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Pblock (15to18)

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44 views23 pages

Pblock (15to18)

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HNO, — HNld, +0 ty Hgts ee Oxides - halrilr anal, yolaides re rtede Ah0y fro ho 20s \ os patdic WS “Lat fonpho fy, 0¢ bees 4 Shas Bid, 4 Boric Hydiides +4 Ng + fitg, Hs) SbMs + Penta oxicles ace mote covalent arnef adic than teroxides ire? aSees myc sits by Kenn agile position 3 Hebomobin Mp > Ply desis Sb Ky Lr Reducing nefure Feri (duc to @E) Gori naaners Nu > > - ttedielys 5° Ex. 7 Ng, NC, NM, NI3 e : AS a Sb qa gi ” x Only Bifs imic, hat covalent 5 14 ie f halide x — \ Ls-Steble a familar ity 940 7) loa o™ Ke Cn does not Gow pontelnatite) fhe, Bets, Mur | # only Nf, is stable amody Nt Aste Asks Kes ave unsteble 4 Cxplosive 4 explosive sbfe , Shr Nig priuargul SP a stability of Gobel Bis omy | Fails > Chabal) roms > rodiles geabilty, Geet OD OK. sake in vhange Dk He * most Common ) —272, +446 * Tenduneg fp chow -2 £46 V4 frum the group (+4 ns) wit flourine [2 shows +i £42 19 tho, Hus, Me se, MTe ua bo H-bonding) Hydardes RRO IySk th sec mpTe oP ee 5 / Red. car : a re (dee) 3 . Sahil 4o> -- pH, Te e suty - >W0 (Tendenty t2 dora at, hee. fo ED) hide 4 Wye - > stew DAY 7 Gionide tuicndy | Oe $ a $0 eyo, $0, Sq0 CNet Imp) $ _ c Su, Se02 «| 4 1 x ao i 0, COs a Anip : fo0, 2 fo My) oid ic : soy oiling get ¥ <0, + both oxidising aunt hacusing eget a. oxidisig it (464 Se not as stuble 4 Jo sutpluct) Nol SHO, bette ox tent than $0, (0% pocprty no down she peop) ides decreary down the of (du fo s. in stobility Of +6) ¥ Tendleney fe foun tulos Habides ¥ Stability > yloonides > = -- > Todices Among pecahabites only Resa powile x di, petaa, 4 toes labile one feted gorse ( ari stable) x some dimeric babies ade also Jovored , Out they is praportionate ey Sey «= Set Seely f, S| 8% | Sty, Soy | Shyetty | 34 Se | Seats SB) | Cl | Semy Te ~ [Feta Te Te ee lee |Teaty Tels | oe Po _ | Pod, , PO Be | pocty Pots | \ \ Poly Noles Shy Ts staicatly Irate a cy SF, the a ne be Drepososion Gf clamatants Nitya + Nand, — Nino, 3? Nyt 0 Nity), (03 Ne Ee? + Ho (Min, (40a Ba _- 2 Heading off Amma a —r—e yt on +e So nium sachs hai ny Nuyr0s “SY +1, tot Me oxidising Anions BN Oe eae (Hemember Nyx qua Nao nok wa) Nyt G0 ZK? Nyt Me Nu, + Me —4 Ns * _ > By oxictahion d) Mg Nu, + Nawcg —o Ne + Piette ea nu,t Mou, Ny, + aur * he + by (tions dstitladion J) atk (‘ gree 4% ) BEA On = Vy fluke Ny fs obteened by reshing Azide CW) Ba(igh, xr be * 3M fo pleotend, roa gO ae Casio, + fw oy ee ee Oaygen <7 fy brvcching onicles _ + 0 (Aad Hye, Had, RMaty, Ki Ady KLb, Pbay, fo wrth Tah Phy» ed 0. 