INSTRUCTION MANUAL

Document QuickCOD®ultra-07E4317
10/2017
Software-Version: 4.4
 LAR | PROCESS ANALYSERS AG

Certificate
Standard ISO 9001:2015
Certificate Registr. No. 01 100 5122

Certificate Holder:

LAR Process Analysers AG

Neuköllnische Allee 134
D - 12057 Berlin

Scope: Development, production, distribution and technical support

of measurement-instruments for environmental and process
analysis

Proof has been furnished by means of an audit that the

requirements of ISO 9001:2015 are met.
201 4.08 E A4 ® TÜV, TUEV and TUV are registered trademarks. Utilisation and application requires prior approval.

Validity: The certificate is valid from 2017-05-24 until 2020-05-18.

First certification 1998

2017-05-24
TÜV Rheinland
Rheinl
nland
nl
l Cert GmbH
Gmb
Am Grauen Stein · 51105 Köln

www.tuv.com

LAR Process Analysers AG

Neuköllnische Allee 134 PHONE +49 30 278958-55
D - 12057 Berlin FAX +49 30 278958-706
www.lar.com E-MAIL [email protected]

© Copyright by LAR Process Analysers AG 1993-2017.

All rights reserved. This manual is meant to help the owner to operate the LAR analyser and is provided only for this.
No part of this manual may be reproduced, stored in any retrieval system, transmitted, or used in any form or by any
means, whether graphic, electronic, mechanical, photocopy, or otherwise by technology known or unknown, without
the prior written permission of LAR Process Analysers AG. Rights remain reserved to matters changes for technical
improvements. QuickCOD®ultra is a registered trademark by the German Patent and Trademark Office for LAR Pro-
cess Analysers AG.
LAR | PROCESS ANALYSERS AG

CONTENTS
1 General Information.......................................................................................................................... 1
1.1 Safety Information ................................................................................................................. 1
1.2 Safety Signs .......................................................................................................................... 2

2 Operating Principle of the QuickCOD®ultra ..................................................................................... 3

2.1 The Measurement of COD according to conventional DIN method ...................................... 3
2.2 Advantages of the QuickCOD®ultra ....................................................................................... 3
2.3 Methods for the determination of thermal COD .................................................................... 4
2.3.1 CODo Method........................................................................................................... 4
2.3.2 CODi Method............................................................................................................ 4
2.4 The Measurement Principle of the CODo Method ................................................................ 5
2.5 Peak Area Integration of the CODo Method ......................................................................... 6
2.6 Calculation to determine the required O2-content ................................................................ 7
2.7 Measurement Ranges of the COD Measurement ................................................................ 8

3 Product .............................................................................................................................................. 9
3.1 Scope of Delivery .................................................................................................................. 9
3.2 Nameplate ............................................................................................................................ 9
3.3 Construction of the Analyser ............................................................................................... 10
3.3.1 Front View of the Analyser ..................................................................................... 10
3.3.2 Bottom View of the Analyser .................................................................................. 11
3.3.3 Top View of the Analyser........................................................................................ 11
3.3.4 Right Side View of the Analyser ............................................................................. 12
3.3.5 Left Side View of the Analyser................................................................................ 12
3.4 Components of the Analyser .............................................................................................. 13
3.4.1 Pump System ......................................................................................................... 13
3.4.1.1 Tube Cassette Pump ...................................................................................... 14
3.4.1.2 Tubes (for Tube Cassette Pump) ................................................................... 14
3.4.1.3 Sample Pump ................................................................................................. 15
3.4.2 Glass Components ................................................................................................. 16
3.4.3 Furnace System ..................................................................................................... 17
3.4.4 Connections............................................................................................................ 18
3.4.4.1 Installation Plate ............................................................................................. 18
3.4.4.2 Mains Connection ........................................................................................... 19
3.4.5 Electronic Connections (digital and analog connections) ....................................... 20
3.4.5.1 Connections on the TRC-Board ..................................................................... 20
3.4.5.2 RS232 Serial Interface ................................................................................... 22
3.4.5.3 Digital Inputs ................................................................................................... 22
3.4.5.4 Relays ............................................................................................................ 23
3.4.5.5 Analog Outputs ............................................................................................... 23
3.5 Carrier Gas ......................................................................................................................... 27

4 Installation ....................................................................................................................................... 29
4.1 Installation Procedure ......................................................................................................... 29
4.1.1 Installation of the Analyser ..................................................................................... 29
4.1.2 Installation of optional Accessories ........................................................................ 29
4.2 Site Selection - Ambient Conditions ................................................................................... 31
4.3 Mounting and Installation of the Analyser on Site ............................................................... 32
4.3.1 Maximum Swing Open of the Housing ................................................................... 33
4.3.2 Wall Mounting......................................................................................................... 34
4.4 Provide Carrier Gas ............................................................................................................ 36
4.5 Provide Sample Inlet and Drain .......................................................................................... 36
4.6 Provide Power Supply ........................................................................................................ 36
4.7 Install Signal Connections .................................................................................................. 37
4.8 Provide Rinsing Water ........................................................................................................ 37
4.9 Provide Acid Solution (TOC-Direct and TOC-Difference Method) ...................................... 37

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4.10 Provide Calibration Standards .......................................................................................... 38

5 Start-Up............................................................................................................................................ 39
5.1 Start-Up Procedure ............................................................................................................. 39
5.1.1 Start-Up of the Analyser ......................................................................................... 39
5.1.2 Start-Up of optional Accessories ............................................................................ 39
5.2 Checking the Pre-Fusing .................................................................................................... 41
5.3 Checking the Installation Plate ........................................................................................... 41
5.4 Remove Transportation Locks ............................................................................................ 41
5.4.1 Furnace Transport Screw ....................................................................................... 42
5.4.2 Cable Tie at XY-System ......................................................................................... 43
5.5 Align the Voltage ................................................................................................................. 44
5.6 Switch on the Fuses ........................................................................................................... 44
5.7 Filling and Installation of the Reactor Pipe ......................................................................... 45
5.8 First switch on of the Analyser ............................................................................................ 46
5.9 Completing the Furnace System ........................................................................................ 47
5.10 Installation of the Glass Components ............................................................................... 48
5.11 Installation of the Pump Tubes ......................................................................................... 49
5.11.1 Installation of the Tubes in the Tube Cassette Pump........................................... 49
5.11.2 Installation of the Tubes in the Sample Pump ...................................................... 50
5.12 Tubing of the Analyser ...................................................................................................... 51
5.13 Test Run ........................................................................................................................... 52
5.14 Rinse the Injection System und Sample Tubes ................................................................ 52
5.15 Costumisation of application specific Settings .................................................................. 52
5.16 Checking the Status Parameters ...................................................................................... 52
5.17 Perform a Calibration ........................................................................................................ 53
5.18 Start the Measuring Mode ................................................................................................ 53

6 Reagents and Calibration Standards ............................................................................................ 55

6.1 Reagents ............................................................................................................................ 55
6.1.1 Deionised Water ..................................................................................................... 55
6.1.2 Rinsing Water ......................................................................................................... 56
6.1.3 Phosphoric Acid (H3PO4) for TOC-Difference Method........................................... 56
6.1.4 Hydrochloric Acid (HCl) for TOC-Direct Method (NPOC-Method) .......................... 57
6.1.5 Cleaning Solution for Glass Components............................................................... 57
6.2 Production of Calibration Standards (CODo Method) ......................................................... 58
6.2.1 Calibration Standards - CODo Method................................................................... 59
6.3 Production of Calibration Standards (CODi Method) .......................................................... 60
6.3.1 Calibration Standards - TOC-Difference Method.................................................... 61
6.3.1.1 Stock Solution - TOC-Difference Method ....................................................... 61
6.3.1.2 Dilution of the Stock Solution - TOC-Difference Method ................................ 62
6.3.2 Calibration Standards - TOC-Direct Method / TConly Method ............................... 63
6.3.2.1 Stock Solution - TOC-Direct Method / TConly Method ................................... 63
6.3.2.2 Dilution of the Stock Solution - TOC-Direct Method / TConly Method ............ 64

7 How to work with the QuickCOD®ultra ........................................................................................... 65

7.1 General remarks concerning the operating software .......................................................... 66
7.1.1 Online-Mode ........................................................................................................... 66
7.1.2 Keypad ................................................................................................................... 66
7.1.3 Access rights / operator levels................................................................................ 67
7.2 Configuration ...................................................................................................................... 69
7.2.1 Adjusting the operating parameters........................................................................ 69
7.2.2 Measurement parameter ........................................................................................ 70
7.2.2.1 Measurement interval 1 to 6 Streams ............................................................. 71
7.2.2.2 Moving average .............................................................................................. 71
7.2.2.3 Correlation factor CODi / TOC ........................................................................ 71
7.2.2.4 Filling sample vessel time ............................................................................... 71
7.2.2.5 Stripping time ................................................................................................. 71
7.2.2.6 TC delay ......................................................................................................... 71

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7.2.2.7 TIC delay ........................................................................................................ 71

7.2.2.8 Measurement replicates ................................................................................. 72
7.2.2.9 Measurements outliers ................................................................................... 72
7.2.2.10 Measurements max. CV ............................................................................... 72
7.2.2.11 Rinse before sampling .................................................................................. 72
7.2.2.12 Rinsing count 1 to 6 streams ........................................................................ 72
7.2.3 Calibration .............................................................................................................. 73
7.2.3.1 Calibration carry out ....................................................................................... 74
7.2.3.2 Calibration result ............................................................................................. 78
7.2.3.3 Active calibration ............................................................................................ 79
7.2.4 Injection volume...................................................................................................... 80
7.2.4.1 Dilution ........................................................................................................... 80
7.2.4.2 TC for each stream ......................................................................................... 80
7.2.4.3 TIC for each stream ........................................................................................ 80
7.2.5 Relay setting........................................................................................................... 81
7.2.5.1 Tools for programming ................................................................................... 82
7.2.5.2 Relay testing ................................................................................................... 82
7.2.6 PC settings ............................................................................................................. 83
7.2.6.1 Operator password ......................................................................................... 83
7.2.6.2 Date/ Time ...................................................................................................... 83
7.2.6.3 Full software version ....................................................................................... 84
7.2.7 Display channel ...................................................................................................... 84
7.2.8 Measurement value screen .................................................................................... 85
7.2.9 Signal curve............................................................................................................ 86
7.2.10 Status screen........................................................................................................ 87
7.2.11 Service action ....................................................................................................... 88
7.2.11.1 Choose stream for operation ........................................................................ 89
7.2.11.2 Maintenance ................................................................................................. 89
7.2.11.3 Rinsing sample tubes ................................................................................... 90
7.2.11.4 Rinse injection system .................................................................................. 90
7.2.11.5 Furnace on / off ............................................................................................ 90
7.2.11.6 Furnace valve open / close ........................................................................... 90
7.2.11.7 Condensate pump on / off ............................................................................ 91
7.2.11.8 Stirrer on/off .................................................................................................. 91
7.2.12 Single measurement............................................................................................. 92
7.2.13 Test run ................................................................................................................ 94
7.2.13.1 Manual test run ............................................................................................. 94
7.2.13.2 Positioning / justification of the x - axis ......................................................... 95
7.2.13.3 Puncture test ................................................................................................ 95
7.2.13.4 Test injection system .................................................................................... 95
7.2.13.5 Cancel last operation .................................................................................... 95
7.2.14 Auto - Check......................................................................................................... 96
7.2.14.1 Automatic - check: automatic calibration using standards ............................ 97
7.2.14.2 Auto-check: automatic verification using standards ..................................... 97
7.2.15 Limit setting .......................................................................................................... 98
7.2.16 Data base ............................................................................................................. 99
7.2.16.1 Measurement data as a table ..................................................................... 101
7.2.16.2 Measurement data as a curve .................................................................... 102
7.2.17 Log - book........................................................................................................... 103
7.2.18 Data storage ....................................................................................................... 105
7.2.19 Analog out calibration ......................................................................................... 106
7.3 Important tasks, good to know .......................................................................................... 107
7.3.1 Password.............................................................................................................. 107
7.3.2 Software version................................................................................................... 107
7.3.3 Terminating RUN mode (stop).............................................................................. 107
7.3.4 Furnace On/ Off.................................................................................................... 107
7.3.5 Condensate Pump On/ Off ................................................................................... 107
7.3.6 Date and time ....................................................................................................... 108

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7.3.7 Language.............................................................................................................. 108

7.3.8 Save ..................................................................................................................... 109
7.3.9 Wizards................................................................................................................. 110
7.4 The status identification (control state) and errors ............................................................ 111
7.5 Level III: Only For Trained Users ...................................................................................... 114
7.5.1 Access rights ........................................................................................................ 114
7.5.2 Operating level III ................................................................................................. 114
7.5.2.1 Level II: measurement parameters ............................................................... 115
7.5.2.1.1 Percentage with multiple determinations ............................................. 115
7.5.2.2 Level II: PC setting ....................................................................................... 117
7.5.2.2.1 Activate and deactivate the password ................................................. 117
7.5.2.2.2 Drag and Drop ..................................................................................... 117
7.5.2.3 Calibration result ........................................................................................... 118
7.5.2.4 Active calibration .......................................................................................... 119
7.5.2.5 CAN selftest ................................................................................................. 120
7.5.2.6 Hardware info ............................................................................................... 121
7.5.2.7 Digital IN 1 and 2 .......................................................................................... 123
7.5.2.8 Digital OUT 1 and 2 ...................................................................................... 124
7.5.2.9 Calibration in level III .................................................................................... 125
7.5.2.9.1 Service calibration ............................................................................... 125
7.5.2.10 Service parameters .................................................................................... 128
7.5.2.10.1 Calibration values for carrier gas stream ........................................... 128
7.5.2.10.2 Allowed deviation .............................................................................. 128
7.5.2.10.3 Measurement even if airflow is incorrect ........................................... 128
7.5.2.10.4 Threshold value of the carrier gas humidity ...................................... 129
7.5.2.10.5 Calibrating gas flow ........................................................................... 129
7.5.2.10.6 TIC-Port with motor ........................................................................... 129
7.5.2.11 Name and Unit ........................................................................................... 130

8 Care and Maintenance.................................................................................................................. 131

8.1 Overview of regular Care and Maintenance Actions ........................................................ 132
8.2 Visual Inspection ............................................................................................................... 133
8.3 Perform Visual Inspection ................................................................................................. 134
8.3.1 Zero Signal (weekly)............................................................................................. 134
8.3.2 Carrier Gas (weekly)............................................................................................. 134
8.3.3 Injection System (weekly)..................................................................................... 134
8.3.4 Injection Needle (weekly) ..................................................................................... 135
8.3.5 Glass Components (weekly)................................................................................. 135
8.3.6 Canister and Supply Tubes (weekly).................................................................... 135
8.3.7 Inlet and Drain Tubes (weekly)............................................................................. 135
8.3.8 Injection Tube (3 monthly) .................................................................................... 136
8.3.9 TIC Stripping Vessel (3 monthly).......................................................................... 137
8.3.10 Running Rails (XY-System) (3 monthly)............................................................. 138
8.3.11 Tube Cassette Pump and Pump Tubes (3 monthly) .......................................... 138
8.3.12 Sample Pump and Pump Tubes (3 monthly)...................................................... 138
8.3.13 Viton Tubes (3 monthly) ..................................................................................... 138
8.3.14 Filter Mats (3 monthly)........................................................................................ 139
8.3.15 Acid Trap (3 monthly) ......................................................................................... 140
8.3.16 Quartz Wool Filter (3 monthly)............................................................................ 140
8.4 Care Actions ..................................................................................................................... 141
8.5 Perform Care Actions ....................................................................................................... 142
8.5.1 Rinse the Injection System ................................................................................... 142
8.5.2 Clean Glass Components..................................................................................... 142
8.5.3 Fill Canisters......................................................................................................... 142
8.5.4 Clean Canisters .................................................................................................... 143
8.5.5 Clean Supply Tubes ............................................................................................. 143
8.5.6 Clean Inlet and Drain Tubes................................................................................. 143
8.5.7 Clean Teflon Tube (Reactor Foot)........................................................................ 143

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8.5.8 Clean Reactor Foot .............................................................................................. 144

8.5.9 Clean Injection Tube............................................................................................. 144
8.5.10 Clean Reactor Pipe ............................................................................................ 145
8.5.11 Clean TIC Stripping Vessel ................................................................................ 146
8.5.12 Clean Gas Cooling Pipe ..................................................................................... 146
8.5.13 Clean Running Rails (XY-System) ..................................................................... 147
8.5.14 Grease Running Rails (XY-System) ................................................................... 147
8.5.15 CleanTube Cassette Pump and Pump Cassettes .............................................. 148
8.5.16 Clean Sample Pump........................................................................................... 148
8.5.17 Adjust Sample Pump .......................................................................................... 149
8.5.18 Clean Viton Tube................................................................................................ 149
8.5.19 Clean Injection Needle ....................................................................................... 150
8.5.20 Renew Calibration Standard............................................................................... 150
8.5.21 Clean Needle Guide (Injection Port)................................................................... 150
8.5.22 Check the Furnace System ................................................................................ 151
8.5.23 Check the Gas Cooling Pipes............................................................................. 152
8.5.24 Clean and oil Injection Port................................................................................. 153
8.5.25 Move Pump Tubes (Tube Cassette Pump) ........................................................ 154
8.5.26 Check the mechanical backlash of the XY-System ............................................ 154
8.5.27 Check the Injection Port ..................................................................................... 155
8.6 Maintenance Actions ........................................................................................................ 156
8.7 Perform Maintenance Actions ........................................................................................... 157
8.7.1 Replace Supply Tubes ......................................................................................... 157
8.7.2 Replace Inlet and Drain Tubes ............................................................................. 157
8.7.3 Replace Teflon Tube (Reactor Foot) .................................................................... 157
8.7.4 Replace Reactor Pipe Filling / Reactor Pipe ........................................................ 158
8.7.5 Replace Small Furnace Head Seal (upper).......................................................... 160
8.7.6 Replace Big Furnace Head Seal (Silicone O-Ring with PFA coat)....................... 161
8.7.7 Replace Injection Tube......................................................................................... 161
8.7.8 Replace Viton Tube .............................................................................................. 161
8.7.9 Replace Acid Trap Filling...................................................................................... 162
8.7.10 Replace Acid Trap .............................................................................................. 162
8.7.11 Replace Quartz Wool Filter Filling ...................................................................... 163
8.7.12 Replace Quartz Wool Filter ................................................................................ 163
8.7.13 Replace Filter Mats............................................................................................. 164
8.7.14 Replace Injection Needle.................................................................................... 165
8.7.15 Replace Silicone Seal for TIC-Port (TOC-Difference Method) ........................... 165
8.7.16 Replace Needle Guide Seal (Injection Port)....................................................... 166
8.7.17 Replace Silicone Seals for Glass Components .................................................. 166
8.7.18 Replace Seal for Reactor Foot ........................................................................... 167
8.7.19 Replace Pump Tube (Tube Cassette Pump)...................................................... 168
8.7.20 Replace Pump Tube (Sample Pump)................................................................. 168
8.7.21 Replace Gas Filter.............................................................................................. 168
8.8 Function Tests .................................................................................................................. 169
8.8.1 Check Device Status ............................................................................................ 169
8.8.2 Tightness Test ...................................................................................................... 170
8.8.3 Test Run (XY-System).......................................................................................... 170
8.8.4 Checking the Measurement Results..................................................................... 170
8.8.5 Checking the Measurement Process.................................................................... 170
8.9 Short-Time- and Long-Time Interruptions ......................................................................... 171
8.9.1 Switching On/Off for Short-Time-Interruptions (<1 Week) ................................... 171
8.9.2 Switching On/Off for Long-Time Interruptions (>1 Week) .................................... 171

9 Accessories and Options............................................................................................................. 173

9.1 Overview of Opportunities for Accessories and Options .................................................. 173
9.2 Reagent Cabinet ............................................................................................................... 174
9.2.1 Construction of the Reagent Cabinet ................................................................... 174
9.2.2 Installation of the Reagent Cabinet ...................................................................... 175

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9.2.3 Start-Up of the Reagent Cabinet .......................................................................... 176

9.3 Permeation Unit ................................................................................................................ 177
9.3.1 Construction of the Permeation Unit..................................................................... 177
9.3.2 Installation of the Permeation Unit........................................................................ 178
9.3.3 Start-Up of the Permeation Unit ........................................................................... 179
9.3.3.1 Electrical Connection of the Permeation Unit ............................................... 179
9.3.4 Care and Maintenance Actions (Permeation Unit) ............................................... 180
9.3.5 Perform Visual Inspection (Permeation Unit) ....................................................... 181
9.3.5.1 Temperature ................................................................................................. 181
9.3.5.2 Silicone Tube ................................................................................................ 181
9.3.5.3 Tightness ...................................................................................................... 181
9.4 Ambient Air Preparation Unit ............................................................................................ 182
9.4.1 Construction of the Ambient Air Preparation Unit................................................. 182
9.4.1.1 Activated Carbon .......................................................................................... 183
9.4.1.2 Soda Lime Pellets ........................................................................................ 183
9.4.1.3 Flow Diagram of the Ambient Air Preparation Unit ....................................... 183
9.4.2 Installation of the Ambient Air Preparation Unit.................................................... 184
9.4.3 Start-Up of the Ambient Air Preparation Unit........................................................ 185
9.4.3.1 Transportation Locks .................................................................................... 185
9.4.3.2 Tubing of the Ambient Air Preparation Unit .................................................. 186
9.4.3.3 Electrical Connection of the Ambient Air Preparation Unit ........................... 188
9.4.4 Care and Maintenance Actions (Ambient Air Preparation Unit) ........................... 189
9.4.5 Perform Visual Inspection (Ambient Air Preparation Unit).................................... 190
9.4.5.1 Fine Filter Element ....................................................................................... 190
9.4.5.2 Filter Unit ...................................................................................................... 191
9.4.5.3 Soda Lime .................................................................................................... 191
9.4.5.4 Tube Connections ........................................................................................ 191
9.4.5.5 Pre Pressure of the Carrier Gas ................................................................... 191
9.4.6 Perform Care and Maintenance Actions (Ambient Air Preparation Unit).............. 192
9.4.6.1 Replace Soda Lime ...................................................................................... 192
9.4.6.2 Replace Gas Filter ........................................................................................ 193
9.4.6.3 Replace Filter Mats ....................................................................................... 194
9.4.6.4 Replace Fine Filter Unit ................................................................................ 194
9.4.6.5 Replace Coarse Filter Unit ........................................................................... 195
9.4.6.6 Replace Activated Carbon ............................................................................ 195
9.5 FlowSampler® ................................................................................................................... 196
9.5.1 Variants of FlowSampler® .................................................................................... 196
9.5.2 FlowSampler® DN25 ............................................................................................ 197
9.5.3 FlowSampler® DN17 ............................................................................................ 198
9.5.4 Installation of the FlowSampler® .......................................................................... 199
9.5.5 Start-Up of the FlowSampler® .............................................................................. 199
9.5.6 Care and Maintenance Actions (FlowSampler®) .................................................. 200
9.5.7 Perform Visual Inspections (FlowSampler®) ........................................................ 201
9.5.7.1 Flow .............................................................................................................. 201
9.5.7.2 Sampling Pipe (Needle) ................................................................................ 201
9.5.8 Perform Care and Maintenance Actions (FlowSampler®) .................................... 202
9.5.8.1 Clean Sampling Pipe (Needle) ..................................................................... 202
9.5.8.2 Clean FlowSampler® .................................................................................... 202
9.6 CO2-Remover ................................................................................................................... 203
9.6.1 Procedure of compressed air drying and CO2 removal........................................ 203
9.6.2 Construction of the CO2-Remover........................................................................ 203
9.6.3 Installation of the CO2-Remover........................................................................... 204
9.6.4 Start-Up of the CO2-Remover .............................................................................. 205
9.6.5 Care and Maintenance Actions (CO2-Remover) .................................................. 206
9.6.6 Perform Visual Inspections (CO2-Remover)......................................................... 207
9.6.6.1 Housing ........................................................................................................ 207
9.6.6.2 Service-Lamp ............................................................................................... 207
9.7 Mounting Rack .................................................................................................................. 208

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9.8 Multi Stream Option .......................................................................................................... 210

9.9 Multi Parameter Option ..................................................................................................... 211
9.10 High Salt Option .............................................................................................................. 211
9.11 Auto-TIC-Port .................................................................................................................. 212
9.11.1 Construction of the TIC Reactor with Auto-TIC-Port .......................................... 212
9.11.2 Start-Up of the TIC Reactor with Auto-TIC-Port ................................................. 212
9.11.3 Care and Maintenance Actions (Auto-TIC-Port)................................................. 213
9.11.4 Perform Visual Inspections (Auto-TIC-Port) ....................................................... 214
9.11.4.1 Microswitch on Auto-TIC-Port (6 Months) .................................................. 214
9.11.5 Perform Care and Maintenance Actions (Auto-TIC-Port) ................................... 215
9.11.5.1 Replace Needle Guide Seal (Auto-TIC-Port) (1 Month) ............................. 215
9.11.5.2 Clean Needle Guide (Auto-TIC-Port) (1 Month) ......................................... 216
9.11.6 Clean and oil Auto-TIC-Port (3 Months) ............................................................. 217
9.12 Internal Sample Dilution .................................................................................................. 218
9.12.1 Software Settings for the Internal Sample Dilution ............................................. 218
9.12.2 Flow Diagram with Internal Sample Dilution....................................................... 219

10 Minor disruptions - quickly rectified ......................................................................................... 221

10.1 Preconditions for fault-free Measurement Mode ............................................................. 221
10.2 Breakdowns .................................................................................................................... 222
10.3 Check the Fuses - Automatic Circuit Breaker ................................................................. 223
10.4 Breakdowns of the Temperature Regulators .................................................................. 224

11 Technical Information................................................................................................................. 225

11.1 Analyser Specifications ................................................................................................... 225
11.2 Ambient Conditions ......................................................................................................... 226
11.3 Specifications of Accessories and Options ..................................................................... 226

12 Flow Diagrams for QuickCOD®ultra ........................................................................................... 227

12.1 Component Labeling ....................................................................................................... 228
12.2 CODo Method (1 Sample Stream) .................................................................................. 230
12.3 CODi Method via TOC-Difference Method (1 Sample Stream) ...................................... 231
12.4 CODi Method via TOC-Difference Method (3 Sample Streams) .................................... 232
12.5 CODi Method via TOC-Direct Method (1 Sample Streams) ........................................... 233
12.6 CODi Method via TOC-Direct Method (2 Sample Streams) ........................................... 234
12.7 CODi Method via TConly Method (1 Sample Stream) .................................................... 235
12.8 CODi Method via TConly Method (2 Sample Streams) .................................................. 236
12.9 Flow Diagram of the Ambient Air Preparation Unit (Option) ........................................... 237
12.10 Flow Diagram with Internal Sample Dilution (Option) ................................................... 238

13 Operating, Care and Maintenance Logs ................................................................................... 239

13.1 Operating Log ................................................................................................................. 240
13.2 Visual Inspections Log (Analyser) .................................................................................. 241
13.3 Care Log (Analyser) ........................................................................................................ 242
13.4 Maintenance Log (Analyser) ........................................................................................... 243
13.5 Function Test Log (Analyser) .......................................................................................... 244
13.6 Visual Inspection Log (Permeation Unit) ........................................................................ 245
13.7 Visual Inspection Log (Ambient Air Preparation Unit) ..................................................... 246
13.8 Care and Maintenance Log (Ambient Air Preparation Unit) ........................................... 247
13.9 Visual Inspection Log (FlowSampler) ............................................................................. 248
13.10 Care and Maintenance Log (FlowSampler) .................................................................. 249
13.11 Visual Inspection Log (CO2-Remover) ......................................................................... 250
13.12 Care and Maintenance Log (CO2-Remover) ................................................................ 251
13.13 Visual Inspection Log (Auto-TIC-Port) .......................................................................... 252
13.14 Care and Maintenance Log (Auto-TIC-Port) ................................................................. 253

14 Safety Data Sheets...................................................................................................................... 255

15 Contact......................................................................................................................................... 257

07E4317 Instruction Manual QuickCOD®ultra vii

 LAR | PROCESS ANALYSERS AG

15.1 LAR Contact ................................................................................................................... 257

15.2 Distributors / Authorized Service Partners ...................................................................... 257
15.3 Optimization .................................................................................................................... 257

viii Instruction Manual QuickCOD®ultra 07E4317

 1 General Information
LAR | PROCESS ANALYSERS AG 1.1 Safety Information

1 General Information

The following symbols are used in this operating manual to highlight instructions:

i x !
Notice Danger Caution

• The operating manual must be read carefully prior to use!

i • Keep the operating manual for later reference!

Notice • The warranty can become void if the analyser is used improperly.

1.1 Safety Information

• The general codes for working with chemicals and electrical equipment must be
! observed whilst the analyser is being used.
• The voltage specified on the nameplate of the analyser must match that of your
Caution
power supply.

• Those with a pacemaker fitted must keep away.

• Bear in mind the hazards potentially emanating from the different waters.

• Use protective gloves and goggles as required.

• The analyser must be switched off before work on live parts is carried out.
• The rear part of the analyser may only be opened by authorised personnel (for
safety reasons)!
• When work is carried out in the front part of the enclosure, you must ensure that
the analyser is in Offline mode, and so the XY system is in the Stop position. It
must not be moving (to prevent hand injuries).
• If faults occur when the analyser is running which you cannot rectify yourself,
please contact your local partner or the Technical Support of LAR (Chapter 15
on page 257).

07E4317 Instruction Manual QuickCOD®ultra 1

 1 General Information
1.2 Safety Signs LAR | PROCESS ANALYSERS AG

1.2 Safety Signs

i •

•
A few safety symbols are affixed to the analyser for the safety of users.

Please observe the different symbols when working on the analyser.

Notice

Mandatory signs:

Observe manual Wear glasses Wear gloves

Warning signs:

Hot surface Corrosive substances High voltage

Prohibition signs:

Off limits to unauthorized

personnel!

2 Instruction Manual QuickCOD®ultra 07E4317

 2 Operating Principle of the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 2.1 The Measurement of COD according to conventional DIN method

2 Operating Principle of the QuickCOD®ultra

The QuickCOD®ultra is an online measurement system which can determine the corresponding parame-
ters using the high temperature method at 1,200°C according to the following measurement methods:

• CODo Method: COD / TOD (Measurement of oxygen consumption according to ASTM D6238-98
(Reapproved 2011))
• CODi Method: correlated COD (Correlation from TOC according to DIN EN 1484:1997 and
US-EPA 415.2)

2.1 The Measurement of COD according to conventional DIN method

The COD (Chemical Oxygen Demand) is a widespread sum parameter for determining organic waste
loads. It is used in the planning of sewage treatment plants, the control of their purification capacity, and
the calculation of wastewater disposal. Its determination is standardized for concentrations greater than
15 mg/l in DIN 38409-H41 (Issue Dec. 1980) or between 5 and 50 mg/I in DIN 38409-H44 (Issue May
1992). The processes defined there are based on the wet chemical oxidation of a wastewater sample
with potassium dichromate in sulfuric acid solution. As a catalyst, silver ions are added and mercury sul-
fate is used to mask chloride ions. This results in highly toxic chemicals, which have stringent require-
ments for occupational health and safety and must be disposed of in a costly manner. Furthermore, the
described method is quite time-consuming and not suitable for online monitoring since a determination
takes about 3 hours.

2.2 Advantages of the QuickCOD®ultra

The QuickCOD®ultra allows fast and easy determination of the COD in 3 minutes by the thermal oxidation
of the wastewater sample in a high temperature furnace at 1,200°C. Hazardous chemicals are not used
and catalysts are not necessary. Nevertheless, high recovery rates are obtained which are comparable
to those of the DIN method. Depending on the composition of the wastewater, a generally constant ratio
between DIN COD and thermal COD is obtained, which can be taken into account by means of an ad-
justable correlation factor with the measured value. The interferences caused by chloride ions that occur
in the DIN process, which require a mercury mask, do not play a role in thermal oxidation. A combination
of the COD determination with the other methods (TOC, TNb) is possible.

07E4317 Instruction Manual QuickCOD®ultra 3

 2 Operating Principle of the QuickCOD®ultra
2.3 Methods for the determination of thermal COD LAR | PROCESS ANALYSERS AG

2.3 Methods for the determination of thermal COD

To determine the thermal COD, two methods are available that are based on different detection princip-
les:

2.3.1 CODo Method

The analyser measures the oxygen consumption in the thermal oxidation of the sample contents by
means of a potentiometric oxygen sensor based on zirconium dioxide directly. The oxygen consumption
determined by this method corresponds to the total oxygen consumption (TOD). A sufficient amount of
oxygen is supplied to the carrier gas and is predefined according to the measuring ranges. The oxygen
consumption after the oxidation of the sample can be determined on the software side, by recording the
short-term decrease in the oxygen content in the carrier gas from the detector and recording it as a peak.
The peak area, which is determined by integration, is directly proportional to the COD of the sample.

The measured oxygen demand of the sample correlates over a wide range with the DIN COD. The cor-
relation is largely independent of the sample composition. The quotient between DIN COD and TOD is
always 1 or smaller than 1. In contrast to DIN COD, all organic substances are 100% decomposed be-
cause of the high decomposition potential of the thermal oxidation. Furthermore, there is no cross-sen-
sitivity with CI- when compared to the COD cuvette test.

The CODo method is particularly recommended for applications where no constant factor is possible bet-
ween the DIN COD and the TOC value (see CODi method), changing sample compositions are to be
expected, or matrix effects with common COD measurements occur. Furthermore, the process is ideally
suited for applications where the assessment of the actual water load is the focus in order to implement
control processes quickly and effectively.

• The oxygen consumption appears as a positive peak in the curve as the signal

i output of the oxygen detector is inverted.

• When combining the CODo method with a TC or TNb determination, the
Notice parameters are measured simultaneously with the signals from all detectors being
evaluated.

2.3.2 CODi Method

With the CODi method, the organic carbon content is determined in the first step by means of NDIR de-
tection (see parameter TOC) and then correlated by software by means of a previously determined factor
to the COD. The correlation factor is determined using relevant laboratory results and is stored in the
operating software of the analyser. The calculation and output of the correlated COD value takes place
automatically. The output of the measured TOC value can be activated as an option.

For the CODi method it should be noted that there are strong dependencies of the sample composition.
In the case of strongly changing concentrations, inaccuracies may occur. The method is therefore mainly
suitable for measurements of constant loads/concentrations.

4 Instruction Manual QuickCOD®ultra 07E4317

 2 Operating Principle of the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 2.4 The Measurement Principle of the CODo Method

2.4 The Measurement Principle of the CODo Method

Fig. 1: The Measurement Principle of the CODo Method

First, the sample is transferred into the sample vessel via the inlet by the help of a peristaltic pump, be-
fore the sample is injected into the ceramic furnace via the injection system (a-b in Fig. 1, page 5).

The sample oxidises completely at 1,200°C in the ceramic furnace. The oxygen consumption corre-
sponds to the oxygen demand of the sample. The carrier gas, which flows continuously through the ce-
ramic furnace, transports the oxidized gas further.

The water vapour produced by oxidation is condensated out by the cooler, and remaining corrosive com-
bustion gasses are then cleaned by the filters. Then the O2-concentration is determined in a O2-detector.

07E4317 Instruction Manual QuickCOD®ultra 5

 2 Operating Principle of the QuickCOD®ultra
2.5 Peak Area Integration of the CODo Method LAR | PROCESS ANALYSERS AG

2.5 Peak Area Integration of the CODo Method

The measuring system is continuously perfused with a carrier gas (consisting of oxygen-enriched nitro-
gen 5.0) (see Chapter 2.7 on page 8 and Chapter 3.5 on page 27). This carrier gas has a defined O2-
concentration which is steadily determined by the O2-detector and is expressed as the initial value (base-
line) for the calculation of consumption (see graph „a“ in Fig. 2, page 6). During oxidation at 1,200°C,
oxygen is consumed. This oxygen consumption is represented as a peak and is calculated using a sur-
face integration (see graph „b“ in Fig. 2, page 6). After that, the oxygen consumption is output as a COD
value from the system. The peak is inverted to have a better illustration of the measured COD value (see
graph „c“ in Fig. 2, page 6).

Fig. 2: Peak Area Integration of the CODo Method

6 Instruction Manual QuickCOD®ultra 07E4317

 2 Operating Principle of the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 2.6 Calculation to determine the required O2-content

2.6 Calculation to determine the required O2-content

To determine the required O2-content in the carrier gas, use the following formula:

Fig. 3: Formula for calculating the required O2-content

• Ensure that sufficient oxygen is always available for oxidation, because otherwise
! the measuring cell can become sooty as the organic/carbon is not completely
oxidized.
Caution

07E4317 Instruction Manual QuickCOD®ultra 7

 2 Operating Principle of the QuickCOD®ultra
2.7 Measurement Ranges of the COD Measurement LAR | PROCESS ANALYSERS AG

2.7 Measurement Ranges of the COD Measurement

The following table shows the standard measurement ranges of the analyser with required O2-content
in the carrier gas and recommended carrier gas treatment.

Table 1: Standard Measurement Ranges of the COD Measurement

Recommended
COD Measurement Recommended Carrier Gas
O2-content in the
Range [mg/l] Treatment
carrier gas* [ppm]
10 - 150 450 Nitrogen 5.0 and Permeation Unit
100 - 2,000 6,000 Nitrogen 5.0 and Permeation Unit
500 - 8,000 24,000 Nitrogen 5.0 and Permeation Unit
1,000 - 15,000 45,000 Nitrogen 5.0 and Permeation Unit
5,000 - 30,000 90,000 Nitrogen 5.0 and Permeation Unit
20,000 - 250,000 21 Vol.-% Ambient Air Preparation Unit

* Theoretical Value; The calculation is based on an injection volume of 100 µl, 3 was expected as factor (X) and
the upper measurement range point was selected as CODexpected (see Chapter 2.6 on page 7).

