Cover: Safety Data Sheet (SDS)

The attached Safety Data Sheet is for the information of users of this product.

The SDS sheets are prepared by RICOH Japan, and cannot be altered.

The material referred to in this SDS is classified as:

Non-Hazardous.
Whilst the materials used in the manufacture of this product are not in sufficient
quantities to be harmful, please observe the manufacturer’s cautions when handling
the product.

For first aid information contact:

POISONS INFORMATION CENTRE

24 Hour Emergency Number: 13 11 26

For all SDS Information please refer to the Ricoh website:

www.ricoh.com.au

Ricoh Australia Pty Ltd

2 Richardson Place ,
North Ryde
New South Wales 2113
Australia.
Telephone (61-2-8977 1111)
Fax (61-2-8977 1120)

Q001 Issue 4
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07/2017 Date : 11/07/2017

Safety Data Sheet (ISO GHS - Australia - form)

1.Identification of the Substance/Preparation and of the Company/Ｕndertaking

Product Name : Print Cartridge Black MP C2503S (Black toner)
General Use : The Image Formation of Printing Machine or Copier
Product : Toner Cartridge
Description
MSDS Number : 841932
Company / Undertaking Identification
Company Name : Ricoh Company,Ltd.
Department : Safety and Reliability Engineering Department, Quarity Management
Divison
Address : 146-1 Nishisawada, Numazu-shi, Shizuoka-ken, 410-0007, Japan
Telephone Number : 055-920-1470, Japan
Telefax Number : 055-920-1479, Japan
Emergency Telephone : 055-920-1470, Japan
Number
E-mail : [email protected]

2.Hazards Identification
Classification
EXPLOSIVES Classification not possible
FLAMMABLE GASES Not Applicable
FLAMMABLE AEROSOLS Not Applicable
OXIDIZING GASES Not Applicable
GASES UNDER PRESSURE Not Applicable
FLAMMABLE LIQUIDS Not Applicable
FLAMMABLE SOLIDS Classification not possible
SELF-REACTIVE SUBSTANCES AND
Not Applicable
MIXTURES
PHYSICAL PYROPHORIC LIQUIDS Not Applicable
HAZARD(S) PYROPHORIC SOLIDS Classification not possible
SELF-HEATING SUBSTANCES AND
Classification not possible
MIXTURES
SUBSTANCES AND MIXTURES,
WHICH ON CONTACT WITH WATER, Classification not possible

－1－ [ISO/GHS]
 EMIT FLAMMABLE GASES
OXIDIZING LIQUIDS Not Applicable
OXIDIZING SOLIDS Classification not possible
ORGANIC PEROXIDES Classification not possible
CORROSIVE TO METALS Classification not possible
ACUTE TOXICITY(ORAL) Not Classified
ACUTE TOXICITY(DERMAL) Classification not possible
ACUTE TOXICITY
Not Applicable
(INHALATION - GAS)
ACUTE TOXICITY
Not Applicable
(INHALATION - VAPOUR)
ACUTE TOXICITY
Classification not possible
(INHALATION - DUST AND MIST)
SKIN CORROSION/IRRITATION Not Classified
SERIOUS EYE DAMAGE/EYE
Not Classified
IRRITATION
HEALTH HAZARD(S) RESPIRATORY SENSITIZER Classification not possible
SKIN SENSITIZER Not Classified
GERM CELL MUTAGENICITY Classification not possible
CARCINOGENICITY Classification not possible
TOXIC TO REPRODUCTION Classification not possible
TARGET ORGAN SYSTEMIC
TOXICITY FOLLOWING SINGLE Classification not possible
EXPOSURE
TARGET ORGAN SYSTEMIC
TOXICITY FOLLOWING REPEAT Classification not possible
EXPOSURE
ASPIRATION HAZARD Classification not possible
ACUTE HAZARDS TO
Classification not possible
THE AQUATIC ENVIRONMENT
ENVIRONMENTSL CHRONIC HAZARDS TO
HAZARD(S) THE AQUATIC ENVIRONMENT
Classification not possible
HAZARDOUS TO THE OZONE LAYER Classification not possible

－2－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07 2017 OutputDate : 11/07/2017

Label element
Pictogram：
Signal word(s)： Not applicable
Hazard statement(s)： Not applicable
Precautionary
statement(s) Not applicable
【Prevention】
【Response】
Not applicable
【Storage】 Not applicable
【Disposal】 Not applicable
Specific Hazards
Dust explosion (like most finely grained organic powders)

3.Composition/Information on Ingredients
Substance or Preparation
Preparation
Chemical Nature
Ingredients Chemical Formula CAS.No. Contents(%)
Polyester Resin Confidential Confidential 60-90
Wax Confidential Confidential 1-20
Carbon Black C 1333-86-4 1-20
Titan Oxide TiO2 13463-67-7 0.1-1
Silica O2Si 7631-86-9 ＜10

This product does not contain any of the following substances as ingredients.
Cadmium, Hexavalent Chromium, Mercury, Lead, Polybrominated biphenyls (PBB), Polybrominated

－3－ [ISO/GHS]
diphenyleters (PBDE), SVHC (substances of very high concern: published by ECHA).
And if it contains any impurities, it does not exceed any of the thresholds of RoHS.

