Module Ii. Measurement of Humidity
Module Ii. Measurement of Humidity
Module Ii. Measurement of Humidity
MEASUREMENT OF HUMIDITY
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MODULE II. MEASUREMENT OF HUMIDITY
INTRODUCTION
LEARNING OUTCOMES
2. Demonstrate the ability to use the psychrometric chart and the Sling
Psychrometer in measuring moist air properties.
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LESSON 1. CONCEPTS, TERMS AND DEFINITIONS
Humidity
The word "humidity"
denotes the presence of water
vapour in air or other gas. Water
vapour is the gaseous form of
water, and can be thought of
much like any other kind of gas.
It is normally transparent, and
makes up about one hundredth
(or one percent) of the air around
us. Humidity arises in practice
because, in the same way that
hot water gives off steam, so
water at lower temperatures -
including ice - also gives off water
vapour. Wherever there is water
or ice, there is evaporation (or its
opposite, condensation). The
extent to which this happens
depends upon a number of
factors, the most important of
which is temperature. Similarly,
other liquid or solid materials -
most of which have some water
content - will give off (or
sometimes soak up) water
vapour. Of
course, water vapour can also be found in
Figure 3.1 Saturation vapour
pressure of places where there is no liquid or solid water increases with
temperature. nearby, for example in remote parts of the Earth's atmosphere.
The air that contains its full capacity of water vapour, is said to be "saturated". The
"relative humidity" of the air expresses how fully saturated it is with water vapour.
A variety of other ("absolute") measures are used to express how much water vapour
is actually present (irrespective of temperature or level of saturation).
Definitions and units
Some vocabulary specific to humidity (and other common words with
specialised meanings in this context) are as follows:
Absorption-The retention (of water vapour) by penetration into the bulk of
a material.
Adsorption-The retention (of water vapour) as a surface layer on a material.
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Condensate-This refers to the condensed material, e.g. liquid water or ice.
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Celsius (0C) or occasionally in other units of temperature (e.g. in degrees
Fahrenheit ( °F) in USA).
Enthalpy (of humid gas). Measure of the total energy in a humid gas.
Enthalpy is a function of the gas temperature and pressure, and of the
moisture content, since water absorbs energy on changing from condensed
state to vapour. Enthalpy is a useful concept in air conditioning, where it is
important to know how much of the "stored" energy will be consumed, or
released, when the temperature or water content is raised, or lowered.
Enthalpy of a gas can be defined as the sum of "sensible" and "latent" heat
for each component in the gas. Values of enthalpy are conventionally
expressed relative to a datum point (i.e. a zero or base line). For a dry gas,
this is normally the heat content at 0 °C. For water vapour, the enthalpy is
usually expressed relative to the heat content of liquid water at 0.01 °C.
Expressed in terms of energy per quantity of dry gas, i.e. kilojoules per
kilogram (kJ/kg) (or other units, for example British thermal units per
pound, Btu/lb.).
Equilibrium relative humidity (ERH) (over a substance). The value of
relative humidity of the air at which there is no net exchange of moisture
with any nearby substance. This is used for indirectly indicating or
controlling the condition of moisture-sensitive substances such as paper.
Expressed as a percentage (%).
Frost point (or frost-point temperature). The temperature at which frost
forms on cooling a gas. This is, in effect, the temperature at which air is
saturated in equilibrium with ice. It is the exact counterpart to dew point
(though values differ). Expressed in degrees Celsius, °C, or occasionally in
other units of temperature, i.e.
in degrees Fahrenheit (°F), in USA.
Latent heat. Heat stored in a substance but not directly related to its
temperature. For example, heat is stored in a gas because this heat was
originally supplied to evaporate it. "Latent" means "hidden". Expressed in
energy per unit mass of substance, i.e. joules per kilogram (J/kg ).
