Material Safety Data Sheet - MSDS

RTV Silicone Sealant

Section 1. Chemical Product and Company Identification
Common Name : RTV Silicone Sealant Code : RTV3, RTV8, RTV10,
RTV10W
Synonym : Not available. Validation Date : 2004-10-24.
Trade name : RTV Silicone Sealant RTV3, RTV8, RTV10, In Case of Emergency : (714) 739-1408
RTV10W.
Manufactured for : L.H. Dottie Company
6131 S. Garfield Avenue
Commerce, California 90040
Tel: (323) 725-1000

Section 2. Composition, Information on Ingredients

Name CAS # % by Weight Exposure Limits
Silica, Amorphous 7631-86-9 15-30 NIOSH REL (United States, 2001).
TWA: 6 mg/m3 10 hour(s). Form: All forms
Titanium dioxide 13463-67-7 1-3 ACGIH TLV (United States, 2003). :
TWA: 10 mg/m3 8 hour(s). Form: All forms
OSHA PEL (United States, 1993).
TWA: 15 mg/m3 8 hour(s). Form: Total dust
Silanetriol, ethyl-, triacetate 17689-77-9 1-3 Not available.
Silanetriol, methyl-, triacetate 4253-34-3 1-3 Not available.
This material is classified as not hazardous under OSHA regulations.

See Section 8 for Exposure Limits.

See Section 11 for Toxicological Data.

Section 3. Hazards Identification

Physical State and : Solid. (Paste)
Appearance
Emergency Overview : No specific hazard.
USE WITH CARE.
Follow good industrial hygiene practice.
Routes of Entry : Absorbed through skin. Eye contact. Inhalation. Ingestion.
Potential Acute Health Effects
Eyes : Slightly hazardous in case of eye contact (irritant).
Skin : Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin.
Inhalation : Not available.
Ingestion : Not available.
Potential Chronic Health : CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Effects MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Medical Conditions : Repeated or prolonged exposure is not known to aggravate medical condition.
Aggravated by
Overexposure:
Over-exposure : Not available.
signs/symptoms
See Section 11 for Toxicological Data.

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Section 4. First Aid Measures

Eye Contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
water for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact : In case of contact, immediately flush skin with plenty of water. Get medical attention.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion : Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. If large quantities of this material are swallowed, call a physician immediately.
Notes to Physician : No specific antidote. Medical staff must contact Poison Information Center.

Section 5. Fire Fighting Measures

Flammability of the Product : May be combustible at high temperature.
Auto-ignition Temperature : Not available.
Flash Points : Not available.
Flammable Limits : Not available.
Products of Combustion : These products are carbon oxides (CO, CO2). Some metallic oxides.
Fire Hazards in Presence of : May be combustible at high temperature.
Various Substances
Explosion Hazards in : Risks of explosion of the product in presence of mechanical impact: Not applicable.
Presence of Various Risks of explosion of the product in presence of static discharge: Not applicable.
Substances
Fire Fighting Media : SMALL FIRE: Use dry chemical powder.
and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire) : Be sure to use an approved/certified respirator or equivalent.

Special Remarks on Fire : Not available.

Hazards

Section 6. Accidental Release Measures

Small Spill and Leak : Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill and Leak : Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7. Handling and Storage

Handling : After handling, always wash hands thoroughly with soap and water.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Avoid extreme
temperature (below 0°C (32°F) or over 30°C (85°F)).

Section 8. Exposure Controls, Personal Protection

Engineering Controls : No special ventilation requirements.
Personal Protection
Eyes : Splash goggles.
Body : Lab coat.
Respiratory : Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Hands : Gloves.
Feet : Not applicable.
Protective Clothing :
(Pictograms)

Personal Protection in Case : Splash goggles. Full suit. Dust respirator. Boots. Gloves.
of a Large Spill
Exposure Limits

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Product Name Exposure Limits

Silica, Amorphous NIOSH REL (United States, 2001).
TWA: 6 mg/m3 10 hour(s). Form: All forms
Titanium dioxide ACGIH TLV (United States, 2003). :
TWA: 10 mg/m3 8 hour(s). Form: All forms
OSHA PEL (United States, 1993).
TWA: 15 mg/m3 8 hour(s). Form: Total dust

Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties

Physical State and : Solid. (Paste)
Appearance
Color : Not available.
Odor : Acetic acid.
Molecular Weight : Not applicable.
Molecular Formula : Not applicable.
pH (1% Soln/Water) : Not available.
Boiling/Condensation Point : Not available.
Melting/Freezing Point : 1830.05 to 1850.05°C (3326.1 to 3362.1°F) based on data for: Titanium dioxide. Weighted average:
1727.01°C (3140.6°F)
Specific Gravity : 1.04 (Water = 1)
Vapor Pressure : Not available.
Vapor Density : Not available.
Volatility : <5% (v/v).
Odor Threshold : Not available.
Evaporation Rate : Not available.
VOC : 5 (%)
Viscosity : Not available.
LogKow : Not available.
Solubility : Very slightly soluble in cold water, hot water.

Section 10. Stability and Reactivity

Stability and Reactivity : The product is stable.
Conditions of Instability : Not available.
Incompatibility with : Reactive with oxidizing agents.
Various Substances
Hazardous Decomposition : Not available.
Products
Hazardous Polymerization : Will not occur.

Section 11. Toxicological Information

Toxicity Data
Ingredient Name Test Result Route Species
Silanetriol, methyl-, triacetate LD50 2060 mg/kg Oral Rat

Chronic Effects on Humans : CARCINOGENIC EFFECTS: Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.
Other Toxic Effects on : Slightly hazardous in case of skin contact (irritant), of eye contact (irritant).
Humans Non-sensitizer for skin.
Special Remarks on Toxicity : Not available.
to Animals
Special Remarks on Chronic : Not available.
Effects on Humans
Special Remarks on Other : Not available.
Toxic Effects on Humans

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Section 12. Ecological Information

Ecotoxicity Data
Ingredient Name Species Period Result
Titanium dioxide Daphnia magna (EC50) 48 hour(s) >1000 mg/l

BOD and COD : Not available.

Biodegradable/OECD : Not available.
Mobility : Not available.
Products of Degradation : These products are carbon oxides (CO, CO2) and water. Some metallic oxides.
Toxicity of the Products of : The product itself and its products of degradation are not toxic.
Biodegradation
Special Remarks on the : Not available.
Products of Biodegradation

Section 13. Disposal Considerations

Waste Information : Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Consult your local or regional authorities.

Section 14. Transport Information

Regulatory Information UN number Proper shipping name Class Packing Label Additional
Group information

United States (DOT) Not regulated. - - - -

IMDG Code Not regulated. - - - -

IATA-DGR Class Not regulated. - - - -

NAERG : Not applicable.

Section 15. Regulatory Information

HCS Classification : Not controlled under the HCS (United States).
U.S. Federal Regulations : TSCA 8(b) inventory: All components listed.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Titanium dioxide
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Titanium dioxide: Immediate (Acute)
Health Hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.

SARA 313
Form R - Reporting : No products were found.
Requirements

Supplier Notification : No products were found.

State Regulations : Pennsylvania RTK: Silica, Amorphous: (generic environmental hazard); Titanium dioxide: (generic environmental
hazard)
Massachusetts RTK: Silica, Amorphous; Titanium dioxide
New Jersey: Silica, Amorphous; Titanium dioxide

California prop. 65: No products were found.

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Section 16. Other Information

Label Requirements : USE WITH CARE.
Hazardous Material Health 1 National Fire
Information System Fire Hazard 1 Protection 1 Fire Hazard

(U.S.A.) Reactivity 0 Association Health 1 0 Reactivity

Personal Protection C (U.S.A.) Specific Hazard

References : - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#,
Proper Shipping Names, PG. ANSI Z400.1, MSDS Standard, 2001. -Manufacturer's Material Safety Data
Sheet.

Responsible Name : Kemika XXI Inc. +1-450-435-7475

Date of printing : 2004-10-28.
Date of issue : 2004-10-24.
Date of Previous Issue : No Previous Validation.
Version : 1
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.