1.

2000

1.0000
CALCUL
T/ °C
0.8000 COMPONENTS
94.880568
COMPOUND NO. CAS NO. COMPOUND NAME 94.694586
0.6000
1 141-78-6 Ethyl Acetate 94.620923
2 67-56-1 Methanol 94.516761
0.4000
94.262815
Whereas,
0.2000 Chart Title94.151668
γ1 and γ2 Activity coefficients for components 1 and 2 93.478417
390
0.0000 x1 and x2 Liquid mole fractions of components 1 and 2 93.392543
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000
gij 385
Parameter for interaction between components i and j 93.011412
α Column S Column R
380 Non-randomness parameter 92.784718
R Gas Constant 92.691477
375
T Temperature in K 92.592828
370 92.495055
ANTOINE'S 365CONSTANTS 92.068186
Methyl
360
Acetate Methanol 91.954464
Components
1 2 91.783813
355
A 7.10179 8.08097 91.667758
B 1244.951
350 1582.271 91.314972
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.
C 217.881 239.726 91.114754
Tmin (K) 189.6 523.3 91.037294
Tmax (K) 175.47 512.5 90.988883
91.045818
NRTL PARAMETERS 91.945397
g12 (J·mol )-1
1124.6 93.101411
g21 (J·mol-1) 2202.2 94.318922
Pressure (kPa) 300 kPa 95.476649

NOMENCLATURE
T Temperature of the system in °C
xi Liquid mole fraction of component i
Psati Vapor pressure of component i in Kpa
P Pressure of the system in kPa
yi Vapour mole fraction of component i
γi Activity coefficient of component i

α 0.47
R (J·mol-1·K-1) 8.3144598
γi Activity coefficient of component i
 CALCULATION OF VAPOR - LIQUID EQUILIBRIUM FOR ETHYL A
T/K x1 x2 τ12 τ21 G12 G21 γ1 γ2
368.03057 0.0000 1.0000 0.3675192991 0.7196789975 0.7130176325 0.8413613278 2.1814 1.0000
367.84459 0.0220 0.9780 0.3677051162 0.7200428658 0.712895704 0.8412878516 2.1325 1.0005
367.77092 0.0310 0.9690 0.3677787664 0.7201870881 0.7128473824 0.8412587304 2.1133 1.0010
367.66676 0.0440 0.9560 0.3678829598 0.7203911204 0.7127790271 0.8412175342 2.0865 1.0020
367.41281 0.0770 0.9230 0.368137231 0.7208890363 0.7126122417 0.8411170084 2.0228 1.0061
367.30167 0.0920 0.9080 0.3682486307 0.7211071799 0.7125391831 0.8410729705 1.9958 1.0087
e
366.62842 0.1890 0.8110 0.3689248569 0.722431371 0.7120958582 0.8408056979 1.8474 1.0367
366.54254 0.2020 0.7980 0.3690112894 0.7226006238 0.712039214 0.8407715423 1.8306 1.0420
366.16141 0.2610 0.7390 0.3693953862 0.723352765 0.7117875481 0.8406197753 1.7628 1.0705
365.93472 0.2970 0.7030 0.3696242241 0.7238008771 0.7116376524 0.8405293683 1.7274 1.0918
365.84148 0.3120 0.6880 0.3697184294 0.7239853505 0.7115759543 0.8404921534 1.7140 1.1016
365.74283 0.3280 0.6720 0.3698181511 0.7241806263 0.7115106492 0.8404527611 1.7004 1.1126
365.64505 0.3440 0.6560 0.36991704 0.7243742713 0.7114458953 0.8404136997 1.6877 1.1243
365.21819 0.4160 0.5840 0.3703494003 0.7252209224 0.7111628488 0.8402429371 1.6393 1.1855
365.10446 0.4360 0.5640 0.3704647563 0.7254468134 0.7110873495 0.8401973826 1.6284 1.2051
364.93381 0.4670 0.5330 0.3706379942 0.7257860492 0.7109739822 0.840128975 1.6135 1.2380
364.81776 0.4890 0.5110 0.3707559003 0.7260169336 0.7108968345 0.8400824198 1.6043 1.2633
364.46497 0.5640 0.4360 0.371114776 0.7267196867 0.7106620684 0.8399407337 1.5817 1.3628
0.8000 1.0000 1.2000
364.26475 0.6200 0.3800 0.3713187583 0.7271191264 0.7105286636 0.839860211 1.5729 1.4523
364.18729 0.6510 0.3490 0.3713977353 0.7272737797 0.7104770192 0.8398290367 1.5709 1.5084
364.13888 0.6840 0.3160 0.371447112 0.7273704696 0.7104447329 0.839809547 1.5709 1.5738
364.19582 0.7550 0.2450 0.3713890432 0.7272567588 0.710482703 0.8398324677 1.5784 1.7371
365.0954 0.8720 0.1280 0.3704739569 0.7254648301 0.7110813281 0.8401937494 1.6114 2.0909
366.25141 0.9320 0.0680 0.3693046147 0.7231750155 0.7118470149 0.8406556391 1.6374 2.3246
367.46892 0.9720 0.0280 0.368081022 0.7207789673 0.7126491078 0.8411392296 1.6575 2.5042
368.62665 1.0000 0.0000 0.3669250089 0.718515254 0.7134077309 0.8415963667 1.6725 2.6422

