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Student's Solution Copy [CODE - 13838]

11th_JEE
11th JEE (M) - Phase 1
SILVASSA

Date: 18-Jun-2023 Duration: 3 Hours Max Marks: 300

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Maths - Section A

1. Answer: B 2. Answer: A

Sol: Sol:
2x - 8 1 - 2x
log 1 . 5 x-2
<0 log 3 x
≤0

2x - 8 1 - 2x
>0 >0
x-2 x

2x - 1
<0
x

x < 2 or x > 4
2x - 8
x-2
<1
x ∈ (0, 1 / 2)
2x - 8
x-2
-1<0 1 - 2x
x
≤1
x-6
x-2
<0 2x - 1
x
+1≥0
x ∈ (2, 6)
3x - 1
≥0
∴ x ∈ (4, 6) x

x ≤ 0 or x ≥
1
3
⇒x
[ )
1 1
,
3 2

3. Answer: D 4. Answer: B

Sol: Sol:

Given,
(
log 0 . 5 x 2 - 5x + 6 > - 1 ) log3(log9x + 1/2 + 9x) = 2x
x 2 - 5x + 6 > 0
taking antilog
(x - 3)(x - 2) > 0
log9x + 1/2 + 9x = 32x = 9x
x < 2 or x > 3
⇒ log9x = −1/2
x2 - 5x + 6 < 2
Again, taking antilog
(x - 4)(x + 1) < 0 ⇒ x = 9−1/2
x ∈ (1, 4)
⇒ x = 1/3
∴ dx ∈ (1, 2) ∪ (3, 4)

5. Answer: B 6. Answer: A

Sol: Sol:
c a4 b 5 = 1
b = a 2, c = b 2, a
= 33
log aa 4b 5 = 0
⇒ c = 27a  ⇒  b 2 = 27a 
4logaa + 5 logab = 0
⇒ a = 3,  a > 0
4
c = 81, b = 9 4 + 5 logab = 0 ⇒ logab = − 5

∴  a + b + c = 3 + 9 + 81 = 93
( )
log a a 5b 4 = 5log aa + 4log ab

=5+4
( ) −4
5

16
=5−
5

25 − 16 9
= 5
= 5

7. Answer: B 8. Answer: B

Sol: Sol:

3 2log 3x - 2x - 3 = 0  Base change theorem

= log abc √bc + log abc√ca + log abc√ab
⇒  x 2 - 2x - 3 = 0
= log abc √bc. √ca. √ab = log abcabc = 1
(x - 3)(x + 1) = 0 
Therefore, correct answer is option (B)
⇒  x = 3, x = - 1  but x ≠ - 1

∴ x = 3.

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9. Answer: C 10. Answer: B

Sol: Sol:

Let log5x = t 6x + 10 - x 2 > 3

⇒ x = 5t
3 · 5 t   log 52 + 2 t = 64 ∴ x 2 - 6x - 7 < 0
⇒ 3.2t + 2t = 64      ⇒ 4·2t = 64
(x + 1)(x - 7) < 0
⇒ 2t = 16     ⇒ t = 4
⇒ log5x = 4     ⇒ x = 625
  ⇒ 0, 1, 2, 3, 4, 5, 6 ⇒ B

11. Answer: D 12. Answer: C

Sol: Sol:

x2 − 3x + 2 > 0,

x2 − 3x − 4 ≤ 0
( )(x - 5 )(x - 17)
x2 x - 3 2 ≤0

⇒ (x − 1)(x − 2) > 0 and

(x − 4)(x + 1) ≤ 0
x  ∈  [3, 5]  ∪  {0, 17}
⇒ x ∈ (−∞, 1)∪(2, ∞)

and x ∈ [–1, 4]

Therefore, common solutions is

[–1, 1)∪(2, 4]

Therefore, the correct answer is (D)

13. Answer: C 14. Answer: B

Sol: Sol:
x 2 + 6x − 7 2 x 2 − 7x + 12
− ≤0 ⇒ >0
x2 + 1 1 2x 2 + 4x + 5
x 2 + 6x − 7 − 2x 2 − 2
≤0 ∴ denominator always positive
x2 + 1
− x 2 + 6x − 9 x 2 − 7x + 12
≤0 ∴ >0
⊕
x2 + 1
(x−3) (x−4)
{
x 2 − 6x + 9 ≥ 0 x 2 + 1 > 0 } 2x 2 + 4x + 5
>0

