01-06-22 - Sr.S60, ELITE, TARGET & LIIT - Jee-Main-GTM-18 - KEY & Sol'S
01-06-22 - Sr.S60, ELITE, TARGET & LIIT - Jee-Main-GTM-18 - KEY & Sol'S
01-06-22 - Sr.S60, ELITE, TARGET & LIIT - Jee-Main-GTM-18 - KEY & Sol'S
CHEMISTRY
31) 3 32) 2 33) 1 34) 2 35) 3
36) 3 37) 4 38) 1 39) 1 40) 1
41) 4 42) 1 43) 4 44) 4 45) 1
46) 3 47) 2 48) 1 49) 3 50) 4
51) 10 52) 288 53) 19 54) 0 55) 16
56) 106 57) 2 58) 50 59) 33 60) 19
MATHEMATICS
61) 3 62) 2 63) 4 64) 1 65) 1
66) 3 67) 3 68) 3 69) 2 70) 3
71) 1 72) 2 73) 3 74) 2 75) 2
76) 4 77) 2 78) 2 79) 2 80) 2
81) 5 82) 2 83) 120 84) 84 85) 0
86) 34 87) 2 88) 16 89) 15 90) 9
SOLUTIONS
PHYSICS
1. Sol.
a 1 / Ta 1 / T [ 1 / T ]
0.693
ln2
t nT1 n 2 5 449yr
1620
2
2
2 x 2 a2 x2
x asin(t / 2) cos t and sin t
a a2
y2
y asin2t sin 2 2t (2sintcost ) 2
2
a
y2 a 2 x 2 x 2
4
a2 a 2 a 2
a 2 y 2 4 x2 a 2 x2
600 600
2
7. = L0dt 1dT 2 n 2
7
300 300
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2 0.7 1.4
8. Theoretical
9. Theoretical
10. n C T 100
C 4
n CV T 15
CV 3
R 4 R
C CV 1 CV
n 1 3 n 1
R R
(n 1)3 n 1
n 1 3 3
n 4 4.2
1
n 0.2
5
3mg
11. vB
4
mg
vA
4
22
12. L1
4 3
2
41 2
3
13. Theoretical
14. f A 300
f B 301 Beats f A , f B 1Hz
fC 302 Beats f A , fC 2 Hz
so 2 beats
M 1L2T 2
|EB| Energy
15. M 1T 3
0 Area x Time L2T 1
16. As 2 Asinkx , 2mm 4mmsinkx
5 5 1
kx , x2 x1
6 6 6 6 ] k 3
As the string is vibrating in fundamental mode
L 2 L 3m
2
So, required separation between two points, x2 x1 1m
17.
1 1 1 1 1
1 3R 3R 3R R
R
1 1
R R
R2 R / 2
V
18. i 0 e t / RC
R
V t
n I n 0
R RC
By increasing C.
dB
19.
dt
A dB
E dl dl dt
E
BOA AB
2
dl a 2 1
E
22 0
20. v 220V i 2.2A
10 0
21. The intensity at distance x-from central order bright on screen is
2
I I1 I 2 2 I1 I 2 cos ,
I min I 0 I 0 3I o
I 3 / 4 I min I 3I 0
3I0 I 0 I 0 2 I 0 I0 cos
3I 0 I 0 (1 cos ) cos 1 / 2
yd
/ 3,2 / 3, / 3,.
D 6
D
y , ,
6 d 6 6
Where I 0 maximum intensity
fringle width
Hence the required distance 2 0.20 mm
6 3
2h
22. T t 2t1 (1 2e)
g
p 1 mm
23. LC 0.01 mm
N 100
The instrument has a positive zero error, e n( LC ) (6 0.01) 0.06 mm
Linear scale reading 2 (1 mm) 2 mm
Circular scale reading 62 (0.01 mm) 0.62 mm
Measured reading 2 0.62 2.62 mm
A sin
sin
A
True reading 2.62 0.06 2.56 mm 24.
sin A / Z
sin A
3 2cos A / 2
sin A / 2
cos A / 2 cos30o A 60o
D D D
25. 1
2d 2(2d ) 4d
26. A 2.21 10 1 2.2 10 1
A 4.9 10 2 m 2
1/3 3
R1 A1 A1 1 R1 1 1
27.
