1® (JEE (Main + Advanced) 2023 REVISIONASSIGNMENT | rynwesse course REVISION ASSIGNMENT COORDINATION COMPOUNDS INORGANIC CHEMISTRY Single Correct Answer Type Ina complexometric titration of metal ion with ligand, M(Metal ion) + L(Ligand) -> C (complex) End point is estimated spectrophotometrically(through light absorption), If‘M’ and ‘C’ do not absorb light and only ‘L’ absorbs, then the titration plot between absorbed light(A) versus volume of ligand ‘L’ (V) would look like a A A (A) (B) () (D) ViLigand) > ViLigand)> V(Ligand)> V(Ligand) > A diamagnetic complex ,with molecular formula Ni(NO,),.4py.2H,0 is formed by the reaction of Ni(NO,),,,q) With excess of pyridine, Select the correct statement about complex:~ (A) It shows geometrical isomerism (B) complex is optically active. (C) Ni? is sp? hybridised. (D) None of the these. ‘The complex K,[Zn(CN),(O,),] is oxidised to K,[Zn(CN),(O,),], then which of the following is correct - (A) Zn (II) is oxidised into Zn(IV) (B) 0-0 bond length decreases (C) Paramagnetic nature decreases (D) Complex becomes diamagnetic Select the correct set of statements for Zeise’s salt (K[PtCl,(C,H,))- (1) The carbon atom exhibit some electrophilic character. (11) C-C bond length in zeise’s salt is shorter than that in C,H, - (111) Coordination number of central metal (IV) Complex is diamagnetic. (A) Land II (B) land IV (©), Mand IV (D) Il and IV Select the correct order for magnitude of A, in complexes which are given with their colour, () (THX),] (Blue) (11) [TI(Y),* (Red) (AMI) [Ti(Z), }** (Yellow) (A) I> > 1 (B) I> > (ule (D> ul Consider following species I. [Fe(en)C1,Br]! IL, [Fe(en),BrCl]"! Il, [Fe(C,0,),F IV. [Fe(H,0), C1,Br] ‘The species in which at least one geometrical isomer is optically active is/are : (A)I, only (B) IL, IV only (C)I, Monly (D) only INORGANIC CHEMISTRY Scanned with CamScannerJEE (Main + Advanced) 2023, REWISION ASSIGNMENT ENTHUSIAST COURSE 7. Arred coloured octahedral complex of Co™ contains NH,,NO; and Cl-ion(s). 4 moles of ions are precipitated on reaction of 1 mole of complex with excess AgNO, solution. This complex is easily decomposed by acids to give nitrous acid (HNO,). The correct formula of complex can be (A) [Co(NH,),CI(NO,), (B) [Co(NH,),(NO,)ICI, (C) [Co(NH,) (ONO)ICI, (D) None of these 8 How many cationic units are present in the complex diammine silver (1) hexacyanoferrate (II) 1 (B)2 (3 (D)4 9. Consider the complex : [Fe(en)(gly)(OH)(NH,)), then the incorrect statement is : (A) Co-ordination number = 6 (B) Oxidation state= +3 (©) Fe -O bonds = 1 (D) Fe—N bonds =4 10. Which of the following pair ofions have same magnetic nature and geometry ? (A) [Ni(CN), >, [Cu(NH,),P* (B) [Ni(NH,),?*, [Mn(CN),]° (©) [CX(H,0),*, [CO(C_0,), (D) [PtCLP’, [Fe(CN),P 11, d-orbitals which are used in hybridisation by central metal in K,[NiF,] are (A) 4d,2,4d, (B) 34,.,34,. , © Med (D) 3434, 12, Which type of isomerism is not exhibited by the complex [Ru(NH, ), (HO) (S,0,)]C1? (A) Ionisation isomerism (B) Linkage isomerism (C) Geometrical isomerism () Optical isomerism 13. A square planar complex [Ma,] (M = central metal, a= monodentate ligand) adds two molecules of water to produce an octahedral complex. The new compound formed : (A) has zero CFSE (B) isa cis isomer (C) isoptically active (D) have centre