dws: A ane Oo LA, Us iu Tos lam 4 4s ine Miz ctw 9 te Cae 3a: Te yoate, we inwte Cade: by = atm, | Pats = tains | age: @) 1 Cte imw — conta WY T@vemie — cand Gola: Gat: He iis oy ~ Po Xn Pro ~ Pa an se a en nat OR = 6a - Cn . y Tore > Prope — atm = vat Pir Pom > & 3[o) Ce, * = 5 ves 19215 cates Li _+ 10-batm | Po > OTS) FOF pe en Wi Te moh t tink —@ Tet Pe) Pinky Play Orbe Soe Pie Yay hs = PS ep Gs Pe feo ({+ xe) Hey - the = = Pos Pa 0-198 fete Pe Rete ny) ea OUD (“ae 4 ee Patt — te Mey Crag tt 24 5 = Pe Xt Kee er tory = 25( 0.98 7 fe) : bes Per Poke s 2.5 (0.10%) > 0-915 atm ©: TA tte + Wo Pea 25(oAT Pa) + OS 1 ~ 0.57 HOMO + 7 Pr= 0-GIGt =” 0.60 aw * — Cher T 1 >_10, Bo - lod an finde A tte et Teas . 4 Ww Vad a nin ae aarb yams et fenton) Rags | Vv Corin | came bow oles Cow bi =e tk Cant: “Th k ~ 4s ber) & yr, as Fo kG ttt Ay > ot os =u -tr) = by +f Pare rihetyd” (0m « wate) Cc a ‘ ‘a 6 Pos tem oy). win her) pe en Jot hing te DFO: Pro=e ~ be ya: [po i]| 1 ‘CHE 23_A MIDTERM O23 Encircle the letter that corresponds to the correct answer. Absolutely no erasures. | i | scort x NAME: i, Alan Dovid J: DP The following data were taken for a liquid-phase reaction in a continuous flow stirred tank reactor having a volume of 2 ft. Initial concentration of the reactant A is 0.20 lbmoles/ft? and all runs ap. at the same temperature. | 'bmoles A converted per hr flowrate rate, ft'/hr 0.0450 | 0.265 @ 0.1250 0.835 | Find the | 1.2 conversion for the second run (3 pts) | 2.) 0.7485 b.0.8491 09721 a.06895 | 1.2/onversion for the first run (3 pts) | 8491 b. 0.7623 €.0.6126 doses | \ | 1.3 the magnitude of the rate constant (4 pts). « | a. 34.78 b.41.23 (es @e. 7 | 1.4 apparent order of pae-reaction (4 pts) | a3 b. 4 @17 1.5 Using the same initial concentration, calculate the volume (ft?) of a tubular flow reactor to convert 90% of the reactant to products at a flow rate of 40 ft'/hr at the same Cae (S pts) 9 a. 53.81 b.673 ©1069=" Patani, Alan Dovid TO ENCHAA 1. Which of the following is suitable for viscous reactions? wel a, Batch Reactor (b.)Mixed Flow Reactor % Plug Flow Reactor 4. Fluidized Bed Reactor 2. A reactor that offers good control of reaction is: ‘paiva ‘a,) Semi-batch Reactor / B. Mixed Flow Reactor ¢. Plug Flow Reactor d. Batch Reactor 3. Irreversibility of reaction increases with: ‘a. Temperature .. Concentration of a Product Equilibrium Constant / ‘d._ Variability in the Volume 4, Which of the & isn’t tue for a first-order ineversible reaction? Cac=0 ~ Kae 17 Kao Cresent >>Crocy a b. a a 5, Which isn’t true for varying volume batch reactor?” a. Used for isothermal operations b. Used for isobaric operations Used for any type of reaction / @._ Most of the time designed as a PFR 6. A-constant-density system is one where a. Reacting system is aqueous / b. Pressure is constant / ©. Vote = Vresstor (@ Allo these 7. At equilibrium, a. Products and reactant cone. are equal (B®) Rate of forward ram equals reverse rxn c. The reaction stops 4. The reactant is completely used up. (geno Io CHEN A 8. Reactor that offers good product quality: a, Semi-batch Reactor b. Packed Bed Reactor © Plug Flow Reactor; Steady State Flow Reactor / 4. Batch Reactor 9, Residence time of all fluid elements inside the Feactor is the same: . Semi-batch