4 0, x M04 le keto, =" Ka + 2 ence! Had, gt Mad * gO Aly 0, 4 Mnt 4, ty Cadialis 4 ctr 4 gence dsitabion Jee Seeeplu 9 ¥ ys +0, — 6450, +0 tromonia (Nig) * Prcparahion © iy hao Ammonium salt Containing, rill oxidising oe iameoxieicig anim SY (Ny), $0, (ty COs, Mute Nity OH bp (Nu), $0, Zt Aly # 0% 52s ¥ ott, Ammonium sates can Sebesre ammonia when teotee! wth Gon, % 4 4 Nity(Oy # Caen), —> Nu, + la Wm) $2 by bya iteacles MN + Ho —— Aeon, hr Hy em, * Ny a ww a BO CO nO) ees ee ee £ Maber'n power Nobel, mixed with waht veped lampe died ny Lime (cao), not by Com. Hy $0, Py O19 A Ombyd. CAUla Nay + HS, Ae b ferd- bare Re? Nug & uO, Cau, # Nig a thy Nie cham, Qed) Nis sa nit tS Ulleurten £ potsonous af high Come ty aerds , it x ik is pteak bare Gout Apnmumium set 4 so prrupitebes hydgorides J) MNT melds 4, Fey egg %M0 Meer) Sh (6H) Zad, 7 2ne", Wee) mem x it also femmes soluble Lommpleres uit with mary metals when Feken in exten (tal ee) cy tu? + yntu, — [lo 4,77 Tat of NUg ia Kolitg 4] Ns Tens Grnon (Hao agQmy)t) + Nessla'p Aeaqend we Rot wth Oy) Ay 0, (Umid) tN Go cee by (excess) 9 NO4HD ey? viet Nu eX, Aly + ly mn ZO Auth ae con Nu + Xp (exe) eee Nee Nut Na — Nast $147 jw mun “ay : “tue Ulour, in got” ini ally ) Phaasph ne Cie) Preparation 39 0) GP, * M0 > AON), + Py Gi) Pyt Now —4 Nate fo, + My [ts poisonous, Soluble in tS. + “ ych_ smell 4 pi, has a gute hoffen firth sm fashatty soluble in 0 * Tt explodes iv purwnee 4) oxid'sing aget i in weaker fo qiet Red P x Tt decomposes in ¥ help weg ph, +40 — with Ha. 4HD vey What Games x th Ty okeeck by haste X” « ange AT NE f Lb Hgcs, * it ques pt 9) thosp ide woth dna, b Mgch Cau, + Phy — Ole Se!) yet, £0 tig Host (eck) hile sianal. (it Uonleans Gt, al Gah ¥ It is wed Holmes Sra a si buss spontancensty fo sve @ SY ‘Ay 2:1, Oxides of nirogen we, ae Preparation Properties eo RNS pg secreceeracaread a * fee - 1 sara Eats a Se = eee ee || a $ Wr. wesaNOrbeao | t Rice ean ih een + 3No Ss L0-+NO, ae IG + aa omer ae ogee eee ‘trioxide) ANO + 0, + 2N,0,, NOw HO» 2HNO, fe eee ea | eee asa ‘cone : 7 + Mined marae oe ceva a | Baal See : ee 5 [Retractors ne NOM] * Tee tvenponcons oper a oer oe | EAS no, Oxides phosphorous hy sa oo Poeparabion :- A doy Pact Oy (binited) —? P40 ! a VV Of ve © Mud, + 0 — hef0; —a* Hg p0,+* Ms (ed) © Pah + M0 cesatmy — HPO # OMe ® $0, #4 — AOro Rudo fhe i O Py O excess) —? Puro aie 7 Ho ete yet 0 cea 200, Hugh "8 poe ee 7 y x ho =\ Cw, inclaphosphoue Tettaaphospree espe oy — aud aud oo @ Pade 1s sthorg dabydrading agent HNO, + tye — Nyde +o 14504 + Mow —# Sz + the Ogme +7 a thepared by passing deteicnt discharge thay pcx + oly 0; 30, = 40s (lor Cone: ) ¥It fs peemanent bleach nt fit Te pale