 2
Soybean Oil Fatty Acid Methyl Ester 3737 CAS No
Styrene (monomer) 1273 3 (2) 3 R 3 NI 1 0 2 2 2 CM FE 3
Styrene monomer 669 CAS No 100-42-5
Styrene butadiene rubber latex 1274 0 NI 0 NR 0 NI 0 0 (1) 0 1 D 1
Latex: Carboxylated styrene-Butadiene copolymer; Styrene-Butadiene rubber 414 CAS No
Sulpho hydrocarbon (C3-C88) (LOA) 1972 4 NI 4 NR 2 NI 0 0 0 0 0 Fp 2
Sulphohydrocarbon (C3-C88) 672 CAS No
Sulpholane 1277 0 1 1 NR 2 0 1 0 0 1 2 SD 2
Sulpholane 673 CAS No 126-33-0
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 60 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Sulphonated polyacrylate solution 1760 NI 0 0 NI 0 NI (0) (0) (0) (0) (0) D 0
Sulphonated polyacrylate solution 674 CAS No
Sulphur 906 Inorg 0 0 Inorg 0 NI 0 0 (1) 1 1 S 1
Sulphur (molten) 675 CAS No 7704-34-9
Sulphuric acid 1280 0 NI 0 Inorg 2 NI 0 (0) 3 3C 3 C D 3
Sulphuric acid, spent 677 CAS No 7664-93-9
Sulphuric acid 1280 0 NI 0 Inorg 2 NI 0 (0) 3 3C 3 C D 3
Sulphuric acid 676 CAS No 7664-93-9
Sulphuric acid 1280 0 NI 0 Inorg 2 NI 0 (0) 3 3C 3 C D 3
Oleum 549 CAS No 7664-93-9
Sulphurized fat(C14-C20) (LOA) 1853 0 NI 0 NR 1 NI 0 (0) (1) 0 (1) FD 1
Sulphurized fat (C14-C20) 2257 CAS No
Sulphurized polyolefinamide alkene(C28-C250)amine (LOA) 1855 0 NI 0 NR 0 NI 0 0 (0) 0 0 FD 0
Sulphurized polyolefinamide alkene (C28-C250) amine 2258 CAS No
Sunflower oil 1283 0 NI 0 R 0 NI (0) (0) (1) (0) (1) Fp 2
Sunflower seed oil 2782 CAS No 8001-21-6
sym-Dichlorodiethyl ether 588 1 1 1 NR 1 0 2 3 4 1 3 T SD 3
Dichloroethyl ether 233 CAS No 111-44-4
Tall oil acids/linoleic acid dimer/polyalkylenepolyamines/dodecylbenzenesulphonic acid complexes in 2448 0 NI 0 NR 1 NI 0 0 (0) 0 0 CM Fp 3
naphtha/isopropanol
Tall oil acids/linoleic acid dimer/polyalkylenepolyamines/dodecylbenzenesulphonic acid complexes in 3866 CAS No
naphtha/isopropanol
Tall oil acids reaction products with diethylenetriamine and acrylic acid in ethylene glycol 2497 3 NI 3 R 2 NI 0 0 (1) 0 1 Ss D 2
Tall oil acids reaction products with diethylenetriamine and acrylic acid in ethylene glycol 4131 CAS No 85586-18-1
Tall oil acids reaction products with triethanolamine 2492 4 NI 4 NR 2 NI 0 0 (1) 1 0 Fp 2
Tall oil acids reaction products with triethanolamine 4126 CAS No 67784-78-5
Tall oil, crude and distilled 1285 (4) NI (4) (R) (2) NI 0 0 (0) 0 0 Ss Fp 2
Tall oil (crude and distilled) 678 CAS No 68187-71-3
Tall oil, distilled 2283 0 NI 0 R 0 NI 0 (0) (0) 0 (0) Fp 2
