0 Q General Introduction 1. Which one of the following forms part of seven basic Slunits? (@) Wat (&) Candela (c) Newton (d) Pascal 2. Which of the following is an example of a homogeneous mixture? (@) Water + Alcohol (b) Water + Sand (©) Water + Oi (@) Petrol + Water 3. Few quantities with their units are listed below. Mark the units which are not correctly matched. (i) Density: kgm” (ii) Velocity of light : ms"! (Gi) Planck’ constant"! st (iv) Acceleration : ms (©) Force: kgm (@) (i) and (iv) (©) (and Gi) (©) (ii) and) (@) (iv) and (¥) 4. Which of the following is an example of matter ‘o physical state at room temperature and pressure? (@) Solid () Liguia © Gas (A) Allofthese 5 Given the numbers : 461 cm, 0.461 cm, 0.0461 cm. The ‘numberof significant figures forthe three numbers is (a) 3.3and4 respectively (b) 3,4 and 4 respectively (0 3,4and 5 respectively (€) 3, 3and 3 respectively © A pure substance can only be (2) acompound () anclement (©) an element or a compound (@) ahomogeneous mixture, 7 Which ofthe following is @ compound? (a) Graphite . (b) Brass (©) Cement @ Marble (d) Gay-Lussac, 9 Ammonia contains 82.35% of nitrogen 2. and 17.65% Indogen, Nat contains 88508 a eppeng o o 4 (a) Law of conservation of mass (b) Law of definite proportions (©) Lawof reciprocal proportions (4) Law of multiple proportions 10. Which among the following combinati, law of reciprocal proportions? ns Hasta, @) NONOwN:0s (6) NaC Nady (©) H,0,H,5, $0, (@ PH, P,0,, Pro, 11. For the gaseous reaction = Hy) +Cly, hy 40 mL of hydrogen completely reacts with chin’ find out the required volume of chlorine and vols" produced HCl,» (a) 20 ml, 40 mL (b) 40 mL, 80 mi (©) 40ml, 20 mL (@) 80 mL, 40 m1 12, Which one ofthe following pairs of compounds ists the law of multiple proportions? (@) H,0,Na,0 (b) MgO, Na, (©) Na,0, Ca0 @ 80,50, 13, “The law of conservation of mass holds good for ll ofthe following except (a) chemical reactions (b) nuclear reactions (©) exothermic reactions (d) endothermic reactions 14. Which of the following statements illustrates the lav ‘multiple proportions? (2) Anelement forms two oxides, XO and XO; containing 50% and 60% oxygen respectively. The ratio of muses ‘of oxygen which combines with 1 g of element is2:3 (©) One volume of nitrogen always combines wit te volumes of oxygen to form two volumes of anmnoni (©) 3.47 g of BaCl, reacts with 2.36 g of NaS0, 1 g* 3.88 g of BaSO, and 1.95 g of NaCl. (@) 20 mL of ammonia gives 10 volumes of N; and 3 volumes of H, at constant temperature and pressure 15. Which ofthe following equations does not obey the ‘conservation of mass? @ 4H+0,52H,0 — (b) H,+052H,0 © 2H+0,>H,0 (a) Both (b) and(e) 16. Two gaseous samples were analysed. One contained! of carbon and 3.2 g of oxygen. The other contained 279° and 72.7 % oxygen. The experimental data © accordance with (2) law of conservation of mass (©) law of definite proportions (©) law of reciprocal proportions (@) law of multiple proportions. Chemist"Y17 Different proportions of oxygen in the various oxides of nitrogen prove the law of (@) conservation of mass (0) multiple proportions (©) constant proportions (@) reciprocal proportions. 18, Inthe reaction N, + 3H, — 2NH,, ratio by volume of N, Hy and NH, is 1:32. This (@) conservation of mass (©) definite proportions (©, multiple proportions (@) gaseous volumes. 