blue gar, dark Bue Lipo! ¥ 0, is ‘theynodynami ally unstable (0; ¥ Tt fs st fama oxidising aguel due (> Keleate To) Ande , volt black solrel 0, + oI) Y nascent Oxygen we Hg— “gee Crating 4 mary ) * a Pbs— PbsOy ¥ KT — T, * No NO, 0. ; 201 Mreparstbion 9 Gy $40, —9 $0 a éés==2-2+- Cinclast sinkly) x it how sugpocading ow Buutning smell Sutphut, aude in natule- ¥Tt ts both oxidi'sing ama Reeloring oget ¥ 50, + 4,0 — $0, (Seuphrceas aud) pratt ¥ S044 Nao —t Na, so; * S0,+Cf, —7 SO. ‘ Ya 2 Dy Ly Coueplurayl chloe) b peloton kx? * $0,+0, eds. so, + ° +4 +e Dyichising aye tia _ keduuing og nt i ($0, 7593) ee Hino Mn ( clecdlourizes Punungrt) « Ss 7S * A — os (runs dicrromat peer) Cqven) t, $0 + pot RO +RS oo ge ¥ A ry got IF Noler+ TE (s temper, blanching opel ( $% 50g frugassien > Hn s04 tate —t SOs * "9071 fe So, 40, == $% Peau), 3 Fes aus a4 Kedlclngy Snel, —t Sntly ako —t th, $0, + £00) ) + SO; eit ts oxidising agent and ade oxide Nitiows Adel CHING) treperain 2? 8D, ty 60, ¥ TE ts unshable teak av'd ana) pale bux solution HNO, —* HNO, + NO —_— Bago, + HAND, Nitwic_he'd Clon)? fab muted? 4NaNg+ Hr$04—4 Nagsoy tHHNOz faye seabe 19 or ostutalel Press PE-Rh 7 ET SNo + Ho Cy Ng Oa gang Gi) 2No +0, = NO anno, +NO Gi) BNO, + 0 —> # (me KINO, fs Sthorg Ceeaea) tae Table: Reactions of Elements (Metals wih HNO, Element NatweotHNO, Changesto Reactions (A) Meals placed above H in electrochemical series (ECS) 1.Mg Mn MNO), Me 2480, -» NO}, +H, Rune NNO! A2netOHNO, »42NND). “NANO, 3H.0 No A2ne OHNO, 42D, +H. BO no, 2n+ HNO, 3 Zn(NO,),+ 20, + 24.0 350 (erate NANO, ASne1CHNO, +480), +NHNO,+3H.0 (@heencertates NO, {Sn 4HNO, +500, + 4NO,+ HO 4 (ayane no 3Pb* BAN,» 3PH|NO,),¢ 280+ AH.0 (@yeencertates NO, Poe aio,» Pato), aN, + 24.9 (Metals below Hin ECS 5.cu.Ag. Ho (arate no gout, 0uno} +290 440 Hato aN, (@heencernied NO, CreaNO, » CUNO), +2NO, +240 (cymeraiots ‘Ae concentted NO, 80+ SHNO, +1800, + 5NO,+H0 (W) Concerted nivic ac so vdsesnon-metals andthe compounds. lee Is ised to ae aed, arbontacaron cence, suphurio H.50, and phosphons phospraic acd 1,1 1OHNO, ——» 210, + 10N0, 4440 5,+48 HNO, (oncontates) + 8/50, +48NO,+ 16140 Pl 20HNO,encentated) —> 4.PO,+20NO, +4140 Brown - hing Test a noe * no + Ft A Fe (trode C0]} $04 (Borwn- copa) 92, Oxy acids of phosphorous: ane | Forma | Ostnion | Chars Prapton Tipspreesesee| RP] rw PO ae SE Totoro) Teor [omapoptoom | APT Tero FOR Sievers as bo8 Proper | PB | I —| Tro Fa APSr ro twoh=0 TiS | APD, | | roa Bo a Ta TwoP=0, ee aE | | | Teo FoaTAT a RT| PO Tete OR | Pa SST ar Tee? <0 inaveaed ue ie AA Ak OR Abd. ‘Acton ohet on phosphoric acid and it sts: Hp0, 2 HP. prphosporcaci); HP,0, 8S HPO, imetaphossor a) nsipo,—*, neo, +H 2ia}PO, 