SAFETY DATA SHEET

PLEXIGLAS® V-GRADE ACRYLIC RESIN

1. PRODUCT AND COMPANY IDENTIFICATION

Company

Altuglas LLC
100 PA Rt. 413
Bristol, PA 19007, USA

Altuglas LLC

Customer Service Telephone Number: (800) 523-1532

(Monday through Friday, 8:00 AM to 5:00 PM EST)

Emergency Information

Transportation: CHEMTREC: (800) 424-9300

(24 hrs., 7 days a week)
Medical: Rocky Mountain Poison Center: (866) 767-5089
(24 hrs., 7 days a week)

Product Information

Product name: PLEXIGLAS® V-GRADE ACRYLIC RESIN

Synonyms: Not available
Molecular formula: Mixture
Chemical family: Acrylic copolymers
Product use: Polymers industry, Special applications, in general

2. HAZARDS IDENTIFICATION

Emergency Overview

Color: Clear - colourless

Physical state: solid
Form: pellets
Odor: slightly acrylic

*Classification of the substance or mixture:

Not a hazardous substance or mixture.

GHS-Labelling

Supplemental Hazard Statements:

Processing may release vapors and/or fumes which cause eye, skin and respiratory tract irritation.

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Supplemental information:

Potential Health Effects:

The product, in the form supplied, is not anticipated to produce significant adverse human health effects.
Contains high molecular weight polymer(s). Effects due to processing releases or residual monomer: Irritating to
eyes, respiratory system and skin. Possible cross sensitization with other acrylates and methacrylates.
Prolonged or repeated exposure may cause: headache, drowsiness, nausea, weakness.(severity of effects
depends on extent of exposure) .

Other:
Handle in accordance with good industrial hygiene and safety practice. (pellets/granules) This product may
release fume and/or vapor of variable composition depending on processing time and temperature.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Wt/Wt GHS Classification**

Acrylic copolymers >= 98 - <= 100

Proprietary* Not classified
%

*The specific chemical identity is withheld because it is trade secret information of Altuglas LLC.

**For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1. Description of necessary first-aid measures:

Inhalation:
If inhaled, remove victim to fresh air.

Skin:
In case of contact, immediately flush skin with plenty of water. If molten polymer gets on the skin, cool rapidly with
cold water. Do not peel solidified product off the skin. Obtain medical treatment for thermal burns. Remove material
from clothing. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Eyes:
Immediately flush eye(s) with plenty of water. Obtain medical treatment for thermal burns.

Ingestion:

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If swallowed, DO NOT induce vomiting. Get medical attention. Never give anything by mouth to an unconscious
person.

4.2. Most important symptoms/effects, acute and delayed:

For most important symptoms and effects (acute and delayed), see Section 2 (Hazard Statements and Supplemental
Information if applicable) and Section 11 (Toxicology Information) of this SDS.

4.3. Indication of immediate medical attention and special treatment needed, if necessary:

Unless otherwise noted in Notes to Physician, no specific treatment noted; treat symptomatically.

5. FIREFIGHTING MEASURES

Extinguishing media (suitable):

Water spray, Carbon dioxide (CO2), Foam, Dry chemical

Protective equipment:
Fire fighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear
(full Bunker Gear) and self-contained breathing apparatus (pressure demand / NIOSH approved or equivalent).

Further firefighting advice:

Fire fighting equipment should be thoroughly decontaminated after use.

Fire and explosion hazards:

Heated material can form flammable vapors with air.
When burned, the following hazardous products of combustion can occur:
Carbon oxides
Hazardous organic compounds

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, Emergency procedures, Methods and materials for containment/clean-up:

Prevent further leakage or spillage if you can do so without risk. Ventilate the area. Sweep up and shovel into
suitable properly labeled containers for prompt disposal. Possible fall hazard – floor may become slippery from
leakage/spillage of product. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for
assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinent
environmental permits.

Protective equipment:
Appropriate personal protective equipment is set forth in Section 8.

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7. HANDLING AND STORAGE

Handling

General information on handling:

Avoid breathing dust.
Avoid breathing processing fumes or vapors.
Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding
unnecessary exposure and removal of material from eyes, skin, and clothing.

Storage

General information on storage conditions:

This material is not hazardous under normal storage conditions; however, material should be stored in closed
containers, in a secure area to prevent container damage and subsequent spillage.

Storage incompatibility – General:

Store away from sources of heat and light.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Airborne Exposure Guidelines:

Particles Not Otherwise Specified / Nuisance Dust (Proprietary)

US. ACGIH Threshold Limit Values

Form: Respirable particles.