19, There ate two common oxides of sulphur, one of which contains 50% O, by weight, the other almost exactly 60%, ‘The weights of sulphur which combine with 1 g of O, (xed) are in the ratio of (@) 2:3 2:1 1:3 @ 3:2 20, H,S contains 94.11% sulphur; SO, contains 50% oxygen and H,O contains 1.11% hydrogen, Thus, (2) law of conservation of mass is followed (b) law of reciprocal proportions is followed (6) law of multiple proportions is followed (@) all ofthe above Dalton’s Atomic Theory 21, Which ofthe following postulates of Daltons atomic theory ‘explains the law of multiple proportion? (2) Atoms oftwo elements may combine with one another to form more than one compound, (b) Atoms combine in the ratio of small whole numbers to form compounds. (6) The relative number and kinds oftoms are constant in, given compound. (@) Allofthe above. 22. Which of the following facts went against the Daltons theory? @) Discovery of radioactivity (6) Discharge tube experiment (©) Discovery ofisotopes (@) Allofthese 23, ‘The main drawback of Dalton’ atomic theory is () itcould not explain the law of gaseous volumes (Hit could not explain why atoms of different elements hhave diferent masses, sizes, ete (©) it could not explain how and why atoms combine to form molecules (@) all ofthe above. 24, Which ofthe following postulates is nota part of Daltons atomic theory? (2) Compounds are formed by the combination of atoms ‘ofmore than one element in fixed whole number ratios. (©) Chemical reactions involve only the rearrangement of ‘atoms. ‘Some Basie Concepts of Chemistry lustrates law of 2, 31. 32, 2. (©) Equal volumes of gases contain equal number molecules under the sime conditions of temperature and pressure. (@) Atom is the smallest particle that takes part in a chemical reaction Daltons atomic theory could not explain (@) lw of conservation of mass (b) law of definite proportions (©) Gay Lussac’ law of combining volume (€) allof these Atomic and Molecular Masses The modern atomic weight scale is based on (@ ¥c ) “o @ "Yo (@'H Chlorine occurs as two isotopes Cl-35 (atomic mass 34,9689 u) and CI-37 (atomic mass 36.9659 u). 75.77% of natural chlorine is C1-35. The atomic weight of chlorine is (a) 35 (b) 34.96 ©” (@) 35.45 If the mass of neutron is assumed to half ofits original value whereas that of proton is assumed to be tice of ts original value, then the atomic mass of $C will be (@) same () 14.28 % less (© 14.28% more (@) 2856% more ». Bromine has two naturally occuring isotopes, Br-79 and Br 81. The atomic mass and percent natural abundance of Br-79 are 78,9183 w and 50.54%, What isthe atomic mass of the second isotope, Br-817 (@) 8150 (b) 80.90 © 4946 (@) 7905 | Lamu is equal to 1 (@) J ofmass oft atom of C-12 1 (0) of mass of 1 atom of O- 5 f 1 atom of 0-16 © 1gofH, (2) 1.65% 10 ky. ‘An clement has the following isotopic composition 2; 90%, 7A :8.0% and "A: 2.0%, The weighted average atomic mass of the naturally occuring clement A is @) 2050 ©) 2100 © 1900 (@) 2000 How many grams are contained in 1 gram-atom of Mg? () 2g () 2%. Os ws Aires detelt psu escapee we shencfereg epee ceuomeee os Oo 68 oe 15‘pe, Fe and Fe “Given that the abundances of isotopes “Fe, ion a0 and 5% respectively, the atomic mass of Fe is (b) 55.95 8.75 cs Sas 35. Specific heat of a solid element is 0.1 cal 8” °C and its cpvlent weights Is exact atomic weights (a) 35.8 (b) 63.6 (Q 18 (d) 95.4 ‘Which property ofan clement isnot variable? * pee (b) Atomic