2 Nap, +40 NaQai¥PO, 2 NaPO, 1047140 Coleum {2 hy S04 a Preparation Of Ha. $04 eee me “it (ortact prow s > pe | mee | ceo, —* 8% = 7 “TAR | a ys, +0, LMS “HO | so, + Hq, | t a -F £50, +0, +0 SOF MSP Loapatis 4 tasty +? x it is dense ofly Uqurd (known as orl of vitgorl) * a we waht Te higidy erotic, tent aud is adeled to utatr nt tater ant x it bos vity Low valapilibg due fp inf molertat H- bonding x mae volatile avids con be male a sally tg. Nace Cant th $04 Nay So, + HCL(™) Nanto, + n Nag Sy * HNO, (1) * at is sthory avd and Keach, with bore anal salts Nag tog + eS!) —" Nay s0y + Heo Hr ee Nese tao + Se go + M0 $0 7 ASOy 2 # of is sthoy derydcahry agent Cry, Oy + om Mose ee Ine HUH? Channing of Saget) (sages) dy 1 Ho + Cot Oy, Hoge 4 1 —t hore ¥ Tt fs sthong oxidising agent tu + Cont. HrS0, > tus # SO, + H20 (No x? with al 14504) waa dh ratty only yy achive lal kena pre Hil) bike Zn Sa tne HoS0, —? $02 M20 ce ch 5 wo, + Slav M2? ime hay + 0 HE? Pea, anal Pele Puls + Oh —+ dy Clirerted) 6 M4 (wart. ) By + SOC —F Pst Oy + S16by, Reasons © Pet, + Heo —> Hsfogt Hee ° @ ged-ou + Pits — @ Reo + oly pecan + Malls Pele 4 eC eee Pile (alma) (excess) ea $0,, Pde SOx O Pele + 420 —> POs hcl Luo, Hepat SHOE é tect tH, geen cet Heh |@ R-cov + PCI —> Rael + pougt Hct © Reon + Ps —4 Rock + poclgt HCL Cle qe gto © pete +A Agel + Pale @ Pele + sntlyt PUs + thethne Teigenat bipysarnidal fo solid stafe it exists a4 5 Lrety)® Cece) 3 cAg(pty), Of? Plowmoapabie ae Nagai + Ogi ay imp. hen 7 CAE Josep UAE Nat og LNaZ 0 a =S=Stsésésrsrsrsss—SsSS ) Keb negcly 40> a ‘Atomic & Physical Properties : 'SINO. | Property F a ‘Br 1 [| Atomic Number 9 7 6 53 2,_| Atomic Massig mor 19 3545 79.90 126.90 loco configuration . 2 | canteen crating | el 2525" e226 | ayaa" ant| Pea Covalent Radius 7pm Oo | estan oa 9 4 199 Tonic Radius X"7 pm sl peavats 133 184 196 20 Tonization enthalpy 7 (kJ mor") 1680 1256 1142 1008 6 | @>c>er>n 7 Due feteese fv atomic aie, risa enthaby decreases down the grou -333 -M9 -325 -296 Electron, enthalpy /(kJ mot) gamenthaipy)m21") - Gfeximam negative electron gain enthalpy in the (Cl > F > Br >. mi 7 \« 2) + Negative electron gain enthalpy of fluorine < chlorine ‘Due fo small size of Ruorine atom. As a rest, there are strong infer-elecronic repuisons nthe relatively small 2p orbitals of fluorine and thus, the extra electron (incoming) does not experience much atracion. Distance X-Ipm 8 | Br->F-F>1-D inF, molecule Electonegativify 10. | esci>er>p 4 32 30 27 TWeting pont TK 1. | @Cl>Br>D) + Smaller the ion, higher isthe hydration energy. E*/V (SRP) ; Xz (g)+ 2e” > 2X" (aq) | 287 136 1.09 054 14. | (> Gly> Bre>I) + More the value of the SRP, more powerful is the