Mechanics of Balsa (Ochroma Pyramidale) Wood: MIT Open Access Articles
Mechanics of Balsa (Ochroma Pyramidale) Wood: MIT Open Access Articles
Mechanics of Balsa (Ochroma Pyramidale) Wood: MIT Open Access Articles
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Citation: Borrega, Marc, and Lorna J. Gibson. “Mechanics of Balsa (Ochroma Pyramidale)
Wood.” Mechanics of Materials 84 (May 2015): 75–90.
As Published: http://dx.doi.org/10.1016/j.mechmat.2015.01.014
Publisher: Elsevier
Version: Author's final manuscript: final author's manuscript post peer review, without
publisher's formatting or copy editing
Abstract
Balsa wood is one of the preferred core materials in structural sandwich panels, in
applications ranging from wind turbine blades to boats and aircraft. Here, we investigate
the mechanical behavior of balsa as a function of density, which varies from roughly 60
to 380 kg/m3. In axial compression, bending, and torsion, the elastic modulus and
strength increase linearly with density while in radial compression, the modulus and
strength vary nonlinearly. Models relating the mechanical properties to the cellular
structure and to the density, based on deformation and failure mechanisms, are described.
Finally, wood cell-wall properties are determined by extrapolating the mechanical data
for balsa, and are compared with the reduced modulus and hardness of the cell wall
measured by nanoindentation.
1
Introduction
Balsa (Ochroma pyramidale), a tropical hardwood native to the Americas, is one of the
fastest growing wood species, reaching about 20 m in height and up to 75 cm in diameter
in 5-8 years (Fletcher 1951). Most balsa wood used commercially is harvested from
plantations, particularly from Ecuador. Because of its fast growth, the wood density is
very low, making balsa the lightest commercial timber available. Density values for balsa
typically range between 100 and 250 kg/m3, although they can vary as much as from 60
to 380 kg/m3. The low density is extremely valuable in applications that require
lightweight materials with good mechanical performance. Balsa wood is one of the
preferred core materials in structural sandwich panels for wind turbine blades, sporting
equipment, boats and aircraft.
The large density variations in balsa derive predominantly from the fibers (Borrega et al.
2014), long prismatic cells that act as the main load-bearing elements in wood.
Consequently, the mechanical performance of balsa is strongly dependent on its density.
The axial compressive Young's modulus and strength increase linearly with density,
reaching values up to 6 GPa for modulus and 40 MPa for strength at the highest densities
(Da Silva and Kyriakides 2007). The failure mode in compression transitions from plastic
buckling of fibers to kink band formation as the density increases (Vural and
Ravichandran 2003; Da Silva and Kyriakides 2007). Kink band formation in high density
balsa is facilitated by local misalignment of fibers due to the presence of rays
(parenchyma cells), which leads to the development of shear stresses during compression.
The shear modulus and strength in balsa vary linearly with density, reaching values up to
350 MPa for modulus and 5 MPa for strength (Da Silva and Kyriakides 2007). In the
transverse direction, compressive modulus and strength vary roughly with the cube and
square of density, respectively, due to bending of the fiber cell walls (Easterling et al.
1982). Transverse compressive modulus and strength values are about an order of
magnitude lower than those in the axial direction. The transverse compressive modulus
and strength are higher in the radial than in the tangential direction because the rays act as
reinforcement.
2
The mechanical properties of balsa have been modeled, particularly in compression, by
considering the wood structure to resemble a honeycomb (Easterling et al. 1982; Gibson
and Ashby 1997; Vural and Ravichandran 2003; Da Silva and Kyriakides 2007).
Although this assumption is a simplification of the heterogeneous cellular structure in
wood, the models have proven to be useful in describing its mechanical properties over a
wide range of densities. As a cellular solid, the mechanical behavior of balsa (and other
woods) depends on the properties of the material from which the cell walls are made. The
dry density of the cell wall material is about 1469 kg/m3 for all woods (Kellogg and
Wangaard 1969), and thus the relative density of balsa, that is, the density of balsa
divided by that of the cell wall, is generally lower than 0.25. The mechanical properties
of the cell walls of wood have been determined by extrapolating mechanical data for
several woods of widely different densities; extrapolated values for axial cell-wall
Young’s modulus and strength are about 35-40 GPa and 120 MPa, respectively (Cave
1969; Gibson and Ashby 1997).
The axial cell-wall Young’s modulus has also been determined by a number of direct
methods, including tensile tests of isolated fibers and bending of a fiber cell wall.
Measured values for modulus are generally lower than those obtained by extrapolation.
A mean axial cell-wall modulus of about 20 GPa has been obtained by tensile tests on
mechanically and chemically isolated spruce fibers, but this elastic modulus was probably
affected by mechanical damage and degradation of structural components during the
isolation procedures (Burgert et al. 2005). Alternatively, an axial cell-wall modulus of
about 28 GPa has been obtained by Orso et al. (2006) by bending of cantilever beams,
which were produced with a focused ion beam (FIB) from the cell wall of spruce fibers.
The axial compressive strength of the secondary cell wall in spruce, Keranji and Loblolly
pine fibers, measured on micropillars machined by FIB, was 120-160 MPa (Zhang et al.
2010; Adusumalli et al. 2010). Typical values for the reduced modulus of the cell-wall
measured by nanoindentation range from 16 to 24 GPa (Gindl et al. 2004; Wu et al.
2009). However, this technique tends to underestimate the cell-wall modulus because it
reflects a combination of both axial and transverse properties, arising from the anisotropy
of the wood cell wall.
3
The relatively high mechanical properties of balsa, for its density, make it attractive for
cores in sandwich panels. To date, there are no engineered materials suitable for
sandwich panel cores with a similar combination of mechanical properties and low
density. With a view towards guiding the design of engineering materials inspired by
balsa, we recently conducted a detailed characterization of its structure and composition
(see Borrega et al. 2014). In this paper, we investigate its mechanical behavior over a
wide range of densities and analyze the failure mechanisms under different loading
conditions, relevant to the use of balsa wood in structural sandwich panels. The reduced
modulus and hardness of the cell wall are also measured by nanoindentation. The
mechanical properties are then modeled using existing models for cellular materials,
microstructural data for balsa, and cell-wall properties determined by extrapolating the
results from mechanical testing of macroscopic balsa specimens.