R2 A2 A2 2 R23 2 1
28. 208 10 6 1.6 10 19 N 10 10 6
10
N 1019
208 1.6
1000
N 1017
208 1.6
N 3 1017
1
29. 100 2% 2 1% 3
3
5%
15 3 12 2
30. M
18 18 3
CHEMISTRY
31. Sol. Bond order between P O
no. of bonds in all possible directioin 5
= 1.25
totalno.of resonatingstructures 4
32. Sol. At low pressure and high temperature real gas nearly behave like ideal
gas. Hence deviation in minimum from ideal behavior
33. Sol. Since, in the first reaction gaseous products are forming from solid
carbon hence entropy will increase i.e., S ve.
1
C(gr.) O2 (g) CO(g); S ve
2
Since, G o H o T S hence the value of G decrease on increasing temperature.
34. Sol. MY M Y
K SP s 2 6.2 1013
s 6.2 1013
NY3 N 3 3Y
K SP s (3s)3 27s 4 6.2 1013
1/4
6.2 1013
s
27
molar solubility of NY3 is more than MY in water.
35. Sol. Volume strength 5.6 Normality
5.6 1.5 8.4L
36. Sol. Ca and CaH 2 both react with water to from H 2 gas,
Ca 2H 2O
Ca(OH)2 H2
CaH 2 2H 2O Ca(OH)2 2H2
whereas
K gives H 2 while KO 2 gives O 2 and H 2O 2
2K 2H 2O
2KOH H 2
2KO2 2H 2O 2KOH O2 H 2O2
Also, Ba gives H 2 while BaO 2 gives H 2O 2
Ba 2H 2O
Ba(OH)2 H2
BaO2 2H 2O
Ba(OH)2 H 2O2
37. Sol. Potash Alum K 2SO 4 .Al2 (SO 4 ).24H 2O is a double salt.
38. Sol. In the molecules
Actually this reaction is autocatalyzed and involves complex calculation for concentration
terms.
We can look at the above results in a simple way to find the dependence of reaction rate
(i.e. rate of disappearance of Br2 )
rate k[CH3COCH3 ]1[Br2 ]0[H ]1 k[CH 3COCH 3 ][H ] .
46. Sol. According to this law the coagulation effect of an ion on dispersed
phase of opposite charge increases with the valency of the ion. The precipitating power of
Al3 , Ba , Na ions is in order Al3 Ba 2 Na .
47. Sol. Al 2O3 cannot be reduced by carbon.
48. Sol. Magnesium and managanese are the metals that produce hydrogen
with dilute nitric acid
Mg 2HNO3 Mg(NO3 )2 H2
49. Sol. Both are reducing agents.
50. Sol. The total number of isomers for the complex compound
[Cu II (NH3 )4 ][Pt IICl 4 ] is four. These four isomers are
[Cu(NH3 )3 Cl][Pt(NH 3 )Cl3 ],
[Cu(NH3 )Cl3 ][Pt(NH 3 )3 Cl],
[CuCl4 ][Pt(NH 3 ) 4 ] and [Cu(NH3 ) 4 ][PtCl4 ]
1 100
ln
t
51. Sol. 99.9% K 0.1
t 50% 1
ln 2
K
ln1000 3ln10 3 2.3
t50% 1 10
ln 2 ln 2 0.69
52. Sol. From Kohlrausch’s law
2
m (BaSO4 ) m (Ba ) m (SO 4 )
2
m (BaSO 4 ) m (BaCl2 ) m (H 2SO 4 )
2
m (HCl)
280 860 2(426)
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As we know that ethylene diamine is a bidentate ligand and ammonia is a mono dentate
ligand. It means overall two ethylene diamine is required to replace the all neutral
ligands (four ammonia) from the coordination sphere of this complex.
