SAFETY DATA SHEET

Hysol MB 50

Section 1. Chemical product and company identification

GHS product identifier Hysol MB 50
Product code 465450-FR01
SDS no. 465450

Relevant identified uses of the substance or mixture and uses advised against
Product use Metalworking fluid - soluble.
For specific application advice see appropriate Technical Data Sheet or consult our
company representative.

Supplier Lubricants UK Limited,

Chertsey Road,
Sunbury On Thames,
Middlesex,
TW16 7BP

+44 (0)345 600 8125

EMERGENCY TELEPHONE Carechem: +44 (0) 1235 239 670 (24/7)
NUMBER

Section 2. Hazards identification

Classification of the SKIN CORROSION/IRRITATION - Category 2
substance or mixture SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A
SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 2
LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3

GHS label elements

Hazard pictograms

Signal word Warning

Hazard statements H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H401 - Toxic to aquatic life.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements
Prevention P280 - Wear protective gloves. Wear eye or face protection.
P273 - Avoid release to the environment.
P264 - Wash hands thoroughly after handling.
Response P362 + P364 - Take off contaminated clothing and wash it before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 - If skin irritation occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
Storage Not applicable.

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Section 2. Hazards identification
Disposal P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not Defatting to the skin.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture Mixture
Highly refined base oil (IP 346 DMSO extract <3%), emulsifiers and additives.

Ingredient name % Identifiers Classification Type

2-Amino- ≤10 CAS: 124-68-5 SKIN CORROSION/IRRITATION - Category [1]
2-methylpropanol 2
SERIOUS EYE DAMAGE/EYE IRRITATION -
Category 2A
SHORT-TERM (ACUTE) AQUATIC
HAZARD - Category 3
LONG-TERM (CHRONIC) AQUATIC
HAZARD - Category 3
dicyclohexylamine ≤6 CAS: 101-83-7 ACUTE TOXICITY (oral) - Category 3 [1]
ACUTE TOXICITY (dermal) - Category 3
SKIN CORROSION/IRRITATION - Category
1B
SERIOUS EYE DAMAGE/EYE IRRITATION -
Category 1
SHORT-TERM (ACUTE) AQUATIC
HAZARD - Category 1
LONG-TERM (CHRONIC) AQUATIC
HAZARD - Category 1
Poly(oxy- ≤5 CAS: 68909-67-1 SERIOUS EYE DAMAGE/EYE IRRITATION - [1]
1,2-ethanediyl), .alpha.- Category 2A
hydro-.omega.-
hydroxy-, mono(C8-18
and C18-unsatd. alkyl)
ethers, phosphates
neodecanoic acid ≤3 CAS: 26896-20-8 ACUTE TOXICITY (oral) - Category 5 [1]
2,2',2''-nitrilotriethanol ≤3 CAS: 102-71-6 Not classified. [2]
Boric acid ≤3 CAS: 10043-35-3 ACUTE TOXICITY (oral) - Category 5 [1] [2]
REPRODUCTIVE TOXICITY - Category 2
undecanedioic acid ≤3 CAS: 1852-04-6 SERIOUS EYE DAMAGE/EYE IRRITATION - [1]
Category 2A
Amines, tallow alkyl, ≤1 CAS: 61791-26-2 ACUTE TOXICITY (oral) - Category 4 [1]
ethoxylated SERIOUS EYE DAMAGE/EYE IRRITATION -
Category 1
SHORT-TERM (ACUTE) AQUATIC
HAZARD - Category 1
LONG-TERM (CHRONIC) AQUATIC
HAZARD - Category 1
3-Iodo-2-propynyl ≤0.3 CAS: 55406-53-6 ACUTE TOXICITY (oral) - Category 4 [1]
butylcarbamate ACUTE TOXICITY (inhalation) - Category 3
SERIOUS EYE DAMAGE/EYE IRRITATION -
Category 1
CHEMICALS THAT CAUSE
SENSITIZATION - Chemical which cause
skin sensitization
SPECIFIC TARGET ORGAN TOXICITY -
REPEATED EXPOSURE - Category 1
SHORT-TERM (ACUTE) AQUATIC
HAZARD - Category 1

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Section 3. Composition/information on ingredients
LONG-TERM (CHRONIC) AQUATIC
HAZARD - Category 1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Inhalation In case of inhalation of decomposition products in a fire, symptoms may be delayed.
If inhaled, remove to fresh air. The exposed person may need to be kept under
medical surveillance for 48 hours. Get medical attention if symptoms occur.
Ingestion Do not induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Wash out mouth with water if
person is conscious. Get medical attention if adverse health effects persist or are
severe.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash skin thoroughly with soap
and water or use recognised skin cleanser. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention.
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.
Check for and remove any contact lenses. Get medical attention.
Most important symptoms/effects, acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
Indication of immediate medical attention and special treatment needed, if necessary
Specific treatments No specific treatment.
Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Treatment should in general be symptomatic and directed to relieving any effects.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide
media extinguisher or spray.
Unsuitable extinguishing Do not use water jet.
media

Specific hazards arising Fire water contaminated with this material must be contained and prevented from
from the chemical being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure
increase will occur and the container may burst. This material is toxic to aquatic life.
This material is harmful to aquatic life with long lasting effects.
Hazardous thermal Combustion products may include the following:
decomposition products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
nitrogen oxides (NO, NO2 etc.)