of symmetry 14. For Mn” ion, the electron pairing energy (P) is 28000 cm''. The splitting energy for complex [Mn(H,0),]°*ion is 15800 em, The crystal field stabilisation energy of complex ion [Mn(H,0),]"* is. (A)-9480 em (B)2720 em" (C)-25, 280m (D) -18, 520 em" 15, Net dipole moment can be non-zero for the species : (A) [Ni(CO),] (B) Trans-[Fe(NH,),Cl,] (© [Pbm),* (NIC? 16, The magnitude of crystal field splitting energy (A) in the complex [Cu(NH, ),]SO, is (A) Less than energy difference between 6s and Sf-orbitals of hydrogen atom. (B) Less than energy difference between Is and 2p-orbitals of hydrogen atom. (C) Equal to energy difference between 2s and 2p-orbitals of hydrogen atom. (D) More than energy difference between 6p and 1s-orbital of hydrogen atom, INORGANIC CHEMISTRY 2 Scanned with CamScannerEos JEE (Main + Advanced) 2023, ALLEN) REWISION ASSIGNMENT ENTHUSIAST COURSE fe 17. The three complex compounds[Ti (H,O),]"", [TiF,]* and [Ti (CN),]*" aborbs light of wavelengths 4000 A, 4920 A and 5900 A. the complexes which absorb light of wavelength 5900 A and 4000 A respectiveely are. (A) [TiF,}° and [Ti(H,0), (B) [TWCN),}* and [TW(H,0), (©) (THF, and [Ti(CN),} (D) [Ti(H,O),}" and [T(CN), 18. Ksf(CN)s Co) —Co(CN)s] © Ks[(CN)s Co (0) —Co(CN)s]. mw In both the complexes Co have t,,°e," configuration. ‘The bond energy of (0 —O) in X and Y is (A) bond energy of (0 — 0) in Y < bond energy of (O— 0) in X. (B) bond energy of (0 — 0) in X < bond energy of (— 0) in Y. (C) bond energy of (O— 0) in X= bond energy of (— 0) in Y. (D) bond energy of (O — 0) in X and bond energy of (O— O) in ¥ can’t be compared 19, If the bidentate ligand ethane 1, 2-diamine (en) is progressively added in green aqueous solution of [Ni(H,0),]CI, in the molar ratios en : Nias, 1: 1,2: 1,3: 1 then their associated colours are respectively (A) Pale blue, violet, blue (B) Violet, pale blue, blue (C) Violet, blue, pale blue (D) Pale blue, blue, violet 20. The enthalpy of hydration of Cr is 460 kcal/mol. In the absence of crystal field stabilisation energy, the value of AH would be ~435 kcal/mol. The value of crystal field splitting energy in complex [Cr(H,O),}* is (A) 41.67 ki/mol (B) 20.83 kJ/mol (C) 175.01 ki/mol (D) 87.49 ki/mol 21, Barium ions, CN ' and Co® form on ionic complex. If this complex is 75% ionised in aqueous solution with van’t Hoff factor, i equal to 4 and magnetic moment is 1.73 BM (due to spin only) then hybridisation state of Co(II) in the complex will be (A) sp'd. (B) dsp? © sp? (D) dsp* 22. On treatment of 100 mL of 0.1 M solution of CoCl, . 6130 with excess AgNO,; 1.2 x 102 ions are precipitated. The complex is :~ (A) (Co(H,0), CIICI.2H,0 (B) [Co(H1,0),C1,].3H,0 (C) [Co(HO),ICl; (D) [Co(H,0),C1C1,.H,0 INORGANIC CHEMISTRY 3 Scanned with CamScannerJEE (Main + Advanced) 2023, REWISION ASSIGNMENT ENTHUSIAST COURSE Multiple Correct Answer Type 23, CoSO,(aq) EEA + B Asc B— 355 no reaction CoSO, (aq) +0, > DS > E Note : for 3d-series element, M"(aq) = [MGH,0),]" Select correct statement(s) : (A)A.C, Eare optically active (B)A & Care stereoisomers (C) Bis diamagnetic while C is paramagnetic. (D) A & B are optical isomers 24, Which of the following are low spin, inner orbital as well as diamagnetic ? (A) [Co(NH,),](NO,), (B)[Cr(en),]Cl, (C)KINIF,) (D) K FeO) OCN)] 25. In