Appendix E

SELECTED THERMODYNAMIC DATA AT 298.15 K

D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

Aluminum Be(OH)2(s) 2907.1 50.2 2817.6

Al(s) 0 28.3 0 BeSO4(s) 21205.20 77.91 21093.80
AlCl3(s) 2704.2 110.7 2628.9
Al2O3(s) 21676 50.92 21582 Bismuth
AlPO4(s) 21733.8 90.76 21617.9 Bi(s) 0 56.74 0
Al2(SO4)3(s) 23440.84 239.3 23099.94 BiCl3(s) 2379.1 177.0 2315.0
Bi2O3(s) 2573.88 151.5 2493.7
Antimony Bi2S3(s) 2143.1 200.4 2140.6
Sb(s) 0 45.69 0
Sb4O6(s) 21417.1 246.0 21253.0 Boron
Sb2O5(s) 2971.9 125.1 2829.2 B(s) 0 5.86 0
SbCl5(,) 2440.2 301 2350.1 BCl3(,) 2427.2 206.3 2387.4
SbCl3(s) 2382.17 184.1 2259.4 B2H6(g) 35.6 232.11 86.7
BF3(g) 21137.00 254.12 21120.33
Argon H3BO3(s) 21094.33 88.83 2968.92
Ar(g) 0 154.843 0 NaBH4(s) 2183.34 104.68 2119.54

Arsenic Bromine
As(s) 0 35.1 0 Br(g) 111.8 174.9 82.4
H3As(g) 66.44 222.78 68.93 Br2(,) 0 152.23 0
As2O5(s) 2924.87 105.4 2782.3 Br2(g) 30.91 245.4 3.14
AsCl3(,) 2305.0 216.3 2259.4 BrF3(g) 2255.6 292.4 2229.5
HBr(g) 236.4 198.59 253.43
Barium
Ba(s) 0 62.8 0 Cadmium
BaCl2(s) 2860.1 126 2810.9 Cd(s) 0 51.76 0
BaCO3(s) 21216.3 112.1 21137.6 CdCl2(s) 2391.50 115.27 2343.93
BaF2(s) 21207.1 96.36 21156.8 CdO(s) 2258.2 54.8 2228.4
Ba(NO3)2(s) 2992.07 213.8 2796.59 CdS(s) 2161.9 64.9 2156.5
BaO(s) 2553.5 70.42 2525.1
BaSO4(s) 21465 132 21353 Calcium
Ca(s) 0 41.6 0
Beryllium Ca(g) 192.6 154.8 158.9
Be(s) 0 9.54 0 Ca21(aq) 2542.8 253.1 2553.5
BeCl2(s) 2490.4 82.68 2445.6 CaBr2(s) 682.8 130 2663.6
BeF2(s) 21026.8 53.35 2979.4 CaC2(s) 262.8 70.3 267.8
BeO(s) 2609.6 14.14 2580.3 CaCO3(s) 21207 92.9 21129