(x − 3) 2 ≥ 0
⇒x∈R
x ∈ (∞, 3) ∪ (4, ∞)
∴ x = (− ∞, ∞)
Therefore, the correct answer is (B)

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15. Answer: C 16. Answer: B

Sol: Sol:
|x − 1| + |x − 2| + |x − 3| ≥ 6 2x 1
>
2x 2 + 5x + 2 x+1

{
x≥3 2x 1
⇒  − >0
2x 2 + 5x + 2 x+1
2≤x<3
∴
1≤x<3 (
2x ( x + 1 ) - 2x 2 + 5x + + 2 )
x<1 ⇒  >0
( )
2x 2 + 5x + 2 ( x + 1 )

x ≥ 3 put
2x 2 + 2x - 2x 2 - 5x - 2
⇒  >0
x ≥ 4                            
( 2x + 4x + x + 2 ) ( x + 1 )
2

x ∈ [4, ∞) .......(i) − 3x − 2
⇒ >0
{ 2x ( x + 2 ) + 1 ( x + 2 ) } ( x + 1 )
2 ≤ x < 3 put
( 3x + 2 )
x - 1 + x - 2 - (x - 3) ≥ 6 ⇒ <0
( x + 2 ) ( 2x + 1 ) ( x + 1 )
x ≥ 6

No Value......(ii)

1 ≤ x < 2 put

x - 1 - (x-2) - (x-3) ≥ 6
∴   x ∈ ( − 2, − 1) ∪ ( −2
3
,
−1
2 )
-1 + 2 + 3 -x ≥ 6 Therefore, the correct answer is (B).
4−x ≥ 6

−x ≥ 2

[ x ≤ − 2] .......(3)

x<1

−(x − 1) − (x − 2)− (x−3) ≥ 6

⇒ (x−1) + (x−2) + (x− 3) ≤ −6

⇒ 3x − 6 ≤ −6

x ≤  0

x ∈ [4, ∞) ........(4)

final x ≤ 0  or x ≥ 4

17. Answer: B 18. Answer: A

Sol: Sol:
1 1
log 10(x + 2) + log 10(x − 1) = 1 (x+4) 5 (x+3) 3
1 ≥0
x + 2 > 0&x − 1 > 0 (x−2) 7

{x > - 2,  x > 1} for x, using number line.

∴  domain  = x > 1 x = –4, and x = –3

log 10(x + 2)(x − 1) = 1 and (x–2) ≠ 0

⇒  x ≠ 2
( 2
)
log 10 x + x − 2 = log 1010

x 2 + x − 2 = 10

x 2 + x − 12 = 0 ∴  x∈ [–4, –3] ∪ (2, ∞)

x= −4 Therefore, the correct answer is (A).

x=3

 x= – 4 not lies in domain

x=3

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19. Answer: A 20. Answer: C

Sol: Sol:

Given
log 7
( )
2x − 6
2x − 1
>0
( √x + 5 + √x ) = 0
log 7log 5

2x − 6 2x − 6 ⇒ log 5 (√x + 5 + √x ) = 1
2x − 1
>1⇒ 2x − 1
−1>0

2x − 6 − 2x + 1
⇒ √x + 5 + √x = 5
⇒ 2x − 1
>0
⇒ √x + 5 = 5 − √x
−5 5
>0⇒ <0 ⇒ x + 5 = 25+x − 10√x
2x − 1 2x − 1

1 ⇒ 10√x = 20
⇒x< 2
⇒x=4

Therefore, correct answer is option (C)

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Maths - Section B

21. Answer: 1 22. Answer: 3

Sol: Sol:

We write given equations,

| | | ||
Rearrange the given equation  x | 2 − x + 4  = 2x 2 − 3 x + 1
a x = bb y = cc z = a and generate a quadratic equation, then solve that
x
a = b
y
equation for the value of x. 
b = c
z

| | | ||
c = a

  x | 2 − x + 4 = 2x 2 − 3 x + 1
Taking log on both sides
xloga = log bylogb = log czlog c = loga
x log a = log  b | | ||
2 x |2 - x |2 - 3 x + | x | + 1 - 4 = 0
y log b = log  c

z log  c = log a
|x | - 2 | x | - 3 = 0
2

logb logc loga

xyz = .
loga logb logc
.          = 1 ( | x | - 3)( | x | + 1) = 0
log b log c log a
xyz =
log a
.
log b
.
log c |x| =  3                  ( ∵ | x| ≠ - 1)
         = 1

Final answer:

The value of xyz is 1

23. Answer: 2 24. Answer: 1

Sol: Sol:

Consider the given equation as 1 +  xyz  = 1 + log 2aa ⋅ log 3a2a. log 4a3a
1 1 1 = 1 + log 4aa
log bcabc
+ log caabc
+ log ababc
.
= log 4a4a + log 4aa
Using the log property, we get
= log abcbc + log abcca + log abcab = log 4a4a 2

Again, using the product log property, we get & 2yz = 2. log 3a2a ⋅ log 4a3a

= log abca 2b 2c 2 = 2 = 2log 4a2a

2 2 2
= log a b c
= log 4a4a 2
abc

= 2

25. Answer: 1 26. Answer: 4

Sol: Sol:

Given log4(log2x) + log2 (log4x) = 2

1
10 log 10x
2 ⇒    2
log2(log2x) + log2 (log4x) = 2
y= x ⇒   log2(log2x) + 2log2(log4x) = 4
x2
⇒   log2{(log2x) (log4x)2} = 4
y=

( )
x log 2x 2
1
⇒   (log2x)  2
= 24
y= x
⇒   (log2x)3 = 26 = (22)3
= y3 ⇒   log2x = 4  ⇒   x = 24  ⇒   x = 16
a=1

27. Answer: 5 28. Answer: 90

Sol: Sol:

(log10 x)2 + 2log10 x + 1 = (log10 2)2 put 2 log 9x = y we get y 2 − 6y + 8 = 0 ⇒ y = 4 or 2

⇒ (log10 x + 1)2 = (log10 2)2
⇒ log10 (10 x) = ± log10 2 ⇒ 2 log 9x = 2 2 ⇒ log 9x = 2 ⇒ x = 81
⇒ log10 (10x) = log10 2
or log10 (10x) = log10 1 or 2 log 9x = 2 1 ⇒ log 9x = 1 x = 9]
2

⇒ x = 1/5 or x = 1/20

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29. Answer: 0 30. Answer: 2

Sol: Sol:

3 log 45 = a or log45 = log3a Given that,

log5 loga log 34. log 45. log 56. log 67. log 78. log 89
log4
= log3
log4 log5 log6 log7 log8 log9
log3 loga = log3
× log4
× log5
× log6
× log7
× log8
log4
= log5
log9
3 a = log3
= log 39 = 2
log 4 = log 5

a = 5log 34     

or log 5a  =  log 43

or a = 5 log 43

⇒ 3 log 45 − 5 log 43 = 0

Therefore, the correct answer is 0.

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Physics - Section A

1. Answer: B 2. Answer: A

Sol: Sol:

SI unit of Rydberg const. = m–1 n1u1 = n2u2

SI unit of Plank's const. = kg m2s–1 0 . 05

128Kg/m3=n2
0 . 25 3
SI unit of Magnetic field energy density= kg m–1s–2
0 . 05
SI unit of coeff. of viscosity = kg m–1s–1 n2=128 ×
0 . 25 3

n2= 40 units

therefore the correct answer is (A).

3. Answer: A 4. Answer: A

Sol: Sol:
→ α β- α γ
1 →→ 1
= I V 1 + V 2I D → D1 → D2 → D3 → D4
2 2

During a decay atomic number decrease by 2 and mass

number decreases by 4.
182 α 178
D→ D1
74 72

During β– decay, neutron converts into  proton. Atomic

number increase by one and mass number remains same.

178 β -1 178 178 α 174

D1 → D2 D2 → D3
72 73 73 71
−1
178 β 178
D1 −
→ D2
72 73

178 α 174
D2 → D3
73 71

During γ decay, photon is emitted, no change in mass

number or atomic number.

5. Answer: C 6. Answer: C

Sol: Sol:
μ
As μr =  μ ρ = F xV yT z
m

[μr] = [M0L0T0] [ML ] = [MLT ] [LT ] [T]

-3 -2 x -1 y z

[Power factor] =  (cos ϕ)  which is dimensionless

1 = x                             x = 1 - 3 = x + y                    y = - 40 = - 2x - y + z          z = 2x + 4 =
B0
-2 1 = x                             x = 1
μ­0 =  H  (unit = NA ) : Not dimensionless
− 3 = x + y                    y = −4

[μ0] = [MLT-2A-2]
0 = −2x − y + z          z = 2x + 4 = 2 − 4 = −2

−4 −2
ρ = FV T
Energy  stored
Quality factor (Q) =  energy dissipated per cycle
Therefore, the correct answer is (A).
So Q is unitless and dimensionless.