• The measurement ranges up to 30,000 mg/l require the use of nitrogen 5.0 as

i carrier gas. The oxygen, which is required for the oxidation, is fed to the carrier gas
(nitrogen 5.0) by means of a Permeation Unit under defined conditions.
Notice • For the upper measurement range (20,000 - 250,000 mg/l), conditioned ambient
air can be used. In this case, instead of a Permeation Unit, an Ambient Air
Preparation Unit is connected.

8 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.1 Scope of Delivery

3 Product

The following section introduces the design of the analyser and its components.

3.1 Scope of Delivery

The “QuickCOD®ultra” analyser, associated individual parts and any operating material required are de-
livered in sturdy wooden packaging.

The content of this packaging includes:

• Analyser „QuickCOD®ultra“
• Instruction Manual „QuickCOD®ultra“
• Reactor Foot
• Injection Port
• Furnace Head
• Reactor
• Tube Cassettes
• Vessels
• Operating Material
• Data Stick
• Spare Part Box
• optional Accessories (Chapter 9 from page 173)

3.2 Nameplate

On the side of the housing is a nameplate with name of the analyser, serial number, year built, mains
voltage, power consumption and contact address of LAR.

Fig. 4: Nameplate (Example)

07E4317 Instruction Manual QuickCOD®ultra 9

 3 Product
3.3 Construction of the Analyser LAR | PROCESS ANALYSERS AG

3.3 Construction of the Analyser

The layout of the analyser from several sides is shown below.

3.3.1 Front View of the Analyser

1 3 User
Interface
4

5
15

6
16

10 11 12 17
13
9 Compart-
ment
7

8
14
Legend:
1) Touchscreen 10) TIC Reactor (CODi Method)
2) Temperature Regulator (Actual / Target) 11) Calibration Vessel
3) USB 2.0 Port 12) Rinse Vessel
4) Pressure Display of Carrier Gas Prepressure 13) Sample Vessels
5) Precision Flow Regulator 14) Magnetic Stirrer
6) Glass Spray Unit 15) Precision Pressure Regulator
7) Injection Port 16) Acid Trap
8) Furnace Head 17) Quartz Wool Filter
9) Injection Needle with XY-System
Fig. 5: Front View of the QuickCOD®ultra
(Example: CODi Method via TOC-Difference Method, 2 Sample Streams)

• Those without authorisation are not permitted to open the front door of the
! housing. A system key is included for those with authorisation to open the
analyser.
Caution • The area around the injection port and furnace head (No. 7 and 8 in Fig. 5,
page 10) can be very hot! Please do not touch without heat-resistant gloves!
• Moving parts! To avert injuries, please keep hands and loose objects out of the
range of the XY system with injection needle during operation.

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 3 Product
LAR | PROCESS ANALYSERS AG 3.3 Construction of the Analyser

• The positioning of the vessels can differ depending on the number of sample

i streams and the measurement method.

• Furthermore, depending on the measurement method and number of samples,
Notice there can be pump housings on the right-hand side of the analyser which are used
to transfer samples into the analyser.

3.3.2 Bottom View of the Analyser

Drain feedthroughs for

samples, condensate,
acid and rinsing water

Ventilation Pump

Pump
housing
Front housing part

Rear housing part

Rinsing water inlet, acid
inlet, carrier gas inlet

Power supply

Power supply for Carrier gas inlet

Ambient Air Pre-
paration Unit

Fig. 6: Bottom View of the Analyser (Example: CODo Method - 2 Sample Streams)

3.3.3 Top View of the Analyser

Rear housing part

Front housing part

Pump
housing

Pump

Fig. 7: Top View of the Analyser (Example: CODo Method - 2 Sample Streams)

07E4317 Instruction Manual QuickCOD®ultra 11

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3.3 Construction of the Analyser LAR | PROCESS ANALYSERS AG

3.3.4 Right Side View of the Analyser

Front housing part

Rear housing part

Carrier gas outlet

Tube feedthroughs for

samples
Pump

Pump
housing

Fig. 8: Right Side View of the Analyser (Example: CODo Method - 2 Sample Streams)

3.3.5 Left Side View of the Analyser

Inlet for RS232 serial interface

Inlet for relays

Inlet for digital inputs Inlet for analog outputs

Rear housing part

Front housing part

Main switch
Ventilation

Fig. 9: Left Side View of the Analyser (Example: CODo Method - 2 Sample Streams)

12 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

3.4 Components of the Analyser

To provide you with an overview of the components fitted, this section explains the most important com-
ponents, and their positions and functions in the analyser.

3.4.1 Pump System

Depending on the number of sample streams and the selected measurement method, the number of
pumps, pump type, and position of the pump may vary within the analyser (installed inside or outside).

The following table shows the possible variants of the pump system in the analyser:

Table 2: Variants of the Pump System

Amount of CODo, TOC-Difference & TOC-Direct

Pump type & TConly Method Method
Sample
transported medium
Streams Inside Outside Outside
Sample &
Tube Cassette Pump 1
1 Acid
Sample Pump Sample 1
Sample &
Tube Cassette Pump 2
2 Acid
Sample Pump Sample 2
Sample &
Tube Cassette Pump 3
3 Acid
Sample Pump Sample 3
Sample &
Tube Cassette Pump 4
4 Acid
Sample Pump Sample 4
Sample &
Tube Cassette Pump 5
5 Acid
Sample Pump Sample 5
Sample &
Tube Cassette Pump 6
6 Acid
Sample Pump Sample 6

• A tube cassette pump is installed inside the analyser, which is equipped with five

i tube cassettes on the factory side. This tube cassette pump is used to drain the
condensate and, when using the TOC-Difference Method, to transport the required
Notice acid into and out of the TIC Reactor.

07E4317 Instruction Manual QuickCOD®ultra 13

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

3.4.1.1 Tube Cassette Pump

The tube cassette pump (Fig. 10, page 14) has different applications within the analyser. These are de-
rived from the measurement method selected.

Fig. 10: Tube Cassette Pump with five Tube Cassettes (Example)

• Do not reach into the pump whilst it is running!

! • Note the installation direction of the tube cassettes!
Caution

3.4.1.2 Tubes (for Tube Cassette Pump)

The tubes for the tube cassette pumps have three colour-coded-stoppers (Fig. 11, page 14). The three
stoppers enable uniform spanning of the tube at all times - which has a positive effect on reproducibility
of the flow rate. The colour coding enables reliable identification of the tube dimension. The flow rates
of the individual tubes depend on their internal diameters.

Tube Cassette

Color-Coded-Stoppers

Tube

Fig. 11: Tubes for Tube Cassette Pump

14 Instruction Manual QuickCOD®ultra 07E4317

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LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

3.4.1.3 Sample Pump

The sample pump (Fig. 12, page 15) is used to transport the sample(s) for the TOC-Difference and
TConly Methods. The number of sample pumps varies depending on the number of sample streams.

Fig. 12: Sample Pump (closed)

! • Do not reach into the pump whilst it is running!

Caution

07E4317 Instruction Manual QuickCOD®ultra 15

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

3.4.2 Glass Components

The following glass components are inside the analyser, which can vary depending on the number of
sample streams and the measurement method:

• Calibration Vessel
• Rinse Vessel
• Sample Vessel(s)

i
• For optimal operation, LAR recommends a maximum of four sample streams. This
ensures that calibration of the analyser and rinsing of the injection needle can be
automatic without any additional overhead.
Notice

Calibration Vessel

Rinse Vessel
V1 Sample Vessel
V2
V3 V4
V5
V6

Magnetic Stirrer

Fig. 13: Glass Components (Example - CODo Method with 4 Sample Streams)

• For an analyser with five sample streams, there is only one position left for
! calibration vessel or rinsing vessel. This position may have to be swapped with the
calibration or rinse vessel depending on requirement. Only one place is available
Caution for one of the vessels.
• For an analyser with six sample streams, six sample vessels take up all the space
for vessels (V1-V6). For a calibration, the first vessel must be removed from the
position and be replaced by a calibration vessel. Before a calibration can be
performed, the positioning must be checked on the „Test Run“ display
(Chapter 7.2.13 from page 94). To rinse the injection needle, a sample vessel must
be defined, at best in one in which no repeat measurements take place and
preferably low concentrations are present.

16 Instruction Manual QuickCOD®ultra 07E4317

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LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

3.4.3 Furnace System

The catalyst-free ceramic furnace is the heart of the analyser. In it, all carbon compounds are reliably
oxidised at 1,200°C, enabling a complete analysis of the sample. Absolute safety is guaranteed in every
environment despite the high temperatures.

Injection Port

Furnace Head

Reactor Pipe (ceramic)

Ceramic Furnace

Thermocouple

Reactor Foot

Fig. 14: Furnace System

! • Use heat-resistant gloves when working with the furnace system!

Caution

07E4317 Instruction Manual QuickCOD®ultra 17

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

3.4.4 Connections

The analyser has different port and connectors, which are shown below.

3.4.4.1 Installation Plate

! • A mains cable is not included in the delivery. This must be provided by the user.

Caution

Fig. 15, page 18 shows the installation plate positioned in the rear housing part of the analyser:

TRC-Board (RS232 Connection Termi-

Serial Interface, Re- nals for Analog Out-
lays, Digital Inputs) puts (X101)

Switching Power
Supply (24 V / 13 A)
Analog Output Node

Relays for Sample

Pumps
Digital Node for
Sample Stream 1
and 2
Switching Power Supply
(12 V)
Through Terminals
Switching Power Supply
(5 V)

Mains Connections Digital Node for Multi-

Stream-Analyser

Motor circuit breaker Analog Output Node

(for analysers with
EX-Zone housing)

Main Fuse (8 A)

Furnace Contactor
Water Detector
(for analysers with
EX-Zone housing)

Connection Terminal for

Permeation Unit / Ambient
Air Preparation Unit (24 V/ Switching Power Sup-
DC) ply of the furnace

Fig. 15: Installation Plate with maximum Placement

18 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

3.4.4.2 Mains Connection

Legend:
PE (green): Protective erath
N (blue): Neutral
L (gray): Conductor

Fig. 16: Mains Connection

• Before the analyser is switched on, a check must be run on whether the local
! voltage supply matches that on the nameplate (Fig. 4, page 9).
• If this power supply is not available, please contact your local partner or the
Caution Technical Support of LAR (Chapter 15 on page 257).
• Do not switch the analyser on before using it for the first time without the presence
of a technician authorised by LAR - because otherwise this voids the warranty of
your analyser.

07E4317 Instruction Manual QuickCOD®ultra 19

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

3.4.5 Electronic Connections (digital and analog connections)

• Ensure that the analyser is disconnected from the power before cabling the
! system.
Caution

3.4.5.1 Connections on the TRC-Board

The analyser is fitted with a TRC board which is used to connect to external devices and/or process con-
trol systems. It is in the top left-hand side of the installation plate in the rear part of the housing (Fig. 15,
page 18). The rear part of the housing needs to be opened to access it.

Fig. 17: TRC-Board (complete)

The following connections are offered by the TRC board:

• 1x RS232 Serial Interface

• 8x Digital Inputs
• 8x Relays

i • A cable cross-section of 1.5 mm2 = cable diameter of 1.4 mm can be used to

connect the signal lines to the TRC board,
Notice

20 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

Fig. 18: TRC-Board (RS 232 Serial Interface, Digital Inputs, Relays)

07E4317 Instruction Manual QuickCOD®ultra 21

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

3.4.5.2 RS232 Serial Interface

The RS232 serial interface can be used to send current data to a remote computer unit, connected to
the analyser with a RS232 cable. The pin assignment of the interface is shown in Fig. 18, page 21. Set
the serial interface parameters on your computer unit as follows:

Table 3: Serial Interface Parameters

Baud Rate 9600Bd
Parity no
Data Bits 8
Stop Bits 1
Protocol Xon / Xoff

Example:

When you send letter „D“, the analyser responds by sending the current data in the following format:

Date;Time;ReadingDisplay1;ReadingDisplay2;...Last ReadingDisplay;Respective status

Formats:
• Date;Time: dd.mm.yyyy-hh:mm:ss
• ReadingDisplay: @@@@@@.@@ (six places before and two after the decimal point; places
not used are filled with zeroes)

• Status (examples): "Errors = (E1835_E1836)" ; "Limits = (L1_max LV1_max)" ; "Status = (M1)"

(the underline stands for space)

Different activities are listed in the status string. The maximum length of the string sent is 4095 chars.

3.4.5.3 Digital Inputs

The analyser can be monitored and controlled via the digital inputs. This option enables for example only
one measurement to be started when there is a sample. The input signals (0 - 24 V DC) necessary must
be provided by the user:

Table 4: Digital Inputs DC voltage applied

Digital Input 1, 2, 4, 5, 6, 7 (Measurement of Sample)
0-3V Analyser waits
12 - 24 V Measurement

Digital Input 3 (General Stop of the Analyser)

0-3V No Changes
12 - 24 V Measurement is stopped

i • The digital inputs are assigned to the corresponding sample streams. For an
overview, see Fig. 18, page 21.
Notice

22 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

3.4.5.4 Relays
The analyser has eight isolated relays (switch contacts). They are capable of activating external circuits
up to 24V AC/DC with 1A, and can be assigned in the system software by the user. The relays can be
programmed as NCC (normally closed) or NOC (normally open). (The settings are in the software, NOC
is the default.) (Chapter 7.2.5 from page 81).

3.4.5.5 Analog Outputs

The maximum apparent ohmic resistance for the isolated 0/4-20mA current loops is 500 Ohm. The type
of analog output (0-20 mA or 4-20 mA current loop) can be set in the software. If it is set to 4-20 mA, a
“Live-Zero” feature can be set in the system software. This means instrument faults are output with 0
mA. The conditions for the fault display can be programmed individually in the system software. On the
installation plate of the analyser (Fig. 15, page 18) is terminal strip X101 for the analog outputs (Fig. 19,
page 23).
The individual terminals of X101 are labelled. The first digit stands for the sample stream and the second
for the outgoing parameter.

• No current or voltage must be applied to the analog outputs. LAR analysers only
! output different currents in mA.
Caution

Fig. 19: Analog Output

• Please note that the following terminal diagram (from Fig. 20, page 24 to Fig. 22,

i page 26) is shown as an example of the maximum configuration (six sample

streams), and the analyser ordered corresponds to your configuration.
Notice • The relays and analog outputs can be programmed individually by your local
partner or the Technical Support of LAR (Chapter 15 on page 257) as part of the
start-up.

07E4317 Instruction Manual QuickCOD®ultra 23

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3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

Established Analog Outputs

Optional

Sample Stream
1

Fig. 20: Terminal Diagram (Part I) - Power Supply, established Analog Outputs, programmable Analog
Outputs

24 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.4 Components of the Analyser

Sample Stream
1
-
Measurement
2
-
Only for option
„Automatic
Ranging“

Sample Stream
2

Sample Stream
3

Fig. 21: Terminal Diagram (Part II) - programmable Analog Outputs

07E4317 Instruction Manual QuickCOD®ultra 25

 3 Product
3.4 Components of the Analyser LAR | PROCESS ANALYSERS AG

Sample Stream
4

Sample Stream
5

Sample Stream
6

Fig. 22: Terminal Diagram (Part III) - programmable Analog Outputs

26 Instruction Manual QuickCOD®ultra 07E4317

 3 Product
LAR | PROCESS ANALYSERS AG 3.5 Carrier Gas

3.5 Carrier Gas

The required carrier gas supply depends on the measurement range set.

The measuring ranges up to 30,000 mg/I presuppose the use of nitrogen 5.0 as carrier gas. The oxy-
gen required for the oxidation is fed to the carrier gas (nitrogen 5.0) by means of a Permeation Unit under
defined conditions.

Conditioned ambient air can be used for the upper measuring range (20,000 - 250,000 mg/l). In this
case, an Ambient Air Preparation Unit is connected instead of a Permeation Unit.

The nitrogen must have a pre-pressure between 2 and 5 bar and should have a purity of at least
99.999 vol.-%; This corresponds to nitrogen of quality 5.0. 20 l/h of the carrier gas is required for the de-
fault setting, where deviations can arise depending on the application.
If no nitrogen 5.0 is available locally e.g. in the form of cylinder gas, a nitrogen generator can be ordered
as an option. The use of a generator is also recommended for operational reasons, since the com-
pressed gas cylinders have to be changed regularly, whereby the exchange frequency depends on the
carrier gas flow. Each cylinder change is connected to maintenance expenses and a short-term interrup-
tion of the measuring operation. In the interest of continuous measurement operation, nitrogen 5.0
should be available continuously.
The oxygen required for the sample oxidation is fed to the carrier gas via a Permeation Unit. A constant
oxygen concentration is adjusted to the measuring range by a diffusion under defined conditions. Special
attention should be paid to the tightness of the gas lines and connections in order to avoid uncontrolled
influx of oxygen from ambient air. At critical points (connection of gas cylinders, inlet and outlet connec-
tions of the Permeation Unit as well as any connectors used) leakages should be ruled out with the aid
of a soap solution or a leak detector spray.

• If you are not in a position to make available a carrier gas with the specifications

i necessary, you can optionally order the Ambient Air Preparation Unit and/or the
Permeation Unit of LAR.
Notice • More detailed information on the “Permeation Unit” option is available in
Chapter 9.3 from page 177.
• More detailed information on the “Ambient Air Preparation Unit” option is available
in Chapter 9.4 from page 182.
• If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).

07E4317 Instruction Manual QuickCOD®ultra 27

 3 Product
3.5 Carrier Gas LAR | PROCESS ANALYSERS AG

28 Instruction Manual QuickCOD®ultra 07E4317

 4 Installation
LAR | PROCESS ANALYSERS AG 4.1 Installation Procedure

4 Installation

Instructions for installing the analyser are in the following section. The following installation process
serves as an overview, and should be carried out and logged properly by you.

4.1 Installation Procedure

The installation process is divided into installation of the analyser and installation of the analyser acces-
sories.

4.1.1 Installation of the Analyser

• Ensure Environmental Conditions (Chapter 4.2 on page 31)

• Mounting and Installation of the Analyser on Site (Chapter 4.3 from page 32)
• Provide Carrier Gas (Chapter 4.4 on page 36)
• Provide Sample Inlet and Drain (Chapter 4.5 on page 36)
• Provide Power Supply (Chapter 4.6 on page 36)
• Install Signal Connections (Chapter 4.7 on page 37)
• Provide Rinsing Water (Chapter 4.8 on page 37)
• Provide Acid Solution (Chapter 4.9 on page 37)
• Provide Calibration Standard (Chapter 4.10 on page 38)

4.1.2 Installation of optional Accessories

• Installation of Reagent Cabinet (Chapter 9.2.2 on page 175)

• Installation of Permeation Unit (Chapter 9.3.2 on page 178)
• Installation of Ambient Air Preparation Unit (Chapter 9.4.2 on page 184)
• Installation of FlowSampler® (Chapter 9.5.4 on page 199)
• Installation of CO2-Remover (Chapter 9.6.3 on page 204)

• Careful documentation is a precondition for any guarantee and warranty claims.

i • If you have any questionto the installations, please contact your local partner or
the Technical Support of LAR (Chapter 15 on page 257).
Notice

07E4317 Instruction Manual QuickCOD®ultra 29

 4 Installation
4.1 Installation Procedure LAR | PROCESS ANALYSERS AG

Table 5: Installation Log for the Analyser

Task Criteria OK Comment

• Dry and frost-proof
• Temperature: 5°C - 35°C
Ensure Environment • Rel. humidity: < 80%
Conditions • No direct exposure to sunlight

• No aggressive environment
• No aggressive sample contents
• Wall mounting:
Free space (W x H x D) 
Mounting and Installa- approx. 1,030 x 1,720 x 1,210 mm
tion of the Analyser on
Site • Mounting rack:
Free space (W x H x D) 
approx. 1,070 x 2,000 x 1,420 mm
• Free of CO2, Carbon, Dust,
Water und Oil
Provide Carrrier Gas 
• Pre pressure 2 - 3 bar
• Available in the direct vicinity
• Depressurised
Provide Sample Inlet
• Available in the direct vicinity

• Depressurised
Provide Drain
• Available in the direct vicinity

• Mains voltage correct
Provide Power Supply • Power cable on power supply 
connected
• Serial interface connected
Install Signal • Digital Inputs connected
Connections • Analog Outputs connected

• Relays connected

Provide Rinsing Water • Rinsing water provided 

Provide Acid Solution • Acid solution provided 

Provide Calibration
Standards
• Calibration Standard provided 

Date: Signature:

Table 6: Installation Log for optional Accessories

Task Criteria OK Comment

• Mounted on the wall, mounting
Installation of Reagent
Cabinet
rack or placed under the 
analyser
Installation of the • Mounted on the wall, mounting
Ambient Air Prepara- rack or placed under the 
tion Unit analyser

Date: Signature:

30 Instruction Manual QuickCOD®ultra 07E4317

 4 Installation
LAR | PROCESS ANALYSERS AG 4.2 Site Selection - Ambient Conditions

Table 6: Installation Log for optional Accessories

Task Criteria OK Comment

Installation of the
Permeation Unit
• Placed under the analyser 
Installation of the • FlowSampler® mounted on the

FlowSampler® wall to the right of the analyser
Installation of the • Mounted on the wall or placed
CO2-Remover under the analyser


Date: Signature:

4.2 Site Selection - Ambient Conditions

The following ambient conditions apply for choosing the analyser location:

• Dry and frost-proof

• Reliable temperature range (5°C – 35°C)
• Max. relative humidity 80%
• No direct exposure to sunlight
• No aggressive environment for housing type IP54
• Mains voltage 115/230 V at 50/60 Hz, 16 A fusing (K-characteristics)

• The mains voltage must match that specified on the nameplate of your analyser.
! The nameplate is on the right-hand side of the analyser (Fig. 4, page 9).
Caution

• Certified, custom enclosures for corrosive environments (in accordance with NEMA

i 4X) and potentially explosive areas (in accordance with ATEX Zones 1 and 2, and
IECEx) are available from LAR.
Notice • If you have any question to site selection and applied ambient conditions, please
contact your local partner or the Technical Support of LAR (Chapter 15 on
page 257).

07E4317 Instruction Manual QuickCOD®ultra 31

 4 Installation
4.3 Mounting and Installation of the Analyser on Site LAR | PROCESS ANALYSERS AG

4.3 Mounting and Installation of the Analyser on Site

The analyser is normally affixed to a wall (Chapter 4.3.2 from page 34) or onto the LAR mounting rack
(Chapter 9.7 from page 208).

Bottom

Fig. 23: QuickCOD®ultra with Permeation Unit and FlowSampler®

(Example: CODo Method, 2 Sample Streams)

i • The mounting of the analyser and options has to be done by the user prior to the
start-up of the analyser.
Notice

32 Instruction Manual QuickCOD®ultra 07E4317

 4 Installation
LAR | PROCESS ANALYSERS AG 4.3 Mounting and Installation of the Analyser on Site

4.3.1 Maximum Swing Open of the Housing

Rear Housing Part

Housing Door

Front Housing Part

Fig. 24: Maximum Swing Open of the QuickCOD®ultra

• For all installation variants, the distance to side and opposing walls must be kept so
! that the analyser can be swivelled open.
Caution

07E4317 Instruction Manual QuickCOD®ultra 33

 4 Installation
4.3 Mounting and Installation of the Analyser on Site LAR | PROCESS ANALYSERS AG

4.3.2 Wall Mounting

The following installation dimensions must be observed:

• min. 1,030 x 1,720 x 1,210 mm (W x H x D)

M1 M2

M3 M4

Legend:
M1 - M4: Brackets of the Analyser
Fig. 25: Wall Mounting of QuickCOD®ultra with Permeation Unit and FlowSampler®
(Example: CODo Method, 2 Sample Streams)

• The distance to side and opposing walls must be kept so that the analyser can be
! swivelled open.
• Take into account the condition of the wall to which the analyser is to be affixed.
Caution The wall should have the solidity of a concrete wall. Gas concrete walls are
unsuitable however!
• Use all of the brackets (M1 - M4) of the analyser for installation.
• Ensure that the analyser is aligned horizontally. Use a spirit level here for example.

34 Instruction Manual QuickCOD®ultra 07E4317

 4 Installation
LAR | PROCESS ANALYSERS AG 4.3 Mounting and Installation of the Analyser on Site

Recommendation for wall installation:

Perform the wall installation as follows with four stud bolts (see Fig. 25, page 34):

• First drill the top left hole (M1) for the stud bolts (diameter 10 mm, depth approx. 100 mm). The hole
should be at least 400 mm from the right-hand wall and 1680 mm from the floor.
• Drill hole (M2) 630 mm horizontally to the right of the first one.
• Drill lower holes M3 and M4, each 920 mm vertically below holes M1 and M2.
• Now insert the stud bolts into all the holes and tighten them until the gap between the hexagon head
of the bolt and the wall is 10 mm.
• Hook the analyser into the fitted stud bolts from above.
• Secure the analyser to the wall by tightening the stud bolts into all of the attachment eyes.

• If the condition of the wall does not meet the requirements, LAR recommends to

i mount the analyser on the LAR mounting rack.

• For information on mounting the analyser on the mounting rack, please refer to
Notice Chapter 9.7 from page 208.

07E4317 Instruction Manual QuickCOD®ultra 35

 4 Installation
4.4 Provide Carrier Gas LAR | PROCESS ANALYSERS AG

4.4 Provide Carrier Gas

For the operation of the analyser, a carrier gas is required with the following specifications. For more
information see Chapter 3.5 on page 27.

With the supply of the carrier gas please ensure that it is:

• free of CO2, Carbon, Dust, Water und Oil

• provided with a pre pressure of 2 - 3 bar
• provided in the direct vicinity of the analyser

• If you are not in a position to make available a carrier gas with the specifications

i necessary, you can optionally order the Ambient Air Preparation Unit and/or the
Permeation Unit of LAR.
Notice • More detailed information on the “Permeation Unit” option is available in
Chapter 9.3 from page 177.
• More detailed information on the “Ambient Air Preparation Unit” option is available
in Chapter 9.4 from page 182.
• If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).

4.5 Provide Sample Inlet and Drain

Please ensure that sample inlet and drain are:

• depressurised
• available in the direct vicinity of the analyser

• If you are not in a position to make available a depressurised sample inlet and

i drain, you can order optional accessories like e.g. the FlowSampler® of LAR.

• More detailed information on the FlowSampler® is available in Chapter 9.5 from

Notice
page 196.
• If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).

4.6 Provide Power Supply

A 115/230 V, 50/60 Hz mains voltage is required to use the analyser. The mains voltage for your analyser
is specified on the nameplate (Fig. 4, page 9) (on the right-hand side). You must provide a mains lead
and connect it to the mains connector (Fig. 16, page 19) on the installation plate (Fig. 15, page 18) of the
analyser.

• It is possible to use other mains voltages.

i • If you have any question, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

36 Instruction Manual QuickCOD®ultra 07E4317

 4 Installation
LAR | PROCESS ANALYSERS AG 4.7 Install Signal Connections

4.7 Install Signal Connections

As described in Chapter 3.4.5 from page 20, the analyser has different digital connections which you
may use if required. The signal lines can be connected up by you on the installation plate in the rear part
of the housing, and be programmed by your local partner or the Technical Support of LAR as part of
initial start-up.

Signal lines to be connected:

• RS232 serial interface to a computer unit via an RS232 cable (Chapter 3.4.5.2 on page 22)
• Digital Inputs (Chapter 3.4.5.3 on page 22)
• Relays (Chapter 3.4.5.4 on page 23)
• Analog Outputs (Chapter 3.4.5.5 on page 23)

• If you have any question, please contact your local partner or the Technical
! Support of LAR (Chapter 15 on page 257) before cabling the system.
• Ensure that the analyser is disconnected from the power before cabling the
Caution system.
• Do not switch the analyser on before using it for the first time without the presence
of a technician authorised by LAR - because otherwise this voids the warranty of
your analyser.

4.8 Provide Rinsing Water

Rinsing Water (provided by the operator) which is used for rinsing the injection needle is required for
Start-Up. Read Chapter 6.1.2 on page 56.

4.9 Provide Acid Solution (TOC-Direct and TOC-Difference Method)

To use an analyser with the TOC-Direct or TOC-Difference Method, an acid solution used for stripping
out inorganic carbon compounds (TIC) must be provided. Please read Chapter 6.1.3 on page 56 for the
TOC-Difference Method or the Chapter 6.1.4 on page 57 for the TOC-Direct Method.

• For the start-up, please use an acid solution which is not older than five days.
! • It is best to keep canisters in the Reagent Cabinet (accessory) or Ambient Air
Preparation Unit (accessory) (Chapter 9 from page 173).
Caution

07E4317 Instruction Manual QuickCOD®ultra 37

 4 Installation
4.10 Provide Calibration Standards LAR | PROCESS ANALYSERS AG

4.10 Provide Calibration Standards

A calibration standard must be provided by the operator to calibrate the analyser. Please read
Chapter 6.2 from page 58.

• The calibration standard must be stored in a cool place (such as in a fridge).

! • For the start-up, please use a calibration standard which is not older than five days.
Caution

• Suitably certified calibration standards can be sourced directly from LAR to

i minimise overhead.
• For more information please contact the Sales Department of LAR (Chapter 15 on
Notice page 257).

38 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.1 Start-Up Procedure

5 Start-Up

Instructions for starting up the analyser are in the following section. The following start-up procedure,
which must be carried out properly and documented by Technical Support of LAR or by somebody
authorised by LAR, serves as an overview.

• Do not switch on the analyser before start-up without completion the installations,
! which are described in the previous chapter, and without the presence of a
technician authorised by LAR - because this voids the warranty of your analyser.
Caution

5.1 Start-Up Procedure

The start-up procedure is divided into start-up of the analyser and start-up of accessories.

5.1.1 Start-Up of the Analyser

• Checking the Pre-Fusing (Chapter 5.2 on page 41)

• Checking the Installation Plate (Chapter 5.3 on page 41)
• Remove Transportation Locks (Chapter 5.4 from page 41)
• Align the Voltage (Chapter 5.5 on page 44)
• Switch on the Fuses (Chapter 5.6 on page 44)
• Filling and Installation of the Reactor Pipe (Chapter 5.7 from page 45)
• First switch on of the Analyser (Chapter 5.8 on page 46)
• Completing the Furnace System (Chapter 5.9 on page 47)
• Installation of the Glass Components (Chapter 5.10 on page 48)
• Installation of the Pump Tubes (Chapter 5.11 from page 49)
• Tubing of the Analyser (Chapter 5.12 on page 51)
• Test Run (Chapter 5.13 on page 52)
• Rinse the Injection System and Sample Tubes (Chapter 5.14 on page 52)
• Customization of application specific Settings (Chapter 5.15 on page 52)
• Checking the Status Parameters (Chapter 5.16 on page 52)
• Perfom a Calibration (Chapter 5.17 on page 53)
• Start the Measuring Mode (Chapter 5.18 on page 53)
• If necessary, perform a second Calibration (Chapter 5.17 on page 53)

5.1.2 Start-Up of optional Accessories

• Start-Up of the Reagent Cabinet (Chapter 9.2.3 on page 176)

• Start-Up of the Permeation Unit (Chapter 9.3.3 on page 179)
• Start-Up of the Ambient Air Preparation Unit (Chapter 9.4.3 from page 185)
• Start-Up of the FlowSampler® (Chapter 9.5.5 from page 199)
• Start-Up of the CO2-Remover (Chapter 9.6.4 on page 205)

07E4317 Instruction Manual QuickCOD®ultra 39

 5 Start-Up
5.1 Start-Up Procedure LAR | PROCESS ANALYSERS AG

Table 7: Start-Up Log for the Analyser

Task Criterias OK Comment

Checking the Pre-Fuses • Pre-Fuse is installed correctly 
Checking the Installation
Plate
• Components are fixed 
• Furnace Transport Screw is
Remove Transportation removed
Locks • Cable tie at XY-System is

removed
Align the Voltage • Voltage is correct 
• Fuse Lock is removed
Switch on the Fuses
• All Fuses are switched on

Filling and Installation of the • Reactor Pipe is filled
Reactor Pipe • Reactor Pipe is installed

First switch on of the
Analyser
• Analyser is booted 
• Furnace Head is installed
Completing the Furnace
System
• Injection Port is installed 
• Reactor Foot is installed
Installation of Glass
Components
• Glass Components are mounted 
Installation of the Pump
Tubes
• Tubes are inlaid in Pumps 
• Tubing is performed like in Flow
Diagram
Tubing of the Analyser
• Tubes are hand-screwed onto

the screwed joints
Test Run • All Positions are hit 
Rinse the Injection System • Injection System and Sample
and Sample Tubes Tubes are rinsed

Customization of application • Hardware and Parameter
specific Settings Settings are set

• Carrier Gas IN / OUT: approx.
20 l/h
Checking the Status
Parameters
• Humidity: Actual < Target 
• Gas Pressure: Actual < Target
• Zero Signal: 0 - 0.1 FSR
Perfom a Calibration • Analyser is calibrated 
Start the Measuring Mode • Measuring Mode works just fine 
If necessary, perfom a
second Calibration
• Analyser is calibrated 

Date: Signature:

• Careful documentation is a precondition for any guarantee and warranty claims.

i • If you have any question, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

40 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.2 Checking the Pre-Fusing

Table 8: Start-Up Log for Accessories

Task Criteria OK Comment

Start-Up of the
Reagent Cabinet
• Connection to Analyser is made 
• Connection to Nitrogen is made
Start-Up of the
• Connection to Analyser is made
Permeation Unit
• Electrical connection is made
Start-Up of the
• Connection to Analyser is made
Ambient Air
• Electrical connection is made

Preparation Unit
Start-Up of the • FlowSampler® is connected with

FlowSampler® Analyser
• Connections to instrument air (in
Start-Up of the accordance to DIN ISO 8573-1)
CO2-Remover and analyser is made

• Status is in order

Date: Signature:

i • Measurement mode of the analyser must be checked to ensure perfect operation

of the analyser. This may mean start-up can take up to two days.
Notice

5.2 Checking the Pre-Fusing

Before start-up can begin, it is important to ensure that correct pre-fusing has been installed at the op-
erator.

5.3 Checking the Installation Plate

Before start-up can be performed, it is important to ensure that no components have become loose or
suffered damage during transit. The housing and the components on the installation plate in the rear part
of the housing (Fig. 15, page 18) must also be checked.

5.4 Remove Transportation Locks

A few transport locks are affixed to safeguard the analyser and its components during transit. They must
be removed before the analyser is used.

• Transport locks can also be affixed to accessories and options.

i • Information to remove transportation locks of accessories and options can be found
in Chapter 9 from page 173.
Notice

07E4317 Instruction Manual QuickCOD®ultra 41

 5 Start-Up
5.4 Remove Transportation Locks LAR | PROCESS ANALYSERS AG

5.4.1 Furnace Transport Screw

For transportation, the furnace is secured with a bolt and a spacer sleeve, which must be removed for
operation.

Proceed as follows:

• Take a screwdriver.
• Open the furnace door in the analyser.
• Use the screwdriver to remove the transport bolt for the furnace.
• Remove the spacer sleeve.
• Close the furnace door of the analyser.

Fig. 26: Removing the Furnace Transport Screw

42 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.4 Remove Transportation Locks

5.4.2 Cable Tie at XY-System

The XY system is secured with a cable tie for transportation, which must be removed for operation of the
analyser.

Proceed as follows:

• Take side-cutting pliers.

• Use the pliers to carefully remove the cable tie on the XY system.
• Check that the arm can move freely.

Fig. 27: Removing the Cable Tie at XY-System

! • Ensure not to damage any cables, tubes or the XY system with the pliers.

Caution

07E4317 Instruction Manual QuickCOD®ultra 43

 5 Start-Up
5.5 Align the Voltage LAR | PROCESS ANALYSERS AG

5.5 Align the Voltage

• Check the power supply.

• Compare the mains voltage with that specified on the analyser (Fig. 4, page 9).

5.6 Switch on the Fuses

To be able to switch the analyser on, the lock on the automatic circuit breaker must be removed
beforehand and the fuses must be switched on.

Proceed as follows:

• Open the rear part of the housing to access the installation plate (Fig. 15, page 18).
• Remove the cable tie with a side cutter from the lock.
• Remove the safety notice attached to the cable tie out of the analyser.
• Open the yellow lock by pulling it forwards.
• Use your finger and thumb to press in the metal clip, and remove the lock.
• Switch all fuses on.
• Close the rear part of the housing.

Fig. 28: Removing the Lock on the Circuit Breaker

44 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.7 Filling and Installation of the Reactor Pipe

5.7 Filling and Installation of the Reactor Pipe

• Before the analyser is switched on, the reactor pipe must be filled and installed into
! the furnace.
Caution

Some components of the furnace system are packed individually for safety during transit. These com-
ponents must be fitted in the furnace.

Remove the following components from the packaging:

• Reactor Pipe
• Protective Pipe
• Ceramic Sieve
• Ceramic Balls
• Green Protective Seal

Assembly of the ceramic reactor pipe in the furnace:

 

  
  

  
 
  

  
 

!  
! 

