Liquid Solutions

ASSIGNMENTS

SECTION - I
SUBJECTIVE QUESTIONS

LEVEL-I
1. Calculate the molarity of pure water [d = 1 gm / litre]
2. A solution contains 410.3 gm of H2SO4 per litre of solution of 20ºC. If the density is 1.243 gm/ml,
what will be its molality.
3. The density of 3M sodium theosulphate solution is 1.25 gm/ml. Calculate (i) the percent by weight
of sodium theosulphate (ii) molality of Na+ ions
4. The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile solid
weighing 2.175 gm is added to 39.0 gm of benzene. The vapour pressure of solution is 600 mm of
Hg. What is the molecular weight of solid substance.
5. The freezing point of a solution containing 50cm3 of ethylene glycol in 50 gm of water is formed to
be –34ºC. Assuming ideal behaviour calculate the density of ethylene glycol (Kf for water = 1.86 k
kg mol–1.
6. Ten grams of a substance were dissolved in 250 ml of water and the osmotic pressure of the
solution was found to be 600 mm. of mercury of 15ºC. Find the molecular weight of the substance.
7. How many ethyl alcohol must be added to 1.0 litre of water so that the solution will freeze at 14ºF.
(Kf for H2O = 1.86ºC/mole)
8. A 0.5% aq. solution of KCl freezes at –0.24ºC. Calculate the Van’t Hoff factor of the solute at this
concentration. (Kf for water is 1.86º)
9. 0.48 gm of an organic compound dissolved in 10.6 gm of benzene lowered its freezing point by
1.8ºC. Find out the molecular weight of the compound. (Kf for benzene is 5.0 K)
10. Calculate the osmotic pressure of 0.5% solution of glucose at 18ºC, the value of the solution
constant is 0.0821 litre atm deg–1 mole–1.

LEVEL-II
1. What would be molality of solution made by mixing equal volumes of 30.0% by mass of H2SO4
(density 1.218 gm/c.c.) and 70% by mass of H2SO4 (density 1.218 gm/c.c.) and 70% by mass of
H2SO4 (density = 1.61 gm/c.c.)
2. A bottle of commercial sulphuric acid (density 1.787 gm/ml) is labelled as 86% by weight. What is
the molarity of the acid. What volume of the acid has to be used to make 1 litre of 0.2 M H2SO4 .
 Chemistry : Liquid Solutions

3. What would be the vapour pressure of a solution containing 0.05 moles of K2SO4 in 100 gm of
water at 300 K. Degree of dissociation of K2SO4 at this dilution is 0.8 and vapour pressure of pure
water is 31,834 mm of Hg
4. The mole fraction of CCl4(g) in the vapour in equilibrium with liquid mixture of CCl4 and SiCl4 is
0.3474. The vapour pressure of SiCl4 and CCl4 at this temperature are 238.3 and 114.9 mm
respectively. Calculate the percentage by weight of CCl4 in liquid mixture.
5. Calculate the osmotic pressure of solution obtained by mixing 100 ml of 3.4 % solution of urea
(molecular mass = 60) and 100 ml of 1.6% solution of cone sugar (molecular mass = 342) at 20ºC.
6. The solution of non-volatile solute in water freezes at –0.30ºC. The vapour pressure of pure water
at 298 K is 23.51 mm of Hg and Kf far water is 1.86 degree/molal. Calculate the vapour pressure of
this solution at 298 K.
7. A complex is represential as CoCl3.XNH3. Its 0.1 molal solution in water shows Tf = 0.558.0 Kf
for H2O is 1.86 K molality–1. Assuming 100% ionisation of complex and co-ordination number of
CO as six, calculate the formula of complex.
8. A 0.100 molal solution of HNO2 freezes at –0.198 C. The molal freezing point constant of water is
1.86 degree Kg solvant/mole solute. What is the percentage ionisation of nitrous acid at this
concentration.
9. Dry air was successively passed through a solutin of 5 gm solute in 80 gm water acid then through
pure water. The loss in weight of solution was 2.5 gm and that of pure water was 0.04 gm. What is
the molecular weight of solute.
10. At 25ºC, a solution containing 0.2 gm of polyisobutylene in 100 ml of benzene developed a rise of
2.4 mm at osmotic equilibrium. Calculate the molecular weight of polyisobutylene of the density of
solution is 0.88 gm/ml.

