General Instructions

1. The test is of 3 hours duration.

2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has two sections (Section 1 & Section 2).

3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.

4. Section 2 contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL
VALUE. For each question, enter the correct numerical value of the answer. If the answer is a decimal
numerical value, then round-off the value to TWO decimal places. If the answer is an Integer value, then do
not add zero in the decimal places. In the OMR, do not bubble the  sign for positive values. However, for
negative values, Θ sign should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)

5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc. inside the examination room/hall.

6. Rough work is to be done on the space provided for this purpose in the Test Booklet only.

7. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

8. Do not fold or make any stray mark on the Answer Sheet (OMR).

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

2. Section – 2: +4 for correct answer, 0 for all other cases. There is no negative marking.

Name of the Candidate (In CAPITALS) :

Roll Number :

OMR Bar Code Number :

Candidate's Signature : Invigilator's Signature

 Vidyamandir Classes: Innovating For Your Success

PART I : PHYSICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.

1. A simple pendulum consists of a metal wire of coefficient of linear thermal expansion  attached to a
heavy bob. The time period of this pendulum on a cold winter day with temperature 5C is TC , and its
TC
time period on a hot summer day with temperature 35°C is TH . The ratio is close to:
TH
(A) 1  30 (B) 1  30 (C) 1  15 (D) 1  15

2. One mole of a monoatomic gas at 27ºC is allowed to expand isothermally such that its final volume is 8
times its initial volume. The work done by the gas during the expansion is: (loge 2  0.693)
(A) 576 J (B) 1728 J (C) 5183 J (D) 466 J

3. A particle executes SHM along a straight line with frequency f and amplitude A. The minimum time
A
taken by the particle to go from its mean position to a point at a distance from the mean position is:
2
1 1 1 1
(A) (B) (C) (D)
6f 8f 12 f 16 f
4. Let us assume that the sun and another star A are perfect spheres and perfect black bodies. The radius of
star A is four times the radius of the sun and it radiates heat energy at exactly the same rate as the sun. If
the surface temperature of the sun is 6000 K, the surface temperature (in Kelvin) of the star A is:
(A) 8484 (B) 4242 (C) 3000 (D) 2000

5. A gas undergoes the thermodynamic process shown in the P–V diagram. The work done by the gas in
this process is:

9
(A) 3P0V0 (B) 4P0V0 (C) P0V0 (D) 6P0V0
2
6. A small block of mass m is placed on a frictionless horizontal surface and connected to two massless
springs of spring constant k and 2k as shown. The other ends of the springs are fixed to rigid walls.
Initially, both springs are in their natural length. Now, the block is displaced by a small distance to the
right and released. The time period of the resulting SHM is:

m m 2m 3m
(A) 2 (B) 2 (C) 2 (D) 2
3k 2k 3k 2k

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7. Two cuboidal blocks made of different materials of thermal conductivity K and 3K are placed end to end
between two heat reservoirs maintained at constant temperature TA and TB (such that TA  TB ). The
blocks have the same area of cross-section, but lengths L and 2L respectively. The temperature at the
interface between the blocks is:

1 1
(A) T  TA  6TB  (B) T  6TA  TB 
7 7
1 1
(C) T   2TA  3TB  (D) T   3T A  2TB 
5 5

8. Two blocks A and B of mass 4 kg and 2 kg respectively are suspended using two metallic wires as
d
shown. The diameter of the wires are in the ratio 1  1: 2 , and their Young’s moduli are in the
d2
Y1
ratio  3 :1 . The strain produced in them is in the ratio:
Y2

(A) 2:1 (B) 4:9 (C) 2:3 (D) 4:1

9. A simple pendulum consists of a massless string of length L attached to a small bob of mass m. The
pendulum is made to oscillate with small angular amplitude m . The maximum kinetic energy of the bob
during the oscillation is:
1 1 3
(A) mgL 2m (B) mgL 2m (C) mgL 2m (D) mgL 2m
4 2 4

L
10. A thin, uniform rod of length L is pivoted at a point O at a distance from one of its
4
ends, such that it can rotate freely in the vertical plane. From the equilibrium position
shown in the figure, the rod is rotated by a small angle and released from rest. The rod
performs angular SHM of time period:
7L 7L
(A) 2 (B) 2
12 g 3g
21 L 21 L
(C) 2 (D) 2
4g g

