DRABKIN’S SOLUTION MSDS

CAS-No.: MSDS

MATERIAL SAFETY DATA SHEET (MSDS)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture
:
Product code : 03602

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

LOBA CHEMIE PVT.LTD.
107 Wode House Road, Jehangir Villa, Colaba
400005 Mumbai - INDIA
T +91 22 6663 6663 - F +91 22 6663 6699
[email protected] - www.lobachemie.com

1.4. Emergency telephone number

Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to
Regulation (EU) 2015/830 (REACH Annex II)
Acute toxicity (oral), H301
Category 3
Acute toxicity (dermal), H310
Category 1
Acute toxicity H332
(inhalation:vapour)
Category 4
Hazardous to the aquatic H410
environment — Chronic
Hazard, Category 1

Full text of H statements : see section 16

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Adverse physicochemical, human health and environmental effects
No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS06 GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H301 - Toxic if swallowed.
H310 - Fatal in contact with skin.
H332 - Harmful if inhaled.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor
P302+P352 - IF ON SKIN: Wash with plenty of water/…
P310 - Immediately call a POISON CENTER/doctor
P501 - Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % Classification according

to Regulation (EC) No.
1272/2008 [CLP]
Water (CAS-No.) 7732-18-5 >= 99 Not classified
(EC-No.) 231-791-2
Sodium bicarbonate (CAS-No.) 144-55-8 0.1 - 1 Not classified
(EC-No.) 205-633-8
POTASSIUM FERRICYANIDE 98% (CAS-No.) 13746-66-2 <= 0.1 Not classified
POTASSIUM CYANIDE AR (CAS-No.) 151-50-8 0.001 - 0.1 Acute Tox. 1 (Oral), H300
Acute Tox. 1 (Dermal),
H310
Acute Tox. 2 (Inhalation),
H330
Aquatic Chronic 1, H410

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Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get medical
advice/attention.
First-aid measures after skin contact : Wash with plenty of water/….
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. Get medical advice/attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : Harmful if inhaled.
Symptoms/effects after skin contact : Fatal in contact with skin.
Symptoms/effects after ingestion : Harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Carbon dioxide. Dry powder. Water spray. Foam.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.

6.2. Environmental precautions

Very toxic to aquatic life with long lasting effects.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.

6.4. Reference to other sections

No additional information available
SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation
in process area to prevent formation of vapour.

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Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed
areas with mild soap and water before eating, drinking or smoking and when leaving
work.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a well-ventilated place. Keep container tightly closed.

7.3. Specific end use(s)

No additional information available
SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Exposure controls

Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Colour : Yellow Solution.

Odour : No data available

Odour threshold : No data available

pH : No data available

Relative evaporation rate (butylacetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

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Solubility : No data available

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : No data available

9.2. Other information

No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No additional information available

10.4. Conditions to avoid

Direct sunlight. High temperature.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

No additional information available

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Oral: Toxic if swallowed. Dermal: Fatal in contact with skin. Inhalation:vapour:
Harmful if inhaled.

ATE CLP (oral) 100 mg/kg bodyweight

ATE CLP (dermal) 5 mg/kg bodyweight
ATE CLP (vapours) 11 mg/l/4h

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

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STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
No additional information available

12.2. Persistence and degradability

POTASSIUM CYANIDE AR (151-50-8)

Persistence and degradability May cause long-term adverse effects in the environment.

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available
SECTION 13: Disposal considerations

13.1. Waste treatment methods

No additional information available
SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 1588
UN-No. (IMDG) : 1588
UN-No. (IATA) : 1588
UN-No. (ADN) : 1588
UN-No. (RID) : 1588

14.2. UN proper shipping name

Proper Shipping Name (ADR) : CYANIDES, INORGANIC, SOLID, N.O.S.
Proper Shipping Name (IMDG) : CYANIDES, INORGANIC, SOLID, N.O.S.
Proper Shipping Name (IATA) : Cyanides, inorganic, solid, n.o.s.
Proper Shipping Name (ADN) : CYANIDES, INORGANIC, SOLID, N.O.S.