LEVEL-III
1. If potassium iodide, KI behaves as though it were completely dissociated in solution, the freezing
point of a-1 molal aq. solution should be –3.72ºC (The depression should be twice Kf because one
mole of KI provides two moles of ions in the solution)
Mercuric iodide, HgI2 , is now dissolved in the solution until all the iodide ion has reacted according
to HgI2 + 2I–  HgI4. What should be the freezing point of the new solution. Remember that
solution contains cations as well as anion, that it must be electricity neutral, and that all ions
contribute equally to the depression of the freezing point.
2. An aqueous solution of iodine, of volume 25 ml and containing 2 mg of iodine, is shapen with 5 ml
of CCl4 and CCl4 is allowed to separate. Given that the solubility of iodine per unit volume is 85
times greater in CCl4 than in water at the temperature of experiment and that both saturated
solutions may be considered to be ‘dilute’. Calculate the quantity of iodine remaining in the water
layer (b) if a second extraction is made of water layer using another 4 ml of CCl4 the quantity of
iodine remaining after the second extraction.
Liquid Solutions

3. Ambient air on particular day in Ahmedabad has the following conditions

Total pressure = 100 K Pa (750 torr)
Dry bulb temperature = 294.3 K
Dew point = 294.3 K
Find the absolute humidity of the air data : vapour pressure of water at 294.3 K = 2.5326 kPa = 19
torr.
4. A solid organic compound contains 18.3.1 C, 0.514 H, and 81.2% Br by weight. A solution of
0.793 gm of compound in 14.80 ml of chloroform (with density of 1.485 gm/ml, boiling point of
60.30ºC and a molal boiling point constant of 3.63 deg C kg solvent/mole solute) boils at 60.63ºC.
Find the molecular formula of the compound.
5. The freezing point of 0.02 mole fraction of acetic acid in benzene is 277.4 K. Acetic acid exist
partly as dinner. Calculate the equilibrium constant for dimerisation. Freezing point of benzene is
278.4 K and heat of fusion of benzene is 10.042 kJ/mole. Assume molarity and molality same.
6. 1 Kg of an aqueous solution of sacrose is cooled and maintained at –3.534ºC. How much 1 cl will
separate out if the solution molality is one.
Kf (H2O) = 1.86 kg mole–1 K.
7. A 0.10 M solution of HgCl2 in H2O freezes at –0.186ºC whereas a 0.10 M solution of Hg(NO3)2
freezes at –0.558º C. Deduce the structural states of these two compounds. The freezing point
depression constant for water is 1.86 kg mol–1 K and assume molality = molarity.
8. The coolant usually constains a solution of anti-freeze prepared by mixing equal volumes of
ethylene glycol and water. The density of ethylene glycol is 1.113 gm/c.c. Calculate the freezing
point of the mixture. Kf for water = 1.86 kg mol–1 K.
9. The vapour pressure of two miscible liquid (A) and (B) are 300 and 500 mm. of Hg respectively. In
a flask 10 mole of (A) is mixed with 12 moles of (B). However as soon as (B) is added, (A) starts
polymerising into a completely insoluble solid. The polymerisation follows first order kinetics.
After 100 minutes, 0.525 mole of solute is dissolved which arrests the polymerisation completely.
The final vapour pressure of the solution is 400 mm of Hg. Estimate the rate constant of the
polymerisation reaction. Assume volume change on mixing and polymerisation, and ideal
behaviour for the final solution.
10. The vapour pressure of H2O at 293 K is 2338 Pa and the vapour pressure of an aqueous solution is
22.98 Pa. If density of solution is 1010 kg/m3 at 313 K. Calculate the osmotic pressure at 313 K.
Molecular weight of solute = 60.
 Chemistry : Liquid Solutions