which of the following complex(s) spin only magnetic moment is independent , from the nature of ligand. (L = monodented ligand) - (A) [NiL,] (B) [NiL,] © [Fe Ly] (D) [CrL,] 26. Which of the following molecule is/are diamagnetic and non planar (A) [Ni(CN), > (B) MnO, (C) [Cu(NH,), (D) Cro, 27. Assuming formal charge to be the net charge developed after consideration of contribution from ligands and from oxidation state, how many statement(s) is/are correct regarding [Fe(CN), ©? (A) Formal charge on Fe is - 4 (B) Maximum 8 atoms are in single plane (C) Total linkage isomers associated with given formula is 7 (including the given isomer) (D) If 3 CN* ions are replaced by H,O molecules and two CN™ are replaced by NH,, the resultant complex will be optically inactis 28. 0.0012 mole of CrCl, 6H,O was passed through a cation exchange resin and acid obtained from it required 28.5 ml of 0.125 M NaOH for complete neutralisation. Select the incorrect statement(s) about complex: (A) Total four ions are produced by a complex in solution. (B) Complex contains water of crystallisation. (C)AIICT ions satisfy secondary valency of central metal ion. (D) Complex exhibit geometrical isomerism 29, Which ofthe following properties are incorrect regarding the diamagnetic complex with molecula formula Ni(NO,),.4py.2H,O formed by the reaction of ag. Ni(NO,), with the excess of pyridine ? (A) complex exhibits ionisation isomerism. —(B) It isa heteroleptic complex. (C) Itisa 1:2 electrolyte (D) There are two geometrical isomers of it. INORGANIC CHEMISTRY 4 Scanned with CamScannerJEE (Main + Advanced) 2023, REWISION ASSIGNMENT ENTHUSIAST COURSE Bes 30. [M(ONO)(NH,),)* _isared coloured complex. The colour of its linkage isomer can not be (A) yellow (B) violet (©) Blue (D) Orange 31, The energy difference between (4,,.4,.,d,,) orbitals and (4,2_,2.4,:) orbitals in tetrahedral complex is considerably less than that in octahedral field, This is due to — (A) There are only four ligands in tetrahedral instead of six in octahedral (B) The direction of p-orbital lobes coincide with the direction of the ligands. (C) There is high steric repulsion between four ligands approching tetrahedraly towards metal ion, (D) All the lobes of d-orbitals are approching by ligand in octahedral but in tetrahedral half of the lobes of d-orbital. 32, With respect to d? ions Cr0;*, Mn0;°, Fe0;? & RuO;? Select the species with maximum and minimum value of 4, (A) Feo? (B) oro; (©) no; (D) Ru07? 33. Which of the following statement is/are incorrect ~ (A) With dsp} hybridisation [FeCl(CN),(,)]* complex is diamagnetic, (B) [NiCI,P- complex is more stable than [Ni(dmg),] due to higher C.F.S.E. value. (C)[V(CO),] easily reduces to [V(CO),] - (D) Ligand such as CO in [Ni(CO),] acts as x-electron donor due to presence of filled m-molecular orbital 34. The complex Ky) Zn(CN), (Os ] is oxidised into K,|Zn(CN),(O, ), ], then which of the following is/are correct ? (A) Zn (II) is oxidised to Zn (IV) (B) 0-0 bond length decreases. (C) Magnetic moment increases. (D) Megnetic behaviour does not change. 