SAFETY DATA SHEET

Solstice® ZE Refrigerant
10638161
Version 1.8 Revision Date 03/05/2019 Print Date 07/03/2023

SECTION 1. IDENTIFICATION

Product name : Solstice® ZE Refrigerant

Number : 000000016095

Product Use Description : Refrigerant

Manufacturer or supplier's : Honeywell International Inc.

details 115 Tabor Road
Morris Plains, NJ 07950-2546

For more information call : 800-522-8001

+1-973-455-6300

(Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-
527-3887
:
: (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : slight ether-like

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Solstice® ZE Refrigerant
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Classification of the substance or mixture

Classification of the : Gases under pressure, Liquefied gas
substance or mixture Simple Asphyxiant

GHS Label elements, including precautionary statements

Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas under pressure; may explode if heated.

May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention:

Use personal protective equipment as required.

Storage:
Protect from sunlight. Store in a well-ventilated place.

Carcinogenicity

No component of this product present at levels greater than or equal to 0.1% is identified as a known
or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical name CAS-No. Concentration

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SAFETY DATA SHEET

Solstice® ZE Refrigerant
10638161
Version 1.8 Revision Date 03/05/2019 Print Date 07/03/2023

trans-1,3,3,3-Tetrafluoroprop-1-ene 29118-24-9 100.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If breathing is irregular or stopped,

administer artificial respiration. Use oxygen as required,
provided a qualified operator is present. Call a physician.

Skin contact : Rapid evaporation of the liquid may cause frostbite. If there is
evidence of frostbite, bathe (do not rub) with lukewarm (not
hot) water. If water is not available, cover with a clean, soft
cloth or similar covering. Call a physician if irritation develops
or persists.

Eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. In case of frostbite water should be
lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the

inhalation section. Do not induce vomiting without medical
advice. Call a physician immediately.

Notes to physician

Indication of immediate : Treat frost-bitten areas as needed.

medical attention and
special treatment needed, if
necessary

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water mist
Dry powder
Foam
Carbon dioxide (CO2)

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Solstice® ZE Refrigerant
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Specific hazards during : Contents under pressure.

firefighting Heating will cause pressure rise with risk of bursting
Cool closed containers exposed to fire with water spray.
Product is not combustible under normal conditions.
However, this material can ignite when mixed with air under
pressure and exposed to strong ignition sources.
Do not allow run-off from fire fighting to enter drains or water
courses.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Some risk may be expected of corrosive and toxic
decomposition products.
Fire may cause evolution of:
Hydrogen fluoride
Carbon oxides
Carbonyl halides
Halogenated compounds

Special protective equipment : In the event of fire and/or explosion do not breathe fumes.
for firefighters Wear self-contained breathing apparatus and protective suit.
No unprotected exposed skin areas.
Exposure to decomposition products may be a hazard to
health.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Immediately evacuate personnel to safe areas.

protective equipment and Keep people away from and upwind of spill/leak.
emergency procedures Wear personal protective equipment. Unprotected persons
must be kept away.
Remove all sources of ignition.
Avoid skin contact with leaking liquid (danger of frostbite).
Ventilate the area.
After release, disperses into the air.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Avoid accumulation of vapours in low areas.
Unprotected personnel should not return until air has been
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Solstice® ZE Refrigerant
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tested and determined safe.

Environmental precautions : Prevent further leakage or spillage if safe to do so.

The product evapourates readily.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).

Methods and materials for : Do not direct water spray at the point of leakage.
containment and cleaning Allow to evaporate.
up

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe : Handle with care.

handling Avoid inhalation of vapour or mist.
Do not get in eyes, on skin, or on clothing.
Wear personal protective equipment.
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50 °C.
Follow all standard safety precautions for handling and use of
compressed gas cylinders.
Use authorized cylinders only.
Protect cylinders from physical damage.
Do not puncture or drop cylinders, expose them to open flame
or excessive heat.
Do not pierce or burn, even after use. Do not spray on a naked
flame or any incandescent material.
Do not remove screw cap until immediately ready for use.
Always replace cap after use.