The cellular structure in balsa wood consists of fibers (66-76%), rays (20-25%) and
vessels (3-9%) (Borrega et al. 2014). The vessels are long tubular structures that run
axially along the trunk of the tree and transport fluids from the roots to the crown. Their
building blocks are known as vessel elements. The rays are brick-like parenchyma cells
that run radially from the central pith to the outer part of the trunk. Their main function is
to store sugars and other nutrients, although they also contribute to the radial strength of
the tree (Burgert and Eckstein 2001). The fibers are long prismatic cells, often resembling
a hexagon in cross-section, that provide mechanical support to the tree. For mechanical
purposes, wood is considered an orthotropic material, the three axes of symmetry being
the longitudinal (L, along the fibers), radial (R, along the rays), and tangential (T, across
the rays) (see Fig. 1). In balsa, the vessels are about 380 µm in length and 200-350 µm in
diameter, the rays are about 30 µm in length and 20-50 µm in cross-section, and the
fibers are about 700 µm in length and 20-40 µm in diameter, decreasing with density.
The thickness of the double cell wall is about 4 µm in vessels, 0.9 µm in rays, and
between 0.8 µm and 3 µm in fibers, increasing with density (Easterling et al. 1982; Da
Silva & Kyriakides 2007; Borrega et al. 2014).
4
The wood cell wall consists of a primary layer and three secondary layers, the S1, S2 and
S3. The S2 is generally the thickest layer, making up about 80-90% of the total cell wall
thickness in spruce tracheids (Fengel and Wegener 2003). In high density balsa, the S2
layer makes up about 73% of the cell wall thickness, while in low-density balsa the S2 is
of similar thickness as the S1 and S3 layers, making up about 30% of the total cell wall
thickness (Borrega et al. 2014). The middle lamella is a thin layer located between
primary layers of adjacent cells, bonding them together.
The cell wall layers in woods are made up of lamellae having a fiber composite structure,
in which cellulose microfibrils are embedded in a matrix of hemicelluloses and lignin. In
the primary layer, the cellulose microfibrils have no definite orientation. In the secondary
S1 and S3 layers, the microfibrils are oriented almost at 90° from the longitudinal cell
axis, while in the S2 layer they are mostly aligned with the longitudinal axis, with angles
typically varying between 10-30° (Barnett and Bonham 2004; Donaldson 2008). In balsa,
the mean microfibril angle (MFA) appears to be less than 2°, irrespective of density
(Borrega et al. 2014). The thickness and the low mean MFA of the S2 layer largely
govern the axial mechanical properties of wood, particularly the stiffness (Cave 1969).
The mechanical contribution of the S1 and S3 layers appears to be significant when wood
is loaded in the transverse direction (Bergander and Salmén 2002).
Cellulose microfibrils in woods contain both crystalline and amorphous regions. The
degree of crystallinity has been determined to be typically on the order of 40-60% for
both softwoods and hardwoods (Andersson et al. 2004; Wikberg and Maunu 2004;
Penttilä et al. 2013). In balsa, the degree of crystallinity appears to be much higher, about
80-90% (Borrega et al. 2014). The cellulose crystallites are about 3 nm in width and
about 20-30 nm in length, much in agreement with values reported for other woods (Hori
et al. 2002; Peura et al. 2008; Penttilä et al. 2013; Borrega et al. 2014). The crystalline
structure of cellulose dominates the axial mechanical properties of wood, while the ligno-
hemicellulosic matrix appears to have a more pronounced effect on the transverse
mechanical properties (Bergander and Salmén 2002).
Balsa wood
5
End-grain balsa blocks with dimensions 50 x 50 mm2 in cross-section and 300 mm in
length were obtained from National Balsa Wood Co. and Specialized Balsa Wood LLC.
In addition, end-grain balsa sheets with dimensions 76 mm in thickness, 610 mm in width
and 1219 mm in length were delivered by Baltek®. The sheets were composed of small
blocks, up to 100 x 100 mm2 in cross-section, glued together. The equilibrium moisture
content of the wood at room ambient conditions, determined by oven-drying
representative samples at 103 °C for 24 hours, was 5.8 ± 1.2%. At this moisture content,
the density of individual blocks varied from 60 to 380 kg/m3. Balsa specimens of
different densities were produced for mechanical testing. Specimens with densities below
100 kg/m3, between 100-200 kg/m3, and above 200 kg/m3 are here denoted as low density
(LD), medium density (MD) and high density (HD) balsa, respectively.
Mechanical testing
An additional set of LD and HD balsa specimens, having a notch on one side at about
mid-length, was tested in axial and radial compression. The notch did not affect the
crushing strength of the specimens, and it only served to initiate failure away from the
compression platens. Here, the strain was not measured with an extensometer, but it was
6
only approximated as the ratio of the cross-head displacement over the length of the
specimen. These particular specimens were used to examine the mode of failure in
compression (see below).
Bending
Balsa beams with dimensions 13 x 13 mm2 in cross-section and 204 mm in length were
tested in three-point bending, with a loading span of 170 mm. The bending tests were
conducted in an Instron 4201, equipped with a 500 N load-cell, under displacement
control. The displacement rate of the cross-head was set to 2 mm/s, and the deflection of
the beams was measured with a Trans-Tek 240 Series linear voltage displacement
transducer (LVDT). From the recorded load and displacement data, the bending stress
and strain, modulus of elasticity (MOE) and modulus of rupture (MOR) were calculated.
The MOR is a measure of the bending stress at fracture, calculated by assuming linear
elasticity up to fracture.
Torsion
Round balsa specimens with dimensions 36 mm in diameter and 300 mm in length were
prepared with a lathe. The middle section of the rods was then further reduced to about
22 mm in diameter, to ensure that failure developed away from the gripping clamps.
Furthermore, to avoid crushing the wood while tightening the clamps, hexagonal end-
caps made out of plywood were machined and glued with DAP Weldwood plastic resin
to both ends of each balsa specimen.
Torsion tests were conducted in an Instron 1321, equipped with a 50 kN load-cell, under
angular displacement control. The angular displacement rate of one of the clamps was set
to 0.5°/s, while the other clamp remained stationary. Two metallic cubes were glued to
the middle section of the balsa specimens, about 60-90 mm apart, and two LVDTs were
used to measure the linear displacement of the cubes during torsion. The linear
displacement was then converted to angular displacement, based on a preset calibration
done at the beginning of each test. From the recorded torque and angular displacement
data, the shear stress, strain, and modulus were calculated.
