VSEPR THEORY

VSEPR Theory
Shahd Elfki 1920522

Gharbia STEM School

Class 12F
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Abstract

The VSEPR model stands for the Valence Shell Electron Pair Repulsion model. It predicts the

geometry of molecules based on the valence shell electrons surrounding the central atom in a

molecule. The model assumes that the valence shell electrons try to minimize their repulsion and

align themselves in a way that has the least amount of energy. Thus, they achieve maximum

stability. The model provides a way to predict the geometry of a molecule, and the shape of a

molecule has a direct impact on its physical and chemical properties. The importance of the

VSEPR model in chemistry cannot be overstated. It helps us understand the bonding and non-

bonding electrons in a molecule and the resulting shape of the molecule. The shape of a molecule

affects its polarity and its reactivity. For example, molecules with symmetrical shapes are usually

nonpolar, while molecules with asymmetrical shapes are usually polar. This is important in

understanding how different molecules interact and bond with each other.

Keywords: VSEPR theory, molecular geometry, electron-pair repulsion, molecular

structure, Lewis structures

The role of valence electrons and electronegativity in the VSEPR Model

Valence electrons are the outermost electrons in an atom. They are involved in the
formation of chemical bonds between atoms. The valence electrons of an atom determine its
reactivity and chemical properties. Elements in the same column of the periodic table have the
same number of valence electrons. For example, all elements in group 1 have one valence electron,
whereas all elements in group 18 have eight valence electrons. The valence electrons have an
important role in the bonding process. Atoms form bonds by sharing or transferring electrons. The
electrons involved in bonding are the valence electrons. When atoms share electrons to form a
covalent bond, they each contribute one or more valence electrons. When ions form by the transfer
of valence electrons, the resulting ions have a full valence shell of electrons. The Valence Shell
Electron Pair Repulsion (VSEPR) model is a theory that describes how the shape of a molecule is
determined by the arrangement of the valence electrons. In the VSEPR model, the valence
electrons are arranged in pairs around the central atom. These pairs of electrons repel one another,
causing the molecule to adopt a certain shape. Electronegativity is the tendency of an atom to
attract electrons toward itself. The more electronegative an atom is, the stronger the attraction it
has for electrons. Electronegativity plays an important role in the VSEPR model. The shape of a
molecule is determined by the arrangement of valence electron pairs, which are in turn influenced
by the electronegativity of the atoms in the molecule. In the VSEPR model, the shape of a molecule
is determined by the arrangement of the valence electron pairs around the central atom. The
electronegativity of the atoms in the molecule determines the polarity of the bonds between them,
and therefore the overall polarity of the molecule. A polar molecule has a partial positive charge
at one end and a partial negative charge at the other end. The polarity of a molecule can have
important implications for its physical and chemical properties.

An outline of molecular geometry

When discussing molecular geometry, it is important to understand the concept of valence

geometry can be divided into two types: electronic geometry and molecular shape. Electronic
geometry refers to the arrangement of atoms and electron pairs around the central atom in a
molecule, while molecular shape refers to the actual shape of the molecule. There are several
factors that influence molecular geometry, including the number of electron pairs, the type of atom
and its hybridization, and the nature of the bonds. One of the most important factors in molecular
geometry is the VSEPR theory (Valence Shell Electron Pair Repulsion). This theory states that
electron pairs in the valence shell of an atom repel each other, causing them to be arranged as far
apart as possible in space. This results in predictable shapes, such as linear, trigonal planar,
tetrahedral, and octahedral. Knowing the VSEPR theory allows us to predict the molecular
geometry of a molecule, which is important for understanding its properties and reactivity.
Molecular geometry is a crucial concept in chemistry. It helps us understand the 3D shape of
molecules and the behavior of atoms in a compound. The VSEPR theory is an essential tool for
predicting molecular geometry, but there are other factors that can influence it, such as the
hybridization of the central atom and the type of bonds present in the molecule. Understanding
molecular geometry can help us design new drugs, predict chemical reactions, and develop new
materials for various applications.

Determining the molecular geometry and molecular shapes.