7. Answer: C 8. Answer: D,

Sol: Sol:

Let Y = (V,  F,  a)

∴ Y = KV xF ya z,   K →  Unitless  ()L

C
 does not have dimension of time.

L
[] [ [ [
∴ Y = V] x F] y a] z RC,
R 
are time constant while  √LC is reciprocal of angular
frequency or having dimension of time.

[
∴ ML - 1 T - 2 = ] [ LT - 1
x
][
MLT - 2
y
][ LT - 2 ]
z

∴ M [ ][L ] = [T ] = [M] [L
-1 -2 y x+y+z
][T - x - 2y - 2z
]
∴ y = 1;   x + y + z = - 1;    - x - 2y - 2z = 2

∴ x + z = - 2   ∴ x + 2y + 2z = 2

∴ x + 2z = 0   ∴ z = 2, x = - 4

[] [
∴ Y = V - 4Fa 2 ]

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9. Answer: D 10. Answer: D

Sol: Sol:
1 Joule-sec is the unit of angular momentum where as other
Dimension of μ0 ∈0 units are of energy.
1 1
c= ⇒ μ0 ∈0
= c2
μ0 ∈0
√

⇒
[ ]1
μ0 ∈0 [ ]
= c2

=
[ ]
L2
  T2

Therefore, the correct answer is (D).

11. Answer: D 12. Answer: B

Sol: Sol:

The number of wavelengths of Kr 86 in 1m is 1650763.73.

[η ] = ML - 1T - 1 so its unit will be kg / m - sec.

SI unit of coefficient of viscosity of the liquid is kg m-1 s-1

which is similar to the unit of viscosity.

13. Answer: A 14. Answer: D

Sol: Sol:

Density ∝ [FaLbTc] GM 2
F=   ⇒  G = [M–1L3T–2]
R2
[ML–3] = [MaLaT–2aLbTc]
E = hν     ⇒  h = [ML2T–1]
[M1L–3] = [MaLa+bT–2a+c]
C = [LT–1]
a = 1 ;          a + b = –3 ;   –2a + c = 0
T  ∝ Gx hy Cz
                    1 + b = –3       c = 2a
[T] = [M–1L3T–2]x [ML2T–1]y [LT–1]z
                    b = – 4             c = 2
[M0L0T1] = [M–x+y L3x+2y+z  T–2x–y–z]
So, density = [F1L-4T2]
On comparing the powers of M, L, T

– x + y = 0           ⇒  x = y

3x + 2y + z = 0  ⇒  5x + z = 0          ....(i)

– 2x – y – z = 1  ⇒  3x + z = –1        ....(ii)
1 5
On solving (i) & (ii) x = y =  2 , z = – 2

Gh
t  ∝  
√ C5

Therefore, the correct answer is (D).

15. Answer: A 16. Answer: B

Sol: Sol:

Let the quantity be Q, then Pyrometer is used for measurement of temperature.

Q = f(v,  F,  T)

Assuming that the function is the product of power

functions of v,  F and T,

Q = Kv xF yT z…(i)

where K is a dimensionless constant of proportionality. The

above equation dimensionally becomes

[]
Q = LT - 1[ ] [MLT ] [T]
x -2 y z

[] [
i.e.,  Q = M yL ( x + y ) T ( - x - 2y + z ) , Now ]
Q =  mass i.e., [Q] = [M]

So Equation (ii) becomes

[M ] = [M L y ( x + y ) T ( - x - 2y + z )
]
its dimensional correctness requires

which on solving yields

x = - 1,  y = 1 and z = 1

Substituting it in Equation (i), we get

Q = Kv - 1FT

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17. Answer: C 18. Answer: A

Sol:
Q
Q = mL ⇒ L = m
  (Heat is a form of energy)

ML 2T - 2
= M [
= M 0L 2T - 2 ]
19. Answer: A 20. Answer: C

Sol: Sol:

Dimension of work will [W] = [F] [d] Dimension of pressure × time 

force
= Area
× time

[ MLT ]
[]
−2

= × T
[l ] 2

[
= ML - 1T - 1 ]
dv
Dim. of coeff. of viscosity  F = A dz η

f dz
η= A
× dv

MLT - 2 [L]
= ×
[L ] 2
[ LT ]-1

[
= ML - 1T - 1 ]
A is true  because
Force
R is false  coeff. of viscosity = Area × Vel   . Gradient

Force
Reason R : Coefficient of viscosity  = Velocity   Gradient

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Physics - Section B

21. Answer: 2 22. Answer: 300

Sol: Sol:

Consider  v = a sin (bt) where v is in meter per second and t

is in second.

