Sri Chaitanya IIT Academy, India 12-11-2022_Jr.

IPL-IC Jee-Main_WTM-14_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.IPL-IC JEE-MAIN Date: 12-11-2022
Time: 10:00AM to 01:00PM WTM-14 Max. Marks: 300

KEY SHEET
PHYSICS
1 4 2 2 3 2 4 4 5 3
6 2 7 2 8 4 9 1 10 2
11 4 12 3 13 3 14 2 15 4
16 1 17 1 18 3 19 2 20 1
21 1 22 1 23 3 24 5 25 2
26 150 27 3 28 1188 29 20 30 1

CHEMISTRY
31 3 32 4 33 3 34 1 35 2
36 1 37 1 38 2 39 4 40 4
41 3 42 3 43 2 44 2 45 1
46 1 47 1 48 3 49 3 50 1
51 24 52 2 53 3 54 9 55 3
56 4 57 4 58 4 59 6 60 3

MATHEMATICS
61 1 62 3 63 2 64 2 65 1
66 2 67 2 68 2 69 1 70 1
71 2 72 3 73 4 74 2 75 2
76 1 77 3 78 2 79 1 80 4
81 2 82 2 83 4 84 1 85 3
86 1 87 2 88 0 89 0 90 2

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 Sri Chaitanya IIT Academy, India 12-11-2022_Jr.IPL-IC Jee-Main_WTM-14_Key & Sol’s

SOLUTIONS
PHYSICS
1. A 
Y1  A c o s w t , Y 2  A s in  w t    t  0,Y  , 
2 6
     
 Y1  Y 2  A c o s w t  A s in  w t    s in   w t   s in  w t   t  .
 2   6  6
2. l l 3
 1 0 0  0 .1   e  10
l l
F
3
A F 10
Y     10  10
11 2 11 2
5 3
N /m N /m .
e Ae 10  10
3. Conceptual
4.  2     
   2  1   t  t   t  t  1 sec    .
 3   2  6 6
5. 1
K .E  mw
2
A 2
 y
2
 0 .4 8  1 0
3
J
2
6. Aw 3
V  w A  x   w A  x 
2 2 2 2
A.
2 2
7. k
w 
m
8. 4 2 2 2
a   w y,a  Y , 
 T  3 s e c .  
2

9 3 T 3
9. T  T '  T  8 8 1 2 8  8 6 4 0 0  1 7 2 8 s e c  2 8 .8 m in u te s lo w .
10. 1 2mg
 m gx  x 
2
Kx .
2 K
11. l 3  2 1
T  2  2 .0 0 7 0 9 s e c V m a x  A w  V m a x   9 .3 9 1 c m s .
g 2 .0 0 7 0 9

12. AR  A
2
 A
2
 2 A1 A 2 c o s 4 5
0
1 2

AR   A 
2 2
A 1 2
2 A1 A 2

13. Y1 F1 / A1 l1 / l1 l1 F1 l1 r2
2
Y2
      2

Y2 F2 / A2 l2 / l2 l2 F2 l2 r1 Y1
14. T2 l2 3/2 l l 7
    l 
T1 l1 2 l 16

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15. 3 F l1 6Fl 2Fl 8FL

l1   , l2  , l  l1  l 2 
Ay 3Ay 3Ay 3AY
16. V  w A Y
2 2
 2 5 3
2 2
 8 c m / s .
17. Fl K 5 l2  l
l     l  5 l1  4 l 2 .
4 l1  l
2
Ay K

18. l
T  2  T l  T1  T 2  2  K l   T1  T 2  2 T .
2 2 2 2 2 2
 
g
19.
 dw   F dx   K xdx  1 8 .7 5 N m .
20. Fl  m1  m 2  g l1 m 2 g l2
l  , lu p p  , l lo w e r  .
AY A Y1 A Y2

21. l
T  2  1 .4 1 9 s e c  1 s e c .
g
22. F

F
 1 .2 7  1 0 N / m
7 2
 1 10 N / m .
7 2

r
2
A

23. 1
 s tr a in 
2
w   25  10 J / m  2 .5  1 0 J / m .
3 3 4 3
Y
2
24. 1 2  A  y  3 y 100  4 y
1 2 2 2 2
m
2
A 2
 y
2
  3 m  y 
2

