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Atomic Structure - Objective

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Atomic Structure - Objective

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Saamarth Sehgal
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02. Structure of atom (1,)Which diagram best represents the appearance ofthe line spectrum of atomic hydrogen in the visible region? erasing wavelength () | el a LT (2.)The observation that the ground state of nitrogen atom has 3 unpaired electrons in its electronic configuration and not otherwise is associated with (c.) Pauli’s exclusion principle (b.) Hund’s rule of maximum multiplicity (c.] Heisenberg’s uncertainty relation (d) Ritz combination principle (3.) What is the maximum number of electrons in an atom that can have the following quantum numbers n=4,m,= +1? (a)4 (b) 15 (c)3 (6 (4.)lonisation energy of He* is 19.6x 107) atom”. The energy of the first stationary state (n = 1) of Li?* is (a.) 4.41 x 10774 atom-* (b.) -4.41 x 10-77] atom-? (c) -22 x 10-*5} atom™ (a) 882 x 10-17} atom? (5.)The electrons, identified by quantum number nandl, can be placed in order of increasing energy, as (a) I Ey > Ey (C.) Eq > Ey > Ee (d) E, > Ey > Ey (8.)The scientist who proposed the atomic model based on the quantization of energy for the first time is (a.) Max Planck (b) Niels Bohr (c) De-Broglie (d) Heisenberg (9.) The number of waves in an orbit are (a)n? (b)n {c)n-1 (d)n-2 (20.)The maximum number of electron in p-orbital with n = 5,m = 1is (a)6 (b)2 (c.) 14 (a) 10 (11.)Which of the following has the maximum number of unpaired electrons? (a.) Mg’* (b) THY (c.) Fe** (a) v* (12.)For an electron in a hydrogen atom, the wave function ¥ is proportional to exp‘/*° , where dg is, the Bohr’s radius. What is the ratio of the probability of finding the electron at the nucleus to the probability of finding it at ao? (aye (b) e (1 (a) Zero (23,)Particle nature of electron was experimentally demonstrated by (a) Max Bon (b,) J.) Thomson (c.) De-Broglie (a) Schrondinger (14.)Which has the highest e/m ratio? (a) He?* (b) Ht (c.) He* (a) Dt (15.)Bohr’s theory is applicable to (a) He (b) Lit (c.) He** (d.) None of these (16.) Which of the following radial distribution graphs correspond ton = 3,1 = 2 for an atom? Py? 3) a Py i (b) a et " (c) eb ry \ (a) “a (17,)Energy of H-atom in the ground state is -13.6 eV, hence energy in the second excited state is, (2) -6.8 ev (b.) -34eV (c)-151ev (@) -453ev (18) Which is not in accordance to aufbau principle? 2p ) LTT (a) o Gana (c) i ara (19.)The velocity of electron in first orbit of H-atoms ‘as compared to the velocity of light is 1 (a) ws th (b) Bath (dag th (a) Same (20.)Blectron behaves both as a particle and a wave. ‘This was proposed by (a.) Heisenberg (b) Gilbert N. Lewis (c.) de-Broglie (d) L. Rutherford (21.)Rutherford's experiment on the scattering of a —particles showed for the first time that the atom has (a.) Electrons (b, Protons (c.) Nucleus (d) Neutrons (22.)The velocity of an electron placed in 3rd or! of H atom, will be (a) 2.79 x 107 em/s (b) 9.27 x 107 cm/s (c.)7.29 x 10 em/s (a) 92.7 x 107 cm/s (23.)The number of photons emitted per second by 60 W source of monochromatic light of wavelength 663 nm is (h = 6.63 x 10~** Js) (a) 4x 10- (b) 1.54 x 107° (c.) 3x 10-0 (a) 2 x 102° (24.)Consider the following statements : Electron density in xy plane in 3d,2_y2 orbital is zero 2Electron density in xy plane in 3d, orbital is zero 3.2s orbital has only one spherical node 4For 2p; orbital yz is the nodal plane The correct statements are (a) Zand 3 (b) 1,2,3,4 (c.) Only 2 (d) Land 3 (25.)The number of spectral lines that can be possible when electrons in 7th shell in different hydrogen atoms return to the 2nd shell, is (a) 12 (b) 15 (c) 14 (a) 10 (26.)Which one of the following set of quantum numbers is not possible for electron in the ground state of an atom with atomic number 19? (a)n=2,1=0,m=0 (b)n=2,1=1m=0 ()n=3, (@n= (27,)The uncertainity in position for a dust particle (m= 10-™ g;; diameter = 10~* cm and velocity = 107* cm/s) will be (The error in measurement of velocity is 1%) (2) 5.27 x 10-* cm (b) 5.27 x 10-5 cm (c.) 5.27 x 10- em (a) 5.27 x 10-7 cm (28 Rutherford scattering formula fails for very small scattering angles because (a.) The kinetic energy of a- particles is larger (b) The gold foil is very thin (c.) The full nuclear charge of the target atom is partially screened by its electron (@) All of the above (29.)Number of neutron in C’? is (a)6 (b)7 (c)8 @eo (30.) What accelerating potential is needed to produce an electron beam with an effective wavelength of 0.090A7 (2,) 1.86 x 104eV (b) 186 x 10%ev (c.) 2.86 x 10%eV (d) 2.86 x 10%ev (31.)Dual nature of particles was proposed by (a) Heisenberg (b) Lowry (c.) de-Broglie (@) Schrodinger (32,)The principal quantum number of H-atom orbital, ifthe electron energy is ~3.4 eV, will be (a) (b)2 ()3 (a) Zero (33,)The Bohr's orbit radius for the hydrogen atom (n = 1) is approximately 0.53A. The radius for the first excited state (n = 2) orbit is (a) 027A (b) 127A (c) 212A (a) 3.12A (34)[Ar]3d?®, 4s* electronic configuration belongs to (a) Ti ()T (c.) Cu @vV (35) Which combinations of quantum numbers n,1,mand s for the electron in an atom does not provide a permissible solution of the wave equation? (a) 3,212 (b) 3,11 (3.3.1 (a) 3,2,-2 (36.)The correct set of quantum numbers (n, and m respectively) for the unpaired electron of chlorine atom is (2)2,1,0 (0) 2,11 (c)3,11 (4) 3,2,1 (37,)The highest number of unpaired electrons are in (a) Fe (b) Fe’ (c) Fe** (d.) All have equal number of unpaired electrons (38,)The energy of an electron in first Bohr orbit of H-atom is ~13. 6 eV. The possible energy value of electron in the excited state of Li?