weight (©) Equivalent weight (d) All of these: |37. Relative density ofa volatile substance with respect to CH, {sts molecular weight would be @ 16 ) 32 © 6 (@ 18 138. A compound possesses 89 sulphur by mass. The least ‘molecular mass is {) 200 (o) 400 (©) 155 (a) 355 139, In chlorine gas, ratio of CI and CP” is @ 1:3 (b) 3:1 ut @ 4 40, ‘Dulong and Petit aw is vali only for @) metals (b) non-metals (©) gaseouselements (4) solid elements Mole Concept and Molar Masses 41, How many carbon atoms are present in 0.35 mol of CHO (@) 126. 10" carbon stoms (©) 6023 » 10" carbon atoms (©, 1.26 10%carbon stoms (@) 6023 « 10° carbon atoms 42. How many atoms are present in one ce of helium gas at STP (@) 602310" () 225 x10! (©) 269% 10" (@) 408 x10" 43, The density (in g/mL) ofa 3.60 M sulphuric acid solution thats 29% H,SO, (molar mass = 98 g/mol) by mass is (a) 2645, (b) 1.882 (© 1216 (a) 1458 44. 14g ofnitrogen gas and 22g of CO, gas are mixed together. Find the volume of gscous mire STP oust meen 10 ee 45: How may lest econ neigh oe Kogan? (9 60x10 tl b) paoe i aaa eee . 9:108%6.023 *' ye ‘What isthe mass of 4 N, molecules of CO,? = @) 25 4g ee (@) 1765 16 47. What the effective molecular weight of air? (a) 28 (b) 32 (©) 2884 (@ 3221 48, The volume occupied by one molecule of (density = 1 gem’) is (@) 9.0% 10 cm* (©) 3010 cm" (b) 6.023 x 10° cm? (€) 55% 107 cm? 49, How many moles of magnesium phosphate Mg,(PO), yy contain 0.25 mole of oxygen atoms? (@) 002 (b) 3.125 x 107 (©) 125x107 (@) 25x10" 50, How many yearsit would take to spend Avogadros nung of rupees at the rate of I million rupees in one second? (a) 19.098 x 10" years (b) 19.098 x 10" years (©) 19098 x 10° years (4) 19.098 x 10" years S51. Atomic mass of mercury is 200 and density is 136 gc How many moles of metal ae present in one lite? @ 55 ©) 68 om (@) 86 52. 044 g ofa colourless oxide of nitrogen occupies 224 mL a STP. The compound is (@) NO () NO © NO, (@) No, 453. Haemoglobin contains 0.25% iron by mass. The molculir ‘mass of haemoglobin is 89600. The number of iron atoms ‘per molecule of haemoglobin is (@) 2 4 6 @s 54, What isthe molecular mass ofa substance, each molecule ‘of which contains 9 carbon atoms, 13 hydrogen stomsand 233. 10 g of other component? (@) 108amu (6) 12508 ama © 1240420 (@) 13504 amo 58, Thealloy aluminium-bronze contains 90% Cu and 10% Al bbymass. In what atomic ratio are the two metas preset 9 the alloy? {) 628727 (b) 14237 kg or) (@) 50:50 56, From 160 g of SOx sample, 1.2046 x 10% molecules of SO) are removed. Then find out the volume of SQ € over a STP @ s6L nat (© 2aL @ 4sL 57. The otal numberof toms ofall elements presen ofanioniam dchromate (a) 6.023 x 10? (b) 19.05 x 10" (©) 114.473 x 10° (a) 84.322 x 10° 8. IFN is Avogadro number, then the number of valet electrons in 4.2 g of N°- ions is (a) 24, (b) 1.6.Nq © 42N, (d) 3.2N, chemist459, ‘The number of potassium ions in two moles of potassium ferrocyanide is (@) 6402310" (6) 26023 «108 (© 4602310" (a) 8602310 460. What isthe ratio of numberof molecules, ifthe mass ratio of Nand 0,8 4:17 (@) 28:32 ©) 4:16 (@ 32:7 (@ 16:32 61, How many number of molecules and atoms respectively are present in 2.8 litres of diatomic pas at STP? {@) 602310975 10° (6) 6023 10°15 10" (© 75% 10%, 15x10? (@) 15% 10,75 x 10" 462 Calculate the number of CI and Ca jons in 222 g anhydrous CaCl, (@) 2Ngions of Ca and 2N, ions of Ct (6) 2Nj ions