C Fumed Silica 2016 US

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Solutions for Your TOUGHEST

MIXING Applications in

CHEMICALS

Dispersion of Fumed Silica

THE FIRST NAME IN HIGH SHEAR MIXERS


Dispersion of Fumed Silica
Fumed Silica (also called colloidal silica) is a fluffy white powder with an extremely
low density, marketed under trade names such as Aerosil®* and Cab-o-sil®*. With both
hydrophobic and hydrophillic grades available, it is widely used as a rheology modifier,
imparting highly thixotropic properties at relatively low percentages. It can also provide
increased tack, better stability in suspensions and prevents “sagging” and settling of
solids in a liquid system. For this reason it is particularly suitable for coatings, inks,
adhesives, resins, sealants and greases.

Fumed silica is also used in some pharmaceutical and cosmetic applications.

The Process
Despite the diversity of end uses and the various processing methods and equipment
used, (ranging from simple agitators to milling equipment) there are a number of
common processing requirement which must be satisfied in order to obtain maximized
“functionality”:

• Mixing equipment must be capable of rapidly incorporating and dispersing


the powder into the base liquid.
• Shear is required to obtain functionality. The dispersion equipment used has as much
of an effect on the viscosity obtained as the concentration of fumed silica. This must
be taken into account when formulating products or altering processing conditions.
• Vigorous in-tank movement must be maintained as the viscosity rises.

The Problem
Using conventional mixers and agitators, a number of problems can be encountered
during production:

• The powder is very low density and is extremely difficult to “wet out”; it floats on the
liquid surface.
• As the powder is extremely fine it poses real problems due to dusting.
• Long processing times are required to fully disperse the powder once it is wetted out.
• Low shear mixing devices are generally unsuitable for dispersing fumed silica. While
the powder may be wetted out, the lack of high shear mixing results in poor yield of
thickening effect.
• Formulations often contain excessive percentages of fumed silica to compensate for
poor yield.
• Incorrect dispersion can lead to great inconsistency between batches, especially when
excessive loadings have been used to compensate for poor yield.

*Registered trademarks of Evonik Industries AG and Cabot Corp. respectively


The Solution
These problems can be overcome by using a Silverson High Shear mixer. The
advantages stem from the 3 stage mixing action of the Silverson rotor/stator
assembly. Operation is as follows:

Stage 1
The powerful suction created by the high speed
rotation of the rotor blades draws both liquid and
solid ingredients into the workhead where they are
rapidly dispersed.

Stage 2
Centrifugal force drives the materials to the periphery
of the workhead where they are subjected to a
milling action in the precision gap between the tips
of the rotor blades and the inner wall of the stator.

Stage 3
The product is expelled from the head and projected
back into the body of the mix. Fresh materials are
simultaneously drawn into the head. In a short
mixing cycle all the material passes through the
workhead many times, rapidly becoming fully
dispersed.

The Advantages
• Fine dispersion results in improved product quality, stability and repeatability
between batches.
• Agglomerate-free mix.
• Shorter processing times reduces wear to mechanical parts.
• Hard tipped rotors and hard surfaced shafts are available as optional extras where
abrasive materials are processed.
• Some grades of fumed silica are “pumpable” and behave like fluids. The powder
can then be pumped from containers directly into the rotor, eliminating dusting/
handling problems.

Immersion units for batch operation, In-Line devices and Flashblend powder/liquid
mixing systems are used for the application, the selection of which depends on
factors including batch size, raw materials and the viscosity of the end product:
High Shear Batch Mixers
• Suitable for small batches
• Sealed units available
• Special units for abrasive products available

Silverson Ultramix
• Excellent in-tank movement
• Capable of rapidly incorporating large volumes of powders
• Ideal for higher viscosity mixes
• Ultra Sanitary CIP design
• Low maintenance

High Shear Bottom Entry Mixers


• Normally used in conjunction with an anchor stirrer/scraper
on high viscosity products; can be used alone on lower
viscosities

High Shear In-Line Mixers


• Ideal for larger batches
• Aeration free
• Must be used in conjunction with an efficient in-tank
agitator to wet out powder
• Easily retrofitted to existing plant
• Self-pumping, depending on product viscosity
• Multistage units available for higher degree of shear
• High Viscosity models available

Silverson Flashblend
• Ideal for larger batches
• Capable of rapidly incorporating large volumes of
powders
• Controlled powder addition rate
• Minimum operator input required
• Can be integrated with bulk powder dispensing
systems e.g. Big Bags (FIBCs)
• Silverson should be consulted regarding systems
involving solvents

For more information click here to go to www.silverson.com


Silverson Machines, Inc. 355 Chestnut Street, East Longmeadow, MA 01028
Ph: (413) 525-4825 [email protected]
Information contained in this report is believed to be correct and is included as a guide
only. No warranty is expressed or implied as to fitness for use or freedom from patents. Issue No. 1CA4
Silverson Machines reserve the right to change product specification without notice.

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