  

" #



  $

% & & '


( '  )
*+66
)
*;6+  <   &  =
>
>
(>   
 

Legend:
1) Reactor Pipe
2) Protective Pipe (Ceramic)
3) Ceramic Balls 1.6mm
4) Ceramic Balls 3.5 - 4.5mm
5) Ceramic Sieve

Fig. 29: Reactor Pipe Filling (Standard)

• Push the needle to the right.

• Note the sequence for filling the reactor pipe.
• Position the ceramic sieve (No. 5 in Fig. 29, page 45) horizontally on the taper of the reactor pipe /
allow it to drop into the reactor pipe.

07E4317 Instruction Manual QuickCOD®ultra 45

 5 Start-Up
5.8 First switch on of the Analyser LAR | PROCESS ANALYSERS AG

• Shake the reactor pipe to move the ceramic sieve into a horizontal position (you can use a torch to
check the position).
• Carefully insert the long protective pipe (No. 2 in Fig. 29, page 45) into the reactor pipe from above.

• Please use a funnel to fill the ceramic balls so that they do not fall between the
! reactor pipe and protective pipe. This can result in damage to the reactor pipe.
Caution

• Fill the ceramic balls with diameters 3.5 mm - 4.5 mm (No. 4 in Fig. 29, page 45) up to the height
specified (210 mm, measured from the top edge with a tape measure).
• Fill the ceramic balls with diameters 1.6 mm (No. 3 in Fig. 29, page 45) up to the height specified
(170 mm, measured from the top edge with a tape measure).
• Fill the ceramic balls with diameters 3.5 mm - 4.5 mm (No. 4 in Fig. 29, page 45) up to the height
specified (150 mm, measured from the top edge with a tape measure).
• Place the green protective seal for the reactor pipe onto the furnace.
• Push the filled reactor pipe through the green protective seal into the centre of the furnace from
above.

• We know from experience that the reactor pipe filling shown (Fig. 29, page 45)

i represents an excellent solution for the majority of applications.

• However, some applications can be optimised with a variation of the standard filling
Notice described. All departures from the standard filling should be discussed upfront with
Technical Support of LAR (Chapter 15 on page 257) or a service partner
authorised by LAR.
• Given that our research and development are advancing continually, we request
you to stay in touch with your contact at LAR to keep abreast of all additions.

5.8 First switch on of the Analyser

The analyser is switched on for the first time by Technical Support of LAR or by somebody authorised
by LAR.

Preconditions:

• Completion of installations (Chapter 4 from page 29)

• Removal of transport locks (Chapter 5.4 from page 41)
• Switch-on of internal fuses (Chapter 5.6 on page 44)
• Filling and installation of the reactor pipe (Chapter 5.7 from page 45)

• Do not switch on the analyser before initial use without completion in full of the
! installations described in the previous section, and without anybody authorised by
LAR, because otherwise the analyser warranty becomes void.
Caution • Fault message “E1820 - Furnace temperature not reached” is shown when the
system is switched on. This message disappears once the furnace has reached the
required temperature and does not need to be confirmed in the log book.

46 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.9 Completing the Furnace System

5.9 Completing the Furnace System

! • Use heat-resistant gloves when working with the furnace system!

Caution

• Place the furnace head onto the furnace and reactor pipe.
• Connect the black tube to the tube connector provided.
• Tighten in a crosswise sequence the attachment bolts of the furnace head with the furnace head
panel.
• Carefully tighten the injection port by hand until slight resistance is felt (the injection port should point
to the front left at an angle).
• Plug in the injection port connector.
• Attach the reactor foot seating to the reactor footplate using three M4x30 bolts.
• Connect the teflon tube (PFA) to the screwed insert.
• Screw the screwed insert into the reactor foot seating.

i • Before you fit the reactor foot, you should wait until the furnace has reached a
temperature of 800°C. This simplifies the installation of the reactor foot.
Notice

• Plug the reactor foot onto the reactor pipe from below.
• Screw on the four spacer bolts.
• Pull the reactor foot down so that the gas path is not blocked by the reactor pipe.
• Attach the bottom grid.
• Insert the filter mats (bottom of housing).
• Attach the ventilation grill (bottom of housing).

07E4317 Instruction Manual QuickCOD®ultra 47

 5 Start-Up
5.10 Installation of the Glass Components LAR | PROCESS ANALYSERS AG

5.10 Installation of the Glass Components

• Check the vessels for integrity.

• Check that the vessels are in the right order (V1 - V6).
• Check that all tube connections are correctly installed.

Calibration Vessel

Rinse Vessel
V1 Sample Vessel
V2
V3 V4
V5
V6

Magnetic Stirrer

Fig. 30: Glass Components (Example - CODo Method with 4 Sample Streams)

48 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.11 Installation of the Pump Tubes

5.11 Installation of the Pump Tubes

The following two chapters show how the pump tubes are installed into both types of pumps.

5.11.1 Installation of the Tubes in the Tube Cassette Pump

In order to pump the solutions, the tubes must be placed into the tube cassette pump correctly.

Proceed as follows:

• Use the overview to localise all tube cassette pumps (Tab. 2, page 13).
• Place the tube into the cassette between two of the coloured stoppers with the marking facing
upwards.
• Apply silicone oil to the tube inserted.
• Place the cassette onto the pulley head of the pump until a click is heard.
• Proceed in the same way with other cassettes on the tube cassette pump and other tube cassette
pumps.

Fig. 31: Tube loading (Example) Fig. 32: Cassette with Fixing Flap (Example)

Fig. 33: Mounting the Tube Cassette (Example) Fig. 34: Tube Cassettes on Pump (Example)

• Tubes with three stoppers can be used longer by relocating them (thereby doubling

i the useful life of a tube).

• To ensure a long lifetime of the tubings and to ensure a good performance, please
Notice only use original LAR pump tubes.

07E4317 Instruction Manual QuickCOD®ultra 49

 5 Start-Up
5.11 Installation of the Pump Tubes LAR | PROCESS ANALYSERS AG

5.11.2 Installation of the Tubes in the Sample Pump

In order to pump the samples, the tubes must be placed into the sample pump correctly.

Proceed as follows:

• Use the overview to localise all sample pumps (Tab. 2, page 13).
• Open the upper shutter of the sample pump (No. 1 - 2 in Fig. 35, page 50).
• Abut the tube firmly against the rollers.
• Ensure that the tube does not turn in on itself.
• Pull the tube down on both sides to ensure that the tube is in the guide on both sides (No. 3 in
Fig. 35, page 50).
• Close the upper shutter of the sample pump (No. 4 in Fig. 35, page 50).
• Proceed in the same way for other pump tubes and sample pumps.

1 2

3 4

Fig. 35: Installation of the Sample Tubes into the Sample Pump

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 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.12 Tubing of the Analyser

5.12 Tubing of the Analyser

Inside the analyser, samples, reagents and the carrier gas are transported from one component to the
next. Different tubes are used for this, which must be connected properly to the components.

i • When routing tubes, follow the flow diagram for your configuration (Chapter 12
from page 227).
Notice

When routing tubes, ensure:

• that they are in perfect condition (so no kinks for examples).

• that the tube routing diagram is observed depending on configuration.
• that the tubes are hand-screwed onto the screwed joints.
• that the drain is depressurised.

-MM
NO
-GS NC
I/O

-CM10

-CM1 -CM7 -CM8

M

-RM

-EB -BP2
-GP2
1200°
-BF1

FA
-HS1 -HQ1

-KH2
NC

I/O

-Y1 -BP1
-EC
O2
FA NO

-BM
Q

-GP1
-KH1
-B4 -BF2 -HQ3 -HQ2

Fig. 36: Flow Diagram (Example: CODo Method - 1 Sample Stream)

07E4317 Instruction Manual QuickCOD®ultra 51

 5 Start-Up
5.13 Test Run LAR | PROCESS ANALYSERS AG

5.13 Test Run

A test run must be performed to check whether the injection needle hits all positions correctly (furnace
and vessels). Follow the instructions in Chapter 7.2.13 from page 94 to perform a test run.

• If the injection needle does not pierce the vessels correctly, the X position must be

i corrected manually from the “Test run” display (Chapter 7.2.13 from page 94).
• If you have any question, please contact your local partner or the Technical
Notice Support of LAR (Chapter 15 on page 257).

5.14 Rinse the Injection System und Sample Tubes

Before the first measurement, the injection system and sample tubes must be rinsed.

Proceed as follows:

• Switch to the “Service Action” display (Chapter 7.2.11 from page 88).
• Rinse the injection system using the “Rinse injection system” function.
• Rinse the sample tubes using the “Rinse sample tubes” function.

5.15 Costumisation of application specific Settings

Application-specific hardware and parameter changes can be made.

Change the following settings:

• Measurement Parameters (Chapter 7.2.2 from page 70)

• Measurement Channels (Chapter 7.2.7 on page 84)
• Relays (Chapter 7.2.5 from page 81)
• Analog Outputs (Chapter 7.2.19 on page 106)

5.16 Checking the Status Parameters

The status parameters on the Status screen must be checked to ensure perfect operation of the analyser.
Use for the check the start-up log (Tab. 7, page 40), in which all relevant status parameters are recorded
with associated status information permitted. The status parameters are on the “Status screen” display
(Chapter 7.2.10 from page 87).

i • If a status parameter is different from the status specification, please contact your
local partner or the Technical Support of LAR (Chapter 15 on page 257).
Notice

52 Instruction Manual QuickCOD®ultra 07E4317

 5 Start-Up
LAR | PROCESS ANALYSERS AG 5.17 Perform a Calibration

5.17 Perform a Calibration

Before the measurements can be started, the analyser must undergo application-specific calibration. A
2-point or multi-point calibration can be used here (Chapter 7.2.3 from page 73).

i • Calibration standards made available by the user serve as preconditions for the
calibration (Chapter 6.2 from page 58).
Notice

5.18 Start the Measuring Mode

To conclude the start-up process, a few measurements are taken to ensure the analyser is working cor-
rectly.

• After pushing the online button the analyser will perform an initial measurement.

i After this initial measurement the analyser will start the regular measurements.
• If you have any question to the start-up, please contact your local partner or the
Notice Technical Support of LAR (Chapter 15 on page 257).

07E4317 Instruction Manual QuickCOD®ultra 53

 5 Start-Up
5.18 Start the Measuring Mode LAR | PROCESS ANALYSERS AG

54 Instruction Manual QuickCOD®ultra 07E4317

 6 Reagents and Calibration Standards
LAR | PROCESS ANALYSERS AG 6.1 Reagents

6 Reagents and Calibration Standards

Deionised water, rinsing water, calibration standards (and possibly acid solutions) are required for the
analyser measurement mode. This section shows how you can prepare the calibration standards and
solutions yourself.

• Please follow the following instructions to prepare the solutions.

! • Observe the safety codes for preparing chemical substances.
Caution

6.1 Reagents

• You can prepare the necessary stock solutions yourself or order them from LAR.
i • When ordering solutions, please bear in mind the supplier specifications for shelf
life and storage conditions.
Notice

6.1.1 Deionised Water

Deionised Water is required to make the calibration standards. It should contain a low fraction of carbon
and nitrogen compounds. The purity of the deionised water is dependent on the working range set.

Table 9: Purity Grades of the Deionised Water for TOC Measurement

Working Range Maximum Permitted C-Concentration

[mg/l C] [mg/l C]
<2 0.1
< 10 0.3
10 - 100 0.5
> 100 1.0

Table 10: Purity Grades of the Deionised Water for COD Measurement

Measurement Range Maximum Permitted COD-Concentration

[mg/l COD] [mg/l COD]
< 25 1.0
25 - 250 2.0
> 250 3.0

07E4317 Instruction Manual QuickCOD®ultra 55

 6 Reagents and Calibration Standards
6.1 Reagents LAR | PROCESS ANALYSERS AG

6.1.2 Rinsing Water

Deionised water is required to rinse the injection needle. The amount is dependent on the measurement
frequency set and the number of sample streams. The conductivity of the deionised water must be bet-
ween 1μS/cm and 10μS/cm, and the maximum permitted concentration for TC may not exceed 1 mg/l.

Proceed as follows:

• Fill a 5 l graduated flask with 5 litres of deionised water.

• Add 1 ml of 85% phosphoric acid (H3PO4).
• Degas the rinsing water using underpressure or put it into an ultrasonic bath for five minutes.
• Keep the rinsing water underneath the analyser (e.g. in the Reagent Cabinet or Ambient Air
Preparation Unit).

6.1.3 Phosphoric Acid (H3PO4) for TOC-Difference Method

1% phosphoric acid (H3PO4) is used for the outgassing or elimination of inorganic carbon compounds
(TIC), such as carbonate. The low pH value converts the ligated CO2 (e.g. carbonate) into gas phase,
which is then gassed out of the liquid and can be determined.

Proceed as follows:

• Fill a 5 l graduated flask with 4 litres of deionised water.

• Add 58 ml of an 85% phosphoric acid (H3PO4).
• Fill the graduated flask up to 5 l with deionised water.
• Add 1 g of copper sulphate (CuSO4 * 5H2O) to the solution to prevent bacteria forming.
• Keep the phosphoric acid solution underneath the analyser (e.g. in the Reagent Cabinet or Ambient
Air Preparation Unit).

• Biological deposits can form in the stripping vessel for strongly biological samples.
! A sulphuric acid (H2SO4) should be used here instead of the phosphoric acid
(H3PO4) for determination of the TIC.
Caution • Please contact your local partner or the Technical Support of LAR (Chapter 15
on page 257) before using another acid.

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 6 Reagents and Calibration Standards
LAR | PROCESS ANALYSERS AG 6.1 Reagents

6.1.4 Hydrochloric Acid (HCl) for TOC-Direct Method (NPOC-Method)

1% hydrochloric acid (HCl) is used for the outgassing or elimination of inorganic carbon compounds (TIC),
such as carbonate. The low pH value converts the ligated CO2 (e.g. carbonate) into gas phase, which is
then gassed out of the liquid and can be determined.

Proceed as follows:

• Fill a 5 l graduated flask with 4 litres of deionised water.

• Add 200 ml of a 25% hydrochloric acid (HCl).
• Fill the graduated flask up to 5 l with deionised water.
• Keep the hydrochloric acid solution underneath the analyser (e.g. in the Reagent Cabinet or Ambient
Air Preparation Unit).

• Hydrochloric acid concentrations between 3 and 5% can also be used depending

i on the application.
• Please contact your local partner or the Technical Support of LAR (Chapter 15
Notice on page 257) before using another concentration.

6.1.5 Cleaning Solution for Glass Components

Conventional cleaning agents can be used to clean sample and calibration vessels. Very thorough
cleaning with a bottle brush is required for analysers working in low TOC working ranges (< 100 mg/l C).
We recommend the following cleaning method for high levels of contamination which cannot be removed
using a bottle brush.

Proceed as follows:

• Fill a 1 l graduated flask with 0.8 litres of water.

• Add 10 ml of concentrated sulphuric acid (H2SO4) and 1 g of potassium manganate (KM4O4).
• Fill the graduated flask up to 1 l with water.
• Allow the glass vessels to stand in this solution overnight.
• Fill a 1 l graduated flask with 0.8 litres of water.
• Add 10 ml of concentrated sulphuric acid (H2SO4) and 10 to 20 ml of hydrogen peroxide (H2O2).
• Fill the graduated flask up to 1 l with water.
• Allow the glass vessels to stand in this solution for about 24 hours.
• Thoroughly rinse the glass vessels at least three times with clean distilled water.

07E4317 Instruction Manual QuickCOD®ultra 57

 6 Reagents and Calibration Standards
6.2 Production of Calibration Standards (CODo Method) LAR | PROCESS ANALYSERS AG

6.2 Production of Calibration Standards (CODo Method)

The concentration of the standard is dependent on the working range set. It should be at least 50% and
at most 100% of the working range end value. The standard is prepared in line with DIN EN 1484:1997.

Example:

If a working range of 1,000 mg/l COD is set, the calibration standard must be between 500 mg/l and
1,000 mg/l COD. A concentration of 750 mg/l or 800 mg/l COD would be ideal in this case.

• Make sure that you provide a logical concentration for your working range.
! Otherwise, the analyser cannot perform correctly after calibration.
Caution

• Appropriate certified calibration standards can be purchased directly from the LAR

i to minimize the effort of preparation.

• For more information please contact the Sales Department of LAR (Chapter 15 on
Notice page 257).

The calibration standards in the calibration vessel should replaced as follows (potassium hydrogen
phthalate):

• Weekly for a concentration > 100 mg/l C or 250 mg/l COD.

• Daily for a concentration < 100 mg/l C or 250 ml COD.

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 6 Reagents and Calibration Standards
LAR | PROCESS ANALYSERS AG 6.2 Production of Calibration Standards (CODo Method)

6.2.1 Calibration Standards - CODo Method

Chemicals required:

• Potassium hydrogen phthalate (C8H5KO4) p.a. dried for 2 hours at 105°C

The concentration of the standard depends on the desired measurement range and can be taken from
the following table.

Table 11: Standards for COD measurement

COD-Measurement COD-Calibration Standard Weighed Portion

Range [mg/l] [mg/l] [g]
100 - 1,000 750 0.638
500 - 5,000 4,000 3.403
1,000 - 15,000 10,000 8.508

Proceed as follows:

• Dissolve the weighed portion in a 1,000 ml graduated flask in 700 ml of deionised water.
• Fill the 1,000 ml graduated flask up to the mark with deionised water.

• The stock solution can be kept in a sealed glass bottle for about four weeks at a

i temperature of 4°C.
• Lower standard concentrations can be prepared by dilution from one of the above
Notice stock solutions.
• Please note that the pipetting accuracy can be negatively impacted when the stock
solution is diluted.

For high measurement ranges:

For high measurement ranges, acetic acid (C2H4O2) with a concentration of 99 - 100% is recommended.

• Fill the required amount of acetic acid in a 1,000 ml graduated flask in 700 ml of deionised water.
• Fill the 1,000 ml graduated flask up to the mark with deionised water.

Table 12: Standards for high measurement ranges

Amount Acetic Acid TOC-Content COD-Content

[ml] [mg/l TOC] [mg/l COD]
2.5 1,000 2,660
25 10,000 26,600
50 20,000 53,200

07E4317 Instruction Manual QuickCOD®ultra 59

 6 Reagents and Calibration Standards
6.3 Production of Calibration Standards (CODi Method) LAR | PROCESS ANALYSERS AG

6.3 Production of Calibration Standards (CODi Method)

The concentration of the standard is dependent on the working range set. It should be at least 50% and
at most 100% of the working range end value. The standard is prepared in line with DIN EN 1484:1997.

Example:

If a working range of 1,000 mg/l C is set, the calibration standard must be between 500 mg/l and 1,000
mg/l C. A concentration of 750 mg/l or 800 mg/l C would be ideal in this case.

• Make sure that you provide a logical concentration for your working range.
! Otherwise, the analyser cannot perform correctly after calibration.
Caution

• Appropriate certified calibration standards can be purchased directly from the LAR

i to minimize the effort of preparation.

• For more information please contact the Sales Department of LAR (Chapter 15 on
Notice page 257).

The calibration standards in the calibration vessel should replaced as follows (potassium hydrogen
phthalate):

• Weekly for a concentration > 100 mg/l C

• Daily for a concentration < 100 mg/l C

60 Instruction Manual QuickCOD®ultra 07E4317

 6 Reagents and Calibration Standards
LAR | PROCESS ANALYSERS AG 6.3 Production of Calibration Standards (CODi Method)

6.3.1 Calibration Standards - TOC-Difference Method

This section explains how you can prepare the calibration standards for the TOC-Difference Method
yourself.

First, a stock solution needs to be prepared which can then be diluted to arrive at the calibration standard
concentration required.

• To minimise mistakes, LAR always recommends using the stock solution as the

i initial solution for dilutions.

• The stock solution can be used as a calibration standard.
Notice
• The stock solution dilutions can be used as a calibration standard.

6.3.1.1 Stock Solution - TOC-Difference Method

This section shows how to prepare a stock solution for TOC-Difference Method analogous to
DIN EN 1484:1987.

Chemicals required:

• 6.382 g Potassium hydrogen phthalate (C8H5KO4) p.a. dried for 2 hours at 105°C
• 4.415 g Sodium carbonate (Na2CO3) dired for 1 hour at 185°C
• 3.500 g Sodium hydrogen carbonate (NaHCO3) dried for at least 24 hours in the exsiccator with
silica gel

Proceed as follows:

• Dissolve the weighted sample of each of the three substances in a 1,000 ml graduated flask in 700
ml of deionised water.
• Fill the 1,000 ml graduated flask up to the mark with deionised water.

The concentration of this stock solution is:

• TC (Total Carbon) = 4,000 mg/l C

• TIC (Total Inorganic Carbon) = 1,000 mg/l C
• TOC (Total Organic Carbon) = 3,000 mg/l C

• The stock solution can be kept in a sealed glass bottle for about four weeks at a
! temperature of 4°C.
• Please note that the pipetting accuracy can be negatively impacted when the stock
Caution solution is diluted.

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 6 Reagents and Calibration Standards
6.3 Production of Calibration Standards (CODi Method) LAR | PROCESS ANALYSERS AG

6.3.1.2 Dilution of the Stock Solution - TOC-Difference Method

Because the analysers work in different working ranges, the following three stock solution dilutions are
listed. These dilutions enable calibration standards to be made which have a lower concentration than
listed in the table below.

Proceed as follows:

• Take a 500 ml/2,000 ml graduated flask.

• Fill the dilution amount specified in the table into the graduated flask.
• Fill the graduated flask with deionised water up to the 500 ml/2,000 ml mark.

Table 13: Dilution of the Stock Solution (TOC-Difference Method)

Amount Stock Solution to TC TIC TOC
Stock Solution : Deionised Water [mg/lC] [mg/lC] [mg/lC]
Dionised Water
Dilution I 1 : 10 50 ml to 500 ml 400 100 300
Dilution II 1 : 40 12.5 ml to 500 ml 100 25 75
Dilution III 1 : 800 2.5 ml to 2,000 ml 5 1.25 3.75

The calibration standard can be diluted further after the stock solution is diluted:

• Take a 100 ml graduated flask.

• Fill the dilution amount specified in the table into the graduated flask.
• Fill the graduated flask with deionised water up to the 100 ml mark.

Table 14: Dilution of the Calibration Standards (TOC-Difference Method)

TC TIC Dilution Amount Dilution TOC

[mg/l C] [mg/l C] [mg/l C]
360 90 I 90 ml 270
300 75 I 75 ml 225
280 70 I 70 ml 210
200 50 I 50 ml 150
120 30 I 30 ml 90
50 12.5 II 50 ml 37.5
40 10 II 40 ml 30
20 5 II 20 ml 15
10 2.5 II 10 ml 7.5
2 0.5 III 40 ml 1.5
1 0.25 III 20 ml 0.75
0.5 0.125 III 10 ml 0.375
0.2 0.05 III 4 ml 0.15
0.1 0.025 III 2 ml 0.075

• The calibration standards can be kept in a sealed glass bottle for about one week
! at a temperature of 4°C.
Caution

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 6 Reagents and Calibration Standards
LAR | PROCESS ANALYSERS AG 6.3 Production of Calibration Standards (CODi Method)

6.3.2 Calibration Standards - TOC-Direct Method / TConly Method

This section explains how you can prepare the calibration standards for the TOC-Direct Method and
TConly Method yourself.

First, a stock solution needs to be prepared which can then be diluted to arrive at the calibration standard
concentration required.

• To minimise mistakes, LAR always recommends using the stock solution as the

i initial solution for dilutions.

• The stock solution can be used as a calibration standard.
Notice
• The stock solution dilutions can be used as a calibration standard.

6.3.2.1 Stock Solution - TOC-Direct Method / TConly Method

This section shows how to prepare a stock solution for TOC-Direct Method and TConly Method
analogous to DIN EN 1484:1987.

Chemicals required:

• 2.125 g Potassium hydrogen phthalate (C8H5KO4) p.a. dried for 2 hours at 105°C

Proceed as follows:

• Dissolve the weighted sample of each of the three substances in a 1,000 ml graduated flask in 700
ml of deionised water.
• Fill the 1,000 ml graduated flask up to the mark with deionised water.

The concentration of this stock solution is:

• TOC (Total Organic Carbon) = 1,000 mg/l C

• The stock solution can be kept in a sealed glass bottle for about four weeks at a
! temperature of 4°C.
• Please note that the pipetting accuracy can be negatively impacted when the stock
Caution solution is diluted.

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 6 Reagents and Calibration Standards
6.3 Production of Calibration Standards (CODi Method) LAR | PROCESS ANALYSERS AG

6.3.2.2 Dilution of the Stock Solution - TOC-Direct Method / TConly Method

Because the analysers work in different working ranges, the following four stock solution dilutions are
listed. These dilutions enable calibration standards to be made which have a lower concentration than
listed in the table below.

Proceed as follows:

• Take a 500 ml/1,000 ml graduated flask.

• Fill the dilution amount specified in the table into the graduated flask.
• Fill the graduated flask with deionised water up to the 500 ml/1,000 ml mark.

Table 15: Dilution of the Stock Solution (TOC-Direct Method and TConly Method)
Amount Stock Solution to TOC [mg/lC]
Stock Solution : Deionised Water Amount
Dionised Water
Dilution I 1:2 250ml to 500ml 500
Dilution II 1 : 10 50ml to 500ml 100
Dilution III 1 : 20 25ml to 500ml 50
Dilution IV 1 : 1,000 1ml to 1,000ml 1

The calibration standard can be diluted further after the stock solution is diluted:

• Take a 100 ml graduated flask.

• Fill the dilution amount specified in the table into the graduated flask.
• Fill the graduated flask with deionised water up to the 100 ml mark.

Table 16: Dilution of the Calibration Standards (TOC-Direct Method and TConly Method)

TOC [mg/l C] Dilution Amount Dilution

375 I 75 ml
250 I 50 ml
125 I 25 ml
50 II 50 ml
40 II 40 ml
20 II 20 ml
10 II 10 ml
5 II 5 ml
25 III 50 ml
5 III 10 ml
2.5 III 5 ml
0.5 III 1 ml

• The calibration standards can be kept in a sealed glass bottle for about one week
! at a temperature of 4°C.
Caution

64 Instruction Manual QuickCOD®ultra 07E4317

 7 How to work with the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG

7 How to work with the QuickCOD®ultra

This section introduces the structure and operation of the operating software of the analyser.

• Do not switch on the analyser without the presence of a technician authorised by

! LAR - because this voids the warranty of your analyser.
Caution

i • The figures in this chapter are examples where six streams can be seen. The
analyser software is always preset to how many streams are ordered.
Notice

Fig. 37: Introductory Screen

07E4317 Instruction Manual QuickCOD®ultra 65

 7 How to work with the QuickCOD®ultra
7.1 General remarks concerning the operating software LAR | PROCESS ANALYSERS AG

7.1 General remarks concerning the operating software

It is not necessary to memorise any commands for operation. The analyser offers a variety of functions
on screen to choose from.

7.1.1 Online-Mode

The analyser is in measurement mode after pushing the green „online“-button.

The online mode can The analyser is in ope-

be started ration mode (e.g.
measurement, calibra-
tion, maintenance or
so on)

Fig. 38: Online Button

• After pressing the green „online“ button the analyser will go into online mode. To
! abort a measurement or any other running operations press the red „offline“ button.
• After pressing the green „online“ button, the online mode is disabled if the
Caution reference temperatures for the furnace or the cooler not yet reached.

7.1.2 Keypad

For input in the main display, the following keypad is shown as soon as the field in question is clicked.

Fig. 39: Keypad and keypad button (on the right side)

66 Instruction Manual QuickCOD®ultra 07E4317

 7 How to work with the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 7.1 General remarks concerning the operating software

7.1.3 Access rights / operator levels

There are two user levels with different access rights. The first level is the „measurement overview“ level.
In this level the user has acccess to the introductory and measurement screens (measurement value
screen and 24h-profile). The second level is the „operator“ level with additional options in comparison to
level one. This level includes the parameters, data base, maintenance operation and so on. Acess to
level II is granted by a password or an USB stick. The password can be created by the user. To access
level II for the first time, type in the default password (Chapter 7.3.1 on page 107).

To enter any screen shown as follows, please push the related function button.

Fig. 40: Menu system - Level I

07E4317 Instruction Manual QuickCOD®ultra 67

 7 How to work with the QuickCOD®ultra
7.1 General remarks concerning the operating software LAR | PROCESS ANALYSERS AG

Fig. 41: Menu system - Level II

68 Instruction Manual QuickCOD®ultra 07E4317

 7 How to work with the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 7.2 Configuration

7.2 Configuration

To configure the analyser, some operating parameters can be adjusted.

7.2.1 Adjusting the operating parameters

In level II the parameters for measurements, calibration, relay settings, operator password, date/time,
name of the streams, units and channel display are already adjusted.
To adjust for specific requirements, the following steps are necessary and should be checked before
starting a measurement.

1) Test run (Chapter 7.2.13 from page 94)

2) Adjustment of measurement parameters (Chapter 7.2.2 from page 70).
3) Definition of the measurement value screen (Chapter 7.2.7 on page 84).
4) Setting limits (Chapter 7.2.15 on page 98).

• Some values are set by LAR or authorised personnel. All values depend on the

i application and have to be adapted to the application. To change the values of the
parameters, please contact your local partner or the Technical Support of LAR
Notice (Chapter 15 on page 257).

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 7 How to work with the QuickCOD®ultra
7.2 Configuration LAR | PROCESS ANALYSERS AG

7.2.2 Measurement parameter

At one stage in level II, there is a point where all measurement parameters can be set. After setting all
measurement parameters, the measurement can be started with the green “online“ button.

Three screens show the measurement values:

• Measurement value screen in level l
• Status screen in level II
• Data base in level II

• The unit is displayed in FSR. FSR stands for "Full Scale Range". Values are

i between 0 to 1 FSR. That implies 0 to 20 or 4 to 20mA.

• On the status screen, all detectors are listed. LAR has predefined the correct
Notice detectors for the analyser. If the settings need to be changed, please contact your
local partner or the Technical Support of LAR (Chapter 15 on page 257).

Fig. 42: Measurement parameter screen - example for three streams

70 Instruction Manual QuickCOD®ultra 07E4317

 7 How to work with the QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 7.2 Configuration

7.2.2.1 Measurement interval 1 to 6 Streams

Here the frequency of the measurement can be selected. If a measurement takes longer than the selec-
ted frequency, the analyser will select the next possible interval.
The following intervals can be selected:

Table 17: Possible analysis intervals

Adjustment Significance
1, 2, 3, 4, 5, 6, 10, 12, 15, 20 and 30 minutes analysis interval in minutes
1, 2, 4, 6, 8, 12 and 24 hours analysis interval in hours
fastest test mode quickest measurement frequency
remote control an external signal can activate the measurement
(for all present sample streams)

If further information or adjustments is required, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Various parameters influence the actual attainable maximum measurement frequency.

7.2.2.2 Moving average

The “moving average“ is a method used to smooth out a series of measurements. Two settings must be
activated for this method:
• Count of measurement value
• Allowed average in percent

The set number of values will be used to calculate the moving average are: 2, 3 or 4. For setting the
allowed percentage deviation 20, 30, 40 and 50%. For Example, a setting of 3 and 20%, would mean
the moving average is calculated from 3 values, which will be restarted at deviation greater than 20% of
the current value.

7.2.2.3 Correlation factor CODi / TOC

This parameter is only for the CODi measurement. The TOC value will be multiplied with the entered
factor in order to calculate the CODi. It is possible to set a correlation factor for each channel, see level
III “Name and Unit“ (Chapter 7.5.2.11 on page 130).

7.2.2.4 Filling sample vessel time

This parameter changes the time needed to fill the sample vessel before the measurement.

7.2.2.5 Stripping time

This parameter is only for the TOCdirect method. It determines the time needed to strip out the TIC in
the sample whilst it is in the sample vessel. This adjustment defines the waiting period after sample de-
livery. Values are variable in seconds.

7.2.2.6 TC delay
This parameter is the waiting time before sampling. The entered value will set the delay time prior to the
TC measurement.

7.2.2.7 TIC delay

This parameter is the waiting time before sampling. The entered value will set the delay time prior to the
TIC measurement.

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 7 How to work with the QuickCOD®ultra
7.2 Configuration LAR | PROCESS ANALYSERS AG

7.2.2.8 Measurement replicates

This option determines the number of separate measurements for one value shown on the display as a
result. The permissible range is 1 - 10, default is 1. More measurements are calculated via the mean
value to measured value. Even with several single measurements in a row the needle is rinsed after each
measurement. However, no fresh sample is delivered to the vessel until the multiple measurements are
completed.

• If a level III user (skilled user) has set (> 0) the parameter “multiple determinations“

i in the screen“ measurement parameters“, the level II user can see this parameter
but can not change it. The parameters “measurement replicates“, “measurement
Notice outliers“ and “measurement maximum CV“ also can not be changed (Fig. 75,
page 116) by level II user.

7.2.2.9 Measurements outliers

Using the outlier correction, outlier values of questionable measurements can be omitted for the calcu-
lation of the mean value. Acceptable are 0 - 2 measurement values as outliers. In order to define the
outlier value, the measurement value with the biggest standard variance to the mean value is chosen. If
the standard variation is within the tolerance zone of the maximum coefficient of variation (cv), then the
value is used for the mean value. If the standard variation is above the maximum cv, the value becomes
an outlier and will not be considered for the calculation of the mean value and the coefficient of variation.
The outlier values are marked with a different color and stay visible until the next measurement.

7.2.2.10 Measurements max. CV

The maximum CV or coefficient of variation is only active in the context of the outlier correction. If the
outlier correction is activated by typing in a percentage value, the maximum CV will be considered for
the calculation of the outlier values. The default value is 0. That means there is no consideration. The
maximum value is 10%.

CV = Standard Deviation / Average * 100

7.2.2.11 Rinse before sampling

This parameter is to prevent constipation in the needle. For the first measurement of an analysis interval,
the needle will be rinsed in advance. If the needle should be rinsed for the other measurements in the
same analysis interval, this can be set with this parameter.

7.2.2.12 Rinsing count 1 to 6 streams

This parameter determines how many needle rinsings should be carried out.

Minimum value 0
Maximum value 5
Default value 1

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7.2.3 Calibration

In level II, there is a possibility to run a calibration. Three screens guide the user through the calibration
process:

1) Calibration carry out (Chapter 7.2.3.1 from page 74), containing:

• Calibration carry out
• Detail of the calibration
• Calibration graphic
2) Calibration results (Chapter 7.2.3.2 on page 78)
3) Active calibration (Chapter 7.2.3.3 on page 79)

A manual calibration should be performed when:

• the analyser is taken into operation for the first time.
• the reactor or the reactor filling material has been replaced.
• the carrier gas flow has been changed.
• the injection volume has been changed.

Before starting a calibration, the calibration solution has to be at hand and the settings have to be adju-
sted in accordance with the “calibration carry out“ screen. Make sure, that the positioning of the calibra-
tion vessel is properly set. The concentrations and the preparation of the standard solutions are
described in Chapter 6.2 from page 58. Depending on the adjusted measurement method, a single stan-
dard or a mixed standard solution may be necessary.
The measurement results of the individual calibration points are displayed on the “calibration result“
screen . For more information, go to Chapter 7.2.3.2 from page 78. The calibration can be cancelled by
using the red “offline” button.

• During a manual calibration, the current carrier gas flow will be stored as the

i reference value. If the volume flow differs more than 5 % from it is value, the error
message “E1835 carrier gas flow is low” will be displayed. If this error occurs, the
Notice seals for the carrier gas should be repaired. (If necessary search for a leakage in
the gas flow path).

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7.2.3.1 Calibration carry out

• The analyser calibration screen displays the number of streams, that the analyser
i has. Please repeat the following for each stream or select all streams to do the
calibration for all steams at once.
Notice

Fig. 43: Calibration carry out screen - example for one stream with two solutions

On this screen, a one point calibration as well as a multiple point calibration can be done for any stream.
For a multiple point calibration, the calibration solutions can only be calibrated one by another.

• Back to the calibration start

With this button, you go back to the screen “Start Calibration“. This button can only be pressed when you
are on the screen “show details“ or “show curve“.

• Show details
Only after a calibration is carried out, this button can be pressed. Press this button to get a more detailed
view of the raw values of the solutions, streams and signals (Fig. 45, page 76). The outliers are marked
yellow automatically and are not taken into calculation. A new calibration cannot be started on this
screen.

• Show curve
Only after a calibration is carried out, this button can be pressed. In this screen, the measurement curve
of the calibration is shown (Fig. 46, page 77). The curve of the current calibration is blue. The new cali-
bration is shown with the red curve.To go back to the screen “calibration start“, press the button “back
to calibration start“.

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Calibration procedure for a one point calibration for one stream:

• Preparation of the calibration solution and positioning of the calibration vessel. You can check the
correct position with the test run (Chapter 7.2.13 from page 94).
• In the selection box “calibration solutions“ the amount of calibration solutions can be chosen.
• After choosing the number of calibration solutions this new amount appears on screen.
• Enter the max. CV in the input field.
• Between “solution“ and “stream“ there are input fields for entering the concentration of the solution.
Enter all ingredients of the solution into the table: Touch on the input field. A number field keyboard
will appear. Please enter the concentration (ppm).
• In order for the analyser to accept the new calibration concentration save it first by pressing the disk
symbol (Chapter 7.3.8 from page 109).
• Activate the check box for the designated stream and the solution.
• Now the calibration can be started by pressing the button “start calibration“.
• Raw values can be seen in the next screen by pressing the button “show details“.
• All check boxes on screen “show details“ are activated for the measured solution and stream. The
outliers are marked yellow automatically and are not taken into calculation.
• The calibration results (slope and intercept) can be seen and activated on screen “calibration results“
(Chapter 7.2.3.2 from page 78).

