Cci400 SDS

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Revision date: 28/01/2020 Revision: 3 Supersedes date: 14/12/2018

SAFETY DATA SHEET


Corroless CCI 400

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name Corroless CCI 400

Product number LC00400

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Paint.

1.3. Details of the supplier of the safety data sheet


Supplier
CORROLESS Corrosion Control
Kelvin Way
West Bromwich
West Midlands
B70 7JZ United Kingdom
t: +44 (0)121 525 5665
f: +44 (0)121 553 2787
[email protected]

1.4. Emergency telephone number


Emergency telephone +44 121 524 2245 (not 24 hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Flam. Liq. 3 - H226

Health hazards STOT SE 3 - H336

Environmental hazards Not Classified

2.2. Label elements

Pictogram

Signal word Warning

Hazard statements H226 Flammable liquid and vapour.


H336 May cause drowsiness or dizziness.

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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P240 Ground/ bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing vapour/ spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/ doctor if you feel unwell.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

Contains HYDROCARBONS, C9 - C11, n-alkanes, isoalkanes, cyclics, <2% aromatics

2.3. Other hazards


SECTION 3: Composition/information on ingredients

3.2. Mixtures

HYDROCARBONS, C9 - C11, n-alkanes, isoalkanes, cyclics, 10-30%


<2% aromatics
CAS number: — EC number: 919-857-5 REACH registration number: 01-
2119463258-33-XXXX

Classification
Flam. Liq. 3 - H226
STOT SE 3 - H336
Asp. Tox. 1 - H304

Dowanol PnB Glycol Ether 1-5%


CAS number: 5131-66-8 EC number: 225-878-4

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319

CRAYVALLAC SUPER 1-5%


CAS number: — EC number: 907-495-0 REACH registration number: 01-
2119545465-35-XXXX

Classification
Aquatic Chronic 3 - H412

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ethanol <1%
CAS number: 64-17-5 EC number: 200-578-6 REACH registration number: 01-
2119457610-43-0000

Classification
Flam. Liq. 2 - H225

methanol <1%
CAS number: 67-56-1 EC number: 200-659-6 REACH registration number: 01-
2119433307-44-0000

Classification
Flam. Liq. 2 - H225
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


Inhalation Move affected person to fresh air at once. Get medical attention if any discomfort continues.

Ingestion Do not induce vomiting. Keep affected person warm and at rest. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical
attention if any discomfort continues.

Eye contact Rinse immediately with plenty of water. Continue to rinse for at least 15 minutes. Get medical
attention if any discomfort continues.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue. It may
be dangerous for first aid personnel to carry out mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it from the affected person, or
wear gloves.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation Vapours may cause drowsiness and dizziness. Headache. Nausea, vomiting.

Ingestion May cause discomfort if swallowed. Diarrhoea. Nausea, vomiting.

Skin contact Prolonged contact may cause redness, irritation and dry skin.

Eye contact Irritation of eyes and mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

Specific treatments No specific chemical antidote is known to be required after exposure to this product.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

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Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture


Specific hazards The product is flammable. Fire-water run-off in sewers may create fire or explosion hazard.
Vapours are heavier than air and may spread near ground and travel a considerable distance
to a source of ignition and flash back. Control run-off water by containing and keeping it out of
sewers and watercourses.

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Carbon dioxide (CO2). Carbon monoxide (CO). Acrid smoke or fumes. Metal oxide(s). Oxides
of nitrogen.

5.3. Advice for firefighters


Protective actions during In case of fire: Evacuate area. No action shall be taken without appropriate training or
firefighting involving any personal risk. Cool containers exposed to heat with water spray and remove
them from the fire area if it can be done without risk.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


For non-emergency personnel No action shall be taken without appropriate training or involving any personal risk. Evacuate
area. Keep unnecessary and unprotected personnel away from the spillage. Do not touch or
walk into spilled material. Eliminate all ignition sources if safe to do so. No smoking, sparks,
flames or other sources of ignition near spillage. Do not breathe gas, fume, vapours or spray.
Provide adequate ventilation. If ventilation is inadequate, suitable respiratory protection must
be worn. Use protective equipment appropriate for surrounding materials.