512
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

CaCl2(s) 2795.0 114 2750.2 CH3NH2(,) 247.3 150.21 35.6

CaF2(s) 21215 68.87 21162 CO(NH2)2(s) 2334 105 2198
CaH2(s) 2189 42 2150 CH3CN(,) 54 150 99
CaO(s) 2635.5 40 2604.2 C3H3N(,) 172.9 188 208.6
2110.5 197.6 2137.2
CaS(s) 2482.4 56.5 2477.4 CO(g)
Ca(NO3)2(s) 2938.39 193.3 2743.07 CO2(g) 2393.5 213.6 2394.4
Ca(OH)2(s) 2986.6 76.1 2896.8 CO2(aq) 2413.80 117.6 2385.98
Ca(OH)2(aq) 21002.8 76.15 2867.6 COCl2(g) 2223.0 289.2 2210.5
Ca3(PO4)2(s) 24120.8 236.0 23884.7 CS2(g) 117.4 237.7 67.15
CaSO4(s) 21433 107 21320 (CH3)2SO(,) 2203 188 299
C6H12O6(s) 21274.5 212.1 2910.56
Carbon (glucose)
C(s,graphite) 0 5.740 0 C12H22O11(s) 22221.7 360.24 21544.3
C(s,diamond) 1.897 2.38 2.900 (sucrose)
C(g) 716.7 158.0 671.3
Cesium
CCl4(,) 2135.4 216.4 265.27
Cs(s) 0 85.23 0
CCl4(g) 2103 309.7 260.63
Cs1(aq) 2248 133 2282
CHCl3(,) 2134.5 202 273.72
CsF(aq) 2568.6 123 2558.5
CHCl3(g) 2103.1 295.6 270.37
CH2Cl2(g) 2121.46 177.8 267.26
Chlorine
CH3Cl(g) 280.83 234.58 257.37
Cl2(g) 0 223.0 0
CF4(g) 2925 261.61 2879
Cl(g) 121.7 165.1 105.7
CF2Cl2(g) 2477 301 2440
Cl2(g) 2226 — —
CH3CF3(,) 2737 280 2668 2
Cl (aq) 2167.29 56.48 2131.26
CH4 (g) 274.81 186.2 250.75
ClO(g) 101.22
C2H2(g) 226.7 200.8 209.2
ClO2(g) 104.60 249.4 123.4
C2H4(g) 52.26 219.5 68.12
Cl2O(g) 80 266 98
C2H6(g) 284.86 229.5 232.9 ClF(g) 254.48 217.89 255.94
C3H6(g) 20.41 266.9 62.75
ClF3(g) 2163.2 281.61 2123.0
C3H8(g) 2103.8 269.9 223.49
HCl(g) 292.31 186.8 295.30
C6H6(,) 49.03 172.8 124.5
HCl(aq) 2167.4 55.10 2131.2
C8H18(,) 2250.3 361.2 16.32
(n-octane)
Chromium
CH3OH(,) 2238.66 126.8 2166.27
Cr(s) 0 23.8 0
C2H5OH(,) 2277.7 161 2174.9
Cr2O3(s) 21139.7 81.2 21058.1
C2H5OH(g) 2235.1 282.6 2168.6
Cr2Cl3(s) 2556.5 123.0 2486.1
HCOOH(aq) 2425.6 92.0 2351
(NH4) 2Cr2O7(s) 21807 — —
HCOOH(,) 2424.72 128.95 2361.35
HCHO(g) 2108.57 218.77 2102.53 Cobalt
CH3CHO(g) 2166.19 250.3 2128.86 Co(s) 0 30.04 0
CH3COOH(,) 2484.5 159.8 2389.9 CoO(s) 2237.94 52.97 2214.20
H2C2O4(s) 2828.93 115.6 2697.2 Co3O4(s) 2891 102.5 2774
H2C2O4(aq) 2825.1 45.61 2673.9 CoCl2(s) 2312.5 109.16 2269.8
HCN(g) 135.1 201.78 124.7 CoSO4(s) 2888.3 118.0 2782.3

