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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: illbruck SP350
· MSDS code: T-I-SP350
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture
Spacings sealant
Adhesives
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
tremco illbruck Produktion GmbH
Zweigniederlassung Traunreut
Traunring 65, D - 83301 Traunreut
Tel: +49 (0) 8669 34100, Fax: +49 (0) 8669 9784
[email protected]
· Further information obtainable from:
tremco illbruck Ltd
Coupland Road, Hindley Green, Wigan, WN2 4HT
T: +44 (0) 1942251400, F: +44 (0) 1942251410
www.tremco-illbruck.co.uk, [email protected]

· 1.4 Emergency telephone number:

During office hours tel.: +44 (0) 1942251400. At all other times please contact your national poisoning
centre.

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Supplemental information:
EUH210 Safety data sheet available on request.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Mixtures
· Description: Silane-terminated, hydrocarbon-based polymer with inorganic fillers
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 1)
· Dangerous components:
CAS: 2768-02-7 trimethoxyvinylsilane 1- <5%
EINECS: 220-449-8 Flam. Liq. 3, H226; STOT RE 2, H373; Acute Tox. 4,
Reg.nr.: 01-2119513215-52-xxxx H332
CAS: 13822-56-5 3-(trimethoxysilyl)propylamine 1- <5%
EINECS: 237-511-5 Skin Irrit. 2, H315; Eye Irrit. 2, H319
Reg.nr.: 01-2119510159-45-xxxx
· Additional information:
While curing the following substances are formed and released by a reaction with atmospheric
humidity:
Methanol (CAS 67-56-1)
For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information: Take affected persons out into the fresh air.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Remove from the skin using a cloth or paper. Then clean with water and soap.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor: No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 2)
· 6.2 Environmental precautions:
No special measures required.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Pick up mechanically.
Dispose of the material collected according to regulations.
· 6.4 Reference to other sections
By a reaction with atmospheric humidity by-products are released. See chapter 8.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection: No special measures required.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional Occupational Exposure Limit Values for possible hazards during processing:
While curing the following substances are formed and released by a reaction with atmospheric
humidity:
Methanol (CAS 67-56-1)
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Do not eat, drink, smoke or sniff while working.
· Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
Filter AX
· Protection of hands: Not required.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 3)
· Material of gloves Not applicable.
· Penetration time of glove material Not applicable.
· Eye protection: Safety glasses
· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Pasty
Colour: According to product specification
· Odour: Characteristic
· Melting point/freezing point: Undetermined.
· Initial boiling point and boiling range: Not applicable.
· Flash point: >151 °C
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product does not present an explosion hazard.
· Density at 20 °C: 1.47 g/cm³
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Solvent content:
Organic solvents: 0.0 %
VOC (EU) 0.2 g/l
VOC (EC) 0.01 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
None if stored according to specifications.
Beginning at approx. 150 °C small amounts of formaldehyde are formed by an oxidative
decomposition.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 4)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· Other information: The product is not biodegradable.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Uncured product may not be disposed of together with household waste and may not reach sewage
system. To dispose of, open product containers and let them stand in open air until the reaction is
finished totally (means there is no more smell). After that, waste can be disposed of as the cured
product.
Cured product can be deposited together with domestic waste. Observe the specific related
regulations of local authorities.
· European waste catalogue
08 04 09* waste adhesives and sealants containing organic solvents or other hazardous substances
08 04 10 waste adhesives and sealants other than those mentioned in 08 04 09
· Uncleaned packaging:
· Recommendation:
Empty contaminated packagings thoroughly. They may be recycled after thorough and proper
cleaning.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG, IATA Void
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 5)
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· UN "Model Regulation": Void

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
"CLP" Regulation (EC) No 1272/2008 (OJ L 353, 31.12.2008, p.1).
"REACH" Regulation (EC) No 1907/2006 (OJ L 396, 30.12.2006, p.1, with subsequent amendments).
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
· National regulations:
· Additional classification according to Decree on Hazardous Materials, Annex II:
No further relevant information available.
· Information about limitation of use: No further relevant information available.
· Other regulations, limitations and prohibitive regulations
· Substances of very high concern (SVHC) according to REACH, Article 57 Not applicable.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
(Contd. on page 7)
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 Page 7/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 07.06.2017 Version number 5 Revision: 07.06.2017

Trade name: illbruck SP350

(Contd. of page 6)
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
· * Data compared to the previous version altered.
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