Quiz - Chemical Thermodynamics

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Name: __________________________ Section: ____________________ Date: _____________

Quiz – Chemical Thermodynamics

Solve the following problems. Box your answer for each.


1. Given the dissolution of CaCl2, compute for the standard free energy change. Is the
reaction spontaneous at standard conditions? (10 points)
−¿(aq) ¿

CaCl 2 ( s ) → Ca 2+¿ ( aq)+2 Cl ¿

CaCl 2 ( s ) Ca 2+¿ (aq) ¿ Cl−¿(aq)¿


∆ H of -795.8 -542.83 -167.16
o
S 104.6 -53.1 56.5

2. Consider the reaction below. Calculate the standard free energy change. Is the reaction
spontaneous at standard conditions? (10 points)

CS 2 ( l )+ 2O2 ( g)→ C O2 ( g)+ 2 S O2 ( g)

CS 2 ( l ) O2 (g) C O2 ( g) S O 2 (g)
o
∆H f 89.70 0 -393.51 -296.83
o
S 153.34 205.14 213.74 248.22

Name: __________________________ Section: ____________________ Date: _____________

Worksheet – Hess’ Law


1. Calculate the ΔH for the reaction:
C2H4 (g) + H2 (g)  C2H6 (g)
from the following data:
C2H4 (g) + 3 O2 (g)  2 CO2 (g) + 2 H2O (l) ΔH = − 1411 kJ /mole
C2H6 (g) + 7/2 O2 (g)  2 CO2 (g) + 3 H2O (l) ΔH = − 1560. kJ / mole
H2 (g) + ½ O2 (g)  H2O (l) ΔH = − 285.8 kJ / mole

2. Find ∆H for the reaction 
3H2 (g) + 2C (s) + ½ O2 (g) → C2H5OH (l)
 using the following thermochemical data:
C2H5OH (l) + 3 O2 (g) → 2 CO2 (g) + 3 H2O (l)   ∆H = ‐875. kJ/mol
C (s) + O2 (g) → CO2 (g)  ∆H = ‐394.51 kJ/mol
H2 (g) + ½ O2 (g) →  H2O (l)  ∆H = ‐285.8 kJ/mol

Name: __________________________ Section: ____________________ Date: _____________

Quiz – Enthalpy and Hess’ Law


Solve the following problems.

1. Calculate the ΔH for the reaction below:


4 NH3 (g) + 5 O2 (g)  4 NO (g) + 6 H2O (g)
From the following data:
(a) N2 (g) + O2 (g)  2 NO (g) ΔH = − 180.5 kJ / mole
(b) N2 (g) + 3H2 (g)  2 NH3 (g) ΔH = − 91.8 kJ / mole
(c) 2 H2 (g) + O2 (g)  2 H2O (g) ΔH = − 483.6 kJ / mole

2. Calculate the ΔH for the reaction:


CH4 (g) + NH3 (g)  HCN (g) + 3H2 (g)
from the following data:
(a) N2 (g) + 3 H2 (g)  2 NH3 (g) ΔH = − 91.8 kJ / mole
(b) C (s) + 2 H2 (g)  CH4 (g) ΔH = − 74.9 kJ / mole
(c) H2 (g) + 2 C (s) + N2 (g)  2 HCN (g) ΔH = 270.3 kJ / mole

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