of CI and AN ions of Ca* (@) 2Ngions of Ca" and 4N, ions of CI (@) None ofthese 63. A hydrate of iron(ID) thiocyanate [Fe(SCN),xH,0), was found to contain 19% H,O. The value of xis @2 3 4 ws ‘64. The vapour density of mixture containing NO; and NO, Js 383 at 27 °C. Calculate the mole of NO; in 100 mole risture. (@) 7660 (by 33.48 (© 3822 (€) None ofthese 65. When gypsum is otaly dehydrated, what isthe percentage weight oss? @ 2093 (©) 31.80 (© 2620 (@) 3640 166. Calculate the total number of N; and O, molecules in a breath in which a person inhales 224 ml ar (at STP) and in air N, and O, ate 78% and 21% respectively. (@) 167 x10" () 6.023 10" (© 5.96 10" (@) 63910” (67. Inasolution of GH, and CQH,CHs, xg the mass % composition of mixture. (05, Calculate (@) 50,50 (b) 459,541 (©) 525,475 (2) 602,398 (68. The density of ©, at 0°C and 1 atm is 1429 g/L. The molar volume of gas is (a) 2241, () 24 (© 56L (@) 3361, 68. The number of moles of oxygen in 1 L of ar containing 21% oxygen by volume, under standard condition, is (@) 0.0093 mol () 2.10 mol (6) 0.186 mol (4) 0.21 mol 70. A sample of ethane has the same mass as 10° molecules ‘of methane, How many ethane molecules does the sample ‘contain? ‘Some Basic Concepts of Chemistry 7. n. a m4. 7. 78. (a) 6.023 x 10 (b) 3.826108 (©) 534% 10° (@) 125x108 Percentage Composition [An oxide of nitrogen gave the following percentage composition N=25,94 and O= 74.06 ‘The empirical formula ofthe compound is (@) No ©) NO (© NO) (@) N40, In a compound 522% carbon, 13% hydrogen, 34.99% ‘oxygen are present and molecular mass of the compound 492. The molecular formula of the compound is (@) CHO. () CyH,0, (© GHO (€) CyB Percentage composition of an organic compound is as follows C= 1006, H = 084, C1=89.10 Which of the following corresponds to its molecular formula ifthe vapour density i 60.02 (@) CHCl () CHCL, (© cH, (@ cHeL Inan organic compound of molar mass 108 g mol" C, H and N atoms are present in 9: 1:35 by weight. Molecular formula can be @) Cathay (0) GHiyN (©) GHNs (2) CyHiyNs A giant molecule contains 0.25% of a metal whose atomic eight i 59. Its molecule contains one atom ofthat metal Its minionum molecular weight is (a) 11800 (b) 23600 10059 (©) 5900 oe @ ads comeeigre ss co ee Ser aes aa - Caffeine has a molecular weight of 194. It contains 28.9% by mass of nitrogen Namie of atoms of mitogen in One molecule of itis. ue (6 @4 3 @s 7Rs an. a 18 ‘organic compound has the composition : C = 58.5%, Hredon, NIT and =260%. What isthe empirical formula ofthe compound? (@) CHNO, () CHO (©) CoHiNO; (@) GHANO, CCaleulate the mass percent of oxygen present in Na,S0,. (@ 324 () 25 os (@ 32 ‘A compound contains 21 atoms of carbon per molecule “Themas percentage ofarbon in the compound i 69.98%. Its molar massis| (@) 1765 () 2522 (© 2876 (@) 360.1 Insulin contains 3.4% sulphur, the minimum molecular ‘weight of insulin is (a) 941.176 (b) 944.328 (©) 946278, (@) 943.265 Stoichiometry and Stoichiometric Calculations ‘Themolarity ofa solution prepared by dissolving 4 g NOH. {n enough water to form 250 ml of te solution is (a) 02M (6) 04M © 06M @iM 3 gof magnesium is burnt ina closed vessel containing 3 g of oxgygen. The weight of excess reactant lft is (2) 05 gof oxygen (b) 10g of magnesium (©) L0gofoxygen (@) 05 g of magnesium Ina gaseous reaction of the type A+ PB cC+ dD Which statement is wrong? (2) mole of combines with b moles