11. The specific heat at constant volume (in J/kgK) of Argon gas (molar mass = 40 g/mol) is close to:
(R = 8.31 J/mol K)
(A) 276 (B) 290 (C) 312 (D) 409

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12. A small block of mass 0.3 kg is suspended with a vertical spring of spring constant
120 N/m as shown and released from rest at t  0 with the spring in its natural
length. If the vertically upward direction is taken as positive, the velocity

(in cm/s) of the block varies with time (in seconds) as: g  10 m/s2 
   
(A) v  t   100sin  0 t   (B) v  t   100sin  0 t  
 2  2
   
(C) v  t   50 cos  0 t   (D) v  t   50cos  0 t  
 2  2
13. Let the latent heat of fusion of ice be denoted by L, and let the specific heat of water be denoted by C. A
mass m1 of ice at 0 oC is mixed with mass m2 of liquid water at T o C , and all the ice melts. Assuming
that no heat is gained from or lost to the surroundings, the final temperature is:
 L L L  L
m1    m2T m2T  m1   m2T  m1   m2T  m1  
(A) C (B)  C  (C)  C  (D) C
 m1  m2   m1  m2   m1  m2   m1  m2 
14. In which of the following thermodynamic processes, the work done by the gas is positive and the change
in its internal energy is negative?
(A) Expansion at constant pressure (B) Compression at constant pressure
(C) Adiabatic expansion (D) Adiabatic compression

15. Two particles A and B each of mass M are fixed in free space with a distance 2a between them. A third
particle of mass m is in equilibrium at the mid-point between the particles A and B. If the particle of mass
m is displaced by a small distance along the perpendicular bisector of AB, and released, it begins SHM of
frequency: (G is the gravitational constant)

1 2GM 1 GM 1 2GM 1 GM
(A) (B) (C) (D)
2 a3 2 a 3 2 3a 3 2 2 a 3

16. The density of a metal at temperature T1 is 1 and its density at temperature T2 is  2 . The volume
thermal expansion coefficient of the metal is given by:
3  1  3  2 
(A)    1 (B)    1
 2 1 2 
T  T   2 1 1 
T  T 

1  1  1  2 
(C)    1 (D)    1
 T2  T1   2   T2  T1   1 
17. A diatomic gas initially at pressure P1 expands such that its pressure and volume follow the relation:
P
 constant . If volume of the gas increases from V1 to V2 during the process, the heat absorbed by the
V3
gas is:
 7   P1  4  11   P1  4
   3  V2  V1     3  V2  V1 
4 4
(A) (B)
4 V
  1  4
  1 V

 7   P1  3  11   P1  3
   2  V2  V1     2  V2  V1 
3 3
(C) (D)
4 V
  1  4
  1 V

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18. A sphere made of steel is initially at the surface of a lake of depth 300 m, where the ambient temperature
is 20 oC . If the sphere is dropped into the lake such that it sinks and settles at the bottom, where the
temperature is 10 o C , the fractional change in its volume is:
(Bulk modulus of steel = 150 GPa, Volume thermal expansion coefficient of steel = 3  106 oC 1 )
(Assume that the density of water everywhere in the lake is 1000 kg/m 3 , and g  10 m/s 2 )
(A) 105 (B)  10 5  (C)   3  105  (D)   5  105 
19. A body at temperature 80.0 oC is placed in a room maintained at a constant temperature 20.0 oC . The
body takes time t1 to cool from 80.0 oC to 79.9 oC , and it takes time t2 to cool from 40.0 o C to 39.9 oC .
t1
Assuming that the cooling process follows Newton’s law of cooling, the ratio is close to:
t2
1 1 1 1
(A) (B) (C) (D)
6 4 3 2
20. 100 g of Nitrogen gas is compressed at constant pressure, such that the rms speed of its molecules before
and after the process is 500 m/s and 700 m/s respectively. The heat rejected by the gas during the process
(in kJ) is:
(A) 12 (B) 20 (C) 24 (D) 28
SPACE FOR ROUGH WORK

SECTION-2
This Section contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value,
then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the
decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign
should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)