* is (a) 122.4 eV (b) 30.6 eV (c.) 30.6 eV (a) 13.6 eV (39.)The energy of a photon is 3 x 10~ ergs. What is its wavelength in nm? (h = 6.62 x 10-?7ergs, (2) 662 (b) 1324 (c) 66.2 (a) 6.62, (40.)Which of the following particles moving with same velocity would be associated with smaller de- Broglie wavelength? (a) Helium molecule (b) Oxygen molecule (c) Hydrogen molecule (d) Carbon molecule (41,)Einstein’s photoelectric equation states that E, =hv-W Here, Ex refers to (a.) Kinetic energy of all ejected electrons (b) Mean kinetic energy of emitted electrons (c) Minimum kinetic energy of emitted electrons (d.) Maximum kinetic energy of emitted electrons (42,)The charge on an electron was discovered by (a) JJ. Thomson (b) Neil Bohr =3 x 10'cm/s) (c.) James Chadwick (@) Mullikan (43.)Zeeman effect refers to the (a.) Splitting up of the lines in an emission spectrum in the presence of an external electrostatic field (b) Random scattering of light by colloidal particles (c.) Splitting up of the lines in an emission spectrum in a magnetic field (@) Emission of electrons from metals when light falls upon them (44,)The electron configuration of the oxide ion is much most similar to the electron configuration of the (2) Sulphide ion (b) Nitride ion (c.) Oxygen atom (@) Nitrogen atom (45.) Which of the following statements does not form a part of Bohr’s model of hydrogen atom? (a.) Energy of the electrons in the orbit is quantised (b.) The electron in the orbit nearest the nucleus has the lowest energy (c.) Electrons revolve in different orbits around the nucleus (d.) The position and velocity of the electrons in the orbit cannot be determined simultaneously (46)Ifn = 3,1 = 0 and m = 0, then atomic number is (a) 12 or 13 (b) 13 or 14 (c) 10 or 11 (d) 11 or 12 (47,)The H atom electron dropped from n = 3 ton = 2, then energy emitted is (2) 19 eV (b) 12 eV (c.) 10.2 ev (a) 0.65 eV (48,)The wave nature of electron is verified by (2. De-Broglie (b) Davison and Germer (c.) Rutherford (d) Allof these (49,)Electronic configuration of deuterium atom is, (a) 1st (b) 2s? (c) 2st (a) 1s? (50.) What is the minimum energy that photons must posses in order to produce photoelectric effect with platinum metal? The threshold frequency for platinum is 1.3x 10"Ss~ (2) 36 x 10-Serg (b) 8.2x 10-erg {c) 82x 10-erg (a) 86x 107 erg (51)Ifr is the radius of first orbit, the radius of n‘* orbit of the H atom will be (a.) rn? (b) rm he (a) r?n2 (52)If the electron of a hydrogen atom is present in the first orbit, the total energy of the electron is (53.)Which of the following is related with both wave nature and particle nature? {a.) Interference (b.) E = me? (c.) Diffraction (4) E=hv (54.)The electronic transitions from n=2 ton=1 will produce shortest wavelength in (where n=principle quantum state) (a.) Lit (b.) He* (c)H (a) Ht (55.)The energy of second Bohr orbit of the hydrogen atom is ~328 kj molt ; hence the energy of fourth Bohr orbit would be (a) 41k) mol (b.) -1312 kj mol~ (c.) -164 kj mol? (a) -82 kj mol“? (56.)An electron beam is accelerated through a potential difference of 10,000 volt. The de-Broglie wavelength of the electron beam is (a.) 0.123 A° (b.) 0.356 A° (c.) 0.186 A° (a. 0.258 A° (57,)The ground state term symbol for an electronic state is governed by (a.) Heisenberg’s principle (b.) Hund’s rule (c.) Aufbau principle (d) Pauli exclusion principle (58,)In a set of degenerate orbitals, the electrons distribute themselves to retain like spins as far as possible. This statement belongs to (a.) Pauli’s exclusion principle (b) Aufbau principle (c.) Hund’s rule of maximum multiplicity (qd) Slater's rule (59.)Aufbau principle does not give the correct arrangement of filling up of atomic orbital’s in (2) Cuand Zn (.) Coand Zn (c.) Mnand Cr (a) Cuand Cr (60.)Compared to the mass of lightest nuclei, the mass of an electron is only (app.) (a.) 1/80 (b,) 1/800 (c) 1/1800 (a) 1/2800 (61,)According to Bohr’s model of hydrogen atom (2.) Total energy of the electron is quantized (b.) Angular momentum of electron is quantised (c.) Both (a) and (b) (d.) None of the above (62,)Heisenberg’s uncertainty principle has no significance for a moving (a.) Proton (b.) Neutron (c.) Electron (@,) Cricket ball (63,)If the quantum number for the 5* electron in carbon atoms are 2,1,1,+1/2, then for the 6th electron, these values would be (2.)2,1,0,-3 (b) 2,0,1,4+4 2 ()2L1-5 (@)2,1,-1,4 =} (64.)A particle A moving with a certain velocity has the de-Broglie wavelength of 1 A®. For particle B with mass 25% of A and velocity 75% of A, calculate the de-Broglie wavelength (a.)3A° (b.) 5.33 AP (c.) 6.88 A° (d) 0.48 Ae (65.)Which of the following statements is incorrect? (a.) The charge on electron and proton are equal and opposite (b.) Neutrons have no charge (c.) The mass of proton and electron are nearly the same (@.) None of the above (66.)A p-orbital in a given shell can accommodate upto (2.) Four electrons (.) Two electrons with parallel spin (c.) Six electrons (d.) Two electrons with opposite spin (67,)Four different sets of quantum numbers for 4 electrons are given below 1 1 782 =31L1-5 @= 32,2430 =3, 00,45 The order of energy of e;,€2,¢3 and e, is (a) e1 > €2 > ea > e4 (b) e,>e,>e,>¢ (c.)es > e1 > ez > e (de > es > ey > er (68.)Ca? is isoelectronic with (a) Na (b) Ar (c.) Mg? (a) kr (69.)The number of unpaired electrons in Fe*tion is (a)3 b)1 (c)5 (ay2 (70.)The magnitude of the spin angular momentum ofan electron is given by (a s=seDS e, = 4,0,0, (b)S=sk (pS =3x% (d.) None of these (71,)The two electrons ins K-sub shell will differ in (a.) Principal quantum number (b) Azimuthal quantum number (c.) Magnetic quantum number (@) Spin quantum number (72)A heavy element has atomic number X and mass number ¥. Correct relationship between X and ¥ is (a)X ¥ yx Y (yx ¥ (4. xX ZY)? (73) Time period of a wave is 5 x 1078s, what is the frequency? (a) 5x 10-8s-? (b.) 2x 10?s~* (c.) 23 x 103s (a) 5 x 102s"? (74)lf the kinetic energy of an electron is increased four times, the wavelength of the de-Broglie wave associated with it would becomes (a) Half times (b) Stimes (c.) Four times (a) Two times (75,)The radius of hydrogen atom in the ground. state is 0.53A. The radius of Li2* ion (atomic number =3) in a similar state is (2)0.1764 (b) 030A (c) 053A (a) 123A (76.)Uncertainty in position of a particle of 25 g in space is 10~5m. Hence, uncertainty in velocity (ms™*) is (Planck’s constant h = 6.6 x 10734Js) {a.) 2.1 x 10-78 (b) 2.1 x 10" (c.) 0.5 x 10-% (a) 5.0 x 10-%* (77 )Isoelectronic pair among the following is (a.) Caand K (b) Arand Ca®* (c.) Kand Ca?