Leaching Notes
Leaching Notes
Leaching is a process widely used in extractive metallurgy where ore is treated with chemicals
to convert the valuable metals within into soluble salts while the impurity remains insoluble.
These can then be washed out and processed to give the pure metal; the materials left over are
commonly known as tailings. Compared to pyrometallurgy, leaching is easier to perform,
requires less energy and is potentially less harmful as no gaseous pollution occurs. Drawbacks
of leaching include its lower efficiency and the often significant quantities of waste effluent
and tailings produced, which are usually either highly acidic or alkali as well as toxic
(e.g. bauxite tailings).
There are four types of leaching:
Types of Leaching
Heap leaching
In-situ leaching
Tank leaching
Heap leaching
Heap leaching is an industrial mining process used to extract precious metals, copper, uranium,
and other compounds from ore using a series of chemical reactions that absorb specific
minerals and re-separate them after their division from other earth materials. Similar to in situ
mining, heap leach mining differs in that it places ore on a liner, then adds the chemicals via
drip systems to the ore, whereas in situ mining lacks these liners and pulls pregnant solution
up to obtain the minerals. Heap leaching is widely used in modern large-scale mining
operations as it produces the desired concentrates at a lower cost compared to conventional
processing methods such as flotation, agitation, and vat leaching.
Additionally, dump leaching is an essential part of most copper mining operations and
determines the quality grade of the produced material along with other factors
Due to the profitability that the dump leaching has on the mining process, i.e. it can contribute
substantially to the economic viability of the mining process, it is advantageous to include the
results of the leaching operation in the economic overall project evaluation.
The process has ancient origins; one of the classical methods for the manufacture
of copperas (iron sulfate) was to heap up iron pyrite and collect the leachate from the heap,
which was then boiled with iron to produce iron(II) sulfate.
Process
The mined ore is usually crushed into small chunks and heaped on an impermeable plastic or
clay lined leach pad where it can be irrigated with a leach solution to dissolve the valuable
metals. While sprinklers are occasionally used for irrigation, more often operations use drip
irrigation to minimize evaporation, provide more uniform distribution of the leach solution,
and avoid damaging the exposed mineral. The solution then percolates through the heap and
leaches both the target and other minerals. This process, called the "leach cycle," generally
takes from one or two months for simple oxide ores (e.g. most gold ores) to two years for
nickel laterite ores. The leach solution containing the dissolved minerals is then collected,
treated in a process plant to recover the target mineral and in some cases precipitate other
minerals, and recycled to the heap after reagent levels are adjusted. Ultimate recovery of the
target mineral can range from 30% of contained run-of-mine dump leaching sulfide copper
ores to over 90% for the ores that are easiest to leach, some oxide gold ores.
The essential questions to address during the process of the heap leaching are:[4]
Can the investment of crushing the ore be justified by the potential increase in recovery
and rate of recovery?
How should the concentration of acid be altered over time in order to produce a solution
that can be economically treated?
How does the form of a heap affect the recovery and solution grade?
Under any given set of circumstances, what type of recovery can be expected before the
leach solution quality drops below a critical limit?
What recovery (quantifiable measure) can be expected?
In recent years, the addition of an agglomeration drum has improved on the heap leaching
process by allowing for a more efficient leach. The rotary drum agglomerator works by taking
the crushed ore fines and agglomerating them into more uniform particles. This makes it much
easier for the leaching solution to percolate through the pile, making its way through the
channels between particles.
The addition of an agglomeration drum also has the added benefit of being able to pre-mix the
leaching solution with the ore fines to achieve a more concentrated, homogeneous mixture and
allow the leach to begin prior to the heap.[5]
Although heap leach design has made significant progress over the last few years through the
use of new materials and improved analytical tools, industrial experience shows that there are
significant benefits from extending the design process beyond the liner and into the rock pile
itself. Characterization of the physical and hydraulic (hydrodynamic) properties of ore-for-
leach focuses on the direct measurement of the key properties of the ore, namely:
The relationship between heap height and ore bulk density (density profile)
The relationship between bulk density and percolation capacity (conductivity profile)
The relationship between the bulk density, porosity and its components (micro and macro)
The relationship between the moisture content and percolation capacity (conductivity
curve)
The relationship between the aforementioned parameters and the ore preparation practices
(mining, crushing, agglomeration, curing, and method of placement)
Theoretical and numerical analysis, and operational data show that these fundamental
mechanisms are controlled by scale, dimensionality, and heterogeneity, all of which adversely
affect the scalability of metallurgical and hydrodynamic properties from the lab to the field.