Multiple point calibration procedure (for three different solutions for example) for one Stream:
• Preparation of the calibration solution and positioning of the calibration vessel.You can check the
correct position with the test run (Chapter 7.2.13 from page 94).
• In the selection box “calibration solutions“, the amount of calibration solutions can be chosen.
• After choosing the number of calibration solutions, this new amount appears on screen.
• Enter the max. CV in the input field.
• Between “solution“ and “stream“, there are input fields for entering the concentration of the solution.
Enter all ingredients of the solution into the table: Touch on the input field. A number field keyboard
will appear. Please enter the concentration.
• In order for the analyser to accept the new calibration concentration, save it first by pressing the disk
symbol (Chapter 7.3.8 from page 109).
• Activate the check box for the first stream and then all solutions that you want to measure.
• Now the calibration can be started pressing the button “start calibration“.
• When the first solution was measured, a stop message appears (Fig. 44, page 76). The stop
message shows the next calibration solution, the vessel position of the calibration solution and the
calibration solution‘s concentration.
• If the second solution is put into position, press the green arrow of the stop message.
• The stop message will come up one more time.
• When all three solutions have been measured, the raw values can be seen with the button “show
details“ on the next screen.
• All check boxes on screen “show details“ are activated for the measured solution and stream. The
outliers are marked yellow automatically and are not taken into calculation.
• The calibration results (slope and intercept) can be seen and activated on screen “calibration results“
(Chapter 7.2.3.2 from page 78).

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Fig. 44: Calibration carry out screen - stop message

Fig. 45: Calibration carry out screen - show details - example for one stream with two solutions

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Fig. 46: Calibration carry out screen - show curve - example

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7.2.3.2 Calibration result

After running a calibration (Chapter 7.2.3.1 from page 74), the results will be displayed on the calibration
results screen (Fig. 47, page 78). Next to it, the values of the previous calibration are shown. Please ac-
tivate the calibration with the button “activate calibration result“. The result will be saved and can be view-
ed on screen “active calibration“ (Chapter 7.2.3.3 on page 79).
The set point of the carrier gas is also shown.

Fig. 47: Calibration results screen - example for one stream

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7.2.3.3 Active calibration

The values of the calibration result will be transferred by the button “activate calibration result“. First run
a calibration (Chapter 7.2.3.1 from page 74). If the values from the calibration are correct, activate the
calibration. After approximately 10 seconds the calibration result values will be transferred to the screen
“active calibration“.

Fig. 48: Active calibration screen - example for one stream

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7.2.4 Injection volume

In this screen, the parameter dilution, TC for each stream and TIC for each stream can be adjust.

Fig. 49: Injection volume screen

7.2.4.1 Dilution
This parameter shows how much water is mixed with the sample in the injection needle for the dilution.
Afterwards the sample and the water are injected into the reactor.

7.2.4.2 TC for each stream

This parameter means how much liquid is injected into the furnace for the TC measurement.

7.2.4.3 TIC for each stream

This parameter means how much liquid is injected into the TIC port for the TIC measurement. (Only for
TOC-Difference Method)

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7.2.5 Relay setting

The analyser is equipped with eight relays. The function of the eight relays can be individually assigned
on this screen. The activities of the analyser are listed in Tab. 19, page 111.

Fig. 50: Relay setting screen (example)

i • As default value, relay 1 is set as “malfunction alarm“. The question marks in the
input field are default settings. User can be individually assigned this seven relays.
Notice

In order to put the required characters into the input field, use the number field keyboard (Fig. 39,
page 66):
• touch the input field (Fig. 50, page 81).
• the keyboard appears at the bottom.
• if not: a keyboard button (Fig. 39, page 66) will appear in the bottom right-hand corner of the screen.
Press this button and the keyboard will appear.
• enter the suitable limits or errors with the programming tools.
• save changes with the floppy disc button (Chapter 7.3.8 on page 109).

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7.2.5.1 Tools for programming

• !-Operator
The ! operator is used to invert a condition (!L1 means for instance that the condition is met if the limit
set point #1 is NOT exceeded).

• &-Operator
The & - operator is used as an “AND“ conjunction of several conditions. The programmed condition is
only met if ALL individual conditions are met (E1835&E1810&E2024 means for instance, that the analog
output only drops to 0 mA if all three errors occur simultaneously).

• |-Operator
The | - operator is used as an “OR“ conjunction of several conditions (E1810|E1844|E2024): the analog
output drops to 0 mA if at least one condition is met.

Examples:

• Malfunction alarm:
Program one of the 8 relays according to "E1810 I E1844 I E2024" (without the quotation marks). If you
want to use the relay as a break contact, the same function would be: "!(E1810 I E1844 I E2024)".
Please note the round brackets!

• Sample-ready:
Program one of the 8 relays according to "!M1" (without the quotation marks). This sequence means that
the relay is closed after completion of the sample stream. This contact remains closed until the beginning
of the next measurement.

7.2.5.2 Relay testing

There are two ways to check the relays:
• Check with a multi meter (only an authorized person should carry out this operation, because the
rear housing must be open) or
• check your programming of the relays to the plant control centre.

• To check the relays with a multi meter:

1) Open the rear housing.
2) Connect the multi meter to the relay. Please switch on the continuity test at the multi meter.
3) On the screen "relay settings", activate the check box where the multi meter is connected. (Example:
the multi meter is connected on the relay number 2. Then on the screen “relay setting“: press the
button for relay 2 “ON“!).
4) A tone will be heard (only if the multi meter can give a tone).
5) If no tone is heard, please check the multi meter. If the multi meter is correct, please contact your
local partner or the Technical Support of LAR (Chapter 15 on page 257).
6) After checking the relays, close the rear housing.

• To check your programming together with the control centre:

1) If a relay is programmed, go to the control centre to check the error.
2) Activate the check box of the desired relay.
3) At the control centre, the error will appear.
4) If no error appears in the control centre, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).

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7.2.6 PC settings

In this menu, there are four options to choose/do:

• Change the operator password
• Change the Date / Time
• Look up the “Software version“
• Calibrate the touch screen

Fig. 51: PC setting screen

7.2.6.1 Operator password

Here the password for level II can be chosen. However, if the password is deactivated, a USB stick with
level II will be necessary.

The password can be changed by touching the input field:

• the keyboard appears.
• type in the new password (making note of upper- and lower case letters) in the field.
• confirm this using the “floppy disc“ symbol (Chapter 7.3.8 on page 109).

7.2.6.2 Date/ Time

The date and time is visible on all screens and is positioned at the upper right hand corner. If the clock
is set to daylight saving time or for timing synchronisation with other operational analysers, it can be set
in screen “PC - Setting“. Under the input field from the date / time is the correct entry. After setting the
date and time, please first save changes (Chapter 7.3.8 on page 109) and then start a new measure-
ment.

correct entry: Year-Month-DayTHour:Minutes:Seconds

example: 2012-08-28T13:51:32

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7.2.6.3 Full software version

The version of the software is displayed in the top line of the “pc setting“ screen.

7.2.7 Display channel

On the screen “display channel“, the different channels can be defined for the measurement value
screen display. A channel is defined by the stream, sensor, function, parameter and channel parame-
ters. This settings are default setting and can be seen in level III in the screen “Name and Unit“
(Chapter 7.5.2.11 on page 130).
The first 8 measured values (display channel) can be seen in the measurement screen.
The settings of the channel display are set in accordance with the requirements of the analyser. The
channel display can be changed using the selection boxes.

Fig. 52: Channel display - example

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7.2.8 Measurement value screen

The measurement screen shows the current measurement values and the time it was measured. If you
want to change the channels, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).

Fig. 53: Measurement value screen - example

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7.2.9 Signal curve

To view the measurement curve of the measurement values, go to the screen “signal curve“ in level II.
If the analyser has more than one detector, select the detector in the top left corner of the screen.

Fig. 54: Signal curve screen - example

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7.2.10 Status screen

In this split screen, the right window gives an overview about the active status values of the analyser.
The left window shows the measured values for each stream. If another stream is required press the
selection field “stream“. Next to the button “choose stream”, the time for the next measurement is shown
for every stream. The first column shows the time [hh:min:sec] of the measurement. The other columns
show the measured values respectively. If the analyser has more than one parameter to be measured,
the next columns show the other measured values (parameter like: TNb, COD).

In the upper right window the following status parameters of the analyser are displayed:
• Furnace status (on / off)
• Gas cooler status (on / off)
• Gas flow inlet and outlet (real value / set point)
• Humidity (real value / set point)
• Gas pressure (real value / set point)
• Status of digital inputs 9 - 11
• Status signals occurred (error, limits and control state)

Below the status signal the sensor values are shown:

• Choose sensor
Below the status signal a sensor selection field is shown.

• Zero signal
The base of the measurement is the zero signal of the detector, measured during an adjustable time pe-
riod before starting the measurement. After finding the zero point or zero signal, the integration will start
if the difference between the current signal and the zero signal is larger than the value of start integration.

• Integration
This value is the integrated peak area from the signal after the measurement.

• Integration TIC
This value is only for the TIC measurement and is the peak area from the signal after the measurement.

• Signal
This value is the current signal of the whole measurement.

Fig. 55: Analyser status screen

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7.2.11 Service action

By going to the screen “service action“, the following actions can be selected:
• Rinse sample tubes (with a input field for sample vessel rinsing time)
• Rinse injection system
• Furnace on/off
• Furnace valve open/close
• Condensate pump on/off
• Stirrer on/off

During a measurement or calibration, none of these actions can be activated. To carry out any of these
service actions, the online mode must be cancelled using the red offline button

Fig. 56: Service action screen in the operation „stop maintenance“

• The sample pumps should not be a continuous operation, otherwise the warranty

i claims for pumps are not applicable.

• On completion of maintenance or if the “start maintenance“ button has been
Notice pressed and a new measurement, calibration or single measurement needs to be
carried out, the “stop maintenace“ button must be pressed first.

In order to activate the screen “service action“:

• end measurement with the „Offline“- button.
• press the „start maintenance“ button.

In order to deactivate the screen “service action“:

• press the „stop maintenance“ button.
• then a new measurement or calibration can be started.

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Fig. 57: Service action screen in the operation „start maintenance“

i • The red circular arrow in the right hand status line appears only when the “start
maintenance“ button was pressed and no measurement can be done.
Notice

7.2.11.1 Choose stream for operation

This selection box is only for operating the “rinse sample tubes“ and “rinse injection system“ button
(Chapter 7.2.11.3 on page 90 and Chapter 7.2.11.4 on page 90).

7.2.11.2 Maintenance
There are two buttons for maintenance:
• stop maintenance and
• start maintenance
The first button (stop maintenance) deactivates all maintenance buttons so that the online mode can be
started.

Example:
If the button “stop maintenance“ is pushed, all maintenance buttons will be greyed out and can no longer
be pressed.
The second button (start maintenance) means all maintenance work buttons on this screen will be ac-
tivated (highlighted).

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7.2.11.3 Rinsing sample tubes

To prepare for measurement operation, the tubes should be filled with the sample. This time for the rin-
sing process can be set here.
• Select the stream with the button “choose stream for operation“ (Chapter 7.2.11.1 on page 89).
• Type in the length of time for the rinsing of the sample tubes and save the changes with the floppy
disc button (Chapter 7.3.8 on page 109).
• Press the “start maintenance“ button (Chapter 7.2.11.2 on page 89).
• Press the “rinse sample tubes“ button.

If the maintenance is completed, the “stop maintenance“ button needs to be pressed.

7.2.11.4 Rinse injection system

This action means, the injection system will be rinsed. In this case, it is not important which stream is
chosen, but one stream must be activated. However, the position of the drain vessel is of more impor-
tance. Default: stream 1.
• Select stream 1, using the “choose stream for operation“ button (Chapter 7.2.11.1 on page 89).
• Press the “start maintenance“ button (Chapter 7.2.11.2 on page 89).
• Press the “rinse injection system“ button.

The operation can take a few minutes but can be stopped with the offline button at any time. If the ope-
ration is completed, the other buttons will be highlighted. If the maintenance is completed, the button
“stop maintenance“ needs to be pressed.

i • The actions “rinse sample tubes“ and “rinse injection system“ can be interrupted
pressing the „Offline“ button at any time.
Notice

7.2.11.5 Furnace on / off

With these two buttons it is possible to activate and deactivate the furnace.
Deactivating the furnace - “furnace off“:
• Press the “start maintenance“ button (Chapter 7.2.11.2 on page 89).
• Press the “furnace off“ button.

In order to turn the furnace back on, the “furnace on“ button has to be pressed. If the maintenance is
completed, the “stop maintenance“ button needs to be pressed and then the furnace will switch “on“
again.

i • The heating up of the furnace takes about 120 minutes = 2 hours. This corresponds
to a heat up rate of 10 °C/min. This setting cannot be changed.
Notice

7.2.11.6 Furnace valve open / close

To open or close the injection valve of the furnace, there are two buttons available.
Opening the furnace valve:
• Press the “start maintenance“ button (Chapter 7.2.11.2 on page 89).
• Press the “furnace valve open“ button.

In order to close the furnace valve, the “close furnace valve“ button needs to be pressed. If the mainte-
nance is completed, the “stop maintenance“ button needs to be pressed.

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7.2.11.7 Condensate pump on / off

To activate and deactivate the condensate pump, there are two buttons available:
Deactivating the condensate pump - “condensate pump off“:
• Press the “start maintenance“ button (Chapter 7.2.11.2 on page 89).
• Press the “condensate pump off“ button.

In order to turn on the condensate pump, the “condensate pump on“ button needs to be pressed. If the
maintenance is completed the “stop maintenance“ button needs to be pressed.

7.2.11.8 Stirrer on/off

With this action, the stirrer can be turned on or off. The number of stirrers depend on the number of
sample streams and they are all turned off during the maintenance at this point.
Turning stirrer off:
• Press “start maintenance“ button.
• Press “stirrer off““ button.

In order to turn on the stirrer, the “stirrer on“ button needs to be pressed. When all maintenance actions
are completed, the “stop maintenance“ button needs to be pressed. Only when the “stop maintenance“
button has been pressed, a measurement can be started.

• The actions “rinse sample tubes“, “rinse injection system“, “open/close furnace
i valve“, “condensate pump on/off“ and “stirrer on/off“ carried out independently of
one another.
Notice

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7.2.12 Single measurement

During single measurements, only single calibration or samples can be measured. The data from single
measurements are not stored. Single measurements are useful for checking calibration solution, to
decide if a new calibration is necessary, or to analyser grabbed samples.

• The measurement values are not stored in the data base or “status screen“. Also

i the values are not transmitted to the analog outputs.

• A screenshot from this screen can be taken with the screenshot button.
Notice
• The measurement values are only shown on screen “single measurement“.
• If the stream is chosen and the vessel is set to “off“, the sample will be taken from
the default sample vessel. If another vessel has been chosen, then the sample will
be taken out of the chosen vessel.
• During the online measurement the buttons “choose stream“, “vessel“ and “start
single measurement“ are deactivated.

Fig. 58: Single measurement screen - example

The stream, the vessel and the three parameters (replicates, outliers and CV) need to be chosen before
a single measurement can be carried out. The position of the vessels depend on the selected stream
and only one stream can be measured at a time. First, the stream should be chosen with the “choose
stream“ button. Furthermore, a vessel can be changed with the “vessel“ button. If the “vessel“ button is
set to “off“, the sample will be taken from the vessel that belongs to the stream. After setting the three
parameters and saving them (Chapter 7.3.8 on page 109), the single measurement can be run with the
start single measurement“ button. In the table the replicates, the results and the CV of the measurement
are shown. The outliers are marked yellow automatically and are not taken in calculation.

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Parameters:

1) Replicates
This option determines the number of single measurements for one value shown as result on the display.
The permissible range is 1 - 10, default is 1. More measurements can be calculated via the mean value
to the measured value. Even with several single measurements being carried out in a row the needle is
rinsed between each measurement. However, no fresh sample is delivered to the vessel until the mul-
tiple measurements are completed.

2) Outliers
Using the outlier correction, outlier values from questionable measurements can be omitted for the cal-
culation of the mean value. Acceptable are 0 - 2 measurement values as outliers. In order to define the
outlier value, the measurement value with the biggest standard variation to the mean value is chosen. If
the standard variation is within the tolerance zone of the maximum CV, then the value is used for the
mean value. If the standard variation is above the maximum CV, the value becomes an outlier and will
not be considered for the calculation of the mean value and the coefficient of variation. The outlier values
are marked with a different color and remain visible until the next measurement.

3) Max. CV
The maximum CV or coefficient of variation is only active in the context of the outlier correction. If the
outlier correction is activated by choosing the numbers one or two, the maximum CV will be considered
for the calculation of the outlier values. The default value is 0, that means there is no consideration. The
maximum value is 10%.

CV = Standard Deviation / Average * 100

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7.2.13 Test run

By pressing the “test run“ button in level II, the positions of the needle on the X-axis can be tested and
configured.

i • Only changes on the x-axis will be stored/recorded.

• To stop the test run or puncture test, press the red “offline“ button.
Notice

Fig. 59: Test run screen

• The position of the needle has to be adjusted so that the needle is positioned

i directly above (2 mm) the centre of the injection port or above the centre of the
vessels for sample or calibration standard. A misalignment in the positioning can
Notice result in poor measurement accuracy or damage to the needle!

7.2.13.1 Manual test run

To check the exact position of the injection needle, perform a manual test run. With the "go to
position" button the needle can be moved to all positions along the X-axis. It will stop above the corre-
sponding position and move down into the vessel or the injection port. This allows for checking the cor-
rect positioning of the injection needle and its accuracy. If the positions are not correct, check the
positioning of the x-axis.

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7.2.13.2 Positioning / justification of the x - axis

If the positions are not correct, align the needle by using the arrow keys. First a manual test run must be
performed and then the correct positioning can be adjusted using the arrows ( and ). When the cor-
rect position has been found, press the “floppy disc“ button (Chapter 7.3.8 on page 109) to save theset-
ting.

• xy - positioning ( and )

These arrows are for the x-y- positioning of the robot arm. Only the x-position can be saved.

• Syringe position ()

The z - positioning is for refilling the syringe.

• X-10 ()
The x-10 means that these buttons move 10 times quicker than the upper buttons (arrows).

7.2.13.3 Puncture test

This allows for checking the correct position of the injection needle in the vessel.
The needle will move to the corresponding vessel with the "go to position" button and then start the punc-
ture test.

i • The puncture test can be done for all position excepting the furnace position.

Notice

7.2.13.4 Test injection system

At this point, there is an opportunity to check the quality of the sample injection function at the particular
injection port.
• The position must be chosen with the selection field “go to position“.
• Press the "test injection system" button.

The needle will move into position above the corresponding vessel, pick up a sample volume adjusted
for this stream and splash it onto the centre of a silicon disk. This allows the correct positioning and in-
jection for the injection needle to be checked (visual test).

7.2.13.5 Cancel last operation

Pressing this button will remove the last entry/input, which will then be replaced by the prior position va-
lue.

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7.2.14 Auto - Check

In this screen, there are two functions:
• Automatic - check: automatic calibration using standards
• Auto - check: automatic verification using standards

Fig. 60: Auto - Check (example for three streams) - The „Automatic - check“ is activated

Fig. 61: Auto - Check (example for three streams) - The „Auto - check“ for stream 2 is activated

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7.2.14.1 Automatic - check: automatic calibration using standards

In this selection box, between eight different calibration intervals can be chosen or to deactivation the
automatic calibration of each stream. Tab. 18, page 97 shows possible calibration intervals.
One must enter a percentage of deviation for the new calibration. The integration area of the automatic
calibration is compared with the last manual calibration. If the new calibration is within this percentage,
it is saved as the current calibration. If the new calibration is not within this percentage, it is deleted au-
tomatically.

• Before starting a calibration or a measurement, please check the status of the

i analyser (Fig. 55, page 87) and the analyser (visual control). Otherwise a wrong
calibration or measurement is possible.
Notice • Ensure that if an automatic calibration is carried out, new calibration standards
must be placed in due time.
• After starting the automatic calibration with the green online button, preselected
calibration cycles starts.

Table 18: Possible calibration intervals

Adjustment Calibration on
NONE No calibration
1 day after 24 hours
2 days after 48 hours
3 days after 72 hours
4 days after 96 hours
5 days after 120 hours
6 days after 144 hours
7 days after one week

Carry out:
• Activating the time interval for each stream (selection box).
• Setting deviation for each activated stream.
• Start the automatic calibration with the online button.

7.2.14.2 Auto-check: automatic verification using standards

In this screen, it can be determined whether the analyser should carry out measurements independently.
To do this, two channels are needed. One channel for online measurement and another channel for con-
trol measurement. This option must be activated, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257). In this screen the setting for how often the auto-check will
run and which vessel will be chosen. During these intervals set by the user, the analyser carries out a
correct operation check independently. There is also the possibility not to choose a vessel. The sample
will then be taken out of the “default vessel“ corresponding to a specific stream.

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7.2.15 Limit setting

41 limits can be adjusted. To set one limit, the following steps have to be carried out:
• the channel
• the minimum value of the measurement value (lower limit)
• the maximum value of the measurement value (upper limit)
• the name of the limit

These first three points are important. The last one, “name“, is only for documentation.
Select the parameter by pressing the button in question. To adjust the value for minimum, maximum or
name, touch the white input field below the “minimum, maximum or name“. A number field keyboard ap-
pears. Please enter your desired limits and save the changes using the “floppy disc“ button
(Chapter 7.3.8 on page 109).

Fig. 62: Limit setting screen - example for two limits

i • To adjust further limits, a channel must be allocated to the last limit set. After which,
a new limit will appear.
Notice

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7.2.16 Data base

By selecting the item “data base”, three screen options are shown:
1) main representation of the database
2) table form for measurement data
3) curve form for measurement data

On the screen „overview data base“, the data per streams on which date are shown. To see the measu-
rement value on a certain day, touch that particular stream option and choose the day by activating the
check box. Once the loading process is finished (100%), the table (No. 2 in Fig. 63, page 99) or the curve
(No 3. in Fig. 63, page 99) with the measurement value can be opened.

1 2 3 4 5 6

Legend:
1) Main representation of the database 5) saving all data (measurement data and
2) table form for measurement data logbook to a USB stick
3) curve form for measurement data 6) overwrite parameters
4) saving selected data to a USB stick

Fig. 63: Data base screen

• Only if measurement data is loaded to 100%, either of the two buttons “table and
i curve for measurement“ can be pressed.
• More than one day can be selected with the check box.
Notice

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• Saving data (No. 4/5 in Fig. 63, page 99)

Measurement data can be saved to an USB stick:
1) Connect the USB stick to the analyser.
2) Choose the desired measurement data.You can activate the measurement data from particular
streams or all the measurement data by activating the check boxes.
3) Press the “save“ button (No. 4/5 in Fig. 63, page 99) and the data will be copied to the USB stick.

• Overwriting parameters (No. 6 in Fig. 63, page 99)

After successfully putting the analyser into operation the preset parameters can be transferred onto a
USB stick for the purpose of parameter storage. When parameters are changed or the analyser suffers
operational disturbances, the preset parameters from the set-up can be transferred back to the analyser
from this USB stick.
1) Cancel measurement.
2) Connect USB stick to the analyser.
3) On the screen database, press the “overwrite parameters“ button.
4) A question with “yes/no“ follows: “yes“ the analyser restarts automatically (program restart).
5) If the overwriting was successful (a new screen has appeared), the stick can be removed.

i • Before the button overwriting parameters will be pressed, please contact your
local partner or the Technical Support of LAR (Chapter 15 on page 257).
Notice

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7.2.16.1 Measurement data as a table

The measurement data is shown in the column to the right of the time column. If you press the “measu-
rement data as a curve“, the associated measurement curve appears.

Fig. 64: Measurement data as a table

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7.2.16.2 Measurement data as a curve

If the chosen measurement data on the screen “main represention of the data“ should be shown as a
curve, the “measurement data as curve“ button has to be activated. Every parameter has its own dia-
gram. You can change the parameter using the buttons in the upper left corner of the screen. On the
screen “measurement data as a table“, you can also get to the curve view. Therefore, press the button
“measurement data as curve“ and the appropriate measurement curve appears.

Fig. 65: Measurement data as a curve - example

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7.2.17 Log - book

Via the status bar, the logbook can be accessed. Use the symbol “ go to the logbook“ (No. 2 in Fig. 66,
page 104) and a selection window will pop up. In this window, touch “control state“ (Fig. 67, page 104).

There are two screens in the log-book:

• Archiving of the logbook
• Current errors

The symbol of the log-book insight consists of three colours:

• Green: no mistake occurred
• Yellow: a mistake occurred that does not affect the measurement
• Red: a mistake occurred and the measurement has been cancelled

For a more detailed view of the current existing mistakes, look in the logbook under current existing
mistakes.

On the screen of the logbook archive, there are four folders:

• system
• errors
• limit
• service log

To view the subfolders (system, errors, limit or service log), touch the triangle in front of the subfolders
name. The system data contains all the information about all changes made in the system and about the
analyser itself.

Example: changes in: measurement settings, parameters, selftest and much more.
The errors and limit data is a list of the error messages and exceedances of limits.
The service log is a list of position changes of the xyz - axis. These, however, do not have to be position
errors. This data file is only interesting for your local partner or the Technical Support of LAR.

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1 2

3 4

Legend:
1) Screen of the logbook (archived and current 3) Current existing errors screen
errors) 4) Archiving the logbook (errors, system, limit and
2) Go to the logbook screen (symbol) service log)
Fig. 66: Log book - archiving

Fig. 67: Go to the log-book

i • Log-book screens can only as be accessed under level II.

Notice

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Fig. 68: Log-book - example

7.2.18 Data storage

During the start-up and maintenance of the analyser the set up data is stored. A backup of the parame-
ters obtained during the installation process is stored for safety reasons.

Please get in touch with your local partner or the Technical Support of LAR to store your data
(Chapter 15 on page 257).

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7.2.19 Analog out calibration

There is the possibility to run the analog outputs in the range of 0 - 20mA or 4 - 20mA. There is a so
called „life zero“- mechanism integrated via the analog outputs. This means that when there is an error,
0 mA can be put out on the electricity output (analog output). Under which circumstances this „life zero“-
mechanism is activated can be set individually by the user in the selection box.
To do this, select “4/20mA“ in the “life zero“ selection box.

Fig. 69: Analog out calibration screen

Only an authorized person should carry out this operation, as the rear housing has to be opened.

1) Open the rear housing.

2) Connect the current meter (ammeter) to the analog output.
3) On the screen “analog out calibration“, type in the “analog out number“ where the current meter is
connected.
4) Select the desired mA value (0, 4, 10, 12 or 20mA).
5) The mA value must be visible on the current meter. If a different mA value is seen, please contact
your local partner or the Technical Support of LAR (Chapter 15 on page 257).
6) After checking the analog output, close the rear housing.

i • Please disconnect any signals to the control system before starting the test.

Notice

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7.3 Important tasks, good to know

7.3.1 Password

The password can be changed by the user on level II on the screen “pc setting“. If a new password is
set it should be documented and stored in a safe place.
If someone changes the default password or deactivates the password, the USB stick with level II access
is necessary. A USB stick will be shipped in the additional spare parts box.

i • The default password set by LAR is: lar

• A USB stick with level II is required if the password is deactivated.
Notice

7.3.2 Software version

The introductory screen (Fig. 37, page 65) in level I as well as the pc settings screen (Fig. 51, page 83)
in level II show the current version of the analyser software.

7.3.3 Terminating RUN mode (stop)

The measurements will continue until they are stopped by using the red “offline” button (upper right hand
corner). The analyser will then switch into standby mode and all data that is not saved yet will be saved.
When the measurement is stopped, the care and maintenance actions (Chapter 8 from page 131) can
be carried out, the operating parameter settings (e.g. measurement frequency) can be modified or pre-
vious measurement values can be evaluated.
If the measurement is terminated by a power failure, an auto start is carried out after reestablishing the
power. The analyser automatically switches back into the RUN mode and continues its operation, when
all operating parameters are ready.

7.3.4 Furnace On/ Off

Several maintenance tasks require that the furnace is switched off. Please note that frequently switching
the furnace on and off will lead to a reduced lifetime of the heating module. On the screen “service ac-
tion“, this can be done (Chapter 7.2.11 from page 88).
The analyser is equipped with a high temperature furnace which enables a complete combustion of the
carbon contained in the sample transforming it into CO2 without using a catalyst. The set points of the
temperature controller are set by LAR and are password protected. Please do not change the tempera-
ture. Problems relating to the temperature should be referred to your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
The controller labelled “temperature control” displays two temperatures: the real value and the set value.
The temperature is monitored and the analyser will turn off the power if the furnace reaches 1,250°C, to
avoid overheating. The device is placed on the rear panel in the housing.
The default setting for the heating up of the furnace is about 120 minutes = 2 hours. This corresponds
to a heat up rate of 10 °C/min. These settings are preset by LAR and cannot be changed.

7.3.5 Condensate Pump On/ Off

The condensate pump is always running by default. For maintenance and service work (changing tubes
etc.), the condensate pump must be turned off (Chapter 7.2.11 on page 88).
Please, do not forget to reactivate the pump after carrying out maintenance and service tasks.

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7.3.6 Date and time

The date and time is visible on all screens and is positioned in the upper right hand corner. To set the
clock to daylight saving time or for synchronisation with other operational analysers, go to the screen “pc
settings“ (Chapter 7.2.6 on page 83).

7.3.7 Language

The software language of the analyser is set by LAR. To change the language, please contact your local
partner or the Technical Support of LAR (Chapter 15 on page 257).

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7.3.8 Save

All changes have to be saved.

To carry out a saving process:
• make the necessary change (for example parameters).
• to save a new entry at the number field, please press “enter“.
• a “floppy disk“ symbol appears in the status line (right upper) (Fig. 70, page 109).
• press the “floppy disk“ button and a new smaller selection window comes up.
• select “save changed parameter“ (see).
• a new window comes up in the middle of the screen (Fig. 71, page 109).
• if the change should be saved, press the green “hook“ on the new window.
• if the change was incorrect press, the red “x“ on the new window to cancel the operation.

Fig. 70: Saving operation - part one

Fig. 71: Saving operation - part two

• In the window two values are displayed. The first value is the prior value and the

i second value is the new value.

• If more than one parameter is changed, only one saving process must be
Notice undertaken.
• The “hook“ next to the new value means the parameter will be changed. That
means if 5 parameters are changed and the saving process starts with the "floppy-
disc", the window appears with the changed parameter. If the first parameter is
wrong, deactivate this parameter with the “hook“ next to the parameter. Then the
saving process can be finished with the green “hook“. The first parameter won‘t
change but the other four are changed.

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7.3.9 Wizards

A wizard is a guided tour that leads you through the LAR software. During this tour, all necessary modu-
les (the screens of the software) are opened one after another, showing additional help texts. The help
texts are marked with a blue frame. This serves as support, which improves the handling and the over-
view. In order to get to the screen “wizard”, click on the light bulb in the upper right hand corner of the
status bar.

The the following wizards can be chosen:

• Wizard-01: check: This wizard presents the basic functions of the LAR ultra wizards and the settings.
This wizard is only for your local partner or the Technical Support of LAR.
• Wizard-02: calibration TConly 1-Solution 1-point: In this wizard, a calibration is done for TConly.
• Wizard-02 is only for users with level stick II or level stick III.

Fig. 72: Wizard screen

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7.4 The status identification (control state) and errors

The current status of operations is reported on the status screen (Chapter 7.2.10 from page 87).
This screen will only display the latest status reports, current errors and limit messages. For a status re-
port per day (24h-profile) please refer to “logbook“ (Chapter 7.2.17 from page 103).
For questions or unsolved issues, please feel free to contact your local partner or the Technical Sup-
port of LAR (Chapter 15 on page 257).

• The following table contains all the possible status codes for the various analyser
i configurations. It is possible that not all status codes apply to your current
configuration.
Notice

Table 19: Status identification (control state)

Status Description Possible Cause Action

Activity
M Measurement (dependent on streams, e.g. one stream analyser  M1)
C Calibration (dependent on streams, e.g. one stream analyser  C1)
W Waiting time, that means the analyser is between two measurement modes
M&W Short waiting time before each measurement (dependent on streams, e.g. one stream
analyser  M1&W)
S Single measurement (dependent on streams, e.g. one stream analyser  S1)
D Autocheck - function (automatic verification using standards) (dependent on streams,
e.g. one stream analyser  D1)
P Offline mode
Limits
L_min Minimum limits (dependent on streams, e.g. one stream analyser  L1_min)
L_max Maximum limits (dependent on streams, e.g. one stream analyser  L1_max)
Selection of instrument errors
E1810 Furnace emergency off Furnace overheating • Check cable and
controller
• Contact Support
(Chapter 15 on page 257)
E1815 Humidity emergency off Relative humidity >60% or • Check the humidity and if
broken cable necessary drainage the
analyser
• Contact Support
(Chapter 15 on page 257)
E1820 Furnace deviation band Furnace too cold • Please wait until the
alarm furnace has reached the
right temperature
E1830 Cooler deviation band Cooler temperature too hot • Please wait until the
alarm carrier gas flow has
reached the right
temperature
E1833 Pressure is high Pressure > 600 mBar, fur- • Demount the reactor foot
nace or filter blocked and check the end of the
reactor
E1835 Carrier gas flow devia- Carrier gas flow is low • Find leakage!
tion > -5%

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Table 19: Status identification (control state)

Status Description Possible Cause Action

E1836 TC carrier gas flow Carrier gas flow is low • Find leakage!
deviation > -5%
E1837 TIC carrier gas flow Carrier gas flow is low • Find leakage!
deviation > -5%
E1841 Injection error stream 1 Injection of air, no sample • Check sample supply
E1842 Injection error stream 2 Injection of air, no sample • Check sample supply
E1843 Injection error stream 3 Injection of air, no sample • Check sample supply
E1844 Injection error stream 4 Injection of air, no sample • Check sample supply
E1845 Injection error stream 5 Injection of air, no sample • Check sample supply
E1846 Injection error stream 6 Injection of air, no sample • Check sample supply
E1850 - Limit exceeded detector • Contact Support
(Chapter 15 on page 257)
E1851 Zero signal NDIR1 out CO2-detector 1 defective or • Check detector cable and
of range soda lime pellets exhausted change soda lime pellets
E1852 Zero signal NDIR2 out CO2-detector 2 defective or • Check detector cable and
of range soda lime pellets exhausted change soda lime pellets
E1853 Zero signal EC cell out NO-detector defective • Check detector cable
of range
E1854 Zero signal oxygen O2-detector defective or the • Check Zirox detector
detector out of range Permeation Unit has a leak cable, if necessary adjust
the signal
E1950 Sample missing (IN 05 Sample is not available • Check sample supply
digital input)
E1960 Reagents missing (IN Reagents are not available • Check/Prepare reagents
06 digital input)
E2128 Error when opening the Furnace valve defective • Contact Support
furnace valve (Chapter 15 on page 257)
E2136 Error at the time of clos- Furnace valve defective • Contact Support
ing the furnace valve (Chapter 15 on page 257)
E2188 Deviation of the dosing Motor defective • Contact Support
volume (Chapter 15 on page 257)
E2234 - Needle sensor defective • Contact Support
(Chapter 15 on page 257)
Positioning Error
E2010 Measurement stopped Positioning error • Check the xy-axis: is
due to repetitive posi- there an obstruction?
tion errors Timing belt and
mechanical wear? Check
the permeability of the
seal of the needle guide
E2022 Measurment mode: Positioning error • Check the xy-axis: is
fault with the approach there an obstruction?
to the Y sensors Timing belt and
mechanical wear?
E2024 Fault with vertical Y Positioning error • Check the xy-axis: is
there an obstruction?
Timing belt and
mechanical wear?

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Table 19: Status identification (control state)

Status Description Possible Cause Action

E2026 Measurement mode: Positioning error • Check the xy-axis: is
fault in position of the X there an obstruction?
sensors Timing belt and
mechanical wear? Check
the permeability of the
seal of the needle guide
E2028 Measurement mode: Positioning error • Check the xy-axis: is
fault with X position there an obstruction?
(horizontal) Timing belt and
mechanical wear?
E2030 Furnace close error Furnace valve does not • Check the xy-axis: is
close there an obstruction?
Timing belt and
mechanical wear?
E2044 Measurement mode: Positioning error • Check the xy-axis: is
fault with Y (horizontal) there an obstruction?
Timing belt and
mechanical wear? Check
the permeability of the
seal of the needle guide
E2045 Measurement mode: Positioning error • Check the xy-axis: is
fault with X sensor there an obstruction?
Timing belt and
mechanical wear? Check
the permeability of the
seal of the needle guide
E2046 Measurement mode: Positioning error • Check the xy-axis: is
fault Y sensor there an obstruction?
Timing belt and
mechanical wear? Check
the permeability of the
seal of the needle guide
E2049 Measurement mode - Positioning error • Problem with the syringe
rinsing - fault with Z or the motor of the
sensor syringe

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7.5 Level III: Only For Trained Users

In addition to the two operating levels mentioned in the previous chapters, there is a further operating
level. This third level is only accessible with a specific USB stick.

Furthermore, some parameters in level II are also accessible for level III users:
• measurement parameters
• pc setting
• calibration result
• active calibration

7.5.1 Access rights

Only a skilled user should access level III or make changes in this level. In order to gain a USB stick with
access authorization for this level, the user should have completed a technical training at LAR. To do so
please contact your local partner or the Technical Support of LAR (Chapter 15 on page 257).