369.45
368.85
368.55
368.15
367.65
367.45
367.05
367.05
367.05
367.15
367.25
367.35
367.45
368.05
368.25
368.55
368.85
369.75
370.45
371.05
371.75
373.25
378.25
381.55
384.25
387.95
M FOR ETHYL ACETATE (1) + METHANOL (2) USING MARGULES EQUAT
P1 (in kPa) P2 (in kPa) P (in kPa) y1 y1 y2 y1 + y 2
0.0000 300.0000 300.0000 0.0000 0.0000 1.0000 1.0000
8.2247 291.7753 300.0000 0.0274 0.0350 0.9726 1.0000
11.4604 288.5396 300.0000 0.0382 0.0490 0.9618 1.0000
16.0110 283.9890 300.0000 0.0534 0.0630 0.9466 1.0000
26.9614 273.0386 300.0000 0.0899 0.1020 0.9101 1.0000
31.6797 268.3203 300.0000 0.1056 0.1170 0.8944 1.0000
59.0576 240.9424 300.0000 0.1969 0.1930 0.8031 1.0000
62.3887 237.6113 300.0000 0.2080 0.1960 0.7920 1.0000
76.7510 223.2489 300.0000 0.2558 0.2340 0.7442 1.0000
85.0136 214.9864 300.0000 0.2834 0.2540 0.7166 1.0000
88.3666 211.6334 300.0000 0.2946 0.2680 0.7054 1.0000
91.8931 208.1069 300.0000 0.3063 0.2750 0.6937 1.0000
95.3737 204.6263 300.0000 0.3179 0.2820 0.6821 1.0000
110.6154 189.3846 300.0000 0.3687 0.3200 0.6313 1.0000
114.7705 185.2295 300.0000 0.3826 0.3280 0.6174 1.0000
121.1853 178.8147 300.0000 0.4040 0.3440 0.5960 1.0000
125.7379 174.2627 300.0007 0.4191 0.3520 0.5809 1.0000
141.4730 158.5270 300.0000 0.4716 0.3970 0.5284 1.0000
153.7317 146.2684 300.0001 0.5124 0.4260 0.4876 1.0000
160.8384 139.1619 300.0002 0.5361 0.4460 0.4639 1.0000
168.7497 131.2508 300.0005 0.5625 0.4670 0.4375 1.0000
187.4675 112.5325 300.0000 0.6249 0.5250 0.3751 1.0000
227.0865 72.9135 300.0000 0.7570 0.6670 0.2430 1.0000
255.2602 44.7399 300.0001 0.8509 0.7930 0.1491 1.0000
279.3465 20.6536 300.0001 0.9312 0.8920 0.0688 1.0000
300.0003 0.0000 300.0003 1.0000 1.0000 0.0000 1.0000
RGULES EQUATION AT 300 KPA