Advice on protection : Do not spray on a naked flame or any incandescent material.

against fire and explosion Keep away from direct sunlight.
Fire or intense heat may cause violent rupture of packages.
Vapours may form explosive mixtures with air.
The product is not easily combustible.

Storage

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Solstice® ZE Refrigerant
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Conditions for safe storage, : Keep containers tightly closed in a cool, well-ventilated place.
including any Keep away from direct sunlight.
incompatibilities Protect cylinders from physical damage.
Store away from incompatible substances.

Further information on : Keep only in the original container at temperature not

storage conditions exceeding 50°C

Advice on common storage : Do not store together with:

Oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour.

Avoid contact with skin, eyes and clothing.
Ensure that eyewash stations and safety showers are close to
the workstation location.

Engineering measures : Local exhaust

Eye protection : Goggles

Hand protection : Protective gloves

Skin and body protection : Impervious clothing

Wear cold insulating gloves/ face shield/ eye protection.

Respiratory protection : In case of insufficient ventilation wear suitable respiratory

equipment.
Wear a positive-pressure supplied-air respirator.

Hygiene measures : Avoid breathing vapours, mist or gas.

Keep working clothes separately.

Exposure Guidelines
Components CAS-No. Value Control Upda Basis
parameters te

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Solstice® ZE Refrigerant
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trans-1,3,3,3- 29118-24-9 TWA : (800 ppm) 2012 WEEL:US. OARS.

Tetrafluoroprop- Time WEELs Workplace
1-ene weighted Environmental
average Exposure Level
Guide

trans-1,3,3,3- 29118-24-9 TWA : (800 ppm) 31.03. Honeywell:Limit

Tetrafluoroprop- Time 11 established by
1-ene weighted Honeywell
average International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : colourless

Odor : slight ether-like

pH : Note: neutral

Boiling point/boiling range : -19 °C

Flash point : Note: Not applicable

Lower explosion limit : Note: No LEL and UEL was assigned at standard testing
conditions, 20°C., Exhibits flame limits at temperatures in
excess of 28˚ C.

Upper explosion limit : Note: No LEL and UEL was assigned at standard testing
conditions, 20°C., Exhibits flame limits at temperatures in
excess of 28˚ C.

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Solstice® ZE Refrigerant
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Version 1.8 Revision Date 03/05/2019 Print Date 07/03/2023

Vapor pressure : 4,271 hPa

at 20 °C(68 °F)
11,152 hPa
at 54.4 °C(129.9 °F)

Vapor density : 4 Note: (Air = 1.0)

Density : 1.17 g/cm3 at 21.1 °C

Water solubility : 0.373 g/l

Partition coefficient: n- : log Pow: 1.6

octanol/water

Ignition temperature : 368 °C

Method: Auto-ignition temperature

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Hazardous polymerisation does not occur.

reactions
Conditions to avoid : Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 50 °C.
Can form a combustible mixture with air at pressures above
atmospheric pressure.
Do not mix with oxygen or air above atmospheric pressure.

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Version 1.8 Revision Date 03/05/2019 Print Date 07/03/2023

Incompatible materials : Reactions with alkali metals.

Hazardous decomposition : Halogenated compounds

products Carbon oxides
Hydrogen fluoride
Carbonyl halides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : Note: Not applicable study technically not feasible

Acute inhalation toxicity : Species: Mouse

Note: Acute (4-Hour) Inhalation Toxicity Screening Study
(mouse): No lethality at >100,000 ppm.

: LC50: > 207000 ppm

Exposure time: 4 h
Species: Rat

Acute dermal toxicity : Note: no data available study technically not feasible

Skin irritation : Species: Rabbit

Result: No skin irritation
Method: OECD Test Guideline 404

Eye irritation : Note: no data available study technically not feasible

Sensitisation : Cardiac sensitization

Species: dogs
Result: Did not cause sensitisation on laboratory animals.

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: Species: human
Result: Does not cause skin sensitisation.