7.5.2 Operating level III

Fig. 73: Operating Level III

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7.5.2.1 Level II: measurement parameters

7.5.2.1.1 Percentage with multiple determinations

If the parameter “multiple determinations“ is set (>0), the parameter “measurement replicates“ will be de-
cided to take or not. If the value is higher than the measured value, the sample will be measured again,
like the value in the parameter “measurement replicates“.
If the parameter is active (>0), the level II user can see this parameter as well but the level II user can
not change this four parameters.

Fig. 74: Measurement parameters in level II as a level III user

Example:
• Considered the parameter “multiple determinations“
“Measurement replicates“ is set on 2 and the parameter “multiple determinations“ is set on 10%:
The mains when the value is higher then 10% as the value before (100ppm to 111ppm), the parameter
n“Measurement replicates“ will be considered. That means that a second measurement from the same
sample will be taken.

• Excluded the parameter “multiple determinations“

“Measurement replicates“ is set on 2 and the parameter “multiple determinations“ is set on 10%:
The mains when the value is lower then 10% as the value before (100ppm to 109ppm), the parameter
“Measurement replicates“ will be excluded. That means no second measurement will be measured. A
new sample will pump in the sample vessel and a new sample will be taken.

i • If the parameter “multiple determinations“ is set on to 0, the parameter

“measurement replicates“ will be taken.
Notice

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Fig. 75: Measurement parameter screen (if the level III user set the parameter „multiple determina-
tions“ > 0)

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7.5.2.2 Level II: PC setting

On this screen, in level II, the user (in level III) can change two further parameters that the level II user
cannot change:
• Activate or deactivate the password for level II
• Drag and drop function

Fig. 76: PC setting in level II as a level III user

7.5.2.2.1 Activate and deactivate the password

The level III user has the possibility to activate and deactivate the password. The default is activated. If
the status is changed, the adjustment must be saved with the “floppy disc“. If the password is deactiva-
ted, the entrance to level II is then only possible with the access stick. The default password is: lar.

7.5.2.2.2 Drag and Drop

On this screen, it is also possible to turn the drag and drop function on or off. The function enables icons
(buttons) to be moved from location to location (higher level to lower levels).

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7.5.2.3 Calibration result

This screen is in level II. However, only level III user can change and modify the result (intercept and
slope).

Fig. 77: Calibration result in level II as a user III

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7.5.2.4 Active calibration

This screen is in level II. However, only level III user can change and modify the result.

Fig. 78: Active calibration in level II as a user III

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7.5.2.5 CAN selftest

The analyser has a so called CAN circuit diagram. All parts of the analyser are registered here and every
part has its own ID. The analyser tests this plan independently and shows the results here. So if a node
is missing its name, ID and additionally the words „not found“ will be shown on this screen.

Fig. 79: CAN selftest

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7.5.2.6 Hardware info

This screen shows information about the hardware of the analyser:
• PC info
• Sensors
• Nodes
• Info of the sensors
Also the voltage of the analog outputs for the parts of the analyser is shown.

Fig. 80: Hardware info

Fig. 81: Hardware info - PC info and sensors

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Fig. 82: Hardware info - Nodes and info of the sensors

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7.5.2.7 Digital IN 1 and 2

In these two screens, the states of the digital inputs 1 and 2 are shown.

Fig. 83: Digital IN 1

Fig. 84: Digital IN 2

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7.5.2.8 Digital OUT 1 and 2

In these two screens, the state of the digital outputs 1 and 2 (on/off) can be defined.

Fig. 85: Digital OUT 1

Fig. 86: Digital OUT 2

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7.5.2.9 Calibration in level III

For the level III user, there is also the possibility to run a calibration. There is one screen in this level for
the task "calibration":
• Service Calibration
• Calibration carry out
Before starting a calibration, the calibration solution has to be provided and settings have to be selected
on the screen "calibration carry out" (level II). The concentrations and the preparation of the standard
solutions are described in Chapter 6.2 from page 58. Depending on the adjusted measurement method,
a single standard or a mixed standard solution may be used.
On the screen “calibration result“ (level II), the measurement results of the individual calibration points
are displayed.
The calibration can be cancelled by using the red “offline” button.

7.5.2.9.1 Service calibration

The outliers are marked yellow automatically and are not taken into calculation. The outliers can be taken
into calculation manually by activating their check box. The check boxes in the first column activate/
deactivate all other check boxes in that particular row.

Fig. 87: Service Calibration

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Procedure of a one point calibration for one stream:

• Preparation of the calibration solution (Chapter 6.2 from page 58) and placement of the calibration
vessel.
• How many solutions are to be measured? On the screen “calibration carry out“, in level II, a selection
box for the calibration solution is present. Choose the number of calibration solutions: 1.
• On the screen „service calibration“, level III, the chosen number of the solution will be shown.
• Enter the max. CV in the input field.
• Click on the solution and the stream will appear.
• Click on the stream and the five repetitions (signals) will appear.
• Between solution and stream, there are input fields for the concentration of the solution. Enter all the
solution ingredients in the table:
• Double click on the input field. A number field and keyboard will appear. Please key in the suitable
concentration. All concentrations can be configurable.
• To accept the new calibration concentration, save them with the “floppy disc“ icon (Chapter 7.3.8 on
page 109).
• Activate the check box for the stream and the solution.
• Now the calibration can be started with the “start calibration“ button.
• After the calibration, the five repetitions (raw value of the measurement) and the average value will
be shown on this screen.
• All check boxes on this screen are activated for the measured solution and stream. The outliers are
marked yellow automatically and are not taken into calculation
• If you see an outlier, it is possible to take it out of the calculation by deactivating the outlier‘s check
box.
• After the calibration and the manual outlier correction, the calibration result will be displayed on the
screen “calibration result“ in level II.
• Go to the service calibration result screen and activate the calibration with the button “activate
calibration result“ (Chapter 7.2.3.2 on page 78).

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Procedure for a multi point calibration (three solution) for one stream:
• Preparation of the calibration solutions (Chapter 6.2 from page 58) and placement of the calibration
vessel.
• How many solutions should be measured? On the screen “calibration carry out“, level II, a selection
box for the calibration solution is present. Choose the number of calibration solutions: 3.
• Enter the max. CV in the input field.
• On the screen „service calibration“, level III, the chosen number of solutions will be shown.
• Click on the solutions and the stream will appear.
• Click on the streams and the five repetitions (signals) will appear.
• Between solution and stream, there are input fields for the concentration of the solution. Enter all
ingredients of the solution in the table:
• Double click on the input field. A number field and keyboard will appear. Please key in the suitable
concentration. All concentrations for each calibration can be set.
• To accept the new calibration concentrations, save them with the “floppy disc“ icon (Chapter 7.3.8 on
page 109).
• Activate the check box for the stream and then all solutions that you want to measure.
• Now, the calibration can be started with the “start calibration“ button.
• When the first solution has be measured, a stop message appears (Fig. 44, page 76). The stop
message shows the next calibration solution, the vessel position of the calibration solution and the
calibration solution‘s concentration.
• If the second solution is put into position, press the green arrow of the stop message.
• The stop message will come up one more time.
• After the three calibrations have been carried out, each of the five repetitions (raw value of the
measurement) and the average values for all solutions will be shown.
• All check boxes on this screen are activated for the measured solution and stream. The outliers are
marked yellow automatically and are not taken into calculation.
• If you see an outlier, it is possible to take it out of the calculation by deactivating the outlier‘s check
box.
• After the calibration and the manual outlier correction, the calibration result will be displayed on the
screen “calibration result“.
• Go to the service calibration result screen and activate the calibration with the button „activate
calibration result“ (Chapter 7.2.3.2 on page 78).

• If a multi point calibration is carried out, the calibration solution is measured one

i after another.
• On the screen „service calibration“, the first check box on the left is for the whole
Notice line. Deactivating the first check box means that all parameters (check boxes) for
that line will be deactivated.

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7.5.2.10 Service parameters

On this screen, parameters concerning the carrier gas flow can be seen and defined.

The following parameters can be set by a level III user:

• Measurement even with an incorrect airflow

The following parameters can only be seen:

• Calibration value for carrier gas stream
• Allowable deviation
• Measurement with an incorrect airflow
• Threshold for carrier gas humidity
• Calibrate gas flow

Fig. 88: Service parameters

7.5.2.10.1 Calibration values for carrier gas stream

After a calibration, the values for the carrier gas flow are shown here. If the actual value of a measure-
ment does not correspond with the calibration value, the measurement is terminated and the error needs
to be rectified before a new measurement can be started.

7.5.2.10.2 Allowed deviation

Here, the allowed deviation of the carrier gas flow is set. If the deviation is less than the set percentage,
then the measurement will still be carried out.

7.5.2.10.3 Measurement even if airflow is incorrect

Here, you can choose between YES and NO. If YES is chosen, the measurement will also be carried out
even if the deviation of the carrier gas flow is higher than the set value.

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7.5.2.10.4 Threshold value of the carrier gas humidity

The threshold value for the humidity of the carrier gas is defined here. If the actual value does not cor-
respond to the set value, no measurement can be carried out until the error is evened out. On the “status
screen“ for the two carrier gas sensors, a set point value is shown. This set point value is generated from
the “calibration value for the carrier gas flow“. The values that are created during a calibration are shown
automatically.

7.5.2.10.5 Calibrating gas flow

Here, the carrier gas in- and outputs can be seen.

7.5.2.10.6 TIC-Port with motor

For the TOC and/or TIC determination this option can be ordered. A new sample vessel with a motor is
needed.
If the option is ordered the parameter is adjusted to “Yes“. In the screen Digital OUT2 (Chapter 7.5.2.8
on page 124) the TIC-Port can be manually switched (off/on). The status (off/on) from the TIC-Port can
be seen in screen Digital IN2 (Chapter 7.5.2.7 on page 123).

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7.5.2.11 Name and Unit

In this screen the adjustment for parameter and channel are seen. Also a correlation factor can changed
for each channel. Setting or changing from the parameter "correlation factor" are recorded in the log
book.

Fig. 89: Name and Unit - example

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8 Care and Maintenance

Only minor effort is required to service and maintain the QuickCOD®ultra. This section shows you the best
way to look after your analyser to guarantee trouble-free operation. The documentation of maintenance
and service work is a precondition for any warranty and guarantee claims, and also represents a valuab-
le aid in locating resolutions when malfunctions occur (Chapter 10 from page 221).

• The scope of analyser maintenance and care work depends on the application.
i • All maintenance and care action, and intervals, pertain to the most demanding of
applications and are to be understood as recommendations from LAR.
Notice

Care and Maintenance:

• Care actions are dependent on application and is understood to be a recommendation from LAR.
Care actions require about 30 minutes per week.

• Maintenance actions include the swapping out of wearing parts and consumables. Maintenance
actions require 5 to 10 minutes per week.

• After performing care and maintenance actions, some function tests must always be carried out to
check the analyser status (Chapter 8.8 from page 169).

• If you have any questions to care and/or maintenance actions, please contact your

i local partner or the Technical Support of LAR (Chapter 15 on page 257).

• As part of the customer support program, the Technical Support of LAR offers
Notice individually configurable maintenance agreements and equipment-specific
training in which you can broaden your expertise. More information is available
from www.lar.com.

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8.1 Overview of regular Care and Maintenance Actions LAR | PROCESS ANALYSERS AG

8.1 Overview of regular Care and Maintenance Actions

The following maintenance schedule provides an overview of recommended and regular actions for car-
ing and maintaining your analyser. Visual inspections are used to check the applicative need for care
and maintenance actions.

Table 20: Recommended, regular Care and Maintenance Actions

Kind of
Interval Action Page Reference
Action
Renew calibration standard Care Chapter 8.5.20 on page 150
1 Week
Replace silicone seal for TIC-Port Maintenance Chapter 8.7.15 on page 165
Clean needle guide seal Care Chapter 8.5.21 on page 150
Replace needle guide seal Maintenance Chapter 8.7.16 on page 166
1 Month
Replace silicon seals for glass
Maintenance Chapter 8.7.17 on page 166
components
Check the furnace system Care Chapter 8.5.22 on page 151
Check the gas cooling pipes Care Chapter 8.5.23 on page 152
3 Months Clean and oil injection port Care Chapter 8.5.24 on page 153
Move pump tubes Care Chapter 8.5.25 on page 154
Replace seal for reactor foot Maintenance Chapter 8.7.18 on page 167
Check the injection port Care Chapter 8.5.27 on page 155
6 Months Chapter 8.7.19 on page 168
Replace pump tubes Maintenance and
Chapter 8.7.20 on page 168
1 Year Replace gas filter Maintenance Chapter 8.7.21 on page 168

i • If you have any question, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

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8.2 Visual Inspection

Performing regular visual inspections is recommended to guarantee trouble-free operation of your ana-
lyser. Use the following log for this:

Table 21: Visual Inspection Log

Interval Visual Inspection Criteria OK Action

 Check soda lime
Zero Signal • 0 - 0.1 FSR 
 Contact support
• Carrier Gas IN / OUT:  Check connections
Carrier Gas 
approx. 20 l/h  Contact support
• no air bubbles in the tube
Injection System   Rinsing necessary
or glass syringe
• no contamination  Cleaning necessary
1 Week Injection Needle 
• smooth surface  Replace needle
Glass Components • no contamination   Cleaning necessary
• fill level > 1 litre  Fill canister
Canisters and Supply
Tubes
• no contamination   Clean canister
• normal elasticity  Replace tube
• no contamination  Replace tube
Drain and Inlet Tubes 
• normal elasticity _____________________
• no contamination  Cleaning necessary
Injection Tube 
• normal elasticity  Replace tube
TIC Stripping Vessel • no contamination   Cleaning necessary
• no contamination  Cleaning necessary
Slide Rails
• optimal grease state   Grease necessary
(XY-System)
• mechanical play  Contact support
• no moisture  Cleaning necessary
Tube Cassette Pump • rolls easily movable  Put forth tubes

and Pump Tubes • no contamination  Replace tubes
3 Months • normal elasticity  Contact support
Sample Pump and • no contamination  Cleaning necessary

Pump Tubes • rolls easily movable  Contact support
• no contamination  Cleaning necessary
Viton Tubes 
• normal elasticity  Replace tubes
Filter Mats • no discolouration   Replace filter mats
• zinc is > 1/3 shiny  Replace filling material
Acid Trap 
• brass wool > 1/3 yellow  Replace acid trap
• no moisture  Replace filling material
Quartz Wool Filter 
• no discolouration  Replace filter

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question to visual inspections, please contact your local partner
or the Technical Support of LAR (Chapter 15 on page 257).
Notice

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8.3 Perform Visual Inspection

Procedure for visual inspections:

• Take a log for visual inspections (Chapter 13.2 on page 241).

• Follow the instructions below for visual inspections of individual components.
• Carry out care and/or maintenance actions when test criteria are not met, and document them in the
care and/or maintenance log (Chapter 8.4 on page 141 and/or Chapter 8.6 on page 156).
• After the check and any care and/or maintenance actions, conclude the documentation of the log(s).

• If care and/or maintenance action is undertaken, please document it in the care

! and/or maintenance log because careful documentation is a precondition for any
guarantee and warranty claims.
Caution • Please note that, following all visual inspections, care and/or maintenance action,
some tests need to be performed before measurements can start again
(Chapter 8.8 from page 169).

• In all cases, turn the analyser in offline mode by pressing the red button to avoid
x injury by e.g. moving parts.
Danger

8.3.1 Zero Signal (weekly)

• Check in the display “Status Screen” (Chapter 7.2.10 on page 87) whether the zero signal is between
0 and 0.1 FSR.
• If the signal is not within the range permitted, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

8.3.2 Carrier Gas (weekly)

• Check from the “Status Screen” display (Chapter 7.2.10 on page 87) using the carrier gas volume
flow at the carrier gas inlet (IN) and carrier gas outlet (OUT) that the carrier gas is being transported
through the system at a rate of approx. 20 l/h (± 5 l/h).
• If too high a difference is ascertained, check the individual attachments (tube connections, etc.) or
please contact your local partner or the Technical Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

8.3.3 Injection System (weekly)

• Ensure that the analyser is in offline mode.

• Check the injection system for air bubbles in the tube or glass syringe.
• Rinse the injection system if there are air bubbles in the tube or glass syringe (Chapter 8.5.1 on
page 142).
• Once the test criterion is met, proceed with the next step.

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8.3.4 Injection Needle (weekly)

• Ensure that the analyser is in offline mode.

• Check the cleanliness and smooth surface of the injection needle.
• If contamination is ascertained, the injection needle must be cleaned (Chapter 8.5.19 on page 150).
• If higher levels of deposits or a roughened surface are/is ascertained, the injection needle must be
replaced (Chapter 8.7.14 on page 165).
• Once all test criteria are met, proceed with the next step.

8.3.5 Glass Components (weekly)

• Check the cleanliness of all vessels.

• If contamination is ascertained, the glass components must be cleaned (Chapter 8.5.2 on page 142).
• Once the test criterion is met, proceed with the next step.

8.3.6 Canister and Supply Tubes (weekly)

• Check the cleanliness of the canisters and whether the fill levels of the canisters are > 1 litre.
• If too low a fill level is ascertained, the canisters must be filled (Chapter 8.5.3 on page 142).
• If contamination is ascertained, the canisters must be cleaned (Chapter 8.5.4 on page 143).
• Check the cleanliness and elasticity of the supply tubes.
• If slight contamination is ascertained, the tubes must be cleaned (Chapter 8.5.5 on page 143).
• If a higher level of contamination or damage is ascertained, the supply tube must be replaced
(Chapter 8.7.1 on page 157).
• Once all test criteria are met, proceed with the next step.

8.3.7 Inlet and Drain Tubes (weekly)

• Check the cleanliness and elasticity of the inlet and drain tubes.
• If slight contamination is ascertained, cleaning is necessary (Chapter 8.5.6 on page 143).
• If a higher level of contamination or damage is ascertained, the tube must be replaced (Chapter 8.7.2
on page 157).
• Once all test criteria are met, proceed with the next step.

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8.3.8 Injection Tube (3 monthly)

• Ensure that the analyser is in offline mode.

• Check the cleanliness and elasticity of the injection tube between the solenoid valve and injection
needle.
• If slight contamination is ascertained, the injection tube must be cleaned (Chapter 8.5.9 on
page 144).
• If a higher level of contamination or damage is ascertained, the tube must be replaced (Chapter 8.7.7
on page 161).
• Once all test criteria are met, proceed with the next step.

Fig. 90: Injection Unit

i • At the bottom of this figure a cross-section shows how to fit the tubes between the
rinsing water canister and the injection needle.
Notice

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8.3.9 TIC Stripping Vessel (3 monthly)

• This instruction applies only to analysers that determine the COD via the CODi

i Method using the TOC-Difference Method. When using other methods, the TIC
Reactor is not installed in the analyser.
Notice • To shorten maintenance and care times, it is recommended to keep every single
glass component in stock.

• Check the cleanliness of the TIC stripping vessel.

• If contamination is ascertained, cleaning is necessary (Chapter 8.5.11 on page 146).
• Once the test criterion is met, proceed with the next step.

Legend:
1) TIC Reactor
2) TIC Port
3) TIC Stripping Vessel
Fig. 91: TIC Reactor

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8.3.10 Running Rails (XY-System) (3 monthly)

• Ensure that the analyser is in offline mode.

• Check the cleanliness and optimal grease state of the XY system.
• If contamination is ascertained, the running rail must be cleaned (Chapter 8.5.13 on page 147).
• If the running rail is too dry, it must be greased (Chapter 8.5.14 on page 147).
• Once all test criteria are met, proceed with the next step.

8.3.11 Tube Cassette Pump and Pump Tubes (3 monthly)

• Ensure that the analyser is in offline mode.

• Take the cassettes from the pump.
• Take the tubes from the pump cassettes.
• We recommend relocating or replacing the tubes removed (Chapter 8.5.25 on page 154 or
Chapter 8.7.19 on page 168)
• Check the cleanliness, dryness and ease of movement of the pump, pump cassettes and rollers.
• If contamination is ascertained, the tube cassette pump must be cleaned (Chapter 8.5.15 on
page 148).
• If noticeable moisture and/or difficult movement are/is ascertained, please contact your local
partner or the Technical Support of LAR (Chapter 15 on page 257).
• Once all test criteria are met, fix the tubes into the pump cassette, apply a slight amount of oil to the
mounted surface, insert the pump cassettes into the pump and continue with the next step.

8.3.12 Sample Pump and Pump Tubes (3 monthly)

• Ensure that the analyser is in offline mode.

• Take the tubes from the pumps.
• Check the cleanliness and elasticity of the tubes.
• If contamination or damage is ascertained, the pump tube must be replaced (Chapter 8.7.20 on
page 168).
• Check the cleanliness, dryness and ease of movement of the pump and rollers.
• If contamination is ascertained, the sample pump must be cleaned (Chapter 8.5.16 on page 148).
• If noticeable moisture and/or difficult movement are/is ascertained, please contact your local
partner or the Technical Support of LAR (Chapter 15 on page 257).
• Once all test criteria are met, fix the tubes into the pumps and continue with the next step.

8.3.13 Viton Tubes (3 monthly)

• Check the cleanliness and elasticity of the black viton tubes from the gas cooler unit.
• If slight contamination is ascertained, cleaning is necessary (Chapter 8.5.18 on page 149).
• If a higher level of contamination or damage is ascertained, the tube must be replaced (Chapter 8.7.8
on page 161).
• Once all test criteria are met, proceed with the next step.

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8.3.14 Filter Mats (3 monthly)

• Open the ventilation grid on the left side of the analyser by levering out the ventilation flap (Fig. 92,
page 139).
• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Check the white colour of the filter mats.
• If strong discolouration is ascertained, the filter mat must be replaced (Chapter 8.7.13 on page 164).
• Once the test criterion is met, close the ventilation grids and proceed with the next step.

Fig. 92: Checking the Filter Mats on the left side of the Analyser

Fig. 93: Checking the Filter Mats on the bottom side of the Analyser

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8.3.15 Acid Trap (3 monthly)

• Check that more than 1/3 of the brass wool is light yellow.
• Check that more than 1/3 of the zinc is shiny.
• If strong discolouration is ascertained, the acid trap or its filling must be replaced (Chapter 8.7.9 on
page 162 or Chapter 8.7.10 on page 162)
• Once all test criteria are met, proceed with the next step.

8.3.16 Quartz Wool Filter (3 monthly)

• Check the quartz wool for dryness and white colour.

• If strong discolouration or moisture is ascertained, the quartz wool filter or its filling must be replaced
(Chapter 8.7.11 on page 163 or Chapter 8.7.12 on page 163)
• Once all test criteria are met, proceed with the next step.

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8.4 Care Actions

Use the following care log for the documentation of care actions:

Table 22: Care Log

Interval Action Done Comment

Rinse the Injection System 
Clean Glass Components 
Fill Canisters 
Clean Canisters 
Clean Supply Tubes 
Clean Inlet and Drain Tubes 
Clean Teflon Tube (Reactor Foot) 
Clean Reactor Foot 
Clean Injection Tube 
If Clean Reactor Pipe 
necessary
Clean TIC Stripping Vessel 
Clean Gas Cooling Pipe 
Clean Running Rails (XY-System) 
Grease Running Rails (XY-System) 
Clean Tube Cassette Pump and Pump

Cassettes
Clean Sample Pump 
Adjust Sample Pump 
Clean Viton Tube 
Clean Injection Needle 
1 Week Renew Calibration Standard 
1 Month Clean Needle Guide (Injection Port) 
Check the Furnace System 
Check the Gas Cooling Pipes 
3 Months
Clean and oil the Injection Port 
Move Pump Tubes (Tube Cassette Pump) 
Check the mechanical backlash of the XY-
System

6 Months Check the Injection Port 

Date: Signature:

i • A corresponding copy of the log is in Chapter 13 from page 239.

• Careful documentation is a precondition for any guarantee and warranty claims.
Notice

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8.5 Perform Care Actions LAR | PROCESS ANALYSERS AG

8.5 Perform Care Actions

If test criteria are not met during visual inspections, service and maintenance actions must be performed.
Also, some actions must be performed at certain intervals to guarantee trouble-free operation of the an-
alyser. Below are the instructions for care work.

Procedure for care work:

• Always stop measurement mode before carrying out care work.

• Take a care log (if necessary copy from Chapter 13.3 on page 242).
• Follow the instructions below for care work for individual components.
• Document in the care log the care actions taken.
• Take maintenance actions as required.
• Conclude documentation of the log once the care actions are performed.
• Perform the function tests (Chapter 8.8 from page 169).
• Once the care actions are concluded, start measurement mode.

• In all cases, turn the analyser in offline mode by pressing the red button to avoid
x injury by e.g. moving parts.
Danger

8.5.1 Rinse the Injection System

Precondition: - Air bubbles in the tube or glass syringe.

• Go to the display “Service actions” in the user interface (Chapter 7.2.11 from page 88).
• Press there the “Rinse injection system” button.
• Allow the rinse to run its course.

8.5.2 Clean Glass Components

Precondition: - Glass components are contaminated.

• Unscrew the covers of the glass components to be cleaned.

• If the level of contamination is low, the glass components can be cleaned with deionised water using
a bottle brush.
• Please follow the instructions in Chapter 6.1.5 on page 57 if contamination levels are higher.
• Screw the covers back onto the glass components.

8.5.3 Fill Canisters

Precondition: - Fill level of the canister is < 1 litre.

• Screw the covers back onto the glass components.

• Prepare the right solution for your measurement method (Chapter 6.1 from page 55).
• Fill the canister with the new solution.
• Put the canister back into the reagent cabinet or circulation air conditioner (optional).
• Insert the tube back into the canister down to the base.

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8.5.4 Clean Canisters

Precondition: - Canister is contaminated.

• Pull the tube from the canister.

• Dispose of the remaining solution in the canister in an environmentally responsible way.
• Fill commercially available cleaning or rinsing agent into the canister with 2 litres of warm water.
• Keep the canister (with water in it) closed for about 1 minute.
• Use a bottle brush if the contamination level is high.
• Drain the canister.
• Rinse out the canister using at least 1 litre of deionised water.
• Prepare the right solution for your measurement method (Chapter 6.1 from page 55).
• Fill the canister with the new solution.
• Put the canister back into the reagent cabinet or circulation air conditioner (optional).
• Insert the tube back into the canister down to the bottom.

8.5.5 Clean Supply Tubes

Precondition: - Supply tube is slightly contaminated.

• Pull the tube for cleaning from the canister.

• Undo the tube connector of the tube to be replaced in the analyser.
• Pull the tube to be cleaned out of the analyser and from the reagent cabinet or circulation air
conditioner.
• Clean the tube.
• Guide the cleaned tube into the analyser and into the reagent cabinet or circulation air conditioner.
• Attach the tube at the tube connector in the analyser.
• Insert the new tube back into the canister down to the bottom.

8.5.6 Clean Inlet and Drain Tubes

Precondition: - Inlet and/or drain tube are/is slightly contaminated.

• Undo the tube connectors of the tube to be cleaned.

• Pull the tube out of the analyser.
• Clean the tube
• Guide the cleaned tube into the analyser.
• Secure the tube at the tube connectors.

8.5.7 Clean Teflon Tube (Reactor Foot)

Precondition: - Teflon tube is slightly contaminated.

• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it. Now the reactor foot is visible.
• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Clean the tube.
• Fit the tube back on the reactor seat.

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8.5.8 Clean Reactor Foot

Precondition: - Reactor foot is contaminated.

• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it. Now the reactor foot is visible.
• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Carefully pull the reactor foot from the reactor pipe end.
• Take all individual parts of the reactor foot (reactor foot seating, screwed insert, glass insert and
reactor foot seal).
• Use a paper towel and water to clean the reactor foot seating and glass insert.
• Use a pipe cleaner and water to clean the screwed insert.
• Reassemble all the individual parts of the reactor foot.

Fig. 94: Clean reactor foot seating, screwed insert and glass insert (Example: high salt reactor foot)

8.5.9 Clean Injection Tube

Precondition: - Injection tube is contaminated.

• Take the injection tube from the injection needle and the solenoid valve.
• Clean the injection tube using a pipe cleaner or single-use syringe.
• Refit the injection tube between the injection needle and solenoid valve.

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8.5.10 Clean Reactor Pipe

Precondition: - Reactor pipe is contaminated.

• Use heat-resistant gloves for cleaning!

• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it. Now the reactor foot is visible.
• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Carefully pull the reactor foot from the reactor pipe end.
• Use a 3.5 mm drill bit to carefully drill into the reactor pipe by hand [note: do not use a cordless or
power drill].
• Then use if required a bigger drill bit of maximum size 5.5 mm.
• Manually drill into the reactor pipe all the way by hand to remove the deposits.
• A drill bit is not necessary when the high salt option is used. Remove the deposits using a large
screwdriver.

Legend:
1) Reactor pipe underneath the analyser
2) Drill bit
3) Turn the drill bit manually
Fig. 95: Manual cleaning of the reactor pipe with a drill bit

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8.5.11 Clean TIC Stripping Vessel

i
• This instruction applies only to analysers that determine the COD via the CODi
Method using the TOC-Difference Method. When using other methods, the TIC
Reactor is not installed in the analyser.
Notice

Precondition: - TIC stripping vessel is contaminated.

• Take the screw cap on the TIC port.

• Suck up the acid using a syringe.
• Take all tube connectors for the TIC stripping vessel.
• Take the TIC stripping vessel from the pipe clamps.
• Place the TIC stripping vessel in an ultrasonic bath for 10 minutes for cleaning.
• Carefully rinse out the TIC stripping vessel with deionised water to remove all residues from the frit.
• Refit the TIC stripping vessel into the pipe clamps.
• Reconnect all tube connectors for the TIC stripping vessel.
• Screw the screw cap back onto the TIC stripping vessel.

8.5.12 Clean Gas Cooling Pipe

Precondition: - Gas Cooling Pipe is contaminated

• Unscrew the 3 or 6 connection pieces with the tube connectors.

• Carefully pull the relevant gas cooling pipe upwards out of the cooler guide.
• For cleaning, use a laboratory bottle filled with deionised water, or a single-use syringe, and as
required a small bottle brush, a pipe cleaner or a moist cotton cleaning cloth.
• Use a soft paper towel to clean the surface of the gas cooling pipe.
• Rinse the gas cooling pipe from inside by gradually spraying deionised water into the openings of the
cooling tube.
• If contamination levels are high, glass cleaning agents can also be used (however the cooling tube
must be rinsed out afterwards with at least 200 ml of deionised water).
• Use a soft paper towel to dry the surfaces of the gas cooling Pipe.
• Dry the side tube connectors of the gas cooling pipe using a pipe cleaner.
• Coat the skin surfaces of the gas cooling pipe with silicone-free, heat-conductive paste.
• Use a soft paper towel to clean the seats of the cooler.
• Push the gas cooling pipe back into the seats of the cooler.
• Connect the tubes correctly back to the tube connectors of the gas cooling pipe.

• Do not pull the gas cooling pipe out by the weld-on tube connector because it could
! break.
• The seats of the gas cooler may not be cleaned with sharp objects because
Caution otherwise the transition area from the cooler to the cooling tube could be damaged.
• Ensure the tubes are connected correctly because incorrect measurement results
can entail if they are not.

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8.5.13 Clean Running Rails (XY-System)

Precondition: - Running rails are contaminated.

• Use a lint-free paper towel to remove decontamination from the XY running rail.

8.5.14 Grease Running Rails (XY-System)

Precondition: - Running rails are dry.

• Ensure that the mains supply is disconnected.

• Open the analyser door.
• Position a grease gun at the front grease nipple on the guide bearing.
• Press grease into the XY system through the grease nipple.
• Close the analyser door.
• Open the rear part of the analyser housing.
• Take the plug door to the compartment part.
• Position a grease gun at the rear grease nipple on the guide bearing.
• Press grease into the XY system through the grease nipple.
• Insert the plug door.
• Close the rear part of the housing.

! • Please only use special grease from LAR for grease.

Caution

1
2

Legend:
1) X-Axis (horizontal)
2) Front grease nipple on the guide bearing
3) Y-Axis (vertical)
Fig. 96: Grease Nipple

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8.5.15 CleanTube Cassette Pump and Pump Cassettes

Precondition: - Tube cassette pump and/or pump cassettes are contaminated.

• Take the pump cassettes from the pump.

• Take the tubes from the pump cassettes.
• Clean the pump and the pump cassettes.
• Fit the tubes into the pump cassettes.
• Insert the pump cassettes into the pump.

8.5.16 Clean Sample Pump

Precondition: - Sample pump is contaminated.

• Open the pump head.

• Take the tube from the sample pump.
• Use a paper cloth and a little water to clean the pump rollers.
• Whilst cleaning the rollers, rotate them by hand so that everywhere can be cleaned.
• Insert the pump tube back in.
• Close the pump head.

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8.5.17 Adjust Sample Pump

Precondition: - Sample pump not adjusted correctly.

• Open the pump head all the way (the cover must be vertical).
• Turn the adjustment wheel on both sides (left and right) so that the setting value is 3.2 or 4.8
depending on the tube used.

Tube diameter

Wall thickness

Adjustment wheel

Fig. 97: Setting of the sample pump

• The adjustment of the pump head is dependent on the application and is based on
! the tube diameter.
• Different adjustments can cause poor pump delivery rate and incorrect results.
Caution

8.5.18 Clean Viton Tube

Precondition: - Viton tube is slightly contaminated.

• Undo the tube connectors of the tube to be cleaned.

• Use compressed air and a pipe cleaner to clean the viton tube.
• Reattach the tube at the tube connectors.

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8.5.19 Clean Injection Needle

Precondition: - Injection needle is slightly contaminated.

• Use distilled water to moisten a clean cloth.

• Use a cloth to clean the injection needle from outside.

8.5.20 Renew Calibration Standard

Precondition: - Calibration standard is empty/is older than one week.

Recommendation: - Renew calibration standard after one week.

• Follow the instructions in Chapter 6.2 from page 58 to make a calibration standard.

8.5.21 Clean Needle Guide (Injection Port)

Recommendation: - Clean needle guide after 1 month.

5 10
6
7

11
9
12

Legend: 4) Needle guide seal 9) Holes for M3x45 screws

1) Union nut 5) Lower needle guide 10) Injection port
2) Attachment for upper needle 6) Washer 11) Cock plug (PEEK)
guide 7) Cock plug seal 12) Spacer sleeves
3) Upper needle guide 8) Union nut for cock plug
Fig. 98: Injection Valve (Injection Port)

• Unscrew the union nut and the attachment of the needle guides (No. 1 & 2 in Fig. 98, page 150).
• Use a moist paper towel and rinsing water (Chapter 6.1.2 on page 56) to clean the needle guides
and all individual parts.
• If the level of contamination is high, first clean the needle guides mechanically and then in a bath
(with 1% phosphoric acid).
• After the cleaning process, refit all individual parts for the complete injection port.
• Screw the needle guides and union nut back onto the injection port.

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8.5.22 Check the Furnace System

Recommendation: - Check the furnace system every 3 months.

• Allow the furnace to fully cool (for 2 hours).

! • The temperature of the reactor pipe is still 400°C to 500°C one hour after the
furnace is switched off.
Caution
• Wear heat-resistant gloves when working on the furnace.

• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it. Now the reactor foot is visible.
• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Check the cleanliness and elasticity of the teflon tube.
• If slight contamination is ascertained, the teflon tube must be cleaned (Chapter 8.5.7 on page 143).
• If a higher level of contamination or damage is ascertained, the teflon tube must be replaced
(Chapter 8.7.3 on page 157).
• Carefully pull the reactor foot from the reactor pipe end.
• Check the cleanliness of the reactor foot.
• If contamination is ascertained, the reactor foot must be cleaned (Chapter 8.5.8 on page 144).
• Once all test criteria are met, continue with the visual inspection of the reactor pipe without fitting the
reactor foot.
• Ensure that the reactor foot is already removed (Chapter 8.3.8 on page 136)
• Look into the end of the reactor pipe and check its cleanliness (use a mirror and protective goggles
as aids).
• You can see the filter once the reactor pipe is free.
• If contamination is ascertained, the reactor pipe must be cleaned (Chapter 8.5.10 on page 145).
• Check whether the reactor pipe has suffered any damage.
• If damage is ascertained, the reactor pipe must be replaced (Chapter 8.7.4 on page 158).
• Once all test criteria are met, refit the reactor pipe and reactor foot, and continue with the next step.
• Unplug the injection port connector.
• Carefully undo in a crosswise sequence the screws of the furnace head.
• Undo the tube from the tube connector (return valve).
• Take the furnace head and injection port from the reactor pipe.
• Undo the injection port on the furnace head by carefully turning it anticlockwise by hand.
• Check to see whether the O-rings are in perfect condition.
• If damage is ascertained, the respective O-ring must be renewed (Chapter 8.7.5 on page 160 and/or
Chapter 8.7.6 from page 161).
• Place the furnace head onto the furnace and reactor pipe.
• Connect the black tube to the tube connector provided.
• Tighten in a crosswise sequence the attachment bolts of the furnace head with the furnace head
panel.
• Careful tighten the injection port by hand until slight resistance is felt (the injection port should point
to the front left at an angle).
• Plug the injection port connector back in.
• Once all test criteria are met, proceed with the next step.

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8.5.23 Check the Gas Cooling Pipes

Recommendation: - Check the gas cooling pipes every 3 months.

• Unscrew the 3 or 6 connection pieces with the tube connectors.

