Date O) J01 22

Expt. No. 03 PageNo.

AM OF THE EXPERIMENT
To determie tre_rato conston of ocid cotolysed
hydnrolsi Of Qthyl ocotate
ChLoical Requied
iEthy ocofare.
iHyd0chloc CLciclL
iu) Ccilium hydroxide
vIce Cold watis
ARParatus Reauree. -
Ruretto fittedwitn Atond
) Pipette (25u1)
ConiCol fias K
Atop wath
w a t e ath
9ndicatoY USg
Pherolpthalein
hey
The hydrolysiB Of thyl acetate In Presence Cf HC[
is PSeudo firkt o7de 2action Actuall iA
is o
biomoleculo mmoctioo havingorder one 0 Concootra
Of_oONcthy1acetate i5 Chonged duriOY the CcuTA
re anaction into ater IS faKa 2KCQAA0 H8
CooCootasion Seons to bouncbangh
LHCo0CGH tHo H (CóOH +GHOH
Theofe Constogt K lorhe omoction Con be chteYmne
b the ollowinq Oouatio
Ke0 loo VaVo
VD-V
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whur
K=a t e Con ta9F
t time io Aeconds
V valumo o NooH ulec at t= O_
V= Volumo Of NhoH USe d at tAecond
Pcocedute
Tako loom) Of Hcl C0.5N) in a Clo02 Ono claruy ConIca
flaek Atoper it and Keep iEio o oate bath at roo
flasK
tempiatatur.
2TaK0 20m1 of othyl ocetate in a 50 ml Conical lask
Aloppa tand Keep in tbe Aome ator bah.
3 AloL2 he AQ 0 4andarc fo 20 min._
URiDs0 0nd fl -be busntte wi th ho NooH Koluion
5PipeiteQd loml Of0te_aod xankter it to the
Cooica HasK Cogtoining Co5)N L AolAhaKe the mxturg
GNo Pipetto CuI 10n1 ot tho mixture io to a Comica
Flask Cootaioing 25 O Ie Colo waroy Add 1-2
dorop QF Phenblptbalein_indicoto to it
Tumaleit aghinst N1o AboH Ao frpon ie husrt
I dba _colou changurom ColurleLs to l ' t Dink
Toxo foitial 0dl Eigal kuetie rnQclind.Nbke
da th diffarence Cohich hveA Yo
Repeal the Same lo Lach 10mi to q/e five TOodeng
Cwuch qAVL V)
fioalluy beat ho CmCal hosK Containine Mochion
mixture in he wate bath aT coc fo Lh
Aqhn tiirate lom Of thl3 mxture aounst
Nlo NaoH+ b usi ne Aamne broCadure tahichVL
Noo
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Olotervation
S
Ioble
TiML io| Burret modi ny (»1) Remork
0 ufes BR
FBR DfHrce
5.5 Vo
5.5 1. 5.9 V0
20 1.3 .9 V20
30 173 23.2 G.9 V20
y0 23.2 29. G.
29.1 35 5.9 60
35 UO. 9
5.9
CALCULATlON
The yaluL of ae conAt_K au diffeseot 4im intevl
COL be Colculaiecl bu thg follou in equation
K 2.30 loey VoVo
Vb-V
Vb-Vt
E 2:303 0a/ uo.9-5.5 -0.2303 x 0.04 = 0.018
TO
UO.9-1
K22.30 100/ yo.9-55 0 xO.1 = 0.01
20 uo.9 19.3
L3 2.303 109 u09-55 0.016x0.3010= 0.022
30 uo.9 -23.2
Ly= 2402
y0
10q u0-5 -0.05t x0.977 =0.02 1
yo.929
30 j09 Uo.g -55 0.0M6 x 0.31 =0.03%
50 up.-35

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0.024 0.0351
0.018+0. 018t t0.022%

0.02uu6

ColculatLO five volue Of K_onol HaKe the avgr0/

Ibo anlO a y als0 b0 det emine dl u uphico
noihod

CONCLUSON
Tne voluu Of rale cong togt K_Of he acid
Catased hudrolsi8 Of_ethy| acoBate jA_found
to be 0.02up