7
After the mechanical tests, sections containing the failure zone were cut out from selected
LD and HD balsa specimens, and the mode of failure in compression, bending and
torsion was examined in a JEOL JSM-6610LV scanning electron microscope (SEM). The
surface layers in the sections were removed with an industrial razor blade to obtain better
images in the SEM. All sections were observed without coating. Micrographs were taken
using the secondary electron detector in the SEM, operated at an accelerating voltage of
5-20 kV and in low-vacuum (30 Pa) mode.
Nanoindentation
A small HD balsa (264 kg/m3) cube was embedded in Spurr’s resin and placed under
vacuum for 48 hours to complete impregnation. Then, to produce a smooth surface for
nanoindentation, thin sections across the grain were cut with an ultramicrotome (Leica
Ultracut UCT) equipped with a diamond knife. After microtoming, the cube was glued to
a metal shim and magnetically clamped to the sample stage of a Hysitron TriboIndenter
system (Hysitron Inc., Minneapolis, USA). Images of the fiber cell walls were produced
with the indenter tip by means of in situ scanning probe microscopy (SPM). From the
SPM images, the indent positions were manually selected at about half-thickness of the
cell wall. Nanoindentation experiments were performed with a Berkovich tip (a three-
sided pyramid) in load-control mode, using a force of 100 µN. The three segments of the
load-displacement curve were: loading in 10 s, holding time of 5 s, and unloading in 10 s.
The hardness of the cell wall and the reduced elastic modulus, determined from the
unloading curve, were calculated according to Oliver & Pharr (2004).
Nanoindentation experiments were also conducted on a LD balsa (75 kg/m3) cube, after
preparing the sample following the procedure described above. However, we were unable
to obtain reliable data due to the small cell wall thickness relative to the indent size, even
at loads as low as 15 µN. For this reason, only those results from nanoindentation on HD
balsa will be reported.
Axial compression
8
Axial compression is one of the main loading modes of balsa wood in structural sandwich
panels. Typical stress-strain curves in axial compression for LD (71 kg/m3) and HD (265
kg/m3) balsa specimens are shown in Fig. 2. The stress-strain curves showed an initial
linear elastic response, followed by non-linear plastic yielding. Once the maximum stress
(compressive strength) was reached, the evolution of the stress was dependent on the
wood density. In LD balsa, the stress transitioned smoothly into a plateau, while in HD
balsa the stress dropped abruptly and then increased again until it seemingly reached a
plateau (Fig. 2). The drop in stress and the subsequent transition to a plateau were more
pronounced in balsa specimens of higher density. The axial compressive response of
balsa observed in this study is similar to that reported by Easterling et al. (1982) and Da
Silva & Kyriakides (2007).
The axial Young’s modulus and compressive strength of balsa increased linearly with
density, reaching values up to 9 GPa for the modulus and 43 MPa for the strength (Fig.
3). The data for the modulus showed some scatter at the highest densities, and thus the
goodness of the linear fit was lower than in the case of strength. By extrapolating the
linear fits up to a density equivalent to the density of the wood cell wall, one may obtain
a measure of the axial cell-wall properties. The dry density of the cell wall is about 1469
kg/m3 in all woods (Kellogg and Wangaard 1969), and considering that the moisture
content of balsa at the time of testing was about 6%, the density of the cell wall was
calculated to be 1557 kg/m3. Substituting this density into the linear fit equations in Fig. 3
gave an axial Young’s modulus and compressive strength for the cell wall of 41 GPa and
185 MPa, respectively.
The axial elastic modulus in wood is strongly dependent on the MFA in the S2 layer of
the cell wall. For MFAs smaller than 10°, the axial cell-wall modulus, extrapolated from
tensile experiments of Pinus radiata samples, appears to be around 40 GPa (Cave 1969).
In balsa, the mean MFA is less than 2° (see Borrega et al. 2014), and thus the axial cell-
wall modulus extrapolated here (41 GPa) is in agreement with the modulus reported by
Cave (1969). The extrapolated axial cell-wall compressive strength (185 MPa) is similar
to the values of 190-200 MPa estimated from compression data of balsa by Vural &
Ravichandran (2003) and Da Silva & Kyriakides (2007). These strength values are
somewhat higher than the 125-160 MPa measured from direct compression of cell wall
9
micropillars in spruce, Keranji and Loblolly pine fibers (Zhang et al. 2010; Adusumalli et
al. 2010). Artifacts produced during FIB milling as well as dimensional variations in the
cross-section of the micropillars might explain their lower compressive strength values.
The cellular structure in balsa wood is mostly composed of fibers; their volume fraction
is between 66-76% (Borrega et al. 2014). Fibers are long prismatic cells with a somewhat
hexagonal cross-section. If the cellular structure in balsa is idealized to resemble a
honeycomb, that deforms and then yields uniaxially, then the axial Young’s modulus
(EA*) and compressive strength (σA*) can be calculated as:
!∗
E!∗ = 𝐸! !!
(1)
!∗
𝜎!∗ = 𝜎! !!
(2)
where ES and σS are the axial cell-wall modulus (41 GPa) and compressive strength (185
MPa), and ρ* and ρs are the density of balsa and the density of the wood cell wall (1557
kg/m3), respectively (Gibson and Ashby 1997). The model from Eq. 1, plotted in Fig. 3a,
showed a good agreement with the linear fit determined experimentally. The model from
Eq. 2, plotted in Fig. 3b, seemed to slightly overestimate the compressive strength as a
function of density. This may due to the fact that the cellular structure in balsa (and in
woods) does not only consist of fibers, but other types of cells such as rays and vessels
exist. Therefore, at a given density, the fibers in balsa wood carry a higher share of the
load than the cells in a honeycomb. It is also possible that uniaxial plastic collapse of
fibers is not the only failure mechanism in axial compression, but other mechanisms are
involved.
