Aluminium, Copper and Its Alloys
Aluminium, Copper and Its Alloys
Aluminium, Copper and Its Alloys
alloys
Properties
• Brasses
• Brasses are copper zinc alloys containing up to about 45% zinc, with possibly small additions of
lead for machinability, and tin for strength. Copper zinc alloys are single phase up to about 37%
zinc in the wrought condition. The single phase alloys have excellent ductility, and are often used
in the cold worked condition for better strength. Alloys with more than about 37% zinc are dual
phase, and have even higher strength, but limited ductility at room temperature compared to the
single phase alloys. The dual phase brasses are usually cast or hot worked.
• Typical uses for brasses are architecture, drawn & spun containers and components, radiator cores
and tanks, electrical terminals, plugs and lamp fittings, locks, door handles, name plates, plumbers
hardware, fasteners, cartridge cases, cylinder liners for pumps.
Copper nickel are alloys of copper with nickel, with a small amount of iron and sometimes other minor
alloying additions such as chromium or tin. The alloys have outstanding corrosion resistance in waters,
and are used extensively in sea water applications such as heat exchangers, condensers, pumps and
piping systems, sheathing for boat hulls.
Nickel silvers contain 55–65% copper alloyed with nickel and zinc, and sometimes an addition of lead to
promote machinability. These alloys get their misleading name from their appearance, which is similar
to pure silver, although they contain no addition of silver. They are used for jewelry and name plates and
as a base for silver plate (EPNS), as springs, fasteners, coins, keys and camera parts.
Properties of Copper Alloys
• Corrosion Resistance of Copper. All copper alloys resist corrosion by fresh water and steam. In most rural, marine and industrial
atmospheres copper alloys are also resistant to corrosion. Copper is resistant to saline solutions, soils, non-oxidizing minerals, organic acids
and caustic solutions. Moist ammonia, halogens, sulfides, solutions containing ammonia ions and oxidizing acids, like nitric acid, will attack
copper. Copper alloys also have poor resistance to inorganic acids.
• The corrosion resistance of copper alloys comes from the formation of adherent films on the material surface. These films are relatively
impervious to corrosion therefore protecting the base metal from further attack.
• Ductility can be restored by annealing. This can be done either by a specific annealing process or by incidental annealing through welding or
brazing procedures.
• There are four common ways to harden (strengthen) copper. A fifth, spinodal composition, is currently used commercially only in certain
copper-nickel-tin alloys. Combinations of strengthening mechanisms are often used to provide higher mechanical properties in high-copper
alloys.
• Strain Hardening. The application of cold work, usually by rolling or drawing, hardens copper and copper alloys. Strength, hardness and
springiness increase, while ductility decreases. Conductivity is reduced to a small extent, normally not to the extent that it hinders use of the
alloys in electrical products. The effect of cold work can be removed by annealing, in which case full conductivity returns. Strain hardening is
the only strengthening mechanism that can be used with pure copper.
• Solid-Solution Hardening. Alloying elements that remain dissolved in solidified copper strengthen the lattice structure. If the addition is
within the limit of the element’s solid solubility, no secondary phases form, and the appearance under the microscope is similar to that of pure
copper.
• Precipitation Hardening. Some alloying elements exhibit higher solubility in solid copper when hot than when cold. This means they can be dissolved by solution
treatment (solution annealing) at high temperatures, around 950–1000°C, and then removed from solution by a precipitation (or "aging") treatment at a lower
temperature, commonly around 1200°F (650°C).
Applications of Copper
• Definition
• Brass: Brass is a metal alloy composed of copper and zinc.
• Bronze: Bronze is a metal alloy composed of copper and tin.
• Appearance
• Brass: Brass is often bright golden in color.
• Bronze: Bronze is reddish-brown in color.
• Components
• Brass: Brass is mainly composed of copper and zinc. But sometimes aluminum and lead are also added.
• Bronze: Bronze is mainly composed of copper and tin metals. But sometimes, arsenic, phosphorous, aluminum,
manganese and silicon are also added.
• Malleability
• Brass: Brass has a high degree of malleability.
• Bronze: Bronze is hard and brittle.
Continue……
Corrosion Resistance
Uses
Bronze: Bronze is used in the production of boat and ship fittings due to corrosion resistance towards salt water.
Hardness
Brass: Brass is a soft metal and should not be used around flammable materials.
Bronze: Bronze is a hard metal, so it can be used around flammable and explosive materials.