Nou-Brajara Pan
Branth Civii Engy
Pyd no210110U O1Y

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Expt. No. Q U PageNo. 2

AM OF THE EXRERIMENT-
Stondordization Of KMoa usinq Sodium oxolare
DetermioaTio Offerous_ibo in Mom's o l
by PoBassium Pesmon90nate
CHEMICAL REQUIRE D:
DiAOdium 0xglatoAolurioo (o.1) andl VMnasol (o.N)
ulphur ic aid (101
KMnQ Aoluuti on
1 Moh'A Aalt Aolution
ARPARATUREQUJRED-
iBuretto fitted with tandd
D Pipette (loM)
uConicallouk
IHEQRYy
PoBosAtum Pirman9anate act s 0 0 onq 0xidiA9,
agho 1) acidic modum Duu to ihid Prope?tu VMn0u
Cnbe Hitratecl0gaunst Aocarol rmducing/ ciodhE likL
disccluum 0xalate bulphuric OLucL ia&uitobl2 fo
2KMNOs 3H,s0 L SOut2M0&0+3H,0 +5[O
MOO
o bas PioK colou. Durin the tiirouti02
MOT Of MM reducecl to colou LA HOAbe
nd Doiot ohe 9 the nole ducinq/ IA full OxIclis
Hho ddditi0 nal_RXCAs Crop O MOy 9/ves piox
Colou Here MnOy_0CiA,0S AelE1odudt afi0)
2MOOt l6H'+5C,Hu 2M' HO 1OC0,
Mos Aalt lo a dauble Aàlt hovina forulca
FLSOy(NH)2 SOu 6H0 SioCO Potassium Poxognoano
OCtA gh tocong aducing agent in_gcidc ediu
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Soit Coo bo_us0d for the gthration o I0O wbeO

Mob A Aalt iA Lilaatec 0ai O4 VMO0 soluio0
FoToDA Ore Converecd 46 fe 100.0 HRTe KMnaMOO
acts aA indcafor
Bl+Mnoy +8H 5E+M M4UH0
Since KMOOY decompotes Quuclu2 io_riieOCo O
lLh A0 i}8 r e nqth iA o# fixedl for a lontim
Rinco 0nd ill the burete with oiyon KMOOy A0
2Pipette ou lom 0f Atocdlod soluh02 Oxolat
Kol in to a conical lask
2.Add 10m 0 CO (101) t0
CaYeull4/ hea the IoSKto G0-10 Tequireol

GTitcute it with he YMDOyKO by ooop uO1A oddi tio

9 4 be colou ChongA Srom Colouls to Piok
6 To 1he initial dod ficca bumette readina
Notedow he disfornte
ARepeaf to get three Concordlot modino
OBLERVAILON Tablk)

Volume Burett readu Renok 3

no Lgive fol (m 1BR FBR
10 0.0 Rough
2 q.8 1. 9.9 ConCordo0
3 10 19.2 29.6 q.9
29.6 39.2

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Expt. No. PageNo.

Tablo-2)
SL Volume . Burette amadin
no gve9 Aol BR FBR
RorK
DfLnce
10 0.0 0 . 5 10.5Raugh
lo 10.5 211 10.b Contordo9E
3 0 21.1 21. 10. 6 LOdin
31. U2.3 10.6

CALCULAILON(fo toble-)
NoTollyp Of KMn04 Aol lN, =0.1N
Voluma0 MA04 Ao (V2) =Q9m
volume Of mohA Aal toxen V)==lom
rom ibe law 0f (hemiCol Equvolence
N NhV2 O.1 x9.9-0.09
V N
10
Stmnath
NX 09. wt offe
0.0qx 6h
5.0M /L
fnr lable 2
NV Of lo,0y =N,V Of MDOy
N,=N 0.1x10 00qu3N
V2 10.
.Slrength 0f KMn0= Norolitu,Of KMnO, xlqwt oF
= 0.09u 3x 31,6=2 94
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Expt. No. Page No.

CONCLUON
The At1ngth_0f give0 mohs solt sol 1 faun
t0 b 5.UL /L
The Airength Of ivo Mooy A01 1 fuod to
b 2.0+9m/L

Nom Brayaraylans
Branch Civi £ng/
Regdoo 2101)0014

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