MATRIX SCIENCE ACADEMY

MHT CET CHEMISTRY PAPER-II 2022-23

Time : 60 Min Chem : Groupwise Paper Marks : 50
Hints and Solutions

01) Ans: B) 3
02) Ans: B) orlon

Sol:
03) Ans: B) Sulphur
Sol: Sulphur occurs in allotropic form as
(1) Monoclinic (2) Rhombic (3) Plastic. 10) Ans: B) Sandmeyer's reaction.
04) Ans: D) +6 11) Ans: D) Astatine

05) Ans: A) AB3 12) Ans: C) B2 A3

1 Sol: In closest packing there is one octahedral hole
Sol: Number of atoms of A per unit cell  8  1 per atom. As atom 'B' occupy 2/3rd of the
8
octahedral voids, therefore no. of B atoms in the
1
Number of atoms of B per unit cell  6  3 2 2n
2 lattice  n  
3 3
Therefore, the composition is AB3 .

06) Ans: B) Butadiene and styrene 2n 2

 Ratio of B : A  : n  :1  2 : 3  B2 A3
Sol: SBR (Styrene Butadiene Rubber) is also known 3 3
as Buna-S and it is a coplanar of styrene
13) Ans: D) Cl  ClO
C6H5CH  CH2  and 1, 3-butadiene
Sol: 2NaOH  Cl2  NaCl  NaOCl  H2O
CH2  CH  CH2  . The structure of Buna-S is  
....CH2  CH  CH  CH2  CH2  CH  CH2  Na  Cl Na  OCl
  

CH2  C H  CH2  CH2 ......... 14) Ans: C) Dacron

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C6H5 15) Ans: B) CH3NC

Sol: CH3  Cl  AgCN  alc   CH3  NC  AgCl
07) Ans: A) tert-butyl bromide only 16) Ans: A) Cubic
08) Ans: B) I and II Sol: The characteristics of cubic system are
a  b  c, and       90
The crystals belonging to this system are highly
symmetric.
17) Ans: C) H3PO3
Sol: Sol: H3PO3

18) Ans: D) molecular crystal.

19) Ans: C) reaction of conc. H2SO4 with Cu
Sol: Cu  2H2SO4  CuSO4  SO2  2H2O
C H2CN 20) Ans: B) propan - 2 - ol
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09) Ans: C)
Sol:
CH2CN alc. KOH
CH3  CH2  CH2  Br   CH3  CH  CH2
Sol: (A)
HBr aq. KOH
 CH3  CH CH3 
 CH3  CH  CH3
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Br OH
Propan 2ol

21) Ans: C) HF
22) Ans: B) R-22
MHT CET CHEMISTRY 2023
 MATRIX SCIENCE ACADEMY

Cl
23) Ans: A) SO3 |
Sol: H2SO4  SO3  H2S2O7 Sol: CH2  C  CH  CH2
(Oleum or Fuming H2SO4 )
36) Ans: D) Freons containing chlorine and
24) Ans: B) half filled stability fluorine
25) Ans: C) AB 37) Ans: D) A is optically active compound, while
Sol: Atoms are at eight corners of the cube. So, the B is not.
8 38) Ans: C) vulcanisation.
number of A atoms in the unit cell   1 , atoms B
8
39) Ans: A) H2SO5
per unit cell = 1. Therefore, the formula is AB.
Sol: H2SO5
26) Ans: C) Hexane-1, 6-dioic acid
Sol: Adipic acid has a formula 40) Ans: D) molecular solid
HOOC   CH2 4  COOH. Therefoere, its IUPAC 41) Ans: B) Hexamethylene diamine and adipic
name is hexane-1, 6-dioic acid acid
 1 2 3 4 5 6  42) Ans: C) benzylic halide
 HOOC C H2  C H2  C H2  C H2  C OOH  .
  Sol: Benzylic halide  C6H5  CH2  Br
27) Ans: C) 2 43) Ans: B) (i) HBr, (ii) NaCN
Sol:

28) Ans: D)

44) Ans: B) HOF

Sol: 45) Ans: A) Cellophane

29) Ans: A) Nylon - 6 46) Ans: A) 1-Chloropentane

Sol: 1-Chloropentane does not have a chiral
30) Ans: A) 5.55  1023 cm3 C-atom.
Sol: For BCC structure, 47) Ans: B) does not change.
2M 2  60 Sol: As no ions are missing from the crystal as a
d  3.6 
NA .a 3
6  1023 a 3   whole, thus there is no effect on density.

2  60  10 23 48) Ans: C) NaWO3

 a3   5.55  1023 cm3 Sol: In an unit cell, W atoms at the corner
6  3.6
1
31) Ans: C) Face centred cubic  8 1
8
Sol: No. of atoms per unit cell are : simple cubic
1
 1,bcc  2 and fcc  4 . O atoms at the center of edges   12  3
4
32) Ans: C) Nylon Na atoms at the center of the cube = 1
33) Ans: A) titanium tetrachloride and trimethyl Thus, W : O : Na  1: 3 :1,  Formula  NaWO3
aluminium. 49) Ans: A) Cellulose
34) Ans: B) tert-butyl alcohol Sol: Cellulose is a biodegradable polymers.
50) Ans: A) FCC
nM 
Sol: d  400 pm  4  108 cm
N .a 3 
A


Sol: n  27 
2.7 
 
3
6  1023  4  108

2.7  64  1024  6  1023

n   3.84  4
27
 Unit cell is FCC type.
Cl
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35) Ans: B) CH2  C  CH  CH2

MHT CET CHEMISTRY 2023