2  2 

 25  y  5 cm .
2
y
25.  2  VT A  1 .5
V  A  A   A 
 T  2

26. YA l
F   F  150 N
L
27.
l 0 .0 5
T  2  2  3 .1 4  3 .1 4 2  3 s e c
g 0 .2
28. T 1 l 1 0 .0 2 7 3
T l    86400    1188 sec .
T 2 l 2 0 .9 9 2 7
29.
 20   x  2    20 J .
du d 2
F  
dx dx
30. l
T  2
g

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 Sri Chaitanya IIT Academy, India 12-11-2022_Jr.IPL-IC Jee-Main_WTM-14_Key & Sol’s

CHEMISTRY
31. N 2  3H 2
 2NH 3

1 2 0
1 x 2  3x 2x

1
2 x  1, x 
2

NH 3
2
2
1
Kc    16.
N2 H 
3 3
2  1  1 
  
 2  2 
32. 5
2NH 3
 O2 2 N O  3 H 2O
2
Equation adding b+3c-a
K2  K3
3

K 
K1
33.  SO2  O2 
2
 0 .5   0 .2 5 
2

1
Kc    1 m o le  lit .
 SO3   0 .2 5 
2 2

34. A  2B

1 0

1    2
T o ta l m o le s  1    2   1  
2
 2 
 P 
4
2 2
PB 1 
K    P
1
p
1
2
PA 
 P 
1 
35. N H 4 H S S  NH 3 g 
 H 2S s

2 P  3 0 a tm  P  1 5 a tm

 P  P  1 5  1 5  2 2 5 a tm .
2
K P

36.  6
 6, H  10
H
P
 9
Concof H decreased by 1000 times means  H 
 becomes 1 0 , new

 9.
H
P

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 Sri Chaitanya IIT Academy, India 12-11-2022_Jr.IPL-IC Jee-Main_WTM-14_Key & Sol’s

37.  PK a  PK b   1 0  lo g 9 .2  5  lo g 1 .8 
 7  
H
P  7
 
 2   2 
 7.
H
P
10
38. K sp  1  1 0 m

O H   10 5
m

POH  5

 9
H
P
39. A pair of acid and base which different by only one proton.
3 3
40. N aVa  N bVb  10  V  10 V  P
H
 0.
41. 2 butane is symmetrical molecule.
Zn  H 2O
42. H 3C  HC C CH 3 O3  
CH 3
CH 3
 C H O  C H 3C O C H 3

43. Conceptual
44. conceptual
45. A  CH 2
 CH 2

B  CH 3
 CH 2
 OH
46. CH 3  CH CH 2 
alc . KOH
1equivalent
 CH 3  CH CH Br

Br Br
47. CH 2  H 2O 
 0   CH 3  CH
KMnO
CH 3  CH
4
CH 2

OH OH
48. Conceptual
49. Conceptual
50. CH 3

H 3C HC C CH 3 OSO4  H C OH
CH 3 CH 3 C OH

CH 3
51. K  K1  K 2  K3
K  2  4  3  24

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52. C aC O2  C aO  C O2

0 .2 0 0
0 .2  x x x

t=0
mole at equilibrium 
x
5 .6

x  5 0 % o f 0 .2  0 .1

0 .1
 K c  RT   0 .0 8 2 1  1 0 9 2 
n 1
K P
  1 .6 .
5 .6
53. S O 2 , S C l 4 , P C l3

54. S  0 .2
 p  lo g  4 .7 5  lo g  4 .7 5
OH Kb
p
B 0 .2

 1 4  4 .7 5  9 .2 5
H
p

55. x 
m OH X  m  XOH

x
12
 3
 3
 3 3 x
x
K sp  s  xs   27  10  10 10  10

3
x  3  27, x  3

56. Br Br
CH 2 CH 2 CH CH 2 + Br2  CH 3 CH 2 CH CH CH 3

2-chiralcentres
4 Isomers
57. Cl
Cl
Cl

Cl

58. Conceptual
59. Conceptual
60. Conceptual

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MATHEMATICS
61.  x  a 16 x  x  a 
15 16 16
 16 x a  a
16 15 16
d  1 16  15 x
. x  a   
16
 
dx  x  a x  a x  a
2 2


y  sec T an x 
62. 1 1
x  1 x
2 2
sec T an

dy 2x x  dy  1
     
dx 2 1 x
2
1 x
2
 d x  x 1 2
63. y 
1
lo g  1  x  
1
lo g  1  x  
1
Tan
1
x
4 4 2
1 x 1 x
2
dy 1 1 1 1 1 1 x
       