Appendix E 513
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

Copper Iron
Cu(s) 0 33.15 0 Fe(s) 0 27.3 0
CuBr(s) 2104.6 96.11 2100.8 FeCl2(s) 2340.67 117.9 2302.3
CuCl(s) 2137.2 86.2 2119.86 FeCl3(s) 2399.49 142.3 2334.00
CuCl2(s) 2220.1 108.07 2175.7 FeCO3(s) 2741 93 2667
CuI(s) 267.8 96.7 269.5 Fe(CO)5(,) 2774.0 338 2705.4
CuO(s) 2157 42.63 2130 2733.8 445.2 2697.3
Fe(CO)5(g)
Cu2O(s) 2168.6 93.14 2146.0
FeO(s) 2272 — —
CuS(s) 253.1 66.5 253.6
Fe2O3 2824.2 87.40 2742.2
Cu2S(s) 279.5 120.9 286.2
(s, hematite)
CuSO4(s) 2771.36 109 2661.8
Fe3O4 21118 146 21015
(s, magnetite)
Fluorine
Fe(OH)2(s) 2569.0 88 2486.5
F2(g) 2322 — —
Fe(OH)3(s) 2823.0 106.7 2696.5
F2(aq) 2332.6 — 2278.8
FeS2(s) 2177.5 122.2 2166.7
F(g) 78.99 158.6 61.92
FeSO4(s) 2928.4 107.5 2820.8
F2(g) 0 202.7 0
HF(g) 2271 173.7 2273 Lead
HF(aq) 2320.08 88.7 2296.8 Pb(s) 0 64.81 0
PbCl2(s) 2359.4 136 2314.1
Germanium
PbO(s, yellow) 2217.3 68.70 2187.9
Ge(s) 0 3 0
PbO2(s) 2277.4 68.6 2217.33
GeH4(g) 91 217 113
Pb(OH)2(s) 2515.9 88 2420.9
GeCl4(g) 2496 348 2457
PbS(s) 2100.4 91.2 298.7
GeO2(s) 2551 55 2497
PbSO4(s) 2919.94 148.57 2813.14
Gold
Lithium
Au(s) 0 48 0
Li(s) 0 28.0 0
Helium LiAlH4(s) 2116.3 78.74 244.7
He(g) 0 126.150 0 LiCl(s) 2408.61 59.33 2384.37
LiF(s) 2615.97 35.65 2587.71
Hydrogen LiH(s) 290.54 20.008 268.35
H(g) 218.0 114.6 203.3 LiNO3(s) 2483.13 90.0 2381.1
H2(g) 0 130.6 0 LiOH(s) 2487.23 50 2443.9
H2O(,) 2285.8 69.91 2237.2 LiOH(aq) 2508.4 4 2451.1
H2O(g) 2241.8 188.7 2228.6
H2O2(,) 2187.8 109.6 2120.4 Magnesium
Mg(s) 0 32.5 0
Iodine Mg21(aq) 2454.668 2138.1 2455.57
I(g) 106.6 180.66 70.16 MgBr2(s) 2524.3 117.2 2503.8
I2(s) 0 116.1 0 MgCl2(s) 2641.8 89.5 2592.3
I2(g) 62.44 260.6 19.36 MgCO3(s) 21095.8 65.7 21012.1
ICl(g) 17.78 247.4 25.52 MgF2(s) 21123.4 57.24 21070.2
HI(g) 26.5 206.5 1.72 MgI2(s) 2364.0 129.7 2358.2