. Mixing ratio. Mass of water vapour per unit mass of dry air with which it is
associated. It is a dimensionless ratio, but is often expressed in grams of
water per kilogram of dry gas (gv/ kgda) or in other units of mass.
Moisture content. A humidity term best reserved for general descriptive or
qualitative use only. Use of this term to identify a measured quantity should
be avoided, as there is a risk of confusion because "moisture content" has
been used in the past to mean both mixing ratio and specific humidity:
Moisture content is also a term particularly used to refer to the proportion
of water held in liquids or solids.
Mole. Amount of substance which contains as many elementary entities as there
are atoms in 12 grams of carbon 12. Expressed in moles (symbol, mol).
Mole fraction .The mole fraction of a component is the ratio of the amount
(number of moles) of that component to the total amount of substance
present. Expressed as a dimensionless ratio.
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Partial pressure (of water vapour). The part of the overall pressure exerted by
the water vapour component in a gas. Expressed in units of pressure such as
Pascals (Pa) or in multiples; kilopascals (kPa) or Megapascals (MPa), with
non-SI alternatives such as millibar (mbar) or millimetres of mercury
(mmHg). 100 Pa= 1 mbar""' 0.75 mmHg.
Relative humidity. The ratio of the actual vapour pressure to the saturation
vapour pressure over a plane liquid water surface at the same temperature,
expressed as a percentage. This is commonly understood when the term "X
percent relative humidity" is used. For actual vapour pressure, e, and
saturation vapour pressure,
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of uncertainty in a humidity measurement is the effect of temperature
differences from place to place in the process, room or chamber. The
importance of considering the temperature effects carefully cannot be
overstated when relative humidity is the parameter of interest.
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where e is the water vapour pressure, and e, is the saturation vapour
pressure at the prevailing ambient temperature.)
Roughly speaking, at room temperature, a change in dew point of 1 °C
corresponds to a change in relative humidity of 6 percent of the relative
humidity value. For example at 50 %rh, an uncertainty in dew point of ±1
°C corresponds to an uncertainty of ±3 %rh. A change of 1 °C in the
measurement of the ambient temperature has almost exactly the same
significance. Overall, a useful rule of thumb is that ±1 °C uncertainty in
either dew point or temperature leads to an uncertainty of ±6 percent of
the relative humidity value.
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unaltered by the pressure change. This can also be deduced from the fact
that the definition, of mixing ratio does not involve pressure or
temperature. The rule is similar for other dimensionless measures of
concentration (those expressed in mass per unit mass, or volume per unit
volume), such as mole fraction and specific humidity, including cases where
these are expressed in terms of parts per million.
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LESSON 2. INTRODUCTION TO METHODS FOR HUMIDITY MEASUREMENT
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thin-film technology. Electrical hygrometers are often portable and
compact. The common form of this instrument is a small wand-shaped probe
connected by a cable (or directly attached) to the main body of the
instrument. Specially shaped probes are often available for particular
purposes. They are often equipped with a filter to protect against
contamination. (Response times are faster, though, without this protection.)
Impedance hygrometers are usually also fitted with a temperature sensor.
Readings are displayed directly, sometimes with a choice of units (e.g.
relative humidity or dew point), and output of an electrical signal (e.g.
analogue voltage) may also be available.
There are several distinct types of electrical sensors.
Capacitive sensors respond most closely to relative humidity, rather than
dew point, with best linearity at low relative humidities. In general
capacitive sensors are not damaged by condensation (i.e. relative humidity
of 100 %rh), though calibration may shift as a result. ·
Resistive sensors respond most closely to relative humidity, rather than
dew point. Linearity of resistive sensors is best at high humidities. Most
resistive sensors cannot tolerate condensation. However, some are
"saturation guarded", with automatic heating to prevent condensation. One
type of resistive sensor is sometimes referred to as "electrolytic" because of
the use of a polyelectrolyte as the hygroscopic element of the sensor. This
should not be confused with electrolytic sensors which use electrolysis as
the sensing mechanism .
