MSE3207 Lec01
MSE3207 Lec01
MSE3207 Lec01
2 LECTURE 1
Compare:
Fourier’s Law Fick’s 1st Law
q̄ = −kVT J¯ = −DVc
Why does heat behave this way?
Energy minimization ⇒ Entropy maximization
ut inn − heat
hheat h utoutn h(+ heat generation)
ut
= heat accumulation
n h ut n
A · qin A · qout chemical reaction, resistance
∂H
V · ∂T
∂H
A qin − A qout = V
∂T
3.044 MATERIALS PROCESSING 3
∂H
qin − qout = Δx
∂T
∂H
q|x − q|x+Δx = Δx
∂T
∂T ∂T ∂H
−k |x − |x+Δx = Δx
∂x ∂x ∂T
∂H k ∂T ∂T
= ( |x+Δx − |x )
∂T Δx ∂x ∂x
k ∂T
= Δ( )
Δx ∂x
∂( ∂T )
= k ∂x
∂x
∂H ∂2T
=k 2
∂T ∂x
The values of k, cp and ρ for any material can be looked up in tables and do not
need to be experimentally determined. Therefore α is a materials property.
Compare:
Heat Conduction Equation Fick’s 2nd Law
∂T ∂2T ∂c ∂2c
= hutn
α = hutn
D
∂t ∂x2 ∂t ∂x2
↓ h 2i ↓ h i
2
thermal diffusivity ms diffusivity ms