514 Appendix E
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

Mg(NO3)2(s) 2790.65 164.0 2589.4 NH4Cl(aq) 2300.2 — —

MgO(s) 2601.8 27 2569.6 NH4HCO3(s) 2847 12.1 2666
Mg(OH)2(s) 2924.7 63.14 2833.7 NH4I(s) 2201.4 117 2113
Mg3(PO4)2(s) 23780.7 189.20 23538.7 NH4NO3(s) 2365.6 151.1 2184.0
MgS(s) 2347 — — (NH4)2SO4(s) 21180.85 220.1 2901.67
MgSO4(s) 21284.9 91.6 21170.6 NF3(g) 2125 260.6 283.3
NO(g) 90.25 210.7 86.57
Manganese NO2(g) 33.2 240.0 51.30
Mn(s) 0 32.01 0
MnCl2(s) 2481.29 118.24 2440.50 N2O(g) 82.05 219.7 104.2
MnO(s) 2385.22 59.71 2362.90 N2O3(g) 83.72 321.28 139.46
MnO2(s) 2520.03 53.05 2465.14 N2O4(g) 9.16 304.2 97.82
Mn2O3(s) 2959.0 110.5 2881.1 N2O5(g) 11 356 115
Mn3O4(s) 21387.8 155.6 21283.2 N2O5(s) 243.1 178 114
MnSO4(s) 21065.25 112.1 2957.36 NOCl(g) 52.59 264 66.36
HNO3(,) 2174.1 155.6 280.79
Mercury HNO3(g) 2135.1 266.2 274.77
Hg(,) 0 76.02 0 HNO3 (aq) 2206.6 146 2110.5
Hg(g) 61.32 174.96 31.82
HgCl2(s) 2224.3 146 2178.6 Oxygen
Hg2Cl2(s) 2224 146 2179 O2(g) 0 205.0 0
HgO(s, red) 290.83 70.29 258.56 O(g) 249.2 161.0 231.8
HgS(s, red) 28.2 82.4 250.6 O3(g) 143 238.8 163
OF2(g) 23 246.6 41
Neon
Ne(g) 0 146.328 0 Phosphorus
P(g) 314.6 163.1 278.3
Nickel P4(s, white) 0 177 0
Ni(s) 0 30.1 0 P4(s, red) 273.6 91.2 248.5
NiCl2(s) 282.0 52.97 279.5 P4(g) 58.91 279.98 24.44
Ni(CO)4(g) 2602.9 410.4 2587.3 PCl3(g) 2306.4 311.7 2286.3
NiO(s) 2244 38.6 2216 PCl5(g) 2398.9 353 2324.6
NiS(g) 282.0 52.97 279.5 PF3(g) 2918.8 273.24 2897.5
NiSO4(s) 2872.91 92 2759.7 PH3(g) 5.4 210.1 13
P4O10(s) 22984 228.9 22698
Nitrogen H3PO4(s) 21281 110.5 21119
N2(g) 0 191.5 0
N(g) 472.704 153.19 455.579 Potassium
NH3(g) 246.11 192.3 216.5 K(s) 0 63.6 0
NH3(aq) 280.29 111.3 226.50 KBr(s) 2393.798 95.90 2380.66
NH41(aq) 2132.51 113.4 279.31 KCl(s) 2436.5 82.6 2408.8
N2H4(,) 50.63 121.2 149.2 KClO3(s) 2391.2 143.1 2289.9
(NH4)3AsO4(aq) 21268 — — KClO4(s) 2432.747 82.59 2409.14
NH4Br(s) 2270.83 113 2175.2 K2CO3(s) 21151.02 155.52 21063.5
NH4Cl(s) 2314.4 94.6 2201.5 K2Cr2O4(s) 21403.7 200.12 21295.7

