Roadmap - Main Corrected 2013
Roadmap - Main Corrected 2013
Roadmap - Main Corrected 2013
R''NH2 R'R''NH
R C R' R C R' R OTos R NR'R''
R'' = H or R'' = H or
N carbon chain O carbon chain
R''
CrO3 / H+ or R'R''NH
1. LiAlH4 1. LiAlH4 TosCl / X R',R'' = H or
2. H+ / H2O Cr2O72- / H+ or 2. H+ / H2O pyridine carbon chain
CrO3 / pyridine
OH
R CH R' R CH R' R OH R X
NHR'' OH
Mg /
dry ether
1. R'CHO
R'O CN
2. H+ / H2O
1. R' C R''
R'
O
R C R'' R MgX R O R' R CN
2. H+ / H2O
OH
H+ / H2O
1. CH2O
2. H+ / H2O 1. CO2
2. H+ / H2O
R C OR'
R'R''NH R',R'' = H or
R'NH2
R C H R C H CrO3 / H+ or H+/ carbon chain