TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES ChE REFRE: ch (ether 44 a SHER COURSE DAY 1- CHEMICAL AND PHYSICAL PRINCIPLES L Ithas been found by mass spectrometric analysis that in nature, the relative abundances of the various isotopic atoms of silicon are 92.23% “Si, 4.67% “Si and 3.1% ™Si. Calculate the atomic weight of silicon from this information and from the nuclidic masses. Nuclidic mas ses: Si 27.97693 u; "Si 28.97649 u; “Si 29.9737 u. ‘AL 28.085 B. 28.850u C._28.580u D. 28.058u Only two isotopes of copper are present in naturally Calculate the percent composition of naturally occurrin ‘occurring copper: "Cu (62.9298 u) and “Cu (68.9278 u). 1g “Cu using the atomic mass of 63.546 u, 13.8% H and 24.196 N. Its molecular weight is 116 g/mol A. 69.17% B._ 30.83% C._46.65% D. 53.35% '3._What is the mass of an electron? A_LIZE2AKg BL 122E22kg C_imeiske D. SA ESi he “Calculate the number of molecules in a tablespoon of sugar, CiaH,0,,, weighing 10.5 grams. _ A. 6.02 £23 B. 6.29 £24 | c 1.85 622 D. 1.13 £23 'S._The percent composition of an unknown element X in CH;X Is 3296, Which of the following is element X? AL H BF ore ecl Du 6._What is the empirical formula of a compound that is 51.9% carbon, 4.86% hydrogen, and 43.2% bromine? AL GH:Br B._CHeBra [Gab D. CoH» Br 7. Hexamethylenediamine is one of the materials used to produce a type of nylon. Elemental analysis gives 62.1% C, 1. What is the molecular formula? A. CoHsNy B._GHisN [Gch DCN Page 1 of 24% 3 A volumetric analysis of a gaseous mixture Is as follows: 12% CO, 4% O,, 82% N; and 2% CO. What is the percentage of CO on mass basis? _ 7 A 1% B. 12% C_ 15% D.19% '9._The density of a solution that is 20.0% by weight HCIO, is 1.138 g/mL. Calculate the molarity of HCIOs. AL 0.482 B. 1.99 [c. 3.45 D. 2.26 410. A solution is prepared by mixing 8 grams of ethanol and 50 grams of water. Calculate the molality of the solution? ‘A 30m BL 3.5m C_4m D. 45m jon of H,SO, if ithas a sperifc gravity of 1.84 and contains 95% H,S0 by weight? A. 3.56N B._5.63N | c 653N “| d. 35.6N 12. Convert a 0.25 M solution of H,S0,to normality. A_2N BIN [_c 05N DOAN 43, How many mililiters of water must be added to 5 mL of 12M HCI solution to make a 3M HC/ solution? A. 10m 8.15mi [© 20m. D. 25m 14. A solution is made by mixing 30,0 mL of &M HG, 100 mL of 2M HG, and enough water to make 200 ml of solution. What is the molarity of HCl in the final solution? ‘A. 0.455 M B. 100M. c_1.20M D._ 220M Page 2 of 2115. Express the concentration of a 3% by welght CaSO, solution in water in terms of ppm. ‘A._ 20,000 825,000 30,000 D._ 35,000 16. A polluted pond contains 25 ppb of lead ions. What is the concentration of lead ions in molarity units? A. 1.268 B.126-7M. C_2SEEM D. 0.121M. 17. Calculate the boiling point of a solution containing 4.27 g of sucrose in 50 g water. A 101.71°C B._101.12°C ._100.87°C D._100.13°C 48. When 5.50 g biphenyl (C.aHy) is dissolved in 100 g benzene, the bolling point increases by 0.903 °C. What is the Kb of benzene in K/molal? A 2.12 BL 253 2.80 D. 3.06 49. Calculate the freezing point of a solution containing 4.27 g of sucrose in 50 g water. AL -0.46 °C B. -0.65°C C_-0.76°C D, 082°C 20. If 4.35 g of ethylene glycol is dissolved in 100 g of water, the resulting solution has a freezing point of -1.31 °C. Galculate the molecular weight of ethylene glycol. A 61 B. 62 c 8 D. 64 Page 3 of 21Zi. A solvent storage tank 19.0 m high contains liquid styrene (sg 0.928). a pressure gage, which gives KPa reading, is fixed at the base of the tank to be used to determine the level of styrene. Determine the gage