Appendix E 515
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

K2Cr2O7(s) 22061.5 291.2 21881.8 Sodium

KF(s) 2567.27 66.57 2537.75 Na(s) 0 51.0 0
KI(s) 2327.9 106.4 2323.0 Na(g) 108.7 153.6 78.11
KMnO4(s) 2837.2 171.71 2737.6 Na1(g) 601 — —
1
KNO3(s) 2494.63 133.05 2394.86 Na (aq) 2240.2 59.0 2261.9
KO2(s) 284.93 116.7 2239.4 NaBr(s) 2359.9 86.82 2348.98
K2O2(s) 2494.1 102.1 2425.1 NaCl(s) 2411.0 72.38 2384
KOH(s) 2424.7 78.91 2378.9 NaCl(aq) 2407.1 115.5 2393.0
KOH(aq) 2481.2 92.0 2439.6 NaClO4(s) 2383.30 142.3 2254.85
K2SO4(s) 21437.79 175.56 21321.37 NaCN(s) 287.49 118.49 276.4
NaCH3COO(s) 2708.80 123.0 2607.18
Rubidium Na2CO3(s) 21131 136 21048
Rb(s) 0 76.78 0 NaF(s) 2573.647 51.46 2543.494
RbOH(aq) 2481.16 110.75 2441.24 NaH(s) 256.275 40.016 233.46
NaHCO3(s) 2950.81 101.7 2851.0
Selenium
NaHSO4(s) 21125.5 113.0 2992.8
Se(s) 0 42.442 0
NaH2PO4(s) 21538 128 21387
H2Se(g) 29.7 219.02 15.9
Na2HPO4(s) 21749 151 21609
Silicon NaI(s) 2287.78 98.53 2286.06
Si(s) 0 18.8 0 NaNO3(s) 2467.85 116.52 2367.00
SiBr4(,) 2457.3 277.8 2443.9 Na2O(s) 2414.22 75.06 2375.46
SiC(s) 265.3 16.6 262.8 Na2O2(s) 2510.87 95.0 2447.7
SiCl4(g) 2657.0 330.6 2617.0 NaOH(s) 2426.7 64.45 2379.49
SiCl4(,) 2687.0 239.7 2619.84 NaOH(aq) 2469.6 49.8 2419.2
SiH4(g) 34.3 204.5 56.9 Na3PO4(s) 21917.40 173.80 21788.80
SiF4(g) 21615 282.4 21573 Na2S(s) 2364.8 83.7 2349.8
SiI4(g) 2132 — — Na2SO4(s) 21387.08 149.58 21270.16
SiO2(s) 2910.9 41.84 2856.7 Na2S2O3(s) 21123.0 155 21028.0
H2SiO3(s) 21189 134 21092
H4SiO4(s) 21481.1 192 21332.9 Strontium
Na2SiO3(s) 21079 — — Sr(s) 0 52.3 0
H2SiF6(aq) 22331 — — SrCl2(s) 2828.9 114.85 2781.1
SrCO3(s) 21220.1 97.1 21140.1
Silver SrO(s) 2592.0 54.4 2561.9
Ag(s) 0 42.55 0
Ag1(aq) 105.79 73.86 77.12 Sulfur
AgBr(s) 2100.37 107.1 296.90 S(s, rhombic) 0 31.8 0
AgCl(s) 2126.904 96.085 2109.8 S(g) 278.8 167.8 238.3
AgI(s) 261.84 115.5 266.19 S8(g) 102.30 430.98 49.63
AgNO3(s) 2124.39 140.92 233.41 S2Cl2(g) 218 331 231.8
Ag2O(s) 231.05 121.3 211.20 SF6(g) 21209 291.7 21105
AgS(s) 232.59 144.01 240.67 H2S(g) 220.6 205.7 233.6
AgSCN(s) 87.9 131.0 101.36 H2SO4(,) 2814.0 156.9 2690.1
Ag2SO4(s) 2715.88 200.4 2618.41 H2SO4(aq) 2907.5 17 2742.0

516 Appendix E
 D H f° S° D G f° D H f° S° D G f°
(kJ (J mol21 (kJ (kJ (J mol21 (kJ
Species mol21) K21) mol21) Species mol21) K21) mol21)

SO2(g) 2296.8 248.1 2300.2 Uranium

SO3(g) 2395.6 256.6 2371.1 U(s) 0 50.21 0
SOCl2(,) 2206 — — UF6(s) 22147.4 377.9 22063.7
SO2Cl2(,) 2389 — — UO2(s) 21084.9 77.03 21031.7
UO3(s) 21223.8 96.11 21145.9
Tellurium
Te(s) 0 49.71 0 Xenon
TeO2(s) 2322.6 79.5 2270.3 Xe(g) 0 169.683 0
Tin XeF2(g) 2130 260 296
Sn(s, white) 0 51.55 0 XeF4(g) 2215 316 2138
Sn(s, gray) 22.09 44.1 0.13 XeO3(g) 502 287 561

SnCl2(s) 2350 — — Zinc

SnCl4(,) 2511.3 258.6 2440.2 Zn(s) 0 41.63 0
SnCl4(g) 2471.5 366 2432.2 ZnCl2(s) 2415.05 111.46 2369.398
SnO(s) 2285.8 56.5 2256.9 ZnCO3(s) 2812.78 82.4 2731.52
SnO2(s) 2580.7 52.3 2519.7 ZnO(s) 2348.3 43.64 2318.3
Zn(OH)2(s) 2643.25 81.6 2555.07
Titanium
ZnS(s) 2205.6 57.7 2201.3
Ti(s) 0 30.6 0
ZnSO4(s) 2982.8 110.5 2871.5
TiCl4(,) 2804.2 252.3 2737.2
TiCl4(g) 2763.2 354.8 2726.8

Tungsten
W(s) 0 32.6 0
WO3(s) 2842.9 75.90 2764.1

Appendix E 517