of B to give Cand D. () alitre of A combines with b litre ofB to give Cand D, (©) @gof A combines with bg of B to give Cand D. (4) a molecules of A combines with b molecules of B to sive Cand D. + 0.2 mole of orthophosphoric acid and 1.0 mole of calcium hhydroxide were allowed to react. Calculate the maximum ‘number of mote of calcium phosphate formed. (@) 0A mole (b) 0.1 mole (© 02 mole (@) 09 mole How many grams of pure KMnO, should be heated with H,S0, to produce 48 g of 0? (@) 1805 ¢ (b) 189.65 (©) 1505 (@) 310 1000 g aqueous solution of CaCO, contains 10g of calcium carbonate, Concentration of solution is (@) 10 ppm (©) 100 ppm (©) 1000 ppm (4) 10000 ppm, What weight of magnesia is obtained te combustion of two grams of metal? ee (@) 246 ©) 33g © 488 ©) 66g a 91. How many moles of lead) chloride wil be fn reaction between 65 g of PbO and 32 gof fic} (@) 0.088 ©) 0033 © oon (@ 0029 9% In a reaction container 100 § of yd, 100 g of Cl, are mixed for the formation of Hci is the limiting reagent and how much HCl is for.” reaction? (3) His limiting reagent and 365 g of HCl formes (b) Chis iting reagent nd 1028 of 11 wy (©) Has limiting reagent and 142 g of HCI ison {@) Gl, ilimiting reagent and 73 g of His ormey Wh formed in, 93. 2ale20, +405 9 gof Al will eact with (a) 6g0; 0) 850, © 980 @) 4g0, 94. The hydrated salt, NaSO,xH,0 undergoes 55.9% los in weight on heating and becomes anhydrous. The vale» willbe @ 6 5 07 (@) 10 95. How many grams of 80% pure marble stone on canto «an give 14 grams of quick ime? (@) 5g () 31258 (© 26855 (a) 35153 96. Inthe reaction 2Aly) + HCl) > 2Aliy + 6Clig + 3H (@) 6L Clg i consumed for every LH, produced (©) 33.61 Hg is produced regardless of temperature and pressure for every mole Al that eats (6) 67.2 L Hyg) at STP is produced fr every mole Al hat reacts (2) 11.2 L Hyg at STP is produced for every mole HCl. consumed. 97. Forthe reaction A + 28> C,6molof A and 8 mol of Bwill produce (@) Smolofc (b) 4mol of C © 8molofc (@) mol of 98. A solution contains one mole of alcohol and four motes of Water. What are the fractions of water and alcohol? (a) 4/4 () 14,4/1 (© 485,15 @ 15,415 9% 100 ml of 30% (w/v) NaOH solution is mixed wh 100 mi. 90% (w/v) NaOH solution. Find the mols ° final solution (@) 15M, ® BM 1 —M (@ 18M 100, Volume of O; at STP required to burn completely 701° acetylene is (a) 100m. (0) 150 mL (© 175 mt (€) 200 mt. chemist1 L of CO; is passed over hot coke. When the volume ‘of reaction mixture becomes 1.4 L, the composition of reaction mixture is (@) 06L.CO (b) 08L.Co, (©) 061.C0, and 08 .CO (4) 0.81.0, and 0.6L CO 102. In the reaction 4NHyp)+ 50,4) —> 4NOjy + 6H,Oy when 1 mol of ammonia and 1 mol of O, are made to react to completion (a) 1.5 mol of H,0 is produced () 15 mol of NO is produced (©) all the oxygen is consumed (@) all the ammonia is consumed. 103. 10 mL of concentrated HO, (18 M) is diluted to one litre. ‘The approximate strength ofthe dilute acid is (@) 180M (b) 18M (© 018M (@ 18M 104.18 mL of uncombined O, remain after exploding O, with 4mL of hydrogen, the number of ml. of O, originally were (@) 10 ) 15 on (@) 20 105. Density of 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of same solution is (@) 5.56 mol kg”! (b) 3.28 mol kg" (©) 2.28 mol kg"! (2) 1.28 mol kg" 106. The production cos of hydrogen from a mineral acid using zincis rupees 10 per mole. How many electrons is worth of fone