* (d) Arand K (78.)The uncertainties in the velocities of two particles A and B are 0.05 and 0.02 ms" respecively. The mass of B is five times to that of mass A. What is the ratio of uncertainties (34) in a jons? (b) 0.25 (c)4 (a1 (79.)Which transition in the hydrogen atomic spectrum will have the same wavelength as the transition, n=4 to n=2 of Het spectrum? (an (b)n (c)n (d)n=2to (80,)The quantum numbers + and ~ for an electron represent (a.) Rotation of electron in clockwise and anticlockwise direction respectively (>) Rotation of electron in anticlockwise and clockwise direction respectively (c.) Magnetic moment of electron pointing up and down respectively (a) Two quantum mechanical spin states which have no classical analogue (81.)An electron jumps from an outer orbit to an inner orbit with an energy difference of 3.0eV. What will be the wavelength of the line emitted? (2) 3660A (b) 3620A (c.) 4140 A, (d.) 4560 A (82.) Which one of the following has unit positive charge and 1 u mass? {a.) Electron, (b) Neutron (c) Proton (d) None of these (83.) Which one of the following groupings represents a collection of isoelectronic species? (At. no. Cs=55, Br=35) (2.) Na, Ca?, Mg? (b) N3,F,Na (c) Be, AP, Cl (a) Ca?, Cs, Br (84.)In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the same energy in the absence of ‘magnetic and electric fields? (A)n=11=0,m (B)n=2,1=0,m=0 (n=21=1,m (D)n=3,=2,m=1 (En =3,1=2,m {a.) (D) and (E) (b) () and (D) (c.) ®) and © (a) (A) and (B) (85.)The number of orbitals present in the shell withn = 4is (a) 8 (b) 16 {c.) 18 (a) 32 (86.)The wavelength of a spectral line emitted by hydrogen atom in the Lyman series ise cm. What is the value of n,2(R=Rydberg constant) (a)2 (b)3 {c)4 (a1 (87,)The orbital angular momentum of an electron in 3s-orbital is ee Oz 1h (C) 5am (a) Zero (88.)The maximum number of sublevels, orbitals and electrons in N-shell of an atom are respectively {a.) 4, 12,32 (b) 4, 16, 30 {c.) 4, 16, 32 (d.) 4, 32, 64 (89.)Identify the least stable ion amongst the following (a) Liv (b) Be () B- (a) c (90.)The absolute value of the charge on electron was determined by (a.) JJ. Thomson (b) RA. Millikan (c.) Rutherford (a) Chadwick (91.)Consider the ground state of (Z = 24). The numbers of electrons with the azimuthal quantum numbers, ! = 1 and 2 are respectively (a) 12and 4 (b) 12 and 5 (c.) 16and 4 (a) 16 and 5 (92.)Calculate the velocity of an electron having wavelength of 0.15 nm Mass of an electron is 9.109 x 10°, (h = 6626 x 10-erg's) (a,) 0.262 x 10-%cm. (b) 2.062 x 10-*cm.s~* (c.) 4.84 x 10%cm.s~* (a) 2.062 x 10-%cm.s™* (93,)The de-Broglie equation applies (a) To protons only (b.) To electrons only (c.) All the material objects in motion (d) To neutrons only (94.)Cr has electronic configuration as (a.) 3s*3p%3d*4s? (b.) 3s?3p®3d54s" (c.) 3s?3p3d® (a) None of these (95.)The statement that does not belong to Bohr's model of atom, is (a.) Energy of the electrons in the orbit is quantized (b. The electron in the orbit nearest to the nucleus is in lowest energy state (c.) Electrons revolve in different orbits around the nucleus (d_) The electrons emit energy during revolution due to the presence of Coulombic forces of attraction (96.)The uncertainty in the momentum of an electron is 1.0 x 10-Skg ms“, The uncertainty in its position will be (a) 1.50 x 10-%m (b) 1.05 x 10-2¢m (c.)5.27 x 10-°m (97,)Which of the following expressions gives the de-Broglie relationship? @p=s @)a=5 (a=e (d) am == (98) Which ofthe following reaction led tothe discovery of neutrons? (a) 6C+ pt 7NI*+ ont (b) «Be? + zHe* + gC? + on? (c.) 5B + 1D? 4C%+ on? (d) 4Be®+ Het + C14 gn (99.)Bohr model can explain (a) The solar spectrum () The spectrum of hydrogen molecule (c.) Spectrum of any atom or ion containing one electron only (d) The spectrum of hydrogen atom only (100,)The atomic number of an element is 35 and its mass is 81. The number of electrons in its ‘outermost shell is (a)3 (b)5 (c)7 (a9 (101 JThe line spectra of two elements are not identical because (a) The elements do not have the same number of neutrons (b) They have different mass numbers {c.) Their outermost electrons are at different energy levels (d)) All of the above (202.)Nuclear theory of the atom was put forward by (a) Rutherford (b) Aston (c) Neils Bohr (a) JJ. Thomson (103.)Deflection back of a few particles on hitting thin foil of gold shows that (a) Nucleus is heavy (b.) Nucleus is small (c.) Both (a) and (b) (d) Electrons create hinderance in the movement of a- particles. (104. Which of the following sets of quantum numbers represents an impossible arrangement? no lom os (a3 2-2 + ()3 2 -3 +3 1 ()4 0 0 =F 1 @s5 3 0 =F (105.)The correct ground state electronic configuration of chromium is {a.) [Ar]3d54s* (b.) [Ar]3d*4s? (c) [Ar]3d°4s° (a) [Ar}4d54st (106.) Which of the following elements has least number of electrons in its M-shell? (a) K (b) Mn (c.) Ni (a) Se (107.)An electron with values 4,3, -2 and + ; for the set of four quantum numbers n, l,m, and ma, respectively, belongs to (a.) 4s orbital (b) 4p orbital (c.) 4d orbital (d) 4f orbital (108,)The ground state term symbol for an electronic state is governed by (a.) Hund’s rule (b.) Heisenberg's principle (c.) Aufbau principle (@) Pauli’s exclusion principle (109.)The radius of electron in the first excited state of hydrogen atom is (Where, ag is the Bohr’s radius) (2.) ao (b) day (c) 2a9 (d.) Bay (110.)What is the atomic number of the element with M?* ion having electronic configuration [ar]3d°2 {a.) 25 (b,) 28 (c)27 (a) 26 (111,)The number of spherical nodes in 3p orbitals is (2)0 (b)1 (c)2 (3 (112,)The orbital angular momentum for an electron revolving in an orbit is given by Ji * This momentum for an s-electron will be given by 1h (athe (b) Zero n (clog @) v2.5 (113, )What is the mass ofa photon of sodium light with a wavelength of 5890 A'2(h = 6.63 x 10-2” ergs) {a.) 5.685 x 10-83 g (b) 6.256 x 107% g {c.) 4.256 x 10733 g (d) 3.752 x 107% g (114,)The set of quantum numbers for the outermost electron for copper in its ground state is (a) 44,144 (0) 3,2,2,42 (c.)4,0,0,45 (4) 4,2,2,45 (215.)Among the following sets of quantum numbers, which one is incorrect for 4d —electron? ()4,3,2,45 1 D421 (€)4,2,-24+5 (a) 4,2,1,-5 (116.)An isobar of y9Ca*” is (a) s9Ar* (b) aoCa*® fe.) aoa? (a) ,Ar®® (117,)The number of electrons and protons in an atoms of third alkaline earth metal is (a) €20,p 20 (b.) e 18,p 20 (c.)e 18,p 18 (d.) e 19,p 20 (128 )Which one of the following is the set of correct quantum numbers of an electron in 3d orbital? (a)n=3,0 -1/2 (b) n=2,1=3,m=0,s = 41/2 (c)n=3,l=1,m=0,5 (@)n=3,1=2,m (119.)Choose the