pressure when the __tankis full of styrene. A. 173 8.172000 C2004 D177 22. A Fahrenheit and a centigrade thermometer are both immersed in @ fluid and indicates a Fahrenheit reading that numerically twice that of the centigrade reading. What is the temperature of the fluid expressed as degrees B 780 C a3 [3.420 23. A fixed quantity of gas at a constant temperature exhibits a pressure of 737 torr and occupies a volume of 20.5 L Use Boyle’s law to calculate the volume the gas will occupy if the pressure is increased to 1.80 atm. AL 83941. B. 1L0L C381 D. 2051 24. A child’s balloon filled at 27 °C has a radius of 10 cm. if the balloon is taken outside on a very hot day when the temperature is 50°C, what is the new radius of the balloon? ‘A. 10.15em B, 10.25em [© 10.40cn D, 1055em 25. A balloon filed with helium has a volume of 10,000 liters at atmospheric pressure and 30 °C. it rises to a height where the pressure has dropped to 0.60 atm and the temperature Is -20 °C. What is the volume of the balloon then? ‘A. 10,0001. B._ 12,000. C._ 13,000 D._ 140001 26. A'5,000 em’ container holds 4.90 grams of ges when the pressure is 75 cm Hg and temperature is SO °C. What will be the pressure if 6.0 grams of this gas is confined in a 2,000 cm? container at 0 °C? ‘A104 em He B._139cmHe C_154.em Hg D._308em Hg Page 4 of 2127. Two gases occupy two containers, A and B. the gas in A, of volume 0.11 m’ exerts a pressure of 1.38 MPa. The gas, in B, of volume 0.16 m®, exerts a pressure of 0.69 MP2. The two containers are united by a tube of negligible Volume and the gases are allowed to intermingle. What is the final pressure in the container if the temperature remains constant? _ ‘A078 MPa B. 083 MPa C092 MPa [3.057 MPa 28. Calculate the density of H,S gas at 0.122 atm and 25 ° D._2.03e/ AL 4.9963 g/L B. 0.119 ¢/L ©_ 0.170) 29. At STP a 5.0 L flask filled with air has a mass of 543.251 grams. The air in the flask is replaced with another ges, and the mass of the flask is then determined to be 566.107 grams. The density of air is 1.29 g/L. What is the gas that replaced the air? ‘A._Neon B._ Oxygen [Nitrogen D. Xenon 30. A gas mixture contains twice as many moles of O, a3 Nz. Addition of 0.20 mole of argon to this mixture increases the pressure from 0.80 to 1.10 atm. How many moles of 0; are in the mixture? A 0355 B._ 0.178 C0533 [_5. 0.200 34. A100 ml sample of air exhaled from the lungs is analyzed and found to contain 0.083 g Nz, 0.0194 g 0,, 0.0064 g CO, and 0.00442 g water vapor at 35 °C. What is the total pressure of the sample? A__0.95 atm BL latm c. L2atm I ). 1.42 atm 32. From the data in #31, what is the partial pressure of water? ‘A._0.749 atm B._0.153 atm 0.0368 atm [3 006i9 atm Page 5 of 2133, At the same temperature and pressure, which gas will diffuse through air at the fastest rate? ‘A. Hydrogen “B._ Oxygen C._Carbon monoxide D. Carbon dioxide 34, It takes 16.6 min for a 10 mL sample of unknown gas to effuse through a pinhole. A 10 ml sample of helium ‘required 5.0 min. What is the molecular weight of the unknown gas? ‘A. 13.3 g/mol B._44.1 g/mol C177 g/mol D._73g/mol 35. The rms speed of the molecules in an ideal gas with molecular mass of 32 is 400 m/s. What is the average translational kinetic energy of the gas in joule? A. SE22 B._5.25E-21 C 425621 D. 456-21 36. A solution is prepared at 20 °C containing 7.8% wt. benzene in non-volatile oll (MW 422). Vapor pressure of benzene at 20 °C is 75 mm Hg. What is the equilibrium pressure of benzene vapor in mm Hg above the solution. A. 343 Bas C756 [pb 2358 137. Solvents A and 8 form an ideal solution. Solvent A