oxidising (Crafting pone’) 1 45, | Colour (atroom temp) ‘green ] Greenish | Reddish brown | Dark violet yellow gas._| yellow gas | liquid solid 76, | Ondization state a et) a | ot, $5.47 $5.47 $5.47 Chemical Reachvihy Holegens ane his Reactive » heackiviy lecreares dawn the qoup, * f mw! most 4 x” OMe © and tt fs SH ‘is mast Mahive t of its & xplosi z ” plosive. Le topat oxic CT ee (i) due bow Be g fF bod Gi) Ng hyduacion enthalpy Y 0) pxidising nahse J) Halogen » "Ey can oxidise a, wt” fy + ax oF Xr » Cf, Won oxidise only a” ey KH a oxidise only I” * fat WSO ae Os * _ hey + Hock bb Lispurpotinal innate] YL ky Hho km F Hom ¥ T+ H0— No &s” (Ioan be pxidised wrth 2) Ae i) oe fe? wth, My deegen a b- HE (ken is voilent) Kt ¥%y a aHee an due (Slow b Kevessible bbe sia neh ert int up 7 Hb? Hoy > HL ed estalpy = daa Ky ak i ae fo H- bom Pe “ fedving Power intents aieenice te Ck Be r ¥ OF, b Os Fr #60, LO, 2 | Bro, Bed, | 1%, M20, TOz, ¥ lest stele T40 ¥ most stable % only OF, is stable (O06) 5 la OF ak Loum temp (atk) | Higa Await, oxides and * ponteyul oxidising} * ae _ aading » story flouinat Ox idhising re 7 Beau agents agent 4 exist a dud ded to explode oniged tow feunp | ¥ To 0 ek typ, 2 19 (10, Qe —Otfe 9 lu pie Ms (Pufomium fs soe) © L,0e fs sthny Ox. gent + 2 ep estimation Y co trae a oxides 9 17 078M Toe +O 7 Ty Chboine Cir) _Prepasacion « 299 dab meted metas Cy Mindy + unce —? Mnct, + Ch 7 kino Gi) Kanoy THE Myc He * 42? @ 4 detslysis J) Nace © Deacon pouers (Endusthiet Metlad) tude UG, tae yee + 0; Hse acy i. Reachions d) Prt ote Haley spare £ Cavebent und ron meter (fier ae : rae te melals 4 bap oe 7 > fa feu, 7 ds & ¢ Hebel Xt My Fae ee enlace PE Xp (im'e) —t Kg S+ Uy (united) —4 Sa ee +X - ss sr ct, Coxe 1 Sy St Fy (ees) — $f fet ty Na ee Nu, bY = a (excess) xgr HX Nu, HX NX3 (ex) Be wth Not] ae wih fy Nuoy — OF, + Naf (dil. ) F,+ Neon ——+ 0, + NaF Conc.) we (hy fs eumanent Bleak eek + (oJ at no + AME (co te? x Oxid'si ae 1 HL 05 fer ok ~ soe soy sat HY Nach # lane Hs, —> HOE? Naa Soy stsong aud + NM : 2pt ie nett bike Ba HP white fumes ° a Wel +? Peep. — we ik 1S Closers , pungent smelling 4% landicslve. Noble Aywctegie( Stn) 2h —+ hace ant HNO + Ip 3 M5 (el Ory coud Kategen Hypohaloos aviel hoe HOCe Hom HoL Cer, except #) Halo od 4S) |= a - - Habic avid FS) _ ces ee Porhobic uid (+1) = HCW, Hay Hoy 3 ° Werks _ xs x an wo’ 4 wet? inter ounds ke AB, ABs CAE, Bhs ae CLE, Ms Th (hfe, Bs, Tfy Wa, Le, tug ss The Cex'sta as a ce) (aol isola) ze Deparedin © Uy + A — aur @ mt a Tefe Caparo) (exc ty ie pth, ORs Ceypat v9) cexcen @ & +f — BF e O nth 28 Ife (exw) (exam ) [ : Propestics a O Thue Compound uit! be Sob’, dig, & ge @ Laage infechalogen OX waaay