SECTION - II
SINGLE CHOICE QUESTIONS
1. Which solution will have lowest freezing point
(a) 1 % solution of glucose in H2O (b) 1% solution of sodium chloride in H2O
(c) 1% solution of zinc sulphate in H2O (d) 1% solution of urea in H2 O
2. Which pair of solution can we expect to be isotonic at the same temperature
(a) 0.1 M NaCl and 0.1 M Na2SO4 (b) 0.1 M urea and 0.1 M NaCl
(c) 0.1 M urea l and 0.1 M MgCl2 (d) 0.1 M Ca(NO3)2 and 0.1 M Na2SO4
3. A maxima or minima obtained in temperature composition curve of a mixture of two liquids
indicates.
(a) An azeotropic mixture
(b) a eutectic formation
(c) liquid are miscible with one another
(d) liquid are partially miscible at the maximum or minimum
4. In lowering of freezing point experiment the equilibrium exists between
(a) solid solvent and solid solute (b) liquid solvent and liquid solute
(c) liquid solvent and solid solvent (d) solid solvent and liquid solute
5. The pilots (1/xA) vs (1/YA), where XA and YA are mole fraction of log A in liquid and vapour phase
respectively, is linear with slope and intercept respectively given as

(a)
PAo
and

PAo  PBo  (b)
PAo
and
PBo  PAo
PBo PBo PBo PBo
PBo P o  Po PBo P o  Po
(c) o
and A o B (d) o
and B o A
PA PB PA PB
6. 0.2 molal acid HX is 20% ionised in solution K 'f  1.86 K molality–1. The freezing point to
solution is
(a) –0.45ºC (b) –0.90ºC
(c) –0.31ºC (d) –0.53ºC
7. When HgI2 is mixed with aqueous solution of KI then
(a) freezing point decreases (b) freezing point does not change
(c) freezing point increases (d) boiling point remain unchanged
8. The plant cell will shrink when placed in
(a) water (b) hypotonic solution
(c) hypertonic solution (d) isotonic solution
9. Glucose is added to 1 litre water to such an extent that Tf / K f because equal to 1/1000, the
amount of glucose added is
(a) 180 gm (b) 18 gm
(c) 1.8 gm (d) 0.18 gm
Liquid Solutions

10. Which of the following is incorrect

(a) Relative lowering of vapour pressure is independent of the nature of the solute and the solvent
(b) The vapour pressure is a colligative property
(c) Vapour pressure of solution is lower than that of solved
(d) The relative lowering of vapour pressure is directly proportional to teh original pressure
11. 1 mole benzene (p obenzene  42 mm) and two mole toluene (p otoluene  36 mm) will have
(a) total vapour pressure 38 mm.
(b) mole fraction of vapours of benzene above liquid mixture is 7/19
(c) positive deviation from Rault's law
(d) negative deviation from Rault's Law
12. Consider the vapour pressure composition graph, sp is equal to

