Material Safety Data Sheet

Revision Number: 003.3 Issue date: 06/30/2011

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: BONDERITE M-AD 131 IDH number: 595349
ACCELERATOR known as
ACCELERATOR 131
Product type: Additive
Region: United States
Company address: Contact information:
Henkel Corporation Telephone: 248.583.9300
32100 Stephenson Highway MEDICAL EMERGENCY Phone: Poison Control Center
Madison Heights, MI 48071 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 2
Color: Yellow FLAMMABILITY: 0
Odor: Odorless PHYSICAL HAZARD: 0
Personal Protection: See MSDS Section 8
WARNING: HARMFUL OR FATAL IF SWALLOWED.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: This product may be harmful by inhalation. This product is irritating to the respiratory system.
Skin contact: This product may cause irritation to the skin. This product may discolor the skin. A component
in this product may be absorbed through the skin, especially if skin is damaged.
Eye contact: This product may cause irritation to the eyes.
Ingestion: This product may be fatal if it is swallowed. This product may cause methemoglobinemia
characterized by a reduction in oxygen carrying capacity of the blood with symptoms including
headache, dizziness, flushed face, fatigue, nausea, vomiting, drowsiness, stupor, tremors,
uneven heart action, coma and rarely death.

Existing conditions aggravated by Eye, skin, and respiratory disorders. Preexisting cardiovascular or bone marrow diseases.
exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous components CAS NUMBER %
Sodium nitrite 7632-00-0 30 - 60

IDH number: 595349 Product name: BONDERITE M-AD 131 ACCELERATOR known as ACCELERATOR 131
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 4. FIRST AID MEASURES
Inhalation: If mist or vapor of this product is inhaled, remove person immediately to fresh
air. Seek medical attention if symptoms develop or persist.

Skin contact: Remove contaminated clothing and footwear. Immediately wash skin
thoroughly with soap and water. If symptoms develop and persist, get medical
attention.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Get immediate medical attention. Do not induce vomiting. Never give anything
by mouth to a victim who is unconscious or is having convulsions.

Notes to physician: Treat symptomatically and supportively.If cyanosis is severe, intravenous

injection of methylene blue, 1 mg/kg body weight, may be of value.

5. FIRE FIGHTING MEASURES

Flash point: Not applicable

Autoignition temperature: Not determined

Flammable/Explosive limits - lower: Not applicable

Flammable/Explosive limits - upper: Not applicable

Extinguishing media: Use media appropriate for surrounding material.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: If evaporated to dryness, solid residue is an oxidizing agent and may cause
spontaneous ignition of combustible materials.

Hazardous combustion products: Irritating and toxic gases or fumes may be released during a fire.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up. Do not allow product to
enter sewer or waterways.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, State and local governmental
regulations.

7. HANDLING AND STORAGE

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of
this product. For industrial use only. Do not take internally. Wash thoroughly
after handling. Do not mix this product with material which contain AMINES.
NITROSAMINE may be formed.

Storage: For safe storage, store between 4.4 °C (39.9 °F) and 37.8 °C (100°F)
Keep container tightly closed and in a cool, well-ventilated place away from
incompatible materials. Store away from acids, ammonium compounds, and
reducing agents,particularly cyanides, thiocyanides and thiosulfates. Sodium
nitritemay react with organic amines to form nitrosamines.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 595349 Product name: BONDERITE M-AD 131 ACCELERATOR known as ACCELERATOR 131
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 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER

2 mg/m3 TWA
Sodium nitrite None None None
Respirable fraction.

Engineering controls: Use general ventilation and use local exhaust, where possible, in confined or
enclosed spaces.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.
Respirators should be selected by and used under the direction of a trained
health and safety professional following requirements found in OSHA's
respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory
protection (Z88.2-1992). A written respiratory protection program, including
provisions for medical certification, training, fit testing, exposure assessments,
maintenance, inspection, cleaning, and convenient, sanitary storage must be
implemented. If concentrations are below the TLV and/or PEL, a NIOSH
approved disposable dust/mist respirator may be used for personal comfort.
For concentrations above the TLV and/or PEL but less than 10 times these
limits, a NIOSH approved half-facepiece respirator equipped with dust-mist
cartridges may be used. For concentrations greater than 10 times these limits,
consult the NIOSH respirator decision logic found in Publication No. 87-116 or
ANSI Z88.2-1992.