For emergency responders Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses. Spillages or uncontrolled
discharges into watercourses must be reported immediately to the Environmental Agency or
other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Absorb spillage with non-combustible, absorbent material.

6.4. Reference to other sections


Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions For professional users only. Eliminate all sources of ignition. Use only in well-ventilated areas.
Wear protective clothing as described in Section 8 of this safety data sheet. Earth container
and transfer equipment to eliminate sparks from static electricity. For the greatest protection,
clothing should include anti-static overalls, boots and gloves. Use only non-sparking tools.
Keep away from heat, sparks and open flame. Avoid inhalation of vapours/spray and contact
with skin and eyes. Inhalation of dust during cutting, grinding or sanding operations involving
this product may cause irritation of the respiratory tract.

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Advice on general Do not eat, drink or smoke when using this product. Good personal hygiene procedures
occupational hygiene should be implemented. Wash hands thoroughly after handling. Take off contaminated
clothing and wash it before reuse. Remove contaminated clothing and protective equipment
before entering eating areas. Change work clothing daily before leaving workplace.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store at temperatures between 10°C and 25°C. Store in accordance with national regulations.
Store in tightly-closed, original container. Avoid contact with oxidising agents.

Storage class Flammable liquid storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters


Occupational exposure limits
HYDROCARBONS, C9 - C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
Long-term exposure limit (8-hour TWA): WEL 1000 mg/m³
ethanol
Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1920 mg/m³
methanol
Long-term exposure limit (8-hour TWA): WEL 200 ppm 266 mg/m³
Short-term exposure limit (15-minute): WEL 250 ppm 333 mg/m³
Sk
WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.

HYDROCARBONS, C9 - C11, n-alkanes, isoalkanes, cyclics, <2% aromatics

DNEL Industry - Dermal; Long term : 208 mg/kg/day


Industry - Inhalation; Long term : 871 mg/m³

CRAYVALLAC SUPER

PNEC - Soil; 217 mg/kg/day


- Marine water; 0.00432 mg/l
- Fresh water; 0.0432 mg/l
- Sediment (Marinewater); 108 mg/kg/day
- Sediment (Freshwater); 1080 mg/kg/day
- STP; 10 mg/l

ethanol (CAS: 64-17-5)

DNEL Industry - Inhalation; Short term local effects: 1900 mg/m³


Industry - Dermal; Long term systemic effects: 343 mg/kg/day
Industry - Inhalation; Long term systemic effects: 950 mg/m³

PNEC - Fresh water; Long term 0.96 mg/l


- Marine water; Long term 0.79 mg/l
- Sediment; Long term 3.6 mg/kg
- Soil; Long term 0.63 mg/kg

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methanol (CAS: 67-56-1)

DNEL Industry - Dermal; Short term systemic effects: 40 mg/kg/day


Industry - Dermal; Long term systemic effects: 40 mg/kg/day
Industry - Inhalation; Short term systemic effects: 260 mg/m³
Industry - Inhalation; Short term local effects: 260 mg/m³
Industry - Inhalation; Long term systemic effects: 260 mg/m³
Industry - Inhalation; Long term local effects: 260 mg/m³

PNEC - Fresh water; 154 mg/l


- Marine water; 15.4 mg/l
- Soil; 23.5 mg/kg
- STP; 100 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist. Use
explosion-proof ventilating equipment.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. Personal protective equipment for eye and face protection should
comply with European Standard EN166. Chemical splash goggles or face shield. If inhalation
hazards exist, a full-face respirator may be required instead.

