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Datos Termodinámica

The document appears to be data from multiple experiments measuring temperature changes over time. Small masses of different substances were added to a solution and the temperature was recorded at regular intervals. The substances tested include KCl and Na2CO3, and the data will be used to calculate heat capacities and enthalpy changes.

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Angela Villegas
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11 views7 pages

Datos Termodinámica

The document appears to be data from multiple experiments measuring temperature changes over time. Small masses of different substances were added to a solution and the temperature was recorded at regular intervals. The substances tested include KCl and Na2CO3, and the data will be used to calculate heat capacities and enthalpy changes.

Uploaded by

Angela Villegas
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Intento 1 intento 2 intento 3 intento 4 Promedio

TIEMPO TEMPERATU RA (°C)


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C(calori) J/°C ∆T (°C) n1= solv n2= soluto ∆H(int)
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∆H (kJ/mol) Cp ag (J/g°C) Cp calorim 1 177.343549
-55.83 4.184 Intento 1 Intento 2 Cp calorim 2 177.162283
T1 27.4 27.3 5.5
T2 32.9 32.9 5.6

KCL 74.5513
masa teo (g) masa tomada n T1 T2 densid (g/mL)Cp ∆H (J)
0 0 0 26.5 26.5 177.252916
0.5 0.5 0.00670679 27 26.7 0.99659 344.042218 103.212666
1 1.01 0.01354772 25 24.7 0.99713 344.132593 103.239778
2 2 0.02682716 26.1 25.5 0.99686 344.087406 206.452443
3 3 0.04024075 27.3 25 0.99713 344.132593 791.504963
4 4 0.05365433 25.3 22.6 0.99762 344.214599 929.379418
5 5 0.06706791 20.3 19.6 0.99829 344.32673 241.028711

Na2CO3 115.9888
masa teo (g) masa tomada n T1 T2 densid (g/mL)Cp ∆H (J)
0 0 0 26.5 26.5 0.99686 344.087406 0
0.5 0.5 0.00431076 27.3 27.8 0.99659 344.042218 -172.021109
1 0.99 0.00853531 27.6 28.6 0.99631 343.995358 -343.995358
2 2.01 0.01732926 27.4 30.3 0.99631 343.995358 -997.586537
3 3 0.02586457 26.3 31.3 0.99631 343.995358 -1719.97679
4 4.01 0.0345723 27.6 33.7 0.99571 343.894942 -2097.75914
5 5 0.04310761 24.7 32 0.99631 343.995358 -2511.16611
Promedio
177.252915974

Calor integral (J/mol) vs molalidad (mol


∆H int (kJ*L/mol)m (mol/L) 10.00000
…... 0 f(x) = − 29.2572271749085 x³ + 52.0902357184344 x² − 20.621198790111
6.15571071232 0.16766978 R² 5.00000
= 0.890106004967764
3.048182039248 0.33869295
0.00000
3.078259607901 0.67067912 0 0.2 0.4 0.6 0.8 1 1
7.867696530193 1.00601867 -5.00000

∆H int (kJ*L/mol)
6.928644378799 1.34135823
1.437520300951 1.67669779 -10.00000

-15.00000
f(x) = 25.3848804179226 x² − 38.6482869074966 x − 10
R² = 0.920209371606727
∆H int (kJ*L/mol)m (mol/L)
-20.00000
….. 0
-15.96202 0.10776903 -25.00000
-16.12105 0.21338267
-23.02664 0.43323148 -30.00000
-26.59974 0.64661416 m (mol/L)
-24.27098 0.86430759
-23.30137 1.07769026 Na2CO3 Polynomial (Na2CO3)
KCl Polynomial (KCl )
mol) vs molalidad (mol/L)

57184344 x² − 20.6211987901118 x + 5.73014725814769

0.6 0.8 1 1.2 1.4 1.6

226 x² − 38.6482869074966 x − 10.8925303579794


727

m (mol/L)

Polynomial (Na2CO3)
Polynomial (KCl )

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