Reactor b, Packed Bed Reactor © Plug Flow Reactor, @. Batch Reactor 10. The conditions in the reactor vary-with-posit ion nas-wellas-time— a True False ’True only for Flow Reactors , / d. True only for Batch Reactors 1. The performance sqysion ntereate te if reaction, the exi@ht of reaction, the reactor volun, and: a. Concentration @) Feed Rate“ ©. Rate Law d. Conversion o 12, An element of fluid reacts for the same length of ‘timg in the ‘a. Batch and Mixed Flow Reactor (b) Mixed Flow and Plug Flow Reactor . Batch and Plug Flow Reactor d. Fluidized Bed Reactor 13. For the Plug Flow reactors, which statement is true? a. For parallel connections, the space-time for each branching should be the same b. For series connections, the no. of reactors in the series could be represented by just one plug flow reactor with its volume equal to the sum of the volumes of each of the reactors.X The composition for each parallel connections should be equal, / 4. Alll of the above. 14, The energy and material balance equations for all reactors types are being tied together by the a. Rate of accumulation term b. Input term Term containing the rate law / Output term 15. The extent of a particular type of reaction can be measured using the change in of a reacting component. a. Concentration b. Partial Pressure ¢. Conversion © sy of these 16. The statements below are all true except: a. The space-velocity can be a performance measure for flow reactors. b. The residence time for all elements of fluid of the plug flow reactor should be the same ©) For multiple or solid catalyzed reactions, a plug flow reactor is recommended. 4. For plug flow reactors, composition of fluid varies from point to point along the flow path. 17. For autocatalytic reactions A+R—R+R a. Therate is maximum when concentrations of product and reactant are equal The rate will rise as reactant is consumed ¢c.) The rate drops to zero as more product is Produced 4. At any time the concentrations of reactant and product are equal 18. For all irreversible two-step reactions in series A>~R-S The greatest rate of increase in the concentration of the final product is observed when the intermediate concentration is max. / b. The amount of R decfeases exponentially ¢c. The total no. of moles at any time is constant regardless of stoichiometry. 4. All ofthe above 19. Ifempirical data is so large, a. Integral analysis is advised b. Trial and error procedure in problem solving ‘could be used .) Differential analysis is preferred / Any of the above 20. An energy balance is performed over the whole reactor or a selected volume of reacting fluid when process is a. Isochoric/isometric b. Adiabatic ©. Non-isobaric Non-isothermal / For a zero-order reaction, with stoichiometry A —> rR taking place in a constant-volume bomb, = latm when t= 0 and x= 1.Satm when t= Is. For the same reaction, same feed composition and initial pressure taking place in a constant- pressure setup, find V at t= 2s if V= 1.2 liatt= 0s. 2. The homogeneous gas reaction 3A —> 2R follows second-order kinetics. For a feed rate of 4m°fhr of pure A at Satm and 350°C, an experimental reactor consisting of 2.5em ID pipe 2m long gives 60% conversion of feed. A commercial plant is to treat 320m'/hr of feed consisting of 50% A, 