• Carefully pull the relevant gas cooling pipe upwards out of the cooler guide.
• Check the cleanliness of the gas cooling pipe removed (Note that the white silicone-free, heat-
conductive paste is not contamination).
• If contamination is ascertained, cleaning is necessary (Chapter 8.5.12 on page 146).
• Once the test criterion is met, refit the gas cooling Pipe, reconnect the tubes correctly to the tube
connectors and proceed with the next step.

• Do not pull the gas cooling pipe out by the weld-on tube connector because it could
! break.
• The seats of the gas cooler may not be cleaned with sharp objects because
Caution otherwise the transition area from the cooler to the cooling tube could be damaged.
• Ensure the tubes are connected correctly because incorrect measurement results
can entail if they are not.

2 1

Fig. 99: Gas Cooler (overall view)

3 3
4 4

5 6

Fig. 100: Connections (TOC-Direct Method and Fig. 101: Connections (TOC-Difference Method)
TConly Method)
Legend:
1) Cooler 4) Viton tube (to quartz wool filter)
2) Tube connector 5) Viton tube (to TIC valve)
3) Teflon tube (from reactor foot) 6) Tube (from TIC reactor)

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8.5.24 Clean and oil Injection Port

Recommendation: - Clean and oil the injection port every 3 months.

• Unscrew the cover cap to access the cock plug.

• Undo the two screws of the attachment between motor and injection port carefully (because there is
a spring between the motor and cock plug).
• Take the motor. The injection port is now free.
• Unscrew the union nut (red screw joint) of the cock plug.
• Moisten a lint-free paper or cleaning cloth (you can use a pipe cleaner for openings).
• Thoroughly clean the surface of the injection port and cock plug.
• Apply a very thin layer of oil to the front and rear areas of the cock plug.
• Now push the cock plug back into the opening of the injection port.
• Turn it inside the injection port for good distribution of the oil.
• Fit the washer in front of the cock plug seal and the union nut when the cock plug is in the injection
port.
• Screw the complete injection port onto the furnace head.
• Secure the two M3x45 screws to attach the injection port.
• Fit the cover cap (tighten by hand).

• There is a pressure spring between the cock plug and motor!

! • Please use only the silicone oil of the LAR for the oiling of the cock plug.
Caution

Fig. 102: Clean Injection Port Fig. 103: Oil the Cock Plug thin

Fig. 104: Three steps to mount the components of the Injection Port

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8.5.25 Move Pump Tubes (Tube Cassette Pump)

Precondition: - The area fixed in the pump is inelastic.

Recommendation: - Relocate the tubes after three months.

• Take the pump cassettes from the pump.

• Take the tubes from the pump cassettes.
• Fix the tubes into the pump cassettes at the second, previously unused fixing point between the
colour-coded stoppers.
• Oil the tubes with a drop of silicone oil (available from LAR) at the points mounted.
• Insert the pump cassettes into the pump.

• Tubes can be relocated once. Thereafter they must be replaced if required.

! • The tubes for the tube cassette pump must be oiled to preserve their function as
long as possible.
Caution
• Do not oil any other tubes.
• Use tubes and oil provided by LAR only.

8.5.26 Check the mechanical backlash of the XY-System

Recommendation: - Check the mechanical backlash of the XY-system every3 months.

• Enclose the upper part of the Y-axis with the hand.

• Move your hand forward and backward and look at the end of the injection needle.
• If the injection needle moves more than 1 mm, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
• If the injection needle does not move, proceed with the next step

Legend:
1) X-Axis (horizontal)
2) Y-Axis (vertical)
Fig. 105: Axes of the XY-System

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8.5.27 Check the Injection Port

Recommendation: - Check the Injection Port every 6 months.

3 6

2
1
4

7 8

5
Legend:
1) 2x Screws M3x45 5) 2x Screws M3x6, 2x Washers M3
2) Injection Port 6) Micro-switch housing
3) Cover Cap 7) Switch lever of micro-switch
4) 2x Nuts M3, 4x Washers M3 8) Switch knob on valve cock plug
Fig. 106: Injection Port

• Undo the two Torx screws (No. 5 in Fig. 106, page 155) with spring washers on the cover cap.
• Pull the cover cap upwards.
• Access the display “Service actions”.
• Close and open the injection port to test the ease of movement of the closing and opening functions
for the injection port (rotation test).

• Closing and opening effects rotation of the valve cock plug.

i • There is a switch knob on the valve cock plug (No. 8 in Fig. 106, page 155). When
the valve is closed, the valve cock plug turns until the switch knob on the next
Notice switch lever of a micro-switch triggers the switch process and ends rotation of the
valve.

• When turning the valve cock plug, check that the switch levers of the micro-switch are not pressed
down onto the micro-switch housing by the switch knob of the valve cock plug.
• Ensure that the minimum distance of 1 mm between the switch levers of the micro-switches and the
respective micro-switch housing is not dropping below.
• If the test criteria are not met, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).

• Keep away fingers from the switch area when the valve switches (as there is a
! crushing risk).
Caution

• Once all test criteria are met, screw on the cover cap of the injection port.

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8.6 Maintenance Actions

Use the following maintenance log for the documentation of maintenance actions:

Table 23: Maintenance Log

Interval Action Done Comment

Replace Supply Tubes 
Replace Inlet and Drain Tubes 
Replace Teflon Tube (Reactor Foot) 
Replace Reactor Pipe Filling / Reactor Pipe 
Replace Small Furnace Head Seal (upper) 
Replace Big Furnace Head Seal (Silicone

O-Ring with PFA coat)
If
necessary Replace Injection Tube 
Replace Viton Tube 
Replace Acid Trap filling 
Replace Acid Trap 
Replace Quartz Wool Filter filling 
Replace Quartz Wool Filter 
Replace Filter Mats 
Replace Injection Needle 
1 Week Replace Silicone Seal for TIC-Port 
Replace Needle Guide Seal (Injection Port) 
1 Month Replace Silicone Seals for Glass Compo-

nents
3 Months Replace Seal for Reactor Foot 
Replace Pump Tube (Tube Cassette Pump) 
6 Months
Replace Pump Tube (Sample Pump) 
1 Year Replace Gas Filter 

Date: Signature:

i • A corresponding copy of the log is in Chapter 13 from page 239.

• Careful documentation is a precondition for any guarantee and warranty claims.
Notice

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8.7 Perform Maintenance Actions

If test criteria are not observed during visual inspections, service and/or maintenance actions must be
performed. Below are the instructions for the maintenance work.

Procedure for maintenance actions:

• Always stop measurement mode before carrying out maintenance work.

• Take a maintenance log (if necessary copy from Chapter 13.4 on page 243).
• Follow the instructions below for maintenance work for individual components.
• Document in the maintenance log the actions taken.
• Conclude documentation of the log once the maintenance actions are performed.
• Perform the function tests (Chapter 8.8 from page 169).
• Once the maintenance actions are concluded, start measurement mode.

• In all cases, turn the analyser in offline mode by pressing the red button to avoid
x injury by e.g. moving parts.
Danger

8.7.1 Replace Supply Tubes

Precondition: - Supply tubes are contaminated.

• Pull the tube to be replaced from the canister.

• Undo the tube connector of the tube to be replaced in the analyser.
• Pull the tube to be replaced from the analyser and optionally from the reagent cabinet or circulation
air conditioner.
• Guide the new tube into the analyser and optionally into the reagent cabinet or circulation air
conditioner.
• Attach the new tube at the tube connector in the analyser.
• Insert the new tube back into the canister down to the bottom.

8.7.2 Replace Inlet and Drain Tubes

Precondition: - Inlet and/or Drain tubes are/is contaminated.

• Undo the tube connector of the tube to be replaced in the analyser.

• Pull the tube to be replaced from the analyser.
• Guide the new tube into the analyser.
• Attach the new tube at the tube connector in the analyser.

8.7.3 Replace Teflon Tube (Reactor Foot)

Precondition: - Teflon tube is highly contaminated or damaged.

• Undo the tube connectors of the teflon tube.

• Remove the old teflon tube and replace it with a new one having the same length.
• Attach the new teflon tube at the tube connectors provided.

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8.7.4 Replace Reactor Pipe Filling / Reactor Pipe

Voraussetzung: - Reactor Pipe Filling is blocked or Reactor Pipe is damaged.

Legend:
1) Reactor Pipe
2) Ceramic Protective Pipe
3) Ceramic Balls 1.6mm
4) Ceramic Balls 3.5 - 4.5mm
5) Ceramic Sieve

Fig. 107: Reactor Pipe Filling (Standard)

i • A blockage can result in pressure build-ups within the reactor pipe.

Notice

• Allow the furnace to completely cool down (for 2 hours).

! • The temperature of the reactor pipe is still 400°C to 500°C one hour after the
furnace is switched off.
Caution
• Wear heat-resistant gloves when working on the furnace.
• Note that all parts removed and/or taken apart must be reassembled according to
their original state.

Disassembly:
• Switch the furnace off from the display “Service Actions” (Chapter 7.2.11 from page 88) and let it cool
for two hours.
• Move the Y arm to the right using a test run (Chapter 7.2.13 from page 94).
• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it. Now the reactor foot is visible.

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• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Carefully pull the reactor foot from the reactor pipe end and put it to one side.
• Unplug the injection port connector.
• Undo the injection port by carefully turning it anticlockwise by hand.
• Carefully undo in a crosswise sequence the screws of the furnace head.
• Undo the tube from the tube connector.
• Take the furnace head and injection port from the reactor pipe and place both to one side.
• Ensure that the furnace head, injection port and reactor foot are removed.
• Once the furnace has cooled completely (after about two hours), use heat-resistant gloves to pull the
reactor pipe from the furnace.
• Place the reactor pipe onto a fire-resistant surface or put it into a bucket filled with sand (with the
taper pointing downwards) and let it cool completely.

Replacement:
• If the reactor pipe is damaged, replace it with a new reactor pipe.
• Note the sequence for filling the reactor pipe.
• Position the ceramic sieve (No. 5 in Fig. 107, page 158) horizontally on the taper of the reactor pipe /
allow it to drop into the reactor pipe.
• Shake the reactor pipe to move the ceramic sieve into a horizontal position. (You can use a torch to
check the position).
• Carefully insert the long protective pipe (No. 2 in Fig. 107, page 158) into the reactor pipe from
above.

• Please use a funnel to fill the ceramic balls so that they do not fall between the
! reactor pipe and protective pipe, as this can result in damage to the reactor pipe.
Caution

• Fill the ceramic balls with diameters 3.5 mm - 4.5 mm (No. 4 in Fig. 107, page 158) up to the height
specified (210 mm, measured from the top edge with a tape measure).
• Fill the ceramic balls with diameter 1.6 mm (No. 3 in Fig. 107, page 158) up to the height specified
(170 mm, measured from the top edge with a tape measure).
• Fill the ceramic balls with diameters 3.5 mm - 4.5 mm (No. 4 in Fig. 107, page 158) up to the height
specified (150mm, measured from the top edge with a tape measure).

Reassembly:
• Place the green protective seal for the reactor pipe onto the furnace.
• Push the filled reactor pipe into the centre of the furnace from above.
• Place the furnace head onto the furnace and reactor pipe.
• Connect the black tube to the tube connector provided.
• Tighten in a crosswise sequence the attachment bolts of the furnace head with the furnace head
panel.
• Careful tighten the injection port by hand until slight resistance is felt (the injection port should point
to the front left at an angle).
• Plug the injection port connector back in.
• Attach the reactor foot seating to the reactor footplate using three M4x30 bolts.
• Connect the teflon tube (PFA) to the screwed insert.
• Screw the screwed insert into the reactor foot seating.
• Plug the reactor foot onto the reactor pipe from below.
• Screw on the four spacer bolts.
• Pull the reactor foot down so that the gas path is not blocked by the reactor pipe.
• Reattach the bottom grid.
• Reattach the ventilation grid.
• Dispose the old reactor pipe filling and, if necessary, the old reactor pipe.
• Switch the furnace back on from the display “Service Actions” (Chapter 7.2.11 from page 88).

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• We know from experience that the reactor pipe filling shown in Fig. 107, page 158

i represents an excellent solution for the majority of applications.

• However, some applications can be optimised with a variation of the standard filling
Notice described. All departures from the standard filling should be discussed upfront with
Technical Support of LAR (Chapter 15 on page 257) or a service partner
authorised by LAR.
• Given that our research and development are advancing continually, we ask you to
stay in touch with your contact at LAR to keep abreast of all additions.

8.7.5 Replace Small Furnace Head Seal (upper)

Precondition: - Small furnace head seal is damaged.

Recommendation: - Replace small furnace head seal every 6 months.

• Wear heat-resistant gloves.

• Unplug the injection port connector.
• Carefully undo in a crosswise sequence the screws of the furnace head.
• Undo the tube from the tube connector.
• Take the furnace head and injection port from the reactor pipe.
• Undo the injection port on the furnace head by carefully turning it anticlockwise by hand.
• Carefully remove the old, small furnace head seal (upper) from its groove using pliers or a small
slotted screwdriver.
• Insert a new, small furnace head seal (upper) into the furnace head groove.
• Place the furnace head onto the furnace and reactor pipe.
• Connect the black tube to the tube connector provided.
• Tighten in a crosswise sequence the attachment bolts of the furnace head with the furnace head
panel.
• Careful tighten the injection port by hand until slight resistance is felt (the injection port should point
to the front left at an angle).
• Plug the injection port connector back in.

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8.7.6 Replace Big Furnace Head Seal (Silicone O-Ring with PFA coat)

Precondition: - Big furnace head seal is damaged.

Recommendation: - Replace big furnace head seal every 6 months.

• Wear heat-resistant gloves.

• Unplug the injection port connector.
• Carefully undo in a crosswise sequence the screws of the furnace head.
• Undo the tube from the tube connector.
• Take the furnace head and injection port from the reactor pipe.
• Undo the injection port on the furnace head by carefully turning it anticlockwise by hand.
• Carefully remove the old, big furnace head seal (O-ring with PFA coat) from its groove using pliers or
a small slotted screwdriver.
• Insert a new, big furnace head seal (O-ring with PFA coat) into the furnace head groove.
• Place the furnace head onto the furnace and reactor pipe.
• Connect the black tube to the tube connector provided.
• Tighten in a crosswise sequence the attachment bolts of the furnace head with the furnace head
panel.
• Careful tighten the injection port by hand until slight resistance is felt (the injection port should point
to the front left at an angle).
• Plug the injection port connector back in.

8.7.7 Replace Injection Tube

Precondition: - Injection tube is highly contaminated or damaged.

• Undo the tube connectors of the injection tube.

• Remove the old injection tube and replace it with a new one having the same length.
• Attach the new injection tube at the tube connectors provided..

! • You should only use the tubes of the LAR.

Caution

8.7.8 Replace Viton Tube

Precondition: - Viton tube is highly contaminated or damaged.

• Undo the tube connectors of the viton tube.

• Remove the old viton tube and replace it with a new one having the same length.
• Attach the new viton tube at the tube connectors provided.

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8.7.9 Replace Acid Trap Filling

Preconditions: - Up to 2/3 of the brass wool has a red-brown discolouration.

- The zinc is up to 2/3 matt.

• Wear gloves and if necessary a breathing mask during the replacement of the
! filling.
Caution

• Use a screwdriver to open the pipe clamps.

• Take the tubes to the acid trap.
• Take the acid trap from the holder.
• Remove the contents of the acid trap.
• Fill the quartz wool into the acid trip carefully because otherwise the quartz wool becomes pulverised
and a blockage of the gas paths is created when it is stuffed by too much (bottom).
• Fill the zinc into the acid trap (middle).
• Fill the brass wool into the acid trap (top). No brass wool may be protruding.
• Check the order (from the bottom up): Quartz wool, zinc, brass wool.
• Fit the filled acid trip into its holder.
• Reconnect the tubes to the acid trap.

• LAR offers filled acid traps for simple and quick maintenance.
i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

8.7.10 Replace Acid Trap

Preconditions: - Up to 2/3 of the brass wool has a red-brown discolouration.

- The zinc is up to 2/3 matt.

• Use a screwdriver to open the pipe clamps.

• Take the tubes to the acid trap.
• Remove the acid trap from the holder.
• Fit the new acid trip into its holder.
• Connect the tubes to the acid trap.

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8.7.11 Replace Quartz Wool Filter Filling

Preconditions: - Quartz wool has a grey colouring.

- Quartz wool is damp.

• Wear gloves and if necessary a breathing mask during the replacement of the
! filling.
Caution

• Make a note of the gas pressure [in mbar] on the display “Status Screen” (Chapter 7.2.10 on
page 87).
• Put gloves on.
• Take the tubes from the quartz wool filter.
• If required, use a screwdriver to open the pipe clamps.
• Take the quartz wool filter from the holder.
• Undo the upper and lower screw connections.
• Remove and dispose the old quartz wool.
• Fill the quartz wool filter carefully with quartz wool because otherwise the quartz wool becomes
pulverised and a blockage of the gas paths is created when it is stuffed by too much. Ensure that the
quartz wool is filled loose at the bottom and a little more compact at the top. No quartz wool may be
protruding.
• Clean the red threaded connections.
• Place the O-ring into the recess provided.
• Screw back in the upper and lower quartz wool filters.
• Fit the quartz wool filter into the holder.
• Connect the tubes to the quartz wool filter.
• Check the gas pressure on the display “Status screen”.

• LAR offers filled quartz wool filters for simple and quick maintenance.
i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

8.7.12 Replace Quartz Wool Filter

Preconditions: - Quartz wool has a grey colouring.

- Quartz wool is damp.

• Make a note of the gas pressure [in mbar] on the display “Status screen” (Chapter 7.2.10 on
page 87).
• Put gloves on.
• Take the tubes from the quartz wool filter.
• If required, use a screwdriver to open the pipe clamps.
• Remove the quartz wool filter from the holder.
• Fit the new quartz wool filter into the holder.
• Connect the tubes to the quartz wool filter.
• Check the gas pressure on the display “Status screen”.

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8.7.13 Replace Filter Mats

Precondition: - Filter mats have strong discolouration.

Recommendation: - Replace filter mats every 3 months.

• Open the ventilation grid on the left side of the analyser by levering out the ventilation flap (Fig. 108,
page 164).
• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 109, page 164).
• Remove the filter mats which to be replaced.
• Dispose the filter matd in an environmentally responsible way.
• Insert new filter mats.
• Close the ventilation grid.

Fig. 108: Replace the Filter Mats on the left side of the Analyser

Fig. 109: Replace the Filter Mats on the bottom side of the Analyser

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8.7.14 Replace Injection Needle

Precondition: - Injection needle is damaged.

Recommendation: - Replace injection needle every 12 months.

• Undo the injection tube from the injection needle.

• Use a spanner to detach the injection needle.
• Fit the new injection needle.

• Please note that, following care and/or maintenance work, some function tests
! (such a test run) need to be performed before measurement mode can be started
again (Chapter 8.8 from page 169).
Caution

8.7.15 Replace Silicone Seal for TIC-Port (TOC-Difference Method)

i
• This instruction applies only to analysers that determine the COD via the CODi
Method using the TOC-Difference Method. When using other methods, the TIC
Reactor is not installed in the analyser.
Notice

Precondition: - Seal on TIC port is one week old.

• Unscrew the cover of the TIC port (Fig. 91, page 137).
• Use a thin object (such as 2 mm diameter screwdriver) to puncture the cover from above to press out
the old TIC seal.
• If the inner surfaces are contaminated, clean the cover and screw cap.
• Insert a new seal.
• Screw the cover with the new seal onto the TIC reactor.

• Two TIC port seals can be placed into the cover for samples which bubble
! intensely. The slits of the seals should be offset by 45°.
Caution

• We recommend keeping TIC port seals in stock.

i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

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8.7.16 Replace Needle Guide Seal (Injection Port)

Precondition: - Needle guide seal (injection port) is one month old.

• Unscrew the union nut of the injection port.

• Lift the top part of the needle guide and remove the old needle guide seal (Fig. 110, page 166).
• Insert the new needle guide seal into the clean groove.
• Place the top part of the needle guide onto the lower part of the needle guide.
• Tighten the union nut again.

• Do not remove the needle guide seal with a screwdriver or other sharp object
! because this could scratch the groove, thereby causing leaks. Instead, use a soft
object like a wooden toothpick or pencil to lever out the seal.
Caution

Fig. 110: Replace needle guide seal

• We recommend keeping needle guide seals in stock.

i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

8.7.17 Replace Silicone Seals for Glass Components

Precondition: - Silicone seals are 1 month old.

• Unscrew the screw caps of the glass components.

• Remove the old silicone seals from the cover.
• Insert a new silicone seals into the cover.
• Note its position. If the silicone seals has a teflon-coated side, it must face the glass.
• Hand tighten the screw caps.

• We recommend keeping silicone seals in stock.

i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

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8.7.18 Replace Seal for Reactor Foot

Recommendation: - Replace the seal for reactor foot every 3 months.

• Use heat-resistant gloves to change the reactor foot seal.

• Remove the ventilation grid on the bottom side of the analyser by pulling it forward with your hands
(Fig. 93, page 139).
• Undo the screws of the second bottom grid behind it and detach it.
• Now the reactor foot is visible.
• Unscrew the four black spacer bolts (there are two for the high salt option).
• Unscrew the three screws from the seating of the reactor foot.
• Undo the screwed insert with teflon tube from the reactor foot seat.
• Carefully pull the reactor foot from the reactor pipe end.
• Remove the old reactor foot seal and replace it with a new one.
• Reconnect the screwed insert with teflon tube to the reactor foot seating.
• Screw back in the three screws for seating the reactor foot.
• Screw on the four black spacer bolts (there are two for the high salt option).
• Pull the reactor foot with disc onto the spacer bolts so that the gas path is not blocked by the reactor
pipe.
• Use the screws to attach both bottom grids.
• Mount the ventilation grid.

4
1
4
5

Legend:
1) Spacer bolts (4x) 4) Reactor foot disc
2) Seating of the reactor foot 5) Reactor foot plate
3) Teflon tube 6) Screws M4x30 (3x)

Fig. 111: Bottom view of the Reactor Foot

3
1

Legend:
1) Spacer bolts (4x)
2) Minimum distance between reactor foot plate and reactor foot disc
3) Reactor foot seat (cylindrically)
Fig. 112: Side view of the Reactor Foot

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8.7.19 Replace Pump Tube (Tube Cassette Pump)

Precondition: - Both fixing points are inelastic.

Recommendation: - Replace pump tube every 6 months.

• Take the pump cassettes from the pump.

• Remove the tubes from the pump cassettes.
• Fix the new tubes into the pump cassettes between two colour-coded stoppers.
• Oil the tubes with a drop of silicone oil (available from LAR) at the points mounted.
• Insert the pump cassettes into the pump.

8.7.20 Replace Pump Tube (Sample Pump)

Precondition: - Pump tube is highly contaminated or damaged.

Recommendation: - Replace pump tube every 6 months.

• Remove the tubes from the sample pump.

• Fix a new tube having the same length into the sample pump.

8.7.21 Replace Gas Filter

Precondition: - Gas filter is contaminated.

Recommendation: - Replace gas filter every 12 months.

• Open the rear part of the housing.

• Open the pipe clamp in the top right, in which the gas filter is attached.
• Pull the connection tubes of the old filter from the connectors (see white arrows in Fig. 113,
page 168.
• Note the direction of the volume flow (see black arrow).
• Insert the new filter.
• Close the pipe clamp.
• Close the rear part of the housing.

Direction to disconnect
the tube from the filter

Fig. 113: Gas filter

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 8 Care and Maintenance
LAR | PROCESS ANALYSERS AG 8.8 Function Tests

8.8 Function Tests

Following care and maintenance work, some tests should be carried out to ensure perfect functioning of
the analyser.

Use the following log for the documentation of the function tests:

Table 24: Function Test Log

Visual Inspection Criteria OK Action

• Zero signal is between  Contact Support
0 - 0.1 FSR __________________________
Check Analyser 
• Carrier Gas IN / OUT: __________________________
approx. 20 l/h __________________________
• Carrier gas volume flow  Contact Support
Tightness Test 
falls to < 5 l/h __________________________
• All positions are hit by the  Contact Support
Test Run (XY-System) 
injection needle __________________________
• Measurement results
Checking the  Contact Support
matches the calibration 
Measurement Results __________________________
standard
• Measurement Process
Checking the  Contact Support
goes on without 
Measurement Process __________________________
complications

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question to function test, please contact your local partner or the
Technical Support of LAR (Chapter 15 on page 257).
Notice

8.8.1 Check Device Status

• Check in the “Status Screen” display (Chapter 7.2.10 on page 87) whether the zero signal is between
0 and 0.1 FSR.
• If the signal is not within the range permitted, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
• Check from the “Status Screen” display (Chapter 7.2.10 on page 87) using the carrier gas volume
flow at the carrier gas inlet and carrier gas outlet that the carrier gas is being transported through the
system at a rate of approx. 20 l/h (± 5 l/h).
• If too high a difference is ascertained, check the individual attachments (tube connections, etc.) or
please contact your local partner or the Technical Support of LAR (Chapter 15 on page 257).
• Once all test criteria are met, proceed with the next step.

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8.8.2 Tightness Test

• Access the “Status Screen” display (Chapter 7.2.10 on page 87).

• Set the pressure on the pressure regulator to 0.5 bar.
• Disconnect the black viton tube at the output of the cooler with a tube clamp.
• Check in the Status display whether the carrier gas volume flow falls to below 5 l/h.
• If a discrepancy is ascertained, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).
• Once the test criterion is met, undo the tube clamp again, set the pressure to 1.2 bar and proceed
with the next step.

8.8.3 Test Run (XY-System)

• Perform a test run of the XY system (Chapter 7.2.13 from page 94).
• If some of the positions are not hit properly, reposition the injection needle and repeat the test run
(Chapter 7.2.13.2 on page 95).
• If the situation persists as regards positions not being hit, please contact your local partner or the
Technical Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

8.8.4 Checking the Measurement Results

• Make available a standard solution (Chapter 6.2 from page 58).

• Fill the standard solution into a clean calibration vessel.
• Fit the calibration vessel at any position.
• Perform a single measurement (Chapter 7.2.12 from page 92).
• Check the results.
• If the results differ, please contact your local partner or the Technical Support of LAR (Chapter 15
on page 257).
• Once the test criterion is met, proceed with the next step.

8.8.5 Checking the Measurement Process

• Start the analyser Online mode.

• Watch the first measurement process.
• If irregularities occur, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).
• Once the test criterion is met, finish the documentation.

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 8 Care and Maintenance
LAR | PROCESS ANALYSERS AG 8.9 Short-Time- and Long-Time Interruptions

8.9 Short-Time- and Long-Time Interruptions

8.9.1 Switching On/Off for Short-Time-Interruptions (<1 Week)

Switching off:

• End measurement mode.

• Close your sample feed.
• Allow your sample to drain.

Switching on:

• Open your sample feed.

• Prepare calibration solutions (Chapter 6.2 from page 58).
• Perform a calibration if required (Chapter 7.2.3 from page 73).
• Start measurement mode.

i • The analyser is not switched off for short-term interruptions.

Notice

8.9.2 Switching On/Off for Long-Time Interruptions (>1 Week)

Switching off:

• End measurement mode.

• Close your sample feed.
• Empty the tube system and glass components.
• Clean the glass components if required.
• Close the carrier gas supply.
• Switch the analyser off.
• Depressurise the pump tubes.

Switching on:

• Have acid and reagent solution ready (Chapter 6.1 from page 55).
• Open your sample feed.
• Insert the tubes.
• Switch the analyser on.
• Open the carrier gas supply.
• Prepare calibration solutions (Chapter 6.2 from page 58).
• Perform a calibration (Chapter 7.2.3 from page 73).
• Start measurement mode.

i • For long-term interruptions, the pump tubes must be depressurised to prevent long-
term deformation of the tube material and a reduction of delivery rate.
Notice

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 9 Accessories and Options
LAR | PROCESS ANALYSERS AG 9.1 Overview of Opportunities for Accessories and Options

9 Accessories and Options

In this section illustrations for and explanations of components you can select as accessories or options
for the analyser are shown.

9.1 Overview of Opportunities for Accessories and Options

Accessories:

• Reagent Cabinet
• Permeation Unit
• Ambient Air Preparation Unit
• FlowSampler®
• CO2-Remover
• Mounting Rack

Options:

• Multi Stream Option

• Multi Parameter Option
• High Salt Option
• Auto-TIC-Port (only for TOC-Difference Method)
• Internal Sample Dilution

i • If you have questions, please contact the Sales Department of LAR (Chapter 15
on page 257).
Notice

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9.2 Reagent Cabinet LAR | PROCESS ANALYSERS AG

9.2 Reagent Cabinet

The reagent cabinet is used for the protected safekeeping of the following reagents:

• Acid
• Rinsing Water

• The containers for the reagents are delivered separately.

i • The reagent cabinet has different outputs for the solutions, which are labelled
specifically for the application. Please note the labelling.
Notice

9.2.1 Construction of the Reagent Cabinet

1
1

Legend:
1) Tube feedthroughs
2) Housing lock

Fig. 114: Reagent Cabinet

i • The dimensions of the Reagent Cabinet are in Chapter 11.3 on page 226.

Notice

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LAR | PROCESS ANALYSERS AG 9.2 Reagent Cabinet

9.2.2 Installation of the Reagent Cabinet

Installation of the Reagent Cabinet is dependent on the mounting variant.

Variant 1 (without mounting):

• Place the Reagent Cabinet onto the floor or the PVC plate of the mounting rack under the analyser.

Variant 2 (Wall mounting):

• Fit the Reagent Cabinet with the stud bolts on the wall underneath the analyser (Chapter 4.3.2 from
page 34).

• Do not fit the Reagent Cabinet too high (near to the analyser) because otherwise
! the ventilation unit underneath the analyser is difficult to access.
Caution

Variant 3 (Mounting Rack):

• Use holes Q1 and Q2 in the mounting rack, and holders Q1 and Q2 on the Reagent Cabinet, for
fitting on the mounting rack (Chapter 9.7 from page 208).

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9.2.3 Start-Up of the Reagent Cabinet

At delivery, the tubes are rolled up inside the analyser and secured with a cable tie.

Follow these instructions to operate the reagent cabinet:

• Use side-cutting pliers for example to remove the cable tie.

• Guide the tubes through the cable feedthroughs provided on the side of the reagent cabinet.
• Undo the union nuts of the canisters.
• Put the tubes into the relevant canisters.
• Secure the union nuts of the canisters.

• Ensure not to damage the tubes when removing the cable tie.
! • The tubes must be connected to the right canisters. Note the labelling.
Caution

i
• A suitable O-ring can be pulled onto a tube so that it has the correct penetration
depth (Fig. 115, page 176). The O-ring should be fitted about 6 cm from the end of
the tube.
Notice

Fig. 115: Tube with O-Ring

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 9 Accessories and Options
LAR | PROCESS ANALYSERS AG 9.3 Permeation Unit

9.3 Permeation Unit

The Permeation Unit is connected on the nitrogen inlet to a nitrogen supply (e.g. nitrogen generator or
pressurised gas cylinder with nitrogen 5.0), which supplies a pre-pressure between 2 and 5 bar, and to
the analyser on the carrier gas outlet (No. 4 in Fig. 116, page 177). Upon delivery the tube provided for
this purpose is coiled up at the rear of the housing. It has to be led out through the opening and connec-
ted to the carrier gas outlet of the Permeation Unit. Prior to this, the openings have to be sealed with
plastic bushings. These can be found in the included spare case. The Permeation Unit contains a pres-
sure regulator with screwed-on manometer, a diffusion tube whose length depends on the desired
measurement range, a heating fan, and a temperature controller (Chapter 10.4 on page 224). When the
Permeation Unit is closed, the temperature should stabilize at a constant level of 45°C after approx. 30
minutes of waiting time.

• Since the diffusion tube is pressurised when the Permeation Unit is connected to
! the nitrogen supply, protective goggles and appropriate gloves should be worn
when opening the housing.
Caution • The Permeation Unit must not be opened before all measurements have been
terminated or stopped since this can possibly lead to distortion of the
measurements.
• After the Permeation Unit is closed again, the oxygen concentration in the carrier
gas stabilizes within approx. 30 minutes. No measurements should be carried out
during this time.

9.3.1 Construction of the Permeation Unit

3 4 5

Legend:
1) Temperature Controller 4) Carrier Gas Outlet to Analyser
2) Ambient Air Inlet 5) Nitrogen Inlet
3) Power Connection to Analyser 6) Housing Lock

Fig. 116: Permeation Unit (Exterior View)

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9.3 Permeation Unit LAR | PROCESS ANALYSERS AG

2 3 4
5

7
1

Legend:
1) Temperature Controller 5) Pressure Regulator
2) Power Connection to Analyser 6) Pressure Gauge
3) Carrier Gas Outlet to Analyser 7) Silicone Tube
4) Nitrogen Inlet 8) Heating Fan (behind the tube)
Fig. 117: Permeation Unit (Interior View)

9.3.2 Installation of the Permeation Unit

Installation of the Permeation Unit is dependent on the mounting variant.

Variant 1 (Wall mounting):

• Fit the Permeation Unit with the stud bolts on the wall underneath the analyser (Chapter 4.3.2 from
page 34).

• Do not fit the Permeation Unit too high (near to the analyser) because otherwise
! the ventilation unit underneath the analyser is difficult to access.
Caution

Variant 2 (Mounting Rack):

• Place the Permeation Unit onto the PVC plate of the mounting rack under the analyser.

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LAR | PROCESS ANALYSERS AG 9.3 Permeation Unit

9.3.3 Start-Up of the Permeation Unit

• Connect the nitrogen inlet of the Permeation Unit (No. 4 in Fig. 117, page 178) with the nitrogen
supply (nitrogen generator or pressurised gas cylinder with nitrogen 5.0).
• Connect the carrier gas outlet of the Permeation Unit (No. 3 in Fig. 117, page 178) with the carrier
gas inlet of the analyser.
• Connect the electrical connection as described in Chapter 9.3.3.1 on page 179.

9.3.3.1 Electrical Connection of the Permeation Unit

• Guide the power connection cable with the brown, blue and green-yellow wires through Point 2 of the
Permeation Unit (Fig. 117, page 178).
• Open the rear part of the housing of the analyser to reach the installation plate (Fig. 15, page 18).
• Locate the connection terminal of the Permeation Unit with 24 V/DC (X4).
• Connect the brown wire to brown (Point 8).
• Connect the blue wire to black (Point 9).
• Connect the green-yellow wire to green-yellow (Point 10).
• Close the rear part of the housing.

Fig. 118: Electrical Connection of the Permeation Unit in the Analyser

! • The terminal of the Permeation Unit has a voltage of 24 V/DC.

Caution

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 9 Accessories and Options
9.3 Permeation Unit LAR | PROCESS ANALYSERS AG

9.3.4 Care and Maintenance Actions (Permeation Unit)

Only minor effort is required to service and maintain the Permeation Unit. This section shows the best
way to look after your Permeation Unit to guarantee trouble-free operation. The documentation of main-
tenance and service work is a precondition for any warranty and guarantee claims, and also represents
a valuable aid in locating resolutions when malfunctions occur (Chapter 10 from page 221).

Table 25: Visual Inspection Log (Permeation Unit)

Interval Visual Inspection Criteria OK Action

• Temperature is
 Contact Support
1 Week Temperature between 44.8°C and 
45.2°C _____________________

• no contamination  Contact Support

Silicone Tube
• normal elasticity 
_____________________
3 Months • Carrier gas flow falls
to 0 l/h  Contact Support
Tightness
• Pressure remains at

_____________________
1.2 bar

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question to visual inspections please contact your local partner or
the Technical Support of LAR (Chapter 15 on page 257).
Notice

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LAR | PROCESS ANALYSERS AG 9.3 Permeation Unit

9.3.5 Perform Visual Inspection (Permeation Unit)

Procedure of visual inspections:

• Use a visual inspection log (Permeation Unit) (Chapter 13.6 on page 245) for documentation.
• Follow the instructions below for visual inspections of individual components.
• Contact your local partner or the Technical Support of LAR (Chapter 15 on page 257) when test
criteria are not met.
• After the check conclude the documentation of the log.

• Protective gloves and protective goggles should be worn when working on the
! Permeation Unit!
Caution

9.3.5.1 Temperature
• Check the temperature setting on the temperature control located at the front of the Permeation Unit.
• If the temperature deviates by more than 0.2° C from 45° C, please contact your local partner or the
Technical Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

9.3.5.2 Silicone Tube

• Check the cleanliness and elasticity of the tube.
• If a higher level of contamination or damage is ascertained, the tube must be replaced. Please
contact your local partner or the Technical Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

9.3.5.3 Tightness
• Clip the tubing between the analyser and Permeation Unit with a tube clamp.
• Check the pressure gauge of the analyser to see if the pressure drops to 0 bar.
• Check whether the carrier current drops to 0 I/h on the status screen (Chapter 7.2.10 from page 87).
• Open the Permeation Unit.
• Read the pressure on the Permeation Unit pressure gauge. This should be at 1.2 bar.
• Interrupt the supply of nitrogen.
• Check the pressure on the Permeation Unit pressure gauge. The pressure should not drop after the
interruption of the nitrogen supply.
• If the pressure drops, check the attachment of the tube connectors and repeat the test if necessary.
• If one of the test criteria is not met, please contact your local partner or the Technical Support of
LAR (Chapter 15 on page 257).
• If all test criteria are met, remove the tube clamp between the analyser and Permeation Unit, open
the nitrogen supply, and continue with the next step.

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9.4 Ambient Air Preparation Unit

The Ambient Air Preparation Unit is used to prepare ambient air, which then can be used as carrier gas.

