MSE3207 Lec01

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MSE 3207 MATERIALS PROCESSING

2 LECTURE 1

q̄ → heat flux mJ2 s = m


W
: J

−k → thermal conductivity m:WK J


: J
Fourier’s Law: q̄ = −kVT ,
VT → temperature gradient K m

Compare:
Fourier’s Law Fick’s 1st Law
q̄ = −kVT J¯ = −DVc
Why does heat behave this way?
Energy minimization ⇒ Entropy maximization

Heat Conduction Equation:

First think in 1-D

Heat balance in a small element:

ut inn − heat
hheat h utoutn h(+ heat generation)
ut
= heat accumulation
n h ut n
A · qin A · qout chemical reaction, resistance
∂H
V · ∂T

∂H
A qin − A qout = V
∂T
3.044 MATERIALS PROCESSING 3

∂H
qin − qout = Δx
∂T
∂H
q|x − q|x+Δx = Δx
∂T
∂T ∂T ∂H
−k |x − |x+Δx = Δx
∂x ∂x ∂T
∂H k ∂T ∂T
= ( |x+Δx − |x )
∂T Δx ∂x ∂x
k ∂T
= Δ( )
Δx ∂x
∂( ∂T )
= k ∂x
∂x
∂H ∂2T
=k 2
∂T ∂x

How does H relate to T?

where cp is heat capacity


ΔH = ΔT cp ρ
and ρ is density
∂H ∂T
= ρ cp
∂t ∂t
∂ 2T ∂T
k 2 = ρ cp
∂x ∂t
k ∂2T ∂T
=
ρ cp ∂x2 ∂t
∂ 2T ∂T
α 2 =
∂x ∂t
∂T ∂2T
=α 2
∂t ∂x

α is the Thermal Diffusivity


: W J
k mK
α=
m3
: kg K J
ρ J
cp kg
2
k m
α=
ρ cp s
4 LECTURE 1

The values of k, cp and ρ for any material can be looked up in tables and do not
need to be experimentally determined. Therefore α is a materials property.

Compare:
Heat Conduction Equation Fick’s 2nd Law
∂T ∂2T ∂c ∂2c
= hutn
α = hutn
D
∂t ∂x2 ∂t ∂x2
↓ h 2i ↓ h i
2
thermal diffusivity ms diffusivity ms

Topic for Future Discussion:


In 3-D ...
∂T
ρ cp = V · kVT
∂t
∂T
= αV2 T
∂t

** assuming k is constant with respect to the derivative

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