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Atoms (Solution)

1. The number of possible elements in the hydrogen spectrum is 60. The maximum number of states for each value of n is 2n2. 2. Bohr radius is directly proportional to n2. The size of atoms is on the order of 10-10 m. 3. Transition A corresponds to the Lyman series limit. Transition B is the third line of the Balmer series. Transition C is the second line of the Paschen series.
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0% found this document useful (0 votes)
34 views2 pages

Atoms (Solution)

1. The number of possible elements in the hydrogen spectrum is 60. The maximum number of states for each value of n is 2n2. 2. Bohr radius is directly proportional to n2. The size of atoms is on the order of 10-10 m. 3. Transition A corresponds to the Lyman series limit. Transition B is the third line of the Balmer series. Transition C is the second line of the Paschen series.
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SUMANDEEP CLASSES

TOPIC NAME:- Atomic Physics


Subject : - Physics Date :
Time:- 60 Min (Solution) Marks :- 180
1. (a) 1 1 7
But    n1  3 and n2 = 4
Sol. For n=1, maximum number of states  2n2  2 and for n 32 4 2 144
= 2, 3, 4, maximum number of states would be 8, 18, 32 (Paschen series)
respectively, Hence number of possible elements 16. (b)
= 2 + 8 + 18 + 32 = 60. Sol. Potential energy of electron in n th orbit of radius r in H-
 n 2 h2 e2
2. (d)Sol. Bohr radius r  0 2 ;  r  n2 . atom U   (in CGS)
Zme r
3. (a)Sol. 1 e2
∵ K.E.  | P.E. |  K 
2 2r
17. (b)
Sol. Let the energy in A, B and C state be EA. EB and EC, then
from the figure
E12  3.4  (13.6)  10.2 eV .
1  1 1 
4. (d) Sol.  RZ 2  2  2 
  1 2 
For di-ionised lithium the value of Z is maximum.
5. (c) Sol. Lyman series lies in the UV region. hc hc hc
(EC  EB )  (EB  EA )  (EC  EA ) or  
6. (b) Sol. The size of the atom is of the order of 1Å = 10 –10m. 1 2 3
7. (b) Sol. Balmer series lies in the visible region. 12
8. (c) Sol. Transition A (n =  to 1) :  3  .
1  2
Series limit of Lyman series
18. (c)
Transition B (n = 5 to n = 2) :
Sol. According to Bohr’s second postulate.
Third spectral line of Balmer series
19. (c)
Transition C (n = 5 to n = 3) :
1  1 1  3R 16 16
Second spectral line of Paschen series Sol.  R 2  2       105 cm
9. (a)  2 4  16 3R 3
Sol. D is excitation of electron from 2nd orbit c 3  1010 9
Frequency n     1015 Hz
corresponding to absorption line in Balmer series and E is the  16 5 16
energy released to bring the electron from  to ground state  10
3
i.e. ionisation potential. 20. (d)
10. (b) Sol. Energy required to remove electron in the n = 2 state
Sol. Paschen series lies in the infrared region. 13.6
11. (b)   3.4 eV
(2)2
Sol. Linear momentum
21. (d)
 mv  9.1  10 31  2.2  10 6
Sol. (Eion)Na  Z 2(Eion )H  (11)213.6 eV
 2.0  1024 kg  m / s
22. (d)
12. (c)
hc hc
Sol. r  n2  rn  n2a0 ( r1  a0 ) Sol. 2E  E  E
 
13. (c) 4E hc E hc '
Sol. For the ionization of second He electron. He  will act as E     3   '  3 .
3 ' 3 ' 
hydrogen like atom.
23. (b)
Hence ionization potential
Sol. Because atom is hollow and whole mass of atom is
 Z 2  13.6 volt  (2)2  13.6  54.4 V concentrated in a small centre called nucleus.
14. (c) 24. (d)
Sol. Energy required  n 2 h2 n2
13.6 13.6 Sol. r  0 2 ;  r 
   0.136 eV Zme Z
n2 102 25. (b)
15. (c) r(n 2) 4 9
1 1 1 1 1 1
Sol. r  n2    r(n 3)  R  2.25 R
Sol.  R  2  2   2  2  r(n 3) 9 4
  n1 n2  n1 n2 R 26. (a)
1 7 Sol. In the revolution of electron, coulomb force provides the
 7 10
 0.0486  .
1.097  10  18752  10 144 necessary centripetal force

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4
ze 2 mv 2 ze 2
 2
  mv 2 
r r r
1 ze 2
 K.E.  mv 2  .
2 2r

39. (c)
1  1 1 
Sol. Wave number   R 2  2 
  
 n1 n2 
27. (d) For first Balmer line n1= 2, n2=3
Sol.According to Bohr’s theory  1 1   9  4  5R
 Wave number  R 2
 2   R  .
h 2 3   9  4  36
mvr  n
2 40. (a)
 h  Sol. Energy required to ionise helium atom
 Circumference 2r  n    n . = 24.6 eV
 mv 
41. (b)
28. (c)
Sol. From diagram
kZe 2 kZe 2 K.E. 1
Sol. K.E  and P.E.   ;   .
2r r P.E. 2
29. (d)
Sol.Lyman series lies in the UV region.
30. (d)
Sol.If E is the energy radiated in transition
then ERG  EQS  ERS  EQR  EP Q E1  13.6  (3.4)  10.2 eV
For getting blue line energy radiated should be maximum E2  13.6  (1.51)  12.09 eV
 1 E3  1.51  (0.85)  0.66 eV
 E   . Hence (d) is the correct option.
  E4  3.4  (1.51)  1.89 eV
31. (b) E3 is least i.e. frequency is lowest.
Sol.Energy released 42. (a)
 1 1 
 13.6  2  2   2.55 eV . ke 2 e2 1 e2
 (2) (4)  Sol. P.E.    ; K.E.   (P.E.) 
r 4 0r 2 8 0r
32. (c) nh h
Sol.The absorption lines are obtained when the electron jumps 43. (c) Sol. mvr  , for n =1 it is .
2 2
from ground state (n = 1) to the higher energy states. Thus
only 1, 2 and 3 lines will be obtained. 44. (d) Sol. Minimum energy required to excite from ground state
33. (c) 1 1
 13.6  2  2   10.2 eV
Sol.Wave number  1 2 
1 1 1   1 1  3R 45. (d)
 R 2  2   R   . 2
  n1 n2   4 16  16 2 2k 2e 4 m  1  2 2me 4
Sol. R    
ch3  4  ch3
34. (a)  0 
Sol. K.E. = – (T.E.) 46. (d)
35. (d) Sol. -particles cannot be attracted by the nucleus.
13.6 47. (c)
Sol.Required energy 3 E  2
 1 .51eV
3 1 1
36. (d) Sol. By using   RC  2
 2
Sol.As n increases P.E. also increases.  n1 n2 
37. (a) 1 1
   107  (3  108 )  2  2  = 6.75  1013 Hz.
Sol.When an electron jumps from the orbit of lower energy 4 5 
(n=1) to the orbit of higher energy (n=3), energy is absorbed. 48. (c) Sol. For M shell (n = 3), orbital quantum number l = 0, 1, 2.
38. (a) n(n  1)
Sol.  E1  E2 49. (d) Sol. Number of possible emission lines 
2
 1   2 Where n = 4; Number 
4(4  1)
 6.
i.e. photons of higher frequency will be emitted if transition 2
takes place from n = 2 to 1. 50. (a) Sol. Diameter of nucleus is of the order of 10–14m and radius
of first Bohr orbit of hydrogen atom
r  0.53  10 10 m.

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