9.4.1 Construction of the Ambient Air Preparation Unit

The number of connector tubes between analyser and Ambient Air Preparation Unit depends on the
method used. A maximum of three connector tubes and one cable are connected:

• Connector tube for rinsing water

• Connector tube for carrier gas
• Connector tube for acid
• Cable for power supply

• Protective gloves and goggles must be worn when working with the Ambient Air
x Preparation Unit because there might be caustic substances in the conditioner.
Danger

1 2

3 4 5 6

8 7

Legend:
1) Power connection to analyser 6) Activated carbon cartridge
2) Carrier gas to analyser 7) Housing lock
3) Tube feedthroughs (back row) 8) Condensate drain
4) Tube feedthroughs (front row) 9) Ventilation grill
5) Soda lime cartridge
Fig. 119: Front View of the Ambient Air Preparation Unit

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9.4.1.1 Activated Carbon

Highly volatile carbon compounds (such as solvents) which negatively impact measurements may be in
the ambient air (depending on installation location). Most highly volatile carbon compounds can be
absorbed using activated carbon. Working with activated carbon is non-hazardous as it poses no risk.
The filter cartridge for the activated carbon is on the right-hand side of the cabinet (Fig. 119, page 182).

9.4.1.2 Soda Lime Pellets

The CO2 in the ambient air must be removed before it enters the analyser. When soda lime pellets are
used, the safety regulations for caustic substances must be observed. Protective gloves and goggles
must always be worn to prevent chemical burns. A breathing mask must also be worn when dust is
produced. The filter cartridge for the soda lime pellets is on the left-hand side of the cabinet (Fig. 119,
page 182).

• The zero signal of the CO2 detector increases once the intake capacities of the
! aforementioned chemicals are depleted.
• The zero signal can be checked on the “Status Screen“ display (Chapter 7.2.10 on
Caution page 87).

9.4.1.3 Flow Diagram of the Ambient Air Preparation Unit

The carrier gas for the measurements must meet certain criteria (Chapter 3.5 on page 27). Ambient air
must be conditioned accordingly if used. The tubing for the Ambient Air Preparation Unit is shown below.

14
14 -BP10
12 13a 13b
-HQ10 -HQ11 -HQ12 -HQ13 -KH10
-GQ

10 11
-HS11 15

-HS12 15

-HQ14 16

Legend:
10) HQ10 - Gas filter 14) KH10 - Pressure regulator
11) GQ - Compressor + BP10 - Pressure display
12) HQ11 - Water separator 15) Connection to activated carbon (HS11) and
13) Complete compressed air filter unit connection to soda lime (HS12)
a) HQ12 - Coarse filter unit 16) HQ14 - Fine filter (then to analyser)
b) HQ13 - Fine filter unit 17) Electrical connection (bipolar connector - from
analyser, to compressor)
Fig. 120: Flow Diagram of the Ambient Air Preparation Unit

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9.4.2 Installation of the Ambient Air Preparation Unit

Installation of the Ambient Air Preparation Unit is dependent on the mounting variant.

Variant 1 (without mounting):

• Place the Ambient Air Preparation Unit onto the floor or the PVC plate of the mounting rack under the
analyser.

Variant 2 (Wall mounting):

• Fit the Ambient Air Preparation Unit with the stud bolts on the wall underneath the analyser
(Chapter 4.3.2 from page 34).

• Do not fit the Ambient Air Preparation Unit too high (near to the analyser) because
! otherwise the ventilation unit underneath the analyser is difficult to access.
Caution

Variant 3 (Mounting Rack):

• Use holes Q1 and Q2 in the mounting rack, and holders Q1 and Q2 on the Ambient Air Preparation
Unit, for fitting on the mounting rack (Chapter 9.7 from page 208).

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9.4.3 Start-Up of the Ambient Air Preparation Unit

• Tubes should be routed according to the flow diagram in Fig. 120, page 183 to
! ensure air flow.
Caution

9.4.3.1 Transportation Locks

The Ambient Air Preparation Unit is supplied with a bypass of the soda lime filter cartridge (left filter
cartridge) and activated carbon filter cartridge (right filter cartridge) to prevent the use of soda lime
pellets.

For transport (Fig. 121, page 185):

• Tube A is attached between Points 1 and 4

• Tube B is attached between Points 2 and 3

1 3

2 4

Legend:
1) Carrier gas outlet of soda lime cartridge A+B) Carrier gas tube
2) Carrier gas inlet of soda lime cartridge
3) Carrier gas outlet of activated carbon cartridge
4) Carrier gas inlet of activated carbon cartridge

Fig. 121: Ambient Air Preparation Unit with Transportation Locks

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9.4.3.2 Tubing of the Ambient Air Preparation Unit

Please route the tubes of the Ambient Air Preparation Unit in accordance with the flow diagram in
Fig. 122, page 186:

• Undo Tube A from Point 1 (Fig. 121, page 185).

• Guide Tube A into the Ambient Air Preparation Unit through Point 6 (Fig. 122, page 186).
• Fit Tube A in the Ambient Air Preparation Unit to pressure regulator KH10 (Fig. 123, page 187).
• Route Tube C (in the Ambient Air Preparation Unit at the fine filter) outwards through Point 7.
• Fit Tube C to Point 1.
• Tube B remains at Points 2 and 3.
• Guide Tube D from the analyser into the Ambient Air Preparation Unit through Point 9.
• Fit Tube D on fine filter HQ14 in the Ambient Air Preparation Unit (Fig. 124, page 187).

1 3
D
C E
7
8 9

6
5

A
B

2 4

Legend:
1) Carrier gas outlet of soda lime cartridge 7) Carrier gas inlet of the Ambient Air Preparation
2) Carrier gas inlet of soda lime cartridge Unit to soda lime cartridge
3) Carrier gas outlet of activated carbon cartridge 8) Feedthrough power connection cable
4) Carrier gas inlet of activated carbon cartridge 9) Feedthrough for carrier gas tube to the
5) Ambient air inlet analyser
6) Carrier gas outlet of the Ambient Air
Preparation Unit to activated carbon cartridge A-D) Carrier gas tubes (blue)
E) Power connection cable (black)

Fig. 122: Ambient Air Preparation Unit in Use

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14 13 11 17
12

15
b a
16

10
C
Legend:
10) HQ10 - Gas filter 14) KH10 - Pressure regulator
11) GQ - Compressor + BP10 - Pressure display
12) HQ11 - Water separator 15) Connection to activated carbon (HS11) and
13) Complete compressed air filter unit connection to soda lime (HS12)
a) HQ12 - Coarse filter unit 16) HQ14 - Fine filter (then to analyser)
b) HQ13 - Fine filter unit 17) Electrical connection (bipolar connector - from
analyser, to compressor)
Fig. 123: Way of carrier gas (No. 10-16) and electrical connection (No. 17) of the Ambient Air Prepa-
ration Unit

16

D
Legend:
C)Carrier gas tube comes from soda lime cartridge (fixed on the Ambient Air Preparation Unit)
D)Carrier gas tube to analyser
16)HQ14 - Fine filter

Fig. 124: Detail view of the fine filter - HQ14

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9.4.3.3 Electrical Connection of the Ambient Air Preparation Unit

• Guide the power connection cable with the brown, blue and green-yellow wires from the Ambient Air
Preparation Unit through Point 8 (Fig. 122, page 186).
• Open the rear part of the housing of the analyser to reach the installation plate (Fig. 15, page 18).
• Locate the connection terminal of the Ambient Air Preparation Unit with 24 V/DC (X4).
• Connect the brown wire to brown (Point 8).
• Connect the blue wire to black (Point 9).
• Connect the green-yellow wire to green-yellow (Point 10).
• Close the rear part of the housing.

Fig. 125: Electrical Connection of the Ambient Air Preparation Unit in the Analyser

! • The terminal of the Ambient Air Preparation Unit has a voltage of 24 V/DC.

Caution

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9.4.4 Care and Maintenance Actions (Ambient Air Preparation Unit)

Only minor effort is required to service and maintain the Ambient Air Preparation Unit. This section shows
the best way to look after your Ambient Air Preparation Unit to guarantee trouble-free operation. The do-
cumentation of maintenance and service work is a precondition for any warranty and guarantee claims,
and also represents a valuable aid in locating resolutions when malfunctions occur (Chapter 10 from
page 221).

Table 26: Visual Inspection Log (Ambient Air Preparation Unit)

Interval Visual Inspection Criteria OK Action

 Contact Support
1 Week Fine Filter Element • no contamination  _____________________
_____________________

• condensate drains
 Contact Support
Filter Unit
normally
 _____________________
_____________________
• no discolouration  Replace
Soda Lime
(purple/violet)

3 Months _____________________
• connected  Fix tubes
Tube Connections
handtightened

_____________________
Pre Pressure of the  Contact Support
Carrier Gas
• still at 2 - 3 bar 
_____________________

Date: Signature:

Table 27: Care and Maintenance Log (Ambient Air Preparation Unit)

Kind of
Interval Action OK Comment
Action
If
necessary
Replace Soda Lime Maintenance 

Replace Gas Filter Maintenance 

3 Months
Replace Filter Mats Maintenance 

Replace Fine Filter Element Maintenance 

1 Year Replace Coarse Filter Element Maintenance 

Replace Activated Carbon Maintenance 

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question to visual inspections, please contact your local partner
or the Technical Support of LAR (Chapter 15 on page 257).
Notice

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9.4.5 Perform Visual Inspection (Ambient Air Preparation Unit)

Procedure for visual inspections:

• Use a visual inspection log (Ambient Air Preparation Unit) (Chapter 13.7 on page 246) for
documentation.
• Follow the instructions below for visual inspections of individual components.
• Carry out care and/or maintenance actions when test criteria are not met, and document them in the
care and/or maintenance log (Ambient Air Preparation Unit).
• After the check and any care and/or maintenance actions, conclude the documentation of the log(s).

Fig. 126: Inner space of the Ambient Air Preparation Unit

9.4.5.1 Fine Filter Element

• Open the Ambient Air Preparation Unit.
• Check the cleanliness of the condensate drain of the filter unit.
• Once all test criteria are met, proceed with the next step.

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9.4.5.2 Filter Unit

• Unplug the electrical connector for the compressor so that there is no more pressure in both filters.
• On both filters, pull the black lug down and turn the containers to release the containers of the
compressed air filter (coarse or fine).
• As a test, fill the containers with water (min. 30 ml) to above the float and reinsert them.
• Plug the electrical connector of the compressor back into the jack. The pressure rises and the
condensate should drain at a pressure > 1 bar.
• If it does not, the float mechanism is defective and the relevant filter unit needs to be replaced.
• Once all test criteria are met, proceed with the next step.

Maximum Water Level

Fig. 127: Sub-micro filter with the float

9.4.5.3 Soda Lime

• Look at the left cartridge filled with soda lime pellets.
• Check the white colour of the soda lime pellets.
• If up to 75% of the soda lime pellets are discoloured (purple/violet), they must be replaced
(Chapter 9.4.6.1 on page 192).
• Once the test criterion is met, proceed with the next step.

9.4.5.4 Tube Connections

• Check that all tube and screwed connections are hand-tightened.
• Once the test criterion is met, proceed with the next step.

9.4.5.5 Pre Pressure of the Carrier Gas

• Check that there is a carrier gas primary pressure and that it is 2 - 3 bar.
• Once the test criterion is met, proceed with the next step.

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9.4.6 Perform Care and Maintenance Actions (Ambient Air Preparation Unit)

Procedure for care and maintenance actions:

• Disconnect the electrical connection of the Ambient Air Preparation Unit to the analyser for care and
maintenance actions.
• Use a care and maintenance log (Ambient Air Preparation Unit) (if necessary copy from
Chapter 13.8 on page 247) for documentation.
• Follow the instructions below for care and maintenance actions for individual components.
• Document in the care and maintenance log the care and maintenance actions taken.
• Conclude documentation of the log once the care and maintenance actions are performed.
• Reconnect the electrical connection of the Ambient Air Preparation Unit to the analyser.

9.4.6.1 Replace Soda Lime

Precondition: - Soda lime is more than 75% discoloured (purple/violet).

Fig. 128: Soda Lime Cartridge

• Take the upper and lower tubes of the filter cartridge.

• Use a screwdriver to open the pipe clamps.
• Take the filter cartridge from the Ambient Air Preparation Unit.
• Carefully open the filter cartridge from the top. Mind out for the spring in the filter cartridge (Fig. 128,
page 192).
• Take the cover, O-ring, filter mats, perforated disc and spring.
• Dispose of used soda lime pellets in an environmentally responsible way.
• Fill new soda lime pellets into the filter cartridge, leaving enough space to fit the spring.
• Place the following components onto the soda lime pellets in this order - the filter mats, the
perforated disc, the spring and the O-ring into the groove of the filter cartridge. (Fig. 128, page 192).
• Now fit the cover by hand and attach it using the four screws.
• Fit the filter cartridge back into the pipe clamps.
• Reconnect the upper and lower tubes to the filter cartridge.

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Fig. 129: Filter Cartridge (exploded assembly drawing)

9.4.6.2 Replace Gas Filter

Recommendation: - Replace the gas filter every 3 months.

• Pull the connection tubes of the old filter from the connectors.
• Connect the new filter with the connection tubes of the Ambient Air Preparation Unit, noting the
direction of flow (black arrow).

Fig. 130: Gas Filter (Ambient Air Preparation Unit)

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9.4.6.3 Replace Filter Mats

Recommendation: - Replace filter mats every 3 months.

• Open the ventilation grids on the left and the right side of the analyser by levering out the ventilation
flap (Fig. 131, page 194).
• Replace the filter mats.
• Close the ventilation grids.

i • The Ambient Air Preparation Unit has two filter mats. One on the right and one on
the left side.
Notice

Fig. 131: Replace the Filter Mats on both sides of the Ambient Air Preparation Unit

9.4.6.4 Replace Fine Filter Unit

Recommendation: - Replace the fine filter unit every 12 months.

• To depressurise the filter unit, disconnect the compressor from the water separator (undo the tube on
the water separator).
• Pull the black lug of the left container down and turn the container to remove it.
• The sub-micro filter is visible.
• Unscrew the filter.
• Screw on the new filter.
• Fit the container onto it.
• Establish the connection to the compressor.

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9.4.6.5 Replace Coarse Filter Unit

Recommendation: - Replace the coarse filter unit every 12 months.

• To depressurise the filter unit, disconnect the compressor from the water separator (undo the tube on
the water separator).
• Pull the black lug of the left container down and turn the container to remove it.
• The white separator is visible.
• Turn the black plastic disc and take the white separator.
• Screw on the new filter.
• Fit the container onto it.
• Establish the connection to the compressor.

9.4.6.6 Replace Activated Carbon

Recommendation: - Replace the activated carbon every 12 months.

• Proceed analogously to the replacement of the soda lime in Chapter 9.4.6.1 from page 192.

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9.5 FlowSampler® LAR | PROCESS ANALYSERS AG

9.5 FlowSampler®

The FlowSampler® is a sample feed, which works without filtration according to the principle of inertia
separation because the sample is extracted in the centre of the sample flow in the opposite direction to
the main flow of the waste water. This means all solid and heavy coarse materials (such as sand) are
reliably removed. Smaller solid particles are caught, whereby the sample enters the analyser in its pure
form. The FlowSampler® can also master the most difficult challenges - including sample taking at a clar-
ification plant inlet in front of the coarse screen.

9.5.1 Variants of FlowSampler®

LAR offers two variants which differ by diameter size:

• FlowSampler® DN25
• FlowSampler® DN17

• The diameter size is dependent on the realisable flow rate of the sample.
i • If you have any question, please contact the Sales Departement of LAR
(Chapter 15 on page 257).
Notice

Material (depends on the temperature of the sample):

• from 00°C to 50°C: Polyvinylchloride (PVC)

• from 50°C to 90°C: Polypropylene (PP)

Numbers of sample streams:

• The FlowSampler® can be used for a maximum of six sample streams.

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9.5.2 FlowSampler® DN25

2 3

Legend:
1) Sampling Pipe (Needle) 4) Sample Inlet
2) Analyser Outlet (depressurized) 5) Window
3) Tube fitting (DN25) 6) Sample Outlet (DN25)
Fig. 132: FlowSampler® DN25

• Tube fitting (Sample Inlet and Outlet): DA = 32 mm

• Tube fitting (Analyser Outlet): DA = 32 mm

• Required Flow: 1.0 - 3.0 m3/h

• Sample backpressure on Outlet: depressurized (max. < 0.2 bar)

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9.5.3 FlowSampler® DN17

]XP$QDO\VDWRU 1
IU6FKODXFK
39&[3UHQH
=XODXI
33UREH

*HUlWHDEODXI2 [5RKUYHUVFKUDXEXQJ
'1'$ RGHU
GUXFNORV
4
6FKODXFK'$



%HIHVWLJXQJDP
/$50RQWDJHJHVWHOOPLW
5
[6FKUDXEH0[
RGHUDQGHU:DQGPLW


[+RO]VFKUDXEH[
6
5RKUYHUVFKUDXEXQJ
'1'$ RGHU
7
6FKODXFK'$ 

 8
 $EODXI
Legend: 3UREH
1) Sampling Pipe (Needle) 5) Window
2) Analyser Outlet In (depressurized) 6) Sample Outlet (DA=20 mm) $QJDEHQLQPP
3) Tube fitting (DA=20 mm) 7) Tube fitting (DA=32 mm)
4) Sample Inlet 8) Analyser Outlet Out
Fig. 133: FlowSampler® DN17

• Tube fitting (Sample Inlet and Outlet): DA = 20 mm

• Tube fitting (Analyser Outlet): DA = 32 mm

• Required Flow: 0.3 - 1.5 m3/h

• Sample backpressure on Outlet: depressurized (max. < 0.2 bar)

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9.5.4 Installation of the FlowSampler®

Ideally, LAR‘s FlowSampler® should be mounted immediately to the right of the analyser (e.g. on the
wall). So that the analyser drain inlet is at least 30 cm beneath the analyser.

The sample can be pumped for example with an immersion pump provided by the user. Depending on
the sample composition a cutting unit may be required. The immersion pump must ensure the required
flow rate of the FlowSampler® regarding to the distance.

Analyser Drain Analyser Inlet

Immersion Pump
(by User)
Sample Inlet

Sample Outlet

Fig. 134: Installation of the FlowSampler®

• The drain should be at least 30 cm beneath the analyser.

! • At the sampling pipe (needle) the sample must not be pressed out. Ideally, air
should be sucked into the FlowSampler® through the sampling pipe.
Caution

9.5.5 Start-Up of the FlowSampler®

• Establish all connections to the analyser and sample.

• Open the sample feed.

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9.5.6 Care and Maintenance Actions (FlowSampler®)

Only minor effort is required to service and maintain the FlowSampler®. This section shows the best way
to look after your FlowSampler® to guarantee trouble-free operation. The documentation of maintenance
and service work is a precondition for any warranty and guarantee claims, and also represents a valuab-
le aid in locating resolutions when malfunctions occur (Chapter 10 from page 221).

Table 28: Visual Inspection Log (FlowSampler®)

Interval Visual Inspection Criteria OK Action

 Contact Support
1 Week Flow • Transport of Liquids  _____________________
_____________________

Sampling Pipe
 Cleaning necessary
3 Months
(Needle)
• no contamination  _____________________
_____________________

Date: Signature:

Table 29: Care and Maintenance Log (FlowSampler®)

Kind of
Interval Action OK Comment
Action
If
necessary
Clean Sampling Pipe (Needle) Care 

3 Months Clean FlowSampler® Care 

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

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9.5.7 Perform Visual Inspections (FlowSampler®)

Procedure for visual inspections:

• Use a visual inspection log (FlowSampler®) (Chapter 13.9 on page 248) for documentation.
• Follow the instructions below for visual inspections of individual components.
• Carry out care and/or maintenance actions when test criteria are not met, and document them in the
care and/or maintenance log (FlowSampler®).
• After the check and any care and/or maintenance actions, conclude the documentation of the log(s).

9.5.7.1 Flow
• Look through the window to check if a steady, continuous liquid flow can be seen (No. 5 in Fig. 132,
page 197 or No. 5 in Fig. 133, page 198).
• Once the test criterion is met, proceed with the next step.

9.5.7.2 Sampling Pipe (Needle)

• Check the cleanliness of the sampling pipe (needle) of the FlowSampler®.

• Once the test criterion is met, proceed with the next step.

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9.5.8 Perform Care and Maintenance Actions (FlowSampler®)

Procedure for care and maintenance actions:

• Stop the Measurement Mode of the analyser with the Offline-Button.

• Close the sample inlet.
• Disconnect all connections of the FlowSampler®.
• Use a care and maintenance log (FlowSampler®) (if necessary copy from Chapter 13.10 on
page 249) for documentation.
• Follow the instructions below for care and maintenance actions for individual components.
• Document in the care and maintenance log the care and maintenance actions taken.
• Conclude documentation of the log once the care and maintenance actions are performed.
• Reconnect all connections of the FlowSampler®.
• Open the sample inlet.
• Start the Measurement Mode of the analyser with the Online-Button.

9.5.8.1 Clean Sampling Pipe (Needle)

Precondition: - Sampling pipe (needle) is contaminated.

• Detach the sampling pipe (needle) with a spanner.

• Clean the sampling pipe (needle).
• Fit the sampling pipe (needle).

9.5.8.2 Clean FlowSampler®

Recommendation: - Clean the FlowSampler® every 3 months

• Clean the FlowSampler® thoroughly.

• Clean the sample pipe with a pipe cleaner.
• Replace the tube to the analyser if necessary.

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9.6 CO2-Remover

The CO2-Remover serves to dry the compressed air and to remove the CO2 from the compressed air
and operates according to the principle of pressure swing adsorption. Two identical columns with a hy-
groscopic desiccant bed are used.

9.6.1 Procedure of compressed air drying and CO2 removal

The compressed air is transported through a filter and pressure regulator unit to the CO2-Remover. In
this filter and pressure regulator unit, most of the moisture, as well as oil aerosols and particles are re-
moved. The compressed air is then lead through one of the two columns of the CO2-Remover. Each co-
lumn contains a densely filled desiccant cartridge in which any remaining moisture and the contained
CO2 is adsorbed. Subsequently, a large portion of the CO2-free dry air flows through the particle filter
(<1 micron / ISO8573.1, class 2) from the CO2-Remover to the analyser.
For regeneration, a small amount of this CO2-free dry air flows down countercurrently through the other
desiccant cartridge, removing the absorbed moisture and the absorbed CO2 from this desiccant cart-
ridge. This air is released into the atmosphere and the desiccant cartridge is ready for the next adsorp-
tion.
The control switches regularly between the columns after renewed pressurisation at the upper end. This
ensures a continuous supply of CO2-free dry air at constant pressure. The CO2-Remover may also be
controlled by a zero-volt signal from the compressor. This energy saving mode detects when the com-
pressor is off and stops the operation until the compressor starts again.

9.6.2 Construction of the CO2-Remover

Fig. 135: Construction of the CO2-Remover

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9.6.3 Installation of the CO2-Remover

Installation of the CO2-Remover is depending on the preferred way of mounting it.

Variant 1 (without mounting):

• Place the CO2-Remover unit on the floor or the PVC plate of the mounting rack underneath the
analyser and mount the filter and pressure regulator of the CO2-Remover on the wall near the
analyser.

Variant 2 (Wall mounting):

• Install the CO2-Remover unit and the filter and pressure control unit on the wall near the analyser.

• When mounting on the wall, make sure that the CO2-Remover unit is in a vertical
! position by rearranging the mounting feet.
Caution

Fig. 136: Dimensions of the CO2-Remover

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LAR | PROCESS ANALYSERS AG 9.6 CO2-Remover

9.6.4 Start-Up of the CO2-Remover

• Make sure that air can flow before the CO2-Remover is put into operation (turned
! on). If the air does not flow, there may be a desiccant contamination, which means
that the desiccant has to be replaced.
Caution

Fig. 137: Start-Up of the CO2-Remover

• Connect all pipelines as shown in Fig. 137, page 205 to the CO2-Remover.
• Connect the CO2-Remover to a suitable power source (100 - 240 V AC / 50 - 60 Hz).
• Supply the CO2-Remover with suitable instrument air (in accordance to DIN ISO 8573-1) (4 to 12 bar
and +1,5°C to +50°C).

• Please ensure that the filter and pressure control unit is correctly connected to the
! CO2-Remover unit.
Caution

• Release the instrument air supply slowly until the CO2-Remover is under pressure.
• Turn on the CO2-Remover to display its status and begin operation.
• Let the CO2-Remover work for 2 cycles.
• After the first 2 cycles, open the exhaust valve of the CO2-Remover.

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9.6 CO2-Remover LAR | PROCESS ANALYSERS AG

9.6.5 Care and Maintenance Actions (CO2-Remover)

Only minor effort is required to service and maintain the CO2-Remover. This section shows the best way
to look after your CO2-Remover to guarantee trouble-free operation. The documentation of maintenance
and service work is a precondition for any warranty and guarantee claims, and also represents a valuab-
le aid in locating resolutions when malfunctions occur (Chapter 10 from page 221).

Table 30: Visual Inspection Log (CO2-Remover)

Interval Visual Inspection Criteria OK Action

• no damage  Contact Support
Housing
• no contamination

_____________________
1 Day
• red service-lamp is  Contact Support
Service-Lamp
inactiv

_____________________

Date: Signature:

Table 31: Care and Maintenance Log (CO2-Remover)

Kind of
Interval Action OK Comment
Action
12,000 Replace the desiccant cartridges Maintenance 
operating
hours
Replace the internal ball valves Maintenance 
(or every 2 Replace all seals which removed
during maintenance
Maintenance 
years)
24,000
operating
hours Replace the exhaust valves Maintenance 
(or every 4
years)

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

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LAR | PROCESS ANALYSERS AG 9.6 CO2-Remover

9.6.6 Perform Visual Inspections (CO2-Remover)

Procedure for visual inspections:

• Use a visual inspection log (CO2-Remover) (Chapter 13.11 on page 250) for documentation.
• Follow the instructions below for visual inspections of individual components.
• Carry out care and/or maintenance actions when test criteria are not met, and document them in the
care and/or maintenance log (CO2-Remover).
• After the check and any care and/or maintenance actions, conclude the documentation of the log(s).

9.6.6.1 Housing
• Check the housing of the CO2-Remover for integrity.
• If you see damage, please contact Technical Support.
• Check the CO2-Remover for cleanliness.
• If contamination is detected, remove it with a damp cloth.
• Once all test criteria are met, proceed with the next step.

• Do not clean the CO2-Remover with abrasives or solvents. Use only a mild
! detergent.
Caution

9.6.6.2 Service-Lamp
• Check the red service light for inactivity.
• If the red service light is lit, maintenance of the CO2-Remover is required to ensure the best possible
air quality. Please contact the Technical Support of LAR (Chapter 15 on page 257).
• Once the test criterion is met, proceed with the next step.

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9.7 Mounting Rack LAR | PROCESS ANALYSERS AG

9.7 Mounting Rack

The analyser can be supplied with an optional LAR mounting rack.

M1 M2

M3 M4

Q1
Q2

Legend:
M1 - M4: Holes for the fixing of the Analyser
Q1 - Q2: Holes for the fixing of the Ambient Air Preparation Unit / Reagent Cabinet
Fig. 138: LAR Mounting Rack

• The LAR mounting rack is not fully assembled on delivery. The cross braces and
! adjustable feet of the installation rack must be fitted before the installation.
Caution

Fig. 139: Mounting of the LAR Mounting Rack

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LAR | PROCESS ANALYSERS AG 9.7 Mounting Rack

The following installation dimensions must be observed:

• min. 1,500 x 2,000 x 1,420 mm (W x H x D)

• The distance to side and opposing walls must be kept so that the analyser can be
! swivelled open.
• If you do not have access to a forklift or lifting equipment, the analyser should be
Caution fitted by at least four people.

Recommendations for installation on the LAR mounting rack:

1) The simplest method is to lay the analyser in the horizontal (flat) position after pre-assembly onto the
similarly horizontal LAR installation rack and secure it with four M8 bolts (M1 - M4). It is then raised
into the vertical position using lifting equipment (or a crane).

or

2) In the second method, the analyser is mounted directly onto the vertical LAR rack using the M8 bolts.
The weight of the analyser means lifting equipment or a forklift is required for this variant. First,
screw two bolts into the upper holes of the rack so they protrude by about 15 mm. Then hook the
analyser into these bolts with the mounting eyes, and lower it until the rear part of the housing is
resting against the rack. Then screw the bottom bolts through the mounting eyes into the LAR rack,
and tighten all the bolts.

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9.8 Multi Stream Option LAR | PROCESS ANALYSERS AG

9.8 Multi Stream Option

The analyser may measure up to six sample streams in succession. Each sample stream is equipped
with a sample vessel and pump. The parallel switchover means that during the measurement cycle of
one sample the preparation of the next sample starts thus there are no measurement delays.

i
• For optimal operation, LAR recommends a maximum of four sample streams. This
ensures that calibration of the analyser and rinsing of the injection needle can be
automatic without any additional effort.
Notice

• For an analyser with five sample streams, there is only one position left for
! calibration vessel or rinsing vessel. This position may have to be swapped with the
calibration or rinse vessel depending on requirement. Only one place is available
Caution for one of the vessels.
• For an analyser with six sample streams, six sample vessels take up all the space
for vessels (V1-V6). For a calibration, the first vessel must be removed from the
position and be replaced by a calibration vessel. Before a calibration can be
performed, the positioning must be checked on the „Test Run“ display
(Chapter 7.2.13 from page 94). To rinse the injection needle, a sample preparation
vessel must be defined, at best in one in which no repeat measurements take place
and preferably low concentrations are present.

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LAR | PROCESS ANALYSERS AG 9.9 Multi Parameter Option

9.9 Multi Parameter Option

The analyser may measure multiple parameters with single sample streams. This can be factory-set or
be upgraded later.

The analyser can be fitted with up to four detectors for this option. The parameters can also be set for
every sample stream and channel.

The parameters can be measured are:

• TOC = Total Organic Carbon

• TIC = Total Inorganic Carbon
• TC = Total Carbon (TOC + TIC)
• COD = Chemical Oxygen Demand
• TNb = Total Nitrogen bound

i • Please contact the Sales Department of LAR if you are interested in upgrading to
this option (Chapter 15 on page 257).
Notice

9.10 High Salt Option

In contrast to many other analysers the QuickCOD®ultra can also work with salt loads up to 10 g/l without
problem, even up to 300 g/l cooking salt (NaCl) with the high salt option available additionally. This
means that the sample needs not be diluted, not even for the highest salt concentrations. This in turn
has a positive effect on the accuracy of measurement results.

When fitting the high salt option, you have instead of a standard reactor foot a high salt reactor foot -
which can be screwed off and is used for quick removal of salt residues. Also, the analyser has instead
of a standard reactor pipe a high salt reactor pipe which has a larger taper so that the salt residues do
not block the reactor pipe.

i • If you have any question, please contact the Sales Department of LAR
(Chapter 15 on page 257).
Notice

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 9 Accessories and Options
9.11 Auto-TIC-Port LAR | PROCESS ANALYSERS AG

9.11 Auto-TIC-Port

An Auto-TIC-Port considerably reduces the efforts for care and maintenance work of the analyser.
The injection by the Auto-TIC-Port is effected automatically by a mechanical motor which can open and
close the injection channel (similiar to the injection port on the furnace head).

The benefits here are increased level of sealing which will result in increased measurement accuracy
and less maintenance.

9.11.1 Construction of the TIC Reactor with Auto-TIC-Port

Legend:
1) TIC reactor with Auto-TIC-Port 3) TIC stripping vessel
2) Auto-TIC-Port 4) Tube connections

Fig. 140: TIC Reactor with Auto-TIC-Port

9.11.2 Start-Up of the TIC Reactor with Auto-TIC-Port

If ordered, the TIC reactor with Auto-TIC-Port is delivered with the analyser preconfigured by the manu-
facturer.

i • If you want to add this option to an existing analyser, please contact your local
partner or the Technical Support of LAR (Chapter 15 on page 243).
Notice

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LAR | PROCESS ANALYSERS AG 9.11 Auto-TIC-Port

9.11.3 Care and Maintenance Actions (Auto-TIC-Port)

Only minor effort is required to service and maintain the Auto-TIC-Port. This section shows the best way
to look after your Auto-TIC-Port to guarantee trouble-free operation. The documentation of maintenance
and service work is a precondition for any warranty and guarantee claims, and also represents a valuab-
le aid in locating resolutions when malfunctions occur (Chapter 10 from page 221).

Table 32: Visual Inspection Log (Auto-TIC-Port)

Interval Visual Inspection Criteria OK Action

• Ease of movement of
Micro-switch on
the closing and  Contact support
6 Months
Auto-TIC-Port
opening function  _____________________
• Observance of the _____________________
minimum distance

Date: Signature:

Table 33: Care and Maintenance Log (Auto-TIC-Port)

Kind of
Interval Action OK Comment
Action

Replace needle guide seal Maintenance 

1 Month
Clean needle guide Care 

3 Months Clean and oil the Auto-TIC-Port Care 

Date: Signature:

• A corresponding copy of the log is in Chapter 13 from page 239.

i • If you have any question to visual inspections, please contact your local partner
or the Technical Support of LAR (Chapter 15 on page 257).
Notice

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9.11 Auto-TIC-Port LAR | PROCESS ANALYSERS AG

9.11.4 Perform Visual Inspections (Auto-TIC-Port)

Procedure for visual inspections:

• Use a visual inspection log (Auto-TIC-Port) (Chapter 13.13 on page 252) for documentation.
• Follow the instructions below for visual inspections of individual components.
• Carry out care and/or maintenance actions when test criteria are not observed, and document them
in the care and/or maintenance log (Auto-TIC-Port).
• After the check and any care and/or maintenance actions, conclude the documentation of the log(s).

9.11.4.1 Microswitch on Auto-TIC-Port (6 Months)

4
1

2 5 6

Legend:
5) Cover Cap 8) Micro-switch housing
6) Injection Valve 9) Switch lever of micro-switch
7) 4x Screws M3x6, 4x Washers M3 10) Switch knob on valve cock plug
Fig. 141: Injection valve

• Stop the Measruement Mode of the Analyser with the Oflline-Button.

• Undo the two Torx screws (No. 3 in Fig. 141, page 214) with spring washers on the cover cap.
• Pull the cover cap upwards.
• Access the “Service actions” display.
• Close and open the injection port to test the ease of movement of the closing and opening functions
for the injection port (rotation test).

• Closing and opening effects rotation of the valve cock plug.

i • There is a switch knob on the valve cock plug (No. 6 in Fig. 141, page 214). When
the valve is closed, the valve cock plug turns until the switch knob on the next
Notice switch lever of a micro-switch triggers the switch process and ends rotation of the
valve.

• When turning the valve cock plug, check that the switch levers of the micro-switch are not pressed
down onto the micro-switch housing by the switch knob of the valve cock plug.
• Ensure that a minimum distance of 1 mm between the switch levers of the micro-switches and the
respective micro-switch housing is not dropping below.
• If the test criteria are not met, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).

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LAR | PROCESS ANALYSERS AG 9.11 Auto-TIC-Port

• Keep away fingers from the switch area when the valve switches (as there is a
! crushing risk).
Caution

• Once all test criteria are met, screw on the cover cap of the Auto-TIC-Port.

9.11.5 Perform Care and Maintenance Actions (Auto-TIC-Port)

Procedure for care and maintenance actions:

• Stop the Measurement Mode of the analyser with the Offline-Button.

• Take a care and maintenance log (Auto-TIC-Port) (if necessary copy from Chapter 13.14 on
page 253).
• Follow the instructions below for care and maintenance actions for individual components.
• Document in the care and maintenance log the care and maintenance actions taken.
• Conclude documentation of the log once the care and maintenance actions are performed.
• Start the Measurement Mode of the analyser with the Online-Button.

9.11.5.1 Replace Needle Guide Seal (Auto-TIC-Port) (1 Month)

Recommendation: - Replace needle guide seal (Auto-TIC-Port) every month.

• Unscrew the union nut of the Auto-TIC-Port (Fig. 142, page 216).
• Lift the top part of the needle guide and remove the old needle guide seal (Fig. 142, page 216).
• Insert the new needle guide seal into the clean groove.
• Place the top part of the needle guide onto the lower part of the needle guide.
• Tighten the union nut again.

• Do not remove the needle guide seal with a screwdriver or other sharp object
! because this could scratch the groove, thereby causing leaks. Instead, use a soft
object like a wooden toothpick or pencil to lever out the seal.
Caution

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 9 Accessories and Options
9.11 Auto-TIC-Port LAR | PROCESS ANALYSERS AG

9.11.5.2 Clean Needle Guide (Auto-TIC-Port) (1 Month)

Recommendation: - Clean the needle guide every month.

• Detach the Auto-TIC-Port from the TIC stripping vessel.

• Unscrew the cover cap.
• Unscrew the union nut and the attachment of the needle guides (No. 1 & 2 in Fig. 142, page 216).
• Use a moist paper towel and rinsing water (Chapter 6.1.2 on page 56) to clean the needle guides
and all individual parts.
• If the level of contamination is high, first clean the needle guides mechanically and then in a bath
(with 1% phosphoric acid).
• After the cleaning process, refit all individual parts for the complete injection port.
• Screw the needle guides and union nut back onto the Auto-TIC-Port.
• Fix the cover cap (handtightened).
• Check the position. If necessary adjust (Auto-TIC-Port should point to the front left at angle).
• Perform a test run (Chapter 7.2.13 from page 94).

• Please note the order in which the individual parts are fitted. First the washer, then
! the cock plug seal and finally the union nut for the cock plug.
• To mount the injection valve, two spacer sleeves have to installed in front of the
Caution M3x45 screws.

