SAFETY DATA SHEET

Revision Date 04-Jan-2019 Version 3

1. IDENTIFICATION
Product identifier
Product Name SUPER GLUE 1 OZ

Other means of identification

Product Code 49450

Recommended use of the chemical and restrictions on use

Recommended Use This product is a cyanoacrylate-based adhesive
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address: [email protected]

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin corrosion/irritation Category 2

Serious eye damage/eye irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Flammable liquids Category 4

Label elements

Emergency Overview
Signal word
Warning

Causes skin irritation

Causes serious eye irritation
May cause respiratory irritation
Combustible liquid

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Appearance Clear Physical state Liquid Odor Irritating

Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking

Precautionary Statements - Response

Call a POISON CENTER or doctor/physician if you feel unwell

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Call a POISON CENTER or doctor/physician if you feel unwell
In case of fire: Use CO2, dry chemical, or foam to extinguish.

Precautionary Statements - Storage

Store in a well-ventilated place. Keep cool
Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children

Unknown acute toxicity 15 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No Weight-%

ETHYL-2-CYANOACRYLATE 7085-85-0 60 - 100

4. FIRST AID MEASURES

Description of first aid measures

General advice Get medical advice/attention if you feel unwell.

Eye contact IF IN EYES:. Immediately flush with plenty of water. After initial flushing, remove any
contact lenses and continue flushing for at least 15 minutes. If eyelids are bonded closed,
release eyelashes with warm water by covering with a wet pad. Do not force eyes open. If

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eye irritation persists: Get medical advice/attention.

Skin contact IF ON SKIN:. Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. Allow warm water to penetrate the bond and gently
attempt to move bonded areas without pulling the skin away from bonded area. If skin
irritation persists, call a physician.

Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.

Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an

unconscious person. Call a physician.

Self-protection of the first aider Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use, Dry chemical, Carbon dioxide (CO2), Water spray (fog), Alcohol resistant foam

Unsuitable extinguishing media

None

Specific hazards arising from the chemical

Combustible material. Polymerizes with evolution of heat. Keep product and empty container away from heat and sources of
ignition. Risk of ignition.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.

Environmental precautions

Environmental precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off
floor. Sweep up and shovel into suitable containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
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7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep
in properly labeled containers.

Incompatible materials Strong oxidizing agents, Water, Alcohols, Alkalis, Amines

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
ETHYL-2-CYANOACRYLATE TWA: 0.2 ppm - -
7085-85-0
Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Skin and body protection Do not use PVC, nylon or cotton. Wear protective nitrile rubber gloves.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Liquid
Appearance Clear
Odor Irritating
Odor threshold 1 ppm

Property Values Remarks • Method

pH No information available
Melting point / freezing point No information available
Boiling point / boiling range > 149 °C / > 300 °F
Flash point 80-93.4 °C / 176-200 °F Tag Closed Cup
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure <0.2 mmHg

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Vapor density No information available

Relative density 1.06
Water solubility Insoluble in water Solidifies
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature 485 °C / 905 °F
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information
Softening point No information available
Molecular weight No information available
VOC Content (%) <20 g/l ( <2%)
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)

10. STABILITY AND REACTIVITY

Reactivity
No information available

Chemical stability
Stable under normal conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Heat, flames and sparks.

Incompatible materials
Strong oxidizing agents, Water, Alcohols, Alkalis, Amines

Hazardous Decomposition Products

Carbon oxides

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation May cause irritation of respiratory tract.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact Will bond to skin. May cause burns.

Ingestion Not an expected route of exposure.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

ETHYL-2-CYANOACRYLATE > 5 mL/kg ( Rat ) - -
7085-85-0

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
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Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 4990 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity

100 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number Not applicable

14. TRANSPORT INFORMATION

DOT
Proper shipping name: Not regulated

IATA
Proper shipping name: Not regulated

IMDG
Proper shipping name: Not regulated

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
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ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard No
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material

US State Regulations

California Proposition 65
This product is not known to contain any chemicals listed as carcinogens or reproductive toxins.
U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

ETHYL-2-CYANOACRYLATE X - -
7085-85-0
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable

WHMIS Hazard Class

D2B - Toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 2 Flammability 2 Instability 1 -
HMIS Health hazards 2 Flammability 2 Physical hazards 1 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 04-Jan-2019

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Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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