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Year 12 SL Topic 4 Summative Assessment

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Year 12 SL Topic 4 Summative Assessment

Paper One (25 questions) 25 marks


1. Which compound forms hydrogen bonds in the liquid state?

A. C2H5OH

B. CHCl3

C. CH3CHO

D. (CH3CH2)3N
(Total 1 mark)

2. How do the bond angles in CH4, NH3 and H2O compare?

A. CH4 = NH3 = H2O

B. CH4 < NH3 < H2O

C. NH3 < CH4 < H2O

D. H2O < NH3 < CH4


(Total 1 mark)

3. Which combination of the characteristics of element X, a metal, and element Y, a non metal, is
most likely to lead to ionic bonding?
X Y

A. low ionization energy high electronegativity value

B. low ionization energy low electronegativity value

C. high ionization energy high electronegativity value

D. high ionization energy low electronegativity value


(Total 1 mark)
4. Which particles are responsible for electrical conductivity in metals?

A. Anions

B. Cations

C. Electrons

D. Protons
(Total 1 mark)

5. What is the shape of the SO2 molecule?

A. Bent (V-shaped)

B. Linear

C. T-shaped

D. Triangular planar
(Total 1 mark)

6. Which molecule has a non-bonding (lone) pair of electrons on the central atom?

A. BF3

B. SO2

C. CO2

D. SiF4
(Total 1 mark)

7. When C2H2, C2H4 and C2H6 are arranged in order of increasing carbon-carbon
bond strength (weakest bond first), what is the correct order?

A. C2H2, C2H4, C2H6

B. C2H2, C2H6, C2H4

C. C2H6, C2H4, C2H2

D. C2H6, C2H2, C2H4


8. The number of electrons in the valence shell of elements A and B, are 6 and 7
respectively. What is the formula and type of bonding in a compound formed by
these elements?

A. A2B, covalent

B. AB2, covalent

C. A2B, ionic

D. AB2, ionic
(Total 1 mark)

9. Lewis structures are represented in different ways in different parts of the world.
Two ways of drawing the Lewis structure for H3O+ are shown below.

Which statement is correct about H3O+?

A. The ion has a tetrahedral shape.

B. The H–O–H bond angle is 120°.

C. The H–O–H bond angle is 90°.

D. The ion has a trigonal pyramidal shape.


(Total 1 mark)

10. Which is the best description of the bonding present in the ammonium ion, NH4+?

A. Sharing of electrons between atoms

B. Electrostatic attraction between ions

C. Electrostatic attraction between positive ions and delocalized electrons

D. Sharing of electrons between atoms and electrostatic attraction between ions


(Total 1 mark)
11. Which molecule has the shortest carbon-oxygen bond length?

A. CH3COOH

B. CH3CH2OH

C. CO2

D. CO
(Total 1 mark)

12. Which pair of compounds is arranged in the correct order of relative boiling points?

Lower Boiling Point Higher Boiling Point

A. H2S H2O

B. NH3 PH3

C. HF HCl

D. CH3COOH CH3CH2OH
(Total 1 mark)

13. Which statement about the bonding between carbon atoms is correct?

A. In C60 fullerene each carbon atom is covalently bonded to three other carbon atoms.

B. In C60 fullerene each carbon atom is covalently bonded to four other carbon atoms.

C. In graphite each carbon atom is covalently bonded to four other carbon atoms.

D. In graphite each carbon atom forms a double covalent bond with three other carbon atoms.
(Total 1 mark)
14. Which pair of compounds is arranged in the correct order of relative boiling points?

Lower Boiling Point Higher Boiling Point

A. CH3OCH3 CH3CH2OH

B. CH3CHO CH3CH2CH3

C. CH3CH2OH CH3CHO

D. CH3COOH CH3CH2OH

(Total 1 mark)

15. What is the formula of magnesium fluoride?

A. Mg2F3

B. Mg2F

C. Mg3F2

D. MgF2
(Total 1 mark)

16. What is the shape of the ammonia molecule, NH3?


A. Trigonal planar
B. Trigonal pyramidal
C. Linear
D. V-shaped (bent)
(Total 1 mark)

17. Which molecule is polar?

A. CH2Cl2

B. BCl3

C. Cl2

D. CCl4
(Total 1 mark)
18. Which substance can form intermolecular hydrogen bonds in the liquid state?

A. CH3OCH3

B. CH3CH2OH

C. CH3CHO

D. CH3CH2CH3
(Total 1 mark)

19. Which compound has a covalent macromolecular (giant covalent) structure?

A. MgO(s)

B. Al2O3(s)

C. P4O10(s)

D. SiO2(s)
(Total 1 mark)

20. Which species have a dative covalent bond?

I. CO

II. NH3

III. H3O+

A. I and II only

B. I and III only

C. II and III only

D. I, II and III
(Total 1 mark)
21. The electronegativities of four different elements are given below (the letters are
not their chemical symbols).

Element W X Y Z

Electronegativity 0.9 1.2 3.4 4.0

Based on this information which statement is correct?

A. W is a non-metal.

B. W and X form an ionic compound.

C. Y is a metal.

D. Y and Z form a covalent compound.


(Total 1 mark)

22. Which species contain a dative covalent bond?

I. HCHO

II. CO

III. H3O+

A. I and II only

B. I and III only

C. II and III only

D. I, II and III
(Total 1 mark)

23. Which substance is made up of a lattice of positive ions and free moving electrons?

A. Graphite

B. Sodium chloride

C. Sulfur

D. Sodium
(Total 1 mark)
24. Which order is correct when the following compounds are arranged in order of
increasing melting point?

A. CH4 < H2S < H2O

B. H2S < H2O < CH4

C. CH4 < H2O < H2S

D. H2S < CH4 < H2O


(Total 1 mark)

25. What type of solid materials are typically hard, have high melting points and poor
electrical conductivities?

I. Ionic
II. Metallic
III. Covalent-network

A. I and II only

B. I and III only

C. II and III only

D. I, II and III
Paper Two (4 questions) 20 marks

1. Explain why silicon dioxide is a solid and carbon dioxide is a gas at room temperature.

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(Total 2 marks)

2. Explain the electrical conductivity of molten sodium oxide and liquid sulfur trioxide.

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(Total 2 marks)

3. Methoxymethane, CH3OCH3, and ethanol, C2H5OH, have the same relative molecular
mass.

Explain why methoxymethane has a much lower boiling point than ethanol.

...............................................................................................................................

...............................................................................................................................

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(Total 3 marks)
4. Ethene, C2H4, and hydrazine, N2H4, are hydrides of adjacent elements in the
periodic table.

(a) (i) Draw Lewis (electron dot) structures for C2H4 and N2H4 showing all
valence electrons.

(2)

(ii) State and explain the H–C–H bond angle in ethene and the H–N–H bond angle in
hydrazine.
(5)

...............................................................................................................................

...............................................................................................................................

...............................................................................................................................

...............................................................................................................................

(b) The polarity of a molecule can be explained in terms of electronegativity.

(i) Define the term electronegativity.


(2)

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...............................................................................................................................
(ii) Compare the relative polarities of the C–H bond in ethene and the N–H bond in
hydrazine.
(1)

...............................................................................................................................

...............................................................................................................................

(iii) Hydrazine is a polar molecule and ethene is non-polar. Explain why ethene is
non-polar.
(1)

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...............................................................................................................................

(c) The boiling point of hydrazine is much higher than that of ethene. Explain this
difference in terms of the intermolecular forces in each compound.
(2)
(Total 13 marks)

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