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Section 5. Firefighting measures
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus
equipment for fire-fighters (SCBA) and full turnout gear.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Avoid breathing vapour or
mist. Provide adequate ventilation. Put on appropriate personal protective
equipment. Floors may be slippery; use care to avoid falling. Contact emergency
personnel.
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist
or fume is extremely hazardous without the correct respiratory protective equipment
and a safe system of work. Wear self-contained breathing apparatus. Wear a
suitable chemical protective suit. Chemical resistant boots. See also the
information in "For non-emergency personnel".

Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

Methods and material for containment and cleaning up

Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert
material and place in an appropriate waste disposal container. Dispose of via a
licensed waste disposal contractor.
Large spill Stop leak if without risk. Move containers from spill area. Approach the release
from upwind. Prevent entry into sewers, water courses, basements or confined
areas. Contain and collect spillage with non-combustible, absorbent material e.g.
sand, earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations. Contaminated absorbent material may pose the
same hazard as the spilt product. Dispose of via a licensed waste disposal
contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in
the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container. Avoid contact of spilt material and
runoff with soil and surface waterways. Avoid prolonged or repeated contact with
skin. During metal working, solid particles from workpieces or tools will contaminate
the fluid and may cause abrasions of the skin. Where such abrasions result in a
penetration of the skin, first aid treatment should be applied as soon as reasonably
possible. The presence of certain metals in the workpiece or tool, such as
chromium, cobalt and nickel, can contaminate the metalworking fluid and as a result
may induce allergic skin reactions. Evaporation of water from soluble cutting fluids
during use may lead to an increase in concentration which may result in the
development of skin conditions due to irritation and defatting. It is important to
monitor fluid strength on a regular basis with a refractometer and maintain it at the
recommended concentration. Lubricants from other sources and other
contaminants should be minimised. Swarf and other debris should be removed. To
maintain optimum performance and minimise bacterial spoilage, machine tool

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Section 7. Handling and storage
coolant systems should be cleaned on a regular basis.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove
contaminated clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage, Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Store and use only in equipment/containers designed for
use with this product. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination. DO NOT ADD
NITRITES TO THIS FLUID.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Boric acid Ministry of Health and Social
Development MAC (Russian Federation).
STEL: 10 mg/m³ 15 minutes. Issued/
Revised: 6/2003 Form: Aerosol
Whilst specific OELs for certain components may be shown in this section, other components may be present in any
mist, vapour or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are
provided for guidance only.
Biological exposure indices
No exposure indices known.

Appropriate engineering Provide exhaust ventilation or other engineering controls to keep the relevant
controls airborne concentrations below their respective occupational exposure limits.
All activities involving chemicals should be assessed for their risks to health, to
ensure exposures are adequately controlled. Personal protective equipment should
only be considered after other forms of control measures (e.g. engineering controls)
have been suitably evaluated. Personal protective equipment should conform to
appropriate standards, be suitable for use, be kept in good condition and properly
maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards.
The final choice of protective equipment will depend upon a risk assessment. It is
important to ensure that all items of personal protective equipment are compatible.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.

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Section 8. Exposure controls/personal protection
Eye/face protection Undiluted fluid: Chemical goggles.
Diluted fluid: Safety glasses with side shields.
Skin protection
Hand protection Wear suitable gloves. Undiluted fluid: Wear chemical resistant gloves.
Recommended: nitrile gloves.
Diluted fluid: Wear protective gloves if prolonged or repeated contact is likely.
Recommended: nitrile gloves. The correct choice of protective gloves depends
upon the chemicals being handled, the conditions of work and use, and the
condition of the gloves (even the best chemically resistant glove will break down
after repeated chemical exposures). Most gloves provide only a short time of
protection before they must be discarded and replaced. Because specific work
environments and material handling practices vary, safety procedures should be
developed for each intended application. Gloves should therefore be chosen in
consultation with the supplier/manufacturer and with a full assessment of the
working conditions.
Body protection Use of protective clothing is good industrial practice.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Cotton or polyester/cotton overalls will only provide protection against light
superficial contamination that will not soak through to the skin. Overalls should be
laundered on a regular basis. When the risk of skin exposure is high (e.g. when
cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons
and/or impervious chemical suits and boots will be required.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals being
handled, the conditions of work and use, and the condition of the respiratory
equipment. Safety procedures should be developed for each intended application.
Respiratory protection equipment should therefore be chosen in consultation with
the supplier/manufacturer and with a full assessment of the working conditions.

