SWAK

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Product name : SWAK

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Swagelok Supplier:
29495 F.A. Lennon Drive Distributor, add your contact information
44139 Solon, OH - United States
T 440-349-5600 - F 440-519-3304
www.swagelok.com

1.4. Emergency telephone number

Emergency number : Infotrac: North America: 1-800-535-5053 International: 1-352-323-3500

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU)
2015/830 (REACH Annex II)
Organic Peroxide Category E H242
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category H319
2
Skin sensitization, Category 1 H317
Specific target organ toxicity (single H335
exposure) Category 3
Hazardous to the aquatic environment - H413
Chronic Hazard Category 4
Full text of H statements : see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labeling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS07
Signal word (CLP) : Warning
Hazardous ingredients : Poly(oxy-1,2-ethanediyl), .alpha.,.alpha.'-[(1-methylethylidene)di-4,1-phenylene]bis[.omega.-[(2-
methyl-1-oxo-2-propenyl)oxy]-; Polyethylene glycol; Cumene hydroperoxide
Hazard statements (CLP) : H242 - Heating may cause a fire.
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H413 - May cause long lasting harmful effects to aquatic life
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P234 - Keep only in original packaging.
P240 - Ground and bond container and receiving equipment.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 - Wash hands, forearms and face thoroughly after handling.
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SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

P271 - Use only outdoors or in a well-ventilated area.

P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear personal protective equipment (PPE).
P302+P352 - IF ON SKIN: Wash with plenty of water.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction)
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use media other than water to extinguish.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P410 - Protect from sunlight.
P411 - Store at temperatures not exceeding .
P420 - Store separately.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.

2.3. Other hazards

Other hazards not contributing to the : Exposure may aggravate pre-existing eye, skin, or respiratory conditions. Inhalation of fumes
classification from overheating "TEFLON" PTFE may cause polymer fume fever, a temporary flu-like illness
with fever, chills and sometimes cough, of approximately 24 hours duration. This material
contains an organic peroxide. Heating may cause hazardous decomposition. Hazardous
decomposition products from peroxides are flammable and can be explosive under
confinement. Dust is not expected to be generated, however repeated or prolonged exposure
to titanium dioxide dust via inhalation is suspected of causing cancer of the respiratory tract.
Due to the product’s final form, combustible dusts are not likely to be generated, however if
small particles are generated during further processing, handling or by other means, may form
combustible dust concentrations in air.

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according to Regulation

(EC) No. 1272/2008 [CLP]
Poly(oxy-1,2-ethanediyl), .alpha.,.alpha.'-[(1- (CAS-No.) 41637-38-1 30 - 40 Skin Irrit. 2, H315
methylethylidene)di-4,1-phenylene]bis[.omega.-[(2- (EC-No.) 609-946-4 Eye Irrit. 2, H319
methyl-1-oxo-2-propenyl)oxy]- Skin Sens. 1, H317
STOT SE 3, H335
Aquatic Chronic 4, H413
Polyethylene glycol (CAS-No.) 25322-68-3 20 - 30 STOT SE 3, H335
(EC-No.) 500-038-2
Cumene hydroperoxide (CAS-No.) 80-15-9 <= 1 Org. Perox. E, H242
(EC-No.) 201-254-7 Acute Tox. 4 (Oral), H302
(EC Index-No.) 617-002-00-8 Acute Tox. 4 (Dermal), H312
Acute Tox. 3 (Inhalation:dust,mist), H331
Skin Corr. 1B, H314
STOT RE 2, H373
Aquatic Chronic 2, H411
Name Product identifier Specific concentration limits: CLP
Cumene hydroperoxide (CAS-No.) 80-15-9 (C < 10) STOT SE 3, H335
(EC-No.) 201-254-7 ( 1 =<C < 3) Eye Irrit. 2, H319
(EC Index-No.) 617-002-00-8 ( 3 =<C < 10) Eye Dam. 1, H318
( 3 =<C < 10) Skin Irrit. 2, H315
(C >= 10) Skin Corr. 1B, H314

Full text of R- and H- phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.

Created On: 10/28/2022 EN (English US) 2/8

SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

First-aid measures after skin contact : Wash with plenty of soap and water. water. Wash contaminated clothing before reuse. Specific
treatment (see first aid measures on this label). If skin irritation or rash occurs: seek medical
attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause an allergic skin reaction. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Use extinguishing measures that are
appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Contains substances that are combustible dusts. If dried and allowed to accumulate, may form
combustible dust concentrations in air that could ignite and cause an explosion. Take
appropriate precautions.
Explosion hazard : Product itself is not explosive but if dust is generated, dust clouds suspended in air can be
explosive.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Avoid breathing (vapor, mist, spray). Do not get in eyes, on skin, or on clothing. Avoid
generating dust. Remove ignition sources. Keep away from heat, hot surfaces, sparks, open
flames, and other ignition sources. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : Keep away from heat, sparks, open flames, hot surfaces. – No smoking. This material contains
an organic peroxide. Heating may cause hazardous decomposition. Hazardous decomposition
products from peroxides are flammable and can be explosive under confinement. Inhalation of
fumes from overheating "TEFLON" PTFE may cause polymer fume fever, a temporary flu-like
illness with fever, chills and sometimes cough, of approximately 24 hours duration.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. Avoid breathing vapor, mist or spray. Use only outdoors or in a well-ventilated area.
Avoid dust formation.
Hygiene measures : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out
of the workplace. Wash contaminated clothing before reuse.