35. Consider the following two carbonyl compounds : (i) [Te(CO),]* and (ii) [Nb(CO),] Select incorrect statement(s) for given carbonyl compounds : (A) [Te(CO),]* acts as reducing agent and [Nb(CO),]- acts as oxidizing agent. (B) [Nb(CO),J- acts as reducing agent and [Te(CO),]* acts as oxidizing agent. (C) “Nb-C” bond order in [Nb(CO),}- is greater than “Te-C” bond order in [Te(CO),}*. (D) “CO” bond order is greater in [Nb(CO),}- than in [Te(CO),]*3. 36. K,[Ni(CN),] —Na> *X” Regarding this reaction correct statement is/are : (A) *X’ is K, [Ni(CN),] (B) The oxidation state of Ni changed +2 to zero. (C) The structure of *X” is tetrahedral (D) [Ni(CN),]* is square planar complex. INORGANIC CHEMISTRY 5 Scanned with CamScanner= ALLEN REVISION ASSIGNMENT © ‘exnwsusrcounse 2028 fe 37. Assuming that the complex Barium dichlorodioxalatocobaltate(III) is water soluble. Select the correct statement(s) for the above complex. (A) Itis diamagnetic. (B) When 1 mole of complex solution is treated with excess of Na,SO,, 2 mole of BaSO, is precipitated. (C) Complex ion is dsp" hybrid. (D) Only one isomer of the complex is optically active. 38. A complex of Ni**, [Ni(PPh,),Br,] is paramagnetic where as [Pd(PPh,),Br,] is diamagnetic. Pick the correct match for two complexes. One of the complexes aborbs blue and other absorbs green coloured radiations in light. INiPPh,),Br,] [Pa(PPh,),Br,] (A) Number of isomer 0 2 (B) Hybridisation sp dsp? (©) Colour Red Orange (D) Degenerate orbitals e 39. Consider the following redox reaction K,[Ni(CN),] —Si> *X°(Ni containing) Regarding thisreactioncorrect statementis/are (Nickel doesnotshow negative oxidationstateinitseyano complexes): (A) °° is a homoleptic complex (B) The oxidation state of Ni is changed. (C) The geometry of complex is different from (D) Ni is d's hybridised in *X”. 40. Assuming formal charge to be the net charge developed after consideration of contribution from ligands and from oxidation state, have many statement(s) is/are correct regarding [Fe(CN),]* ? (A) Formal charge on Fe is 4 (B) Maximum & atoms are in single plane (C) Total linkage isomers associated with given formula is 7 (including the given isomer) (D) If 3 CN" ions are replaced by H,O molecules and two CN ' are replaced by NH,, the resultant complex will be optically inactive. 41. The paramagnetic species are : (A) Co(CO), (B) Cr(NO), (C) Xe[PR,] H[AuCl,] 42. On the basis of crystal field theory, select most stable tetrahedral complex (A) @ (high spin) (B) d*(high spin) (Cd (high spin) (D) d (high spin) INORGANIC CHEMISTRY 6 Scanned with CamScannerEos JEE (Main + Advanced) 2023, ALLEN) REWISION ASSIGNMENT ENTHUSIAST COURSE fe 43. 0.0012 mole of CrCl,6H,0 was passed through a cation exchange resin and acid obtained from it required 28.5 ml of 0.125 M NaOH for complete neutralisation. Select the incorrect statement(s) about complex: (A) Total four ions are produced by a complex in solution. (B) Complex contains water of crystallisation. (C)AIICE ions satisfy secondary valency of central metal ion. (D) Complex exhibit geometrical isomerism. 44, [M(ONO)(NH,),}* is red coloured complex. The colour of its linkage isomer can not be (A) Violet (B) Blue (©) Yellow (D) Orange 45. K, [PtCl,] + 2Kgly > X +4 KCI [Pt (NH,),] (NO,), +2 Kgly > Y +2KNO,, + 4NH,* (Kgly is potassium glycinate.) *X’ is soluble in polar solvent while *Y” is soluble in non-polar solvent Choose the incorrect statement(s) (A) (X) and (Y) are linkage isomers (B) (X) ismirror image of (Y). (©) (X) and (Y) are stereoisomers. (D) All atoms in (X) and (Y) lie in same plane. 