Dimensional homogenity: The combination of dimensions

assigned to each variable are consistent with both sides of
the equation.

By the dimensional homogenity: P0 +

250
0.5 ( )
+ ρg 40 × 10 - 2 = P 0 + 2 ρν 2
1

a has same dimension of v = LT - 1  sin  bt [ ] () 500 +

1000 × 10 × 40
=
1
× 1000 × ν 2
100 2
Also sin (bt) has no dimension as it is trigonometric
function. V = 3 m / s 

Then dimensional formula of a is: V = 300 cm / s

[a] = M οL 1T - 1

Dimensional formula of b is:

[b] = M οL οT - 1

Then the sum of dimensions with respect to the time of a

and b is: ( − 1) + ( − 1) = −  2

Given the sum of dimensions with respect to the time of a

and b is −x, then the value of x is 2.

23. Answer: 3 24. Answer: 43

Sol: Sol:

As force is always directed towards origin so net torque B 20c

about origin = 0 I= 2μ 0
I = 0 .22 w / m 2,

- So we can conserve angular momentum about origin 2μ 0I

→ →
(
→ →
)
L i   abtO   =  L f   abtO   m r i × v i = m r f × v f
→ →
( → →
)
B0 =
√ c
c = 3 × 10 8m / sec

L =  L
2 × 4π × 10 − 7 × 0 .22

√
i  abtO   f   abtO  

→ → → → B0 = = 4 .3 × 10 − 8 ϵ 0 = 8 .85 × 10 − 12C 2N − 2
m( r i × v i ) = m( r f × v f ) 3 × 10 8

for any arbitary position, angular momentum can be

written as (about origin) B 0 = 43 × 10 − 9T

| |
î ĵ k̂
→
r ×v= → x y z
vx vy vz

→
only k̂ component, of L-

=  xv y –  yv x

as L remains constant so it must satisfies initial condition

also.
1
so, put x =  , v x = - √2,  y = √2,  v y = √2
√2
1
xv y –  yv x × √2 - √2 x - √2 =  1  +  2  =  3
√2
xvy  –  yvx

1
× √2 − √2 x − √2
√2

=  1  +  2  =  3

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25. Answer: 21 26. Answer: 7

Sol: Sol:

v2 = ω2 A2 − x2 ( ) A = 10cmGiven

Area of cross section = 120 cm 2

Equivalent thermal conductivity
( ( ))
v2 = ω2 A2 −
A 2
2
x = 5cm =
A
2

( )
1+
5
α
K ( ( ( )) ()
3v) 2 = ω 2 A ′2 −
A 2
2
   . . . ii

L Equation (ii) divided by (i)

R eq = R 1 + R 2                R  =   kA
4A ′2 − A 2
9= A= √xcm
1 ( L1 + L2 ) L1 L2 4A 2 − A 2
= +
K eq A K 1A K 2A

L1 + L2 L1 L2 4 + 2 .5 4 2 .5
( )
9 3A 2 = 4A ′2 − A 2
= + ⇒ = +
K eq K1 K2 KA K 2K
28A 2 = 4A ′2
6 .5 10 .5
= A′ = √7A
K eq 2K

65 × 2 130 26 A ′ = 10√7
K eq = 105
= 105
= 21
A′ = √700cm
K eq =
26
21
= 1+ ( ) 5
21
K
On comparison ofA ′whith√x

1+5 5 x = 700cm
=1+
α 21

α = 21

27. Answer: 5 28. Answer: 2

Sol: Sol:

[We will ignore all the units in this question as we are Given,
talking about velocity and acceleration functions. We could
Force × displacement
use the units carefully but that would unnecessarily
time
complicate the solution. Also if we take units carefully A, B
m m m
and 2 will have units
s 3,
s 2  and  s
] Dimension of force =  MLT - 2 [ ]
Given that velocity function, v(t) = At 2 + Bt + 2 Dimension of displacement = [L]
dv(t)
So, acceleration function, a(t) = = 2At + B Dimension of time = [T]
dt
Dimension of
Now at t = 1s
Force × displacement
2
 v(1) = A(1) + B 1 + 2 = 5  () time

[ MLT ] [ L ]
-2
⇒A+B=3
= [T] [
= ML 2T - 3 ]
Also, a(1) = 2A + B  =  1 [MLT
−2
][L]

=
So,
[T]