58. Sol. For A 2 X
A 2 X 2A X 2
2S1 S1
K sp 4S12 4 1012
S1 104
for MX
MX M X
S2 S2
SA 2X 104
So 50
SMX 2 106
59. Sol. For BCC 3 a 4r
3
so r 27
4
for FCC a 2 2r
3 3
2 2 27 27 33
4 2
60. Sol. In Duma's method of estimation of Nitrogen.
0.1840 gm of organic compound gave 30 mL of nitrogen which is collected at 287 K &
758 mm of Hg.
Given ; Aqueous tension at 287 K = 14 mm of Hg.
Hence actual pressure = (758 - 14) = 744 mm of Hg.
MATHEMATICS
61. Sol. We have
2 1 n
n 1
S 1 ...
1
n n
But n cos i sin 1
n n
2
Thus, S
1
But 1 1 cos i sin
n n
2
2sin 2 2i sin cos
2n 2n 2n
2i sin cos i sin
2n 2n 2n
1
2
Thus, S cos i sin
2i sin( n) 2n 2n
Alternatively, we write
2e i /2n
S
e i /2 n e i /2 n
1 i cot
2n
62. Sol. x 2 (k 3) x k 4
( x 1)( x k 4)
(1) can be written as
2019
| x 1| k2 | x k 4| 0
k 1
x 1
2019 2
k | x k 4 | 0 x R
k 1
63. Sol. a c 2b 3b a b c 3 / 2 b 1/ 2
Thus, a c 1 and a 2 c 2 b 4 1 / 6
a 2 (1 a )2 1 / 16 a (1 a ) 1 / 4
a2 a 1 / 4 0
1 1 1
a or a
2 2 2
1 1 1
As a b c and b , we get a .
2 2 2
64. Sol. A B A( A B )1 A B ( A B )1 B
A[ I ( A B )1 A] [ I B( A B) 1]B
A( A B )1[ A B A] [ A B B]( A B )1 B
A( A B)1 B A( A B)1 B
O
65. Sol. Taking c3 common from R3 and applying R2
R2
R3 and
R1
R1
R3 . We obtain
a12 b1 a1a2 b2 a1a3 b3
1 c3 b1b2 b22 b2b3
c1 c2 c3
1
P ( X 4) [all xi ' s are equal to 4]
n
6
Now,
E ( X ) 1P( X 1) 2 P( X 2) ... 6 P ( X 6)
1 1
[(6n 2n 3n ) 2(3n 2) 3(2n 1) 4(1) 5(1) 6(1)] (6n 3n 2n 1 8)
6n 6n
2sec 4sec 2 4
67. Sol. 1, 1
2
sec tan
As and 1 1
6 12
We get 1 sec tan
2 tan 4 tan 2
Next, 2 , 2 tan sec
2
Let the coordinates of A be (a, 0) and that of B be (0, b) Fig. Since ZAOB = k/2, the line
AB is a diameter of the circle circumscribing the triangle OAB, its centre
is the mid-point of AB, i.e., (a/2, b/2), and its radius is
a2 b2
AL m and BM n
2 2
a b a 2 b2
Hence m n a 2 b2 is the diameter of the circle.