50% inerts at 25atm and 350°C to obtain 80% conversion. How many 2.5m lengths of 2.0em ID pipe should be used? 3. At present, the elementary liquid-phase reaction A+B 2R+S takes place ina plug flow reactor using equimolar quantities of A and B. Conversion is 96%, Cao= Cno= 0.12moV/i. What is the concentration of R if the same reaction is, carried in an MFR?Under appropriate conditions, A decomposes as follows: A>R-S, ki= k= 0.1/min, R is to be produced from 1000 L/hr of feed in which Cao = 1 moV/L, Cro = Cso= 0. If a backmix reactor is used to cary out the reaction, determine: 1. The time (mins) when cone. of R is max: a 136 #10 b. 75 @, 112 2. Max. cone. (mol/L) of R: a. 0.632 ©. 0.1782 03679 d. 0.519 3. Degree of conversion of A in the reactor at max. cone. of R F 0632 ©. 0.1782 b. 0.3679 d. 0.519 4. Size of reactor to achieve max. conc. of R. a 432.10L c 243.1L b. S712L A. 286.38L ***1£ Cao= 0.25 mol/L, for same reactor used: 5. Time (min) when cone. of R is max. a 63 75 Bl dag 6. Max. cone. (moV/L) of R ; & 0472 c. 0.293 b. 0.621 d. 0.815 7. Degree of conversion of A in the reactor at max. cone. of R a. 0.787 05276 / b. 0.891 d. 0.635 8. Size of reactor to achieve max. cone. of R. a 272 ©. 462.1 b. 346.2 AL 186.15 The ff. data were taken for a liquid-phase reaction in a CSTR having a volume of 2ft° Initial conc. of the reactant A is 0.20Ibmol/f? and all rns are at the same temperature. Tbmol A converted /hr — Flowrate. fhe 0.0450 0.268 0.1250 0.835 1. Conversion for the first run f 0.8491 b. 0.7623 ¢. 0.6126 d. 0.593 2. Conversion for the second run ff 9-7485 b.0.8491 ¢.0.9721 d. 0.6895 y ML, Vv. 2 Apparent Order of the Reaction a3 2 a4 ‘Magnitude of rate constant a. 34.78 £2485 b. 41.23 4.18.97 Using the same initial concentration, calculate the volume (ft*) of a tubular flow reactor to convert 90% of the reactant to products at a flow rate of 40 f° /hr at the same a7 temperature a. 673 172.9 b. 81.69 4.53.81 1.5L/s of a 40% ozone — 60% air (viewed as inerts) mixture at 2.5atm at 82°C passes through a PFR. Under this conditions, ozone decomposes by the homogeneous reaction: 203+ 302 -Toame = kC? k= 0.1L/mol-s For 75% conversion, 8 K0 The space time (6) is equal to: 9%" 206 b02 04 408 The size of the reactor (Liters) is a. 157% 6.227 #1625, 369 If carried out in a batch reactor, what is the time (seconds) to accomplish the same version? 977 b.4I2 6.734. 2136 The homogeneous gas reaction 3A — 2R follows second-order kinetics, For a feed rate of 4m*/hr of pure A at Satm and 350°C, an experimental reactor consisting of 2.5em ID pipe 2m long gives 60% conversion of feed. A commercial plant is to treat 320m*/hr of feed consisting of 50% A, 50% inerts at 2Satm and 350°C to obtain 80% conversion. What is the size (m°) of the experimental reactor? a. 0.000124 0.000982 b. 0.00746 ‘4. 0.00835 we Specific rate constant (L, mol, hr units): “2 187404 c. 358429 476301 d. 651983 For the commercial plant, what is the concentration of A (moV/L) left unreacted? 