Molecular geometry is an important concept in chemistry that can help predict various properties
and behaviors of molecules. The molecular geometry of a substance refers to the spatial
arrangement of its atoms and its overall shape. Determining the molecular geometry is critical
when analyzing the bonding and reactivity of molecules. The process used to determine molecular
geometry involves several steps. First, the structure of the molecule must be drawn and its Lewis
structure identified. The Lewis structure shows the arrangement of atoms, bonds, and lone pairs
within the molecule. Using this, the next step is to determine the electron geometry of the molecule,
which is based on the arrangement of the electron pairs around the central atom. Once the electron
geometry is determined, the molecular geometry can be deduced. This is based on the number of
bonding and non-bonding electron pairs, and also the electronegativity of the atoms in the
molecule. For instance, if there is only one type of atom in the molecule, it will be linear. If there
are three atoms in the molecule, the shape may be trigonal planar, depending on the electron
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configuration. Identifying the electron pairs and molecular shapes can be achieved by following a
few basic steps. Firstly, the Lewis dot structure of the molecule needs to be drawn, carefully
labeling each atom and identifying the number of valence electrons they possess. Electrons that
belong to a bond are counted as a pair, while lone pairs are individual sets of electrons. Next, the
VSEPR (Valence Shell Electron Pair Repulsion) theory can be used to determine the optimal shape
of the molecule. This theory assumes that electron pairs in the valence shell adopt an arrangement
that minimizes their repulsion with one another. The shape can then be predicted by identifying
the number of atoms bonded to the central atom and the number of lone pairs surrounding the
central atom. In order to identify the type of molecular geometry, the final step involves comparing
the molecule to a list of known geometric shapes. These include linear, trigonal planar, tetrahedral,
trigonal bipyramidal, and octahedral. Depending on the number and arrangement of electron pairs,
the molecule can fall into any one of these categories. This information can be useful in
understanding the reaction properties and interactions of the molecule.

Limitations of VSEPR theory

Despite its usefulness, the VSEPR (Valence Shell Electron Pair Repulsion) model has some
limitations that make it unable to account for certain chemical properties. Firstly, the VSEPR
model is limited to predicting the molecular shape of molecules with central atoms containing only
one s- and three p-orbitals, which significantly restricts the scope of its applicability. This
limitation arises because VSEPR theory assumes that lone pairs and bonding pairs of electrons
prefer to occupy positions in space that minimize their repulsion. However, this assumption fails
for central atoms that lack the required symmetry to allow easy arrangement of lone and bonding
pairs of electrons. Secondly, the VSEPR model cannot predict the relative strengths of different
types of bonding, like ionic, covalent and metallic, among other factors. This limitation arises
because the VSEPR model is primarily focused on predicting geometric shapes of molecular
compounds based on electrostatic repulsion between valence electrons. Unfortunately, electron
distribution does not provide information about polarity, bond strength or stability that is essential
for understanding the physical and chemical properties of molecules. The VSEPR model cannot
account for the existence of compounds with non-integer valences or hypervalent central atoms.
Such molecules can have additional lone pairs of electrons located in d-orbitals, which are not
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accounted for in the VSEPR model. Therefore, researchers need to use additional models and
computational methods to predict the properties of complex molecules and structures, making it
hard to rely solely on the VSEPR model. In summary, while the VSEPR model is a useful heuristic
for predicting molecular shapes, it has limitations that reduce its utility for understanding other
chemical and physical phenomena.

Conclusion.

VSEPR (Valence Shell Electron Pair Repulsion) theory explains the geometry of molecules based
on the repulsion between electron pairs in their valence shell. It assumes molecules with different
shapes, such as linear, trigonal planar, tetrahedral, and octahedral. However, these assumptions are
not always accurate and may need to be adjusted based on experimental data. Overall, the article
provides a clear introduction to VSEPR models and their application in predicting the geometry
of molecules.
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References

- Gillespie, R. J. (2016). The VSEPR model of molecular geometry. Chemical education

research and practice, 17(2), 271-285.

- Gillespie, R. J. (2002). Modern approaches to determining molecular structure. In

Comprehensive Coordination Chemistry II (pp. 9-54). Elsevier.

- Steudel, R. (2010). Chemical bonding, structural chemistry and VSEPR theory: An

organic–inorganic example. Chemical Society Reviews, 39(4), 1252-1259.

- Park, J. H., Kim, K. S., & Lee, I. (1997). Introduction to molecular symmetry and group

theory for chemistry. Journal of Chemical Education, 74(11), 1348.

Tables

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