P poB
vapour pressure

p oA
PA Q
R
PB

xA=1 S xB=1
xB=0 Composition xA=0

(a) PQ + RS (b) PQ + QR + RS
(c) SR + SQ (d) PQ + QR
13. When 1.2 gm of sulphur is melled with 15 gm of naphthalene, the solution freezes at 77.2ºC. What
is molar mass of this form of sulphur. Melting point of naphthalene is 80ºC and its Kf value is 6.80
km–1.
(a) 180 (b) 190
(c) 260 (d) 450
14. What is the molarity of HCl in a solution prepared by dissolving 5.5 gm HCl in 200 gm enthanol if
density of solution is 0.79 gm/ml.
(a) 0.93 M (b) 6  10–4 M
(c) 0.58 M (d) 1.7 M
15. pH of 0.1 M monobasic acid is measured to be 2. Its osmotic pressure at a give temperature is
(a) 0.1 RT (b) 0.11 RT
(c) 1.1 RT (d) 0.01 RT
16. The solution of H2SO4 of molarities x and y are mixed in the ratio of V1 and V2 ml to form a
solution of molarity M1. If they are mixed in the ratio of V2 ml and V1 ml, they form a solution of
V x M1 5
molarity M2. Given 1   1 and  then x : y is
V2 y M2 4
(a) 2 : 1 (b) 4 : 1
(c) 1 : 2 (d) 3 : 1
 Chemistry : Liquid Solutions

17. The pressure on a sample of water at its triple point is reduced whole the temperature is held
constant. Which phase changes are favoured.
(I) fusion (II) sublimiation (III) vaporiation
(a) I-only (b) III-only
(c) I and II only (d) II and III only
18. At 100ºC and 1 atm, if the density of liquid water is 1.0 gm / c.c. and that of water vapour is 0.006
gm/c.c. then the volume occupied by water molecules in one litre of steam of the temperature
(a) 0.06 c.c. (b) 0.6 c.c.
(c) 66 c.c. (d) 6 c.c.
19. The degree of dissociation of (A) a weak electrolyte AxBy is related to Van’t Hoff factor (i) by the
expression
i 1 i 1
(a)   (b)  
(x  y  1) (x  y  1)
x  y 1 x  y 1
(c)  (d)  
i 1 i 1
20. A certain solution of benzoic acid in benzene has freezing point depression of 2.4º
(Kf = 5.12º mol–1 kg) and boiling point elevation of 2.5º (Kb = 2.53 mole–1 kg). Select the correct
statement
Statement-I : There is dimer formation when undergoing freezing
Statement-II : There is no change when undergoing boiling.
Statement-III : reverse of I and II
Statement-IV : dimer formation in freezing and boiling state
(a) I, II (b) II and III
(c) III, IV (d) only I

SECTION - III
MULTIPLE CHOICE QUESTIONS
(with one or more than one answer correct)

1. Consider an ideal homogenous liquid solution of methanol (a volatile big) and water having vapour
pressure of Pmm Hg at 25ºC. If PMo and PWo are vapour pressure of pure methanol and pure water
respectively at 25ºC, then
(a) P  PMo (b) P  PMo
(c) P  PWo (d) P  PMo  PWo
2. Which are true statements for the following equilibrium
H 2 O(l ) H 2 O(g)
(a) Increase in pressure will result in the formation of more liquid water
(b) Increase in pressure will increase the boiling point
(c) Decrease in pressure will vaporize H2O(l) to a greater extent
(d) Increase in pressure will liquefy steam
3. When a non volatile solute is added to a pure solvent, the
Liquid Solutions