incorrect relation on the basis of Bohr’s theory (a) Velocity of electron e + (b.) Frequency of revolution e (c.) Radius of orbit o n?Z (d.) Force on electron o = (220.)No two electrons can have the same values of vm quantum numbers. {a.) One (b) Two (c) Three (d) Four (121,)The velocities of two particles A and B are 0.05 and 0.02 ms~? respectively. The mass of B is five times the mass of A. The ratio of their de- Broglie's wavelength is, (a) 2:1 (b.) 1:4 (c.) 1:1 (jit (122,)Ifan electron has spin quantum number of +> and a magnetic quantum number of —1, it cannot be represented in an (a.) s —orbital (b.) p —orbital (c)d -orbital (a) f —orbital (123,)The compound in which cation is isoelectronic with anion is (a.) NaCl (b) CsF (c.) Nal (a) KS (124,)Choose the arrangement which shows the increasing value of e/m for e, p,n and a-particles fajn, Neutron and electron (c.) Proton and neutron (d.) Proton, neutron and electron (127,)The de-Broglie wavelength of a tennis ball of mass 60g moving with a velocity of 10 m/s is approximately (Planck's constant, h = 6.63 x 10-3*Js) (2) 10-%m (b) 10-#'m (c) 107m (a) 10-5 (128 .) Which of the followings sets of quantum numbers represents the highest energy of an atom? 3,1=1,m=1,s = 41/2 +1/2 (c)n=4,1=0,m (d)n=3,1=0,m=0,s= +1/2 (129.)If the shortest wavelength of H-atom in Lyman series is x, the longest wavelength in Balmer series of He* is 36x (a) = ) > (l= @= (130.)The energy of the electron in first Bohr’s orbit is —13.6eV. The energy of the electron in its first excited state is (a) -3.4eV (b.) — 27.8 eV (c) 68 eV (@) -10.2eV (131.)Which of the following is correctly matched? (a.) Momentum of H atom when electrons return 3h “+ (b) Momentum of photon: Independent of wavelength of light (c.) e/m ratio of anode rays : Independent of gas in the discharge tube (d.) Radius of nucleus : (Mass no. )¥/2 (132.)Which of the following is isoelectronic with carbon atom? (ay Nt (b.) 0% (c.) Nat (a) A+ (133./The work function (4) of some metals is. listed below. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metals is : Metal Li Na K Mg Cu Ag Fe Pt Ww (eV) 24 23 22 37 48 43 47 63 475 fromn =2ton= (a)2 (b)4 ()6 (@8 (134.)The probability of finding the electron in the orbital is (a) 100% (b) 90-95% (c.) 70-80% (a) 50-60% (135.)The frequency of radiation emitted when the electron falls from n=4 to n=1 ina hydrogen atom will be (Given, ionisation energy of 103 H=2.18 x 107" J atom” and h = 6.625 x 107% Js) {a.) 1.54 x 10'%s-1 (b.) 1.03 x 10° (c.)3.08 x 105s (d.) 2.00 x 1075s" (136.)What is the energy (in eV) require to excite the electron from n = 1 ton = 2 state in hydrogen atom? (n=principle quantum number) (a) 136 (b) 3.4 (c)17.0 (d.) 10.2 (137,)The electronic configuration with maximum exchange energy will be (a) 3d3,3d},3d3,45" (b) 3d}y3d}.3d},3d!._,.3d2.45 (c.) 3d2y3d},3d2,3d72_y23d2.48? (d) 3d23d},3d2,3d2._,.3d2.45" (138 )Which hydrogen like species will have same radius as that of Bohr orbit hydrogen atom? (a) n= 2,Li* (b) n= 2,Be™* (c)n = 2,He* (a) n= 3,Li%* (139.)The atomic numbers of elements X, ¥ and Z are 19, 21 and 25 respectively. The number of electrons present in the M-shell of these elements follow the order (ajZ>X>Y¥ (b.)X>Y¥>Z ()Z>¥>X (d)¥>Zz>Xx (140.)Non-directional orbital is (a.) 4p (b.) 4d (4p (d.) 3s (141,)In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainity with which the position of the electron can be | f= 6.6 x 10°*4kg m?s~?, keested ls (masseter, = 9.1 x 107g, (a) 1.52 x 10-*m (b) 5.10 x 10-m. (c) 1.92 x 103m (a) 3.84 x 10-m. (142,)lz molecule dissociates into atoms after absorbing light of 4500 A®. If one quantum of energy is absorbed by each molecule, the KE of iodine atoms will be (BE of Iz = 240 kj/mol) (a) 240x 107" (b) 0.216 10799 J (c.) 2.16% 10729) (d.) 2.40x 1079} (143,)The radius of second Bohr’s orbit of hydrogen atom is (a.) 0.053 nm (b) 0.106nm (c)0.2116 nm (4) 0.4256 nm (244 )Angular momentum of an electron in the n th orbit of hydrogen atom is given by a2 (b) nh ae (c) mm, Qin (145.)The one electron species having ionisation energy of 54.4 eV is (a)H (b.) Het (c.) BY (a) Li?* (146,)The radius of hydrogen atom is 0.53A. The radius of sLi?* is of (a) 127A (b)0.17A (c.)0.57A (4) 099A (147,)How many unpaired electrons are present in Nit cation? (At. No. = 28) (ajo ()2 (c)4 (46 (248 .)The potential energy of an electron present in the ground state of Li?* ion is (a) +n O-ae ater @-35 (149 )The number of electrons in the valence shell of calcium is (a)2 (b)4 (c)6 @s (250.)The maximum number of electrons that can have principle quantum number, n = 3 and spin quantum number, m, = —3,is (a)3 (b)5 (c)7 @9 (151,)The frequency of a spectral line for electron transition in an atom is directly proportional to (a.) Number of electrons undergoing transition (b.) Velocity of electron (c.) The difference of energy between energy levels, involved in the transition (d.) None of the above (152.)In photoelectric effect, the number of photoelectrons emitted is proportions to {a.) Intensity of incident beam (b.) Frequency of incident beam (c.) Wavelength of incident beam (d.) All of the above (153.)The energy required to break one mode of Cl— Cl bonds in Cl, is 242k|mol-'. The longest wavelength of light capable of breaking a single l= Clbond is (a) 594nm. (b.) 640 nm (c) 700 nm (a) 494nm (154.)The energy of hydrogen atom in its ground state is -13.6 eV. The energy of the level corresponding to the quantum number n=5 is (a) -5.4eV (b) -0.54 eV (c.) -2.72 eV (d.) 0.85 ev (155.)The ionization energy of the ground state hydrogen atom is 2.18 x 10-® J. The energy of an electron in its second orbit would be {a.) —2.67 x 10718] (b.) -5.45 x 10°] (c) 3.58 x 107°] (d.) 4.68 x 10729) (156.)Which of the following statements is wrong about cathode rays? (a. They produce heating effect (b.) They carry negative charge (c) They produce X¥ —rays when strike with ‘material having high atomic masses (A) None of the above (157.)What is the wavelength of an a-particle having mass 6.6 x 10-2” kg moving with a speed of 105 cm s~*? (h = 6.6 x 10*+kg m? — 5) (a) 2x 107! m (b) 3x 107 m (c.) 1x 1077 m (2x 107 m (158,)An electron from one Bohr stationary orbit can go to next higher orbit (a) By emission of electromagnetic radiation (b) By absorption of any electromagnetic radiation (c) By absorption of electromagnetic radiation of particular frequeney (d) Without emission or absorption of electromagnetic radiation (159 )The ground state electronic configuration of nitrogen atom can be represented as @to ow oat4 ®t Ve ow (c) 1 7 beoe (a) All ofthe above (160,)When a —particles are sent through a thin metal foil, most of them go straight through the foil because (a) Most part of the atom is empty space (b. Alpha particles move with high speed (c.) Alpha particles are much heavier than electrons (d.) Alpha particles are positively charged (161.)Increasing order (lowest first) for the values of e/m for electron (e), proton (p), neutron (n) and acparticles is (leprae (b) n,a,p,€ (c)np.ea @)npae (162.)After np electronic configuration, the next orbital filled will be (a)(rttd (b) (n+ 1)s (c)@+Df (d,) None of these (163.)Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 x 10*ms~* (Mass of proton = 1.67 x 10°?7kg and h = 6.63 x 10-* js) (a) 0.032 nm (b) 0.40 nm (c)25nm (d) 14.0 nm (164,) What is the frequency of photon whose momentum is 1.1 x 10-?kg ms~?? (a) 5 x 10°°Hz (b) 5x 10"7 Hz (c.) 0.5 x 10°°Hz (a) 5 x 10H (165,)Common name for proton and neutron is (a) Deutron (b) Positron (c) Meson (a) Nucleon (266.) When a gold sheet is bombarded by a beam of ‘@ -particles, only a few of them get deflected, whereas most go straight, undeflected. This is because (a.) The force of attraction exerted on @- particle by electrons is insufficient (b.) The volume of nucleus is smaller than atom (c.) The force of repulsion acting on fast moving @- particle is very small (d) The neutrons have no effect on a-particle (167,)The values of four quantum numbers of valence electron of an element are n=4,1=0,m=0ands= +3. The element is ()K (b.) Ti (c.) Na (a) Se (168, The equation, a = was deduced by (2.) Newton (b,) de-Broglie (c.) Planck (d) Heisenberg (169.)For a particular value of azimuthal quantum, number, the total number of magnetic quantum number values are given by (270)The number of p-electrons in bromine atom is (a.)12 (b) 15 (c)7 (a) 17 (171,)If uncertainties in the measurement of position and momentum of an electron are equal, the uncertainty in the measurement of velocity is (a.) 8.0 x 1012 ms“? (b.) 42 x 10" ms~ (c.) 85x 10" ms (d) 6.2% 10" ms? (172,)The frequency of light emitted for the transition n=40 to n=2 of He* is equal to the transition in H atom corresponding to which of the following? (a)n=3ton=1 (b)n=2ton (c)n=3ton=2 (d.)n=4ton (173) What does the electronic configuration 1s?, 2s, 2p5, 3s1 indicate? (2.) Ground state of fluorine (b) Excited state of fluorine (c.) Excited state of neon (@.) Excited state of the 0; ion (174.)Which of the following statements incorrect? (2.) Extra stability of half filled and completely filled orbitals among s and p block elements is reflected in trends of IE across a period (b) Extra stability of half-filled and completely filled orbitals among s and p block elements is reflected in EA trends across a period (c.) Aufbau principle is incorrect for cases where energy difference between ns and (n — 1)d sub- shell us larger (a. Extra stability to half filled sub-shell is due to higher exchange energies (175.)A photon having a wavelength of 845 A, causes the fonisation of N atom. What is the ionisation energy of N? (a) 14k (b) 14 x 10* kj (c.) 1.4 x 10? kj (d.) 1.4 x 10? kj (176.)The electronic configuration of P in HPO, is (a.) 15%, 252, 2p%, 35%, 3p* (b) 1s, 2s%, 2p®, 3s (c.) 1s?, 25%, 2p® (d.) 1s?, 2s, 2p, 35”, 3p%, 4s" (177,)An electron with values 4, 2, —2 and +1/2 for the set of four quantum numbers n, l,myand s respectively, belongs to (a.) 4s-orbital (b) 4p-orbital (c.) 4d-orbital (d) 4f-orbital (178.)The value of Rydberg constant is (a.) 10,9678 em-* (b,) 10,9876 cm-* (c.) 10,8769 cm (d.) 10,8976 em (179.)The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state 1, would be (Rydberg constant =1.097 x 10’m=") (a) 9Lnm (b) 192mm (c.) 406 nm (4) 9.1.x 10-%nm (180.)Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers, ! = 1 and 2 are, respectively (a) 12and 4 (b.) 12 and 5 {c.) 16 and 4 (a) 16 and 5 (181,) Which among the following is correct for ;B in normal state? (a.) Is 2p tL 1 + Against Hund’s rule (bt 14 Against Aufbau principle as well as Hund’s rule ct 4 : Violation of Pauli’s exclusion principle and not Hund’s rule @t 4 :Against Aufbau principle (182.) Which one of the following sets of quantum numbers represents the highest energy level in an atom? (a)n=4,1=0,m=0,5= +2 (b) (jn “ yt 3,1=1,m=1s=+4 2,5 (dn =3,1 =0,m=0,5= +2 (183,)The de-Broglie wavelength relates to applied voltage ror 1 1 = 2,m + (184.) Which of the following will violates aufbau principle as well as Pauli’s exclusion principle? (a) Is 2s 2p wow oad (b) 1s 2s 2p tow nd (c) 4s 2s 2p 1 1 no14 (d.) None of the above (185.)How many neutrons are present in tritium nucleus? (a)2 (b)3 {c)1 (ao (186 )Isotopes are (c.) Atoms of different elements having same mass number (b) Atoms of same elements having same mass number {c.) Atoms of same elements having different mass number (d@) Atoms of different elements having same number of neutrons (187.)In Bohr’s series of lines of hydrogen spectrum, the third line from the red end corresponds to which one of the following inner-orbit jumps of the electron for Bohr orbit in an atom of hydrogen? (a) 342 (6) 52 (c) 401 (a) 245 (188, Which of the following statement is relation to the hydrogen atom is correct? (a.) 3s, 3p and 3d-orbitals all have the same energy (b. 3s and 3p-orbitals is lower energy than 3d- orbital (c.) 3p-orbital is lower in energy than 3d-orbital (a) 3s-orbital is lower in energy than 3p-orbital (189, Which of the following is Heisenberg uncertainty principle? (a) dx.dp > (b) Ax. dp = 5 (c)ax.dp s% (4) dx. ap <7 (190) The total spin for atoms with atomic number 7,24,34 and 36 will be (a) 0,41, £3,43/2 (b) +1,0, +3/2,+3 (c.) £3/2,£3,41,0 (@) £3,410, $3/2 (191.)The number of radial nodes of 3s and 2p- orbitals are respectively (a)2,0 (b) 0,2 (c) 4,2 (@)2,11 (192.)An electron, a proton and an alpha particle have KE of 16E, 4£ and E respectively. What is the qualitative order of their de-Broglie wavelengths? (a) Ae > Ap > Ae (b) Ay =Aa > Ae (cap < de < Aa (d) da < Ae ® Ay (193.)The characteristic not associated with Planck's theory is (a.) Radiations are associated with energy (b) The magnitude of