Time weighted average 3 mg/m3
Form: Inhalable particles.
Time weighted average 10 mg/m3

US. OSHA Table Z-3 (29 CFR 1910.1000)

Form: Respirable fraction.

Time weighted average 15millions of particles per cubic foot of air

US. OSHA Table Z-3 (29 CFR 1910.1000)

Form: Total dust

Time weighted average 50millions of particles per cubic foot of air

US. OSHA Table Z-3 (29 CFR 1910.1000)

Form: Respirable fraction.

Time weighted average 5 mg/m3

US. OSHA Table Z-3 (29 CFR 1910.1000)

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Form: Total dust

Time weighted average 15 mg/m3

Only those components with exposure limits are printed in this section. Limits with skin contact designation above have skin contact
effect. Air sampling alone is insufficient to accurately quantitate exposure. Measures to prevent significant cutaneous absorption
may be required. Limits with a sensitizer designation above mean that exposure to this material may cause allergic reactions.

Engineering controls:
Investigate engineering techniques to reduce exposures below airborne exposure limits or to otherwise reduce
exposures. Provide ventilation if necessary to minimize exposures or to control exposure levels to below
airborne exposure limits (if applicable see above). If practical, use local mechanical exhaust ventilation at
sources of air contamination such as open process equipment.

Respiratory protection:
Avoid breathing dust. Avoid breathing processing fumes or vapors. Where airborne exposure is likely or
airborne exposure limits are exceeded (if applicable, see above), use NIOSH approved respiratory protection
equipment appropriate to the material and/or its components and substances released during processing.
Consult respirator manufacturer to determine appropriate type equipment for a given application. Observe
respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where
there may be a potential for significant exposure or where exposure limit may be significantly exceeded, use an
approved full face positive-pressure, self-contained breathing apparatus or positive-pressure airline with
auxiliary self-contained air supply. Respiratory protection programs must comply with 29 CFR § 1910.134.

Skin protection:
Processing of this product releases vapors or fumes which may cause skin irritation. Minimize skin
contamination by following good industrial hygiene practice. Wearing protective gloves is recommended. Wash
hands and contaminated skin thoroughly after contact with processing fumes or vapors. Wash thoroughly after
handling.

Eye protection:
Use good industrial practice to avoid eye contact. Processing of this product releases vapors or fumes which
may cause eye irritation. Where eye contact may be likely, wear chemical goggles and have eye flushing
equipment available.

9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear - colourless

Physical state: solid

Form: pellets

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Odor: slightly acrylic

Odor threshold: No data available

Flash point Not applicable

Auto-ignition 739 °F (393 °C)

temperature:

Lower flammable limit Not applicable

(LFL):

Upper flammable limit Not applicable

(UFL):

pH: Not applicable

Density: 1.19 g/cm3

Specific Gravity (Relative No data available

density):

Boiling point/boiling Not applicable

range:

Melting point/range: Not applicable

Freezing point: Not applicable

Evaporation rate: No data available

Solubility in water: Not applicable

Viscosity, dynamic: No data available

% Volatiles: 0%

Oil/water partition (No data available)

coefficient:

Thermal decomposition: 572 °F (300 °C)

Flammability: See GHS Classification in Section 2 if applicable

10. STABILITY AND REACTIVITY

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Stability:
This material is chemically stable under normal and anticipated storage, handling and processing conditions.

Hazardous reactions:
Hazardous polymerization does not occur.

Materials to avoid:
None under normal conditions of use.

Conditions / hazards to avoid:

Avoid flames, welding arcs, potential ignition sources, or other high temperature sources which induce thermal
decomposition.

Hazardous decomposition products:

Thermal decomposition giving flammable and toxic products :

Carbon oxides
Acrylates
Methacrylates
Hazardous organic compounds

11. TOXICOLOGICAL INFORMATION

Data on this material and/or its components are summarized below.

Data for Acrylic copolymers (Proprietary)

Other information
The information presented is from representative materials in this chemical class. The results may vary
depending on the test substance. Effects due to processing releases or residual monomer:
Possible cross sensitization with other acrylates and methacrylates.

12. ECOLOGICAL INFORMATION

Chemical Fate and Pathway

No data are available.

Ecotoxicology
No data are available.