The dismissal of these mechanisms can result in a number of practical and financial problems
that will resonate throughout the life of the heap impacting the financial return of the operation.
Through procedures that go beyond the commonly employed metallurgical testing and the
integration of data gleaned through real time 3D monitoring, a more complete representative
characterization of the physicochemical properties of the heap environment is obtained. This
improved understanding results in a significantly higher degree of accuracy in terms of creating
a truly representative sample of the environment within the heap.[6]
By adhering to the characterization identified above, a more comprehensive view of heap leach
environments can be realized, allowing the industry to move away from the de facto black-box
approach to a physicochemical inclusive industrial reactor model.
The crushed ore is irrigated with a dilute alkaline cyanide solution. The solution containing the
dissolved precious metals in a pregnant solution continues percolating through the crushed ore
until it reaches the liner at the bottom of the heap where it drains into a storage (pregnant
solution) pond. After separating the precious metals from the pregnant solution, the dilute
cyanide solution (now called "barren solution") is normally re-used in the heap-leach-process
or occasionally sent to an industrial water treatment facility where the residual cyanide is
treated and residual metals are removed. In very high rainfall areas, such as the tropics, in some
cases there is surplus water that is then discharged to the environment, after treatment, posing
possible water pollution if treatment is not properly carried out.
The production of one gold ring through this method, can generate 20 tons of waste material.
The most common methods to remove the gold from solution are either using activated carbon
to selectively absorb it, or the Merrill-Crowe process where zinc powder is added to cause a
precipitation of gold and zinc. The fine product can be either doré (gold-silver bars) or zinc-
gold sludge that is then refined elsewhere.
Copper ores
The method is similar to the cyanide method above, except sulfuric acid is used to
dissolve copper from its ores. The acid is recycled from the solvent extraction circuit
(see solvent extraction-electrowinning, SX/EW) and reused on the leach pad. A byproduct
is iron(II) sulfate, jarosite, which is produced as a byproduct of leaching pyrite, and sometimes
even the same sulfuric acid that is needed for the process. Both oxide and sulfide ores can be
leached, though the leach cycles are much different and sulfide leaching requires a bacterial,
or bio-leach, component.
In 2011 leaching, both heap leaching and in-situ leaching, produced 3.4 million metric tons of
copper, 22 percent of world production.[8] The largest copper heap leach operations are in
Chile, Peru, and the southwestern United States.
Although heap leaching is a low cost-process, it normally has recovery rates of 60-70%. It is
normally most profitable with low-grade ores. Higher-grade ores are usually put through more
complex milling processes where higher recoveries justify the extra cost. The process chosen
depends on the properties of the ore. The final product is cathode copper.
Nickel ores
This method is an acid heap leaching method like that of the copper method in that it
utilises sulfuric acid instead of cyanide solution to dissolve the target minerals from crushed
ore. The amount of sulfuric acid required is much higher than for copper ores, as high as
1,000 kg of acid per tonne of ore, but 500 kg is more common. The method was originally
patented by Australian miner BHP and is being commercialized by Cerro Matoso in Colombia,
a wholly owned subsidiary of BHP; Vale in Brazil; and European Nickel for the rock laterite
deposits of Turkey, Talvivaara mine in Finland, the Balkans, and the Philippines. There
currently are no operating commercial scale nickel laterite heap leach operations, but there is a
sulphide HL operating in Finland.
Nickel recovery from the leach solutions is much more complex than for copper and requires
various stages of iron and magnesium removal, and the process produces both leached ore
residue ("ripios") and chemical precipitates from the recovery plant (principally iron oxide
residues, magnesium sulfate and calcium sulfate) in roughly equal proportions. Thus, a unique
feature of nickel heap leaching is the need for a tailings disposal area.