rupee? (@) 6022 x 10” (© 24x10 107.26 mL. of CO, are passed over red hot coke. The volume of| CO evolved is @) 26mL (>) 10mL (© 20mt (@) 52m 108. In the aqueous solution of sulphuric acid the mole fraction ‘of water i 085, The molality ofthe solution is (b) 1210” (d) None of these (a) Im (b) 019m (©) 98m @ 25m 109. Two solutions of a substance (non-electrolyte) are mixed in the following manner: 500 ml. of 1.5 M of first solution with 500 mL of 1.2 M of second solution, The molarity of final solution is @) 120M (@) 150M © 135M (@) 270M 110. How many moles of potassium chlorate need to be heated to produce 1.2 litres oxygen at NTP? : + mot (@) 5 mol o> 1 © bm (@) 1 mol (0 § mol 1111. Which ofthe following relations is incorrect for solutions? @) 1MAI,(S0)) = 6N Als(SO)s (b) 2MH,S0,=4N H,SO, ‘Some Basic Concepts of Chemistry (©) 1MH,PO,= 1/3 N HPO, (€) 3N ALSO); = 0.5 M Alx(SO)s 112. 4g ofeach pure hydrochloric acid and pure caustic soda are together dissolved in water. The weight of sodium chloride obtained is (a) 585g © 4g 113.04 mol of BaCl; is mixed with 0.2 mol of NasPO,. ‘The ‘maximum number of moles of Ba,(PO,), that can be (b) 5858 (4) none of these. formed is 3BaCI, + 2NaPO,->Ba,(PO,)s + 6NaCl (@ 07 (b) 05 (903 (@) 01 114, How many gram of KCI would have tobe dissolved in 40 g HO to give 20% by weight of solution? @ 158 () log (© 1158 @ 3158 115. The percent los in mass after heating a pure sample of potassium chlorate (mol. mass = 122.5) wil be @) 245 (@) 2850 (©) 3918 (@) 490 116. Liquid benzene (C,H) burns in oxygen according to the equation 2C,Hgp) + 150) -> 12COmp + 6H20¢p. How many litres of O, at STP will be needed for the complete combustion of 39g of liquid benzene? (Mol. et. of 0, = 32, Hg = 78) (@) 1001 @) u2L (© 2aL (@ sai 117. 500 mL of gaseous hydrocarbon when burnt in excess of, gave 2.5 | of CO, and 3.0L of water vapours under same conditions, Molecular formula ofthe hydrocarbon is @ GH, ©) Cy (© CHa @ Gy 118. Equal weights of ethane and hydrogen are mixed in an ‘empty vessel at 25 °C, The fraction of the total pressure exerted by hydrogen is @ in 1 © ine (@) 15/6 119.2, of metal carbonate is neutralized completely by 100 mL of0.1 N HCL The equivalent weight of metal carbonate (@ 50 (0) 100 (© 150 (@) 200 120.The minimum quantity in gram of H,S needed to precipitate 63.5 g of Cu" will be Cu" + HS Cu,$-+ 2H" (@) 31755 0) 635g (© 4g (@) 68g 121.40% w/V NaCl solution (specific gravity = 1.12) is equivalent to (@) 357.108 ppm (6) 3.57 x10 ppm (©) 110" ppm (@) 410° ppm 19a beget hed Se (a) CB tovicwise Warmup [Dp 1 ) 11. ) 21. (b) 31. (d) 41. 51. (b) 61. (<) 71. (d) 81. (0) 91. (d) 101.(c) 111.0 121.(a) oe 12. 22. 32. 42. 52. 62. 72. 82. 92, 102. 112. 122. (a) (@) @ (b) © (a) © (b) (d) (b) © () (a) a; 13. 23. 33. 43. 53. 63. 73. 83. 93. 103. 113. 123. © (b) (@) @ © (b) (b) (b) @) (b) © @) © 114, 124, (d) (d) (@) © (b) @ @) (b) @ (b) @ @ (b) © 45. ee 15. 25. 35. 45. 55. 65. 75. 85. 95. 105. 115. 125. (b) (@) (d) ) (b) (d) (b) (a) (b) Co) (b) ( i) (b) 6. 16. 26. 36. 46. 56. 76. 86. 96. 106. 116. © (b) (a) (b) (d) (b) ( © ( (d) (b) (d) a 17. 27. 37. 47. ST 67. 77. 87. 97. 107. 117. @ © (d) C) © © (b) (b) (b) () @ @ 8. 18. 28. 38. 48. 58. 68. 78. 88. 98. 108. 118. ( (d) (O (b) ( (a) (a) ( (b) o io) (d) 9. 19. 29. 39, 49. 59. 69. 79. 89, 99. 109. 119. © (d) (b) (b) (b) (d) fa) ( @) (d) ) @ 10, 20. 30, 40. 50. 60, 70. 80. 90. 100. 110. 120.