13. DISPOSAL CONSIDERATIONS

Waste disposal:
Where possible recycling is preferred to disposal or incineration. If recycling is not an option, incinerate or dispose of
in accordance with federal, state, and local regulations. Pigmented, filled and/or solvent laden product may require
special disposal practices in accordance with federal, state and local regulations. Consult a regulatory specialist to
determine appropriate state or local reporting requirements, for assistance in waste characterization and/or
hazardous waste disposal and other requirements listed in pertinent environmental permits. Note: Chemical
additions to, processing of, or otherwise altering this material may make this waste management information

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incomplete, inaccurate, or otherwise inappropriate. Furthermore, state and local waste disposal requirements may
be more restrictive or otherwise different from federal laws and regulations.

14. TRANSPORT INFORMATION

US Department of Transportation (DOT): not regulated

International Maritime Dangerous Goods Code (IMDG): not regulated

15. REGULATORY INFORMATION

Chemical Inventory Status

US. Toxic Substances Control Act TSCA The components of this product are all on
the Active TSCA Inventory.

United States – Federal Regulations

SARA Title III – Section 302 Extremely Hazardous Chemicals:

The components in this product are either not SARA Section 302 regulated or regulated but present in negligible
concentrations.

SARA Title III - Section 311/312 Hazard Categories:

No SARA Hazards

SARA Title III – Section 313 Toxic Chemicals:

The following components are subject to reporting levels established by SARA Title III, Section 313:

Chemical name CAS-No. De minimis Reportable threshold:

concentration
2-Propenoic acid, ethyl ester 140-88-5 0.1 % 10000 lbs (Otherwise
used (non-
manufacturing/processing))
25000 lbs (Manufacturing
and processing)

Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Reportable

Quantity (RQ):

Chemical name CAS-No. Reportable quantity

Methyl methacrylate 80-62-6 1000 lbs

2-Propenoic acid, ethyl ester 140-88-5 1000 lbs

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16. OTHER INFORMATION

Miscellaneous:

Grades: V825SF22-100, VMHFSF5NA-100, V920SF11NA-100,

V825UVA5A-100, V825NA -100, V825-100, V045NA-100, V046P-
100, V825UVA-100, V826-100, V052-100, V045SF16-100,
V046LSF1NTP-100, V825-100, V920SF11LT-100, V826A-100,
V920NC-101, V826P2-100, V920-100, V045-100, V920NA-100,
V920SF11-100, VS-100, V044-100, V825T-101, V920T-101

Latest Revision(s):

Reference number: 600001875

Date of Revision: 04/30/2021
Date Printed: 05/01/2021

® Trademark of Trinseo S.A. or its affiliates.

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof.
Since the conditions and methods of use of the product and of the information referred to herein are beyond our control, Altuglas
LLC expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such
information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY
OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION
PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable
when such product is used in combination with other materials or in any process. The user should thoroughly test any application
before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be
construed as an inducement to infringe any patent and the user is advised to take appropriate steps to be sure that any proposed
use of the product will not result in patent infringement. See SDS for Health & Safety Considerations.

Altuglas LLC has implemented a Medical Policy regarding the use of Altuglas LLC products in Medical Devices applications that are
in contact with the body or circulating bodily fluids. Altuglas LLC has designated Medical grades to be used for such Medical Device
applications. Products that have not been designated as Medical grades are not authorized by Altuglas LLC for use in Medical
Device applications that are in contact with the body or circulating bodily fluids. In addition, Altuglas LLC strictly prohibits the use of
any Altuglas LLC products in Medical Device applications that are implanted in the body or in contact with bodily fluids or tissues for
greater than 30 days. The Altuglas LLC trademarks and the Altuglas LLC name shall not be used in conjunction with customers'
medical devices, including without limitation, permanent or temporary implantable devices , and customers shall not represent to
anyone else, that Altuglas LLC allows, endorses or permits the use of Altuglas LLC products in such medical devices.
It is the sole responsibility of the manufacturer of the medical device to determine the suitability (including biocompatibility) of all raw
materials, products and components, including any medical grade Altuglas LLC products, in order to ensure that the final end-use
product is safe for its end use; performs or functions as intended; and complies with all applicable legal and regulatory requirements
(FDA or other national drug agencies) It is the sole responsibility of the manufacturer of the medical device to conduct all necessary
tests and inspections and to evaluate the medical device under actual end-use requirements and to adequately advise and warn
purchasers, users, and/or learned intermediaries (such as physicians) of pertinent risks and fulfill any postmarket surveillance
obligations. Any decision regarding the appropriateness of a particular Altuglas LLC material in a particular medical device should
be based on the judgment of the manufacturer, seller, the competent authority, and the treating physician.

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