has a vapor pressure of 345 mm Hg at room temperature. At the same temperature, solvent B has a vapor pressure of 213 mm He. What is the vapor pressure of a mixture in ‘which the mole fraction of A is 0.285? A. 213 BL 345 C568 D251 38. At30°Ca sample of hydrogen is collected over water in a 500 mi flask. The total pressure in the collection flask is 745 mm Hg. What will be the percent error in the amount of hydrogen reported if the correction for the vapor pressure of water is not made? A 0.0% 8.145% C_45% 0 443% 39, What Is the molar mass of biomolecule that produces an osmotic pressure of 12 mm H,O when 20 grams is dissolved in 400 mL of water at °C? The A. 1.6764 g/mol 8. 3.6265 C_ 9.765 g/mol D. 8:72 g/mol Page 6 of 2140, At 20 °C and one atmosphere, one liter of water will absorb 0.043 g of oxygen or 0.19 g of nitrogen. Atmospheric air is 20.9% oxygen by volume, and the remainder is assumed to be nitrogen. What mass of oxygen will be absorbed by one liter of water exposed to 20 °C air at one atmosphere? ‘A. 0.009 g [8 0150¢ C_023¢ D. 004g 41, A by-product of the reaction that inflates automotive airbags Is very reactive sodium, which can ignite in air. Sodium produced during inflation process reacts with another compound added to the airbag contents, KNOs, via the reaction: Na + KNO, -> K,O +Na0-+ Nz How many grams of KNOs ate required to remove 5.00 gram of sodium? A. 1108 8. 2.208 C4406 D. 1008 42. For the reaction NO; + H,0 > HNO + NO, How many grams of HNO, can be formed when 1.00 gram of NO; and 2.25 gram of water are allowed to react? A_0913g [ 8. 0.667¢ c i57¢@ D. 1378 43, Urea, CH,NRO, is used as a nitrogen fertilizer. It is manufactured from ammonia and carbon dioxide at high pressure and temperature. NHs + CO, -> CH,N;0 + HO. In a laboratory test, 10 g ammonia and 10 g CO, were added to a reaction vessel. What is the maximurn quantity of urea that can be obtained? A 10.26 [a a2ag C1368 D. 15.68 44. From the date in #43, how many grams of the excess reactant are left at the end of the reaction? “A._23gCO; [__B 12g00; C._1.2gNHy D._23—NH Page 7 of 21‘45, From the date in #43, if 11.2 g of urea is obtained in the laboratory preparation, what is the percentage yield of urea? A. 65.4% B. 75.9% 824% D._ 91.2% . The gas acetylene is produced according to the following reaction by treating calcium carbide with water: CaCy + H.0 > GH + Ca(OH), Calculate the number of hours of service that can be derived from 1.0 Ib of carbide in an acetylene lamp burning 2 ft’ gas per hour at a temperature of 75 °F and a pressure of 743 mmHg. AL 340hr B. 3.45 hr © 2a7hr D._1.86hr 47. Carbon dioxide decomposes at elevated temperature to carbon monoxide and oxygen. At 3000 K, 2 mole of CO; is placed in a 1 L container and allowed to attain equilibrium. At equilibrium, 0.90 mole CO; remains. What is the value for Kc at this temperature? A 0.82 B 188 C244 D. 3.2 448. The equilibrium constant, Ke, for the dissociation of Hi into hydrogen gas and iodine vapor is 21 at a certain temperature. What will be the molar concentration of hydrogen gas if 15 grams of HI gas is introduced into 2 12.0 Lflask and allowed to come to equilibrium? ‘A._4.58 mol/L B. 0.00687 mol/L |G. 446-5 mol/L D._0.137 mol/L 49, Consider the reaction: H; + |, €> HI Kye = 25. Determine the number of moles of H: remaining when 1 mole of both Hand |, are equilibrated in a 1 liter container. ‘A_1/6 mole B._2/7 mole 5/7 mole D._5/6 mole 50. The reaction of Bra q and Ch « to form BrCl jy has an equilibrium constant of 15 at a certain temperature. If 10 {grams of BrCl is present in a 15 Lreaction