Dew-point type impedance sensors are a special case of impedance
hygrometer, used to measure in absolute units rather than relative humidity.
Following a similar general principle, the sensor may feature aluminium
oxide or other metal oxides, or a silicon base for the active element. This
type of sensor responds to the partial pressure of water vapour. Commonly
the signal is converted into other absolute units, resulting in values
displayed by the instrument in dew point or parts per million by volume.
These sensors can have a wide range of measurement, including very dry
gases.
Condensation
Dew-point temperature can be measured by cooling a sample of gas
until condensation appears, and observing the temperature at which this
happens. In an optical dew-point hygrometer, condensation in the form ",Jf
dew or frost is induced on a small mirror within the instrument. The onset
of condensation is sensed optically, by detecting changes in how the mirror
reflects or scatters light. The reading may be recorded at the instant of
condensation, or the mirror may be held at that temperature and a
continuous reading obtained. Designs vary, with some in probe form, while
others employ sampling through a tube. While the probes may be reasonably
compact, the main body of the instrument is usually relatively large, and
not portable. Readings are displayed as a dew-point temperature, and
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output is usually also available in electronic signal form. Other (non-optical)
condensation dew-point sensors detect condensation electrically, or by
other methods such as the change in frequency of a resonating quartz
crystal.
Spectroscopic
In general, a spectroscopic technique is one where the composition
of a gas mixture is found by analysing how substances absorb (or emit) light
of particular wavelengths or frequencies. Every chemical substance has a
characteristic frequency "signature", and these may lie in the ultraviolet or
infrared parts of the spectrum. Spectroscopic measurement can be a useful
approach if concentrations of other substances are to be measured, as well
as that of water vapour. The spectroscopic technique used for high or
moderate humidities is based on infrared absorbance. Water absorbs
infrared radiation at several wavelengths in the range 1 µm to 10 µm. The
intensity of transmitted radiation is measured at one of these wavelengths
and compared with that for a reference wavelength, using a photocell for
detection. The amount of this radiation absorbed by the gas is proportional
to the spatial concentration (or partial pressure) of water vapour.
Spectroscopic techniques can also used to measure extremely low
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concentrations of water vapour, reportedly down to a few parts per billion
(ppb, i.e. parts in one thousand million).
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LESSON 3. SELECTION OF A TYPE OF HYGROMETER
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Type of gas. In gases other than air, chemical compatibility may be an
issue. Calibration specific to the gas in question may be required.
Materials of construction. Aside from considering the hygroscopic nature
of materials, other aspects of suitability may need to be addressed. Some
materials may be chemically incompatible with the environment of interest.
Materials may be unacceptable for other reasons, such as avoidance of
plastics and glass for reasons of hygiene or safety.
Ease of use. Some hygrometers are straightforward to use. Others require
some skill
Error detection. Some hygrometers warn the user of errors in the
instrument itself, or of incorrect usage, for example if the proper humidity
range is exceeded, or if the batteries are running low.
Use for control or monitoring. In some cases the user simply needs to
measure humidity. In others, the humidity measurement is fed into a process
of control of humidity. If so, then access to the electrical output in some
form is usually necessary. For use in control of humidity, the response time
and the degree of hysteresis are usually important.
Hazardous areas. In areas where there is some hazard, such as an explosive
atmosphere, suitable precautions must be taken. For example, extraction
of sample gas to remote probes may reduce the risk in some cases, while
other sensors can be designed to be "intrinsically safe", by limiting the
electrical power to a level low enough that it cannot ignite the atmosphere.
Where this is a concern, an appropriate certification of intrinsic safety
should be sought.
End use. Humidity itself may be of interest, or humidity may be used as an
indication of the moisture content of other solid or liquid substances. If so,
it may give no more than a very indirect indication of the actual content,
though ERH and water activity are proper indications in a different way of
the condition or equilibrium of materials with the environment.