The failure mechanisms in axial compression were examined in detail from selected LD
(71 kg/m3) and HD (265 kg/m3) balsa specimens. These specimens were compressed
either up to failure (crushing strength) or up to 8-10% strain After the compression tests,
the failure zone in the specimens was examined in the SEM. In LD balsa, failure was
initiated by local buckling followed by folding of the fiber cell walls (Figs. 4a,b), in
agreement with observations by Vural & Ravichandran (2003) and Da Silva &
Kyriakides (2007). After failure, the stress remained constant with increasing
compressive strain (see Fig. 2). During this stage, concertina folding developed in the cell
10
walls, and the failure band increased in size as neighboring fibers were crushed (Figs.
4c,d). The rest of the structure, away from the failure band, appeared to remain intact.
During axial compression of all but dense honeycombs, failure by simple plastic collapse
seldom occurs because the limiting stress for plastic buckling of the cell walls tends to be
reached first (Gibson and Ashby 1997). According to Wierzbicki (1983), the stress
required for axial collapse by plastic buckling (σpb*) can be calculated as:
!
∗ !∗ !
𝜎!" = 𝑚 𝜎! !!
(3)
where m is a factor that takes into account the uniformity of the cell wall thickness. For
regular hexagons with uniform wall thickness, m equals to 5.6 (Gibson and Ashby 1997).
In wood, the fibers are not regular hexagons, and the thickness of the cell wall is not
uniform. A value of 3.5 was used in this study to fit the model from Eq. 3 to the axial
compressive strength data of LD and MD balsa. As shown in Fig. 3b, plastic buckling
may be a potential failure mechanism in axial compression of balsa with densities lower
than 200 kg/m3, in agreement with the SEM observations in Fig. 4 and with results
reported by Vural & Ravichandran (2003).
The SEM examination of HD balsa specimens revealed that failure in axial compression
was initiated by buckling, followed by tangential displacement of the buckled fibers
(Figs. 5a,b). This type of failure, reminiscent of kink band formation, is facilitated by
local misalignment of fibers due to the presence of rays, which leads to the development
of shear stresses during compression (Vural and Ravichandran 2003; Da Silva and
Kyriakides 2007). Some cell wall folding can also be observed in Fig. 5b. After failure,
the compressive stress dropped by about 40% and then it slightly recovered with
increasing strain (see Fig. 2). This stress-state corresponded to a progressive tangential
displacement and crushing of the fibers, due to combined compression and shear forces.
Some of the crushed fibers in the failure zone can be seen, in Figs. 5c and d, oriented at
about 90° from their initial alignment. Similarly to LD balsa, the rest of the wood
structure away from the failure band appeared to remain intact.
11
the compressive strength of the material due to increasing shearing forces between the
fibers (Vural and Ravichandran 2003; Da Silva and Kyriakides 2007). The stress required
for kink band formation (σkb*) can be calculated, according to Budiansky & Fleck (1993),
as:
∗
∗ !!
𝜎!" = (4)
!!! !!
where GA* is the axial shear modulus of the material, θ is the angle misalignment and γy
is the yield strain in longitudinal shear. In wood, the axial shear modulus and strength
vary linearly with density (Gibson and Ashby 1997). Moreover, the axial cell-wall shear
modulus (GS) and strength (τS) in balsa wood equal to 2.1 GPa and 31 MPa, respectively
(see torsion results below), thus giving a yield strain (γy) of 0.015, independent of
density. Recently, we have reported the mean fiber misalignment in MD balsa to be 6.1°
(Borrega et al. 2014), similar to misalignment angles measured by Da Silva & Kyriakides
(2007). Substituting these values into Eq. 4, the stress required for kink band formation
was computed and plotted as a function of density in Fig. 3b. It can be seen that balsa
failed in axial compression at stresses much lower than those required for kink band
formation. It is likely that the kink band formation observed in Figs. 5a,b was preceded
by simple plastic collapse of the cell wall. It might also be possible that angles for fiber
misalignment are closer to the 9° measured by Vural & Ravichandran (2003). In fact, at
angles of 10°, the stresses required for kink band formation agreed well with the
compressive strength data for densities higher than 200 kg/m3 (model not shown).
Radial compression
The mechanical behavior of balsa in compression along the radial axis of symmetry (see
Fig. 1) is discussed in this section. Stress-strain curves in radial compression of selected
LD (88 kg/m3) and HD (265 kg/m3) balsa specimens are shown in Fig. 6. The stress-
strain curves showed an initial linear elastic response, followed by non-linear plastic
yielding. In LD balsa, the plastic deformation was accompanied by a plateau in the stress,
while in HD balsa the stress increased slightly as deformation increased. The steeper
slope of the stress-strain curve during plastic deformation in balsa wood of higher density
has also been reported by Easterling et al. (1982) and Da Silva & Kyriakides (2007).
12
The radial Young’s modulus and compressive strength of balsa increased with density,
reaching values up to 0.5 GPa for the modulus and 3.8 MPa for the strength at the highest
densities (Fig. 7). The radial modulus and strength were over an order of magnitude
lower than in axial loading. Wood is weaker and more compliant when loaded in the
transverse (radial or tangential) direction than in the axial direction. The reasons for this
are found in the ultrastructure of the cell wall as well as in the cellular structure of wood.
In transverse compression, the stiffness and strength of wood are lower because the
cellulose microfibrils, which are the main load-bearing elements in the cell wall, are
predominantly oriented perpendicular to the loading direction (Bergander and Salmén
2002; Salmén and Burgert 2009). Furthermore, the fibers are loaded perpendicular to
their main axis, which results in bending of their cell walls, similar to the behavior of
cells in a honeycomb when loaded in-plane (Easterling et al. 1982; Gibson and Ashby
1997). The transverse mechanical properties of wood are higher in the radial direction,
compared to the tangential direction, due to the reinforcing effect of the rays.
To account for the effect of rays in radial loading, a simple rule of mixtures may be used
to determine the radial Young’s modulus (ER*) and strength (σR*) in balsa wood:
where Vr is the volume fraction of rays (Vr = 21.9%, see Appendix 1), Er* and σr* are the
modulus and compressive strength of the rays, and Ef* and σf* are the modulus and
strength of the fibers (for simplicity, here we consider balsa to be made up of only rays
and fibers). Rays are brick-like parenchyma cells with their main axis aligned along the
radial direction in wood, while fibers are long prismatic cells with their main axis aligned
along the axial direction. Therefore, during radial loading, the cell walls in rays are
axially compressed but the cell walls in fibers bend. Then:
!