(a) vapour pressure of solution became lower pressure of the pure solvent
(b) rate of evaporation of pure solvent is reduce
(c) solute does not effect the rate of condensation
(d) rate of evaporation of the solvent-rate of condensation of the solvent at equilibrium
4. An aqueous solution of a solute which neither associates nor dissociates has freezing point
depression of XºC. An equimolar solution of a second salt has a freezing point depression of 3  ºC.
Salt has a freezing point depression of 3  ºC. The second solution could be a salt of formula
(assuming 100% dissociation)
(a) AB3 (b) AB2
(c) A3 B (d) A2B
5. When a solution of non-volatile solute is frozen and cooling is contimend, its
(a) freezing point remains constant (b) freezing point goes on decrease
(c) freezing point goes on increasing (d) only the solvent freezes out
6. According to Rault’s law, the relative decrease in the solvent vapour pressure over the solution is
equal to
(a) mole fraction of solvent
(b) mole fraction of solute
(c) the number of moles of solute
(d) 1 times the mole fraction of the solute which undergoes dissociation or association in the
solvent (i = Van’t Hoff factor)
7. Which is the correct statement
(a) minimum boiling azeotropic mixture boils at temperature lower than either of the two pure
components
(b) Maximum boiling azeotropic mixture boils at temperature higher than either of the two pure
components.
(c) Minimum boiling azeotropic mixture shows positive deviation.
(d) Maximum boiling azeotropic mixture shows negative deviation.
8. Which of the following is/are correct for a solution of a particular concentration
(a) molarity is always less than mole
(b) formality is equivalent to moarity
(c) mole fraction is equivalent to mass fraction
(d) normality of H2SO4 solution is double to that of its molarity
9. Which of the following forms ideal solution
(a) Ethyl bromide and ethyl iodide (b) Ethyl alcohol and water
(c) Chloroform and Benzene (d) Benzene and toulene
10. In which of the following cases osmosis take place. If the solutions are separated by semi permeable
membrane.
(a) 0.1 M NaCl and 0.2 M glucose (b) 0.1 M sucrose and 0.1 M fructose
(c) 0.05 M K4[Fe(CN)6] and 0.1 M CaCl2 (d) 10–3 M CaCl2 and 1.5  10–3 M NaCl
 Chemistry : Liquid Solutions

SECTION - IV
COMPREHENSION TYPE QUESTIONS
I. Consider the given system. Compartment ‘A’ contains 10 gm 1 ck and compartment ‘B’ contains 50
gm water at 273 K. Compartment ‘R’ contains air saturated with water vapour at 1200 mm Hg

A B

1. What will be the final pressure in the vessel after the volume of vessel has been changed to one third
(vapour pressure of water at this temperature 400 torr.)
(a) 3600 mm (b) 2800 mm
(c) 40 mm (d) 1200 mm

2. If the volume of compartment ‘B’ is increased to 1000 times the original one (temperature is
regulated to 298 K)
(a) There will be no change in vapour pressure
(b) All the vapour will condense to form liquid (similar to
(c) All the water will evaporate to form vapour attempting to maintain the vapour pressure
(d) The water will freeze and the vapour will condense

3. Now we changed the temperature to TºK. At this temperature the vapour pressure of water and ice
are 8 torr and 10 torr respectively. What will be the final pressure if the valve is opened
(a) 10 torr (b) 9 torr
(c) 8 torr (d) 25/3 torr

II.

A B

Compound ‘A’ and ‘B’ have following combination of solution

Liquid Solutions

A B
1. 0.1 M KCl 0.2 M KCl
2. 0.1 % (m/V) NaCl 10% (m/V) NaCl
3. 18 gm/L glucose 34.2 m/L sucrose
4. 20% (m/V) glucose 10% (m/V) glucose

4. The solution in which the compartment 'B' is hypertonic

(a) 1, 2 (b) 2, 3
(c) 3, 4 (d) 1, 4
5. Indicate the solution(s) in which the compartment 'A' will show the increase in volume
(a) 1 (b) 2
(c) 3 (d) 4
6. The solution in which there will be no change in the level of the solution in the compartment 'A' and
'B'
(a) 1 (b) 2
(c) 3 (d) 4

MATCHING TYPE QUESTIONS

7. Match the following :
(a) KCl (p) 33.33
(b) Na2SO4 (q) 100
(c) K4 [Fe(CN)6] (r) 50
(d) K3 [Fe(CN)6] (s) 25
(a) (a – q), (b – r), (c – s), (d – p) (b) (a – r), (b – q), (c – s), (d – p)
(c) (a – r), (b – q), (c – p), (d – s) (d) (a – s), (b – p), (c – r), (d – q)
8. Match the following :
(a) i < 1 (p) 0.2 M glucose solution
(b) i = 1 (q) Benzoic acid which forms dimer to the
extent of 75% in benzene
(c) i  1 (r) 0,1 M H2SO4
(d) i=3 (s) NO2 which is cooled from 373 K to 298 K
(a) (a – q, s), (b – p), (c – p, r), (d – r) (b) (a – q, p), (b – s), (c – p, r), (d – r)
(c) (a – q, s), (b – p), (c – p), (d – r) (d) (a – p), (b – q, s), (c – p), (d – p, r)
 Chemistry : Liquid Solutions