0.144 a. 0.245 b.0.027 ¢.0.218 | d.0.753 ho wang dem ag og @8cm 1D. ha pl we A Cony) cat the oan) 4 tral aw owSa A batch reactor is to produce 360Ibmol/day, 200days/year of product B according to the liquid phase reaction AB. Reactor cost is P10,000 / ft, investment cost for separating B from A is P20 / Ibmol unreacted A, the direct cost (for reaction process) is P8 / day and P1 / mol A recovered in a recovery process. MWa=MWp=40; pa=701b/f Kinetic data for overall conversion is based ‘on the equation C, = t in mins. No losses of A and B. Time of charging ang discharging is 30 mins / day. Equipment life is 5 years, Hint: use 1 year operation as basis for computing total cost. Determine: Initial concentration (Ibmol/ft*) of reactant A a 2.76 6.3.25 Yl 175 4.4.91 Total Volume (f°) processed per year. 41,143 32,812 b. 39,273 4. 45,619 Time (min) to achieve production rate at optimum operation a 320 ©. 162 b. 285 4.40 ‘Number of batches per year a 561 ©. 6707 b. 763 4. 496 Volume (ft?) processed per batch a 51 .61/ b. 41 4.82 Total Cost a. 348,291 ©. 475,192 1 b. 248,391 4, 259,112 Size (ft) of batch reactor a 56 48 b. 61, 4.62 A second-order gas-phase reversible reaction 2A+2R with ki =3 and k2=2 in Ibmols, ft, hr units is to be conducted in a single CSTR. If the reaction is carried out at a constant temperature of 70°F and latm with a flow rate of A is 25 f'far, |. What is the equilibrium conversion? a. 0.00256 b. 0.00124 ¢. 0.034 #0551 . What is the rate of reaction at 80% of ‘equilibrium conversion? a, 1.83x10% B 3.23x19° ec. 5.31x10% d. 4.54x10* |. What is the volume (f°) of the reactor to attain 80% of its equilibrium conversion? a. 5,363 b. 10,326 ©. 13,552 #8973“eld Bae ely “folm —Qodow Woes = z aoa enick jamrrte) |, Taye _ O= Pho~ Fa nip = ete)” ay + ket _ Gany Pho 7 Wet eam (cae wo wating int) ee - . Pos fo - &(N-™) 4 he (C09 ay _ wart oar eh YP) Te Cy Saet AOPD S tre eye = and “ate BE) = i+ ke cer) as . fee CRT) 5 ke" Ger i aa = EXPERMERTAY RECTOR, —_ enero | Pr Gate A isy pe asatn oft a lea yy wee ; ne whe ke Patino” a 78 wt fa? qe Veet? AL * Gmane Sra |e viv)” y 1 rs ar vo 250 7 bee 0:80 Ve 00° fr oy Feels =o. TES» oaceasrmtipy » 4% (a ve | Gas = Ee qe roshs fe the Spl : (cr Bu) (aac) (aes “Ve an 0.0821 ye te PewecCoesealers) 40-88 a ge - Foams a Ys Get + ge(rws? “Kote Ha aa ” ve he , hem ces ove ~t forte) _ qe hore > (hte) (OG) _ _. o.1 (10%) - ee oe ni [eve L 70. au fe case” afenYor) | = dee MDL, ie. Gate Gem HaHa HOMeer Co acy * 1) ke a aye © Cini 1 (0 1B OMe 49% meee so(the)* o.so(oC Ynee x= 0.15 /min and k= 0.05/min ‘This reaction system isto be analyzed in continuous flow reactors with volumetric feed rate of 5 {/min and the feed composition Cao = 0.5 mole/ft? and Ceo = Cco= 0. (2) What size backmix reactor will maximize the yield of B and what Is the maximum ‘concentration of B in the effluent stream? {(b) For higher production rate of B, which of the following reactors Is preferable? bai single stirred tank of volume 10 ft? .2 two stirred tanks in series, each with a volume of 5 ft? b.3 a plug flow reactor with a volume of 10 ft? 6.8, 6.9, 6.10, 6.13, 6.18, 6.21 (LEVENSPIEL, 3°° ed.)cueza_a MIDTERM Qz72 | XC NAME: i tan David 1 a onforfis | score: Encircle the letter that corresponds to the orrect answer. Absolutely no erasures. 