energy associated with a quantum is proportional to frequency (c) Radiation energy is neither emitted nor absorbed continuously (d) Radiation energy is neither emitted nor absorbed discontinuously (194,)Choose the correct statement among the following (a.) ¥? represents the atomic orbital (.) The number of peaks in radial distribution is n=l (c.) Anode is a point in space around nucleus where the wave function ¥ has zero value (d) All ofthe above (195 )Which of the following atoms has same number of protons and neutrons in its nucleus? (2) Carbon (b) Deuterium (c.) Tritium (@) Nitrogen (196.)The representation of the ground state electronic configuration of He by box-diagram as tT is wrong because it violates (a.) Heisenberg’s uncertainty principle (.) Bohr’s quantization theory of angular momenta (c.) Pauli exclusion principle (d) Hund’s rule (197.)Which of the following electron transition in hydrogen atom will require largest amount of energy? (a.) Fromn = 1lton=2 (b.) From n 3 (c) Fromn = 0 ton = 1 (d.) Fromn = 3ton=5 (198.)The radius of the first Bohr orbit of hydrogen atom is 0.529 A. The radius of the third orbit of H* will be (a) 846A (b) 0.705 A {c) 159A (4) 4.764 (199.)Bohr’s radius of 2nd orbit of Be** is equal to that of (a.) 4th orbit of hydrogen (b.) 2nd orbit of He* (c.) 3rd orbit of Li?* (A) First orbit of hydrogen (200.)Correct energy value order is (a) ns,mp,nd,(n — Df (b.) ns, np, (n — 1)d, (n - 2)f (c)ns,np,(n—Dd,(n— DF (a) ns,(n = Dd, np, (n= DF (201.)What is the ration of mass of an electron to the mass of a proton? (a) 1:2 (b) 11 (c.) 1:1837 (@)13 (202.)The orbital angular momentum of an electron ina d-orbital is (a) vo ) ae (203.)The lightest particle is (a.)-particle (b) Positron (c.) Proton (d.) Neutron (204|Choose the incorrect statement a.) Every object emits radiation whose predominant frequency depends on its temperature (b) The quantum energy of a wave is proportional to its frequency (c.) Photons are quanta of light (.) The value of Planck's constant is energy dependent (205.)What is the lowest energy of the spectral line emitted by the hydrogen atom in the Lyman series? lanck’s constant, c=velocity of light, yydberg’s constant). she Co eral 2 (206.)A gas absorbs photon of 355 nm and emits at two wavelengths. If one of the emission is at 680 nm, the other is at (a) 1035 nm (b) 325 nm (c.) 743 nm (a) 518 bm (207.)The H-spectrum show (a.) Heisenberg’s uncertainty principle (b) Diffraction (c.) Polarisation (d.) Presence of quantised energy level (208 |The Z —component of angular momentum of, an electron in an atomic orbital is governed by the (.) Magnetic quantum number (b.) Azimuthal quantum number (c.) Spin quantum number (@.) Principal quantum number (209.)If the wavelength of an electromagnetic radiation is 2000A, what is its energy in ergs? (a) 9.94 x 10-1 (b) 9.94 x 10719 (c.) 4.97 x 107? (a) 4.97 x 10719 (210.)Ground state electronic configuration of nitrogen atom can be represented as a OM Go oo) HHIGE) ;, HWObT) @ H@WooG (211,)The atomic transition gives rise to the radiation of frequency 10* MHz. The change in energy per mole of atoms taking place would be (a.) 6.62 x 10-9) (b) 5.32 x 10-78) (c.) 6.62 x 10-29} (4) 3.99 (212.,)The velocity of an electron must possess to acquire a momentum equal to the photon of wavelength 5200 A’, will be (a.) 1398 ms“* (b.) 1298 ms~* (c.) 1400 ms~* (@) 1300 ms-* (213)An orbital in which n = 4 and | = 2is expressed by (a) 4s (b.) 4p (c.) 4a (d.) Sp (214.)Which of the following is not possible? (215.)The stability of ferric ion is due to (a.) Half filled f-orbitals (>. Halffilled d-orbitals (c) Completely filled f-orbitals (d) Completely filled d-orbitals (216.)Which one of the following sets of ions represents a collection of isoelectronic species? (a) K*, Cl", Ca?*, Se3* (b) Ba?*, Sr?*, K+, $?~ (c.) N8-, 07", F,S?- (@) Lit, Nat, Mg*, Ca?+ (217.)The electronic configuration of an element in ultimate and penultimate orbitals is, (m Ds*(m DpS(n Da* ns?. fn 4and x 5 then number of protons in the nucleus is (a) 25 (b) <724 {c.)25 (a) 30 (218 )The electronic configuration of an element is, 1s?,2s*, 2p®, 352, 3p®, 3d, 4s. This represents its (a.) Cationic form (b) Anionic form (c.) Ground state (a) Excited state (219 )Blectron density in the YZ plane of 3d,2_y2 orbital is (2) Zero (b) 0.50 (<)0.75 (a) 0.90 (220.)The mass of a photon with wavelength 3.6 A is (a) 6.135 x 10-%kg (b) 3.60 x 10-kg (c) 6.135 x 10-kg (G) 3.60 x 10-?7kg (221,)If the energy difference between the ground state of an atom and its excited state is 4.4 x 10~*], the wavelength of photon required to produce the transition (a) 2.26 x 10-?m (b) 1.13 x 10722m (c) 452 x 107m (a) 4.52 x 10-"m (222.)A body of mass 10 mg is moving with a velocity of 100 ms~*. The wavelength of de-Broglie wave associated with it would be (h = 6.63 x 1074s) (2) 6.63 x 10-$5m (b) 6.63 x 10-**m (c.) 6.63 x 10-'m (d.) 6.63 x 10-3’m (223 )Blectrons will first enter into the set of quantum numbers n = 5,1 = 0 orn = 3,1= (a)n=5,1=0 (b) Both possible (c)n=3,1=2 (4) Data insufficient (224,)Which of the following pairs have identical values of e/m? (a) A proton and a neutron (b) A proton and deuterium (c) Deuterium and an a-particles (@) An electron and y-rays (225.)The mass of an electron is m, its charg and itis accelerated from rest through a potential difference, V. The velocity of electron will be calculated by formula wo fE (b) « tc) J) (@.) None of these (226.)Choose the incorrect statement (2.) The shape of an atomic orbital depends upon the azimuthal quantum number (b.) The orientation of an atomic orbital depends upon the magnetic quantum number (c.) The energy of an electron in an atomic orbital of multi-electron atom depends on principal quantum number (d.) The number of degenerate atomic orbitals of one type depends on the value of azimuthal and ‘magnetic quantum numbers (227.)A particle moving with a velocity 10° m/s will have de-Broglie wavelength nearly (Given, m = 6.62 x 10-7kg, h = 6.62 x 10-4] — s] {a.) 10-°m (b) 107m (c) 107m (ajiA (228.)The ionisation enthalpy of hydrogen atom is 1.312 x 10°}mol-. The energy required to excite the electron in the atom from n, = 1 tom, = 2is (2) 8.51 x 105 mol“? (b) 6.56 x 108 Jmol"? (c.) 7.56 x 10° | mol“? (4) 9.84 x 108 J mol“? (229.)The maximum kinetic energy of the photoelectrons is found to be 6.63 x 10" J. When the metal is irradiated with a radiation of frequency 2.x 10'S Hz, the threshold frequency of the metal is about (2.) 