Created On: 10/28/2022 EN (English US) 3/8

SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep only in the original container in a cool, well ventilated place away from : children. Keep
container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Strong acids, strong bases, strong oxidizers, amines, active metals, ammonia, combustible
materials, reducing agents, pure oxygen, oxygen scavengers, peroxides.
Storage area : Store in a cool, dry, ventilated area, away from incompatible substances. Keep from freezing.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available

8.2. Exposure controls

Appropriate engineering controls:
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate
ventilation, especially in confined areas. Ensure all national/local regulations are observed. Proper grounding procedures to avoid static electricity
should be followed.
Personal protective equipment:
Avoid all unnecessary exposure.

Materials for protective clothing:

Impervious clothing

Hand protection:
Wear protective gloves.

Eye protection:
Chemical goggles or safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation,
oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection.

Environmental exposure controls:

Avoid release to the environment. Avoid creating or spreading dust.
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Grainy off-white paste with mild odor.
Color : Colorless.
Odor : Low odor.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : > 230 °F
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable
Created On: 10/28/2022 EN (English US) 4/8
SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Vapor pressure : No data available

Relative vapor density at 20 °C : No data available
Relative density : 1.3 g/ml
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
This material contains an organic peroxide. Heating may cause hazardous decomposition. Hazardous decomposition products from peroxides are
flammable and can be explosive under confinement.
10.2. Chemical stability
Stable under normal conditions of use.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Direct sunlight, extremely high or low temperatures, and incompatible materials. Sparks, heat, open flame and other sources of ignition. Dust
accumulation (to minimize explosion hazard). UV light sources.
10.5. Incompatible materials
Strong acids, strong bases, strong oxidizers, amines, active metals, ammonia, combustible materials, reducing agents, pure oxygen, oxygen
scavengers, peroxides.
10.6. Hazardous decomposition products
Toxic gases may be formed, fluoride compounds, silicon oxides, carbon oxides (CO, CO2), phenolic compounds, acrid smoke, hydrogen.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Not classified

Polyethylene glycol (25322-68-3)

LD50 oral rat 22 g/kg
LD50 dermal rabbit > 20 g/kg
Cumene hydroperoxide (80-15-9)
LD50 oral rat 382 mg/kg
LD50 dermal rabbit 0.126 ml/kg
LC50 inhalation rat (ppm) 220 ppm/4h
Irritation : Not classified
Corrosivity : Not classified
Sensitization : Not classified
Repeated dose toxicity : Not classified
Carcinogenicity : Not classified
Mutagenicity : Not classified
Toxicity for reproduction : Not classified

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms

SECTION 12: Ecological information

12.1. Toxicity
Ecology - water : May cause long lasting harmful effects to aquatic life.
Aquatic acute : Not classified
Aquatic chronic : May cause long lasting harmful effects to aquatic life.

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SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

Cumene hydroperoxide (80-15-9)

LC50 fish 1 3.9 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])

12.2. Persistence and degradability

SWAK
Persistence and degradability May cause long-term adverse effects in the environment.
Polyethylene glycol (25322-68-3)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
SWAK
Bioaccumulative potential Not established.
Polyethylene glycol (25322-68-3)
Bioaccumulative potential Not established.
Cumene hydroperoxide (80-15-9)
BCF fish 1 35.5
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available

12.6. Other adverse effects

Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to meet all regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : Not applicable

IMDG
Transport hazard class(es) (IMDG) : Not applicable

IATA
Transport hazard class(es) (IATA) : Not applicable

ADN
Transport hazard class(es) (ADN) : Not applicable

Created On: 10/28/2022 EN (English US) 6/8

SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

RID
Transport hazard class(es) (RID) : Not applicable

14.4. Packing group

Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Not Evaluated

- Transport by sea
Not Evaluated

- Air transport
Not Evaluated

- Inland waterway transport

Not Evaluated

- Rail transport
Not Evaluated
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no REACH candidate substance
Contains no REACH Annex XIV substances.

15.1.2. National regulations

No additional information available

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Other information : None.

Full text of R-, H- and EUH-phrases:
Acute Tox. 3 (Inhalation:dust,mist) Acute toxicity (inhalation: dust, mist) Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
Aquatic Chronic 4 Hazardous to the aquatic environment - Chronic Hazard Category 4
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Org. Perox. E Organic Peroxide Category E
Skin Corr. 1B Skin corrosion/irritation Category 1B
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1

Created On: 10/28/2022 EN (English US) 7/8

SWAK
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

STOT RE 2 Specific target organ toxicity (repeated exposure) Category 2

STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H242 Heating may cause a fire.
H302 Harmful if swallowed
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H331 Toxic if inhaled
H335 May cause respiratory irritation
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
H413 May cause long lasting harmful effects to aquatic life

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

Created On: 10/28/2022 EN (English US) 8/8