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Quality, reliability, lifespan. Quality is not always easy to judge. Aside
from general impressions, compliance with a quality accreditation or
published standard specification may be some indication. When choosing a
"brand name", a manufacturer that specialises in hygrometers may be a
better choice than one making a wide variety of instruments.
Recommendations from other users may be the best guide. Some types of
hygrometer tend to have a long lifespan; others less so.
Versatility. If more than one kind of use is envisaged, the adaptability of
the hygrometer should be borne in mind.
Interchangeability. It may be desirable to have a set of hygrometers which
can be used interchangeably, or to substitute other probes for use with the
main body of the hygrometer. It may be necessary to replace components
of the sensor which might fail. In any of these cases, it is important to
consider how interchangeable the instruments or components really are.
Interchangeability is best ensured by calibration against a consistent
reference. However, replacing a key component of an instrument may
invalidate its previous calibration.
Maintenance .Some types of hygrometer need routine cleaning,
regeneration, or replacement of parts.
Availability of spares. It may be worth knowing about spare parts; whether
they can be fitted by the user, and whether they are freely available locally
and quickly. Any consumable supplies, such as charts, should be available
and clearly coded or identified, as they are not always interchangeable.
After-sales service. The availability of a warranty, or of a good
maintenance or service contract may be a factor in the decision.
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ME 144 ME Laboratory 1
EXPERIMENT NO. 03 MEASUREMENT OF HUMIDITY
I. Objective:
1. To study and learn how to use Sling Psychrometer.
2. To study the principles of psychrometrics and its importance and
applications in mechanical engineering.
V. Procedure:
1. Examine the construction and parts and learn how to use the
sling psychrometer available in the laboratory.
2. Wet the wick (attached cloth) with water on one of the
thermometer bulbs of the sling psychrometer.
3. Whirl the instrument in the air for about three minutes then
record the readings of the two thermometers. The reading from
the thermometer with wet wick is recorded as wet bulb
temperature while that of the thermometer without the wet
wick is dry bulb temperature.
4. Measure the air temperatures in outdoor, indoor without
occupants and indoor with occupants making three trials each.
5. Compute the different psychrometric properties of the air based
on the average dry bulb and average wet bulb temperatures
obtained from the instrument.
6. Determine the same air properties using the psychrometric chart.
7. Tabulate the results then study and compare the properties
computed against the properties determined from the
psychrometric chart.
8. Compute the percentage error between the computed values
against the values read from the psychrometric chart.
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VI. Data and Results:
INDOOR, OC OUTDOOR, OC
OUTDOOR, OC (Without (With Occupants)
Occupants)
TRIALS
Wet Bulb
Dry Bulb Wet Bulb Dry Bulb Wet Bulb Dry Bulb
AVERAGE
B. Air Properties
1. Computed Using Psychrometric Formulas
Dry Bulb OC
twb
Temperature
Wet Bulb O
tdb C
Temperature
Specific
W Kgv/kga
Humidity
Relative
Ø %
Humidity
Dew Point OC
tdp
Temperature
Enthalpy h Kj/kga
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2. Determined From Psychrometric Chart
Dry Bulb OC
twb
Temperature
Wet Bulb OC
tdb
Temperature
Specific
W Kgv/kga
Humidity
Relative
Ø %
Humidity
Dew Point O
tdp C
Temperature
Enthalpy h Kj/kga
C. Percent Error
PERCENTAGE ERROR, %
AIR PROPERTIES
INDOOR
INDOOR w/o With
OUTDOOR
Occupants Occupants
Dry Bulb
Temperature
Wet Bulb
Temperature
Specific Humidity
Relative Humidity
Dew Point
Temperature
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Specific Volume
Enthalpy
VII. Computations:
X. References:
Book title, Author, Publisher, Edition, page/pages
Website
XI. Appendix:
Attach all original data sheets, computations, diagrams and sketches.
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