2 105 s-* (b.) 1x 10" 5-1 (c) 25x 10° (d) 4x 10" s (230.)The valence shell electronic configuration of Cr?* jon is (a.) 48°3d* (b.) 4s73d? (c.) 48?3a° (a) 3p%4s? (231.)The number of d-electrons retained in Fe?* (At. No. Fe=26) ions is (2)3 (b)4 (c)5 (a) 6 (232.)The correct set of four quantum number for the valence electron of rubidium (Z=37) is (o)n=5,1=0,m=0,s= 41/2 a (233 )The total number of electrons present in all thes’ orbitals, all the ‘p’ orbitals and all the ‘a’ orbitals of cesium ion are respectively (a) 8,26, 10 (b) 10, 24,20 (c.) 8,22, 24 (d.) 12, 20, 22 (234.)The emission spectrum of hydrogen is found to satisfy the expression for the energy change, AE (in joules), such that AE = 2.18 x 10-** [= -]), where, n, = 1,2,3,...andn, = 2,3/4,... The spectral lines correspond to Paschen series are (a) ny = Land n, = 2,3,4 (b) ny = Land n; = 3,45 (c.)my = 3.and nz 15,6 (d) ny = Zand n, = 3,45 (235.)According to Bohr's theory, the angular momentum for an electron of 3rd orbit is (a)3h (b) 15h (c)9h (dy 2% (236,)In the ground state of Cu*, the number of shell occupied, sub-shells occupied, fillied orbitals and unpaired electrons respectively are (a) 4,8,15,0 (b.) 3,6,15,1 (c.)3,6,14,0 (4) 4,7,14,2 (237,\Uncertainty in the position of an electron (mass = 9.1 x 10-31kg) moving with a velocity 300 ms~, accurate upon 0.001% will be (h = 6.63 x 10" Js) (a) 19.2 x 10-¢m (b) 5.76 x 10-2m (c) 1.92 x 10-m (d.) 3.84 x 10-2m (238.)Mg?* is isoelectrionic with (a) Cu?* (b) Zn? (c.) Nat (d.) Ca?* (239.) What is the electronic configuration of Mn2*? (a) [Ne]3d5, 45° (b,) [Ar]3d5, 45? (c.) [Ar]3d5, 45° (d.) [Ne]3s5, 4s? (240,\Correct set of four quantum numbers for valence electron of rubidium (Z = 37) is (2) 5,0,0, +2 (b) 5,1,0,+5 (c) 54,43 (@) 6,0,0,+3 (241. }The atomic number of Ni and Cu are 28 and 29 respectively. The electronic configuration 1s?2s*2p°3s?3p°3d"” represents (e.) Cur (b.) Cu?* {c.) Ni* (@) Ni (242.)Which of the following sets of quantum numbers is correct? (a)n=5,l=4,m=0,s= +3 ())n=3,1=3,m=43,5= +3 (c)n=6,l=0,m+1,s=-2 (d)n=4,1=2,m=42,5=0 (243 )The number of electrons accommodated in an orbit with principle quantum number 2, is (2.)2 (b)6 (c.)10 (8 (244 The orbital angular momentum of an electron revolving in a p-otbital is {a.) Zero nh (b) me (ce @s% (245.)The maximum energy is possessed by an electron, when itis present {2.) In nucleus (b.) In ground state (c.) In first excited state (d.) Atinfinite distance from the nucleus (246.)The ionisation energy of hydrogen atom is 13.6 eV. What will be the ionisation energy of He*? (s.) 13.6 eV (b) 54.4eV (c) 1224 eV (a) Zero (247.)A Mo atom in its ground state has a 4d5, 5s" configuration and a Ag atom 4d?°, 5s! configuration. This is because a shell which is half- filled or completely filled is particularly (z.) Strongly exchange destabilized (b.) Weakly exchange stabilized (c.) Weakly exchange destabilized (A) Strongly exchange destabilized (248, )The wave number of the spectral ine in the emission spectrum of hydrogen will be equal to 3 times the Rydberg’s constant if the electron jumps from (a)n=3ton=1 (b)n=10ton=1 (c)n=9ton (@)n=2ton (249,)According to aufbau principle, the correct order of energy of 3d, 4s and 4p-orbitals is la.) 4p < 3d <4s (b.) 4s < 4p <3d (c) 4s < 3d < 4p (d.) 3d < 4s < 4p (250.)Suppose 10~*” J of light energy is needed by the interior of a human eye to see an object. Calculate the number of photons of green light (2 = 550 nm) needed to generate this minimum amount of energy (a.) 26 (b) 27 (c.) 28 (a) 29 (251,)The charge to mass ratio of a-particle is approximately .... the charge to mass ratio of protons (a) Six times (b.) Four times (c) Half (d.) Two times (252.)Which of the following make up an isotonic triad? (a.) 386023 As} Ga (b) $arJ3 KA Ca (c.) 320,335 Th, 32 Pu (a) 130, 180,9N (253,)A cricket ball of 0.5 kg is moving witha velocity of 100 m/s. The wavelength associated with its motion is (a) 1/100 cm (b) 6.6 x 104m (c.) 1.32 x 10-$5m (a) 6.6 x 10-?8m (254,)The radius of the first Bohr orbit of hydrogen atom is 0.529A. The radius of the third orbit of H* will be (2) 846A (b) 0.705 A (c) 159A (a) 4.79A (25S.)The triad of nuclei which is isotonic is (a) {63437 F (b) BCH NSF (c.) BC 35 NI F @) OCH NDF (256.\The correct statement about proton is (2, Itis a nucleus of deuterium (b) It is an ionized hydrogen atom (c) It is an ionized hydrogen molecules (d) Itis an @- particle (257,)An isotone of 38Ge is (2.) 32Ge (b) Bas (c) 34Se (ad) Ze (258.)The number of orbitals present in the shell withn = 4is (2) 16 (b)8 (c.) 18 (a) 32 (259.)The nodes present in 3p-orbitals are (2.) One spherical, one planar (b.) Two spherical (c) Two planar (@) One planar (260.|The ratio of the difference in energy between the first and the second Bohr orbit to that between the second and the third Bohr orbit is 1 ) 2 5 it @z (261 )The electric configuration of element with atomic number 24 is {a.) 1s*, 2822p, 3s*3p°3d*, 4s* (b) 1s?, 2s?2p8, 3573p°3d"? (c.) 1s%, 2s?2p®,3s?3p°3d° (a) 1s?, 2s*2p°, 35?3p°3d5, 4s (262.)The number of 2p-electrons having spin quantum numbers s = — 1/2 are (26 (b)0 (c.)2 (@)3 (263.) Which of the following statements regarding an orbital is correct? (2.) An orbital is a definite trajectory around the nucleus in which electron can move (b) An orbital always has spherical trajectory (c.) An orbital is the region around the nucleus where there is a 90 — 95% probability of finding all the electrons of an atom (@) An orbital is characterized by 3 quantum numbers n,/ and m (264,) Which of the following is non-permissible? (265,)Splitting of spectrum lines in magnetic field is (a) Stark effect (b.) Raman effect (c.) Zeeman effect (d) Rutherford effect (266.)When the azimuthal quantum number has the value of 2, the number of orbitals possible are (a)7 (o)5 ()3 (ajo (267 The energy ration of a photon of wavelength 3000 A and 600A is (a) 4:1 (b) 2:1 (c.) 1:2 (a) 14 (268,)IF helium atom and hydrogen molecules are moving with the same velocity, their wavelength ratio will be (a)4:1 (b.) 1:2. (c)2:1 (d.) 1:4 (269.) Magnitude of kinetic energy in an orbit is equal to (a.) Half of the potential energy (b.) Twice of the potential energy (c.) One fourth of the potential energy (d.) None of the above (270)The radius of which of the following orbit is same as that of the first Bohr’s orbit of hydrogen atom? (a) Lz+(n (b) Li?