The final product can be nickel hydroxide precipitates (NHP) or mixed metal hydroxide
precipitates (MHP), which are then subject to conventional smelting to produce metallic nickel.
In-situ leaching
In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is
a mining process used to recover minerals such as copper and uranium through boreholes
drilled into a deposit, in situ. In situ leach works by artificially dissolving minerals occurring
naturally in a solid state. For recovery of material occurring naturally in solution, see: Brine
mining.
The process initially involves the drilling of holes into the ore deposit. Explosive or pathways
in the deposit for solution to penetrate. Leaching solution is pumped into the deposit where it
makes contact with the ore. The solution bearing the dissolved ore content is then pumped to
the surface and processed. This process allows the extraction of metals and salts from
an ore body without the need for conventional mining involving drill-and-blast, open-cut
or underground mining.
Process
In-situ leach mining involves pumping of a lixiviant into the ore body via a borehole, which
circulates through the porous rock dissolving the ore and is extracted via a second borehole.
The lixiviant varies according to the ore deposit: for salt deposits the leachate can be fresh
water into which salts can readily dissolve. For copper, acids are generally needed to
enhance solubility of the ore minerals within the solution. For uranium ores, the lixiviant may
be acid or sodium bicarbonate.
Potash and soluble salts In-situ leach is widely used to extract deposits of water-soluble salts
such as potash (sylvite and carnallite), rock salt (halite), sodium chloride, and sodium sulfate.
It has been used in the US state of Colorado to extract nahcolite (sodium bicarbonate). In-situ
leaching is often used for deposits that are too deep, or beds that are too thin, for
conventional underground mining.
Uranium
In-situ leach for uranium has expanded rapidly since the 1990s, and is now the predominant
method for mining uranium, accounting for 45 percent of the uranium mined worldwide in
2012.
Solutions used to dissolve uranium ore are either acid (sulfuric acid or less commonly nitric
acid) or carbonate (sodium bicarbonate, ammonium carbonate, or dissolved carbon dioxide).
Dissolved oxygen is sometimes added to the water to mobilize the uranium. ISL of uranium
ores started in the United States and the Soviet Union in the early 1960s. The first uranium ISL
in the US was in the Shirley Basin in the state of Wyoming, which operated from 1961-1970
using sulfuric acid. Since 1970, all commercial-scale ISL mines in the US have
used carbonate solutions.ISL mining in Australia uses acid solutions.[4]
A drum of yellowcake
Examples of in-situ uranium mines include:
The Beverley Uranium Mine, South Australia, is an operating ISL uranium mine and
Australia's first such mine.
The Honeymoon Uranium Mine, South Australia, opened in 2011 and is Australia's second
ISL uranium mine.
Crow Butte (operating), Smith Ranch-Highland (operating), Christensen Ranch
(reclamation), Irigaray (reclamation), Churchrock (proposed), Crownpoint (proposed),
Alta Mesa (operating), Hobson (standby), La Palangana (operating), Kingsville Dome
(operating), Rosita (standby) and Vasquez (restoration) are ISL uranium operations in the
United States.
In 2010 Uranium Energy Corp. began an ISL mining operation in the Palangana deposit
in Duval County, Texas. The ion exchange facility at Palangana trucks uranium-loaded
resin beads to the company's Hobson processing plant, where yellowcake is produced.
Uranium Energy Corp. has three additional South Texas deposits permitted or in
development.
Copper
In-situ leaching of copper was done by the Chinese by 977 AD, and perhaps as early as 177
BC. Copper is usually leached using acid (sulfuric acid or hydrochloric acid), then recovered
from solution by solvent extraction electrowinning (SX-EW) or by chemical precipitation.
Ores most amenable to leaching include the copper carbonates malachite and azurite, the
oxide tenorite, and the silicate chrysocolla. Other copper minerals, such as the
oxide cuprite and the sulfide chalcocite may require addition of oxidizing agents such as ferric
sulfate and oxygen to the leachate before the minerals are dissolved. The ores with the highest
sulfide contents, such as bornite and chalcopyrite will require more oxidants and will dissolve
more slowly. Sometimes oxidation is sped up by the bacteria Thiobacillus ferrooxidans, which
feeds on sulfide compounds.