4 1  x  4 1  x  2 1  x  4 1  x  1  x  2 1  x  2 1  x  2 1  x  1 x
2 2 2 2 4
dx

64. 3 c o s   1  2 s in  
2
3 c o s   6 s in  c o s  c o s  . c o s 2
2
dy
    cot 
 3 s in   6 c o s  s in  3 s in    1  2 c o s   s in  . c o s 2 
2 2
dx

2
65. 1  1
x 
2
x  y  t   t    2   y  2  x  y  2x y  2  2x y  2  x y 1
4 4 2 2 2 4 4 2 2 2 2 2 2
2
t  t 
dy dy
 2x y  2 xy  0  x y  x y  1.
2 2 3 2 2

dx dx

66. x 1 y  y 1 x  0  x 1 y  y 1 x  x 1  y   y 1  x 
2 2

 x  y  x y  xy  0  x  y   x  y   xy  x  y   0  x  y  xy  0
2 2 2 2

x dy  1  x  1  x 1   1
 y       .
1 x    
2 2
dx  1  x  1  x

67. dy
y  x  x  7  7   x 1  lo g x   7 x  7 lo g 7 .
x 7 x 7 x 6 x

dx

68. s in y dy s in    y  c o s y  s in y c o s    y  s in    y  y  s in 
x      .
s in    y    y   y   y
2 2 2
dx s in s in s in

  y
2
dy s in
  .
dx s in 

 s in x  c o s x 
69. d  s in x  c o s x 
  
d 

s in x  c o s x 
 
d 


 
d  s in x  c o s x 
  
d
1   0 .
  s in x  c o s x 
d x  s in x  c o s x 
2
d x  1  s in 2 x  dx  s in
2
x  c o s x  2 s in x c o s x 
2
dx   dx


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70. y
cos x
 x
s in y
 c o s x lo g y  s in y lo g x 
cos x dy
 lo g y   s in x  
s in y
 lo g x c o s y
dy
y dx x dx

 cos x  dy s in y dy y  s in y  x lo g y s in x 
   lo g x c o s y    lo g y s in x   .
 y  dx x dx x  c o s x  y lo g x c o s y 

71. B  120 , C  30
0 0
 A  3 0 . 2 / s in 3 0
0 0
 b / s in 1 2 0
0
 b  4 s in 1 2 0
0
 4 cos 30
0
 2 3

 A r e a   1 / 2  a b s in C   1 / 2   2  2  
3 s in 3 0
0
 3 s q .u n it .

72. G . E .  8 R  s in A c o s  B  C   8 R  s in A s in  B  C  c o s  B  C 
3 3 3 2

 4 R  s in A  s in 2 B  s in 2 C 
2 2

 8 R  s in A s in B c o s B  s in A s in C c o s C  s in B s in C c o s C  s in B s in A c o s A  s in C s in A c o s A  s in C s in B c o s B 
3 2 2 2 2 2 2
 

 8 R  s in A s in B  s in A c o s B  c o s A s in B   s in B s in C  s in B c o s C  c o s B s in C   s in C s in A  s in A c o s C  c o s A s in C  
3

 8 R  s in A s in B s in  s in A  B   s in B s in C s in  s in B  C   s in C s in A s in  C  A  
3

 8R  3 s in 
3
A s in B s in C 3abc

73. G iv e n , c o t A / 2 : c o t A / 2 : c o t C / 2  3 : 7 : 9

ss  a ss  a ss  c s a sb sc a b c

         .
3 7 9 3 7 9 16 12 10
 a :b :c  8 :6 :5

74. a

b

c

s in A

s in B

s in C
 ta n A  ta n B  ta n C  A  B  C  6 0
0

cos A cos B cos C cos A cos B cos C

3
2
2
A rea   3.
4

75. s  bs  c 1
 b  c   a s s  a s  b s  c  2s  cs  b  
2
 a  b  c  2abc  
2 2 2 2

ss  a 4

A 1
 ta n  .
2 4
2 ta n  A / 2  2 1 / 4  8
 ta n A    .
1  ta n A / 2 1  1 / 16
2
15

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 Sri Chaitanya IIT Academy, India 12-11-2022_Jr.IPL-IC Jee-Main_WTM-14_Key & Sol’s
 b  c  8R  4 R s in A  4 R s in B  4 R s in C  8 R  s in A  s in B  s in C  2
2 2 2 2 2 2 2 2 2 2 2 2 2 2
76. a

 cos A cos B cos C  0

  90 or B  90 or C  90
0 0 0

 T h e tr ia n g le is r ig h t a n g le d .