Hand protection To protect hands from chemicals, gloves should comply with European Standard EN374. The
most suitable glove should be chosen in consultation with the glove supplier/manufacturer,
who can provide information about the breakthrough time of the glove material. Considering
the data specified by the glove manufacturer, check during use that the gloves are retaining
their protective properties and change them as soon as any deterioration is detected. For
exposure up to 8 hours, wear gloves made of the following material: Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact. Wear suitable protective equipment for prolonged exposure and/or
high concentrations of vapours, spray or mist. For the greatest protection, clothing should
include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for
information on material and design requirements and test methods.

Hygiene measures Good personal hygiene procedures should be implemented. Wash hands thoroughly after
handling. Wash promptly with soap and water if skin becomes contaminated. Promptly
remove any clothing that becomes contaminated. Care should be taken to avoid contact with
contaminants when removing contaminated clothing. Remove contaminated clothing and
protective equipment before entering eating areas. Use appropriate skin cream to prevent
drying of skin. When using do not eat, drink or smoke.

Respiratory protection Respirator selection must be based on exposure levels, the hazards of the product and the
safe working limits of the selected respirator.

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Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels. Keep container tightly sealed when not in use.
Residues and empty containers should be taken care of as hazardous waste according to
local and national provisions.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Brown.

Odour Characteristic.

Flash point 32-41°C

Relative density 0.88

Solubility(ies) Immiscible with water.

9.2. Other information


SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity No test data specifically related to reactivity available for this product or its ingredients.

10.2. Chemical stability


Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions


Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid heat, flames and other sources of ignition. Do not pressurise, cut, weld, drill, grind or
otherwise expose containers to heat or sources of ignition. Avoid the accumulation of vapours
in low or confined areas.

10.5. Incompatible materials


Materials to avoid Avoid contact with the following materials: Oxidising agents. Strong acids.

10.6. Hazardous decomposition products


Hazardous decomposition None at ambient temperatures. Heating may generate the following products: Carbon
products monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).

SECTION 11: Toxicological information

11.1. Information on toxicological effects


SECTION 12: Ecological Information

12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment

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12.6. Other adverse effects


SECTION 13: Disposal considerations

13.1. Waste treatment methods


General information Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements. Waste is classified as hazardous waste. Waste, residues,
empty containers, discarded work clothes and contaminated cleaning materials should be
collected in designated containers, labelled with their contents.

Disposal methods Residues and empty containers should be taken care of as hazardous waste according to
local and national provisions. Do not empty into drains.

Waste class 08 01 11 Waste paint and varnish containing organic solvents or other dangerous
substances If this product is mixed with other wastes, this code may no longer apply. If mixed
with other wastes, the appropriate code should be assigned.
For further information, contact your local waste authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1263

UN No. (IMDG) 1263

UN No. (ICAO) 1263

UN No. (ADN) 1263

14.2. UN proper shipping name


Proper shipping name PAINT
(ADR/RID)

Proper shipping name (IMDG) PAINT

Proper shipping name (ICAO) PAINT

Proper shipping name (ADN) PAINT

14.3. Transport hazard class(es)


ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

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ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

14.6. Special precautions for user


EmS F-E, S-E

ADR transport category 3

Emergency Action Code •3YE

Hazard Identification Number 33


(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Health and environmental None of the ingredients are listed.


listings

Authorisations (Title VII No specific authorisations are known for this product.
Regulation 1907/2006)

Restrictions (Title VIII No specific restrictions on use are known for this product.
Regulation 1907/2006)

15.2. Chemical safety assessment


A chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms ATE = Acute Toxicity Estimate


used in the safety data sheet CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number

Revision date 28/01/2020

Revision 3

Supersedes date 14/12/2018

SDS number 5589

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Hazard statements in full H225 Highly flammable liquid and vapour.


H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H370 Causes damage to organs .
H412 Harmful to aquatic life with long lasting effects.

Description Wax Corrosion Inhibitor

Mix Ratio Single Pack

Shelf life 2 year

EU Dir 2

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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