Hazardous Ingredients Information

Chemical Name : Carbon Black
CAS Number : 1333-86-4 EEC Number : 215-609-9
OSHA　Z-Tables (USA) : 3.5mg/m3 ACGIH-TLV : 3.5mg/m3
NTP (USA) : Not listed IARC　Monographs : Group 2B
Symbol (EU) : Not listed R-Phrase (EU) : Not listed
DFG-MAK : III 3B OELs-TWA (Australia) : 3.0mg/m3
California Proposition 65 (USA) : Listed
Chemical Name : Titan Oxide
CAS Number : 13463-67-7 EEC Number : 236-675-5
OSHA　Z-Tables (USA) : 15mg/m3 ACGIH-TLV : 10mg/m3
NTP (USA) : Not listed IARC　Monographs : Group 2B
Symbol (EU) : Not listed R-Phrase (EU) : Not listed
DFG-MAK (GER) : Not listed OELs-TWA (Australia) : 10mg/m3
California Proposition 65 (USA) : Not listed

－4－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : Date Modified : 10/07 2017 OutputDate : 11/07/2017

4.First-Aid Measures
Inhalation
Remove from exposure to fresh air and rinse mouth with water. Seek medical advice.
Skin Contact
Wash thoroughly with soapy water.
Eye Contact
Flush with a large amount of water until particle is removed. Seek medical advice.
Ingestion
Drink several glasses of water to dilute ingested toner. Seek medical advice.
Notes to a physician
Not applicable
Most important symptoms/effects, acute, and delayed
Not applicable
Indication of immediate medical attention and special treatment needed, if necessary
Immediate medical attention is not required.

5.Fire-Fighting Measures
Extinguishing Media
CO2, dry chemicals, foam or water.
Extinguishing Media to Avoid
Not applicable
Specific Hazards
Can form explosive dust-air mixtures when finely dispersed in air.
Specific Method
No special fire protecting method is required. Sprinkling or fire extinguishers can be used.
Protection of Fire-fighters
Wear gloves, glasses, a mask if necessary.

6.Accidental Release Measures

Personal Precautions

－5－ [ISO/GHS]
 Do not breathe in dust.
Environment Precautions
Do not flush into sewers or watercourses.
Methods for Cleaning Up
Fine powder may form explosive dust-air mixture.
Confirm there is no source of fire and if there is a source, remove it. Sweep up spilled powder slowly
and clean remainder with wet cloth. If a vacuum cleaner is used, a dust explosion-proof type must be
chosen.

－6－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07/2017 Output Date : 11/07/2017

7.Handling and Storage

Handling
Technical Measures/Precautions
Not applicable
Safe Handling Advice
Do not handle in areas where there is wind or draught, this may cause dust to get into eyes.
Avoid breathing in dust.
Storage
Technical Measures
Not applicable
Storage Conditions
Keep out of reach of children.
Store in dry, well-ventilated area, to maintain quality the temperature should not exceed 35℃ for a
long time. Avoid direct sunlight.
Packaging Material
Not applicable
Specific Use(s)
Image formation in printing machines or copiers.

8.Exposure Controls/Personal Protection

Technical Measures
Use adequate ventilation. None required with intended use.
Control Parameters
USA OSHA PEL (TWA) : 15mg/m3 (Total dust) 5.0mg/m3 (Respirable fraction)
ACGIH TLV (TWA) : 10mg/m3 (Inhalable fraction) 3.0mg/m3 (Respirable fraction)
DFG MAK : 4.0mg/m3 (Total dust) 1.5mg/m3 (Respirable fraction)
Personal Protection
Respiratory Protections
None required in normal use. If the limit of exposure concentration is exceeded, use authorised
respirator.