21. When 10 g of a liquid X at temperature 80 o C is mixed with 20 g of a liquid Y at 20 oC in a perfectly

insulated vessel, the final temperature is 32 oC . Now, if 5 g more of liquid Y at 20 oC is added to the
mixture, the final temperature (in o C ) is _____________.
22. A gas is taken through a Carnot cycle operating between heat reservoirs at temperature 300 K and
500 K. If the heat absorbed by the gas per cycle from the heat reservoir at temperature 500 K is 20 kJ, the
work done by the gas per cycle (in kJ) is ___________.
23. A particle executes SHM on the Y-axis with its mean position at the origin. The speed of the particle
when it is at y = –1 cm is 24 cm/s, and its speed when it is at y = 5 cm is 12 2 cm/s . The maximum
acceleration of the particle during the SHM (in cm/s2 ) is ______________.
24. An otherwise thermally insulated room can only exchange heat with the surroundings through a window
with a glass pane of area 1.2 m 2 and thickness 0.5 cm. A heater placed inside the room supplies heat to
the room at a constant rate 1800 W. On a day when the temperature outside the room is 14 °C, the
temperature inside the room (in °C) a long time after the heater is switched on becomes ____________.
(Thermal conductivity of glass  1 W / m °C )

25. A stationary vessel contains a mixture of equal moles of Nitrogen and Helium gas. The percentage of the
total kinetic energy of the mixture that is possessed by the molecules of Nitrogen is __________.
SPACE FOR ROUGH WORK

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PART II : CHEMISTRY 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. Which of the following compound shows complete cyclic delocalisation of (4n  2) e ? (Here n is a
whole number)

(A) (B) (C) (D)

2. Which of following is an optically inactive compound ?

(A) (B) (C) (D)

8 12
3. Given that Ka1 and Ka 2 of H 2S at 25°C are 10 and 10 respectively. What would be concentration
of the sulphide ions in the saturated solution of H 2S(0.1M) in presence of 0.1 M HCl.
(A) 1012 (B) 1019 (C) 107 (D) 1020
4. Identify correct order of pH of the given solutions at 25°C
(I) NH 4Cl (II) Na 2CO3 (III) K 2SO 4
(A) I < II < III (B) I < III < II (C) II < I < III (D) II < III < I

5. Z 2 undergo disproportion in an alkaline medium into a mixture of Z and ZO3 . Equivalent mass of
Z 2 in the reaction is: [given that atomic mass of Z is 80 gm/mol]
(A) 96 (B) 48 (C) 64 (D) 32
6. Given that K sp of AgCl is 10 10
and formation constant of the complex Ag(NH 3 ) 2 is 106 at 25°C. Then

 Ag(NH 3 ) 2 Cl is:

equilibrium constant of the reaction AgCl(s)  2NH3 (aq) 
(A) 105 (B) 104 (C) 0.002 (D) 102

7. Correct I.U.P.A.C name of the compound is:

(A) 4-Ethyl-2-methyl aniline (B) 2-Methyl-4-ethyl aniline

(C) 3-Methyl-5-ethyl aniline (D) 4-Ethyl-6-methyl aniline
8. Which of following aqueous mixture of CH3COOH and CH 3COONa will have maximum buffer
capacity?
(A) [CH3COOH]  1M, [CH 3COONa]  103 M
(B) [CH3COOH]  0.1M, [CH3COONa]  105 M
(C) [CH3COOH]  0.1M, [CH3COONa]  0.1M
(D) [CH3COOH]  0.001M, [CH3COONa]  0.1M

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9. AgOH solution was neutralized using HNO3 solution. If pH of the solution at 50% neutralization point
is 8 at 25°C, then pK b of AgOH is:
(A) 4.00 (B) 5.52 (C) 6.00 (D) 9.48
10. Which of following species have maximum number of peroxide linkages per molecule?
(A) CrO5 (B) Cr2O72 (C) S2O82 (D) H 2SO5

11. Volume strength of a H 2O 2 solution is 2.8. Normality of the solution is:

(A) 0.1 (B) 0.5 (C) 0.28 (D) 0.56
12. An aqueous solution having 0.01 mole FeSO 4 and 0.01 mole H 2SO4 is just sufficient to decolourise 10
ml of aqueous KMnO 4 . Then molarity of the KMnO 4 in the original solution was:
(A) 0.40 M (B) 0.20 M (C) 0.25 M (D) 0.32 M
13. Select the increasing order of oxidation state of the oxygen atoms in following compounds.
(I) O 2 F2 (II) OF2 (III) H 2O 2
(A) I < II < III (B) III < II < I
(C) III < I < II (D) II < III < I

14. Which of the following diagram correctly represent variation of pH of a solution of NH 4OH by addition
of increasing quantity (volume in ml) of a known HCl solution?