ASSERTION – REASONING TYPE QUESTIONS

The following questions consist of two statements, one labelled as ASSERTION (A) and REASON (R).
Use the following key to choose the correct appropriate answer.
(a) If both (A) and (R) are correct, and (R) is the correct explanation of (A).
(b) If both (A) and (R) are correct, but (R) is not the correct explanation of (A).
(c) If (A) is correct, but (R) is incorrect.
(d) If (A) is incorrect, but (R) is correct.

9. ASSERTION (A) : Henry law and Raoul’s law are not independent or one can be derived from
another.
REASONING (R) : The partial pressure is directly proportional to the mole fraction of the concerned
species for ideal solutions.
10. ASSERTION (A) : Larger the value of cryoscope constant of the solvent, lesser will be the freezing
point of the solutions.
REASONING (R) : Depression in the freezing point depends on the nature of the solvent.

11. ASSERTION (A) : Camphor is used as a solvent in the determination of molecular mass of
naphthalene and anthracene etc.
REASONING (R) : Camphor has high molal, elevation constant.

12. ASSERTION (A) : One molar solution is always more concent rated than one molal solution.
REASONING (R) : The amount of solvent is 1M and 1m aqueous solution is not equal.

13. ASSERTION (A) : Vapour pressure of 0.5 M KCl solution.

REASONING (R) : Lowering of vapour pressure is directly proportional to the number of species
present in the solution.

14. ASSERTION (A) : The sum of mole fractions of all the components of a solutin is unity.
REASONING (R) : Mole fraction is temperature dependent quantity.

15. ASSERTION (A) : 0.1 M solution of glucose has some increment in freezing point than 0.1 M
solution of Urea.
REASONING (R) : Kf for both has different value.
Liquid Solutions

SECTION - V
QUESTIONS
OBJECTIVE

A. Fill in the blanks

Given that Tf is the depression in freezing point of the solvent in a solution of a non–volatile
solute of molality, m, the quantity Lt (Tf / m) is equal to ……….
m o

B. True / False
1. Following statement is true only under some specific conditions. Write the condition, for it.
“Two volatile and miscible liquids can be separated by fractional distillation into pure
components.”

C. Single Choice Questions (Objective Questions)

1. For a dilute solution, Raoult’s law states that : The lowering a vapour–pressure is equal to
the mole–fraction of solute
(b) The relative lowering of avpour–pressure is equal to he mole fraction of solute
(c) The relative lowering of vapour–pressure is proportional to the amount of solute in solution
(d) The vapour–pressure of the solution is equal to the mole–fraction of solvent
2. A molal solution is one that contains one mole of a solute in :
(a) 1000 g of the solvent (b) 1L of the solvent
(c) 1L of the solution (d) 22.4 L of the solution
3. When mercuric iodide is added to the aqueous solution of potassium iodide :
(a) freezing point is raised (b) freezing point is lowered
(c) freezing point does not change (d) boiling point does not change
4. Which of the following 0.1M aqueous solution will have the lowest freezing point?
(a) Potassium sulphate (b) Sodium chloride
(c) Urea (d) Glucose
5. The freezing point of equimolal aqueous solution will be highest for :
(a) C6H5NH3Cl (aniline hydrochloride) (b) Ca(NO3)2
(c) La(NO3)2 (d) C6H12O6(glucose)
6. The molecular weight of benzoic acid in benzene as determined by depression in freezing point
method corresponds to :
(a) ionization of benzoic acid (b) dimerization of benzoic acid
(c) trimerization of benzoic acid (d) salvation of benzoic acid
 Chemistry : Liquid Solutions