－7－ [ISO/GHS]
 Hand Protection
Use vinyl or rubber gloves if necessary.
Eye Protection
Put on goggles if necessary.
Skin and Body Protection
Wear chemical-resistant apron or other impervious clothing if necessary.
Hygiene Measures
Wash hands after handling

9.Physical and Chemical Properties

Appearance
Physical State : Solid
Form : Powder
Colour : Black
Odour : Sligthly plastic odour
Odour : Not available
Threshold
Information
pH : Not
applicable
Specific Temperatures/Temperature Ranges at Which Changes in Physical State Occur
Boiling Point (degrees : Not applicable
centigrade)
Melting Point (degrees : (Softening point) Approx.90
centigrade)
Auto-Ignition Temperature : Not available
Decomposition Temperature (degrees : Not available
centigrade)
Flash Point (degrees centigrade) : Not applicable
Explosion Properties (degrees centigrade) : This product is considered a nonexplosive material
under normal use.

－8－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07/2017 OutputDate : 11/07/2017

Evapolation Rate : Not applicable

Vapor Pressure (Pa) Not applicable
:
Vapor Not applicable
Density(AIR=1) :
Density (g/cm3) Approx.1.2 Measuring Temp (degrees centigrade) : 25
:
Solubility
Water Solubility (g/L) : Insoluble
Chloroform Solubility (g/L) : Slightly soluble
Octanol/Water Partition Coefficient
Not available
Other Information
Flammability : Not flammable
Upper/Lower Flammability or Explosive
Limits
Upper Flammability or Explosive Limits : Not available
(g/m3)
Lower Flammability or Explosive Limits : Not available
(g/m3)
Viscosity (Pa･s) : Not applicable
Volatile (%) : 0.2 or below

10.Stability and Reactivity

Stability
Stable
Hazardous Reaction
Dust explosion, like most finely grained organic powders.
Conditions to Avoid

－9－ [ISO/GHS]
 Not applicable in normal use.
Materials to Avoid
Not applicable in normal use condition.
Hazardous Decomposition Products
Decomposition products will not occur.

11.Toxicological Information
Acute Toxicity
Acute Oral Toxicity (LD50) :
5000 or over [mg/kg] (Rat)
Acute Dermal Toxicity :
Not available
Acute Inhalation Toxicity :
Not applicable (Based on other Ricoh products test results of similar ingredients.)
Local effects
Acute Skin Irritation(PII) :
1.0 or below (Rabbit) (Based on other Ricoh products test results of similar ingredients.)
Acute Eye Irritation :
Non-irritant (Rabbit) (Based on other Ricoh products test results of similar ingredients.)
Sensitization
Acute Allergenic Effects :
Non-skinsensitive (Mouse) (Based on other Ricoh products test results of similar ingredients.)
Specific Effects
Carcinogenicity :
Carbon black and titanium dioxide contained in this product are classified to Group 2B of IARC as
the result of inhalation test in use of rat.
But oral/skin test does not show carcinogenicity.
The toner containing carbon black did not show carcinogenicity in chronic inhalation exposure test
in use of rat.
In the animal experiment with very high concentration of titanium dioxide (excessive burden of rat’s
lungs clearance mechanism (overload phenomenon)), the rat alone showed lung tumor. Under a
normal use practice, the concentration should be far lower than the above; and it is assumed that
there is no such use.
Also, relation between respiratory disease and work exposure of titanium dioxide is not observed
with epidemiological survey.
Mutagenicity : Negative (Ames test)
Reproduction Toxicity : Does not contain substances listed as hazardous to reproductive health.
Spscific target orgen

－10－ [ISO/GHS]
toxicity-single exposure

Spscific target orgen

toxicity-repeated exposure

Asprtation hazard
Does not contain substances listed as hazardous to reproductive health.
Symptoms related to the physical, chemical and toxicological characteristics
Not available

－11－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07/2017 OutputDate : 11/07/2017

12.Ecological Information
Mobility : No data are available on the adverse effect one environment.
Persistence/Degradabilit : Not available
y
Bioaccumulation : Not available
Ecotoxicity
Acute Toxicity for Fish (LC50) : Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/96hr
Acute Toxicity for Daphnia : Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/48hr
(EC50)
Algae Inhibition Test : Not classified as toxic (Regulation (EC) No 1272/2008).mg/l/72hr
(IC50)
Other Advers Effects : Not available

13.Disposal Consideration
General information:
Dispose of waste and residues in accordance with local authority requirements
Disposal methods:
Disposal recommendations are based on material as supplied. Disposal must be in accordance with
current applicable laws and regulations, and material characteristics at time of disposal. Confirm
disposal procedures with local regulations.
Precautions:
Do not throw the toner cartridge or toner into an open flame. The hot toner may scatter and cause burns
or other damage.