Section 9. Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state Liquid.
Colour Yellow. [Light]
Odour Not available.
Odour threshold Not available.
pH 9.65 [Conc. (% w/w): 5%]
Melting point Not available.
Boiling point, initial boiling Not available.
point, and boiling range
Flash point Closed cup: >100°C (>212°F) [Estimated. Water content interferes with flash point
determination.]
Evaporation rate Not available.
Flammability Not applicable. Based on - Physical state
Lower and upper explosion Not available.
limit/flammability limit
Vapour pressure

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Section 9. Physical and chemical properties
Vapour Pressure at 20˚C Vapour pressure at 50˚C
Ingredient name mm Hg kPa Method mm kPa Method
Hg
Distillates (petroleum), <0.08 <0.011 ASTM D 5191
hydrotreated heavy
naphthenic

Water 23.8 3.2

2-Amino- 0.34 0.045 ASTM E 1194

2-methylpropanol

dicyclohexylamine 0.056 0.0075 EU A.4

undecanedioic acid <0.075 <0.01 OECD 104

Relative vapour density Not available.

Relative density Not available.
Density <1000 kg/m³ (<1 g/cm³) at 15°C
Solubility(ies)
Media Result
water Emulsifies in water.
Partition coefficient: n- Not applicable.
octanol/water
Auto-ignition temperature Ingredient name °C °F Method
2-Amino-2-methylpropanol 438 820.4 ASTM D 2161

dicyclohexylamine 255 491

neodecanoic acid 375 707 ASTM E 659

2,2',2''-nitrilotriethanol 324 615.2

Decomposition temperature Not available.

Viscosity Kinematic: 70 mm2/s (70 cSt) at 40°C
Particle characteristics
Median particle size Not applicable.

Section 10. Stability and reactivity

Reactivity No specific test data available for this product. Refer to Conditions to avoid and
Incompatible materials for additional information.

Chemical stability The product is stable.

Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerisation will not
occur.

Conditions to avoid High temperatures

Incompatible materials Reactive or incompatible with the following materials: oxidising materials.
Slightly reactive or incompatible with the following materials: acids.

Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

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Section 11. Toxicological information
Information on toxicological effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
3-Iodo-2-propynyl butylcarbamate Category 1 - larynx

Information on likely routes Routes of entry anticipated: Dermal, Inhalation, Eyes.

of exposure
Potential acute health effects
Eye contact Causes serious eye irritation.
Inhalation Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin contact Causes skin irritation. Defatting to the skin.
Ingestion Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation No specific data.
Skin contact Adverse symptoms may include the following:
irritation
redness
dryness
cracking
Ingestion No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Potential chronic health effects
General No known significant effects or critical hazards.
Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Dermal 5004.86 mg/kg

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Section 12. Ecological information
Environmental effects This material is toxic to aquatic life. This material is harmful to aquatic life with long
lasting effects.

Persistence and degradability

Expected to be biodegradable.

Bioaccumulative potential
Not available.

Mobility in soil
Mobility Liquid. Emulsifies in water.

Other adverse effects No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways, drains and sewers. Diluted
Fluid The spent diluted fluid comprises a relatively stable emulsion. Dispose of via
an authorised person/ licensed waste disposal contractor or by other suitable waste
treatment techniques (e.g. emulsion splitting, coagulation and filtration) approved by
the local authority. Spent fluid should never be disposed of down the drain. The
aqueous phase should not be discharged into sewage systems unless provided for
by local regulations; the non-aqueous phase should be disposed of as undiluted
fluid. Note that separated aqueous solutions or effluents may contain metal salts as
well as traces of oil and must be checked for conformity in these respects against
consents given by the authorities before disposal. Further treatment may be
required.

Section 14. Transport information

IMDG IATA
UN number Not regulated. Not regulated.

UN proper - -
shipping name
Transport hazard - -
class(es)

Packing group - -
Environmental No. No.
hazards

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Section 14. Transport information
Additional - -
information

Special precautions for user Not available.

Section 15. Regulatory information

Regulation according to other foreign laws
REACH Status The company, as identified in Section 1, sells this product in the EU in compliance
with the current requirements of REACH.
United States inventory Not determined.
(TSCA 8b)
Australia inventory (AIIC) At least one component is not listed.
Canada inventory At least one component is not listed in DSL but all such components are listed in
NDSL.
China inventory (IECSC) At least one component is not listed.
Japan inventory (CSCL) All components are listed or exempted.
Korea inventory (KECI) All components are listed or exempted.
Philippines inventory At least one component is not listed.
(PICCS)
Taiwan Chemical All components are listed or exempted.
Substances Inventory
(TCSI)

Section 16. Other information

History
Date of printing 11/14/2022
Date of issue/Date of 11/14/2022
revision
Date of previous issue 6/1/2022
Version 9
Prepared by Product Stewardship
Key to abbreviations ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation [Regulation (EC) No. 1907/2006]
UN = United Nations
Varies = may contain one or more of the following 64741-88-4, 64741-89-5,
64741-95-3, 64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5,
64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1,
64742-62-7, 64742-63-8, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1
References Not available.
Indicates information that has changed from previously issued version.
Notice to reader

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Section 16. Other information
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental
information contained in it is accurate as of the date specified below. No warranty or representation, express or
implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not
use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.
The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use
of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the
material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps
to ensure that any person handling or using the product is provided with the information in this sheet. Employers have
a duty to tell employees and others who may be affected of any hazards described in this sheet and of any
precautions that should be taken. You can contact the BP Group to ensure that this document is the most current
available. Alteration of this document is strictly prohibited.

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