Safety data sheet

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

ORYX
1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: crop protection product, herbicide

1.3. Details of the supplier of the safety data sheet

Company: Contact address:

BASF SE BASF plc
67056 Ludwigshafen PO Box 4, Earl Road, Cheadle Hulme,
GERMANY Cheadle, Cheshire
SK8 6QG, UNITED KINGDOM

Telephone: +44 161 485-6222

E-mail address: [email protected]

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Skin Sens. 1
Carc. 2
Aquatic Acute 1
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
Aquatic Chronic 1

According to Directive 67/548/EEC or 1999/45/EC

Carc. Cat. 3

Possible Hazards:
Limited evidence of a carcinogenic effect.
May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

Globally Harmonized System (GHS) in accordance with UK regulations.

Pictogram:

Signal Word:
Warning

Hazard Statement:
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
EUH401 To avoid risks to human health and the environment, comply with the
instructions for use.

Precautionary Statements (Prevention):

P261 Avoid breathing mist.
P280 Wear protective gloves/clothing.

Precautionary Statements (Response):

P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P391 Collect spillage.

Precautionary Statements (Storage):

P405 Store locked up.

Precautionary Statements (Disposal):

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
P501 Dispose of contents/container to a licensed hazardous-waste disposal
contractor or collection site except for empty clean containers which can
be disposed of as non-hazardous waste.

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: METAZACHLOR

According to Directive 67/548/EEC or 1999/45/EC

Classification/labelling in accordance with UK regulations.

Hazard symbol(s)
Xn Harmful.

N Dangerous for the environment.

R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.

S-phrase(s)
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S20/21 When using do not eat, drink or smoke.
S23.1 Do not breathe spray.
S24 Avoid contact with skin.
S35 This material and its container must be disposed of in a safe way.
S36 Wear suitable protective clothing.
S46 If swallowed, seek medical advice immediately and show this container
or label.
S57 Use appropriate container to avoid environmental contamination.

Hazard determining component(s) for labelling: METAZACHLOR

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Chemical nature

crop protection product, herbicide, suspension concentrate (SC)

Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008

2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide
Content (W/W): 29.5 % Skin Sens. 1B
CAS Number: 67129-08-2 Carc. 2
EC-Number: 266-583-0 Aquatic Acute 1
Aquatic Chronic 1
H317, H351, H400, H410
M-factor acute: 100
M-factor chronic: 100

8-Quinolinecarboxylic acid, 7-chloro-3-methyl-

Content (W/W): 7.3 % Aquatic Chronic 3
CAS Number: 90717-03-6 H412
EC-Number: 402-790-6
REACH registration number: 01-
0000015252-80

phenolsulfonic acid-formaldehyde-polycondensate as sodium salt

Content (W/W): < 5 % Eye Dam./Irrit. 2
Aquatic Chronic 3
H319, H412

Propane-1,2-diol
Content (W/W): < 10 %
CAS Number: 57-55-6
EC-Number: 200-338-0
REACH registration number: 01-
2119456809-23
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
Hazardous ingredients
according to Directive 1999/45/EC

2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide
Content (W/W): 29.5 %
CAS Number: 67129-08-2
EC-Number: 266-583-0
Hazard symbol(s): Xn, N
R-phrase(s): 40, 43, 50/53
Carc. Cat. 3

8-Quinolinecarboxylic acid, 7-chloro-3-methyl-

Content (W/W): 7.3 %
CAS Number: 90717-03-6
EC-Number: 402-790-6
REACH registration number: 01-0000015252-80
R-phrase(s): 52/53

phenolsulfonic acid-formaldehyde-polycondensate as sodium salt

Content (W/W): < 5 %
R-phrase(s): 52/53

Propane-1,2-diol
Content (W/W): < 10 %
CAS Number: 57-55-6
EC-Number: 200-338-0
REACH registration number: 01-2119456809-23

For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Show container, label and/or safety data sheet to physician.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Do not induce vomiting unless told to by a poison control center or doctor. Never induce vomiting or
give anything by mouth if the victim is unconscious or having convulsions.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, foam, dry powder, carbon dioxide

5.2. Special hazards arising from the substance or mixture

carbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds
The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems. Dispose of fire debris and contaminated extinguishing water in accordance with official
regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying
with water if exposed to fire.

SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Do not breathe vapour/spray. Use personal protective clothing. Avoid contact with the skin, eyes and
clothing.

6.2. Environmental precautions

Do not allow contamination of public drains or surface or ground waters. Inform local water plc if
spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental
Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters
surface or ground waters. Keep people and animals away.

6.3. Methods and material for containment and cleaning up

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers,
which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and
detergents, observing environmental regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.

Protection against fire and explosion:

No special precautions necessary. The substance/product is non-combustible. Product is not
explosive.

7.2. Conditions for safe storage, including any incompatibilities

Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.

Protect from temperatures below: -10 °C

The product crystallizes below the limit temperature.
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

57-55-6: Propane-1,2-diol
TWA value 10 mg/m3 (WEL/EH 40 (UK)), Particulate
TWA value 474 mg/m3 ; 150 ppm (WEL/EH 40 (UK)), Total vapour and
particulates

Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United
Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the
following apply.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Combination filter for
gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures

The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: suspension
Colour: off-white
Odour: faint specific odour, aromatic
Odour threshold:
Not determined due to potential
health hazard by inhalation.
pH value: approx. 4 - 6
(20 °C)
crystallization temperature: approx. -4.3 °C
boiling temperature: approx. 100 °C
Information applies to the solvent.
Flash point: (Directive 92/69/EEC, A.9)
No flash point - Measurement made
up to the boiling point.
Evaporation rate:
not applicable
Flammability: not highly flammable (Directive 92/69/EEC, A.12)
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
Lower explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Ignition temperature: 555 °C (Directive 92/69/EEC, A.15)
Vapour pressure: approx. 23 hPa
(20 °C)
Information applies to the solvent.
Density: approx. 1.13 g/cm3 (OECD Guideline 109)
(20 °C)
Relative vapour density (air):
not applicable
Solubility in water: dispersible
Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide
Partitioning coefficient n-octanol/water (log Kow): 2.13
(22 °C)
Information on: 8-Quinolinecarboxylic acid, 7-chloro-3-methyl-
Partitioning coefficient n-octanol/water (log Kow): -1.41 (OECD Guideline 117)
(21 °C; pH value: 7)
----------------------------------
Thermal decomposition: 150 °C, 200 J/g (DSC (OECD 113))
250 °C, 10 J/g (DSC (OECD 113))
285 °C, 90 J/g (DSC (OECD 113))
Viscosity, dynamic: approx. 39 mPa.s (OECD 114)
(20 °C, 100 1/s)
Explosion hazard: not explosive (Directive 92/69/EEC, A.14)
Fire promoting properties: not fire-propagating

9.2. Other information

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:
strong acids, strong bases, strong oxidizing agents

10.6. Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic
by inhalation. The product has not been tested. The statement has been derived from
substances/products of a similar structure or composition.

Experimental/calculated data:
LD50 rat (oral): 4,070 mg/kg (OECD Guideline 401)

LC50 rat (by inhalation): > 5.7 mg/l 4 h (OECD Guideline 403)

LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)

Irritation

Assessment of irritating effects:

Not irritating to the eyes. Not irritating to the skin.

Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Respiratory/Skin sensitization

Assessment of sensitization:
Sensitization after skin contact possible. The product has not been tested. The statement has been
derived from the properties of the individual components.

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

Experimental/calculated data:
Guinea pig maximization test guinea pig: skin sensitizing (similar to OECD guideline 406)
----------------------------------

Germ cell mutagenicity

Assessment of mutagenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity

Assessment of carcinogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

Assessment of carcinogenicity:
Indication of possible carcinogenic effect in animal tests.
----------------------------------

Reproductive toxicity

Assessment of reproduction toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Animal studies gave no indication of a developmental toxic effect at doses
that were not toxic to the parental animals.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
Assessment of repeated dose toxicity:
Repeated exposure to large quantities may affect certain organs.
----------------------------------

Other relevant toxicity information

Misuse can be harmful to health.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

Toxicity to fish:
LC50 (96 h) approx. 22 mg/l, Oncorhynchus mykiss (OPP 72-1 (EPA-Guideline), static)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

Aquatic plants:
EC50 (72 h) 0.043 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

The product has not been tested. The statement has been derived from the properties of the
individual components.

