SAFETY DATA SHEET

According to Canadian Hazardous Products Regulations (HPR) (SOR/2015/17)

SECTION #1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: HTDS 750

OTHER MEANS OF IDENTIFICATION: NAPHTHENIC OIL

RECOMMENDED USE: Process Oil and Compounding Oil

MANUFACTURER/SUPPLIER’S NAME: TOTAL CANADA INC.

220, LAFLEUR
LASALLE, QUEBEC
H8R 4C9
Tel.: (514) 595-7579 or 1-800-463-3955

24 HOURS EMERGENCY: Call CHEMTREC 1-800-424-9300 or 703-527-3887

SECTION #2 HAZARDS IDENTIFICATION

WHMIS CLASS AND DESCRIPTION - According to Hazardous Products Regulations (HPR) (SOR/2015/17)

This product is not regulated by the WHMIS.

EMERGENCY OVERVIEW: Repeated exposure may cause skin dryness.

ROUTES OF ENTRY: Dermal contacts, Eye contact, Inhalation and Ingestion

POTENTIAL ACUTE HEALTH EFFECTS:

INHALATION: Prolonged exposure to high vapor concentration of this product can cause headache,
dizziness and nausea. Short-term overexposure can cause an irritation to the
respiratory passages.
3
Exposure limit to the mist = 5 mg/m (TLV/TWA, ACGIH).

CONTACT WITH EYES: This product may cause eye irritation. Prolonged contact with the product may cause
irritation.

SKIN CONTACT: This product should not cause skin irritation. Prolonged and repeated contact with
this product can cause skin drying.

INGESTION: May cause nausea. Do not induce vomiting.

CARCINOGENICITY Meets requirement of less than 3% (w/w) for total polycyclic aromatic compound
(PAC) using IP 346.

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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OTHER EFFECTS: None expected to cause any significant helth effect under normal conditions of use.
Not MUTAGENIC, GENOTOXIC or SENSITIZING for animals and humans.

SEE TOXICOLOGICAL INFORMATION (SECTION 11)

SECTION #3 COMPOSITION/INFORMATION ON INGREDIENTS

According to Hazardous Products Regulations (HPR) (SOR/2015/17)

NAME % weight CAS #

Severely Hydrotreated Naphthenic Petroleum Oil 100 64742-52-5

• No hazardous ingredients as defined by the Canadian Hazardous Products Act (BILL C70) or by OSHA 29
CFR 1910.1200.
• Canadian DSL status: All ingredients are listed.
• No components of this product have been found carcinogenic or potential carcinogen. Does not contain
ingredients that are listed as carcinogenic or potential carcinogen by OSHA, IARC or the U.S. National
Toxicology Program (NTP). This product or its components have no teratogenic or mutagenic effects known.

SECTION #4 FIRST AID MEASURES

GENERAL ADVICE: IN CASE OF SERIOUS OR ANY PERSISTENT CONDITIONS, CALL A

DOCTOR OR EMERGENCY CARE. Show this material safety data sheet to
the medical personel in attendance.

INHALATION: Remove person to fresh air. See a physician if irritation persists.

CONTACT WITH EYES: Flush immediately with water for at least 15 minutes.

CONTACT WITH SKIN: Wash contaminated skin with mild soap and water. See a physician if irritation
persists.

INGESTION: This product has a low toxicity. May cause nausea and have a laxative effect.
Do not induce vomiting. Contact an Anti-Poison Center (1-800-463-5060).

PROTECTION OF FIRST-AIDERS: Do not use mouth to mouth if the victim has ingested or inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-
way valve or other proper respiratory medical advice. Use personal protective
equipment.

NOTE TO PHYSICIAN: Treat symptomatically.

24 HOURS EMERGENCY: Call CHEMTREC 1-800-424-9300 or 703-527-3887

SECTION #5 FIRE FIGHTING MEASURES

FLASH POINT (COC): ≥200°C

AUTOIGNITION TEMPERATURE (°C): ≥315°C

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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SUITABLE EXTINGUISHING MEDIA: Foam, Dry chemical CO2 and water spray.

UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER
AND SPREAD THE FIRE.

HAZARDOUS COMBUSTION PRODUCTS: Normal combustion products, CO and CO2.

SPECIAL FIRE FIGHTING PROCEDURES: Do not enter confined fire space without adequate protective clothing
and an approved positive self-contained breathing apparatus. Use
water to cool fire exposed containers.