(A) (B) (C) (D)

1
15. pH of M CH 3COONH 4 is: (given that K a of CH 3COOH is 10 5 and K b of NH 4 OH is 105 at
40
25ºC)
(A) 7 (B) 6 (C) 5 (D) 8

16. Which of the following is not a redox reaction?

(A) Reaction taking place during photosynthesis
(B) Decomposition of H 2O 2
(C) Decomposition of CaCO3
(D) Decomposition of AgBr in presence of light
17. I.U.P.A.C name of the following compound is:

(A) 3-Bromo-pent-3-en-oic acid (B) 3-Bromo-pent-2-en-oic acid

(C) 3-Bromo-pent-4-en-oic acid (D) 3-Bromo-pentenoic acid

18. Which of following compound have weakest C – Cl bond?

(A) (B) (C) (D)

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19. Select correct statement out of the following:
(A) Eclipsed conformer of 1, 2-dichloro ethane is more stable than its Anti conformer.
(B) Gauche conformer of ethane-1, 2-diol is more stable than its anti-conformer
(C) Twisted boat form of cyclohexane is less stable than its Boat form
(D) Chair form of cyclohexane is optically active

20. What would be solubility (in mole L1 ) of AgCl (K sp  1010 ) in presence of 10 1 M AgNO3 ?

(A) 105 (B) 0.57  10 5 (C) 109 (D) 0.83  105

SPACE FOR ROUGH WORK

SECTION-2
This Section contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value,
then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the
decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign
should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
Acidic
21. n1Cr2 O72  n 2 FeC 2 O 4 
Medium
 n 3Cr 3  n 4 Fe 3  n 5CO2  n 6 H 2 O here n1 ,n 2 ,n 3 ,n 4 ,n 5 and n 6 are
simplest non fractional coefficients of the balanced redox reaction. Then value of
[n1  n 2  n 3  n 4  n 5  n 6 ] is:
22. Number of stereoisomers possible for the following compound is:

M M
23. 10 ml of H3PO 2 was neutralized by using KOH solution. If pKa of H3PO2 is 2.0 at 25°C then pH
5 5
of the solution at the end point is:

24. Increasing amount of dilute HCl was added to an aqueous solution containing 10 4 M each of Pb 2 and
Hg 2 2 . Given that Ksp values of PbCl2 and Hg 2Cl2 are 108 and 1016 respectively at 25°C then value
of pH of the solution at which precipitation of the least soluble metal halide will start is:
25. Nitrate ion acts as an oxidising agent and gets converted into a gas of vapour density 8.5. The equivalent
mass of nitrate ion is __________. (Given: Atomic mass H = 1, N = 14, O = 16)

SPACE FOR ROUGH WORK

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PART III : MATHEMATICS 100 MARKS

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
2
1. If the sum of all the solutions of the equation 2cos 2 x  3.2cos x  4 which are lying in the interval [0, 315]
is k, then the value of k is :
(A) 1950 (B) 5050 (C) 5151 (D) 5055
2. In an arithmetic progression of which a is the first term. If the sum of the first ten terms is zero and the
sum of next ten terms is –200, then the value of a is:
(A) 7 (B) 9 (C) 11 (D) 13

3. Let 45    90. If tan   cot   tan 2   cot 2  then the value of (sin   cos ), is :

1 3 1 2
(A) 2 (B) (C) (D)
2 2 3 1
10  26
Cr 
4. The value of  r2   is equal to :
 26
Cr 1 
r 1 
(A) 900 (B) 1100 (C) 1300 (D) 1800

5. How many six-digit numbers are there in which no digit is repeated, even digits appear at even places,
odd digits appear at odd places and the number is divisible by 4?
(A) 1440 (B) 2160 (C) 2700 (D) 3600

6. If lines x  y  2  0 and 2 x  y  2  0 meet at a point P then equation of tangent drawn to the parabola
y 2  8 x from the point `P is :
(A) x  2y  8  0 (B) x  y  16  0
(C) 3 x  y  16  0 (D) x  3 y  16  0
7. The sum of rational terms in binomial expansion of ( 2  5 3)10 is :
(A) 32 (B) 25 (C) 41 (D) 9