1. The homogeneous gas-phase decomposition of ammonia to nitrogen and hydrogen 2NH -> N2 + 3H, proceeds ‘at 1200°F and 4.6 atm with a first-order rate ~r4 = (10/hr) Cy. Feed consists of 4 Ibmoles/hr of pure ammonia 1.1 What's the i a. 0.0027 | €.0.0236 4.0.0049 1.2 What's the volumetric flow rate (ft*/hr) of the feed gas? (2 pts) a. 3510 b.2107 | 863 @1053 1.3 What size (t) of PER will carry out the said reaction? (5 pts) @ Bs b. 347 621 4.422 2. Asecond-order gas-phase reversible reaction 24 => 2B with ky= 3 and k= 2 in units of lbmols, ft, hrs to be conducted in a single CSTR. If the reaction is carried out at a constant temperature of 70 deg F and 1atm with a flow rate of Ais 25 ft'/hr, | 1.1 whats the equilibrium conversion? (5 pts) * “ a. 0.00256 0.00124 ©0034 Bossi 1.2 what is the rate of reaction at 80% of equilipium conversion? (5 pts a 1.83x10% b.3.23x10* €.5.31 x10° (asaxt0* | 1.3 What is the volume ofthe reactor to attain 80% of its equilibrium conversion? (5 pts) 363 ft b. 10,226 ft* 13,552 ft 4.8973 f° |LAU bade Le 4 (aru) ev) : Claas ay _ J : Woker-bion tayo anes lage a 8 — + 6 8 — Ae res, ra be nr - + Me : ole ocd LY, 4 [Ko fro Jt . ue = 18 2 wy = joo wily = 60Extremo NADA ME ge Le | tage yea 7 fp 64.0 Typ- 2.0% We ae Mv. Ae [se ee nS yp =f te == fee SE ee — pt Hol! RP ~—— fe = Gta] oe 7 2) BE eg, yw Wight Compare vecatre uber’ _aguinus pha Ye ‘x bee [Nos mae phe Bee ay Yer MH. 97-89 phn ne ay 2 aren pe ‘ - : Sy ee [eit] ox Pt = Ce ES Ft = comnhut fe (rei) fe 2 ed Lagat eort La tf ag “> 0-9o (uven) ! ~ 4Patani, flan David _T- ei Caps.n Gig #9 FT ones ie 1) Giver Pm" go ware 2) Gime “Wy WR Gert, — raged: Yo Xe Rel ae aa cata te gat ir ge on ah 2? Sole: GO an es pum = Flee ht ok (w-& \ Gr = (I-%) Rd Or \ Gor kar = Infi-0.9) = 0.4 ut n(*fou) VY + 2.054% wf mays Pa (Ge 4 RG | wt V@oa |” Re a “1 “HT "Gl Get kGwlhm) i Ge (i-trm)) OQ. 26~ 2 inf wa 1(ard7 Kem) (Ge) (RCM) TeT TC) Gr a ig cto Op-ed i Gow) (14 Rm) Gy 1.99 fi | any xX r ee inated | wm exe) C14 Rox) ip tae i¢ a rye tram. i eae = Ga) (1) = jg Gwe) dent pls tae ke Y= I. FeuRatan, lat Rewid’) To theta HEI9 A Ged 7 aoe ape ie 4 Sa [ WOU Ter ms ey Well i L vane Aw 7 pr the in eis 4 teh tos 1 me Go ae age Pact Ve aotwen, a0 7 Go. wen OF =r ,if — el Gea) a wey st - ae) rte "Ge Ge _ cc Gokt wok (CO: fy. Ham, 7 or + (eo: a. | eh + Ge) (boat, Ge ere > |_ mrt tte au 4 alu) = ts cher F 0.0) oe — Ea er maT T | ng ae ver cri Geli, por aR, ets Gem BD iver: rl Ro) wpe ean oe art * — Gm es : 1. Bo | Whe (re © pee me Sot “eyes fey 8 Faia eaw_(_ me oo) | Crm: ge Gime FIR a Z t t ni | ¢ lp 3Ne = 80) ¥a Ff I | ‘| t Fe fo-fd@ _- f do q Ty pat 7 pros —— fia Wf } 7 mana aX dap , a Ba ~ jar a hel peat ge aot. ot or Mrgett Render: RUE LASALUAN CHOOSE TE HONEST EVEN IF OTHER AE NOT, EVENIF OTHERS CANNOT & EVEN IF OTHERS WL NOT. fromthe Student Handbook 2008-208 See 95,06 75:76 ‘ie Urry strong pros any fom of ite dhonesty, mort comcnon of whch ae CHEATING and lags. Sconcaly ronned we te folowing ac of doses: Chern uring examin hich oe nce frm cop om anche pers’ awe ng for ahora mater ging information to anathar tude coicing of aterting cole wth ther ses darn exominaton, havin some ese ake oe’ ‘arraen tating for another prion andsng nso nee tents dingo xo, The eno fr soho onde The Ace ante! Dahanety iran rom inknam ft! lon f ce forthe signer cr enamiaton ncuron, serine thet fe Soe, par pron arte ano, ‘he ude’ yn the rivera msm pesto mom cana University of St. La Salle ~ Bacolod City COLLEGE OF ENGINEERING& TECHNOLOGY & Midterm Examination AY 2017-2018 o HE23 ~ Chemical Reaction Engineering W Ritam, fic _Davidl_T-_ercruy $s Scorek Cay vy = 22.1 a sn (83.36 )(0. 