Copper ISL is often done by stope leaching, in which broken low-grade ore is leached in a
current or former conventional underground mine. The leaching may take place in
backfilled stopes or caved areas. In 1994, stope leaching of copper was reported at 16 mines in
the US.
Uranium ores
1. Ore Type: Different types of ores have varying mineral composition, hardness, and
accessibility. Some ores are more abundant and easier to extract, leading to higher productivity
and lower costs. For example, open-pit mining of low-grade bulk commodities like coal or iron
ore can be more cost-effective compared to underground mining of high-grade narrow vein
deposits.
2. Deposit Size and Location: The size and quality of the ore deposit play a crucial role. Large,
high-grade deposits tend to be more economically viable due to economies of scale, allowing
for efficient mining and processing. Additionally, the proximity of the deposit to infrastructure
(roads, railways, ports) can impact transportation costs, thereby affecting overall mining costs.
3. Mining Methods: Various mining methods are employed based on the characteristics of the
ore deposit. Common methods include open-pit mining, underground mining, block caving,
and placer mining. Each method has different productivity levels and cost implications. Open-
pit mining is often more productive and cost-efficient for large, near-surface deposits, while
underground mining may be necessary for deeper or more complex deposits.
4. Technological Advancements: Advances in mining technology can significantly impact
productivity and costs. Innovations such as automation, remote sensing, and computer
modeling can optimize operations, increase extraction rates, and reduce labor requirements.
However, implementing new technologies can also require substantial upfront investments.
5. Labor and Energy Costs: Labor and energy costs are significant factors in mining operations.
Wages, benefits, and safety measures for mine workers contribute to the overall cost structure.
Additionally, energy costs for powering mining equipment and processing facilities can have
a substantial impact on the total cost of mining operations.
It's important to note that the productivity and cost dynamics of mining ores can vary greatly
across different regions and time periods. Specific studies and analysis of individual mines or
mining projects are often required to assess productivity and cost factors accurately.
In-situ leaching (ISL), also known as in-situ recovery (ISR) or solution mining, is a mining
method used to extract minerals from ore bodies that are too deep or too low-grade for
conventional mining methods. Instead of physically excavating and transporting the ore to the
surface, ISL involves the injection of a leaching solution directly into the ore deposit, which
dissolves the desired minerals. The pregnant solution is then pumped to the surface for further
processing to extract the minerals.
Principles of In-situ Leaching:
Solution Injection: A leaching solution, typically a weak acid or alkaline solution, is
injected into the ore deposit through wells or boreholes. The solution permeates
through the ore, dissolving the desired minerals.
Mineral Dissolution: The leaching solution comes into contact with the mineral
particles, causing them to dissolve. The minerals are typically soluble or can be made
soluble by adjusting the pH or adding appropriate reagents.
Solution Recovery: The pregnant solution, enriched with the dissolved minerals, is
pumped back to the surface through separate wells or boreholes. It is then processed
to extract the desired minerals using techniques such as precipitation, ion exchange,
or solvent extraction.
Reagent Regeneration: In some cases, the leaching solution may lose its effectiveness
over time due to consumption or contamination. Reagents can be added to regenerate
the solution's leaching capacity, allowing for continued mineral extraction.
Scope of In-situ Leaching:
Low-grade Ores: In-situ leaching is particularly suitable for low-grade ore bodies where
the concentration of valuable minerals is relatively low. By directly injecting the
leaching solution into the deposit, it becomes possible to economically recover
minerals that would be uneconomical to mine conventionally.
Deep Deposits: ISL is advantageous for ore bodies located at significant depths, as it
eliminates the need for extensive excavation and transportation of ore to the surface.
Environmental Impact: Compared to traditional mining methods, ISL generally has a
smaller environmental footprint. It minimizes the disturbance of the surface
environment, reduces energy consumption, and lowers emissions associated with
mining and ore transportation.
It's important to note that the applicability of in-situ leaching depends on the specific
ore deposit and its characteristics. Feasibility studies, environmental assessments, and
regulatory approvals are necessary before implementing ISL as a mining method.