𝐸!∗ = 𝑉! 𝐸!! 𝑆! + 1 − 𝑉! 𝐸!! 𝑆! (7)
!
𝜎!∗ = 𝑉! 𝜎!! 𝑆! + 1 − 𝑉! 𝜎!! 𝑆! (8)
13
where ESr and σSr are the radial cell-wall modulus and compressive strength of rays, ESf
and σSf are the radial cell-wall modulus and compressive strength of fibers, Sr is the solid
fraction of rays and Sf is the solid fraction of fibers. The solid fraction of rays and fibers
appears to vary as a function of balsa density (see Appendix 1), and assuming that ESr =
ESf and σSr = σSf, Eqs. 7 and 8 are transformed into:
!
𝐸!∗ = 𝐶! 𝐸! 𝑉! 𝑆! + 1 − 𝑉! 𝑆! (9)
!
𝜎!∗ = 𝐶! 𝜎! 𝑉! 𝑆! + 1 − 𝑉! 𝑆! (10)
where ES and σS are the axial cell-wall modulus (41 GPa) and compressive strength (185
MPa), and C1 and C2 are coefficients that account for the anisotropy of the wood cell
wall. By fitting Eqs. 9 and 10 to the experimental data in Fig. 7, and extrapolating up to a
density of 1557 kg/m3, radial cell-wall properties of 9.2 GPa (C1=0.22) for modulus and
36 MPa (C2=0.19) for strength were obtained. These cell-wall properties are lower than
the 19 GPa for modulus and 50 MPa for strength extrapolated by Gibson and Ashby
(1997). However, those authors did not consider the effect of the rays in extrapolating the
radial properties of the cell wall. The radial cell-wall modulus extrapolated here (9.2
GPa) agrees well with previous studies suggesting that the transverse cell-wall modulus
in wood is lower than 10 GPa (Cave 1969; Salmén 2004).
The contribution of rays and fibers to the radial Young’s modulus and compressive
strength in balsa is shown in Fig. 7. The models from Eq. 9 and 10 seemed to slightly
underestimate the radial mechanical properties, but nonetheless they showed a rather
good agreement with the experimental data. It appears from Fig. 7a that rays have a
higher contribution than fibers to the radial modulus of balsa wood, while rays have a
higher contribution to the strength only at densities below 200 kg/m3 (Fig. 7b).
The mode of failure in radial loading was examined in the SEM for selected LD (88
kg/m3) and HD (265 kg/m3) balsa specimens. The specimens were compressed either up
to failure (compressive strength) or up to 8-10% strain. Failure in radial compression
occurred, in both LD and HD balsa, by plastic collapse and subsequent flattening of the
cell walls in fibers, but also in rays (Figs. 8a,b). After failure, the stress gradually
transitioned into a plateau in LD balsa, while it appeared to increase slightly in HD balsa.
14
Along with increasing compression strain, wider areas of the balsa structure failed, and
eventually the vessels collapsed (Figs. 8c,d). The progressive collapse of the cell walls
resulted in densification of the structure, which was more evident in HD balsa than in LD
due to the higher solid fraction of fibers in the former.
Bending
15
320 MPa for cell-wall MOR is within the range of 300-400 MPa reported by Cave (1969)
for tensile cell-wall strength in pine wood samples.
If the cellular structure in balsa is idealized to resemble a honeycomb, then the MOE and
MOR can be calculated as:
!∗
𝑀𝑂𝐸 ∗ = 𝐶! 𝐸! !!
(11)
!∗
𝑀𝑂𝑅∗ = 𝐶! 𝜎! !!
(12)
where ES and σS are the axial cell-wall modulus (41 GPa) and compressive strength (185
MPa), and C3 and C4 are factors related to the different compression and tension values in
composite materials. By assuming the extrapolated values from the linear fits in Fig. 10,
then C3 in Eq. 11 equals to 0.88 and C4 in Eq. 12 equals to 1.73. The model from Eq. 11
agrees well with the experimental data for MOE (Fig. 10a), while the model from Eq. 12
appears to overestimate the MOR (Fig. 10b), similar to the model from Eq. 2
overestimating the axial compressive strength in Fig. 3b. As mentioned above, the balsa
structure is not only composed of fibers, as idealized in a honeycomb, but other types of
cells like rays and vessels exist. Therefore, at a given density, the fibers must carry a
higher share of the load than if they were the sole cell type. It appears from Fig. 10 (and
also from Fig. 3), that rays and vessels contribute more to the flexural (and axial)
modulus than to the strength.
Failure of balsa specimens in bending occurred as the flexural stress corresponding to the
MOR was reached on the bottom of the beam, subjected to tension, and the beam
fractured. The fracture of selected LD (88 kg/m3) and HD (227 kg/m3) balsa specimens
was examined in the SEM. The failure crack appeared to propagate across cells, rather
than between cells (Fig. 11a). In LD balsa, the crack propagated rapidly across the depth
of the beam, sometimes splitting it in two. In HD balsa, the propagation of the crack was
somewhat more limited, and it was often hard to see the crack with a naked eye once the
bending test had terminated. Although all specimens ultimately failed in tension,
compressive failure occurred first. This is because wood is generally stronger in tension
than in compression, and thus during bending, a maximum ultimate stress is first reached
on the compression side (Bodig and Jayne 1982). Upon failure by compression, the
16
neutral plane moved towards the tension side, where wood ultimately failed and
fractured. An example of compression failure during bending is shown in Fig. 11b, where
the fibers in HD balsa are clearly seen to buckle, forming a failure band reminiscent of a
kink band. This type is failure is similar to the failure observed during axial compression
of HD balsa (see Figs. 5a,b).
Torsion
Along with axial compression, shear is one of the main loading modes of balsa wood in
structural sandwich panels. Since torsion produces pure shear stress, torsion experiments
were conducted in this study to investigate the shear behavior of balsa. Examples of
stress-strain curves in torsion of LD (85 kg/m3) and HD (240 kg/m3) balsa specimens are
shown in Fig. 12. The initial shear response of balsa was linear elastic, followed by a
broad plastic deformation until failure occurred at about 2.5% strain. The shear modulus
(GA) and shear strength (τA) in torsion increased linearly with density, with values up to
0.55 GPa for modulus and 7 MPa for strength at the highest densities (Fig. 13). The shear
modulus and strength values obtained here were found to be higher than those determined
by Da Silva & Kyriakides (2007). Those authors, however, used a different experimental
setup in order to determine the shear properties of balsa in both the axial-tangential and
axial-radial plane. The extrapolation of the linear fits in Fig. 13, up to a density of 1557
kg/m3, gave a shear cell-wall modulus of 2.1 GPa and shear cell-wall strength of 31 MPa.
