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SULFOCHEMTM B-213K SURFACTANT BLEND

Material Safety Data Sheet


Lubrizol SULFOCHEMTM B-213K SURFACTANT BLEND

Prepared according to 29CFR 1910.1200.

Chemical Product and Company Identification

The Lubrizol Corporation


29400 Lakeland Boulevard
Wickliffe, Ohio 44092
Tel: (440) 943-4200

Product Trade Name SULFOCHEMTm B-213K SURFACTANT BLEND


CAS Number Not applicable for mixtures.
Synonyms None.
Generic Chemical Name Mixture.
Product Type Specialty Surfactants
Preparation/Revision Date 15 January 2013
Transportation Emergency Phone FOR TRANSPORT EMERGENCY call CHEMTREC: (+I) 703-527-3887 (outside the U.S.), 1-800-424-9300 (in the
No. U.S.)
MSDS No. 22349691-3516911-3015331-102103

2 I Hazards Identification
Appearance Clear water white liquid.
Odor Not Available
Principal Hazards Caution.
. May cause eye irritation.
. May cause skin irritation.
. May cause respiratory tract irritation.

See Section 11 for complete health hazard information.

1 3 I Composition/Information on Ingredients
Hazardous Ingredients
Comp CAS No. T -- Percentage (by wt.) Carcinogen
Sodium lauryl ether sulfate 68585-34-2 From 10 to 19.9 percent N/E
Coconut diethanolamide 68603-42-9 From 5 to 9.9 percent IARC Suspect Carcinogen
Cocamidopropyl betaine 61789-40-0 From 5 to 9.9 percent N/E
Glycerin 56-81-5 From 1 to 4.9 percent N/E
Diethanolamine 111-42-2 0.4% IARC Suspect Carcinogen

(N/E) - None established

4 First Aid Measures

Eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists, get medical attention.
Skin Wash with soap and water. Remove contaminated clothing. If skin irritation occurs, get medical attention.
Inhalation Remove exposed person to fresh air if adverse effects are observed. Call a poison center or doctor if exposed or you feel
unwell.
Oral Treat symptomatically. Get medical attention.
Additional Information If exposed or concerned: Get medical attention.

5 Fire Fighting Measures

Flash Point >= 94 °C, 201.2 °F PMCC (Minimum)


Extinguishing Media CO2, dry chemical, foam, water spray, water fog.
Firefighting Procedures Wear full protective firegear including self-containing breathing apparatus operated in the positive pressure mode with full
facepiece, coat, pants, gloves and boots. Water may cause splattering.

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SULFOCHEMTm B-21 3K SURFACTANT BLEND
Unusual Fire & Explosion Hazards Material will not burn until water has been evaporated. Container may rupture on heating. See section 10 for additional
information.

6 Accidental Release Measures

Spill Procedures Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Take precautions
to avoid release to the environment. Ventilate area if spilled in confined space or other poorly ventilated areas. Prevent entry
into sewers and waterways, dispose of in accordance with all federal, state and local environmental regulation. Spilled liquid
and dried film are slippery. Use care to avoid falls. Pick up free liquid for recycle and/or disposal. Residual liquid can be
absorbed on inert material.

7 Handling and Storage

Pumping Temperature Not determined.


Maximum Handling Temperature Not determined.
Handling Procedures Keep containers closed when not in use. Do not discharge into drains or the environment, dispose to an authorized waste
collection point. Use appropriate containment to avoid environmental contamination. Avoid contact with skin or eyes. Avoid
drinking, tasting, swallowing or ingesting this product. Avoid inhalation of aerosol, mist, spray, fume or vapor. Avoid
breathing dust, fume, gas, mist, vapors or spray. Minimize contact with air to reduce contamination with mold, fungus, or
other organisms which could cause decomposition or spoilage. Wash thoroughly after handling. Launder contaminated
clothing before reuse. Empty container contains product residue which may exhibit hazards of product. Dispose of packaging
or containers in accordance with local, regional, national and international regulations.
Maximum Storage Temperature 49 °C, 120.2 °F
Storage Procedures Take precautions to avoid release to the environment. Keep from freezing. Store in a cool, dry, well-ventilated area. Keep
container closed when not in use. Do not store at temperatures greater than 120 deg F (49 deg C). Do not store in open,
unlabeled or mislabeled containers. See section 10 for incompatible materials.
Maximum Loading Temperature Not determined.