vessel, initially, what will the concentration of BrCl be at equilibrium? ‘A. 3.8E-3 mol/L 3mo/t | _C._1,976-3 mol/L D._9.9E-4 mol/L. - Page 8 of 21,51. Given the reaction A + B > 2C, K= 50. Determine the final concentration of C when 1 mole of both A and B are added to a 1 liter container containing 0.1 mole C. A. 0.78 mole B._0.88 mole 1.66 mole D._ 185 mole ‘52. A2 L flask is filled with 0.2 mole Hi. itis allowed to r flask was found to contain 0.078 M HI, calculate Kp. ach equilibrium at high temperature. if at equilibrium the A. 4.266 BL 4265 © 12E7 D._ 0.0199 '53, Ammonia is formed from a mixture of 3 moles hydrogen and 1 mole of nitrogen. At lower temperature the yield is higher, but the time require for equilibrium to be reached be too great to be practical, except for the addition of a catalyst. The pressure is kept high and the temperature low as practical. Under equilibrium conditions at 400 °C and 10 atm pressure, 3.85 mole percent of ammonia is obtained. Calculate Kp for the reaction. The ratio of 3 volumes of hydrogen to 1 volume of nitrogen is maintained, regardless of the amount of ammonia formed. Of the 196.15 percent by volume which is not ammonia, one-fourth is nitrogen and the remaining is hydrogen. ‘A. 0.000139 B._0.000145 0.000157 D. 0.000168 ‘54, The reaction CO; +H; CO + H,0 was investigated by passing mixtures of CO; and Hy over a catalyst at 900 °C at ‘atm pressure. The resulting gas was chilled quickly to room temperature by passage through a capillary and was analyzed. In one experiment the partial pressure were as follows: CO, = 0.2142; H, = 0.2549; CO 2654; H,0 = 0.2654 atm. Calculate the number of moles of hydrogen present in another equilibrium mixture containing 22.72 moles of CO, 22.72 moles H,0 and 48.50 moles CO,. ‘A._76.45 moles B._8.25 moles C_5.48 moles D._10.1 moles 55, When NO3is cooled to room temperature, some of it reacts to form a dimmer, Nz0,, through the reaction NO, © Nas. Suppose 15.2g of NOs is placed in a 10 L flask at high temperature and the flask is cooled to 25 °C. The total pressure is measured to be 0,500 atm. What is the partial pressure of NO; in the flask after the reaction come to equilibrium? ‘A. 0.19 atm B._0.25 atm 0.28 atm D._0.32 atm Page 9 of 24‘56. Ethanol is manufactured by the hydrogenation of acetaldehyde. The feed gas to the reactor contains 30 mole% acetaldehyde 40 mole% hydrogen, 20 mole% nitrogen and 10 mole% water. |f the recation comes to equilibrium: at 650k and 2 bar, and if no other reaction occurs, what is the mole fraction of acetaldehyde to the product gas ‘from the reactor? Assume ideal gases and, for the given reaction, AG° = ~.027 Ki/mole at 650 K (P? = 1 bar). ‘A. 0.120 8. 0.163 C239 D._0.283 57. For the reaction NaHSO, yj 3 NaS,0 iy + HO jg, AH = 19,800 cal and 6G = 9,000 cal at 25 °C. Assuming OH to be constant, calculate the dissociation pressure of NaHSO,at 700 K. ‘A. 13atm B._27 atm Sham D._105 atm 58. Potassium hydroxide ionizes completely in water. What is the pH of 0.05 M KOH? AL 13 B. 115 C25 Daa7 59. The pH of acid rain may be A 16 B 16E3, C 6.3612 ¢ a5 low as 2.80. What is the hydronium ion concentration of such acid rain? D. 9.762 60. Giycolic acid, a constituent of sugar-cane juice, is used In the processing of textiles and leather. A0.10 M solution of glycolic acid, HOCHCOOH, has a pH of 2.41. What is the K, for the acid? ‘A. 16E3 B64, C L6ES D. 16E6 Gi. From the date from #60, what is the degree of ionization in the 0.10 M solution? A 3.9% 8, 89% [© 121%) D.a7.7% Page 10 of 21662, Calculate the OH in 0.1 molar ammonium hydroxide solution K, = 1.8E-5. ‘A. 136-2 B 