These values are similar to the out-of-plane (axial-radial or axial-tangential) shear
modulus (2.6 GPa) and strength (30 MPa) extrapolated by Gibson & Ashby (1997).
!∗
𝜏!∗ = 𝐶! 𝜎! !!
(14)
where ES and σS are the axial cell-wall modulus (41 GPa) and crushing strength (185
MPa), and C5 and C6 are factors related to the cell geometry that are generally found from
fits to data (Gibson and Ashby 1997). The value of C5 was estimated to be 0.05, so the
17
product C5ES would correspond to the extrapolated shear cell wall modulus (GS = 2.1
GPa). The value of C6 was estimated to be about 0.17, so the product C6σS would
correspond to the extrapolated shear cell-wall strength (τS = 31 MPa). As seen in Fig. 13,
the models from Eq. 13 and 14 showed an excellent agreement with the experimental
data, indicating that balsa subjected to torsion can be modeled as a honeycomb. Because
the relative density does not only include the contribution of fibers, but also that of rays
and vessels, it may be concluded that the whole cellular structure in balsa affects its shear
properties.
Failure of balsa specimens during torsion occurred by fracture along the axial direction.
Selected micrographs of LD (85-88 kg/m3) and HD (219-239 kg/m3) balsa specimens
after fracture are shown in Figs. 14 and 15. In 3 out of 4 LD balsa specimens, the failure
crack propagated according to a TR mode, where the first letter indicates the direction
normal to the crack plane, and the second describes the direction of the crack
propagation. This mode of crack propagation in LD balsa can be clearly seen in Figs. 14.
In the remaining LD balsa specimen, as well as in 4 out of 5 HD balsa specimens, the
crack propagated according to a RT mode (Figs. 15). The crack in the fifth HD balsa
propagated in a mixed TR/RT mode. Previous results by Da Silva & Kyriakides (2007)
showed that balsa was generally stronger in shear in the axial-radial plane, compared to
the axial-tangential plane, and that the difference in shear properties between planes
became more pronounced with increasing density. It is then likely that, in HD balsa, the
crack tended to propagate along the weaker (tangential) direction. It may be also possible
that, in LD balsa, the predominant direction (radial) for crack propagation was only
coincidental. Testing a higher number of LD and HD balsa specimens would be needed
to better elucidate on the predominant direction of crack propagation in balsa during
torsion.
In addition to different modes of crack propagation, the fracture of torsion specimens also
differed between LD and HD balsa. In LD balsa, the crack could clearly be seen with a
naked eye, while in HD balsa the crack was rather difficult to see, even with the aid of the
SEM. A closer examination of the fracture zone in LD balsa appeared to reveal that the
crack mostly developed through the ray pockets, pulling apart individual cells (inter-cell
propagation) (Fig. 14). In HD balsa, however, the crack seemed to propagate through the
18
cell walls (intra-cell) in fibers, but possibly also in rays (Fig. 15). This is somewhat
surprising because in LD balsa the rays are denser than the fibers, while in HD balsa the
fibers are considerably denser than the rays (see Borrega et al. 2014). Therefore, one
might expect that the propagation of the crack would be intra-cell in LD balsa but inter-
cell in HD balsa. The reasons for a predominant fracture behavior in balsa samples of
different density, as observed in this study, are not yet fully understood.
Nanoindentation
The reduced modulus and hardness of the wood cell wall can be determined by
nanoindentation. With this technique, a small indenter is driven into the cell wall, and the
force and area of the indent are measured. The hardness is calculated from the area under
the maximum load applied, while the reduced elastic modulus is calculated from the
unloading section of the load-displacement curve (see Oliver and Pharr (2004) and Gindl
and Schöberl (2004)). In HD balsa (264 kg/m3), the mean cell-wall hardness and reduced
modulus were 0.57 ± 0.11 and 19.4 ± 4.4 GPa, respectively. These values are mostly in
agreement with the 0.40-0.56 GPa for hardness and 16-24 GPa for reduced modulus
reported for 10 different hardwoods (Wu et al. 2009) and for spruce wood tracheids with
mean MFAs close to 0° (Gindl et al. 2004). However, the reduced modulus determined
by nanoindentation (19.4 GPa) is about half the value of the axial cell-wall Young’s
modulus (41 GPa) determined by extrapolation in axial compression experiments (see
Fig. 3). It is generally recognized that nanoindentation is not a suitable technique to
determine the axial elastic modulus of the wood cell wall because nanoindentation theory
is based on the assumption of isotropy, which cannot be applied to wood due to the
composite nature of the cell wall. Furthermore, for indents are performed with a
Berkovich tip, a three-sided pyramid, the cellulose microfibrils in the cell wall are loaded
at an angle of 25°, which obviously underestimates the axial elastic modulus (Gindl and
Schöberl 2004).
The mechanical properties of balsa wood in axial and radial compression, bending and
torsion were investigated as a function of density. The density of balsa varied roughly
from 60 to 380 kg/m3. In axial compression, the Young’s modulus and strength increased
19
linearly with density, reaching values up to 9 GPa for the modulus and 43 MPa for the
strength at the highest densities. The main failure mechanism in LD balsa was plastic
buckling, while failure in HD balsa probably occurred by a combination of plastic
collapse and kink band formation. In radial compression, the Young’s modulus and
strength increased nonlinearly with density, and were over an order of magnitude lower
than in axial compression, with values around 0.5 GPa for the modulus and 3.8 MPa for
the strength at the highest densities. The radial mechanical properties were dependent on
the fibers, which were subjected to bending, and on the rays, which were axially
compressed during radial loading. Therefore, the radial modulus and strength increased
with the sum of the fiber and ray contributions: with the cube and the square of the
relative density of fibers, and linearly as a function of the relative density of rays,
respectively. Failure occurred by plastic collapse of the cell walls in fibers and rays,
resulting in densification of the structure.