coloutecl aud more Keortive than rabegens (except fa) @ The oe covalent , dimag nchec @ Gpt & stabi hy x Had ronegadivity Cin genset) © Myladdyst Ly ine AG tee 4 pon + SH 45-1 AB, te + HAO, + FY 4g Age 2 > nAoz + S BH “4 Ae, Hd > HAOy + $0H ass O Ue, BOAR, are ured fe enachment v Ut sue, UF, + SUF Dswedobulidr £ psstorareye> 4 of which one is Nithegen , dimes eno 8 Mae aed a (ong (ontein! _ 4. Pstrcalo halicle psucdohatager Caamide st ON eyanegen as CN) thivcyonide = SiN” sthiocyaneg? ww © Seen’, ow, Nig, Cn % These Aeremble haves in bebaviour £ Kepahis 4 thet Compounds, Noble gud Oceunence $4 Nu elements exept & @ foundanee fr ash > A> Ned Ka > He? Xe HetNe Me preaeat tn hadioartive minaals Like (pittablende, Manage cleurte te.) ® — Raslon is oblained boy deeny 4] Kaciom ne we he Sy” 4 te 88 ee adem octuk- In Homo sph @ bc? nce mph (except He ns’) Oj ate fe vane Wage Cdeucare down tre geoup) @ Aiwmic kaslis — in period ( 1 down the 1°) @ there axe manoafernte, wtenrter counters + Feshelenr mn substances fhopertics? @ He ww Lowest Bept (2K) among at ee Chemo propa, . In (air Nel Bate prepared & Comp Ogt CHES # Oy hos Tt simile fo Me, So he prepared Sinillew comp Xe CHE] + Compounds a uuu Knewn ke qu MAE, _ obsewel. % lathorate Lempouinds 7 Oy tearing Laage nate gas tn fee (alt fe Here) Seneca test ere negansweheue 3 30S1'C maser the pastas ananonbexale mare OE ur, raf: ot: Snir SOPET I a, 1 are EET ye, ‘ecco dn) Ta ct tind mrp scandens ‘carmel ry cl coe ata Pe + | sea -lpef Foo |W), XENON. OXYGEN COMPOUNDS : yiys of and XeF, wth ust gives X20, 6X0F,+12H0 —+ 4X0+200, + 26HF +30, ef, 430 —» X40, + 6HF Paral iyi Xr, ves ryfuades, XeOF and XeOF, XeF, +O —> NeOF 2H Xe, 42HO—> KeO,F, + 4H “00 is acaluressexlsie sl andhas a pyramidal molecular srucure. XeOF, is aclouess valatle ‘nqudandas square pyramel mlocuar cure uses: Foss ana anata ait gas Hench ts fling tars er meter ogea oberon Is also usedn gas-cooled nuclear reactors Liquid helium (p42 K) fds use as cyogeic agent for ‘carying out vanous experiments at low temperatures. 11s used t produce and sustain powerful Supeeandictng magnets whch form an esse! part cf mode NMR speceoretes and Magnet Resonance Imag (MF) sysoms for ical dagrons is used advert for oxygenin ede ig appara because ofits very lw suit bleed. Teo uses cargo tubes ard iunrescat bbs fer averteren play purposes een bubs ze ‘sedi Botanical gardens andin geen heuses. ‘Agen sused marly prviae a ne atrespar nigh parse metal processor wang ‘of metal rallos) nd ling locus ts lo used nto labratey er handing substances that ‘earsenatve, Xenon ard Krypton are san ight bulbs deagned for spec purposes

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