46. Ni forms a Red coloured complex with dmg” (dimethylglyoximate ion). Select the correct statements) about [Ni(dmg),] : (A) Itis stabilized by chelation. (B) All atoms lie in same plane. (C) It doesnot exhibit geometrical isomerism. (D) Ithas no electron in 34, ,. orbital according to crystal field theory. 47. Choose the incorrect matches : Complex IUPAC name (A) Xe(PtF,] ‘Xenon({) hexafluoroplatinate(V) (B) Fe{PtCl,] Iron(II)tetrachloroplatinum(1) (©) [Co(NH,),Br],$O, Bis(Bromochloropentaamminecobalt(II1)) sulphate (D) [cucl,}" Dichlorocuprarte(1) 48. Which of the EAN values corresponding to compounds are correct ? (A) Xe[PUF,], 85 (B) Fe(n-C,H,),, 35 (C)V(CO),, 35 (D) Fe(CO),, 36 49. Consider the complexes : (P) : (Cr(H,0),Br,] Cl2H,0 (Q): [Cr(H,0),Cl] Br, HO Select the correct statement(s) (A) 2 grams of (P) prepared in 2L will show lower conductance as compared with 2 grams of (Q) in 2L solution, (B) Q) has more unpaired electrons than that in (P). (C) Q) does not give white ppt on treatment with excess aq. AgNO, (D) Central metal ion is more hydrated in (Q) than that in (P). INORGANIC CHEMISTRY 7 Scanned with CamScanner= ALLEN REVISION ASSIGNMENT © ‘exnwsusrcounse 2028 Bes 50. There exist bond between metal and ligand in (A) [CHCN),P (B) [Cr(CO),] (©) [T(x -C,H),(CO),] (D) [Fe(x-C,H,),] 51. Choose the correct statement(s) for the complex [Mn(NH,), JCI (A) Central metal is not dsp’ hybridised. (B) The value of spin only magnetic moment is. /3 (©) Pairing energy is greater than 4, (D) Itisan outer orbital complex. 52. Consider the octahedral complexes Col, 6NH, + Ptl,4NH, + Ptl, 2Nal + Crl,4NH, @) @ (R) s) Which produces yellow ppt on treatment with excess AgNO ,(aq,) as well as exhibit geometrical isomerism? (AVP (B)Q (OR (D)S 53. Which of the following complex is inner orbital as well as low spin complex ? (A) [Cr(H,0),]C1, (B) K,[Fe(CN),] (C) K[Cu(CN),} (D) [Mn(NH,),]SO, 54, Consider the following splitting diagram of octahedral and tetrahedral complexes referred to a common barycentre: dp dy. y dy de da . Bary centre = dp dap dd, d,, (tetrahedral), (Octahedal) Choose the correct statement(s) if splitting energy in octahedral field is x kJ: 8 (A) Energy gap between Barycentre and triple degenerate orbitals of tetrahedral complex is = (B) Energy gap between triple degenerate orbitals of octahedral and double degenerate of tetrahedral complex is “2x. PIX 45 (C) The ratio of energy of e, orbitals of octahedral with respect to barycentre to energy of t, orbitals of 27 tetrahedral with respect to baryeentre complex is “~ (D) The energy difference between triple degenerate orbitals of octahedral complex and tetrahedral eomplencia 20% complex is 2 55. Select species which are paramagnetic, and inner orbital ? = | - r r (A) | E002), 0 | (B) [Co(NO,), | (©) [Ni(PR,), J (D) [P1(0, )(en), Br INORGANIC CHEMISTRY 8 Scanned with CamScanneros JEE (Man + Révanced) 2023 ALLEN REVISION ASSIGNMENT ENTHUSIAST COURSE 56. Synergic bonding is not responsible for which of the following : (A) Ni(CO), is volatile. (B) Weakening of C ~ C bond in K[PtCl,(x ~ C,H,)} (©) Dimerisation of Co(CO),. (D) Trigonal bipyramidal geometry of Fe(CO),. 57. The correct order(s) of stability of complexes is/are : (A) [Cd(NH,Me), }** < [Cd(en),?