In bending, the modulus of elasticity (MOE) and modulus of rupture (MOR) increased
linearly with density, reaching values up to 8 GPa for MOE and 70 MPa for MOR at the
highest densities. Failure occurred first on the upper side of the beam, subjected to
compression, but the wood ultimately fractured on the lower side of the beam due to
increased tensile stresses. In LD balsa, the crack propagated across the cell walls, largely
through the whole depth of the beam. In HD balsa, the propagation of the crack was more
limited, and often difficult to observe with a naked eye. Compression failure in HD balsa
occurred as the fibers buckled and were laterally displaced, similar to the failure
mechanism observed during axial compression.
In torsion, the shear modulus and strength increased linearly with density, reaching
values up to 0.55 GPa for modulus and 7 MPa for strength at the highest densities.
Failure occurred by fracture along the axial-radial or axial-tangential planes. The
predominant mode of crack propagation seemingly differed between LD and HD balsa.
In LD balsa, the crack tended to propagate between cells (inter-cell), along the radial
direction and through the rays pockets. In HD balsa, the crack appeared to propagate
across cells (intra-cells) and along the tangential direction in wood, splitting apart the
fiber cell walls. The predominant mode of crack propagation in HD balsa might be
related to the reinforcing effect that the rays exert in the radial direction.
20
The mechanical behavior of balsa was modeled by considering its cellular structure to
resemble a honeycomb. In axial compression and bending, and particularly in torsion, the
mechanical models showed a good agreement to the experimental data. However, the
axial compressive strength and MOR were slightly overestimated, possibly due to the fact
that the cellular structure in balsa (and in woods) does not only consist of fibers, but other
type of cells such as rays and vessels exist. Fibers are the main load-bearing cells in
wood. Therefore, at a given density, individual fibers in balsa were likely to carry a
higher share of the load than individual cells in a honeycomb. In radial compression, a
rule of mixtures was used to account for the contribution of rays to the radial modulus
and strength of balsa wood. The resulting models showed a rather good agreement to the
experimental data, even if the mechanical properties were slightly underestimated.
However, the mechanical models in radial compression were limited by the current
knowledge on the variation in volume and solid fraction of rays with balsa density, as
well as on cell-wall properties in rays and fibers.
The mechanical properties of the wood cell wall were determined by extrapolating the
mechanical properties of balsa up to a density equivalent to that of the solid cell wall
(1557 kg/m3 for a moisture content about 6%). In axial compression, the extrapolated
cell-wall values were 41 GPa for Young’s modulus and 185 MPa for strength, while in
radial compression the extrapolated cell-wall modulus and strength were 9 GPa and 36
MPa, respectively. In bending, the extrapolated cell-wall MOE and MOR were 36 GPa
and 320 MPa, respectively. The cell-wall MOE was a good approximation to the 41 GPa
extrapolated for the axial cell-wall modulus, considering the relatively short span-to-
depth ratio of balsa specimens used in the bending tests. In torsion, the extrapolated cell-
wall shear modulus and strength were 2.1 GPa and 31 MPa, respectively. The axial cell-
wall modulus and hardness were also determined by nanoindentation; in HD balsa, values
of about 19 GPa for the modulus and 0. 57 for hardness were obtained. This cell-wall
modulus was about half of that extrapolated (41 GPa) from mechanical tests of balsa,
most likely due to the fact that, in an orthotropic material like wood, nanoindentation
measures a combination of property values in the different directions.
Acknowledgements
21
Funding provided by BASF through the North American Center for Research on
Advanced Materials (Program Manager Dr. Marc Schroeder; Dr. Holger Ruckdaeschel
and Dr. Rene Arbterx) is gratefully acknowledged. The Hobby Shop in MIT is thanked
for their help in preparing the balsa wood specimens for mechanical testing. Mike
Tarkanian (MIT) is thanked for his help in planning the torsion tests. Dr. Alan
Schwartzman (MIT) is thanked for his kind support with the nanoindentation
experiments. Patrick Dixon (MIT) is thanked for his help in conducting the mechanical
tests and discussing the results.
References
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24
Appendix 1.
The cellular structure of balsa mainly consists of fibers, rays and vessels. The
dimensions, solid fraction and volume fraction of each type of cell in balsa wood of
different densities have been determined by Borrega et al. (2014). Data for solid and
volume fraction of rays are listed in Table A1.
Table A1. Mean solid and volume fraction of rays in balsa wood of different densities.
From the values in Table A1, the solid fraction of rays appears to increase only slightly
as a function of density. However, the volume fraction of rays may be considered
independent of wood density, the mean volume fraction being about 21.9%. Then, the
density of balsa can be calculated as:
𝜌!"#$" = 𝜌! 𝑉! 𝑆! + 1 − 𝑉! 𝑆! (A1)
where ρS is the density of the wood cell wall, Vr (21.9%) is the volume fraction of rays
in balsa, Sr is the solid fraction of rays and Sf is the solid fraction of fibers (for
simplificity, here we consider balsa to be made up of only rays and fibers). The dry
density of the cell wall is about 1469 kg/m3 in all woods (Kellogg & Wangaard 1969),
and considering that the moisture content of balsa at room conditions was about 6%, the
density of the cell wall (ρS) is about 1557 kg/m3. Substituting into Eq. A1, Sf can be
calculated for each of the measured balsa densities in Table A1.
The solid fraction of rays (Sr) and that of fibers (Sf) is plotted as a function of balsa
density in Fig. A1. For ρbalsa = 0, Sr and Sf equal to 0. For ρbalsa = ρS =1557 kg/m3, one
can assume that Sr and Sf equal to 1. As shown in Fig. A1, the volume fraction of rays
and fibers as a function of wood density may be described by a polynomial function.
1.2
Solid
fraction
of
cells,
%
1
y
=
-‐5E-‐08x2
+
0.0007x
0.8
0.6
0.4
y
=
2E-‐07x2
+
0.0003x
0.2
0
0
400
800
1200
1600
Fig. A1. Volume fraction of rays (circles) and fibers (squares) determined for different
balsa densities. Black line and equation correspond to a polynomial fit to the data.