Tall oil, distilled 2890 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 61 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Tall oil fatty acid (resin acids less than 20%) 1287 0 0 0 R 0 0 0 0 (1) 1 0 Fp 2
Tall oil fatty acid (resin acids less than 20%) 679 CAS No 61790-12-3
Tall oil fatty acid, barium salt 1864 NI NI NI NI NI NI (1) (0) (2) 1 2 S 2
Tall oil fatty acid, barium salt 680 CAS No
Tall oil fatty acids reaction products with 2-[(2-aminoethyl)amino]ethanol, di-ethyl sulphate quaternized 2508 (3) NI (3) NR 5 2 NI NI NI (2) (3) Ss D 3
Tall oil fatty acids reaction products with 2-[(2-aminoethyl)amino]ethanol, di-ethyl sulphate quaternized 4160 CAS No 70955-34-9
Tall oil pitch 2323 3 NI 3 NR 0 0 0 0 (0) 0 (0) Fp 2
Tall oil pitch 3051 CAS No
Tall oil soap (disproportionated solution) 1286 NI NI NI NI NI NI (1) (0) (2) 1 2 D 2
Tall oil soap (disproportionated) solution 681 CAS No
Tall oil soap, crude 2432 0 NI 0 R 2 0 (0) (0) (3) (3) (3) Ss Fp 3
Tall oil soap, crude 3735 CAS No
Tallow 1288 0 NI 0 R 0 NI 0 0 (0) (0) (0) Fp 2
Tallow 682 CAS No 61789-21-6
Tallowamidopropylamine Oxide in propylene glycol (70% or less) (#) 2482 NI (2) (2) (R) (4) (2) (1) (1) (3) (3) (3) D 3
4058 CAS No
Tallow fatty acid 1289 0 NI 0 R 0 NI 0 (0) (0) (0) (0) Fp 2
Tallow fatty acid 684 CAS No
1,1,2,2-Tetrachloroethane 53 2 2 2 NR 3 0 2 0 2 2 2 SD 2
Tetrachloroethane 687 CAS No 79-34-5
1,1,2,2-Tetrachloroethylene 1295 3 2 2 NR (3) 2 0 0 0 2 1 C S 3
Perchloroethylene 564 CAS No 127-18-4
Tetrachloromethane 1296 2 2 2 NR 3 0 0 0 0 1 1 CT S 3
Carbon tetrachloride 178 CAS No 56-23-5
Tetradecanoic acid (Myristic acid) 1298 5 NI 0 R 0 NI 0 (0) (1) (1) (1) Fp 2
n-Tetradecanoic acid 491 CAS No 544-63-8
Tetradecanoic acid (Myristic acid) 1298 5 NI 0 R 0 NI 0 (0) (1) (1) (1) Fp 2
Fatty acid (saturated C13+) 347 CAS No 544-63-8
Tetraethylene glycol 1301 0 NI 0 NR 0 NI 0 0 0 1 1 D 1
Tetraethylene glycol 688 CAS No 112-60-7
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 62 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Tetraethylene pentamine 1302 0 NI 0 NR 3 NI 0 2 (3) 3 3 Ss D 3
Tetraethylene pentamine 689 CAS No 112-57-2
Tetraethyl lead 1303 4 5 5 NR 5 NI 3 2 4 2 2 NR S 3
Motor fuel anti-knock compound (containing lead alkyls) 464 CAS No 78-00-2
Tetrahydrofuran 1304 0 NI 0 R 0 NI 0 (0) 0 1 2 DE 2
Tetrahydrofuran 690 CAS No 109-99-9
Tetrahydronaphthalene 1305 3 3 3 NR 3 NI 0 0 (2) 2 0 F 2
Tetrahydronaphthalene 691 CAS No 119-64-2
1,2,3,4-Tetramethylbenzene 1307 4 NI 4 NI 4 NI 0 (0) (1) 1 (1) F 1