77. cos  A / 2  2 R s in B  2 R s in C 2 s in   B  C  / 2  c o s   B C  / 2  c o s   B  C  / 2 
G .E .    
s in A / 2 2 R s in A 2 s in A / 2  cos  A / 2  s in A / 2

 c o s  A / 2   c o s   B  C  / 2   A /2  B C /2  A  B  C  A  C  B  B  90 .
0

78. B C  ss  b   ss  c  s a b c 4a

cot cot          2.
2 2  ss  as  b  s  s  a   s  c   s  a  a  b  c 2 a

79.  ss  a  ss  a s

2

 cot  A / 2         .
 s  s  b   s  c  

b  c  2bc b  c
2 2 2 2 2
cos A 2bc cos A a
 cot A      
s in A 2 b c s in A 4 4

2s a  b  c
2 2
2 2
s 4s
G .E .     .
a  b  c b  c b  c
2 2 2 2 2 2 2 2 2
b  c
2 2 2
/4 a a a

80. a s in 2 C  c s in 2 A  a .2 s in C c o s C  c 2 s in A c o s A
2 2 2 2

c a ac abc
 a cos C  c cos A   a cos C  c cos A    4
2 2

R R R R

81. G iv e n , c  a  b   s e c  
c
a b

c  a  b c  a  b c  a  b  s  as  c
2 2 2
 c  4ab
 ta n   s e c   1    1    
2 2

 a b  a  b a  b a  b
2 2 2
ab

2 ab C
 ta n   s in .
a b 2

82. C A 3b ss  c 3b 3b
 C cos   a   s 
2 2
G iv e n , a c o s
2 2 2 ab 2 2
 2 s  3b  2 b  a  c

83. ss  a 
a  b  c   a  b  c    bc  2s2  s  a    bc  
bc 4
A  
 cos   0   1  0    4.
2

2 4 4

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 Sri Chaitanya IIT Academy, India 12-11-2022_Jr.IPL-IC Jee-Main_WTM-14_Key & Sol’s

84. 
1
 a 
1
 b 
1
 c   
2
, 
2
, 
2
2 2 2 a b c
b  c 1 b  c  a c  a c b c 
2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
2 2 2 a b c a a
     2
 2
 2
 2
    
4 4 4 4  4 4 4 

1  2bc cos A 2ca cos B 2 ab cos C   cot A  cot B  cot C 

    .
 2 b c s in A 2 a b s in C 
 2 c a s in B

85. 1 1 3 b  c a b 3
   
a b b  c a b  c a  b b  c  a b  c

 a  2b  c   a  b  c   3  a  b  b  c 

 a  ab  ac  2 ab  2b  2bc  ca  bc  c  3 a b  3 a c  3b  3b c  b  a  c  ca
2 2 2 2 2 2 2

a  c b 
2 2 2
1 1
 ca  a  c  b    cos B   B 
2 2 2
.
2ca 2 2 3

86.  1  x  x 2  1  x  x 2  
d 1  x  x 
2 4
d  d
ax  b   2 
    1  x  x 2    1  2 x
dx  1  x  x  1 x  x
2
dx   dx

 a  2, b  1  a  b  2  1  1.

87. mn dy y
 x  y  .  n  1  1  2.
m n
If x . y th e n
dx x

88. 1 1 1 1    dy
y  S in 2 x  C os 2 x  Tan 3x  C ot 3x        0.
2 2 2 dx

89. 1  1  3 / 2 1 1 1 1
f ' x    f ' a  
3 / 2
a   a a  x a   a a a    0.
2 x  2 2 a 2 2 2

90. dy d d
 2  
ax
2
ax
lo g 2  ax   2
ax
 lo g 2  a .
dx dx dx

dy
A t x  1,  2  lo g 2  a  a 2 lo g 2  lo g 2 5 6  lo g 2
a a 8

dx

 a2  8  a  2.
a

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