Figure captions
Fig. 1. SEM micrographs of balsa showing the main type of cells in (a) cross-section and
(b) longitudinal view. L, R and T refer to the longitudinal, radial and tangential axes of
symmetry.
Fig. 2. Stress-strain curves in axial compression tests of selected LD (71 kg/m3) and HD
(265 kg/m3) balsa specimens. D and L in the x-axis refer to the displacement of the
compression platen and to the length of the balsa specimen, respectively.
Fig. 3. (a) Axial Young’s modulus and (b) compressive strength of balsa wood as a
function of density. Solid black lines and equations correspond to linear fits to
experimental data. Dashed black lines correspond to models (Eqs. 1 and 2) for modulus
and strength. Red line in (b) corresponds to model (Eq. 3) for plastic buckling. Blue line
in (b) corresponds to model (Eq. 4) for kink band formation.
Fig. 4. SEM micrographs of LD balsa showing (a and b) the initiation of failure by local
buckling in axially crushed fibers (3.3% strain) and (c and d) the evolution of failure at
8.1% compressive strain.
Fig. 5. SEM micrographs of HD balsa showing (a and b) the initiation of failure by kink
band formation in axially crushed fibers (3.3% strain) and (c and d) the evolution of
failure at 10.1% compressive strain.
Fig. 6. Stress-strain curves in radial compression tests of selected LD (88 kg/m3) and HD
(265 kg/m3) balsa specimens. D and L in the x-axis refer to the displacement of the
compression platen and to the length of the balsa specimen, respectively.
Fig. 7. (a) Radial Young’s modulus and (b) compressive strength of balsa wood as a
function of density. Solid black lines correspond to polynomial fits to experimental data.
Dashed black lines correspond to models (Eqs. 9 and 10) for modulus and strength. Red
lines correspond to contribution of the rays, and blue lines correspond to contribution of
fibers.
Fig. 8. SEM micrographs showing (a and b) cell collapse in LD balsa under radial
loading (2.6% strain) and (c and d) the eventual collapse of vessels with increasing
compressive strain, resulting in densification of the structure in (c) LD balsa (9.0% strain)
and (d) HD balsa (9.5% strain).
Fig. 9. Force-displacement curves in bending tests of selected LD (88 kg/m3) and HD
(227 kg/m3) balsa specimens.
Fig. 10. (a) Modulus of elasticity (MOE) and (b) modulus of rupture (MOR) of balsa
wood as a function of density. Solid black lines and equations correspond to linear fits to
experimental data. Dashed black lines correspond to models (Eqs. 11 and 12) for MOE
and MOR.
Fig. 11. SEM micrographs showing (a) the failure crack in bending propagating across
cells on the tension side of LD balsa (0.7% strain) and (b) failure in bending by kink band
formation on the compression side of HD balsa (1.1% strain).
3
Fig. 12. Stress-strain curves in torsion tests of selected LD (85 kg/m ) and HD (240
kg/m3) balsa specimens.
Fig. 13. (a) Shear modulus and (b) shear strength of balsa wood in torsion as a function of
density. Solid black lines and equations correspond to linear fits to experimental data.
Dashed black lines correspond to models (Eqs. 13 and 14) for shear modulus and
strength.
3
Fig. 14. SEM micrographs of LD balsa (85-88 kg/m ) after torsion showing the fracture
crack in the axial-tangential plane (2.1% strain). The crack appears to be inter-cell,
splitting the rays apart.
3
Fig. 15. SEM micrographs of HD balsa (219-239 kg/m ) after torsion showing the fracture
crack in the axial-radial plane (2.6% strain). The crack appears to be intra-cell, splitting
the cell wall in fibers apart.
Fig. 1.
a)
b)
Fig. 2.
Axial
compressive
stress
(MPa)
30
25
HD
balsa
(265
kg/m3)
20
15
10
LD
balsa
(71
kg/m3)
5
0
0
0.02
0.04
0.06
0.08
0.1
D/L
(mm/mm)
Fig. 3.
a)
10
Axial
Young's
modulus
(GPa)
9
8
7
6
5
4
3
2
y
=
0.0266x
-‐
0.4807
R²
=
0.85
1
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
b)
50
Axial
compressive
strength
(MPa)
45
40
35
30
25
20
15
10
y
=
0.1219x
-‐
4.904
5
R²
=
0.96
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
Fig. 4.
a)
b)
Fig. 4.
c)
d)
Fig. 5.
a)
b)
Fig. 5.
c)
d)
Fig. 6.
Radial
compressive
stress
(MPa)
3.5
3
2.5
HD
balsa
(265
kg/m3)
2
1.5
1
LD
balsa
0.5
(88
kg/m3)
0
0
0.02
0.04
0.06
0.08
0.1
D/L
(mm/mm)
Fig. 7.
a)
0.6
Radial
Young's
modulus
(GPa)
0.5
R2
=
0.72
0.4
0.3
0.2
0.1
0.0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
b)
4
Radial
compressive
strength
(MPa)
3.5
3
R2
=
0.81
2.5
2
1.5
1
0.5
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
Fig. 8.
a)
b)
Fig. 8.
c)
d)
Fig. 9.
300
250
HD
balsa
200
(227
kg/m3)
Force
(N)
150
100
50
LD
balsa
(88
kg/m3)
0
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
Displacement
(mm)
Fig. 10.
a)
10
9
Modulus
of
elasticity
(GPa)
8
7
6
5
4
3
2
y
=
0.0235x
-‐
0.4666
R²
=
0.95
1
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
b)
80
70
Modulus
of
rupture
(MPa)
60
50
40
30
20
y
=
0.2157x
-‐
13.007
10
R²
=
0.96
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
Fig. 11.
a)
b)
Fig. 12.
6
5
Shear
stress
(MPa)
4
3
2
1
0
0
0.005
0.01
0.015
0.02
0.025
0.03
Shear
strain
(mm/mm)
Fig. 13.
a)
0.6
0.5
Shear
modulus
(GPa)
0.4
0.3
0.2
0.0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
b)
8
7
Shear
strength
(MPa)
6
5
4
3
2
y
=
0.0196x
+
0.3879
1
R²
=
0.89
0
0
50
100
150
200
250
300
350
400
Density
(kg/m3)
Fig. 14.
a)
b)
Fig. 14.
c)
d)
Fig. 15.
a)
b)
Fig. 15.
c)
d)