Tetramethylbenzene (all isomers) 692 CAS No 488-23-3
Tetrapotassium pyrophosphate 2400 Inorg 0 0 Inorg 1 NI 0 NI NI NI NI D NI
Tetrapotassium pyrophosphate 3635 CAS No 7320-34-5
Thioglycolic acid 2496 0 NI 0 R 2 NI 2 2 3 3B 3 D 3
Thioglycolic acid 4130 CAS No 68-11-1
Thixatrol plus 2210 5 NI 5 R 3 NI 0 0 0 1 1 S 1
Thixatrol Plus 2699 CAS No
Titanium dioxide slurry 2080 Inorg 1 1 Inorg 1 NI 0 0 0 1 1 S 1
Titanium dioxide slurry 2259 CAS No 13463-67-7
Toluene 330 2 2 2 R 3 0 0 0 0 2 2 ANR NT E 3
Toluene 693 CAS No 108-88-3
Toluene diisocyanate 1315 (3) 1 1 NR 2 NI 0 (0) 4 3 3 CSsSr S 3
Toluene diisocyanate 694 CAS No 584-84-9
Toluidines 1316 1 1 1 R 4 2 1 0 (2) 2 2 CM FD 3
o-Toluidine 537 CAS No
2,4-Tolylenediamine 1317 0 2 2 NR 3 0 2 2 4 2 3 CMSs Fp 3
Toluenediamine 695 CAS No 95-80-7
Tolyl triazole 2292 1 NI 1 NR 2 0 1 0 (2) (1) 2 S 2
Tolyl triazole 696 CAS No
Tributyl phosphate 1319 4 2 2 R 3 0 1 0 2 2 2 F 2
Tributyl phosphate 697 CAS No 126-73-8
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 63 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
1,2,3-Trichlorobenzene 2191 4 4 4 NR 4 2 1 0 (2) 2 2 S 2
1,2,3-Trichlorobenzene (molten) 2288 CAS No
1,2,4-Trichlorobenzene 1323 4 5 5 NR 4 1 1 0 (2) 2 2 M S 3
1,2,4-Trichlorobenzene 7 CAS No 120-82-1
1,1,1-Trichloroethane 1326 2 NI 2 NR 2 NI 0 0 0 2 2 SD 2
1,1,1-Trichloroethane 1 CAS No 71-55-6
1,1,2-Trichloroethane 1327 2 1 1 NR 2 0 1 0 1 2 1 SD 2
1,1,2-Trichloroethane 3 CAS No 79-00-5
1,1,2-Trichloro-ethylene 329 2 2 2 NR 3 NI 0 0 0 2 2 MC SD 3
Trichloroethylene 698 CAS No 79-01-6
Trichloromethane 1328 1 1 1 NR 2 0 2 0 2 1 1 CT SD 3
Chloroform 186 CAS No 67-66-3
1,2,3-Trichloropropane 1329 2 2 2 NR 2 0 2 2 2 2 2 C SD 3
1,2,3-Trichloropropane 6 CAS No 96-18-4
1,1,2-Trichloro-1,2,2-trifluoroethane 1330 3 2 2 NR 3 0 0 0 0 1 1 S 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 2 CAS No 76-13-1
Tricresyl phosphate (less than 1% ortho-isomers) 1331 5 (3) (3) (R) (4) (4) 0 1 0 1 1 N S 2
Tricresyl phosphate (containing less than 1% ortho-isomer) 700 CAS No 1330-78-5
Tricresyl phosphate (more than 1% ortho-isomers) 1332 5 3 3 R 4 4 0 1 0 1 1 N S 2
Tricresyl phosphate (containing 1% or more ortho-isomer) 699 CAS No 1330-78-5
Tridecane 1333 0 NI 0 NI 0 NI 0 0 (1) 1 0 Fp 2
Tridecane 701 CAS No 629-50-5
Tridecanoic acid 1334 5 NI 5 (R) 3 NI (0) (0) (1) (1) (1) Fp 2
Tridecanoic acid 702 CAS No 638-53-9
Tridecyl acetate 1768 5 NI 5 NI 0 NI 0 (0) (2) 2 2 F 2
Tridecyl acetate 703 CAS No 1072-33-9
