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Alcohol, Phenol , Ether

OH
Alcohols 1H20
+

CH3
H I
I R-CH =
CH2 R CH
CH3
- -

of
CH,
CHy-CHz-OH
- y---
CH
-
1o alcohol dis H+
R-CH -

CH
H20

2: alcohol So alcohol
Carbocation

OH
vinylic alcohol x
Electrophilic Addition
CHI = CH -

Rate of a stability of
x
alcohol
CH2CH-cHy-oH allylic
=

Run Carbocation
Benzylic alcohol
CHOH Mercuration)
2) OMDM
(Ony Mercuration De

CH2-OH CH2-OH ) HgCOAC2


OH
tRO
dre-or R

cte
R-CH
CH2
2) CH
- -
=

OH
NaBHn
CH2
=

ethylene glycol dia-or Source ofOH: -

H20
glycerol Source of H:
-NaBHy

PreparationofAlcohols NOTE:
addition
From Alkenes
Addition ofWater
x
Ants
)
Markovnikoy'srule
a) Acidcatalysed hydration > No
rearrangement
Reagent: bil. H2SO4 or HT H20 or Hot > No carbocation

Cyclic
x intermediate

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