SECTION #6 ACCIDENTAL RELEASE MEASURES

SPILL AND LEAK PROCEDURES:

Except in case of small spillages. The feasibility of any actions should always be assessed and advised, if possible,
by a trained, competent person in charge of managing the emergency.
If required, notify relevant authorities according to all applicable regulations.
Evacuate non-essential personnel. For personal protection see section 8.
Stop or contain leak at the source, if safe to do so.
In case of large spillages, alert occupants in downwind areas.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

ADVICE FOR NON-EMERGENCY PERSONNEL:

Do not touch or walk through spilled material.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

ADVICE FOR EMERGENCY PERSONNEL:

Take all appropriate steps to avoid fire, explosion and inhalation hazards to the rescuers including the use of
breathing apparatus.
In case of small spillages: normal working clothes are usually adequate.
Large spillages: Chemical resistant clothing, apron. Work gloves (preferably gauntlets) providing adequate chemical
resistance. Remarks: Gloves made of PVA are not water-resistant, and are not suitable for emergency use. Work
helmet, safety shoes or boots. Goggles and/or face shield, if splashes or contact with eyes is possible or anticipated.
Respiratory protection not normally required in normal conditions. A half or full-face respirator with filter(s) for organic
vapors (and when applicable: for H2S would be recommended otherwise. A Self-Contained Breathing Apparatus
(SCBA) can be used according to the extent oxygen deficiency is possible

ENVIRONMENTAL PRECAUTIONS:
Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages
cannot be contained. The product should not be allowed to enter drains, water courses or the soil.

METHODS AND MATERIALS FOR CONTAINEMENT AND CLEANING UP:

Dam up. Ground and bond containers when transferring material. Keep in suitable, closed containers for disposal.
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national regulations (see section 13).
Use clean non-sparking tools to collect absorbed material.

SECTION #7 HANDLING AND STORAGE

STORAGE AND HANDLING: Use approprite equipment (refer to section 8) whenever manipulating this
product. Keep container in a cool and well-ventilated area. Do not enter storage
areas and confined spaces unless adequately ventilated.
Keep container tightly closed and sealed until ready for use.

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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 Store and use away from heat, sparks, open flame or any other ignition source

SECTION #8 EXPOSURE CONTROLS / PERSONAL PROTECTION

3
EXPOSUTE LIMITS: OSHA (PEL) TWA 5 mg/m ,
3
Mineral oil mist: NIOSH (REL) TWA 5 mg/m ,
3
STEL 10 mg/m

VENTILATION: Mechanical ventilation is recommended.

RESPIRATORY PROTECTION: If mist present, chemical cartridge respirator is recommended.

GLOVES: Resistant gloves (Viton, Nitrile, Neoprene) are recommended when

handling this material.

EYE PROTECTION: Chemical safety goggles are recommended.

BODY: Flame retardant clothing is required.

OTHER PROTECTION: In confined spaces or where the risk of skin exposure is higher, resistant
clothing or apron should be worn. Security boots.

SECTION #9 PHYSICAL DATA

PHYSICAL STATE AT 25°C liquid

APPEARANCE AND ODOR: Yellowish to amber with light petroleum odor
INITIAL BOILING POINT: ≥300°C
POUR POINT: -18°C
EVAPORATION RATE: Negligible
LOWER FLAMMABILITY LIMITS: N/A
UPPER FLAMMABILITY LIMITS: N/A
3
DENSITY (g/cm at 15°C): 0.91 to 0.93
VAPOR PRESSURE (mm Hg at 20°C): Negligible
VISCOSITY (cSt at 40°C): 144
EVAPORATION RATE: Negligible
SOLUBILITY IN WATER: Insoluble

SECTION #10 STABILITY AND REACTIVITY

STABILITY: Stable
POSSIBILITY OF HAZARDOUS REACTIONS: None under normal processing
CONDITIONS TO AVOID: Avoid excessive heat, open flames and formation of oil
mist.
INCOMPATIBLE MATERIALS: Oxidants like liquid chlorine, concentrated oxygen, sodium
hypochlorite, calcium hypochlorite.
HAZARDOUS DECOMPOSITION PRODUCTS: CO and normal combustion products.
POLYMERIZATION: Will not occur

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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SECTION #11 TOXICOLOGICAL INFORMATION

SPECIES LD50 ORAL LD50 DERMAL LC50 INHALATION HRS

Rat > 5000 mg/Kg > 2000 mg/Kg N/A ---

CHRONIC EFFECTS ON HUMANS:

Minimally toxic, Negligible hazard at ambient/normal temperature. This product should not be harmful through
inhalation. Prolonged exposure to high vapor concentration of this product can cause headache, dizziness and
nausea and in the case of hot mist, it can cause an irritation to the respiratory passages

CARCINOGENIC EFFECTS:
Does not contain ingredients that are listed as carcinogenic or potential carcinogen by OSHA, IARC or the U.S.
National Toxicology Program (NTP). Meets requirement of less than 3% (w/w) for total polycyclic aromatic compound
(PAC) using IP 346.

TERATOGENICITY/MUTAGENICITY:
This product has no teratogenic or mutagenic effects known.

OTHER TOXIC EFFECTS ON HUMANS:

Repeated exposure may cause skin dryness and cracking.