Triethanolamine 1338 0 0 0 R 1 NI 0 0 (2) 1 2 D 2
Triethanolamine 704 CAS No 102-71-6
3-(Triethoxysilyl)propylamine 2445 1 1 1 R 1 NI 1 0 (3) 3B 3 Ss D 3
3-(Triethoxysilyl)propylamine 3824 CAS No 919-30-2
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 64 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Triethylamine 1339 1 0 0 R 3 0 1 2 2 2 3 D 3
Triethylamine 706 CAS No 121-44-8
1,3,5-Triethylbenzene 1340 5 NI 5 NI 4 NI 0 (0) (2) (2) (1) F 2
Triethylbenzene 707 CAS No 25340-18-5
Triethylene glycol 1341 0 NI 0 R 0 0 0 0 0 0 0 D 0
Triethylene glycol 708 CAS No 112-27-6
Triethylenetetramine 1346 0 NI 0 NR 3 NI 0 2 (3) 3 3 Ss D 3
Triethylenetetramine 709 CAS No 112-24-3
Triethylenetetramine/2-piperazine-1-ylethylamine mixtures (#) 2456 0 NI 0 NR 2 NI 0 2 (3) 3 3 Ss D 3
3872 CAS No
Triethyl phosphate 1348 0 0 0 NR 1 0 1 0 0 (2) (2) D 2
Triethyl phosphate 705 CAS No 78-40-0
Triethyl phosphite 1349 0 NI 0 R 1 NI 1 0 2 1 2 Ss FE 2
Triethyl phosphite 710 CAS No 122-52-1
Triglycerides, C16-C18 and C18 unsaturated, reclaimed (UCO) 2470 (5) NI (5) R (0) (0) (0) (0) (1) (1) (1) Fp 2
Used cooking oil (Triglycerides, C16-C18 and C18 unsaturated)** (m) 4023 CAS No 68990-65-8
Triglycerides, C16-C18 and C18 unsaturated, reclaimed (UCO) 2470 (5) NI (5) R (0) (0) (0) (0) (1) (1) (1) Fp 2
Used cooking oil (m) 3974 CAS No 68990-65-8
Triisopropanolamine 1370 0 0 0 NR 1 0 1 0 0 (2) 3 FD 3
Triisopropanolamine 711 CAS No 122-20-3
Triisopropylated phenyl phosphates 1375 5 5 5 R 4 NI 0 0 0 0 0 S 0
Triisopropylated phenyl phosphates 712 CAS No 68937-41-7
Trimethylacetic acid 1350 1 1 1 R 2 NI 1 1 (2) 2 2 Fp 2
Trimethylacetic acid 714 CAS No 75-98-9
Trimethylamine 1353 0 NI 0 R 1 NI 1 0 2 3 3 DE 3
Trimethylamine solution (30% or less) 715 CAS No 75-50-3
1,2,3-Trimethyl benzene 1354 3 3 3 NR 4 0 0 0 1 2 1 FE 2
Trimethylbenzene (all isomers) 716 CAS No 526-73-8
2,4,4-Trimethyl hexamethylene diamine 1359 1 NI 1 NI NI NI 1 0 (3) 2 3 Ss D 3
Trimethylhexamethylenediamine (2,2,4- and 2,4,4-isomers) 718 CAS No 25620-58-0
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 65 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Trimethyl hexamethylene diisocyanate 1360 0 NI 0 NI 3 NI 0 NI NI NI NI SsSr NI 2
Trimethylhexamethylene diisocyanate (2,2,4- and 2,4,4-isomers) 717 CAS No 28679-16-5
Trimethylol propane polyethoxylate 1362 NI NI NI NR 1 NI 0 0 NI NI NI NI NI
Trimethylolpropane polyethoxylate 719 CAS No
Trimethylol propane, propoxylated 2274 0 NI 0 (NR) 1 0 0 0 (1) 0 1 SD 1