1363 C 4.264 D. 426-2 63. A student is titrating 50 mL of 0.2 N HCI solution with a solution of 0.2N KOH. He accidentally adds one ml too much titrant. What is the pH of the resulting solution? A. 103 8. itt G27. D.73 (64, Calculate the pH of 20.01 M NH,NO, solution given K, = 166-5 for NH. AL 24 B36 C42 D586 65, Calculate the percent ionization of 0.10 M butanoic acid (K, = 1.5E-5) in a solution containing 0.05 M sodium butanoate. ‘A. 3.065 B._3.0E-4 © 3062 D452 66. Ina titration, 2.7 cm? of 0.100 mol dm® sodium hydroxide, NaOH, solution is added to 25.0 em’ of 0.125 mol dm? benzoic acid, CcH;COOH solution. Calculate the pH of the resulting solution given that the pk, of benzoic acid is, 4.19. ‘A, 33 B. 4.12 C705 D. 9.32 Page 11 of 2167. The solubility product of Pbi is 7.5E-S. What is the molar solubility of Pbi,in distilled water? iL a B._ 1256-3 C 5.0E4 D. 8955 68. The solubility of gold (tli) nitrate is 1.0E-4 g/L. what is the solubility product of Au(NO3).? A. 1.0E-16 B.2.7E-15 C._1.26-26 D. 3.26-25 69. What is the equivalent weight of a weak acid that requires 26.3 mL of 0.122 M KOH to neutralize 0.682 gram of the acid? ‘A Zid glequiv B. 4.70 g/equiv C147 g/equiv D. 682 g/equiv 70. What volume of 0.125 M H,SOs Is required to neutralize 2.50 g of CalOH),? AL 54m 8.270 mL 135 mb D070 mi 71. In standardizing a solution oF HCI, it found that 47.26 ml of the acid are equivalent to 1.216 g of pure Na,CO, What is the normality of the acid? A. 0.4855 8. 0.3540 €_0.S020N D. 0.3902 N 72. Vinegar is an aqueous solution of acetic acid. A 5 mL sample of a particular vinegar requires 26.90 mL of a 0.175 M NaOH for its titration. What is the molarity of acetic acid in the vinegar? A052 BL 1.04 © 096 D047 Page 12 of 2173. A mbature of Na;CO, and BaCO, weighing 0.2000 g requires 30.00 mL of 0.1000 N acid for complete neutralization. ‘What is the percentage of Na,CO; in the sample? A. 55.7% B. 40.3% 34.4% D. 42.1% 74. A i-gram sample impure K;CO; is taken for analysis. The solution of dissolved sample required 58.10 mL of 0.14 HCl. However, 0.65 mL of NaOH was used for back titration (1. mL HCl is equivalent to 2.60 mL NaOH). Calculate the putity of the sample expressed as percent K;0. ‘A. 38.14% B._40.23% C 34.4% D._ 42.1% 75. A mixture contains NazCOs, NaOH and inert matter. A sample weighing 1.500 g requires 28.85 mil of 0.500 N HCI to reach a phenoithalein end point. And an additional 23.85 mL to reach a methyl orange end point. What is the percentage of NaOH in the sample? A. 84.27% B. 50.68% C_2057%. D. 6.67% 76. What is the mass of precipitate Formed when 12.0 ml of 0.150 M NaCl is added to 25.0 ml of @ 0.0500 M AgNO, solution? A. 2588 B 01798 C3608 D. 0.2588 Page 13 of 2177. K 2.35-gram sample was dissolved in water and the chioride ions were precipitated by adding sliver nitrate. If 0.435 g precipitate was obtained, what is the percentage of chlorine in the sample? ‘A. 10.8% B. 4.6% C_ 43.5% __ | d. 18% 78. A super phosphate fertilizer was analyzed for phosphorus. A 0.5414-gram sample produce @ 0.1277 gram of Mg:P:0) residue upon ignition of the magnesium ammonium phosphate precipitate. The percentage of P,0; presentin the sampleis A 205% | 8. 