5Nadelführung unten

9 6

Legend:
1) Union Nut 7) Spacer sleeves
2) Attachment for upper needle guide 8) Union nut for cock plug
3) Upper needle guide 9) Injection valve (Auto-TIC-Port)
4) Needle guide seal
5) Lower needle guide
6) Cock plug
Fig. 142: Injection valve (Auto-TIC-Port)

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 9 Accessories and Options
LAR | PROCESS ANALYSERS AG 9.11 Auto-TIC-Port

9.11.6 Clean and oil Auto-TIC-Port (3 Months)

Recommendation: - Clean and oil the Auto-TIC-Port every 3 months.

• Unscrew the Auto-TIC-Port from the TIC stripping vessel.

• Unscrew the cover cap to access the cock plug.
• Undo the two screws of the attachment between motor and injection valve carefully (because there is
a spring between the motor and cock plug).
• Take the motor. The injection valve is now free.
• Unscrew the union nut (red screw joint) of the cock plug.
• Moisten a lint-free paper or cleaning cloth (you can use a pipe cleaner for openings).
• Thoroughly clean the surface of the injection valve and cock plug.
• Apply a very thin layer of oil to the front and rear areas of the cock plug.
• Now push the cock plug back into the opening of the injection valve.
• Turn it inside the injection valve for good distribution of the oil.
• Fit the washer in front of the cock plug seal and the union nut (No. 6 and No. 8 in Fig. 142, page 216)
when the cock plug is in the injection valve.
• Screw the complete injection valve onto the Auto-TIC-Port.
• Secure the two M3x45 screws to attach the injection valve.
• Fit the cover cap (tighten by hand).

! • There is a pressure spring between the cock plug and motor!

Caution

Fig. 143: Clean valve Fig. 144: Oil the Cock Plug thin

Fig. 145: Three steps to mount the components of the valve

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 9 Accessories and Options
9.12 Internal Sample Dilution LAR | PROCESS ANALYSERS AG

9.12 Internal Sample Dilution

Complex sample matrices and/or very high salt concentrations can have a strong impact on the sample
properties and the system, and/or seriously load individual components - something which can entail
higher maintenance effort. The “Internal sample dilution” option can be of assistance in these cases.
Here the sample is diluted with deionised water at an adjustable ratio. If ordered, the internal sample
dilution will be factory-preconfigured in the analyser.

• With „Internal Sample Dilution“ the position for vessel V6 is used for the sample

i dilution vessel. The pump GP7 transports the deionised water in this vessel.
Another position (Vx) is occupied with the rinsing vessel. Thus, when using this
option a maximum of 4 sample streams will be measured/are realized in the
Notice
analyser.

9.12.1 Software Settings for the Internal Sample Dilution

The setting for the internal sample dilution can be configured in the “Measurement Parameters” display
(Chapter 7.2.2 on page 70) with User Level 3.

• For appearance of this option in the software, it must be activated by LAR or an

i authorized partner.
• Users wanting to use the functions on User level 3 must have undergone training
Notice beforehand at LAR. If you are interested in technical training, please contact the
Technical Support of LAR (Chapter 15 on page 257).

Fig. 146: Measurement Parameters - Internal Sample Dilution (Example)

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 9 Accessories and Options
LAR | PROCESS ANALYSERS AG 9.12 Internal Sample Dilution

Dilution factor (only Level 3):

This factor can be set from 1:5, 1:10, 1:15, 1:20 by the user. If one of the settings is changed, a new
calibration must be carried out.

Fill time of the dilution vessel (only Level 3):

This parameter shows how long the pump is active in order to pump sufficient distilled water into the di-
lution vessel. This parameter can only be viewed.

Dilution time (only Level 3):

Afte the sample has been injected into the sample dilution vessel, the dilution (mixing the sample and
water) will start. After this the sample is taken from the vessel. This parameter can only be viewed.

9.12.2 Flow Diagram with Internal Sample Dilution

-MM
NO
-GS NC
I/O

-CM10
?

@
-CM1 -CM7 -CM8 -CM6
M

-RM

-EB -BP2
-GP2 -GP7
1200°
-BF1

FA
-HS1 -HQ1

-KH2
NC

I/O

-Y1 -BP1
-EC
FA NO

-BM

IR 1

Q -GP1
-KH1
-BF2 -B1 -HQ2

Fig. 147: Flow Diagram with Internal Sample Dilution (TConly Method - 1 Sample Stream)

• The care and maintenance of the internal dilution option includes the visual

i inspection of the glass components (Chapter 8.3.5 from page 135), the cleaning of
the glass components (Chapter 8.5.2 from page 142) as well as the replacement of
the silicone seals for glass components (Chapter 8.7.17 on page 166).
Notice
• Note that for the dilution vessel special silicone seals are used.
• If you are interested to upgrade your analyser with this option, please contact the
Sales Department of LAR (Chapter 15 on page 257).

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 9 Accessories and Options
9.12 Internal Sample Dilution LAR | PROCESS ANALYSERS AG

220 Instruction Manual QuickCOD®ultra 07E4317

 10 Minor disruptions - quickly rectified
LAR | PROCESS ANALYSERS AG 10.1 Preconditions for fault-free Measurement Mode

10 Minor disruptions - quickly rectified

10.1 Preconditions for fault-free Measurement Mode

If disruptions of your analyser occur during measurement mode and the causes are not entirely obvious,
please check the following:

a. Ambient conditions
The ambient temperature must be within the range permitted, 5 °C - 35 °C. The relative humidity should
be below 80% (not condensing).

b. Chemicals used
It is advisable to renew all chemicals and calibration standards when you notice that readings or
reproducibility are/is being severely impacted. Contamination of phosphoric acid, hydrochloric acid,
rinsing water and calibration standards can severely impact measurement results and reproducibility. To
prevent gas from forming in the injection system, it is important to acidify the rinsing water of the needle
to pH3.

c. Configuration of the software

If there are questions about the configuration, note the system parameters and please contact your
local partner or the Technical Support of LAR (Chapter 15 on page 257). A USB stick may be used
to store screenshots generated with the Screenshot button (which show system parameters for
example).

d. Autostart in the event of a power cut

After a power outage, the analyser automatically performs an Autostart. If the analyser was performing
a measurement at the time of the power outage, the analyser continues the measurement. The Autostart
can be prevented by pressing the red “Offline” button. If the temperature of the furnace drops so much
during a power outage that it is no longer within the temperature tolerance, the furnace is, after the
Autostart, first heated until it has reached its target temperature. Only then the measurement will be
continued.

e. Storage of the analyser in dry conditions which are protected from frost
The analyser must be stored under dry conditions, protected from frost. The period of storage should not
exceed 6 months.

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 10 Minor disruptions - quickly rectified
10.2 Breakdowns LAR | PROCESS ANALYSERS AG

10.2 Breakdowns

This section provides information on and solutions for possible malfunctions with the measurement
system. Possible causes and actions are listed in the following table - the problem type is used as an
indicator. If you have questions, please contact your local partner or the Technical Support of LAR
(Chapter 15 on page 257).

Table 34: Troubleshooting

Problem Possible cause Actions

Analyser does not start • No voltage • Check the fuses (Chapter 10.3 on
after connecting the power • No power page 223).
supply plug and switching • Switch on if necessary.
the main switch to „ON“
Software does not start/ • Main siwitch off • Switch on the analyser using the
Screen is black • Blown fuse(s) main switch on the left side of the
analyser.
• Check the fuses (Chapter 10.3 on
page 223).
Cooler temperature is too • Ambient temperature is • Ensure the ambient temperature is
low or high too low or high between 5 °C - 35 °C.
• Cooler fuses are blown • Replace the fuses
• Cooler is out of order • Contact your local partner or the
Technical Support of LAR
(Chapter 15 on page 257)
Furnace temperature is too • Furnace fuse is blown • Switch on the fuses
low or high • Connecting cable is • Check the connections
defective • Contact your local partner or the
• Furnace is defective Technical Support of LAR
(Chapter 15 on page 257)
The difference of • Thermocouple is not at • Contact your local partner or the
temperature and the right position or Technical Support of LAR
temperature regulator is defective (Chapter 15 on page 257)
more than 10°C
Calibration values are not • Calibration standard • Produce a new calibration standard
plausible empty or prepared false • Perform a new calibration
Measurement values sway • Sample vessels are • Clean sample vessels
strongly contaminated • Check injection system (glass
• High particle density syringe)
• Bubbles in the injection • Check tighteness and rectify leaks
system
• System leaky
Measurement cannot start • Temperature of cooler or • Check the temperature of the cooler
furnace is not in the and the furnace
allowed range
• Analyser is in
maintenance mode
Error E1810 is shown • Emergency shutdown of • Contact your local partner or the
the furnace Technical Support of LAR
• Error in the position of (Chapter 15 on page 257)
the injection system immediately!

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 10 Minor disruptions - quickly rectified
LAR | PROCESS ANALYSERS AG 10.3 Check the Fuses - Automatic Circuit Breaker

Table 34: Troubleshooting

Problem Possible cause Actions

Needle is dripping • Injection system leaky • Check the tubing of the injection
system.
• Contact your local partner or the
Technical Support of LAR
(Chapter 15 on page 257)
Injection needle does not • Positions have been • Perform a test run and adjust the
hit the needle guide of the altered due to injection positions (Chapter 7.2.13
furnace or other maintenance or care from page 94).
x-positions actions

10.3 Check the Fuses - Automatic Circuit Breaker

A measurement must be ended and the analyser switched off (main switch) before a fuse can be
checked or replaced. Unlock the housing using the key. The automatic circuit breaker is on the rear
installation plate (Fig. 15, page 18). If a fuse has blown, tilt the lever back up to its original position.

Table 35: Check the Fuses

115 V AC 230 V AC
Fuses
Power Supply Power Supply
Analyser (F1) 8 A Type K 8 A Type K

The cooler has 2 x internal 5 AT fuses, which can be checked and/or replaced by unscrewing them from
the back of the plate on the cooler when the rear housing part is opened.

• If a fuse blows again when the analyser is switched on, please contact your local
! partner or the Technical Support of LAR (Chapter 15 on page 257).
Caution

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 10 Minor disruptions - quickly rectified
10.4 Breakdowns of the Temperature Regulators LAR | PROCESS ANALYSERS AG

10.4 Breakdowns of the Temperature Regulators

Your analyser is fitted with a high temperature furnace which facilitates conversion in full of the carbon
contained in the sample to CO2 without catalysts. The target temperatures of the furnace regulators are
factory-set and password-protected.

The programming of the temperature regulator may not be changed. If you have questions, please
contact your local partner or the Technical Support of LAR (Chapter 15 on page 257).

Target temperature ranges of the individual units of the analyser:

Temperature Furnace: 1,180°C – 1,250°C

Temperature Cooler: 4°C – 5°C

Table 36: Error message of the temperature regulator

Display Description Troubleshooting

9999 No connection between temperature • Check the electrical connections, renew
(blinking) element and regulator. the thermocouple if required.
• If the temperature regulator is still
inactive after the thermocouple is
replaced, go to display “Service actions”
(Chapter 7.2.11 on page 88) and
activate „furnace“.

Actual

Target

Fig. 148: Temperature Regulator on the Front Plate

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 11 Technical Information
LAR | PROCESS ANALYSERS AG 11.1 Analyser Specifications

11 Technical Information

i • We reserve the right to make all graphical, electronic and mechanical modifications
serving the purposes of technical progress.
Notice

11.1 Analyser Specifications

Table 37: Analyser Specifications

Type Dimensions/ Description

Housing Splash proof steel housing (IP54), powdercoated
Dimensions approx. 600 x 1,062 x 608 mm (W x H x D) for 1 sample
stream
approx. 820 x 1,062 x 608 mm (W x H x D) for 2 - 6 sample
streams
Weight approx. 115 kg
Power supply 115/230V at 50/60Hz
(Note specification on nameplate) Fusing: min. 16A (K-Characteristics)
Power input max. 900 VA, average 600 VA
Signal output Quantity: 2 - 33 Analog outputs (depending on configuration)

Caution: Every analog output is galvanically isolated from

each other and the analog outputs are also galvanically
isolated from the housing.

0 – 20mA or 4 – 20mA
max. load 500 ohm
Interfaces RS232 serial interface
Sound power level max. 70 dB
Potential free contacts 8 programmable relays (NO or NC)

Voltage: max. 24 V=, 24V~

Amperage: max. 1 A=, 1A~
USB interface USB 2,0
Display 10.4“ resistive Touchscreen, TFT Display
Carrier gas consumption Standard: approx. 30 l/h / High salt: approx. 20 l/h
External air supply (optional) Dew point: max. –5°C
Digital inputs 8 digital inputs

07E4317 Instruction Manual QuickCOD®ultra 225

 11 Technical Information
11.2 Ambient Conditions LAR | PROCESS ANALYSERS AG

11.2 Ambient Conditions

Table 38: Ambient Conditions

Type Dimensions/ Description

Temperature min. 5°C - max. 35°C
Humidity max. 80%
Mounting dimensions
min. 1,030 x 1,720 x 1,210 mm (W x H x D)
(Wall mounting)
Mounting dimensions
min. 1,070 x 2,000 x 1,420 mm (W x H x D)
(LAR mounting rack)

11.3 Specifications of Accessories and Options

Table 39: Specifications of Accessories and Options

Type Dimensions/ Description

Dimensions of the LAR Mounting approx. 1,000 x 2,000 x 815 mm (W x H x D);
Rack Weight: approx. 65 kg
Dimensions of the Ambient Air approx. 500 x 555 x 400 mm (W x H x D);
Preparation Unit
Dimensions of the Permeation Unit approx. 300 x 400 x 220 (W x H x D)
Dimensions of the CO2- Remover approx. 268 x 440 x 210 mm (W x H x D)
Dimensions of the Reagent Cabinet approx. 500 x 500 x 300 mm (W x H x D)
Space for 2x 5l Canister
Dimensions of the FlowSampler® FlowSampler® mounting plate:
approx. 400 x 500 x 120mm (W x H x D)

FlowSampler® mounting plate, 2 sample streams

approx. 400 x 500 x 240 mm (W x H x D)

226 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG

12 Flow Diagrams for QuickCOD®ultra

The analyser can be operated with different configurations and methods. Furthermore, several methods
can be used in one analyser. On the following pages you will find flow diagrams of different methods and
configurations.

i • If you have questions, please contact your local partner or the Technical
Support of LAR (Chapter 15 on page 257).
Notice

07E4317 Instruction Manual QuickCOD®ultra 227

 12 Flow Diagrams for QuickCOD®ultra
12.1 Component Labeling LAR | PROCESS ANALYSERS AG

12.1 Component Labeling

Table 40: Component Labeling

Component Labeling
NDIR 1 B1
NDIR 2 B2
NO detector B3
O2 detector B4
Flow sensor BF1 - BF2
Humidity sensor BM
Pressure display BP1
Pressure sensor BP2
Pressure gauge (Ambient Air Preparation Unit) BP10
Sample vessels CM1 - CM6
Rinsing vessel CM7
Calibration vessel CM8
TIC reactor CM9
Canister (rinsing water) CM10
Canister (phosphoric acid) CM11
Canister (hydrochloric acid) CM12 - CM16
Furnace EB
Gas cooler EC
Air pump (Ambient Air Preparation Unit) GQ
Condensate pump GP1
Sample pump GP2 - GP7
External acidification GP12 - GP17
XY-System GS
Quartz wool filter HQ1
Fine filter HQ2
Activated carbon filter HQ3
Gas filter (Ambient Air Preparation Unit) HQ10
Air-water separator (Ambient Air Preparation Unit) HQ11
Compressed air filter 1 (Ambient Air Preparation Unit) HQ12
Compressed air filter 2 (Ambient Air Preparation Unit) HQ13
Gasfilter (Ambient Air Preparation Unit) HQ14
Acid trap small HS1
Acid trap big HS2
Activated carbon (Ambient Air Preparation Unit) HS11
Soda lime (Ambient Air Preparation Unit) HS12
Pressure regulator KH1
Flow regulator KH2
Pressure regulator (Ambient Air Preparation Unit) KH10
Syringe unit MM
Check valve furnace RM1
Check valve NPOC RM12 - RM17
Restrictors RN1 - RN7

228 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 12.1 Component Labeling

Table 40: Component Labeling

Component Labeling
Humidity valve Y1
TIC valve Y2Y1 - Y2Y2

07E4317 Instruction Manual QuickCOD®ultra 229

 12 Flow Diagrams for QuickCOD®ultra
12.2 CODo Method (1 Sample Stream) LAR | PROCESS ANALYSERS AG

12.2 CODo Method (1 Sample Stream)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1

-BM
I/O

NO
NC

-Y1

-HQ2
-CM8
-CM7

-HQ3
FA

-BF2
-CM1

Q
-GP2

-B4
O2

Fig. 149: Flow Diagram for CODo Method (1 Sample Stream)

230 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 12.3 CODi Method via TOC-Difference Method (1 Sample Stream)

12.3 CODi Method via TOC-Difference Method (1 Sample Stream)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-HQ1

-EC
NO
-RM2

I/O

-Y2Y1
-GS

-GP1
NC

NC
-Y2Y2

I/O
-CM9

NO
-GP1

-GP1

-CM11

-HS1
-BM
I/O

NO
NC

-Y1

-HQ2
Q

-B1
IR 1

-B2
IR 2



-B3
NO
-CM1

-GP2

-HQ3
-CM7

FA

-BF2
Q
-CM8



-B4
O2

Fig. 150: Flow Diagram for CODi Method via TOC-Difference Method (1 Sample Stream)

07E4317 Instruction Manual QuickCOD®ultra 231

 12 Flow Diagrams for QuickCOD®ultra
12.4 CODi Method via TOC-Difference Method (3 Sample Streams) LAR | PROCESS ANALYSERS AG

12.4 CODi Method via TOC-Difference Method (3 Sample Streams)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-HQ1

-EC
NO
-RM2

I/O

-Y2Y1
-GS

-GP1
NC

NC
-Y2Y2

I/O
-CM9

NO
-GP1

-GP1

-CM11

-HS1
-BM
I/O

NO
NC

-Y1

-HQ2
Q

-B1
IR 1
-CM3

-GP4

-B2
IR 2


-CM2

-GP3

-B3
NO
-CM1

-GP2

-HQ3
-CM7

FA

-BF2
Q
-CM8



-B4
O2

Fig. 151: Flow Diagram for CODi Method via TOC-Difference Method (3 Sample Streams)

232 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 12.5 CODi Method via TOC-Direct Method (1 Sample Streams)

12.5 CODi Method via TOC-Direct Method (1 Sample Streams)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1
-HS2

-BM
I/O

NO
NC

-Y1

-HQ2
Q

-B1
IR 1

-B2
IR 2


-RN1

-RM2

-B3
-CM12

NO
-GP12
-CM1

-HQ3
-CM7

FA

-BF2
Q


-CM8

-B4
O2

Fig. 152: Flow Diagram for CODi Method via TOC-Direct Method (1 Sample Streams)

07E4317 Instruction Manual QuickCOD®ultra 233

 12 Flow Diagrams for QuickCOD®ultra
12.6 CODi Method via TOC-Direct Method (2 Sample Streams) LAR | PROCESS ANALYSERS AG

12.6 CODi Method via TOC-Direct Method (2 Sample Streams)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1
-HS2

-BM
I/O

NO
NC

-Y1

-HQ2
-RM3
-RN2

-B1
-CM13

IR 1
-GP13

Q
-CM2

-B2
IR 2


-RN1

-RM2

-B3
-CM12

NO
-GP12
-CM1

-HQ3
-CM7

FA

-BF2
Q


-CM8

-B4
O2

Fig. 153: Flow Diagram for CODi Method via TOC-Direct Method (2 Sample Streams)

234 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 12.7 CODi Method via TConly Method (1 Sample Stream)

12.7 CODi Method via TConly Method (1 Sample Stream)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1

-BM
I/O

NO
NC

-Y1

-HQ2
Q

-B1
IR 1



-B2
IR 2

-B3
NO
-CM1

-GP2
-CM7

FA

-BF2
-CM8

Fig. 154: Flow Diagram for CODi Method via TConly Method (1 Sample Stream)

07E4317 Instruction Manual QuickCOD®ultra 235

 12 Flow Diagrams for QuickCOD®ultra
12.8 CODi Method via TConly Method (2 Sample Streams) LAR | PROCESS ANALYSERS AG

12.8 CODi Method via TConly Method (2 Sample Streams)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM1

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1

-BM
I/O

NO
NC

-Y1

-HQ2
Q

-B1
IR 1



-B2
IR 2
-CM2

-GP3

-B3
NO
-CM1

-GP2
-CM7

FA

-BF2
-CM8

Fig. 155: Flow Diagram for CODi Method via TConly Method (2 Sample Streams)

236 Instruction Manual QuickCOD®ultra 07E4317

 12 Flow Diagrams for QuickCOD®ultra
LAR | PROCESS ANALYSERS AG 12.9 Flow Diagram of the Ambient Air Preparation Unit (Option)

12.9 Flow Diagram of the Ambient Air Preparation Unit (Option)

-HS11

-HQ14
-HS12
-BP10

-KH10
-HQ13
-HQ12
-HQ11
-GQ
-HQ10

Fig. 156: Flow Diagram of the Ambient Air Preparation Unit (Option)

07E4317 Instruction Manual QuickCOD®ultra 237

 12 Flow Diagrams for QuickCOD®ultra
12.10 Flow Diagram with Internal Sample Dilution (Option) LAR | PROCESS ANALYSERS AG

12.10 Flow Diagram with Internal Sample Dilution (Option)

-CM10

-BP2

-KH2

-KH1
-BP1
-RM

-BF1
FA
NO

I/O
-MM

M
NC

-GP1
1200°
-EB

-EC
-GS

-HQ1
-HS1

-BM
I/O

NO
NC

-Y1

-HQ2
-CM6
?


-GP7
@

-B1
IR 1
-CM8
-CM7

FA

-BF2
-CM1

-GP2

Fig. 157: Flow Diagram with Internal Sample Dilution (TConly Method - 1 Sample Stream)

238 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG

13 Operating, Care and Maintenance Logs

On the following pages are the log book and the logs mentioned in the operating manual (as copies).
The recommendation is to make a few copies and include them at the end of this operating manual or
separately in a folder.

• Do not write anything in the templates in this section.

! • Please copy the logs you need for documentation.
Caution

07E4317 Instruction Manual QuickCOD®ultra 239

 13 Operating, Care and Maintenance Logs
13.1 Operating Log LAR | PROCESS ANALYSERS AG

13.1 Operating Log




 










 


 









240 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.2 Visual Inspections Log (Analyser)

13.2 Visual Inspections Log (Analyser)

Interval Visual Inspection Criteria OK Action

 Check soda lime
Zero Signal • 0 - 0.1 FSR   Contact support
• Carrier Gas IN / OUT:  Check connections
Carrier Gas 
approx. 20 l/h  Contact support
• no air bubbles in the tube
Injection System   Rinsing necessary
or glass syringe
• no contamination  Cleaning necessary
1 Week Injection Needle 
• smooth surface  Replace needle
Glass Components • no contamination   Cleaning necessary
• fill level > 1 litre  Fill canister
Canisters and Supply
• no contamination   Clean canister
Tubes
• normal elasticity  Replace tube
• no contamination  Replace tube
Drain and Inlet Tubes 
• normal elasticity _____________________
• no contamination  Cleaning necessary
Injection Tube 
• normal elasticity  Replace tube
TIC Stripping Vessel • no contamination   Cleaning necessary
• no contamination  Cleaning necessary
Slide Rails
(XY-System)
• optimal grease state   Grease necessary
• mechanical play  Contact support
• no moisture  Cleaning necessary
Tube Cassette Pump • rolls easily movable  Put forth tubes

and Pump Tubes • no contamination  Replace tubes
3 Months • normal elasticity  Contact support
Sample Pump and • no contamination  Cleaning necessary

Pump Tubes • rolls easily movable  Contact support
• no contamination  Cleaning necessary
Viton Tubes 
• normal elasticity  Replace tubes
Filter Mats • no discolouration   Replace filter mats
• zinc is > 1/3 shiny  Replace filling material
Acid Trap 
• brass wool > 1/3 yellow  Replace acid trap
• no moisture  Replace filling material
Quartz Wool Filter 
• no discolouration  Replace filter

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 241

 13 Operating, Care and Maintenance Logs
13.3 Care Log (Analyser) LAR | PROCESS ANALYSERS AG

13.3 Care Log (Analyser)

Interval Action Done Comment

Rinse the Injection System 
Clean Glass Components 
Fill Canisters 
Clean Canisters 
Clean Supply Tubes 
Clean Inlet and Drain Tubes 
Clean Teflon Tube (Reactor Foot) 
Clean Reactor Foot 
Clean Injection Tube 
If Clean Reactor Pipe 
necessary
Clean TIC Stripping Vessel 
Clean Gas Cooling Pipe 
Clean Running Rails (XY-System) 
Grease Running Rails (XY-System) 
Clean Tube Cassette Pump and Pump

Cassettes
Clean Sample Pump 
Adjust Sample Pump 
Clean Viton Tube 
Clean Injection Needle 
1 Week Renew Calibration Standard 
1 Month Clean Needle Guide (Injection Port) 
Check the Furnace System 
Check the Gas Cooling Pipes 
3 Months
Clean and oil the Injection Port 
Move Pump Tubes (Tube Cassette Pump) 
Check the mechanical backlash of the XY-

System
6 Months Check the Injection Port 

Date: Signature:

242 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.4 Maintenance Log (Analyser)

13.4 Maintenance Log (Analyser)

Interval Action Done Comment

Replace Supply Tubes 
Replace Inlet and Drain Tubes 
Replace Teflon Tube (Reactor Foot) 
Replace Reactor Pipe Filling / Reactor Pipe 
Replace Small Furnace Head Seal (upper) 
Replace Big Furnace Head Seal (Silicone
O-Ring with PFA coat)

If
necessary Replace Injection Tube 
Replace Viton Tube 
Replace Acid Trap filling 
Replace Acid Trap 
Replace Quartz Wool Filter filling 
Replace Quartz Wool Filter 
Replace Filter Mats 
Replace Injection Needle 
1 Week Replace Silicone Seal for TIC-Port 
Replace Needle Guide Seal (Injection Port) 
1 Month Replace Silicone Seals for Glass Compo-
nents

3 Months Replace Seal for Reactor Foot 
Replace Pump Tube (Tube Cassette Pump) 
6 Months
Replace Pump Tube (Sample Pump) 
1 Year Replace Gas Filter 

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 243

 13 Operating, Care and Maintenance Logs
13.5 Function Test Log (Analyser) LAR | PROCESS ANALYSERS AG

13.5 Function Test Log (Analyser)

Visual Inspection Criteria OK Action

• Zero signal is between  Contact Support
0 - 0.1 FSR __________________________
Check Analyser • Carrier Gas IN / OUT:  __________________________
approx. 20 l/h __________________________
__________________________
• Carrier gas volume flow  Contact Support
Tightness Test 
falls to < 5 l/h __________________________
• All positions are hit by the  Contact Support
Test Run (XY-System) 
injection needle __________________________
• Measurement results
Checking the  Contact Support
matches the calibration 
Measurement Results __________________________
standard
• Measurement Process
Checking the  Contact Support
goes on without 
Measurement Process __________________________
complications

Date: Signature:

244 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.6 Visual Inspection Log (Permeation Unit)

13.6 Visual Inspection Log (Permeation Unit)

Interval Visual Inspection Criteria OK Action

• Temperature is
 Contact Support
1 Week Temperature between 44.8°C and 
45.2°C _____________________

• no contamination  Contact Support

Silicone Tube
• normal elasticity 
_____________________
3 Months • Carrier gas flow falls
to 0 l/h  Contact Support
Tightness
• Pressure remains at

_____________________
1.2 bar

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 245

 13 Operating, Care and Maintenance Logs
13.7 Visual Inspection Log (Ambient Air Preparation Unit) LAR | PROCESS ANALYSERS AG

13.7 Visual Inspection Log (Ambient Air Preparation Unit)

Interval Visual Inspection Criteria OK Action

 Contact Support
1 Week Fine Filter Element • no contamination  _____________________
_____________________

• condensate drains
 Contact Support
Filter Unit
normally
 _____________________
_____________________
• no discolouration  Replace
Soda Lime
(purple/violet)

3 Months _____________________
• connected  Fix tubes
Tube Connections
handtightened

_____________________
Pre Pressure of the  Contact Support
Carrier Gas
• still at 2 - 3 bar 
_____________________

Date: Signature:

246 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.8 Care and Maintenance Log (Ambient Air Preparation Unit)

13.8 Care and Maintenance Log (Ambient Air Preparation Unit)

Kind of
Interval Action OK Comment
Action
If
necessary
Replace Soda Lime Maintenance 

Replace Gas Filter Maintenance 

3 Months
Replace Filter Mats Maintenance 

Replace Fine Filter Element Maintenance 

1 Year Replace Coarse Filter Element Maintenance 

Replace Activated Carbon Maintenance 

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 247

 13 Operating, Care and Maintenance Logs
13.9 Visual Inspection Log (FlowSampler) LAR | PROCESS ANALYSERS AG

13.9 Visual Inspection Log (FlowSampler)

Interval Visual Inspection Criteria OK Action

 Contact Support
1 Week Flow • Transport of Liquids  _____________________
_____________________

Sampling Pipe
 Cleaning necessary
3 Months
(Needle)
• no contamination  _____________________
_____________________

Date: Signature:

248 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.10 Care and Maintenance Log (FlowSampler)

13.10 Care and Maintenance Log (FlowSampler)

Kind of
Interval Action OK Comment
Action
If
necessary
Clean Sampling Pipe (Needle) Care 

3 Months Clean FlowSampler® Care 

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 249

 13 Operating, Care and Maintenance Logs
13.11 Visual Inspection Log (CO2-Remover) LAR | PROCESS ANALYSERS AG

13.11 Visual Inspection Log (CO2-Remover)

Interval Visual Inspection Criteria OK Action

• no damage  Contact Support
Housing
• no contamination

_____________________
1 Day
• red service-lamp is  Contact Support
Service-Lamp
inactiv

_____________________

Date: Signature:

250 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.12 Care and Maintenance Log (CO2-Remover)

13.12 Care and Maintenance Log (CO2-Remover)

Kind of
Interval Action OK Comment
Action
12,000 Replace the desiccant cartridges Maintenance 
operating
hours
Replace the internal ball valves Maintenance 
(or every 2 Replace all seals which removed
during maintenance
Maintenance 
years)
24,000
operating
hours Replace the exhaust valves Maintenance 
(or every 4
years)

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 251

 13 Operating, Care and Maintenance Logs
13.13 Visual Inspection Log (Auto-TIC-Port) LAR | PROCESS ANALYSERS AG

13.13 Visual Inspection Log (Auto-TIC-Port)

Interval Visual Inspection Criteria OK Action

• Ease of movement of
Micro-switch on
the closing and  Contact support
6 Months
Auto-TIC-Port
opening function  _____________________
• Observance of the _____________________
minimum distance

Date: Signature:

252 Instruction Manual QuickCOD®ultra 07E4317

 13 Operating, Care and Maintenance Logs
LAR | PROCESS ANALYSERS AG 13.14 Care and Maintenance Log (Auto-TIC-Port)

13.14 Care and Maintenance Log (Auto-TIC-Port)

Kind of
Interval Action OK Comment
Action

Replace needle guide seal Maintenance 

1 Month
Clean needle guide Care 

3 Months Clean and oil the Auto-TIC-Port Care 

Date: Signature:

07E4317 Instruction Manual QuickCOD®ultra 253

 13 Operating, Care and Maintenance Logs
13.14 Care and Maintenance Log (Auto-TIC-Port) LAR | PROCESS ANALYSERS AG

254 Instruction Manual QuickCOD®ultra 07E4317

 14 Safety Data Sheets
LAR | PROCESS ANALYSERS AG

14 Safety Data Sheets

Different chemicals, depending on the application, are used to operate the analyser. Chemical-suppliers
provide safety data sheets for their produced chemicals. Please ensure that you receive the safety data
sheets from your chemical suppliers.

Please feel free to contact us - we can provide you with safety data sheets for the following chemicals:

• Potassium hydrogen phthalate

• Sodium carbonate
• Sodium bicarbonate
• Potassium permanganate
• Sulfuric acid
• Hydrochloric acid
• Phosphoric acid
• Brass wool (acid trap)
• Zinc chips (acid trap)
• Quartz wool (acid trap)
• Soda lime (Ambient Air Preparation Unit)
• Activated carbon (Ambient Air Preparation Unit)
• Acetic acid
• Nitrogen 5.0

07E4317 Instruction Manual QuickCOD®ultra 255

 14 Safety Data Sheets
LAR | PROCESS ANALYSERS AG

256 Instruction Manual QuickCOD®ultra 07E4317

 15 Contact
LAR | PROCESS ANALYSERS AG 15.1 LAR Contact

15 Contact

15.1 LAR Contact

Table 41: LAR Contact Details

Contact Telephone E-Mail

Technical Support +49 30 278958 - 55 [email protected]
+49 30 278958 - 31
Sales Department [email protected]
+49 30 278958 - 43

15.2 Distributors / Authorized Service Partners

You will find contact details of all our distributors and authorized service partners on our website:

www.lar.com/about-lar/international-sales

15.3 Optimization

If you have any requirements for or comments about the LAR analyser, please contact the Technical
Support of LAR or the Sales Department of LAR.

07E4317 Instruction Manual QuickCOD®ultra 257

 15 Contact
15.3 Optimization LAR | PROCESS ANALYSERS AG

258 Instruction Manual QuickCOD®ultra 07E4317

LAR | PROCESS ANALYSERS AG

INDEX
A N
Acid ....................................................................... 174 Nameplate ................................................................ 9
Acid Solution ........................................................... 37 Needle Guide........................................................ 150
Activated Carbon.......................................... 183, 195 Needle Guide Seal........................................166, 215
Analog Output ................................................ 23, 225 Nitrogen .................................................................... 8
Analyser Specifications ......................................... 225
Automatic Circuit Breaker ..................................... 223 O
Auto-TIC-Port ........................................................ 212 Operating Log ....................................................... 239
Oxygen Demand....................................................... 4
C
Calibration Standard ........................................ 38, 55 P
Canister................................................135, 142, 226 Peak Area Integration ............................................... 6
Care Actions.......................................................... 141 Permeation Unit ................................................8, 177
Carrier Gas.............................................27, 134, 225 Phosphoric Acid...................................................... 56
Cleaning Solution .................................................... 57 Power Supply.......................................................... 36
CO2-Remover ....................................................... 203 Pump System ......................................................... 13
Coarse Filter.......................................................... 195
COD ...................................................................... 211 Q
CODi Method ............................................................ 4 Quartz Wool..................................................140, 163
CODi-Methode ...................................................... 231
CODo Method ..............................................4, 16, 48
R
CODo-Methode ..................................................... 230
Reactor Foot ......................................................... 144
Contact.................................................................. 257
Reactor Foot Seal................................................. 167
Correlation Factor ..................................................... 3
Reactor Pipe ......................................................... 145
Reagent Cabinet................................................... 174
D Reagents ................................................................ 55
Deionised Water...................................................... 55 Relays...............................................................21, 23
Digital Input .................................................... 21, 225 Rinsing Water .................................................56, 174
Dilution of the Stock Solution ........................... 62, 64 Running Rails ...............................................138, 147

F S
Filter Mats .................................................... 139, 194 Sample Drain .......................................................... 36
Fine Filter .............................................................. 194 Sample Inlet............................................................ 36
Flow Diagram ........................................................ 227 Sample Pump ............................... 15, 138, 148, 168
FlowSampler ......................................................... 196 Scope of Delivery...................................................... 9
Furnace Head Seal ............................................... 160 Signal Connections................................................. 37
Furnace System ...................................................... 17 Silicone Seal ......................................................... 166
Soda Lime Pellets................................ 183, 191, 192
G Specifications of Accessories and Options........... 226
Gas Filter..................................... 168, 183, 187, 193 Start-Up .................................................................. 39
Glass Components.................................16, 135, 142 Supply Tube.......................................................... 143

H T
High Salt................................................................ 211 TC ......................................................................... 211
Hydrochloric Acid .................................................... 57 Technical Information ........................................... 225
Teflon Tube...................................................143, 157
I TIC ........................................................................ 211
Injection Needle ...................................135, 150, 165 TIC Port ................................................................ 137
Injection Port .................................................. 17, 153 TIC Reactor ..................................................137, 212
Injection System.....................................52, 134, 142 TIC Stripping Vessel .....................................137, 212
Injection Tube.......................................136, 144, 161 Tightness .............................................................. 170
Installation ............................................................... 29 TNb ....................................................................... 211
Installation Plate...................................................... 18 TOC ...................................................................... 211
Internal Sample Dilution ........................................ 218 TOC-Difference Method........................ 3, 37, 56, 61
TOC-Direct Method.................................... 37, 57, 63
M Transportation Lock .............................................. 185
Mains Connection ................................................... 19 TRC-Board.............................................................. 21
Measurement Principle ............................................. 5 Tube Cassette Pump ............14, 138, 148, 154, 168
Multi Parameter Option ......................................... 211
Multi Stream Option .............................................. 210

07E4317 Instruction Manual QuickCOD®ultra i

 LAR | PROCESS ANALYSERS AG

V
Viton Tube.................................................... 149, 161

X
XY-System .................................. 138, 147, 170, 228

Z
Zero Signal............................................................ 134

ii Instruction Manual QuickCOD®ultra 07E4317