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Proper Shipping Name (RID) : CYANIDES, INORGANIC, SOLID, N.O.S.
Transport document description (ADR) : UN 1588 CYANIDES, INORGANIC, SOLID, N.O.S., 6.1, III, (E),
ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 1588 CYANIDES, INORGANIC, SOLID, N.O.S., 6.1, III, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 1588 Cyanides, inorganic, solid, n.o.s., 6.1, III, ENVIRONMENTALLY
HAZARDOUS
Transport document description (ADN) : UN 1588 CYANIDES, INORGANIC, SOLID, N.O.S., 6.1, III, ENVIRONMENTALLY
HAZARDOUS
Transport document description (RID) : UN 1588 CYANIDES, INORGANIC, SOLID, N.O.S., 6.1, III, ENVIRONMENTALLY
HAZARDOUS

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 6.1
Danger labels (ADR) : 6.1

IMDG
Transport hazard class(es) (IMDG) : 6.1
Danger labels (IMDG) : 6.1

IATA
Transport hazard class(es) (IATA) : 6.1
Hazard labels (IATA) : 6.1

ADN
Transport hazard class(es) (ADN) : 6.1
Danger labels (ADN) : 6.1

RID
Transport hazard class(es) (RID) : 6.1
Danger labels (RID) : 6.1

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:

14.4. Packing group

Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III

14.5. Environmental hazards

Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : T5
Special provisions (ADR) : 47, 274
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container : T1
instructions (ADR)
Portable tank and bulk container special : TP33
provisions (ADR)
Tank code (ADR) : SGAH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Bulk : VC1, VC2, AP7
(ADR)
Special provisions for carriage - Loading, : CV13, CV28
unloading and handling (ADR)
Special provisions for carriage - Operation : S9
(ADR)
Hazard identification number (Kemler No.) : 60
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : 2X

- Transport by sea
Special provisions (IMDG) : 47, 223, 274
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1

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Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Segregation (IMDG) : SG35
Properties and observations (IMDG) : Solids. May be soluble in water. On contact with water, may form a weak hydrogen
cyanide solution. React with acids or acid fumes, evolving hydrogen cyanide, a
highly toxic and flammable gas. Toxic if swallowed, by skin contact or by dust
inhalation. The provisions of this Code shall not apply to complex ferricyanides and
ferrocyanides.
MFAG-No : 157

- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y645
PCA limited quantity max net quantity : 10kg
(IATA)
PCA packing instructions (IATA) : 670
PCA max net quantity (IATA) : 100kg
CAO packing instructions (IATA) : 677
CAO max net quantity (IATA) : 200kg
Special provisions (IATA) : A3, A13
ERG code (IATA) : 6L

- Inland waterway transport

Classification code (ADN) : T5
Special provisions (ADN) : 47, 274, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0

- Rail transport
Classification code (RID) : T5
Special provisions (RID) : 47, 274
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container : T1
instructions (RID)
Portable tank and bulk container special : TP33
provisions (RID)
Tank codes for RID tanks (RID) : SGAH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Bulk : VC1, VC2, AP7
(RID)
Special provisions for carriage - Loading, : CW13, CW28, CW31
unloading and handling (RID)
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 60

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list

Contains no REACH Annex XIV substances

15.1.2. National regulations

Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to
AwSV, Annex 1)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen –
Vruchtbaarheid
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen – Ontwikkeling

Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product

15.2. Chemical safety assessment

No additional information available

SECTION 16: Other information

Full text of H- and EUH-statements:

Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category 1
Acute Tox. 1 (Oral) Acute toxicity (oral), Category 1
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
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Acute Tox. 4 Acute toxicity (inhalation:vapour) Category 4
(Inhalation:vapour)
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
H300 Fatal if swallowed.
H301 Toxic if swallowed.
H310 Fatal in contact with skin.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H410 Very toxic to aquatic life with long lasting effects.

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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