18.20% C_15.0056 D. 14.02% 78. A 0.3991 gram of an unknown sample containing chloride is dissolved and precipitated with 4298 mL excess 0.1056 M AgNO; A sintered glass crucible weighing 23.4101 g is used to fitter out the resulting AgCl. The new weight of the dried crucible is 23.9622 g. Compute the percent of chlorine in the sample. AL 37.56% _ [8 47.82% Cc 34.22% [d. 27.33% ‘80. What is the molar specific volume of a gas in m*/kmol at 1.722 MPa and 99 °C if the compressibility of the gas at these conditions is 0.87? ASA Baa © 16 035 ‘81. Using the Van der Waal’s equation, calculate the pressure exerted b 1 mole of carbon dioxide at 0°Cin a volume of iL. A. 2.45 atm B._11.6atm C_19.8.atm D. 27.9 atm Page 14 of 21‘82. A mass of 500 g gaseous ammonia contained in a 30,000 cm’ steel bomb immersed in a constant temperature bath at 65 °C. Calculate the pressure of the gas using the Redlich-Kwong equation. —_ Ls A. 27.51 bars 8. 23.86 bars [ c._25.40 bars |b. _30.70 bars ‘83. A 20-V potential difference is applied across a parallel combination of 2 10-ohm resistor and a 30-ohm resistor. The current in the 10-ohm resistor is A OSA B. 067A © iA [0 2a ‘84, How many calories are developed in 2 min in an electric heater which draws 3.0 ampere when connected to a 220 volt line? ‘A. 14,800¢al B. 18,920 cal C16,500 cal D._ 17,170 cal 85. How many grams of iron can be plated out at the cathode if a solution of Fe™ is electrolyzed by a current of 1 ampere for 30 minutes? A. 052 8 D. 166 86, An aqueous solution of gold (ll) nitrate is electrolyzed with a current of 0.555 ampere until 1.32 g au has been deposited on the cathode. If the atomic weight of Au is 197, determine the duration of the electrolysis. A. 65.43 min B._ 23.67 min. C_58.28 min. D._ 60.00 min. Page 15 of 2187. in the electrolysis of aqueous NaC] how many liters of Ch; ) at STP are generated by a current of 7.50 A for period of 50 min? ‘A. 45,000 L B 261 C5220 D. 1041 188. What current Is required to produce two grams of metallic copper from copper sulfate solution in 1.5 hours? A O87A B Liza ] ¢ 1528 D. 185A 189. One faraday of current was passed through the electrolytic calls placed in series containing solutions of Ag’, NI™ and Cr” respectively. The amount of Ag (AW 108), Ni (AW 59) and Cr (AW 52) deposited will be: A 108gAg,.295eNi [ B. 108gAg 108g Ni, C 108g Ag, 59g Ni, D. 108g Ag, 1175¢ 175 gCe 108 g Cr 52gCr Ni, 166 g Cr 90. From the following heats of reaction: 2C+Hig> GH OH=227 kl/mol 6C+3H2i > CoHey — BH= 49 ki/mol Calculate the heat for the reaction 3C,H2yp -> CeHew ‘A_26.7ki/mol 8. -26.7 i/mol 78 Wi/mol D._-632 ki/mol 91. Consider the following reaction: 2Na , + Cly jg -> 2NaCl jy OH = -821.8 ki, what is the amount of heat transferred ‘when 5.6 grams of Na reacts at constant pressure? ‘A 8218h) B. 4.6001) C_ 2.08210 D._L0E2 Ki Page 16 of 2192. 1¢ AH for the formation of NOCl,,) from the gaseous elements is 51.71 ki/mol at 25 °C. if the gases are ideal, calculate the AU. A. 52.95 kl/mol B._56.44 ki/mol 58.51 ki/mol D._60.27 ki/mol ‘93. The heat of combustion of a n-heptane at constant volume and 20 °C is 1148.93 kcal/mole. What is the value of the heat of reaction at constant pressure? A. -115.13 cal/mole 8. -1151.3 keal/mole C_-1151.3 cal/mole D._ 1151.3 kcal/mole ‘94, Calculate the heat of reaction for the following at 25 °C and 4 atm; CaGs4)+ 2H:0 y-> Ca(OH) CoH pe A. -20715 cal B._-24800 cal C -29972 ca D._-35420 cal ‘95. A special purpose piece of laboratory glassware, called a pycnometer, is used to measure liquid densities. it has a volume of 25 cc and a mass of 17.24 g when tt Is full of air. When filled with a liquid of unknown density, its mass = 45, G. what is the density of this liquid? A. dai g/mt B. 1.25 g/ml © 4a2 gmt D. i155 ¢/mi ‘96. Using the Antoine equation, the vapor pressure of tetrahydrofuran at 80°C is estimated to be. torr. A200 B. 1518 c 1173 D, 2562, Page 17 of 2197. The coefficient of viscosity for water vapor at 150 °C and 1.01 bar is 1.44585 Pa-s. Calculate the molecular