14.Transport Information
International Regulations
Land Transport
RID/ADR : Not applicable
DOT 49 CFR : Not applicable
ADNR : Not applicable

－12－ [ISO/GHS]
 Sea Transport
IMDG Code : Not applicable
Air Transport
ICAO-TI/IATA-DGR : Not applicable
The UN Classification : Not applicable
Number
UN Proper Shipping Name : Not applicable
Class : Not applicable
Packing Group, If Applicable : Not applicable
Specific Precautionary Transport Measures and conditions
Avoid direct sunlight in quality.

15.Regulatory Information
Regulations
EU Information
Information on the label (1999/45/EC and 67/548/EEC)
Symbols & Indications : Not required
R-Phrase : Not required
S-Phrase : Not required
Special Precautions under 1999/45/EC Annex V : Not required
76/769/EEC
This product complies with applicable rules and regulations under 76/769/EEC
304/2003/EC
Not regulated
US Information
Information on the label : Not required
TSCA (Toxic Substances Control Act) :
This product complies with all applicable rules and regulations under TSCA.
SARA Title III
313 Reportable Ingredients : Not regulated
California　Proposition　65 : Not regulated
Canada Information
WHMIS Controlled product : Not a controlled product

－13－ [ISO/GHS]
Product Name : Print Cartridge Black MP C2503S MSDS Number : 841932
Date Prepared : 29/05/2017 Date Modified : 10/07/2017 OutputDate : 11/07/ 2017

16.Other Information
Date Prepared : 2017/05/29
NFPA Hazard Rating: National Fire Protection Agency (USA)
Health ; 1, Flammability ; 1, Reactivity ; 0
HMIS Rating : The National Paint and Coating Association (USA)
Health ; 1, Flammability ; 1, Reactivity ; 0
Literature References :
ANSI Z400.1-1993
ISO 11014-1
IARC (1996) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vol.65,
Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds", Lyon, pp149-261
H. Muhle, B. Bellman, O. Creutzenberg, C. Dasenbrock, H. Emst, R. Kilpper, J.C. MacKenzie, P. Morrow, U. Mohr,
S. Takenaka and R. Mermelstein(1991) "Pulmonary Response to Toner upon Chronic Inhalation Exposure in Rats"
Fundamental and Applied Toxicology 17, pp 280-299
IARC (2008) "IARC Monograph on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol.93"
NIOSH CURRENT INTELLIGENCE BULLETIN "Evaluation of Health Hazard and Recommendation
for　Occupational Exposure to Titanium Dioxide DRAFT"
ACGIH-TLV : Threshold Limit Values for Chemical Substances and Physical Agents and
Biological Exposure Indices
OSHA　Z-Tables : US Department of Labor, 29CFR Part 1910 , Tables Z-1, Z-2, and Z-3
NTP (USA) : US Department of Health and Human Services National Toxicology
Program Annual Report on Carcinogens
DFG-MAK DFG List of MAK and BAT Value
Symbol (EC) : EU Directive 67/548/EEC
91/155/ EEC : EU Directive 91/155/ EEC
1999/45/EC Annex V : EU Directive 1999/45/EC
76/769/ EEC : EU Directive 76/769/ EEC
EC 304/2003 : Regulation (EC) No 304/2003 of the European Parliament and of the
Council of 28 January 2003 concerning the export and import of dangerous

－14－ [ISO/GHS]
 chemicals
WHMIS Controlled : Canada Workplace Hazardous Information System
product
OELs-TWA (Australia) : Guidance Note on the Interpretation of Exposure Standards for
Atmospheric Contaminants in the Occupational Environment [NOHSC:
3008 (1995)]
Abbreviations :
OSHA PEL PEL (Permissible Exposure Limit) under Occupational Safety and Health Act
ACGIH-TLV TLV (Threshold Limit Values) under American Conference of Governmental Industrial
Hygienists
REACH (EC)No.1907/2006:Council Regulation concerning the Registration, Evaluation,
Authorization and Restriction of Chemicals
SVHC Substances of Very High Concern
ECHA The European Chemicals Agency
DFG-MAK MAK (Maximale Arbeitsplatz Konzentrationen) by Deutsche Forschungs Gemeinschaft
RoHS Restriction of the use of certain Hazardous Substances in Electrical and Electronic
Equipment
TWA Time Weighted Average
IARC International Agency for Research on Cancer
NTP National Toxicology Program
WHMIS Workplace Hazardous Information System
NOHSC National Occupational Health and Safety Commission Act 1985
Disclaimer :
This information is furnished without warranty, express or implied, except that it is accurate to the best
knowledge of RICOH COMPANY, LTD.
It relates only to the specific material designated herein, and does not relate to use in combination with
any other material or process.
RICOH COMPANY, LTD assumes no legal responsibility for use or reliance upon　this information.

－15－ [ISO/GHS]