Atoms (Solution)
Atoms (Solution)
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4
ze 2 mv 2 ze 2
2
mv 2
r r r
1 ze 2
K.E. mv 2 .
2 2r
39. (c)
1 1 1
Sol. Wave number R 2 2
n1 n2
27. (d) For first Balmer line n1= 2, n2=3
Sol.According to Bohr’s theory 1 1 9 4 5R
Wave number R 2
2 R .
h 2 3 9 4 36
mvr n
2 40. (a)
h Sol. Energy required to ionise helium atom
Circumference 2r n n . = 24.6 eV
mv
41. (b)
28. (c)
Sol. From diagram
kZe 2 kZe 2 K.E. 1
Sol. K.E and P.E. ; .
2r r P.E. 2
29. (d)
Sol.Lyman series lies in the UV region.
30. (d)
Sol.If E is the energy radiated in transition
then ERG EQS ERS EQR EP Q E1 13.6 (3.4) 10.2 eV
For getting blue line energy radiated should be maximum E2 13.6 (1.51) 12.09 eV
1 E3 1.51 (0.85) 0.66 eV
E . Hence (d) is the correct option.
E4 3.4 (1.51) 1.89 eV
31. (b) E3 is least i.e. frequency is lowest.
Sol.Energy released 42. (a)
1 1
13.6 2 2 2.55 eV . ke 2 e2 1 e2
(2) (4) Sol. P.E. ; K.E. (P.E.)
r 4 0r 2 8 0r
32. (c) nh h
Sol.The absorption lines are obtained when the electron jumps 43. (c) Sol. mvr , for n =1 it is .
2 2
from ground state (n = 1) to the higher energy states. Thus
only 1, 2 and 3 lines will be obtained. 44. (d) Sol. Minimum energy required to excite from ground state
33. (c) 1 1
13.6 2 2 10.2 eV
Sol.Wave number 1 2
1 1 1 1 1 3R 45. (d)
R 2 2 R . 2
n1 n2 4 16 16 2 2k 2e 4 m 1 2 2me 4
Sol. R
ch3 4 ch3
34. (a) 0
Sol. K.E. = – (T.E.) 46. (d)
35. (d) Sol. -particles cannot be attracted by the nucleus.
13.6 47. (c)
Sol.Required energy 3 E 2
1 .51eV
3 1 1
36. (d) Sol. By using RC 2
2
Sol.As n increases P.E. also increases. n1 n2
37. (a) 1 1
107 (3 108 ) 2 2 = 6.75 1013 Hz.
Sol.When an electron jumps from the orbit of lower energy 4 5
(n=1) to the orbit of higher energy (n=3), energy is absorbed. 48. (c) Sol. For M shell (n = 3), orbital quantum number l = 0, 1, 2.
38. (a) n(n 1)
Sol. E1 E2 49. (d) Sol. Number of possible emission lines
2
1 2 Where n = 4; Number
4(4 1)
6.
i.e. photons of higher frequency will be emitted if transition 2
takes place from n = 2 to 1. 50. (a) Sol. Diameter of nucleus is of the order of 10–14m and radius
of first Bohr orbit of hydrogen atom
r 0.53 10 10 m.
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