*(n (c.) Be#+(n = 2) (d) Het (n = 2) (271,)The increasing order (lowest first) of the value of * for electron (e), proton (p),neutron (n) and alpha particle (a) will be (a) n,a,p,e (J epna ()np.ea (a) n,p.ae (272,)The electronic configuration of Cr** is (a.) [Ar]3d*4s? (b) [Ar]3d*4s° (c.) [Ar]3d?4s? 2) (a) [Ar}3d54st (273.)The incorrect statement about Bohr’s orbit of hydrogen atom is (jr=P— ein) (b) KE of electron = PE of electron (yB=-4 nla) (d.) None of the above is incorrect (274.)Wave nature of electrons was demonstrated by (a.) Schrodinger (b) De-Broglie (c.) Davisson and Garmer (a) Heisenberg (275.)The first emission line in the electronic spectrum of hydrogen in the Balmer series appears atcm™? (276.)Which particle contains 2 neutrons and 1 proton? (a.) :H? (b.) ,Het (c) aT? (a) .D? (277.\Which of the following has the maximum. number of unpaired ‘d’ electrons? (a,) Zn?* (b) Fe** (c.) Ni#* (a) cut (278.) Which of the following sets of quantum. number is correct for an electron in 4f-orbital? (a)n=4,1=3,m= 44,5 = +1/2 4,m = —4,5 =—1/2 (c.) 3m=+1s=+1/2 (d)n =3,1=2,m=-2,s = 41/2 (279.)An f-shell containing 6 unpaired electrons can exchange (a.) 6 electrons (b) 9 electrons (c.) 12 electrons (€) 15 electrons (280.)An electron is moving in Bohr’s fourth orbit. Its de-Broglie wavelength is 2. What is the circumference of the fourth orbit? 2 (a (b) 2a (c)4a (ae (281,)The wave number of the first line in the Lyman series in hydrogen spectrum is (a) 72755.5em™ (b) 109678 cm=? (c.) 82258.5 cm™ (4) 65473.6 em (282 )An electronic transition in hydrogen atom results in the formation of H line of hydrogen in Lyman series, the energies associated with the electron in each of the orbits involved in the transition (in kcal mol) are (2) -313.6, -34.84 (b.) — 313.6,-78.4 (c.) -78.4, -34.84 (d.) -78.4,-19.6 (283,)A particle having a mass of 1.0 mg has a velocity of 3600 km/h. Calculate the wavelength of, the particle (h = 6.626 x 10-*7erg — s) (2.) 6.626 x 10-*cm (b) 6.626 x 10-?%cm (c.) 6.626 x 10-3%cm (d) 6.626 x 10-4em (284,)The number of waves in an orbit are (a) 2 (bn (c)n-1 (d)n-2 (285 )According to Bohr’s theory, the angular momentum of an electron in Sth orbit is (a)25% (b) 1.0" (102 (ay2s% (286)Stark effect refers to the (a.) Splitting up of the lines in an emission spectrum in the presence of an external electrostatic field (b. Random scattering of light by colloidal particles (c.) Splitting up of the lines in an emission spectrum ina magnetic field (d.) Emission of electrons from metals when light falls upon them (287.)Which among the following species have the same number of electrons in its outermost as well as penultimate shell? (2) Mg?* (b) 0% (JF (a) Ca?* (288.)The graph representing node is (a) ae () a (c) : a qd) (289.)Einstein’s theory of photoelectric effect is based on (2.) Maxwell's electromagnetic theory of light (b. Planck's quantum theory of light (.) Both of the above (a) None of the above (290,)The total number of orbitals possible for principle quantum number nis fajn (b) n? (c)2n (a) 2n? (291,)Which of the following transitions are not allowed in the normal electronic emission spectrum of an atom? (a) 2s > 1s (b) 2p > 1s (c.) 3d + 4p (@) 5p > 3s (292.)Among the following series of transition metal, ions, the one in which all metal ions have 3d electronic configuration is (At. no. Ti=22, V=23, Cr=24, Mn=25) (a) TH, V2, Cr+, Mn (b.) Tit, V4+, Cr, Mn+ (c.) Ti**, V3", Cr2*, Mn3* (d.) Ti?*, V3+, Cr+, Mn+ (293,)The electronic configuration of a dipositive ion M** is 2, 8, 14 and its mass number is 56. The number of neutrons present is, (a) 32 (b) 42 (c,) 30 (a) 34 (294.)Which of the following is correct for number of electrons, number of orbitals respectively in n- orbit? (a) 4,4and 8 (b) 4,8 and 16 (c.) 32, 16 and 4 (d) 4,16 and 32 (295,)The electrons identified by quantum numbers ViLn=4=1 ViLn=4,1=0 vill. n=31=2 K n=21=1 Can be placed in order of increasing energy from the lowest to highest as (a) IV (a) N= (302.)Which of the following is correct? (2.) ,H* and He? are isotopes (b.) «Cand ;N" are isotopes (c.) 4K* and yoCa*® are isotones (d.) oF! and ,,Na** are isodiaphers (303.)For a Bohr atom angular momentum M of the electron is (n = 0,1,2,...) (304.)Which of the following is the correct form of Schrodinger wave equation? a) e+ + Se SP e-nys0 (6) 44 St PE yw=0 ee tet ee E vye=o @et+2 42m (e—vyw=0 (305,)Which of the following electronic configuration is not possible? (a) 182,28? (b.) 1s?, 2s?2p® (c.) [Ar]3d?°, 4574p? (a) 1s?, 2572p? 3s (306.)The number of electrons and neutrons of an element is 18 and 20 respectively. Its mass number is (a)2 (b) 17 (c.)37 (a) 38 (307,)A body of mass x kg is moving with a velocity of 100ms~". Its de-Broglie wavelength is 6.62 x 10-*5m. Hence, x is (h = 6.62 x 10-**Js) (2.) 0.1 kg (b) 0.25 kg (c.) 0.15 kg. (a) 02 kg (308 )The relationship between the energy E, of the radiation with a wavelength 8000A and the energy E, of the radiation with a wavelength 16000A is (a) Ey = 6E, (b) Ey = 2E, (c.) Ey = 4Ey (d) Ey = 1/2Ey eeoeecrareaseragace sagen gnToN eT TN Ao Taw AaAanneTH A ooo 190) oooe@oarrnscarTo Te Oe anTeHeTo TON ee HHOAanwsaaHwonwanHoooSe 3) 1) 15) 19) 23) 31) 35) 39) 47) 51) 55) 59) 63) 71) 75) 79) 83) 91) 95) 103) 107) 111) 115) 119) 123) 127) 131) 135) 139) 143) 147) 151) 155) 159) 163) 167) 171) 179) 183) 187) 191) eooeaseocrncarnoneeanecannacacrasanaoasensnnnaceoaoa eeocerravtaxnvooxTxaXxTN TOON NMAXTToENeO TT oN THANK ATS 193) 197) 201) 205) 209) 213) 217) 221) 225) 229) 233) 237) 241) 245) 249) 253) 257) 261) 265) 269) 273) 277) 281) 285) 289) 293) 297) 301) 305) 194) 198) 202) 206) 210) 214) 218) 222) 226) 230) 234) 238) 242) 246) 250) 254) 258) 262) 266) 270) 274) 278) 282) 286) 290) 294) 298) 302) 306) 195) 199) 203) 207) 211) 215) 219) 223) 227) 231) 235) 239) 243) 247) 251) 255) 259) 263) 267) 271) 275) 279) 283) 287) 291) 295) 299) 303) 307) can acoa eace ooaan ease eeac aac 196) 200) 204) 208) 212) 216) 220) 224) 228) 232) 236) 240) 244) 248) 252) 256) 260) 264) 268) 272) 276) 280) 284) 288) 292) 296) 300) 304) 308) ao aoca ewan woo csoaca oc oso aoe oo

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