7. 0.004 M Na2SO4 is isotonic with 0.01 M glucose. Degree of dissociation of Na2SO4 is :

(a) 75% (b) 50%
(c) 25% (d) 85%
8. The elevation in boiling point of a solution of 13.44 g of CuCl2 in 1 kg of water using the
following information will be :
(Molecular weight of CuCl2 = 134.4 and Kb = 0.52 K molal–1).
(a) 0.16 (b) 0.05
(c) 0.1 (d) 0.2

D. Multiple Choice Questions (More than one options are correct)

1. In the depression of freezing point experiment, it is found that the :vapour–pressure of the
solution is less than that of pure solvent
(b) vapour–pressure of the solution is more than that of pure solvent
(c) only solute molecules solidify at the freezing point
(d) only solvent molecules solidify at the freezing point.

SUBJECTIVE
1. The degree of dissociation of Ca(NO3)2 in a dilute aqueous solution, containing 7.0g of the salt
per 100g water at 100°C is 70 per cent. If the vapour pressure of water at 100°C is 760 mm,
calculate vapour pressure of the solution.
2. A very small amount of a non-volatile solute (that does not dissociate) is dissolved in 56.8 cm3 of
benzene (density 0.89g cm–3). At room temperature, vapour pressure of this solution is 98.88 mm
Hg while that of benzene is 100 mm Hg. Find the molality of this solution. If the freezing
temperature of this solution is 0.73 degree lower than that of benzene, what is the value of molal
freezing depression constant of benzene?
3. A solution of non-volatile solute in water freezes at –0.30°C. The vapour pressure of pure water at
298K is 23.51 mm Hg and Kf for water is 1.86 degree/molal. Calculate the vapour pressure of this
solution at 298K.
4. The molar volume of liquid benzene (density = 0.877g mL–1) increases by a factor of 27.50 as it
vaporizes at 20°C and that of liquid toluene (density = 0.867 g mL–1) increases by a factor of 7720
at 20°C. A solution of benzene and toluene at 20°C has a vapour pressure of 46.0 torr. Find the
mole fraction of benzene in the vapour above the solution.
5. What weight of the non-volatile solute, urea (NH2 – CO – NH2) need to be dissolved in 100g of
water, in order to decrease the vapour pressure of water by 25%? What will be the molarity of the
solution?
6. Addition of 0.643g of a compound to 50 mL of benzene (density 0.879 g/mL) lowers the freezing
point from 5.51°C to 5.03°C. If Kf for benzene is 5.12, calculate the molecular weight of the
compound
7. The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile non-
electrolyte solid weighing 2.175g is added to 39.0g of benzene. The vapour pressure of the
solution is 600 mm Hg. What is the molecular weight of the solid substance?
Liquid Solutions

8. The vapour pressure of a dilute aqueous solution of glucose (C6H12O6 ) is 750 mm of mercury at
373 K. Calculate (i) molality and (ii) mole fraction of the solute.
9. To 500 cm3 of water, 3 × 10–3 kg of acetic acid is added. If 23% of acetic acid is dissociated, what
will be the depression in freezing point? Kf and density of water are 1.86 K kg –1 mol–1 and
0.997 g cm–3 respectively.
10. The vapour pressure of two miscible liquids (A) and (B) are 300 and 500mm of Hg
respectively. In a flask 10 mole of (A) is mixed with 12 mole of (B). However, as soon as
(B) is added, (A) starts polymerisating into a completely insoluble solids. The
polymerization follows first-order into a completely insoluble solid. The polymerization
follows first-order kinetics. After 100 minute, 0.525 mole of a solute is dissolved which
arrest the polymerization completely. The final vapour pressure of the solution is 400mm
of Hg. Estimate the rate constant of the polymeristaion reaction. Assume negligible
volume change on mixing and polymerization and ideal behaviour for the final solution.
11. (a) 1.22 g C6H5COOH is added into two solvent and data of Tb and Kb are given as :
(i) In 100 g CH3COCH3 Tb = 0.17,
Kb = 1.7 kg Kelvin/mol
(ii) In 100 g benzene, Tb = 0.13 and
Kb = 2.6 kg /Kelvin/mol
Find out the molecular weight of C6H5COOH is both the cases and interpret the result