Trimethylol propane propoxylated 2870 CAS No
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 1845 4 NI 4 NR 0 NI 0 0 (1) 1 0 F 1
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 26 CAS No
2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate 1364 3 NI 3 NI 2 NI 0 0 (1) 1 1 Fp 2
2,2,4-Trimethyl-1,3-pentanediol-1-isobutyrate 27 CAS No 25264-77-4
Trimethyl phosphite 1365 0 NI 0 R NI NI NI NI NI NI NI S NI
Trimethyl phosphite 713 CAS No 121-45-9
1,3,5-Trioxane 1844 0 NI 0 NI 0 NI 0 0 0 0 1 R SD 3
1,3,5-Trioxane 10 CAS No 110-88-3
Tripropylene glycol 1372 0 0 0 R 0 0 0 0 (0) 0 0 D 0
Tripropylene glycol 720 CAS No 24800-44-0
Trixylenyl phosphate 1377 5 4 4 NR 4 1 (0) (1) (0) (1) (1) R S 3
Trixylyl phosphate 721 CAS No 25155-23-1
Tung oil 1378 0 NI 0 R (2) NI (0) (0) (1) (0) (1) Fp 2
Tung oil 2784 CAS No
Turpentine (wood) 1379 4 NI 4 NI 4 NI 0 (0) 1 (2) 2 SsA (T) D 2
Turpentine 722 CAS No 8006-64-2
Undecanoic acid 1381 4 NI 4 (R) 3 NI (0) (0) (2) 1 (2) Fp 2
Undecanoic acid 723 CAS No 112-37-8
1-Undecanol 1382 4 NI 4 R 4 NI 0 0 (2) 2 (1) Fp 2
Undecyl alcohol 724 CAS No 112-42-5
1-Undecene 1383 5 NI 5 NR 4 NI (0) (0) (1) (2) (1) A F 3
1-Undecene 24 CAS No 821-95-4
Urea 1384 0 0 0 R 1 NI 0 0 (1) 1 (1) D 1
Urea 2627 CAS No 57-13-6
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 66 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Urea 1384 0 0 0 R 1 NI 0 0 (1) 1 (1) D 1
Urea solution 726 CAS No 57-13-6
Urea/Ammonium mono and dihydrogen phosphate/ Potassium chloride solution 1386 0 0 0 R 3 2 NI NI NI NI NI NI NI
Urea/Ammonium mono- and di-hydrogen phosphate/Potassium chloride solution 727 CAS No
Urea/Ammonium nitrate solution (containing < 1% aq. ammonia) 1387 0 NI 0 R (2) (0) 0 0 (1) (1) (1) D 1
Urea/Ammonium nitrate solution 729 CAS No
Urea-ammonium phosphate solutions 2179 0 0 0 R 3 2 (0) (0) (2) (2) (2) D 2
Urea/Ammonium phosphate solution 730 CAS No
Urea-formaldehyde resin solution 1388 NI NI NI NI 1 NI 1 1 NI NI NI Ss NI 2
Urea formaldehyde resin solution 725 CAS No
Vegetable acid oils 2371 0 NI 0 R 0 NI (0) (0) (1) (1) (1) Fp 2
Vegetable acid oils (m) 3138 CAS No
Vegetable oils fatty acid distillates 2369 0 NI 0 R 0 NI (0) (0) (0) (0) (0) Fp 2
Vegetable fatty acid distillates (m) 3137 CAS No
Vegetable protein solution,hydrolyzed 1398 0 NI 0 R 0 NI (0) (0) (0) (0) (0) D 0
Vegetable protein solution (hydrolysed) 734 CAS No
Vinyl acetate 1400 0 NI 0 R 2 NI 1 0 2 1 1 C ED 3
Vinyl acetate 735 CAS No 108-05-4