SECTION #12 ECOLOGICAL INFORMATION

ENVIRONMENTAL EFFECTS:

Do not allow product or runoff from fire control to enter storm or sanitary sewers, lakes, rivers, streams, or public
waterways. Block off drains and ditches. Provincial regulations require and federal regulations may require that
environmental and/or other agencies be notified of a spill incident. Spill area must be cleaned and restored to original
condition or to the satisfaction of authorities.

BIODEGRADABILITY: NOT READILY BIODEGRADABLE.

SECTION #13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODS: Consult relevant local authorities. Reclaim or dispose of at a licensed waste
disposal company. Incinerate with approval of appropriate local authority.

SECTION #14 TRANSPORTATION INFORMATION

TRANSPORTATION in CANADA (TDG)

not regulated; thiese products are not considered a dangerous good

TDG PROPER SHIPPING NAME Not a TDG Regulated Material

TDG HAZARD CLASS Not Regulated
PACKING GROUP Not Regulated
TDG I.D. NUMBER/ UN NUMBER Not Regulated
DOT (USA) Not Regulated

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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 IMO/IMDG Not Regulated
IATA Not Regulated
ADR Not Regulated
RID Not Regulated

SECTION #15 REGULATORY INFORMATION

This product has been classified in accordance with the hazard criteria of the Hazardous Products Regulations (HPR)
(SOR/2015/17) and the Safety Data Sheet (SDS) contains all the information required by the HPR.

THIS PRODUCT IS NOT A WHMIS CONTROLLED SUBSTANCE.

DSL/NDSL Status: This product, or all components, are listed on the Domestic Substances List, as required under
the Canadian Environmental Protection Act. This product and/or all components are listed on the U.S. EPA TSCA
Inventory.

Other Regulatory Status: No Canadian federal standard; however, for general discharge guidance, federal
installations limited to 15 mg/L for total oil and grease. Provincial criteria are likely and should be requested when
notifying provincial authorities.

INTERNATIONAL REGULATIONS:
U.S. Federal Regulations:
TSCA 8(b) inventory: All components are listed.
SARA 302/304/311/312 extremely hazardous substances:
To the best of our knowledge, there are no substances that would be at reportable levels for this regulation in this
product.
SARA 302/304 emergency planning and notification:
To the best of our knowledge, there are no substances that would be at reportable levels for this regulation in this
product.
SARA 302/304/311/312 hazardous chemicals:
Distillates (petroleum), hydrotreated light
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Distillates (petroleum), hydrotreated light: Delayed (chronic) health hazard
SARA 313
This product contains no chemicals in excess of the applicable minimum concentration that are subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and
40 CFR Part 372 (Table 372.65).

Clean Water Act (CWA) 307: To the best of our knowledge, there are no substances that would be at reportable
levels for this regulation in this product.
Clean Water Act (CWA) 311: To the best of our knowledge, there are no substances that would be at reportable
levels for this regulation in this product.
Clean Air Act (CAA) 112 accidental release prevention: To the best of our knowledge, there are no substances that
would be at reportable levels for this regulation in this product.
Clean Air Act (CAA) 112 regulated flammable substances: To the best of our knowledge, there are no substances
that would be at reportable levels for this regulation in this product.
Clean Air Act (CAA) 112 regulated toxic substances: To the best of our knowledge, there are no substances that
would be at reportable levels for this regulation in this product.

STATES REGULATIONS:
To the best of our knowledge, there are no substances that would be at reportable levels for this regulation in this
product.

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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California Proposition 65: To the best of our knowledge, there are no Proposition 65 chemicals present in this product
at levels that would require warning under the California Safe Drinking Water and Toxic Enforcement Act.

OTHER INTERNATIONAL LISTS:

Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
EUROPE (EINECS/ELINCS/NLP): This material is listed or exempted.
Japan inventory: Not determined.
Korea inventory (KECL): This material is listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.

SECTION #16 ADDITIONAL INFORMATION

Label requirements: None (based on WHMIS)

Other Hazardous System Classification: According to the NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
and Hazardous Materials Identification System (HMIS, USA):

NFPA HMIS
0 HEALTH 0 NO SIGNIFICANT RISK
1 FLAMMABILITY 1 PRESENT A WEAK RISK
0 RÉACTIVITY 0 NO SIGNIFICANT RISK
INDIVIDUAL PROTECTION B Eye protection and gloves are recommended

Prepared by:André St-Jean, Chemist

Revised on: May 27 2017, by Maria Cristina Martinez
We believe that technical information and recommendations contained herein to be reliable and accurate. However,
we provide these data without warranty or guarantee of any kind, expressed or implied. We assume no responsibility
for any loss, damage, or expense, direct or consequential, arising from the use of products described herein.

TOTAL CANADA INC 220 AVENUE LAFLEUR, LASALLE QC H8R 4C TEL: 514-595-7579 1-800-463-3955 FAX: 514-367-5767

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