70. Sol.As the ellipse intersect in four distinct points, a 1.
Thus, b 2 5b 7 1
(b 2)(b 3) 0
b (2, 3)
71. Sol. An equation of the plane through the line of intersection of
x 2 y 3 z 2 0 and x y z 3 0 is ( x 2 y 3z 2) x y z 3) 0
or (1 x (2 ) y (3 ) z (2 3 ) 0
Its distance from the point (3, 1, 1) is
| (1 ( ) |
(1 2 (2 2 (3 2
Thus, an equation of required plane is
2( x 2 y 3 z 2) 7( x y z 3) 0
5 x 11 y z 17
dy
72. Sol. 3ax2 2bx c
dx
Since the curve touches x-axis at (2, 0) so
dy
0 12a 4b c 0
dx (2, 0)
The curve cut the y-axis at (0, 8) so
dy
3 c 3
dx (0, 8)
Also the curve passes through (2,0) so
0 8a 4b 4b 2c 8 8a 4b 2 0 (ii)
Solving (i) and (ii) a 1 / 4, b 0
73. Sol. a n b where n Z
74. Sol. For any x R, x [ x ] {x} so
[ x] { x} 2[ x] x. Thus
2 0 1 2
1 | [ x ] {x}| dx (2 x ) dx xdx (2 x ) dx
1 0 1
1 1 3 5
2 2 2
2 2 2 2
75. Sol.Putting u = x y, we det du / dt 1 dy / dx.
The given equation can be written as 1 du / dx cos u (1 cos u ) du / dx
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du 1
1 cos u dx cosec2 (u / 2)du dx
2
x y
x cot(u / 2) const. x cot C.
2
3 3
Putting y 1 C
2 2
a (b × c) [abc]
76. Sol. ap = = =1
[abc] [abc]
b (b × c) 0
bp = = =0
[abc] [abc]
c (c × a)
cq = =0
[abc]
c (a × b)
cr = = (a × b) c = 1 and a r = 0
[abc]
Therefore, the given expression is equal to 1 + 0 + 1 + 0 + 1 + 0 = 3.
77. Sol. Taking log of both the sides with base 3, we have
(log3 x 2 (log3 x )2 10)(log3 x) 2log3 x
This equation is equivalent to
log 3 x 0 or 2log 3 x (log3 x )2 8 0
Hence x 1, 32 , 34 1, 9, 1 / 81.
2
xi 2 xi
78. Sol. Variance
n n
xi 2
4 4 xi 2 40
5
yi 2
and 5 16 yi 2 105
5
2
x 2 yi 2 xi yi
Variance of combined set i
10 10
5.5
79. Equation of the tangent at P ( x1, y1) to the parabola y 2 4ax is yy1 2a ( x x1)
Or 2 ax y1 y 2ax1 0 (i)
If M (h, k) is the mid-point of QR, then equation of QR a chord of the parabola
y 4a x b in terms of its mid-point is ky 2a x h 4ab k 2 4a h b
(usingT = S' ) or 2ax ky k 2 2ah 0 (ii)
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Since (i) and (ii) represent the same line, we have
2a y1 2ax1
2a k k 2 2ah
y12 2ah 2ax1 4ax1 2ax1 2ah
h x1
80. Since ( p q ) p q
[( p r ) (r q )] ( p r ) [ (r q)]
( p r ) ( r q)
81. Sol. Let and be two roots of x 2 px q 0 and assume We have
p, q
As q is prime, we must have q.
Thus, p 1 q p q 1.
As p and q are prime, this is possible if p 3, q 2.
(2 1)(3 1).........(n 1) (22 2 1)(32 3 1)...(n 2 n 1)
82. Sol. an
(2 1)(3 1)........(n 1) (2 2 2 1)(32 3 1)...( n 2 n 1)
Since (k 1)2 (k 1) 1 k 2 k 1, we get
(1)(2) (n2 n 1) 2
an . lim an .
n(n 1) 3 n 3
83. Sol. A function f : A B such that f (0) f (1) f (2) falls is one of the
following four categories.
Case 1 f (0) f (1) f (2)
There are 8 C3 functions in this category.
Case 2 f (0) f (1) f (2)
There are 8 C2 functions in this category.
Case 3 f (0) f (1) f (2)
There are 8 C2 functions in this category.
Thus, the number of desired functions is
8
C3 8C2 8C2 8C1 9C3 9C2 10C3 .
84. Sol. We are given
m
C0 mC1 mC2 46 2m m(m 1) 90
m 2 m 90 0 m 9 as m 0
m
1
Now, (r 1) th term of x 2 is
x
term independent of x is 9C6 84
85. Sol.The given equation can be written as
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