2 −3
= [ML T ]
(2A + B) - (A + B) = 1 - 3 

⇒A= -2 here, the dimension of length is 2

Now, A + B = 3  ⇒ ( - 2) + B = 3  ⇒ B = 5

29. Answer: 1 30. Answer: 2

Sol: Sol:

As the exponential term has no dimension, balancing the

Dimensional formula for force,  F = MLT – 2  and [] [ ] dimensions of both sides of the given equation we get,
[A] = [S] = [Displacement] = [L]
Dimensional formula for power is  P = ML 2T – 1 [] [ ] Now,

⇒
[][ ][]
P
F 2
=
ML 2T – 1
2 2 –4
M L T
=
T3
M
[]at x
A
=1⇒
[ LT ] [ T ]
-2

[L]
x

= 1 ⇒ [T] - 2 + x = 1 = [T] 0 ⇒ - 2 + x = 0 ∴ x = 2

[ ] F 2T 3
Answer: The missing number in the expression is 2.
⇒ [M] = P

Given the unit of force = 10 3N, time = 10 - 3s and power = 10 3W

( 10 ) ( 10 )
3 2 -3 3

Then the units of mass,  ⇒ M = = 1kg 

10 3

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Chemistry - Section A

1. Answer: B 2. Answer: A

Sol: Sol:

One mole A 2 contain 32 mole electron and 36 mole mass of 12C

6 = 12 gm
neutrons.
mass no. of atom
mole = =
So, Number of electron in one molecule =  32 mol. mass NA

32 12C 12
Number of electron in one atom = = 16 No of 6 atom = 12
× NA = NA
2

Number of neutron in one molecule  = 36 1 carbon 12C contain 6 each electrons , protons and
6

36 neutrons.
Number of neutron in one atom  = = 18
2 So, Total No. of e–, P+ and n° = 18 NA = 1.084 × 1025
Atomic number = number of proton = number of electron
(for neutral atom) = 16
Mass number = number of proton + number of neutron
= 16 + 18 = 34

3. Answer: A 4. Answer: D

Sol: Sol:

Molecules = 2.01×1023 C:O:S=3:2:4

2 .01 × 10 23 1 Hydrogen is = 7.7%
Moles = =
6 .02 × 10 23 3
∴ 100 − 7.7 = 92.3 % contains C,O & S
Mass of CO = moles × Molar Mass

=
1
3
× 28 %C=
( ) 3
3+2+4
× 92.3 = 30.76

= 9.3 g 2
%O= 9
× 92.3 = 20.51
Therefore, the correct answer is (A)
4
%S= 9
× 92.3 = 41.02

Simplest
%/Atomic Simple
Elements  % whole
mass ratio
no.
H 7.7 7.7 6 6
30.76/12
C 30.76 = 2.56 2 2

20.15/16
O 20.51 1 1
= 1.28
41.02/32
S 41.02 1 1
= 1.28
∴ empirical formula = C2H6OS

minimum molar mass = 24 + 6 + 16 + 32 = 78

Therefore, the correct answer is (D).

5. Answer: B 6. Answer: D

Sol: Sol:

C x. H y + x + ( ) y
4
O 2 → xCO 2 + 2 H 2O
y

Moles of H2O =
0.72
18
= 0.04
{ Mole =
mass
mol .  wt . }
3.08
Mole of CO2 = = 0.07
44 Emperical formula = C 5NH 7
y
2
= 0.04     ⇒   y = 0.08 Emperical weight = 81
162
x = 0.07 Multiplying factor = 81
=2
x:y
0.07 : 0.08 Molecular formula = C 10N 2H 14
7:8
So, empirical formula = C7H8

Therefore, the correct option is (2)

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7. Answer: D 8. Answer: C

Sol: Sol:

Given, Rules for significant figures

An organic compound contains sulphur =  0. 032 % (By ⇒ Zeros preceding to first nonzero digit are not
mass) significant. Such zero indicates the position of decimal
point.
One molecule contains = 2 sulphur atoms
⇒ For example 0.03 has one significant figure and
Atomic mass of two sulphur atoms= =  2 X 32  = 64 g 0.00520 has three significant figures.
Let the molecular mass of compound- A (i) 0.01010 ⟶ 4 significant figures
We know that, (ii) 0.1010 ⟶ 4 significant figures
Weight of sulphur = percentage of sulphur × (iii) 0.0101 ⟶ 3 significant figures
Molecular mass

64 = 0.032 / 100 × A

A = 64 × /0.032

= 200000 u

9. Answer: D 10. Answer: B

Sol: Sol:

Number of atoms of element present = 3.011×1022 Mass of 1 electron = 9.1 × 10–31

atoms 
Weight of given atoms = 1.15 gm In 1 mole there are NA electrons

Number   of   atoms   present so, mass of 1 mole electrons = 9.1 × 10–31 × NA

Moles of element =  23
6 . 022 × 10
= 9.1 × 6.023 × 10–8
22
3 . 011 × 10 1
=  =  mol = 54.8093 × 10–8
6 . 022 × 10 23 20
= 5.480 × 10–7 kg = 5.48 × 10–7× 1000 g
Given   mass   ( g )
We know, molar mass =  Moles   of   element
= 5.48 × 10–4 g = 54.8 × 10–5g
=1. 15 × 20 = 23 g / mol
23
Atomic mass = 
6 . 022 × 10 23

=23 × 1. 66 × 10 - 24 g  = 23 amu

11. Answer: C 12. Answer: B

Sol: Sol:

Fact According to formula, Molar mass of

chloride=2×VapourDensity

=2 × 59.5

=119
Molar   mass
Equivalent Mass = ​ n -   factor

x
⇒24 = n

​35.5n+x = 2×59.5

35.5n+24n=119

⇒x=2

Molar mass of element =48g/mol

Therefore, the correct answer is (B).

13. Answer: C 14. Answer: A

Sol: Sol:

1) Given weight = 28 g and, Molecular mass of CO = (12 For the following reaction,
given   weight
+ 16) = 28 and, no. of molecules =  Molecular   weight
× N A=  2C57H110O6 + 163O2 ➝ 114CO2 + 110H2O
28
28
× N A=N A. Mass of C57H110O6 = 445g

2) Given weight = 46 g and,  Molecular mass of C 2H 5OH = Molar mass of C57H110O6 = 890
(24 + 5 + 16 + 1)= 46 and, no. of molecules =  mass 445
given   weight 46 Moles of C57H110O6 = molar  mass
= 890
= 0.5 mole
Molecular   weight
× N A=   46 × N A = N A.
So, 2 moles of C57H110O6 produce 110 moles of H2O
3) Given weight = 36 g and, Molecular mass of H 2O = 18 g
110 55
given   weight 0.5 mole of C57H110O6 produce × 0.5 =
and no. of molecules =  Molecular   weight
× N A  =    2 2

36
18
× N A = 2N A max.
( ) Mass of water = moles of H2O × molar mass of water

=
55
× 18 = 495g
2
4) Given weight = 54 g and, Molecular mass of N 2O 5 = (28
+ 16 × 5) = 108  g and no. of molecules = 
given   weight 54 NA
Molecular   weight
× N A =   108 × N A = 2
.

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15. Answer: C 16. Answer: B

Sol: Sol:

Mass of one electron or, one electron weighs

()
Mole  n =
given   mass   ( w )
Molar   mass ( m ) = 9.1 × 10 - 28g and, 1 mole has

Moles of C =
88g
=2 6.022 × 10 23 electrons/particles.
44g
So, Mass of 1 mole of electron
9
Moles of H = 18 = 9. 1 × 10 - 28 × 6. 022 × 10 23
In H2O and CO2 we see. = 54.8 × 10 - 5g
Ratio of carbon to hydrogen moles is 1 : 2
So, mass of half- mole of electron
So, for 1 mole of C we have 2 moles of hydrogen 54 . 8 × 10 - 5
=  = 27. 4 × 10 - 5g
9 2
For 2 moles of C we have 18
× 2 moles of hydrogen
0.274 mg
C        :        H
9
2        :        18
×2

2        :        1

Therefore

2 moles of carbon weight         ➝ 12×2 = 24 g.

1 mole of hydrogen weight         ➝ 1×1 = 1 g.

17. Answer: B 18. Answer: A

Sol: Sol:

Given weight of sulphur = 288 g and, molecular weight of Here, given weight of element = 0.9 g.
sulphur = 32 gm/ mol.
Now, as we know that, 
Now, number of gram atoms = no. of moles.
N ( no .   of   atoms ) given   weight
given   weight   288g
Mol =  = atomic   mass
So, no. of moles =  molecular   weight
= 32g / mol
= 9 moles  or, 9 (
N A avagardro ' s   no . )
gram atoms. 1 . 5 × 10 22 0.9 g
⇒ =
Therefore, option - (2) 9 is the correct ans. 6 . 02 × 10 23 atomic   mass

So, atomic mass = 36 g.