Repeated dose toxicity : Species: Rat

Application Route: Inhalation
Exposure time: 13 Weeks
Note: Causes mild effects on the heart. NOEL 5,000 ppm

Genotoxicity in vitro : Test Method: Chromosome aberration test in vitro

Cell type: Human lymphocytes
Result: negative
Method: OECD Test Guideline 473

: Test Method: Ames test

Result: negative

Genotoxicity in vivo : Test Method: Mutagenicity (in vivo mammalian bone-marrow

cytogenetic test, chromosomal analysis)
Species: Mouse
Cell type: Micronucleus
Application Route: Inhalation
Method: OECD Test Guideline 474
Result: negative

Reproductive toxicity : Test Method: Two-generation study

Species: Rat
Application Route: Inhalation
NOEL: > 20,000 ppm
NOEL: > 20,000 ppm
Method: OECD Test Guideline 416

Teratogenicity : Species: Rabbit

Method: OECD 416
Note: Did not show teratogenic effects in animal experiments.

: Species: Rat
Method: OECD 416
Note: Did not show teratogenic effects in animal experiments.
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Solstice® ZE Refrigerant
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Teratogenicity : Species: RatApplication Route: Inhalation

NOAEC: 15,000 ppm

Method: OECD Test Guideline 414

Further information : Note: Excessive exposure may cause central nervous system
effects including drowsiness and dizziness. Excessive
exposure may also cause cardiac arrhythmia. Rapid
evaporation of the liquid may cause frostbite.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : static test

LC0: > 117 mg/l
Exposure time: 96 h
Species: Cyprinus carpio (Carp)
Method: OECD Test Guideline 203

Toxicity to daphnia and other : static test

aquatic invertebrates EC50: > 160 mg/l
Exposure time: 48 h
Species: Daphnia magna (Water flea)
Method: OECD Test Guideline 202

Toxicity to algae : Growth rate

NOEC: > 170 mg/l
Exposure time: 72 h
Species: Algae
Method: OECD Test Guideline 201

: Biomass
NOEC: > 170 mg/l
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Solstice® ZE Refrigerant
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Exposure time: 72 h
Species: Algae
Method: OECD Test Guideline 201

Elimination information (persistence and degradability)

Bioaccumulation : Note: No bioaccumulation is to be expected (log Pow <= 4).

Biodegradability : aerobic
Result: Not readily biodegradable.

Further information on ecology

Additional ecological : no data available
information

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental

regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163
Proper shipping name : LIQUEFIED GAS, N.O.S.
(trans-1,3,3,3-Tetrafluoroprop-1-ene)
Class 2.2
Packing group
Hazard Labels 2.2

IATA UN/ID No. : UN 3163

Description of the goods : LIQUEFIED GAS, N.O.S.
(trans-1,3,3,3-Tetrafluoroprop-1-ene)
Class : 2.2
Hazard Labels : 2.2
Packing instruction (cargo : 200
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aircraft)
Packing instruction : 200
(passenger aircraft)

IMDG UN/ID No. : UN 3163

Description of the goods : LIQUEFIED GAS, N.O.S.
(TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE)
Class : 2.2
Hazard Labels : 2.2
EmS Number : F-C, S-V
Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances : On TSCA Inventory

Control Act

Australia. Industrial : On the inventory, or in compliance with the inventory

Chemical (Notification and
Assessment) Act

Canada. Canadian : All components of this product are on the Canadian DSL
Environmental Protection
Act (CEPA). Domestic
Substances List (DSL)

Japan. Kashin-Hou Law : On the inventory, or in compliance with the inventory

List

Korea. Existing Chemicals : On the inventory, or in compliance with the inventory

Inventory (KECI)

Philippines. The Toxic : Not in compliance with the inventory

Substances and Hazardous
and Nuclear Waste Control
Act

China. Inventory of Existing : On the inventory, or in compliance with the inventory

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Chemical Substances

New Zealand. Inventory of : On the inventory, or in compliance with the inventory

Chemicals (NZIoC), as
published by ERMA New
Zealand

National regulatory information

SARA 302 Components : No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313 Components : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.

SECTION 16. OTHER INFORMATION

HMIS III NFPA
Health hazard : 1 2
Flammability : 1 1
Physical Hazard : 0
Instability : 0
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Solstice® ZE Refrigerant
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Version 1.8 Revision Date 03/05/2019 Print Date 07/03/2023

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the
use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user. This information should not constitute a guarantee for
any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
Previous Issue Date: 05/12/2016
Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group

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