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).

Information on: 8-Quinolinecarboxylic acid, 7-chloro-3-methyl-

Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
----------------------------------

12.3. Bioaccumulative potential

Assessment bioaccumulation potential:

The product has not been tested. The statement has been derived from the properties of the
individual components.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

Bioaccumulation potential:
No significant accumulation in organisms is expected as a result of the distribution coefficient of n-
octanol/water (log Pow).

Information on: 8-Quinolinecarboxylic acid, 7-chloro-3-methyl-

Bioaccumulation potential:
Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to
be expected.
----------------------------------

12.4. Mobility in soil

Assessment transport between environmental compartments:

Adsorption in soil: The product has not been tested. The statement has been derived from the
properties of the individual components.

Information on: 2-Chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)acetamide

Assessment transport between environmental compartments:
Adsorption in soil: Following exposure to soil, the product trickles away and can - dependant on
degradation - be transported to deeper soil areas with larger water loads.

Information on: 8-Quinolinecarboxylic acid, 7-chloro-3-methyl-

Assessment transport between environmental compartments:
Adsorption in soil: Following exposure to soil, the product trickles away and can - dependant on
degradation - be transported to deeper soil areas with larger water loads.
----------------------------------

12.5. Results of PBT and vPvB assessment

The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria
or the vPvB (very persistent/very bioaccumulative) criteria.

12.6. Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.

12.7. Additional information

Other ecotoxicological advice:

Do not discharge product into the environment without control.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Must be sent to a suitable incineration plant, observing local regulations.

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
This product and any uncleaned containers must be disposed of as hazardous waste in accordance
with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)

Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.

SECTION 14: Transport Information

Land transport

ADR
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains METAZACHLOR)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for Tunnel code: E
user:

RID
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains METAZACHLOR)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

Inland waterway transport

ADN
UN number UN3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains METAZACHLOR)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:
Transport in inland Not evaluated
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
waterway vessel:

Sea transport

IMDG
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains METAZACHLOR)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Marine pollutant: YES
Special precautions for None known
user:

Air transport

IATA/ICAO
UN number: UN 3082
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains METAZACHLOR)
Transport hazard class(es): 9, EHSM
Packing group: III
Environmental hazards: yes
Special precautions for None known
user:

14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

Further information
This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of
Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).

SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

To avoid risks to man and the environment, comply with the instructions for use.

The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'
(United Kingdom).
This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,
(CHIP) (United Kingdom).
This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and
amendments if specific threshold tonnages are exceeded (United Kingdom).

15.2. Chemical Safety Assessment

Advice on product handling can be found in sections 7 and 8 of this safety data sheet.

SECTION 16: Other Information

For proper and safe use of this product, please refer to the approval conditions laid down on the
product label.

Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Xn Harmful.
N Dangerous for the environment.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitization by skin contact.
 Page: 17/17
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 06.10.2014 Version: 5.0
Product: ORYX
(ID no. 30339580/SDS_CPA_GB/EN)
Date of print 08.10.2014
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Skin Sens. Skin sensitization
Carc. Carcinogenicity
Aquatic Acute Hazardous to the aquatic environment - acute
Aquatic Chronic Hazardous to the aquatic environment - chronic
Eye Dam./Irrit. Serious eye damage/eye irritation
Carc. Cat. 3 Carcinogenic substances Category 3: Substances which cause concern
for man owing to possible carcinogenic effects.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H319 Causes serious eye irritation.

If you have any queries relating to this MSDS, it's contents or any other product safety related questions,
please write to the following e-mail address: [email protected]

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.