19. Answer: B 20. Answer: A

Sol: Sol:

As, we know the molar mass of carbon = 12. Mass of anyhydrous  CaCl2  = 111 g

Now, the ratio of mass of titanium atom to the mass of Molar mass of CaCl2 = 40 + 71 = 111 g mol–1
carbon atom is 4 : 1. mass 111
So, mole = molar mass
= 111 = 1 mole
mass   of   titanium 4 mass   of   titanium 4
So,  = ⇒ =
mass   of   carbon 1 12 1 CaCl2   →   Ca2+  +  2Cl–
Hence, mass of titanium = 48 g. 1 mole        1 mole      2 mole
no. of molecules
mole = NA

So, no. of CaCl2 molecules = NA

So, Ca2+ ions = NA

and Cl– ions = 2NA 

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Chemistry - Section B

21. Answer: 0.33 22. Answer: 54.18

Sol: Sol:
1 Molar mass of C7H5N3O6 is 84 + 5 + 42 + 96 = 227
 mol of KClO 3
3
681
3 nC = = 3 moles 
7H 5N 3O 6 227
KClO 3 → KCl + O 2
2
681
3 nN = 227
× 3 = 9 moles of N
 mole or 33. 6 litre O 2 from 1 mole KClO 3
2
No. of N atoms = 9 × 6.02 × 1023
1
11. 2 litre of O 2 formed by   mole KClO 3
3 = 5418 × 1023

= 54.18

23. Answer: 2 24. Answer: 4

Sol: Sol:

Combustion of methane : Mass of iron present in one molecule of heamoglobin = 

0 . 33
CH4+ 2O2 → CO3+ 2H2O 100
× 67200 =  221. 76g

According to POAC - Atomic weight of iron = 56g

n CH × 4  =  n H ×2 Therefore, number of iron atoms present in one molecule
4 2O
221 . 76
81 1 81
of heamoglobin =  56
= 3. 96 ≈ 4 (ans).
n CH = 18
×2× 4
= 36
4

n CH = 2. 25
4

25. Answer: 1 26. Answer: 7

Sol: Sol:

Molar mass of MgSO4. xH2O = 120.4 + 18 X (

  mass   of   Al 2 SO 4 )
3
× 10 6 = 34. 2
percentage of water of crystallization = 13%   mass   of   water  

1 mole of MgSO4. xH2O contains = 18 X water 1 litre solution contains 1000 g of water ⇒ In 1 litre solution,

Hence, mass of Al 2 SO 4 ( )3
13 X (120.4 + 18 X) /100 = 18 X 34 . 2 × 1000
= = 34. 2mg
10 6
120.4 X = 120.4
34 . 2 × 10 - 3
X=1 molarity of Al 2 SO 4 ( )3 = 342
M
Value of X = 1
= 10 - 4M

( )3 (aq ) → 2Al3 + (aq ) + 3SO24 - (aq )

Al 2 SO 4

10 - 4M 2 × 10 - 4M  3 × 10 - 4M

[SO ] = 3 × 10
2-
4
- 4M

27. Answer: 56 28. Answer: 25

Sol: Sol:
0 . 22
Moles of CO2= 44

0 . 22
% of glycine =
[ ]75 × 1
GMM
× 100 = 0.3

Moles of C= 1 × moles of CO2= 44

∴ Wt of carbon= 
0 . 22
44
× 12
GMM =
[ 75 × 100
0.3 ] = 25 × 10 3

0 . 220
44
× 12
% of C  = x
× 100

(x = mass of organic compound)

6
24 = x

x = 0.25 gm
0 . 126
18
×2×1
% of H = × 100
0 . 25

=  5. 6  =  56  ×  10 - 1

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29. Answer: 18 30. Answer: 2

Sol: Sol:
0.2 7.5
Moles of CO 2 = 44
% Hydrogen  =
116
× 100 = 6.46

0.2 60 1
Moles of carbon = 44
% of  Oxygen  =
116
×
16
× 100 = 3. 23

0.2 48.5 1
Weight of carbon = 44
× 12 % of  Carbon  =
116
×
12
× 100 = 3. 48

0.2 100 Ratio C : H : O = 3.48 : 6.46 : 3.23

% of carbon ⇒ 44
× 12 ×
0.3
⇒ 18. 11 %
Simplest form = C : H : O = 1 : 2 : 1
Correct answer = 18
Empirical formula = CH2O = CH3COOH

& HCHO has empirical formula CH2O

Hence, Ans is 2.

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