1 8
I Exposure Controls/Personal Protection
Exposure Limits
Exposure Guidelines
OSHA ACGIH
I
Comp TWA L TWA STEL TWA
Glycerin 15 mg/cu. M N/E 10 mg/cu M N/E N/E
Diethanolamine N/E N/E I mg/cu M (s) 1 N/E N/E

(s) - Skin exposure


(p) - Proposed limit
(c) - Ceiling exposure
(1) - Recommended exposure limit
(u) - Supplier recommended exposure limit
(N/E) - None established
Other Exposure Limits None known.
Engineering Controls Use material in well ventilated area only. Additional ventilation or exhaust may be required to maintain air concentrations
below recommended exposure limits. Prevent inhalation by providing effective general and, when necessary, local exhaust
ventilation to draw spray, aerosol, fume, mist, or vapor away from workers.
Gloves Procedures Use good industrial hygiene practices to avoid skin contact. If contact with the material may occur wear chemically
protective gloves.
Eye Protection Safety Glasses.
Respiratory Protection Use NIOSH/MSHA approved respirator with a combination organic vapor and high efficiency filter cartridge if
recommended exposure limit is exceeded Use self-contained breathing apparatus for entry into confined space, for other
poorly ventilated areas and for large spill clean-up sites.
Clothing Recommendation Gloves, coveralls, apron, boots as necessary to minimize contact. Wear a chemically protective apron when contact with
material may occur. Use nitrite rubber boots when necessary to avoid contaminating shoes. Do not wear rings, watches or
similar apparel that could entrap the material and cause a skin reaction.

9 Physical and Chemical Properties

Flash Point >= 94 °C, 201.2 °F PMCC (Minimum)


Upper Flammable Limit Not determined.
Lower Flammable Limit Not determined.
Autoignition Point Not determined.
Explosion Data Material does not have explosive properties.
Vapor Pressure —18 mm Hg (20 °C)
pH 5.5 - 6 at 10% in water
Specific Gravity 1.06 (20 °C)
Bulk Density 8.84 Lb/gal, 1.06 Kg/L

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SULFOCHEMTM B-213K SURFACTANT BLEND
Water Solubility Dispersible.
Percent Solid — 37% By Weight
Percent Volatile 61 - 65% By Weight
Volatile Organic Compound Not determined,
Vapor Density < 1 Air-1
Evaporation Rate < 1 Butyl acetate —1
Odor Not Available
Appearance Clear water white liquid.
Viscosity < 5000 Centipoise (25 °C)
Odor Threshold Not determined.
Boiling Point — 100 °C, — 212 °F(Typical)
Pour Point Temperature Not determined.
Melting / Freezing Point — 0 °C, — 32 °F

The above data are typical values and do not constitute a specification. Vapor pressure data are calculated
unless otherwise noted

110 I Stability and Reactivity

Stability Material is normally stable at moderately elevated temperatures and pressures.


Decomposition Temperature Not determined.
Incompatibility Strong acids. Strong bases. Oxidizing agents. This material contains amine. Do not add nitrite or other nitrosating agents due
to the potential for nitrosamine formation.
Polymerization Will not occur.
Thermal Decomposition Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete combustion. Irritating and toxic
substances may be emitted upon combustion, burning, or decomposition of dry solids.
Conditions to Avoid Do not freeze.

Toxicological Information

— ACUTE EXPOSURE —
Eye Irritation Weak to moderate eye irritant. Does not meet EU R36 criteria. Based on data from components or similar materials.
Skin Irritation May cause mild skin irritation. Does not meet Canadian D2B or EU R38 criteria. Based on data from components or similar
materials.
Respiratory Irritation May cause nose, throat, and lung irritation. Based on data from components or similar materials.
Dermal Toxicity The LD50 in rabbits is > 2000 mg/Kg. Based on data from components or similar materials.
Inhalation Toxicity Avoid inhalation of mists or vapors.
Oral Toxicity The LD50 in rats is > 10,000 mg/Kg. Based on data from components or similar materials. Swallowing material may cause
irritation of the gastrointestinal lining, nausea, vomiting, diarrhea, and abdominal pain.
Dermal Sensitization No data available to indicate product or components may be a skin sensitizer.
Inhalation Sensitization No data available to indicate product or components may be respiratory sensitizers.

— CHRONIC EXPOSURE —
Chronic Toxicity No data available to indicate product or components present at greater than 1% are chronic health hazards.
Carcinogenicity Diethanolamine has been classified by IARC as a possible human carcinogen (Group 2B). Coconut diethanolamide has been
classified by IARC as a possible human carcinogen (Group 2B).
Mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Reproductive Toxicity No data available to indicate either product or components present at greater than 0.1% that may cause reproductive
toxicity.
Teratogenicity No data available to indicate product or any components contained at greater than 0.1% may cause birth defects.

—ADDITIONAL INFORMATION —
Other Nitrosamines may be formed under certain conditions. Nitrosamines are carcinogenic in animal studies.

[12 [Ecological Information

—ENVIRONMENTAL TOXICITY —
Freshwater Fish Toxicity The acute LC50 is 1 - 10 mg/L based on component data.
Freshwater Invertebrates Toxicity The acute EC50 is 1 - 10 mg/L based on component data. Chronic effects expected at < 1 mg/L based on component data.
Algal Inhibition The acute EC50 is 10 - I00 mg/L based on component data.
Saltwater Fish Toxicity Not determined.
Saltwater Invertebrates Toxicity Not determined.
Bacteria Toxicity Not determined.

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SULFOCHEMTM B-213K SURFACTANT BLEND
Miscellaneous Toxicity Not determined.