8. A point on the ellipse 4 x 2  9 y 2  36, where the normal is parallel to the line 4 x  2 y  5  0 .

 8 9   9 8  9 8 8 9
(A)  ,  (B)  ,  (C)  ,  (D)  , 
5 5   5 5 5 5 5 5
x2 y2
9. The area of the rectangle formed by the perpendicular from centre of   1, to the tangent and
9 4

normal at the point whose eccentric angle equals :
4
30 30 13 26
(A) (B) (C) (D)
13 11 30 11
10. On the sides AB, BC , CA of a ABC , 3, 4, 5 distinct points (excluding vertices A, B, C ) are respectively
chosen. The number of triangles that can be constructed using these chosen points as vertices are :
(A) 220 (B) 215 (C) 210 (D) 205

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11. The equation of line passing through the points of intersection of parabola x 2  8 y and ellipse
x2
 y 2  1, is :
3
(A) 3y 1  0 (B) y 20 (C) y 30 (D) 3y 1  0

x2 y 2 x2 y 2
12. Let the equations of two ellipse be E1 :   1 and E2 :   1 . If the product of their
3 2 16 b 2
1
eccentricities is , then the length of the minor axis of ellipse E2 is :
2
(A) 9 (B) 16 (C) 4 (D) 2
2 4 1
13. If the sum of the series 25  24  23  23  ... is maximum, then
5 5 5
1
(A) last term of the series is 0 (B) last term of the series is
5
(C) number of terms of the series are 42 (D) number of terms of the series are 40
10
 cos  
14. The greatest value of the term independent of x in the expansion of  x sin    is :
 x 
10
C5
(A) 10
C5 (B) 25 (C) 25  10 C5 (D)
25
15. Consider the word ‘CARCASSONNE’. Words are formed using all the letters of this word.
If number of words which contain the word `CAR’ and vowels are separated is k (5!) then k is equal to :

(A) 157 (B) 315 (C) 630 (D) None of these

 1   1   1 1  1 
16. The sum of the infinite series 1  1      1   2   2   ....
 5   2   5 5  2 
20 10 5 5
(A) (B) (C) (D)
9 9 9 3
17. If a , b, c are non-zero real numbers then the minimum value of the expression
 ( a8  4 a 4  1) (b 4  3b 2  1) (c 2  2c  2) 
  equals :
 a 4b2 
(A) 24 (B) 30 (C) 48 (D) 12
sin 7  6sin 5  17sin 3  12sin  
18. The expression when   reduces to :
sin 6  5sin 4  12sin 2 5
 3  
(A) cos (B) 2sin (C) sin (D) 2sin
5 10 5 10
19. The focal chord of the parabola ( y  2)2  16( x  1) is a tangent to the circle x 2  y 2  14 x  4 y  51  0,
then slope of the focal chord can be :

(A) 0 (B) 1 (C) 2 (D) 3

20. The equation of latus rectum of a parabola is x  y  8 and equation of the tangent at the vertex is
x  y  12, then the length of latus rectum is :
(A) 4 2 (B) 2 2 (C) 8 (D) 8 2

SPACE FOR ROUGH WORK

Code A | Page 10 JEE Main - 7 | JEE 2022

 Vidyamandir Classes: Innovating For Your Success

SECTION-2
This Section contains 5 Numerical Value Type Questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value of the answer. If the answer is a decimal numerical value,
then round-off the value to TWO decimal places. If the answer is an Integer value, then do not add zero in the
decimal places. In the OMR, do not bubble the  sign for positive values. However, for negative values, Θ sign
should be bubbled. (Example: 6, 81, 1.50, 3.25, 0.08)
n
 1 
21. If the coefficient of first three terms in the expansion  x  4  where n  N form an arithmetic
 2 x
progression, then find the number of terms in the expansion having integral powers of x.

7 13 19 m
22. The sum of the first 10 terms of the series 2 2
 2 2
 2 2
 .....is the find the value of
2 5 58 8 11 n
(n  12m)?

23. A tangent is drawn to the parabola y 2  48 x which makes an angle of 30º with the axis of x. Find the
distance between the tangent and a parallel normal.

24. A firm of Chartered Accountants in Bombay has to send 10 clerks to 5 different companies, two clerks in
each. Two of the companies are in Bombay and the others are outside. Two of the clerks prefer to work
in Bombay while three others prefer to work outside. In how many ways can the assignment be made if
the preferences are to be satisfied?

x2 y 2
25. If the straight line 4ax  3by  24 is a normal to the ellipse 2
 2  1 ( a  b) , then (a 2  b 2 ) is equal
a b
to_____.
SPACE FOR ROUGH WORK

   End of JEE Main - 7 | JEE 2022   

Code A | Page 11 JEE Main - 7 | JEE 2022