* (B) K,[Ni(CN),] > K,[Ni(CN),) (©) [NiF, > [NiF,- (D) [CuCl > [ZncL- 58. Which of the following complexes have two stereoisomers irrespective of geometry of the complex ? (4) [M@ly).} (B)[MC,0,),] (©) [M(NH,)(py)C1Br] (D) [M(CN),} 59. Which of the following is/are correct representation of Co(III) complex(es) having Co(II), F_and NH, in 1:3: 3 ratio (A) [Co(NH,),F,] (B) [Co(NH,) F][CoF (NH,)} (C) [Co(NH,),F,][CoF (NH,),] (D) [Co(NH,),F],[CoF,], 60. Ifcrystal field splitting energies in tetrahedral octahedral, square planar and cubic fields are denoted by Ay Ag, A, and A. Then which of the following relation is/are correct ? (Assume the central metal and ligands to be the same for all fields) (A) S0= (B) Ao =1.7Asy (©) 4c = 2 (D) A, = 0.264, a 61. Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCI, . 6H,O (X) and NH,CI gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1:3 electrolyte. The reaction of X with excess HC! at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y. Among the following options, which statements is(are) correct ? (A) The hybridization of the central metal ion in Y is d’sp* (B) Z is tetrahedral complex (C) Addition of silver nitrate to Y gives only two equivalents of silver chloride (D) When X and Z are in equilibrium at 0°C, the colour of the solution is pink Linked Comprehension Type Paragraph for Question no. 62 to 63 Consider a metal ion surrounded by cubic field of ligands. Ligands are present at each comer of cube which has the cartesian axes going through the centers of the cube face. 62. Ionswith how many d-electrons would give the greatest crystal field stabilisation energy in such a cubic strong field ? (ay (B)s 6 (D)7 63. Crystal field splitting energy for an octahedral complex of M'? is x kJ. What will be approximate crystal field splitting energy for cubic complex of M? (A) 0.59 x (B) 1.125 x (C) 0.89 x. (D) 0.44x INORGANIC CHEMISTRY 9 Scanned with CamScannerJEE (Main + Advanced) 2023, REWISION ASSIGNMENT ENTHUSIAST COURSE 65. 66. 67. 68. 69, 70. n. 72. 2B. 4. Paragraph for Questions 64 and 65 EAN rule in complexes is similar to octet rule, The central atom satisfies EAN rule if EAN is equal to atomic number of just higher noble gas. Stable carbonyl complexes of transition metals generally satisfy EAN rule, The value of x in H,[Mn(CO),] is (A)2 (B)3 ©l (D4 ‘The oxidation state of Cr in [P(NH,),] [Cr(CN),0,(OH),], is : (3 (B)+2 (+6 (D)+7 Paragraph for Question no, 66 to 67 Magnetic moment, ionic conductance are useful in deciding structure/constitution ofa given complex compound ‘The cyano complex that exhibit highest value of paramagnetism is (A) [Cr(N), (B) [Co(CN), (©)[Fe(CN),P (©) [Mn(CN),} ‘Which complex is the most conducti in aq. solution among gi (consider equimolar solution) ? (A) Potassium diamminetetranitritocobaltate(II1) (B) Triamminetrinitrochromium(ID) (C) Pentaamminenitrochromium( III) hexanitrocobaltate(II1) (D) Magnesium amminepentanitrochromium(IIl) Numerical Answer Type Total how many structural isomers are there for the complex having molecular formula Co(NH,),(CO,)C1.2H, 0 (do not consider non-ionic complexes in counting) K[Zn(CN),(O, sed into K,[Zn(CN),(,),] « The change in O-O bond order = The change in number of unpaired electrons in overall process = y The value