— ENVIRONMENTAL FATE—
Biodegradation At least 75% of the components in this product show rapid biodegradation based on OECD 301-type test data.
Bioaccumulation 25% or greater of the components display no potential to bioconcentrate.
Soil Mobility Not determined.

13 Disposal Considerations

Waste Disposal This material, if discarded, is not a hazardous waste under RCRA Regulation 40 CFR 261. Treatment, storage,
transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations.

14 Transport Information

ICAO/IATA I Not regulated.


ICAO/IATA II Not regulated.
IMDG Not regulated.
IMDG EMS Fire Not applicable.
IMDG EMS Spill Not applicable.
IMDG MFAG Not applicable.
MARPOL Annex II Not determined.
USCG Compatibility Not determined.
U.S. DOT Bulk UN3082 Environmentally hazardous substance, liquid, n.o.s. (Diethanolamine) 9 , 111, RQ (Diethanolamine)
DOT NAERG 171
U.S. DOT (Intermediate) UN3082 Environmentally hazardous substance, liquid, n.o.s. (Diethanolamine) 9 ,1I1, RQ (Diethanolamine)
U.S. DOT Intermediate NAERG 171
U.S. DOT Non-Bulk Not regulated.
U.S. DOT Non-Bulk NAERG Not applicable.
Canada Not regulated.
Mexico Not regulated.
Bulk Quantity 85000 KG, 187391 lbs.
Intermediate Quantity 11000 KG, 24251 lbs.
Non-Bulk Quantity 400 KG, 882 lbs.

Review classification requirements before shipping materials at elevated temperatures.

115 I Regulatory Information

— Global Chemical Inventories —


USA All components of this material are on the US TSCA Inventory or are exempt.

Other TSCA Reg. None known.


EU To obtain information on the REACH compliance status of this product, please visit Lubrizot.com/REACH, or e-mail us at
REACH MSDS_INQUIRIES®LubrizoLcom
Japan All components are in compliance with the Chemical Substances Control Law of Japan.
Australia All components are in compliance with chemical notification requirements in Australia.
New Zealand All components are in compliance with chemical notification requirements in New Zealand.
Canada All components are in compliance with the Canadian Environmental Protection Act and are present on the Domestic
Substances List.
Switzerland All components are in compliance with the Environmentally Hazardous Substances Ordinance in Switzerland.
Korea All components are in compliance in Korea.
Philippines All components are in compliance with the Philippines Toxic Substances and Hazardous and Nuclear Wastes Control Act of
1990 (R.A. 6969).
China All components of this product are listed on the Inventory of Existing Chemical Substances in China.
Taiwan May require notification before sale in Taiwan.

— Other U.S. Federal Regulations —


SARA Ext. Has. Subst. This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substances
list
SARA Section 313 0.4% Diethanolamine, CAS no. 111-42-2
SARA 311 Classifications cute Hazard TYes
Chronic Hazard Yes
Fire Hazard No
Reactivity Hazard No

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SULFOCHEMTM B-213K SURFACTANT BLEND
CERCLA Hazardous Substances
Transit Reportable Quantities

ComP (inentiA:Re portable Q61161104 halts RePorilible RQ


Diethanolamine 22593 lbs. 102481KG

— State Regulations —
Cal. Prop. 65 This product contains the following chemical(s) known to the state of California to cause cancer and/or birth defects: 6 ppm
Formaldehyde, CAS no. 50-00-0 0.008% 1, 4 Dioxane, CAS no. 123-91-1 0.443% Diethanolamine, CAS no. 111-42-2
7.5% Coconut diethanolamide, CAS no. 68603-42-9

— Product Registrations —
U.S. Fuel Registration Not applicable.
Finnish Registration Number Not Registered
Swedish Registration Number Not Registered
Norwegian Registration Number Not Registered
Danish Registration Number Not Registered
Swiss Registration Number Not Registered
Italian Registration Number Not Registered

— Other / International —
Miscellaneous Regulatory
Not determined.
Information

16 Other Information

US NFPA Codes

(N/E) - None established

HMIS Codes Health Fire Reactivity


0
Precautionary Labels Caution.
. May cause eye irritation.
. May cause skin irritation.
. May cause respiratory tract irritation.

Revision Indicators Section: 3 Hazardous ingredients. Changed: 19 October 2012


Section: 4 Additional first aid measures. Changed: 19 October 2012
Section: 5 Flash point. Changed: 27 May 2012
Section: 8 Clothing recommendations. Changed: 19 October 2012
Section: 8 Hazardous ingredients. Changed: 19 October 2012
Section: 9 Flash point. Changed: 27 May 2012
Section: 11 Cacinogenicity. Changed: 19 October 2012
Section: 15 California proposition 65. Changed: 19 October 2012
Section: 15 SARA section 311/312. Changed: 19 October 2012
Section: 15 SARA section 313. Changed: 19 October 2012

As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information
contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the
hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local regulations remains the
responsibility of the user.

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