Worksheet - Covalent Bonding & Intermolecular Forces

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Mentone Grammar Chemistry

Electron dot diagrams for molecular compounds


5. Use electron dot diagrams and structural formulae to illustrate the bonds between each of the following pairs of atoms:

(a) hydrogen and bromine


(b) oxygen and fluorine.

6. Draw the electron dot diagram and the structural formula for nitrogen trifluoride, NF3, in which all three fluorine atoms are
bonded to the nitrogen atom.

7. Draw electron dot diagrams and structural formulae for the following molecules:

(a) CS2 (c) C2H6 (e) I2 (g) HCN


(b) HCl (d) C2F4 (f) C3H8

Predicting molecular shape


8. Copy and complete the following table.

Electron dot Number of lone pairs Number of bonding pairs Shape diagram and name of
Compound
diagram of molecule Around central atom around central atom shape
NI3

CF4

OF2

HOF

C2F2

C2Cl4

Non-polar and polar covalent bonds 1


13. Predict whether the following bonds are polar or non-polar. Show the bond dipoles where they are present using + and –.

(a) H—F
(b) O—H
(c) C—H
(d) N—H
(e) C—C

14. Classify the following bonds as ionic, polar covalent, or non-polar covalent:
(a) HI
(b) KCl
(c) F2.

15. Arrange the following bonds in order from non-polar covalent to ionic:

Li—F, N—N, F—N and Cl—N. Revision questions


Non-polar and polar molecules
16. Sketch the shape of the following molecules and use your knowledge of electronegativity to draw bond dipoles for each and
predict whether it is polar or non-polar.

(a) HI
(b) SiH4
(c) CS2
(d) H2S
(e) CH3Cl
(f) SF2
(g) NF3
(h) CH3F
(i) SiBr4
(j) HCl
(k) N2.

Intermolecular attractions
17. Name the type(s) of intermolecular forces that exist between molecules in each of the following species:

(a) CH4
(b) Cl2
(c) HCl
(d) CH3F
(e) NH3.

Properties of molecular substances in relation to structure


18. The boiling points of HCl, HBr and HI are, respectively, – 85°C, – 67°C and – 35°C. Explain the difference in these boiling
points with reference to the forces that exist between the molecules of each substance.

19. N2 has 14 electrons and Cl2 has 34 electrons. Predict which of these substances would have the higher boiling point. Justify
your answer in terms of intermolecular forces.

20. Two noble gases, helium and argon, have boiling points of –269°C and –186°C respectively. Explain the large difference in
their boiling points.

21. Both Kr (boiling point –152°C) and HBr (boiling point –67°C) have the same number of electrons. Explain what factors could
affect intermolecular forces to cause the difference in boiling points between Kr and HBr.

22. HCl has more electrons than HF so we would expect it to have the higher boiling point. However, this is not the case, as the
boiling points of HCl and HF are –83.7°C and 19.4°C respectively. Explain what factors could account for this reversal in trend.

23. Explain why glucose, C6H12O6, dissolves in water but does not conduct electricity in solid or aqueous form.

24. Explain why F2, O2 and N2 are all gases at room temperature.

25. Predict whether I2 will dissolve more readily in non-polar tetrachloromethane or in polar water. Explain your answer.

26. Predict the following properties of candle wax, C25H52, and explain your predictions using your knowledge of structure and
bonding. Would you expect C25H52 to be:

(a) soft or hard


(b) soluble in water
(c) an electrical conductor?

27. The melting points of compounds Cl2 and BrF are –101°C and –35°C respectively, and their boiling points are –33°C and –20°C
respectively. The masses of the two compounds are similar. Explain the differences in their melting and boiling points.

Mentone Grammar Chemistry


Answers

Mentone Grammar Chemistry


Mentone Grammar Chemistry
Mentone Grammar Chemistry

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