of (2x+y) is ..... How many of the following does react with excess of ethylenediamine (en)? [Co(NH,),JCI, , [Co(NH,), Cl] (no centre of symmetry),{Co(en), CL,]'(have centre of symmetry), Fac-[Cr(NH,),CI,}, Mer-[Cr(NH,),C1,] ‘What is the difference in the number of coordination isomer(s) of Pt(en), PCI, and P(NH,), . PAC, ? The sum of total number of ions in hydrate isomers of CrCl, .6H,O , which exhibit electrical conductance is: If number of t,, and e, electrons are 6 and 0 respectively in hexa aqua complex of 3d series metal ion M®, find group number of metal M in long form of periodic table Find the value of n for diamagnetic complex [Fe(en),], (Co(NH,),(NO,),]} INORGANIC CHEMISTRY 10 Scanned with CamScanner= ALLEN REVISION ASSIGNMENT © ‘exnwsusrcounse 2028 Bes 75. The enthalpy of hydration of Fe” ion is 11.2 keal/mol higher than would be expected if there were no crystal field stabilisation energy. Assuming aquo complex to be high spin, the estimated value of magnitude of crystal field splitting energy for [Fe (H,O),]"? is 7x kcal/mol. The value of x is. 76. How many isomers are there for the complex [Pt(CO),(PPh,)3] ? 77. Inthe crystal field of the complex K,[Fe(C1(CN),(O,)], the electronic configuration of central metal ion is found to be t,,°, e,”. How many unpaired electrons are there in a molecule of it? 78. Total number of structural and geometrical isomers of complex formed by a PE with one Cl-, one NO, , one NO, and one “SCN is x. The value of (x-5) 79. If Hund’s rule is violated, how many unpaired electrons are present in [er(NH), J” complex ion? 80. How many optically active isomers are there for complex [Pt (NH,CH(C,H,)CH(C,HNH,} {NH,C(CH,),CH,NH,}] 2 81. Ifhund’s role is violated, then how many unpaired electrons are present in a [Cr(NH,),}" ion? 82. How many isomers are there for the complex [Pt(CO),(PPh,),] ? 83. If Hund’s rule is violated, how many unpaired electrons are present in [Cr(NH,), |" complex ion? 84. Consider the complex : [Cu(CN),]* (i) Let the number of atoms lying in same pla (ii) Let the number of electrons in lowest energy degenerate set be y. (iii) Let the number of axial orbitals involved in hybridisation of central metal ion be z Find |x —2y + z| 85. Consider following complexes [Mg(EDTA)]}* [Fe(ox), > [Fe(H,0),]"* [FeC!,(H,0), },[Fe(H,0),Cl,Br] Let the complexes which show only geometrical isomerism = x Let the complexes which show only optical isomerism = y Find the value of 2x~y INORGANIC CHEMISTRY 11 Scanned with CamScannerJEE (Main + Advanced) 2023, REWISION ASSIGNMENT ENTHUSIAST COURSE ANSWER KEY (Ay 2 () 3 B) 4B) 5. (A) 6 (D) © 8 (D) © 10. (B) Me (A) 12, (D) )) 14. (A) 15, ©) 16. (B) 12 © 18. (B) 19. (D) 20. (©) 21. (D) 22. (D) 23. (AYO) 24. (AYO) 25. (B,D) 26. (B,D) 27. (AOD) 28. (BCD) 29. (A(BY(D) 30. (BYO) 31. (A) 32. (BD) 33. (A(B)(D) 34. (BYOD) 35. (ABD) 36. (ABYC) 37. (AC) 38. (ABYC) 39. (ABYC) 40. (ACD) 41. (AYO) 4. (A) 43. (BCD) 44. (A,B) 45. (A(B)(D) 46. (ACD) 47. (BYCD) 48. (AYC\(D) 49. (ACD) 50. (BD) SI. (AY(C)(D)_ 52. (BD) 53. (B) 54. ACD 55. (BD 56. (ACD) 57. (ACD) 58. (AB) 59. (A(BXCKD) 60. (ACD) 61. (A,B,D) 62. (A) 63. (C) 64. ©) 65. (©) 66. (A) 67. (©) 68. 4 0. 3 0. 4 7 2 ™m 9 7. 9 7. | 15. 4 16. 0 7 1 7% 7 m1 80. 4 81.1 82. 0 83. 1 84. 0 85: 2 INORGANIC CHEMISTRY 12 Scanned with CamScanner