00385 J2 [oon °. ones] = Boe £t3, 90, (LEVENSPIEL) At present the elementary liquid: phase reaction ZL" A+ B—>®R +S takes place ina plug flow reactor using equic molar quantities of A and B, Conversion 4s 96%, Ca, = Cy = 1 mole/1i (a) If a backmix reactor ten times as large as the plug flow reactor were hooked up in parallel with the existing unit, } what fraction could production be increased? (b) Does the concentration level of the feed affect the an and if s0j in what way? Note: Conversion is to remain unchanged. Solution: Bo) é. rl Ve-v_[ Fe y= 0.04 Po=Cey Things =lmole Li : & TT TT Canoe XA 0%“the-plug-Plow-readvor Material balance around bacimix reactor AML = SAgKa Caan (1)(0.96) ShoXt Cay _(2(0.96) ° 7 ke,” K(.0, 7 ‘ov = 600 er Fe gy Dividing © (1) and (2), Ve oe, PB es Bl at 107 50 Fp = Ook Fy Sand F = Py + Ob Py = 16 PL eo creas: i. ANS. Hence, production is increased wae (bb) For Plug Flow 1g : - a x Ch (=X Cay O; Get év Sey A ea, Gp For the CSTR Chg Ky le K Ga(1 ~ Xq)? HOA, (ax, )* Dividing (3) by (4), we have “yf = A lor 1, za") Fy As we can see Crom the above ratio, the concentration level o° +) feed does not affect the unswer if the conversion is to rv unchanged. The homogeneous gas-phase decomposition of anmonia to nitr hydrogen 2NH; >No + 3ilp proceeds at 1200°F with first rate ~ r, = (10 hr“1)” cj, “What aize’ plu flow reactor at. 2.0) and 4.6 atm can produce 808 conversion of a feed consistinn of Yonoles/nz of pure ils? Solution: Pils ay My + 3H Go (2% i 10 Gow 2A >» Bt+9C ie Th = 10 =210nk v- 1 Va 2b? Ln ae A caren ve ey pag a¥ were bon fye Got aaa pi)a7 07 est B 4 iy Cy etn Cu Xe 38>, Gp - Go Xa Ge Go= (Ov-G) Geis Go-Go + Cy, Cy = wipro! Hy Gr = 0.69 GQ 20 2 foe 2 dh Apo ef low a) tm (aonte) - je Aleca-s “ie (ae yyfala *” JG Joa !* get Ar Pe nye lv Ge tir sctilaa Ae tse i Dene? fe tAte ee eee Gu | a Gy ie . -ntlens eB pti see 2,008 Gs 1008, 0.68) = 0,008 Gx Go 0. Wie Ga OoF <[n awe. ep watae 2 ae 1 Obata, * o . Ooh Cry 6392\(0aqa-ty) © Bila 00009 = Cre 2 gel" O03 oof Gwar Gi G27 G = Gor Gu» Cr é a! 4 Coste 2 2,002 F008, Cro eo%a 1Cke cot | = Def Oc~ se f f J, [ironed Ty Ga 4 KD og ater Bas Meas Plot: He ogy Pins te pepect thes Che 4Q0 AY = ) 4 a Cha © Ga (xa) = h(t vow) tp CGo) pg BC ” > C4) ng Crd Gee a » ye = G azt} G-G= biome d (#4r) banal = 06708 we au ‘A n fy ~de £4, Ce, ot -dt , fA. 7 IP eel 318]Stee IG ae = aes: = DY meenwtih | po 0 kag i) ee Wt 0 fyi: foie: tyr KG” wet ony Mae wot ganas arom | amo | sor ant | cunt | cases Say * et * * Heath Or ne GRY om): fase 2 (Sorem)- ees 0 A) (ox) «Soom cng CRONE) He =F eG hte) me tt ~ ¢ oo" * lina eg, gzinks v0a85 POAC es a a ta onvan te osbal & afar Wn) * afiareqt-hq) 4 DSCC? - 8 = 25 Co (IK) Gattis) Bein sf Cea (Get -ae®) | 9 fe Ge% Cony Coke v 2 om te deol e! vm fe - ere oe | yp 0-0 (0-759) ae ce (“aes He asf uno |fot(r0r8)] -3 (0-40) ese ie TT PS _ Me = 2 2% 1% \vrom.os 3] et Bf +) Sia“sh, ao ae oteue ho =8 ot HEF | nel - a= Or OS ae We? \e Viqp 50-92 RO 1. Plasto Wai 9% ~tp ie pts) [J Linear velocty ofthe es (ft/s) at 70% flooding 4 a9 977 10. 2 a7A24 719% i Jumn in ftis 8 Gpts) J c] The diameter: ee es oa c. 2.606 4.2.70 yp Ptr 009