Vinyl ethyl ether 1405 1 NI 1 NR 1 NI 0 0 0 1 1 E 2
Vinyl ethyl ether 736 CAS No 109-92-2
Vinylidene chloride 1406 2 1 1 NR 2 NI 2 0 (2) 2 2 M SD 3
Vinylidene chloride 738 CAS No 75-35-4
Vinyl neodecanoate 1404 5 NI 5 NR 3 NI 0 0 (3) 3 3 F 3
Vinyl neodecanoate 737 CAS No 45115-34-2
Vinyl toluenes 1409 3 3 3 NR 3 NI 0 0 2 2 1 NM (T) F 3
Vinyltoluene 739 CAS No 25013-15-4
White spirit, low (15-20%)aromatic 1411 (4) NI (4) (R) 3 NI (0) (0) (2) (1) (2) A F 3
White spirit, low (15-20%) aromatic 742 CAS No
Wood lignin with sodium acetate/oxalate 2403 NI NI (0) NR (0) NI 0 (0) (1) (1) (1) D 1
Wood lignin with sodium acetate/oxalate 3638 CAS No
ANNEX 6 - GESAMP COMPOSITE LIST
GESAMP Hazard Profiles 12 April 2019
Page 67 of 67
EHS Name EHS A1a A1b A1 A2 B1 B2 C1 C2 C3 D1 D2 D3 E1 E2 E3
TRN Name TRN
Xylene (mixed isomers) 1408 3 NI 3 NR 3 0 0 0 0 2 2 (T) FE 2
Xylenes 743 CAS No 133-20-7
Xylenes/Ethyl benzene (10% or more) mixture 2269 3 2 2 NR 3 1 (0) (0) (2) (2) (2) (T) FE 2
Xylenes/ethylbenzene (10% or more) mixture 2337 CAS No
Xylenols (mixtures) 1422 2 NI 2 R 3 NI 1 2 (3) 3 3 (T) Fp 3
Xylenol 744 CAS No 1300-71-6
Yeast Extract Solution with Propylene Glycol (25% or less) 2396 NI 0 0 R 0 NI 0 0 (1) 0 1 D 1
Stabilized Yeast Extract Solution 3631 CAS No 8013-01-2
Zinc alkaryl dithiophosphate (C7-C16) (LOA) 1977 0 NI 0 NR 3 NI 0 0 (0) (0) (0) Fp 2
Zinc alkaryl dithiophosphate (C7-C16) 745 CAS No
Zinc alkenylcarboxamide (LOA) 2053 NI 0 0 NR 0 NI 0 0 (1) 1 (1) Fp 2
Zinc alkenyl carboxamide 746 CAS No
Zinc alkyl dithiophosphate 1428 5 NI 5 NR 3 NI 0 0 0 2 2 S 2
Zinc alkyl dithiophosphate (C3-C14) 747 CAS No
Zinc bromide solutions 2227 Inorg 4 4 Inorg 3 NI 1 (2) (3) 3B 3 Ss D 3
Zinc bromide solutions 2617 CAS No
Zinc chloride 1425 Inorg 4 4 Inorg 4 1 (1) (1) (3) (3) (3) D 3
Zinc chloride 2869 CAS No 7646-85-7
Zinc chloride 1425 Inorg 4 4 Inorg 4 1 (1) (1) (3) (3) (3) D 3
Drilling brines (containing zinc chloride) 307 CAS No 7646-85-7

***
EHS 56/9
Annex 7, page 1

ANNEX 7

PROVISIONAL AGENDA FOR THE FIFTY-SEVENTH SESSION OF THE


GESAMP/EHS WORKING GROUP

1 Adoption of the agenda

2 Outcome of other bodies

3 Evaluation of new substances

4 Re-evaluation of substances and consideration of issues related to evaluations

5 Classification issues

6 Consolidation of existing data files

7 Communication and publication

8 Any other business

9 Consideration and adoption of the report

___________

I:\CIRC\PPR\01\PPR 1-CIRC 6.docx

You might also like