12. 75.2g phenol (C6 H5OH) is mixed with 1.0 kg of solvent (Kf = 14 K mol–1 kg). Freezing point
depression of the solution was 7K. Calculate % of phenol in dimmer form:
 Chemistry : Liquid Solutions

ANSWERS
SECTION – I
SUBJECTIVE QUESTIONS
Level-I

1. 55.5 M 2. 5.027
3. (i) 37.92% (ii) 7.730 m 4. 65.25
3
5. d = 1.13 gm/cm 6. 1198
7. 247.31 gm 8. 1.92
9. 125.78 10. 0.6628

Level-II
1. density = 1.61 gm/c.c. 2. M = 15.68, V = 12.75
3. 31.00 mm 4. 50%
5. 7.385 atm 6. p = 23.442 mm
7. [Co(NH3 )5Cl]Cl2 8. 6.5%
9. 70.31 10. 2.39  105

Level-III
1. 2.79ºC
2. 0.11 mg of iodine; 0.0061 mg of iodine
3. 16.16 gm/kg
4. C6H2Br4
5. Kc = 3.39
6. 353
7. (a) i = 0 show Hgcl2 does not ionise in the solution
(b)  = 1 shows Hg(NO3) is 100% ionised.
8. –33.39ºC
9. K = 1.0  10–4
10. 2.53  106 Pa
Liquid Solutions

SECTION – II
SINGLE CHOICE QUESTIONS
1. (b) 2. (d) 3. (a) 4. (c) 5. (b)
6. (a) 7. (c) 8. (c) 9. (d) 10. (d)
11. (a) 12. (c) 13. (b) 14. (c) 15. (b)
16. (a) 17. (d) 18. (b) 19. (a) 20. (a)

SECTION – III
MULTIPLE CHOICE QUESTIONS
1. (a, c, d) 2. (a, b, c, d) 3. (a, b, c, d) 4. (b, d) 5. (b, d)
6. (b, d) 7. (a, b, c, d) 8. (b, d) 9. (a, d) 10. (c)

SECTION – IV
COMPREHENSION TYPE QUESTIONS
1. (b) 2. (c) 3. (c) 4. (a) 5. (d)
6. (c)

MATCHING TYPE QUESTIONS

7. (a) 8. (a)

ASSERTION-REASONING TYPE QUESTIONS

9. (b) 10. (a) 11. (a) 12. (d) 13. (a)
14. (c) 15. (c)
 Chemistry : Liquid Solutions

SECTION - V
QUESTION
OBJECTIVE
(A) Fill in the blanks :
Kf
(B) True or false
If they form an ideal solution which obey Raoult’s law and for which :
H mixing  0 and Vmixing  0

(C) Single Choice Questions (Objective Questions)

(1) (b) (2) (a) (3) (a) (4) (a) (5) (d)
(6) (b) (7) (a) (8) (a)
(D) Multiple Choice Questions (More than one options are correct)
(1) (a), (d)

SUBJECTIVE
1. 745.3 mm 2. 5.034 K m–1
3. 23.4425 mm 4. 0.74
5. 18.52 m 6. 156.056 g/mol
–1
7. 72.5 g mol . 8. 0.9868, 0.73 mol kg–1
9. 0.288K 10. 1 × 10–4
11. (a) (i) M = 122 (ii) M = 244
12. 37%