Eye/face protection: Wear chemical goggles; face shield (if splashing is possible).

Skin protection: Chemical resistant, impermeable gloves. Gloves such as PVC or nitrile are
recommended. Use of impervious apron and boots are recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Yellow
Odor: Odorless
Odor threshold: Not available
pH: 7.0 - 8.0
Vapor pressure: Not determined
Boiling point/range: > 210 °F (> 98.9 °C)
Melting point/ range: -12 °C (10.4 °F)
Specific gravity: 1.30 - 1.32
Vapor density: Not determined
Flash point: Not applicable
Flammable/Explosive limits - lower: Not applicable
Flammable/Explosive limits - upper: Not applicable
Autoignition temperature: Not determined
Evaporation rate: Not determined
Solubility in water: Complete
Partition coefficient (n-octanol/water): Not available
VOC content: 0 % (calculated)

IDH number: 595349 Product name: BONDERITE M-AD 131 ACCELERATOR known as ACCELERATOR 131
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 10. STABILITY AND REACTIVITY
Stability: Stable at normal conditions.

Hazardous reactions: None under normal processing.

Hazardous decomposition products: Irritating and/or toxic fumes and gases may be emitted upon the product's
decomposition. Decomposes with heat to produce oxides of nitrogen.

Incompatible materials: This product may react with ammonium compounds and reducing
agents,particularly cyanides, thiocyanates and thiosulfates. Sodium nitrite
may react with organic amines to form nitrosamines. This product reacts with
acids to produce oxides of nitrogen. If evaporated to dryness, dry residue is
combustible. Keep away from heat, spark and flame. Dry residues of sodium
nitrite and sodium thiosulfate explode upon heating.

Conditions to avoid: This product is an OXIDIZING AGENT - avoid contact with organic material.

11. TOXICOLOGICAL INFORMATION

OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Sodium nitrite No No No

Hazardous components Health Effects/Target Organs

Sodium nitrite Blood, Central nervous system, Mutagen, Vascular

12. ECOLOGICAL INFORMATION

Ecological information: Toxic to aquatic organisms

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

Hazardous waste number: Material, if discarded, is not expected to be a characteristic hazardous waste
under RCRA. Wastes must be tested using methods described in 40 CFR Part
261 to determine if it meets applicable definitions of hazardous wastes.

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Toxic liquid, inorganic, n.o.s. (Sodium nitrite)
Hazard class or division: 6.1
Identification number: UN 3287
Packing group: III
DOT Reportable quantity: Sodium nitrite

International Air Transportation (ICAO/IATA)

Proper shipping name: Toxic liquid, inorganic, n.o.s. (Sodium nitrite)
Hazard class or division: 6.1
Identification number: UN 3287
Packing group: III

Water Transportation (IMO/IMDG)

Proper shipping name: TOXIC LIQUID, INORGANIC, N.O.S. (Sodium nitrite)
Hazard class or division: 6.1
Identification number: UN 3287
Packing group: III

IDH number: 595349 Product name: BONDERITE M-AD 131 ACCELERATOR known as ACCELERATOR 131
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 15. REGULATORY INFORMATION
United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12(b) Export Notification: Sodium nitrite (CAS# 7632-00-0).

CERCLA/SARA Section 302 EHS: None above reporting de minimus

CERCLA/SARA Section 311/312: Immediate Health
CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Sodium nitrite (CAS# 7632-00-0).
CERCLA Reportable quantity: Sodium nitrite (CAS# 7632-00-0) 100 lbs. (45.4 kg)

California Proposition 65: No California Proposition 65 listed chemicals are known to be present.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
WHMIS hazard class: D.1.B, D.2.B, C

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet
format.

Prepared by: Jennifer Mckay, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However,
Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel
Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any
production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the
protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel
Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or
implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel
Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any
kind, including lost profits.

IDH number: 595349 Product name: BONDERITE M-AD 131 ACCELERATOR known as ACCELERATOR 131
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