diameter of the water molecule under these conditions. A. 4.22nm B._3.75am I 212m D._0.40nm ‘9B. A gas whose viscosity & 200 uP flows through a capillary tube 2 mm in diameter an d 2 meters long. iS liters of _g2S pass through the tube every 10 seconds, what must be the pressure head in dynes/cm?? A._5.0965 B. 7.5655 C_8.3265 D. 9.0455 89. A certain liquid has a viscosity of 164 poise and a density of 3.2 g/ml. How long will it take for platinum ball with a 2.5 mm radius to fall 1 cm through the liquid? Density of platinum is 21.4 g/em’. A. 4055 B. 28.45 C3345 D. 48.95 100. A light machinery oil has viscosity of SE-2 Pa-s and density of 870 kg/m? at 25 °C, how long will it take for @ sample to pass through a viscometer if water under the same conditions takes 1 minute? ‘A._59.9 min 8.45.8 min C_38.8 min D._27.9 min Page 18 of 21101. A liquid of density 850 kg/m having a surface tension of 0.055 N/m, will rise how far in a glass capillary of 1.4 mm inside diameter? ‘A_19mm 3 14mm D._0.45 mm 102. Which of these 0.1 M solution will give the highest boil ling at 1 atm? ‘A. Table salt solution B._ Barium chloride C_ Sugar solution D._ Potassium chloride 103. Laci is a salt, and tke virtually all salts it is completely dissociated into ions in aqueous solution. Suppose we dissolve 0.2453 g of LCI? in 10 g of HO. What will be the boiling point of the solution at atmospheric pressure, assuming ideal solution behavior? ‘A. 100.205 °C B._100.051°C C_100.410°C D._100.103°C 104. Find the K, for tartaric is of importance and that 0.10 m= 0.10 M. A. 246-6 BL 5SES I CBE id if a 0.10 m aqueous solution freezes at 0.205 °C. Assume that only the first ionization D. 1ae3 105. The osmotic pressure at STP of a solution made from 2 L of NaCl jy containing 117 g of NaCl is? ‘A. 44.7 atm B._ 48.87 atm C_89.54atm D. 1i7atm 106. How many KJ of heat be removed from 1000 g of water (heat capacity of 4.184 1/g-K) to lower the temperature from 18 °Cto 12°C? A_25E-2K) 8. 14K c 42K D250 Page 19 of 21107. Freon-11, which has the chemical formula CCIyF, has a normal boiling point of 23.8 °C. The specific heats of CChF and CCHF jg are 0.87 and 0.59 J/g-K respectively. The heat of vaporization Is 24.75 ki/mol. Calculate the heat required to convert 10.0 g of Freon-11 from a liquid at -50 °C to a gas at 50°C. A. 015K) 8. 064K C18 D260 108. in an experiment, 0.02 kg of @ substance is heated in a bath of boiling water until ts temperature Is approximately 100 °C. the substance is then placed in an insulated container that is holding 0.10 kg of water at 25°C. the final temperature of the mixture is 32 °C. The specific heat of substance, in kd per kg per °C, is? A. 2.16 B. 257 Tc 4.19 ]_D. 10 109. A25 gice cube at 0°C is placed in a glass with 2.5E2 g of tea at 25 °C. What temperature will the tea cool to? Cp st ten 9 4 18g Si eee a E AL 243°C B. 208°C ] ¢ 15s% Tb. 105°C 710. Calculate the enthalpy change upon converting 1 mol of ice at -25 °C to water vapor at 125 °C under a constant pressure of 1 atm. The specific heats of ice, water, and steam are 2.09 4/g-K, 4.18 /g-K and 1.84 J/g-k, respectively. For water the heat of fusion is 6.01 kl/mole, and the heat of vaporization is 40.67 ki/mol. A. 40K) B. 48k © s6k D. 60K Page 20 of 21111. Ten kilograms of ice -10 °C is added to 100 kg of water at 20 °C. What is the resulting temperature in °C of the water? Assume an insulated container. ‘A. 12.65 B. 9.28 C1183 D._ 10.45 112. Polonium crystallizes in a simple cubic pattern with a unit cell length of 3.63 angstrom. Estimate the density of Po ing/em’. AL 5.44 B. 612 I Cc 784 D. 9.20 Poge 21 of 21